JP4570905B2 - Topical skin preparation - Google Patents

Description

  The present invention relates to an external preparation for skin, particularly to an external preparation for skin containing a film agent.

Cosmetics that give a firm feeling to the skin usually contain a water-soluble or oil-soluble polymer as a film agent. However, the cosmetics have the disadvantage that the stickiness is felt strongly due to the viscosity generated when the solvent is volatilized and the polymer is coated on the skin, and the feeling of use is not good.
Therefore, JP 2000-34218 A discloses a skin external preparation in which a natto extract is combined with a film agent, and the skin external preparation has little stickiness after application and feels firm. It has been reported.

In recent years, skin care cosmetics as well as makeup cosmetics have the effect of blurring skin color unevenness such as spots, freckles, dullness, and uneven skin texture such as pores and wrinkles, creating a transparent skin. There has been a demand for an external preparation for skin having a good skin rendering effect in addition to good usability.
JP 2000-34218 A

However, no product that satisfies both the feeling of use and the skin correction effect has been developed, and the development of a new skin external preparation has been desired.
The present invention has been made in view of the above-described problems of the prior art, and an object thereof is to provide an external preparation for skin having a good firmness without causing stickiness and having an excellent effect of producing beautiful skin.

（式(I)中、Ｇｌｕは多糖化合物の糖残基であり、Ｘはカルボニル基、アミノ基、エーテル基、カルバモイル基、及び−ＣＨ_２ＣＨ（ＯＨ）−から選ばれる２価の結合基である。Ｙは主鎖中に酸素原子、窒素原子、硫黄原子、フェニレン基、カルボニルオキシ基又はオキシカルボニル基を有することができ、ヒドロキシ基、アルコキシ基及びアルキル基から選ばれる置換基を有することができる総炭素数２〜８のアルキレン基である。Ｒ^１は炭素数１〜８の１価有機基であり、Ｒ^２、Ｒ^３、Ｒ^４はそれぞれ同一でも異なっても良く、炭素数１〜８の１価有機基又は−ＯＳｉＲ^５Ｒ^６Ｒ^７で示されるシロキシ基である。ただし、Ｒ^５、Ｒ^６、Ｒ^７はそれぞれ同一でも異なっても良く炭素数１〜８の１価有機基である。ａは０、１又は２である。） As a result of studies conducted by the present inventors in order to achieve the above-mentioned object, the combination of a siliconized polysaccharide compound having a specific structure and a specific inorganic composite powder allows the skin to feel firm without causing stickiness. It was found that a skin external preparation excellent in effect for producing beautiful skin can be obtained, and the present invention has been completed.
That is, the skin external preparation of the present invention comprises (a) 0.01 to 3.0% by mass of a silicone- modified polysaccharide compound having a structure represented by the following general formula (I):
(B) containing 0.1 to 20% by mass of an inorganic composite powder obtained by sequentially laminating two or more inorganic oxides having different refractive indexes from those having a high refractive index on a scaly substrate,
The inorganic composite powder is characterized in that the difference in refractive index between the outermost inorganic oxide layer and the inorganic oxide layer adjacent to the outermost layer is 0.6 or less.
(Chemical formula 1)

(In Formula (I), Glu is a sugar residue of the polysaccharide compound, X is a divalent linking group selected from a carbonyl group, an amino group, an ether group, a carbamoyl group, and —CH ₂ CH (OH) —). Y may have an oxygen atom, a nitrogen atom, a sulfur atom, a phenylene group, a carbonyloxy group or an oxycarbonyl group in the main chain, and may have a substituent selected from a hydroxy group, an alkoxy group and an alkyl group. An alkylene group having 2 to 8 carbon atoms in total, R ¹ is a monovalent organic group having 1 to 8 carbon atoms, and R ² , R ³ , and R ⁴ may be the same or different; 8 or a siloxy group represented by —OSiR ⁵ R ⁶ R ⁷ , wherein R ⁵ , R ⁶ and R ⁷ may be the same or different and each is a monovalent organic group having 1 to 8 carbon atoms. A is 0, 1 or In is.)

In the above-mentioned external preparation for skin, in formula (I), X is preferably a carbonyl group.
The (b) inorganic composite powder is preferably an inorganic composite powder obtained by laminating titanium oxide, aluminum oxide, and silicon oxide in this order on a scaly substrate.
In the above-mentioned external preparation for skin, (a) the compounding amount of the silicone-modified polysaccharide compound is 0.01 to 3.0% by mass, and (b) the compounding amount of the inorganic composite powder is 0.1 to 20% by mass. Is preferred.
In the external preparation for skin, (c) one or two or more kinds of cross-linked polymethylsiloxane selected from the group consisting of dimethicone / vinyl dimethicone cross polymer, dimethicone cross polymer, and vinyl dimethicone / lauryl dimethicone cross polymer It is preferable to include.

  According to the present invention, by blending a combination of a siliconized polysaccharide compound having a specific structure and a specific inorganic composite powder, it is possible to impart firmness to the skin without causing stickiness, and excellent skin correction effect. A skin external preparation can be obtained.

（式(I)中、Ｇｌｕは多糖化合物の糖残基であり、Ｘはカルボニル基、アミノ基、エーテル基、カルバモイル基、及び−ＣＨ_２ＣＨ（ＯＨ）−から選ばれる２価の結合基である。Ｙは主鎖中に酸素原子、窒素原子、硫黄原子、フェニレン基、カルボニルオキシ基又はオキシカルボニル基を有することができ、ヒドロキシ基、アルコキシ基及びアルキル基から選ばれる置換基を有することができる総炭素数２〜８のアルキレン基である。Ｒ^１は炭素数１〜８の１価有機基であり、Ｒ^２、Ｒ^３、Ｒ^４はそれぞれ同一でも異なっても良く、炭素数１〜８の１価有機基又は−ＯＳｉＲ^５Ｒ^６Ｒ^７で示されるシロキシ基である。ただし、Ｒ^５、Ｒ^６、Ｒ^７はそれぞれ同一でも異なっても良く炭素数１〜８の１価有機基である。ａは０、１又は２である。） (A) Siliconized polysaccharide compound The siliconized polysaccharide compound used in the present invention is represented by the following general formula (I).
(Chemical formula 2)

(In Formula (I), Glu is a sugar residue of the polysaccharide compound, X is a divalent linking group selected from a carbonyl group, an amino group, an ether group, a carbamoyl group, and —CH ₂ CH (OH) —). Y may have an oxygen atom, a nitrogen atom, a sulfur atom, a phenylene group, a carbonyloxy group or an oxycarbonyl group in the main chain, and may have a substituent selected from a hydroxy group, an alkoxy group and an alkyl group. An alkylene group having 2 to 8 carbon atoms in total, R ¹ is a monovalent organic group having 1 to 8 carbon atoms, and R ² , R ³ , and R ⁴ may be the same or different; 8 or a siloxy group represented by —OSiR ⁵ R ⁶ R ⁷ , wherein R ⁵ , R ⁶ and R ⁷ may be the same or different and each is a monovalent organic group having 1 to 8 carbon atoms. A is 0, 1 or In is.)

In the general formula (I), Glu represents a sugar residue of a polysaccharide compound. As such a polysaccharide compound, various known polysaccharide compounds can be used, for example, cellulose, hemicellulose, gum arabic, tragacanth gum, tamarind gum. , Pectin, starch, mannan, guar gum, locust bean gum, quince seed gum, alginic acid, carrageenan, agar, xanthan gum, dextran, pullulan, chitin, chitosan, hyaluronic acid, chondroitin sulfate, and derivatives of these polysaccharide compounds such as carboxy Examples thereof include polysaccharide compound derivatives that have been subjected to methylation, sulfation, phosphorylation, methylation, ethylation, addition of alkylene oxides such as ethylene oxide and propylene oxide, acylation, cationization, and low molecular weight.
Of these, ethyl cellulose or pullulan is preferable, and pullulan is particularly preferable. In the present invention, the average molecular weight of the polysaccharide compound varies depending on the kind of the polysaccharide compound, but is usually preferably about 1,000 to 5,000,000.

Examples of the divalent linking group represented by X include a carbonyl group, an amino group, an ether group, a carbamoyl group, —CH ₂ CH (OH), and the like, and particularly a carbamoyl group (═CONH—). It is preferable.
As the alkylene group represented by Y, an alkylene group having an oxygen atom, a nitrogen atom, a sulfur atom or the like in the main chain, an alkylene group having an arylene group such as a phenylene group in the main chain, a carbonyloxy group in the main chain or An alkylene group having an oxycarbonyl group can be exemplified. These alkylene groups can have a substituent such as a hydroxy group, an alkoxy group, or an alkyl group, and the terminal atom of the alkylene group may be a hetero atom such as an oxygen atom, a nitrogen atom, or a sulfur atom. When Y is illustrated, — (CH ₂ ) ₂ —, — (CH ₂ ) ₃ —, — (CH ₂ ) ₄ —, — (CH ₂ ) ₆ —, — (CH ₂ ) ₈ —, — [CH ₂ CH (CH ₃ )] —, — (CH ₂ ) ₂ O (CH ₂ ) ₃ —, —CH ₂ CH (OH) —CH ₂ — and the like are mentioned, and preferably — (CH ₂ ) ₃ —. Propylene group.

In the general formula (I), the monovalent organic group having 1 to 8 carbon atoms found in R ^{1 to} R ⁷ is an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, an alkenyl group, and an alkyl fluoride. Means a group having 1 to 8 carbon atoms selected from a group, for example, an alkyl group such as a methyl group, an ethyl group, a propyl group and a butyl group; a cycloalkyl group such as a cyclopentyl group and a cyclohexyl group; an aryl group such as a phenyl group; An aralkyl group such as a benzyl group; an alkenyl group such as a vinyl group and an allyl group; a fluorinated alkyl group such as a 3,3,3-trifluoropropyl group, and the like.

R ² , R ³ and R ⁴ may each be a siloxy group represented by —OSiR ⁵ R ⁶ R ⁷ . Examples of such a siloxy group include a trimethylsiloxy group, an ethyldimethylsiloxy group, a phenyldimethylsiloxy group, a vinyldimethylsiloxy group, and a 3,3,3-trifluoropropyldimethylsiloxy group. Note ^R 1 to R ⁷ may be the same or different, in the silicone-treated polysaccharide compound of the present invention, in a = ^0, it is particularly preferable R ^2, R 3, ^{R 4} is a methyl group.

上記一般式(II)中、Ｙ、Ｒ^１、Ｒ^２、Ｒ^３、Ｒ^４及びａは前記一般式(I)と同じである。
また、Ａは多糖化合物の有する反応性官能基と反応しうる官能基であり、例えば、イソシアネート基、エポキシ基、ビニル基、アクリロイル基、メタクリロイル基、アミノ基、イミノ基、水酸基、カルボキシル基、メルカプト基等が挙げられる。 The siliconized polysaccharide compound is formed by reacting a reactive functional group (hydroxyl group, carboxyl group, etc.) of the polysaccharide compound with a silicone compound represented by the following general formula (II). A known method can be used for the reaction between the silicone compound and the polysaccharide compound.
(Chemical formula 3)

In the general formula (II), Y, R ¹ , R ² , R ³ , R ⁴ and a are the same as those in the general formula (I).
A is a functional group capable of reacting with the reactive functional group of the polysaccharide compound. For example, isocyanate group, epoxy group, vinyl group, acryloyl group, methacryloyl group, amino group, imino group, hydroxyl group, carboxyl group, mercapto Groups and the like.

A particularly preferable silicone-modified polysaccharide compound used in the present invention is a silicone-treated pullulan represented by the following formula (III). In the formula (III), PL represents a glucose residue of pullulan.
(Chemical formula 4)

  In the silicone-modified polysaccharide compound of the present invention, the bonding ratio of the silicone compound to the reactive functional group of the polysaccharide compound is not necessarily 100%. However, if the bonding ratio of the silicone compound to the polysaccharide compound is too low, the present invention The effect of is not fully demonstrated. In addition, it is preferable to use the silicone-modified polysaccharide compound by dissolving it in a linear or cyclic low molecular weight silicone oil or light isoparaffin, since it can be easily blended into an external preparation for skin and a feeling of firmness is improved. Accordingly, in the present invention, it is desirable that the silicone compound is bound to such an extent that the silicone-modified polysaccharide compound is dissolved in a linear or cyclic low molecular weight silicone oil or light isoparaffin. Specifically, although it varies depending on the type, it is usually preferable that the average number of bonds (substitution degree) of the silicone compound per unit saccharide unit of the polysaccharide compound is 0.5 to 2.5. In the present invention, the degree of substitution is calculated from the Si content (% by mass) in the compound.

  In the external preparation for skin of the present invention, the amount of the silicone-modified polysaccharide compound varies depending on the form of the external preparation for skin, but is preferably 0.01 to 5.0 mass%, preferably 0.01 to 3.0 mass%. It is particularly preferred. If the amount is less than 0.01% by mass, sufficient firmness cannot be imparted, and if it exceeds 5% by mass, the film tends to be twisted and the feeling of use tends to be impaired.

(B) Inorganic composite powder The inorganic composite powder of the present invention is obtained by laminating two or more inorganic oxides having different refractive indexes on a scaly substrate in order from those having a high refractive index. And a difference in refractive index between the inorganic oxide layer and the inner inorganic oxide layer is 0.6 or less.
The scaly substrate preferably has an average particle diameter of 2 to 20 μm and a thickness of 0.05 to 1 μm. Such scaly substrates include natural minerals such as mica, talc and sericite, synthetic mica, synthetic talc, synthetic sericite, plate-like titanium oxide, plate-like silica, plate-like aluminum oxide, boron nitride, plate It is preferable that it is 1 type, or 2 or more types selected from plate-like barium sulfate, plate-like titania-silica composite oxide, and the like.

Examples of inorganic oxides sequentially coated on the scaly substrate together with the refractive index are as follows.
Titanium oxide (2.50), zinc oxide (2.0), zirconium oxide (2.2), cerium oxide (2.2), tin oxide (2.0), thallium oxide (2.1), titanic acid Barium (2.4), aluminum oxide (1.73), magnesium oxide (1.77), yttrium oxide (1.92), silica (1.45), magnesium fluoride (1.38), magnesium carbonate ( 1.5), calcium fluoride (1.43).

In the inorganic composite powder according to the present invention, two or more kinds of inorganic oxides having different refractive indexes selected from the inorganic oxides are formed in order from the higher refractive index. The difference in refractive index between the inorganic oxide formed in the outermost layer and the inorganic oxide in the inner layer must be 0.6 or less, and a particularly preferred range is 0.5 to 0.05.
In the present invention, in order to further enhance the transparency of the light skin, it is desirable that the difference in refractive index between all adjacent layers be 0.6 or less, particularly 0.5 to 0.05. That is, an inorganic oxide whose difference from the refractive index of the inorganic oxide of the first layer is 0.6 or less is selected as the second layer, and the same is selected for the third layer or less formed as necessary. Is desirable.

In addition, the inorganic composite powder according to the present invention has a thickness of at least one layer among the layers below the second layer even when the difference in refractive index between the layers is not less than 0.6. It may be within a range of ± 20% of the calculated value d. This is because the phase of the reflected light in the layer located below the one layer and the reflected light in the one layer are reversed, the reflection of light is suppressed by the light interference action, and it has a sense of transparency. Because.
Formula: d = (λ × X / 4) / n
(In the above formula, λ is the wavelength of visible light, X is an integer that is an odd number, and n is the refractive index of the inorganic oxide.)
In addition, according to the usage purpose of cosmetics such as the desired color tone and color, and the usage environment such as daytime, nighttime, lighting, clothing color, etc. The wavelength of visible light to be used can be selected, and the thickness of the layer can be adjusted.
As the value of the integer X which is an odd number, it is usually preferable to use 1 for the reason that the thickness of the layer can be reduced. For example, when aluminum oxide is coated on a titanium oxide layer, since λ = 550 nm and n = 1.73, the thickness of the aluminum oxide layer is about 80 nm.

In particular, it is preferable to form an inorganic oxide having a refractive index of 1.5 or less, particularly 1.5 to 1.35, in the outermost layer of the inorganic composite powder. A particularly preferred inorganic oxide for the outermost layer is silica.
More preferably, it is a composite powder in which talc or sericite is sequentially coated with titanium oxide, aluminum oxide, and silica. Commercially available materials include, for example, Coverleaf AR-80 ^™ (talc coated with titanium oxide, aluminum oxide, and silica in order; see FIG. 1), Coverleaf AR-20121M ^™ (Sericite with titanium oxide, aluminum oxide, And silica coated in order) (manufactured by Catalyst Kasei Kogyo Co., Ltd.).

As a method for coating the inorganic oxide, a predetermined amount of a metal salt that is a precursor of the inorganic oxide is hydrolyzed, or similarly, a predetermined amount of an organometallic compound is hydrolyzed in an alcohol solvent, and the hydrolyzate is used as a base. A conventionally known method such as a method of depositing on a material or a base material on which a coating layer is formed can be employed.
For example, by dispersing a flaky substrate in water, adding a predetermined amount of a metal salt such as titanyl sulfate, hydrolyzing in an alkaline atmosphere, and depositing a metal salt hydrolyzate on the surface of the flaky substrate A titanium oxide coating layer having a predetermined thickness can be obtained.
In addition, when silica is coated as the outermost layer, a predetermined amount of an alkali metal silicate aqueous solution or an organic silicon compound is added to the dispersion of a scale-like substrate on which a coating layer having a refractive index higher than that of silica is added. Depending on the method, a silica coating layer having a predetermined thickness can be formed by a method such as adding an acid or an alkali to attach a polymer of silicic acid (hydrolysis condensation polymer) to the surface of the scale-like substrate. . In order to form a silica coating layer, other conventional methods may be employed.

  In the present invention, the coating thickness of the inorganic oxide is determined by the geometric surface area of the scaly substrate or the scaly substrate coated with the inorganic oxide or the specific surface area measured by the nitrogen adsorption method or the like. It can be determined from the density of the oxide. Further, a predetermined amount of metal salt or organometallic compound to be added can be calculated from the amount of metal oxide having a predetermined film thickness.

The coating amount of the total inorganic oxide is not particularly limited, but is preferably in the range of 1 to 70 parts by weight, more preferably in the range of 5 to 50 parts by weight with respect to 100 parts by weight of the scaly substrate. If it is less than 1 part by weight, it is difficult to obtain a sufficient skin effect and stickiness reduction effect, and if it exceeds 70 parts by weight, it tends to have an unnatural finish or a poor feel.
The inorganic composite powder of the present invention may be used by treating the surface with silicone, a fluorine compound or the like.

In the external preparation for skin of the present invention, the blending amount of the inorganic composite powder is preferably 0.1 to 20% by mass, and particularly preferably 1.0 to 5.0% by mass. If the amount is less than 0.1% by mass, sufficient stickiness reduction effect and beautiful skin directing effect cannot be obtained. .
The external preparation for skin of the present invention can be uniformly and uniformly oriented on the skin when a skin cosmetic is applied by combining the silicone-modified polysaccharide compound and the inorganic composite powder. Gives skin firmness. Moreover, the stickiness resulting from the silicone-modified polysaccharide compound is reduced. Furthermore, there is a sense of transparency, and it is possible to hide the skin defects, and it is excellent in the effect of producing beautiful skin.

(C) Crosslinkable polymethylsiloxane In the present invention, by further blending the crosslinkable polymethylsiloxane, the twist during application can be reduced and a smooth feel can be imparted.
The cross-linked polymethylsiloxane used in the present invention is an INCI name dimethicone / vinyl dimethicone crosspolymer obtained by cross-linking reaction of an organohydrogensiloxane and vinyldimethylsiloxane, or a poly-silicone-11; Examples include those referred to as INCI name dimethicone crosspolymers obtained by cross-linking alkene; those referred to as INCI name vinyl dimethicone / lauryl dimethicone cross polymers obtained by cross-linking lauryl origanohydrogensiloxane and vinyldimethylsiloxane.
The crosslinked polymethylsiloxane is preferably blended in a state where it is swollen with a low-viscosity oil, particularly a linear or cyclic silicone oil.
Examples of commercially available products of the swelling product of the crosslinked polymethylsiloxane used in the present invention into a low-viscosity oil include the following, which can be obtained and used.
As a swelling product of what is called dimethicone / vinyl dimethicone crosspolymer or polysilicone-11, a mixture of KSG-15 ^™ ((dimethicone / vinyl dimethicone) crosspolymer and cyclopentasiloxane manufactured by Shin-Etsu Chemical Co., Ltd. is used. Crosslinked product is about 5%); KSG-16 ^™ ((dimethicone / vinyl dimethicone) crosspolymer, dimethicone is 6 mPa · s, and the crosslinked product is about 25%); KSG-18 ^™ ((dimethicone / vinyl dimethicone) crosspolymer KSG-41 ((vinyl dimethicone / lauryl dimethicone) crosspolymer, liquid paraffin mixture, about 30% crosslinked); KSG-42 ^™ ((vinyl dimethicone) / Lauryl dimethicone) cross polymer , Cross-linked product with a mixture of light isoparaffin is about ^{25%); KSG-43 TM} (( vinyl dimethicone / lauryl dimethicone) crosspolymer, a crosslinked product of a mixture of glyceryl tri-2-ethylhexanoate was about 30%); KSG-44 ^TM ((vinyl dimethicone / lauryl dimethicone) cross polymer, squalane mixture is about 5% crosslinked) and DC9040 ^TM (dimethicone cross polymer, decamethylcyclopentasiloxane mixture made by Toray Dow Corning Co., Ltd.) DC9041 ^™ (dimethicone crosspolymer, mixture of dimethicone 5 mPa · s and 16% of crosslinked product); DC9045 ^™ (dimethicone crosspolymer, mixture of decamethylcyclopentasiloxane and 12.5% of crosslinked product) ) Or GRANT G ANSIL GCM ^TM (crosslinked product of a mixture of polysilicone -11 and octamethylcyclotetrasiloxane about ^{6%); GRANSIL GCM-5} TM ( polysilicone -11 and mixtures crosslinked product of decamethylcyclopentasiloxane about 6% ); GRANSIL IDS ^™ (polysilicone-11 and isodecane mixture is about 7% crosslinked); GRANSIL DMG-6 ^™ (polysilicone-11 and dimethicone 6 mPa · s mixture is about 18% crosslinked); GRANSIL DMG-20 ^™ (Polysilicone-11 and dimethicone 20 mPa · s mixture is about 25% crosslinked); GRANSIL DMG-50 ^™ (Polysilicone-11 and dimethicone 50 mPa · s mixture is about 26% crosslinked) GRANSIL PM ^TM (Poly And a mixture of silicone-11 and phenyltrimethicone is about 20%), GRANSIL ININ ^™ (a mixture of poly-silicone-11 and isononyl isononanoate is about 15%).

  The cross-linked polymethylsiloxane is preferably blended in an amount of 0.01 to 10 mass%, more preferably 1.0 to 5.0 mass%, based on the total amount of the external preparation for skin. If it is less than 0.01% by mass, sufficient effects of the composition may not be obtained, and if it exceeds 10% by mass, the feeling of use tends to be impaired.

  The skin external preparation of this invention is prepared by mix | blending said essential component with the existing skin external preparation base. In addition to the essential components described above, the external preparation for skin of the present invention is not limited to the effects of the present invention, and other components usually used in external preparations for skin such as cosmetics and pharmaceuticals, for example, powder components, liquid fats and oils, Solid fats, waxes, hydrocarbons, higher fatty acids, higher alcohols, esters, silicones, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, humectants, water-soluble polymers, thickeners , Film agent, ultraviolet absorber, sequestering agent, lower alcohol, polyhydric alcohol, sugar, amino acid, organic amine, polymer emulsion, pH adjuster, skin nutrient, vitamin, antioxidant, antioxidant aid, A fragrance, water and the like can be appropriately blended as necessary, and can be produced by a conventional method according to the intended dosage form.

  Other components that can be blended include, for example, preservatives (ethyl paraben, butyl paraben, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); whitening agents (for example, , Placenta extract, yukinoshita extract, arbutin, kojic acid, vitamin C, magnesium ascorbate phosphate, glucoside ascorbate, etc .; various extracts (eg, alum, auren, shikon, peonies, assembly, birch, sage, loquat) , Carrot, aloe, mallow, iris, grape, yokoinin, loofah, lily, saffron, senkyu, ginger, hypericum, onionis, garlic, pepper, chimney, red snapper, seaweed, etc.), activator (e.g. royal jelly, photosensitizer, A blood circulation promoter (eg, nonyl acid valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, tannic acid, α-borneol, nicotinic acid tocopherol, inositol Hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, etc.); antiseborrheic agent (eg, sulfur, thianthol, etc.); ) And the like.

  The external preparation for skin of the present invention can be widely applied to cosmetics, pharmaceuticals, and quasi drugs applied to the outer skin. The dosage form is arbitrary, such as solution system, solubilization system, emulsification system, powder dispersion system, water-oil two-layer system, water-oil-powder three-layer system, gel, aerosol, mist, capsule, etc. It can be provided in the form. Further, the product form of the external preparation for skin of the present invention is arbitrary, and facial cosmetics such as skin lotion, emulsion, cream, pack, etc .; foundations, funny, blusher, lipstick, eye shadow, eyeliner, mascara, sunscreen, etc. Makeup cosmetics; body cosmetics; aromatic cosmetics; skin cleansers such as make-up removers, facial cleansers, body shampoos; hair cosmetics such as hair rinses and shampoos; ointments; bath preparations; It can be applied in any form as long as it is used.

Hereinafter, the present invention will be described in more detail with reference to examples. The present invention is not limited to these examples. Unless otherwise specified, the blending amount indicates mass%.
Prior to the examples, the evaluation method used in the present invention will be described.
(1) Stickiness The test sample was applied by hand to the upper arms of 20 female panelists, a questionnaire about stickiness after application was conducted, and the following criteria were evaluated.
A: More than 16 panelists answered that there was no stickiness or sliminess.
○: 12 to 15 panelists answered that there was no stickiness or sliminess.
Δ: 8 to 11 panelists who answered that there was no stickiness or sliminess.
×: Seven or fewer panelists answered that there was no stickiness or sliminess.

(2) Feeling feeling The test sample was applied by hand to the upper arms of 20 female panelists, and a questionnaire was conducted on the feeling of stickiness of the skin after application, and the following criteria were used.
A: More than 16 panelists answered that there was a beam on the skin after application.
○: 12 to 15 panelists answered that the skin after application had a beam.
Δ: There were 8 to 11 panelists who answered that there was a beam on the skin after application.
×: Seven or fewer panelists answered that there was a beam on the skin after application.

(3) Shaft A test sample was manually applied to the upper arm of 20 female panelists, a questionnaire was conducted on the warp of the powder after application, and the following criteria were evaluated.
A: More than 16 panelists answered that there was no powder distortion.
○: There are 12 to 15 panelists who answered that the powder was not warped.
Δ: There are 8 to 11 panelists who answered that there was no powder sag.
×: Seven or fewer panelists answered that there was no powder distortion.

(4) Familiarity and Elongation Test samples were applied by hand to the upper arms of 20 female panelists, a questionnaire was conducted on familiarity and elongation during application, and evaluation was performed according to the following criteria.
A: More than 16 panelists answered that they were familiar and stretched well when applied.
○: 12 to 15 panelists answered that they were familiar and good in stretching.
Δ: 8 to 11 panelists answered that they were familiar and stretched well during application.
X: Seven or fewer panelists answered that they were familiar and stretched well during application.

(5) Formulation stability After storing a sample at -20 degreeC for one week, it returned to room temperature and observed the state.
○: No abnormality Δ: Slight aggregation of powder is observed.
X: Agglomeration of powder is observed.

(6) Color unevenness and uneven blurring effect The test sample was applied by hand to the faces of 20 female panelists, and a questionnaire was conducted to determine whether there was an effect of color unevenness and uneven unevenness.
A: More than 16 panelists answered that there was an uneven color and uneven blurring effect.
○: There are 12 to 15 panelists who answered that there was a color unevenness / unevenness blur effect.
Δ: There are 8 to 11 panelists who answered that there was a color unevenness / unevenness blurring effect.
×: Seven or fewer panelists answered that there was a color unevenness / unevenness blurring effect.

(7) Transparency A test sample was applied by hand to the faces of 20 female panelists, and a questionnaire was conducted to determine whether the finish was transparent. Evaluation was made according to the following criteria.
A: More than 16 panelists answered that there was a sense of transparency.
○: 12 to 15 panelists answered that there was a sense of transparency.
Δ: There are 8 to 11 panelists who answered that there was transparency.
×: Seven or fewer panelists answered that there was a sense of transparency.

（＊１）３−［トリス（トリメチルシロキシ）シリル］プロピルカルバミド酸プルラン
（＊２）カバーリーフＡＲ−８０^ＴＭ（触媒化成工業(株)製）
（＊３）サンスフェアーＬ５１^ＴＭ（旭硝子社製）
（＊４）エラストマーブレンドＤＣ９０４１^ＴＭ（ダウコーニング社製） (Table 1)

(* 1) 3- [Tris (trimethylsiloxy) silyl] propylcarbamic acid pullulan (* 2) Coverleaf AR-80 ^™ (manufactured by Catalyst Kasei Kogyo Co., Ltd.)
(* 3) Sunsphere L51 ^TM (Asahi Glass Co., Ltd.)
(* 4) Elastomer blend DC9041 ^™ (Dow Corning)

As can be seen from Table 1, when trimethylsiloxysilicic acid, which is frequently used as a coating agent, and talc are combined (Test Example 3), no stickiness is obtained, stickiness and kinking occur, and formulation stability However, it is not preferable in terms of familiarity and elongation. In addition, color unevenness, uneven blurring effect and transparency were not obtained.
In addition, when silicone-modified polysaccharide and talc were combined (Test Example 4), or when silicone-modified polysaccharide and porous silica were combined (Test Example 5), stickiness, firmness, and transparency were slightly improved. However, it was not sufficient, and no improvement in kink and formulation stability was observed.
The same was true when the silicone-modified polysaccharide and the conventional inorganic composite powder (silica-coated talc) were combined (Test Example 6).
On the other hand, the combination of the trimethylsiloxysilicic acid frequently used as a film agent and the inorganic composite powder of the present invention (Test Example 7) also has drawbacks such as kinking, and has a feeling of use and a beautiful skin effect. Both were not enough.
On the other hand, as can be seen from Test Example 1, by combining the silicone-modified polysaccharide and the inorganic composite powder of the present invention, it has a good elasticity without causing stickiness, and is excellent in the effect of producing beautiful skin. became.
Furthermore, as can be seen from Test Example 2, by combining the cross-linked polymethylsiloxane, stickiness can be more effectively suppressed without impairing the stability of the preparation, and further improved in terms of uneven color and uneven blurring effect. I understood.

Next, the suitable compounding quantity of silicone-ized polysaccharide and inorganic composite powder was examined.
(Table 2)

From Table 2, the effect of adding the silicone-modified polysaccharide is exhibited from 0.01% by mass, and the blending amount is preferably 0.01 to 5.0% by mass, and particularly preferably 0.01 to 3.0% by mass. confirmed.
The addition effect of the inorganic composite powder is exhibited from 0.1% by mass, and the blending amount is preferably 0.1 to 20% by mass, and particularly preferably 1.0 to 5.0% by mass. It was done.
In addition, when the present inventors further examined, the addition effect of the cross-linked polymethylsiloxane is exhibited from 0.01% by mass, and the blending amount is preferably 0.01 to 10% by mass, more preferably It was confirmed to be 1.0 to 5.0% by mass.

Although the suitable Example of the external preparation for skin concerning this invention is shown below, it is not limited to this. In any of the examples, an external preparation for skin was obtained that did not cause stickiness, had a good firmness, and was excellent in the effect of producing beautiful skin.
Example 1 O / W cream formulation (mass%)
(1) Liquid paraffin 3.0
(2) Vaseline 1.0
(3) Dimethylpolysiloxane 1.0
(4) Stearyl alcohol 1.8
(5) Behenyl alcohol 1.6
(6) Macadamia nut oil 2.0
(7) Hardened palm oil 3.0
(8) Squalane 6.0
(9) Stearic acid 2.0
(10) cholesteryl hydroxy stearate 0.5
(11) Cetyl 2-ethylhexanoate 4.0
(12) Polyoxyethylene hydrogenated castor oil 0.5
(13) Self-emulsifying glyceryl monostearate 3.0
(14) Tocopherol acetate 0.1
(15) Retinol 0.01
(16) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(17) 4-t-Butyl-4'-methoxydibenzoylmethane 0.05
(18) paraoxybenzoic acid ester appropriate amount
(19) Diparamethoxycinnamate mono-2-ethylhexanoate glyceryl 0.05
(20) Potassium hydroxide 0.15
(21) Sodium hexametaphosphate 0.05
(22) Trimethylglycine 2.0
(23) Glycerin 8.0
(24) Dipropylene glycol 5.0
(25) α-Tocopherol 2-L-ascorbic acid phosphate diester potassium 1.0
(26) (Acroyldimethyltauronium ammonium / VP) copolymer 0.1
(Aristoflex AVC ^TM ; manufactured by Clariant)
(27) Green tea extract 0.1
(28) Yeast extract 0.1
(29) edetate trisodium 0.05
(30) Carboxyvinyl polymer 0.05
(31) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 1.0
(32) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 10.0
(33) Titanium mica 0.1
(34) Coloring agent appropriate amount
(35) Purified water residue

Example 2 W / O cream formulation (mass%) for beam
(1) Dimethylpolysiloxane 3.0
(2) Decamethylcyclopentasiloxane 13.0
(3) Dodecamethylcyclohexasiloxane 5.0
(4) Polyoxyethylene methylpolysiloxane copolymer 1.0
(5) 3-Tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 1.0
(6) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(7) Retinol acetate 0.1
(8) paraoxybenzoic acid ester appropriate amount
(9) L-menthol appropriate amount
(10) Trimethylsiloxysilicate 2.0
(11) Ethanol 2.0
(12) Glycerin 3.0
(13) Dipropylene glycol 5.0
(14) Polyethylene glycol 6000 5.0
(15) Sodium hexametaphosphate 0.05
(16) Tocopherol acetate 0.1
(17) Caffeine 0.1
(18) Fennel extract 0.1
(19) Hamamelis extract 0.1
(20) Carrot extract 0.1
(21) Yeast extract 1
(22) edetate trisodium 0.05
(23) Dimorpholinopyridazinone 0.01
(24) methyl bis (trimethylsiloxy) silylisopentyl trimethoxycinnamate0.1
(25) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 5.0
(26) Yellow iron oxide appropriate amount
(27) Cobalt titanate appropriate amount
(28) Dimethyl distearyl ammonium hectorite 1.5
(29) Polyvinyl alcohol 0.1
(30) Hydroxyethyl cellulose 0.1
(31) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.1
(32) (Acroyldimethyltauronium ammonium / VP) copolymer 0.1
(Aristoflex AVC ^TM ; manufactured by Clariant)
(33) Fragrance proper amount
(34) Purified water residue

Example 3 O / W cream formulation for wrinkles (mass%)
(1) Liquid paraffin 8.0
(2) Vaseline 3.0
(3) Dimethylpolysiloxane 2.0
(4) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 1.0
(5) Dimethylpolysiloxane blend of cross-linked polymethylsiloxane 0.1
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(6) Stearyl alcohol 3.0
(7) Behenyl alcohol 2.0
(8) Glycerin 5.0
(9) Dipropylene glycol 4.0
(10) Trehalose 1.0
(11) Tetra-2-ethylhexanoic acid pentaerythritol 4.0
(12) Polyoxyethylene glyceryl monoisostearate 2.0
(13) Polystearic acid polyoxyethylene glycerol 1.0
(14) Lipophilic glyceryl monostearate 2.0
(15) Citric acid 0.05
(16) Sodium citrate 0.05
(17) Potassium hydroxide 0.015
(18) Oil soluble licorice extract 0.1
(19) Beech bud extract 0.05
(20) Retinol palmitate (million units) 0.25
(21) Tocopherol acetate 0.1
(22) Yeast extract 5.0
(23) paraoxybenzoic acid ester
(24) Appropriate amount of phenoxyethanol
(25) Appropriate amount of dibutylhydroxytoluene
(26) edetate trisodium 0.05
(27) 4-t-Butyl-4'-methoxydibenzoylmethane 0.01
(28) 2-Ethylhexyl paramethoxycinnamate 0.1
(29) β-carotene 0.01
(30) Polyvinyl alcohol 0.5
(31) Hydroxyethyl cellulose 0.5
(32) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(33) Carboxyvinyl polymer 0.05
(34) (Acroyldimethyltaurine ammonium / VP) copolymer 5.0
(Aristoflex AVC ^TM ; manufactured by Clariant)
(35) Purified water residue
(36) Fragrance proper amount

Example 4 O / W cream formulation for moisturizing (mass%)
(1) Liquid paraffin 10.0
(2) Dimethylpolysiloxane 2.0
(3) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 0.1
(4) Decamethylcyclopentasiloxane blend of crosslinked polymethylsiloxane 3.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(5) Glycerin 10.0
(6) 1,3-butylene glycol 2.0
(7) Erythritol 1.0
(8) Polyethylene glycol 1500 5.0
(9) Polyethylene glycol 6000 1.0
(10) Squalane 15.0
(11) Tetra-2-ethylhexanoic acid pentaerythrit 5.0
(12) Potassium hydroxide 0.1
(13) Sodium hexametaphosphate 0.05
(14) Tocopherol acetate 0.05
(15) Yeast extract 0.1
(16) Fermented soybean extract 0.1
(17) Tonin Extract 1.0
(18) paraoxybenzoic acid ester appropriate amount
(19) Hydroxypropyl methylcellulose 0.3
(20) Polyvinyl alcohol 0.1
(21) Carboxyvinyl polymer 0.2
(22) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.5
(23) Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-2 ^TM ) 0.1
(24) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 5.0
(25) Purified water residue

Example 5 W / O sunscreen formulation (mass%)
(1) Dimethylpolysiloxane 5.0
(2) Decamethylcyclopentasiloxane 10.0
(3) Trimethylsiloxysilicate 3.0
(4) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 5.0
(5) Polyoxyethylene / methylpolysiloxane copolymer 3.0
(6) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(7) Dipropylene glycol 3.0
(8) Cetyl 2-ethylhexanoate 1.0
(9) Silicone coated fine particle zinc oxide (60nm) 10.0
(10) Talc 1.0
(11) Silicone coated fine particle titanium oxide (40nm) 7.0
(12) Yeast extract 1.0
(13) Hibotaurine 0.1
(14) Clara extract 0.01
(15) Adenosine triphosphate disodium 0.5
(16) Novara extract 0.1
(17) Appropriate amount of paraoxybenzoate
(18) Appropriate amount of phenoxyethanol
(19) edetate trisodium 0.2
(20) Dimethyl distearyl ammonium hectorite 1.0
(21) Polymethylmethacrylic acid copolymer spherical powder 3.0
(22 inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalytic Chemical Industry Co., Ltd.) 1.0
(23) Titanium mica 0.5
(24) Purified water residue
(25) Perfume appropriate amount

Example 6 O / W cream
Formula (mass%)
(1) Glycerin 3.0
(2) Decamethylcyclopentasiloxane 7.0
(3) Dimethylpolysiloxane 5.0
(4) Polyoxyethylene sorbitan monooleate (20E.O.) 1.0
(5) Polyethylene glycol 20000 0.5
(6) Polyvinyl alcohol 1.0
(7) Ethanol 5.0
(8) 3-Tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 3.0
(9) Trimethylsiloxysilicate 0.1
(10) Dimorpholinopyridazinone 0.1
(11) Potassium hydroxide 0.12
(12) Titanium mica 0.1
(13) Decamethylcyclopentasiloxane blend of crosslinked polymethylsiloxane 20.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(14) (Acroyldimethyltaurine ammonium / VP) copolymer 2.0
(Aristoflex AVC ^TM ; manufactured by Clariant)
(15) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.1
(16) Carbomer 0.01
(17) Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-2 ^TM ) 0.05
(18) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 5.0
(19) Aluminum oxide 0.01
(20) Xanthan gum 0.1
(21) Sodium carboxymethylcellulose 0.05
(22) Yeast extract 5.0
(23) Tranexamic acid 1.0
(24) Retinol palmitate (1 million units) 0.01
(25) paraoxybenzoic acid ester
(26) Appropriate amount of phenoxyethanol
(27) Perfume appropriate amount
(28) Residual ion exchange water

Example 7 W / O cream
Formula (mass%)
(1) Dipropylene glycol 1.0
(2) Decamethylcyclopentasiloxane 5.0
(3) Dimethylpolysiloxane 1.0
(4) Polyoxyethylene / methylpolysiloxane copolymer 2.0
(5) Glyceryl tri-2-ethylhexanoate 0.1
(6) Polystearic acid polyoxyethylene sorbitan (20E.O.) 0.05
(7) Polyethylene glycol 9000 2.0
(8) Polyvinyl alcohol 0.5
(9) 3-tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 5.0
(10) Dimorpholinopyridazinone 0.1
(11) Potassium hydroxide 0.03
(12) Aluminum oxide 0.1
(13) Titanium oxide 1.0
(14) Cross-linked polymethylsiloxane dimethylpolysiloxane blend 40.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(15) (Acroyldimethyltaurine ammonium / VP) copolymer 0.1
(Aristoflex AVC ^TM ; manufactured by Clariant)
(16) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.1
(17) Carbomer 0.01
(18) Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-2 ^TM ) 0.05
(19) Talc 1.0
(20) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(21) Inorganic composite powder (Coverleaf AR-20121M ^TM ; manufactured by Catalytic Chemical Industry Co., Ltd.) 1.0
(22) Silicic anhydride 1.0
(23) Hydroxyethyl cellulose 0.1
(24) Yeast extract 1.0
(25) Fermented soybean extract 1.0
(26) paraoxybenzoic acid ester appropriate amount
(27) Phenoxyethanol appropriate amount
(28) Perfume appropriate amount
(29) Residual ion exchange water

Example 8 O / W cream for preventing wrinkles and sagging
Formula (mass%)
(1) Glycerin 5.0
(2) Decamethylcyclopentasiloxane 1.0
(3) Dodecamethylcyclohexasiloxane 3.0
(4) Dimethylpolysiloxane 5.0
(5) Methylphenylpolysiloxane 1.0
(6) Octyl methoxycinnamate 0.1
(7) Tetra-2-ethylhexanoic acid pentaerythrit 1.0
(8) Polyoxyethylene sorbitan monolaurate (20E.O.) 0.1
(9) Polyoxyethylene methylpolysiloxane copolymer 1.0
(Polyether-modified silicone oil KF-6018 ^TM : manufactured by Shin-Etsu Chemical Co., Ltd.)
(10) Novara extract 1.0
(11) Fermented soybean extract 3.0
(12) Polyethylene glycol 6000 2.0
(13) Citric acid 0.1
(14) Sodium citrate 0.1
(15) Sodium metaphosphate 0.05
(16) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 0.1
(17) (Dimethicone / Vinyl Dimethicone) Crosspolymer 10.0
^{(KSG-16 TM:} manufactured by Shin-Etsu Chemical Co., Ltd.)
(18) Crosslinked polymethylsiloxane dimethylpolysiloxane blend 5.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(19) (Acroyldimethyltauronium ammonium / VP) copolymer 0.1
(Aristoflex AVC ^TM ; manufactured by Clariant)
(20) Acroyldimethyltaurate ammonium 0.05
/ Beheneth-25 methacrylate cross polymer (Aristoflex HMB ^TM , manufactured by Clariant)
(21) Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-2 ^TM ) 0.05
(22) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL 600 ^TM ; manufactured by SEPPIC) 0.5
(23) Ammonium polyacrylate (SIMULGEL A ^TM ; manufactured by SEPPIC) 0.5
(24) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(25) Inorganic composite powder (Coverleaf AR-20121M ^TM ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(26) (Dimethicone / Vinyl Dimethicone) Cross Polymer 1.0
(BY29-119 ^™ ; manufactured by Toray Dow Corning Silicone)
(27) Yeast extract 1.0
(28) paraoxybenzoic acid ester appropriate amount
(29) Appropriate amount of phenoxyethanol
(30) Fragrance proper amount
(31) Residual ion exchange water

Example 9 O / W emulsion formulation (mass%)
(1) Dimethylpolysiloxane 3.0
(2) Decamethylcyclopentasiloxane 4.0
(3) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 0.5
(4) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 0.5
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(5) Ethanol 5.0
(6) Glycerin 6.0
(7) 1,3-butylene glycol 5.0
(8) Polyoxyethylene methyl glucoside 3.0
(9) Sunflower oil 1.0
(10) Squalane 2.0
(11) Potassium hydroxide 0.1
(12) Sodium hexametaphosphate 0.05
(13) Hydroxypropyl-β-cyclodextrin 0.1
(14) Dipotassium glycyrrhizinate 0.05
(15) Loquat leaf extract 0.1
(16) Sodium L-glutamate 0.05
(17) Fennel extract 0.1
(18) Lavender oil 0.1
(19) Vitamin E 0.1
(20) Diau extract 0.1
(21) Hibotaurine 0.01
(22) Thiotaurine 0.1
(23) Mortierella oil 0.5
(24) Arbutin 3.0
(25) Sodium acetyl hyaluronate 0.1
(26) Marjoram extract 0.1
(27) Yeast extract 0.1
(28) Dimorpholinopyridazinone 0.1
(29) Xanthan gum 0.1
(30) Carboxyvinyl polymer 0.1
(31) Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-2 ^TM ) 0.1
(32) (Acroyldimethyltaurine ammonium / VP) copolymer 1.0
(Aristoflex AVC ^TM ; manufactured by Clariant)
(33) Bengala appropriate amount
(34) Yellow iron oxide
(35) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(36) Titanium mica 0.1
(37) paraoxybenzoic acid ester
(38) Purified water residue

Example 10 O / W emulsion formulation (mass%)
(1) Dimethylpolysiloxane 2.0
(2) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(3) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 1.0
(4) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(5) Behenyl alcohol 1.0
(6) Batyl alcohol 0.5
(7) Glycerin 5.0
(8) 1,3-butylene glycol 7.0
(9) Erythritol 2.0
(10) Yeast extract 5.0
(11) Silica-coated zinc oxide 0.1
(12) Ichiyakuso Extract 0.1
(13) Hardened palm oil 3.0
(14) Squalane 6.0
(15) Tetra-2-ethylhexanoic acid pentaerythrit 2.0
(16) Polyoxyethylene glyceryl isostearate 1.0
(17) Polystearic acid polyoxyethylene glycerol 1.0
(18) Potassium hydroxide appropriate amount
(19) Sodium hexametaphosphate 0.05
(20) Appropriate amount of phenoxyethanol
(21) Carboxyvinyl polymer 0.1
(22) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.1
(23) Purified water residue

Example 11 O / W emulsion formulation (mass%)
(1) Liquid paraffin 7.0
(2) Vaseline 3.0
(3) Decamethylcyclopentasiloxane 2.0
(4) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 0.1
(5) Dimethylpolysiloxane blend of crosslinked polymethylsiloxane 3.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(6) Behenyl alcohol 0.5
(7) Glycerin 5.0
(8) Dipropylene glycol 7.0
(9) Polyethylene glycol 1500 2.0
(10) Jojoba oil 1.0
(11) Isostearic acid 0.5
(12) Stearic acid 0.5
(13) Behenic acid 0.5
(14) Tetra-2-ethylhexanoic acid pentaerythritol 3.0
(15) Cetyl 2-ethylhexanoate 3.0
(16) Glycerol monostearate1.0
(17) Polystearic acid polyoxyethylene glycerol 1.0
(18) Potassium hydroxide 0.1
(19) Sodium hexametaphosphate 0.05
(20) Stearyl glycyrrhetinate 0.05
(21) L-arginine 0.1
(22) Trimethylglycine 0.1
(23) Ascovir-2-glucoside 0.1
(24) Xylitol 1.0
(25) Royal Jelly Extract 0.1
(26) Tocophenol acetate 0.1
(27) Acetylated sodium hyaluronate 0.1
(28) Yeast extract 1.0
(29) edetate trisodium 0.05
(30) 4-tert-butyl-4'-methoxydibenzoylmethane 0.1
(31) 2-ethylhexyl paramethoxycinnamate 0.1
(32) Carboxyvinyl polymer 0.15
(33) (Acroyldimethyltaurine ammonium / VP) copolymer 0.5
(Aristoflex AVC ^TM ; manufactured by Clariant)
(34) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 0.5
(35) Titanium mica 0.1
(36) paraoxybenzoic acid ester
(37) Purified water residue
(38) Fragrance proper amount

Example 12 W / O daytime emulsion formulation (mass%)
(1) Dimethylpolysiloxane 2.0
(2) Decamethylcyclopentasiloxane 25.0
(3) Dodecamethylcyclohexasiloxane 10.0
(4) Polyoxyethylene / methylpolysiloxane copolymer 1.5
(5) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 10.0
(6) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(7) Trimethylsiloxysilicate 1.0
(8) 1,3-butylene glycol 5.0
(9) Squalane 0.5
(10) Talc 5.0
(11) Dipotassium glycyrrhizinate 0.1
(12) Tocophenol acetate 0.1
(13) Yeast extract 0.1
(14) L-serine 1.0
(15) Akebi extract 0.1
(16) edetate trisodium 0.05
(17) 4-t-butyl-4'-methoxydibenzoylmethane 1.0
(18) 2-Ethylhexyl paramethoxycinnamate5.0
(19) Diparamethoxycinnamate mono-2-ethylhexanoate glyceryl 1.0
(20) Silicone coated fine particle titanium oxide (40nm) 4.0
(21) Dimethyl distearyl ammonium hectorite 0.5
(22) Spherical polyethylene powder 3.0
(23) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.1
(24) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(25) Titanium mica 0.1
(26) Appropriate amount of phenoxyethanol
(27) Purified water residue
(28) Perfume appropriate amount

Example 13 skin lotion formula (mass%)
(1) Ethyl alcohol 5.0
(2) Glycerin 1.0
(3) 1,3-butylene glycol 5.0
(4) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(5) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 1.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(6) 3-tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 1.0
(7) Polyoxyethylene polyoxypropylene decyl tetradecyl ether 0.2
(8) Sodium hexametaphosphate 0.03
(9) Trimethylglycine 1.0
(10) Sodium polyaspartate 0.1
(11) α-tocopherol 2-L-ascorbic acid phosphate diester potassium 0.1
(12) Thiotaurine 0.1
(13) Green tea extract 0.1
(14) Western mint extract 0.1
(15) α-Glucosyl hesperidin 0.01
(16) Magnesium ascorbate phosphate 0.01
(17) Potassium 4-methoxysalicylate1.0
(18) Iris root extract 0.1
(19) Yeast extract 0.01
(20) HEDTA 3 sodium 0.1
(21) Carboxyvinyl polymer 0.05
(22) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.05
(23) Potassium hydroxide 0.02
(24) Appropriate amount of phenoxyethanol
(25) Purified water residue
(26) Perfume appropriate amount

Example 14 skin lotion formula (mass%)
(1) Ethanol 10.0
(2) Glycerin 2.0
(3) Dipropylene glycol 1.0
(4) Isostearic acid 0.1
(5) Poly (oxyethylene / oxypropylene) / methylpolysiloxane copolymer 1.0
(6) lauryldimethylaminoacetic acid betaine 0.1
(7) Citric acid 0.02
(8) Sodium citrate 0.08
(9) Sodium hexametaphosphate 0.01
(10) Hipotaurine 0.1
(11) Chamomile extract 0.1
(12) Ogon Extract 0.1
(13) Yeast extract 1.0
(14) Lavender oil 0.001
(15) (Acroyldimethyltaurine ammonium / VP) copolymer 0.01
(Aristoflex AVC ^TM ; manufactured by Clariant)
(16) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(17) Decamethylcyclopentasiloxane blend of crosslinked polymethylsiloxane 1.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(18) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 0.01
(19) Phenoxyethanol appropriate amount
(20) Active hydrogen water 1.0
(21) Purified water residue

Example 15 Pack formulation (mass%)
(1) Ethanol 10.0
(2) 1,3-butylene glycol 6.0
(3) Polyethylene glycol 4000 2.0
(4) Olive oil 1.0
(5) Macadamia nut oil 1.0
(6) Phytosteryl hydroxystearate 0.05
(7) Lactic acid 0.05
(8) Sodium lactate 0.1
(9) L-ascorbic acid sulfate disodium 0.1
(10) α-Tocopherol 2-L-ascorbic acid potassium phosphate diester 0.1
(11) Tocophenol acetate 0.1
(12) Fish collagen 0.1
(13) Molasses extract 1.0
(14) Sodium chondroitin sulfate 0.1
(15) Yeast extract 3.0
(16) Carboxymethylcellulose sodium 0.2
(17) Polyvinyl alcohol 12.0
(18) (Acroyldimethyltaurine ammonium / VP) copolymer 2.0
(Aristoflex AVC ^TM ; manufactured by Clariant)
(19) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.1
(20) Dimethylpolysiloxane blend of cross-linked polymethylsiloxane 3.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(21) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalytic Chemical Industry Co., Ltd.)
(22) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 1.0
(23) paraoxybenzoic acid ester
(24) Purified water residue
(25) Perfume appropriate amount

Example 16 Powdered solid foundation formulation (mass%)
(1) Dimethylpolysiloxane 5.0
(2) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(3) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 0.5
(4) Isostearic acid 0.5
(5) Diisostearyl malate 3.0
(6) Tri-2-ethylhexane sanglyceryl 1.0
(7) Sorbitan sesquiisostearate 1.0
(8) Spherical PMMA-coated mica 6.0
(9) Prism tone powder YR 1.0
(10) Fine zinc oxide 0.5
(11) Fine particle titanium oxide 2.0
(12) Synthetic phlogopite 2.0
(13) Metal soap treated talc 8.0
(14) Spherical silica 5.0
(15) Tocophenol acetate 0.1
(16) δ-Tocopherol 0.1
(17) Isaiyo Rose Extract 0.1
(18) Yeast extract 0.1
(19) paraoxybenzoic acid ester
(20) methyl bis (trimethylsiloxy) silylisopentyl trimethoxycinnamate 1.0
(21) 2-ethylhexyl paramethoxycinnamate 3.0
(22) Spherical polyalkyl acrylate powder 6.0
(23) Methyl hydrogen polysiloxane coated talc Residue
(24) Methylhydrogenpolysiloxane-coated sericite 5.0
(25) Methyl hydrogen polysiloxane coated titanium oxide 15.0
(26) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 10.0
(27) Titanium mica 1.0
(28) Methyl hydrogen polysiloxane coated pigment (colorant) 5.0

Example 17 Powdered solid foundation formulation (mass%)
(1) Ceresin 0.5
(2) Dimethylpolysiloxane 2.0
(3) Methylphenylpolysiloxane 1.0
(4) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 5.0
(5) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(6) Squalane 7.0
(7) Squalane (vegetable) 1.0
(8) Sorbitan sesquiisostearate 1.0
(9) Glycerol-modified silicone resin coated calcined sericite 16.0
(10) Glycerol-modified silicone resin coated sericite 7.0
(11) Yellow iron oxide coated mica titanium 0.1
(12) Fine particle titanium oxide 5.0
(13) Talc 10.0
(14) Titanium oxide coated sericite 0.1
(15) Boron nitride 2.5
(16) Bengala-coated mica titanium 0.1
(17) Phytosterol 0.1
(18) Ascorbyl dipalmitate 0.1
(19) DL-α-tocopherol acetate 0.1
(20) D-δ-tocopherol 0.1
(21) Yeast extract 0.1
(22) paraoxybenzoic acid ester appropriate amount
(23) 2-ethylhexyl paramethoxycinnamate 1.0
(24) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 10.0
(25) Spherical polyalkyl acrylate powder 8.0
(26) Methyl hydrogen polysiloxane-coated mica residue
(27) Methyl hydrogen polysiloxane coated iron oxide titanium oxide sintered product 5.0
(28) Methylhydrogenpolysiloxane-coated sericite 5.0
(29) Methyl hydrogen polysiloxane coated titanium oxide 4.0
(30) Methyl hydrogen polysiloxane coated flaky titanium oxide 5.0
(31) Methyl hydrogen polysiloxane coated pigment (colorant) 5.0
(32) Fragrance proper amount

Example 18 Powdered solid foundation formulation (mass%)
(1) α-olefin oligomer 3.0
(2) Vaseline 3.0
(3) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 5.0
(4) Decamethylcyclopentasiloxane blend of crosslinked polymethylsiloxane 3.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(5) Macadamia nut oil 0.1
(6) Sorbitan sesquiisostearate 1.0
(7) Alkyl-modified silicone resin coated yellow iron oxide 2.0
(8) Alkyl modified silicone resin coated Bengala 1.0
(9) Black iron oxide coated with alkyl-modified silicone resin 0.5
(10) Yellow iron oxide coated mica titanium 5.0
(11) Synthetic phlogopite 5.0
(12) Titanium oxide 1.0
(13) Zinc oxide 1.0
(14) Low-temperature calcined zinc oxide 4.0
(15) Firing sericite 10.0
(16) Golden Mica 1.0
(17) Aluminum oxide 1.0
(18) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 15.0
(19) Talc residue
(20) Synthetic phlogopite 5.0
(21) Cross-linked silicone powder 10.0
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
(22) DL-α-tocopherol acetate 0.1
(23) D-δ-tocopherol 0.1
(24) Yeast extract 5.0
(25) paraoxybenzoic acid ester
(26) 2-Ethylhexyl paramethoxycinnamate 1.0
(27) Calcium alginate powder 1.0
(28) Perfume appropriate amount

Example 19 Solid foundation formulation (mass%)
(1) α-olefin oligomer 10.0
(2) Microcrystalline wax 0.5
(3) Crosslinked polymethylsiloxane dimethylpolysiloxane blend 3.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(4) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 1.0
(5) Ceresin 5.0
(6) Dimethylpolysiloxane 15.0
(7) Methylphenylpolysiloxane 10.0
(8) Macadamia nut oil 0.1
(9) Carnauba 0.1
(10) Glyceryl tri-2-ethylhexanoate 7.0
(11) Cetyl 2-ethylhexanoate 10.0
(12) Sorbitan sesquiisostearate 1.5
(13) Mica 0.5
(14) Aluminum stearate 1.0
(15) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 3.0
(16) Cross-linked silicone powder 8.0
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
(17) N-lauroyl-L-lysine 0.1
(18) Appropriate amount of D-δ-tocopherol
(19) Yeast extract 0.1
(20) Bengala appropriate amount
(21) Yellow iron oxide appropriate amount
(22) Calcium alginate powder 1.0
(23) Nylon powder residual
(24) Spherical Silicic Acid 1.0
(25) Titanium oxide 1.0

Example 20 Emulsion foundation formulation (mass%)
(1) Microcrystalline wax 1.0
(2) Dimethylpolysiloxane 15.0
(3) Decamethylcyclopentasiloxane 2.0
(4) Decamethylcyclopentasiloxane blend of crosslinked polymethylsiloxane 3.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(5) 3-tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 0.5
(6) 1,3-butylene glycol 6.0
(7) Candelilla Row 3.0
(8) Isostearic acid 1.0
(9) Ethylene glycol fatty acid ester 0.1
(10) Lanolin fatty acid octyldodecyl 0.5
(11) 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine
4.0
(12) Titanium oxide 7.5
(13) Barium sulfate 5.0
(14) Titanium oxide 7.0
(15) Talc 3.0
(16) Silicic anhydride 4.0
(17) Cross-linked silicone powder 0.1
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
(18) Sodium metaphosphate 0.1
(19) Hydroxypropyl-β-cyclodextrin 0.1
(20) DL-α-tocopherol acetate 0.1
(21) Hamamelis extract 0.1
(22) Peonies extract 0.1
(23) Sodium chondroitin sulfate 0.1
(24) Sodium hyaluronate 0.1
(25) Yeast extract 0.1
(26) Asenya extract 0.1
(27) paraoxybenzoic acid ester appropriate amount
(28) Bengala appropriate amount
(29) Yellow iron oxide appropriate amount
(30) Black iron oxide
(31) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(32) Xanthan gum 0.1
(33) Sodium carboxymethyl cellulose 0.1
(34) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.5
(35) Merirot Extract 2.0
(36) Purified water residue

Example 21 W / O foundation prescription (mass%)
(1) Dimethylpolysiloxane 3.0
(2) Decamethylcyclopentasiloxane 10.0
(3) Polyoxyethylene / methylpolysiloxane copolymer 3.0
(4) Dodecamethylcyclohexasiloxane 5.0
(5) 3-tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 0.1
(6) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(7) Glycerin 4.0
(8) 1,3-butylene glycol 5.0
(9) Palmitic acid 0.5
(10) Distearyldimethylammonium chloride 0.2
(11) Metal soap treated talc 2.0
(12) Cross-linked silicone powder 0.1
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
(13) Bengala coated mica titanium 0.5
(14) N-lauroyl-L-lysine 2.0
(15) Sodium L-glutamate 2.0
(16) Tocopherol acetate 0.1
(17) δ-Tocopherol 0.1
(18) paraoxybenzoic acid ester appropriate amount
(19) Phenoxyethanol 0.2
(20) Spherical nylon powder 1.0
(21) Spherical polyalkyl acrylate powder 3.0
(22) Merirot Extract 2.0
(23) Cypress extract 1.0
(24) Yeast extract 5.0
(25) Purified water residue
(26) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 2.0
(27) Dextrin fatty acid treatment talc 3.0
(28) Dextrin fatty acid-treated titanium dioxide 15.0
(29) Dextrin fatty acid-treated yellow iron oxide 3.0
(30) Dextrin fatty acid treated black iron oxide 0.5

Example 22 O / W foundation formulation (mass%)
(1) Dimethylpolysiloxane 8.0
(2) Decamethylcyclopentasiloxane blend of crosslinked polymethylsiloxane 20.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(3) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 5.0
(4) Behenyl alcohol 0.5
(5) Batyl alcohol 0.5
(6) 1,3-butylene glycol 5.0
(7) Macadamia nut oil 0.1
(8) Isostearic acid 1.5
(9) Stearic acid 1.0
(10) Behenic acid 0.5
(11) Cetyl 2-ethylhexanoate 5.0
(12) Poly stearate polyoxyethylene glycerin 1.0
(13) Self-emulsifying glyceryl monostearate1.0
(14) Yellow iron oxide coated mica titanium 2.0
(15) Titanium oxide 4.0
(16) Talc 0.5
(17) Kaolin 3.0
(18) Synthetic phlogopite 0.1
(19) Cross-linked silicone powder 0.1
(20) Silicic anhydride 5.0
(21) Potassium hydroxide 0.2
(22) Triethanolamine 0.8
(23) DL-α-tocopherol acetate 0.1
(24) Sodium hyaluronate 0.1
(25) Yeast extract 0.1
(26) Ibuki extract 0.1
(27) paraoxybenzoic acid ester appropriate amount
(28) 2-Methylhexyl paramethoxycinnamate 1.0
(29) Bengala appropriate amount
(30) Yellow iron oxide
(31) Appropriate amount of black iron oxide
(32) Xanthan gum 0.1
(33) Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 1.0
(34) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 5.0
(35) Bentonite 1.0
(36) Carboxymethylcellulose sodium 0.1
(37) Purified water residue
(38) Fragrance proper amount

Example 23 Foundation formulation (mass%)
(1) Dodecamethylcyclohexasiloxane 15.0
(2) Decamethylcyclopentasiloxane Residue
(3) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 5.0
(4) Crosslinked polymethylsiloxane dimethylpolysiloxane blend 30.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(5) Ethanol 10.0
(6) Isostearic acid 0.5
(7) Myristic acid-treated zinc oxide 0.5
(8) Dextrin palmitate coated titanium oxide 10.0
(9) Dalmic palmitate coated talc 7.0
(10) Silicone surface-treated titanium oxide (30 nm) 5.0
(11) Cross-linked silicone powder 1.0
(12) Spherical silica 2.0
(13) L-ascorbyl magnesium phosphate 0.2
(14) DL-α-tocopherol acetate 0.1
(15) D-δ-tocopherol 0.1
(16) Glutathione 0.1
(17) Clara extract 0.1
(18) Psycho extract 1.0
(19) Yeast extract 2.0
(20) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 1.0
(21) 2-Methylhexyl paramethoxycinnamate5.0
(22) Bengala coated with dextrin palmitate
(23) Appropriate amount of dextrin palmitate-coated yellow iron oxide
(24) Appropriate amount of black iron oxide coated with dextrin palmitate
(25) Perfume appropriate amount

Example 24 Makeup Base Formula (mass%)
(1) Dimethylpolysiloxane 5.0
(2) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 0.1
(3) Decamethylcyclopentasiloxane blend of crosslinked polymethylsiloxane 30.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(4) Decamethylcyclopentasiloxane Residue
(5) Ethyl alcohol 8.0
(6) Bitumen coated mica titanium 0.5
(7) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 5.0
(8) Methylsiloxane network polymer 5.0
(9) Cross-linked silicone powder 5.0
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
(10) Citric acid 0.02
(11) Sodium citrate 0.08
(12) Tocopherol acetate 0.1
(13) δ-tocopherol 0.1
(14) Merirot Extract 3.0
(15) Turmeric extract 0.01
(16) Yeast extract 0.1
(17) Purified water 1.0
(18) Poly (oxyethylene / oxypropylene) / methylpolysiloxy acid copolymer 5.0

Example 25 Makeup Base Formula (mass%)
(1) Dimethylpolysiloxane 5.0
(2) Decamethylcyclopentasiloxane blend of cross-linked polymethylsiloxane 5.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
(3) Pullulan 3-tris (trimethylsiloxy) silylpropylcarbamate 5.0
(4) Decamethylcyclopentasiloxane 25.0
(5) Polyoxyethylene / methylpolysiloxane copolymer 3.0
(6) Glycerin 1.0
(7) 1,3-butylene glycol 5.0
(8) Xylit 0.5
(9) Isostearic acid 0.5
(10) Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 10.0
(11) Silica anhydride coated with alkyl-modified silicone resin 2.0
(12) Talc 0.5
(13) Aluminum stearate 1.0
(14) Bengala-coated mica titanium 0.1
(15) Sodium hexametaphosphate 0.05
(16) Dipotassium glycyrrhizinate 0.1
(17) L-serine 0.1
(18) Hypericum extract 0.1
(19) DL-α-tocopherol acetate 0.2
(20) Thiotaurine 0.1
(21) Capsicum extract 0.1
(22) Peonies extract 0.1
(23) Lysolecithin 0.01
(24) Acetylated sodium hyaluronate 0.1
(25) Yukinoshita extract 0.1
(26) Yeast extract 0.1
(27) paraoxybenzoic acid ester appropriate amount
(28) Appropriate amount of phenoxyethanol
(29) Palmitic acid dextrin coated yellow iron oxide 0.1
(30) Dimethyl distearyl ammonium hectorite 1.0
(31) Purified water residue
(32) Trimethylsiloxysilicate 1.5
(33) Spherical silica 1.0
(34) Spherical polyethylene powder 5.0
(35) Fragrance proper amount

It is the figure which showed 1 type of the inorganic composite powder concerning this invention.

Explanation of symbols

10 Inorganic composite powder 12 Spherical silica 14 Aluminum oxide 16 Titanium oxide 18 Talc

Claims (2)

(A) 0.01 to 3.0% by mass of a siliconized polysaccharide compound having a structure represented by the following general formula (I);
(B) on a flaky substrate, titanium oxide, aluminum oxide, and inorganic composite powder of 0.1 to 20 mass% obtained by sequentially stacking a silicon oxide,
(C) dimethicone / vinyl dimethicone crosspolymer, characterized dimethicone crosspolymer, and including that the one or more crosslinked polymethylsiloxane is selected from the group consisting of vinyl dimethicone / lauryl dimethicone crosspolymer Skin external preparation.
(Chemical formula 1)

(In Formula (I), Glu is a sugar residue of the polysaccharide compound, X is a divalent linking group selected from a carbonyl group, an amino group, an ether group, a carbamoyl group, and —CH ₂ CH (OH) —). Y may have an oxygen atom, a nitrogen atom, a sulfur atom, a phenylene group, a carbonyloxy group or an oxycarbonyl group in the main chain, and may have a substituent selected from a hydroxy group, an alkoxy group and an alkyl group. An alkylene group having 2 to 8 carbon atoms in total, R ¹ is a monovalent organic group having 1 to 8 carbon atoms, and R ² , R ³ , and R ⁴ may be the same or different; 8 or a siloxy group represented by —OSiR ⁵ R ⁶ R ⁷ , wherein R ⁵ , R ⁶ and R ⁷ may be the same or different and each is a monovalent organic group having 1 to 8 carbon atoms. A is 0, 1 or In is.)   The skin external preparation according to claim 1, wherein in formula (I), X is a carbonyl group.

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