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JP4463073B2 - Refractory double-layer pipe - Google Patents

Refractory double-layer pipe Download PDF

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JP4463073B2
JP4463073B2 JP2004307421A JP2004307421A JP4463073B2 JP 4463073 B2 JP4463073 B2 JP 4463073B2 JP 2004307421 A JP2004307421 A JP 2004307421A JP 2004307421 A JP2004307421 A JP 2004307421A JP 4463073 B2 JP4463073 B2 JP 4463073B2
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sheet
tube
sound
outer tube
sound insulation
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JP2006090538A (en
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裕之 久保田
貞治 大木田
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フネンアクロス株式会社
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Description

本発明は、合成樹脂製の内管の外周に繊維混入モルタル製の外管をスライド可能に装着した構成を有する耐火二層管に関する。  The present invention relates to a fireproof two-layer pipe having a configuration in which an outer pipe made of fiber-mixed mortar is slidably mounted on the outer periphery of an inner pipe made of synthetic resin.

上記の構成を有する耐火二層管は、1,200℃程度の火災の熱に耐えて防火防災上の安全性が高く、外管がスライド可能であるため、配管長さの切断による調節を簡単に行えるという利点があるが、内管の内部を流れる排水の騒音が外管の外部へと漏れるという不都合があり、高層住宅やホテルなどの静粛性が要求される建物に使用する場合には、耐火二層管の配管後に外管の外周面に遮音シートを巻き付けることで騒音の漏れを防止したり、内管と外管の間に遮音材を介在させて製造した遮音形耐火二層管を使用することでその防止を行っている(特許文献1、2参照)。  The fireproof double-layer pipe with the above structure can withstand the heat of fire of about 1,200 ° C, has high safety in fire prevention and disaster prevention, and the outer pipe is slidable, so adjustment by cutting the pipe length is easy. However, there is an inconvenience that the noise of the drainage water flowing inside the inner pipe leaks to the outside of the outer pipe. When used for buildings such as high-rise houses and hotels where quietness is required, A sound insulation type fireproof double-layer pipe manufactured by wrapping a soundproof sheet around the outer peripheral surface of the outer pipe after the fireproof double-layer pipe is installed, or by producing a sound insulation material between the inner pipe and the outer pipe. This is prevented by using it (see Patent Documents 1 and 2).

また、外管が繊維混入モルタル製であるため、水分が多少とも外管の表層内に浸透し、カビ発生の原因となって好ましくない。
実用新案登録第3036449号公報 特許第3156662号公報
In addition, since the outer tube is made of fiber-mixed mortar, moisture slightly penetrates into the surface of the outer tube, which is not preferable because it causes mold.
Utility Model Registration No. 3036449 Japanese Patent No. 3156661

耐火二層管の配管工事後に遮音シートを巻き付けると、配管作業完成までの時間が長引いてしまう欠点があり、内管と外管の間に遮音材を介在させた構成の耐火二層管は、内管と外管の間の隙間が大きくなるため、内管と外管は遊動状態で嵌まり合い、耐火二層管の運搬や立管として配管施工する際に内管の抜け落ちに注意を払う必要があった。また、従来のスライド可能な繊維混入モルタル製の外管を備えた耐火二層管には、外管に水分の浸透を防止する考慮がなされていない。  When the sound insulation sheet is wrapped after the fireproof double-layer pipe construction, there is a disadvantage that the time until the completion of the piping work is prolonged, and the fireproof double-layer pipe with the structure in which the sound insulation material is interposed between the inner pipe and the outer pipe, Because the gap between the inner and outer pipes becomes large, the inner and outer pipes fit together in a floating state, paying attention to the falling off of the inner pipe when transporting a fireproof double-layer pipe or installing it as a standing pipe. There was a need. In addition, in the conventional fireproof double-layer pipe provided with the outer pipe made of slidable fiber-mixed mortar, no consideration is given to preventing moisture from penetrating into the outer pipe.

本発明は、遮音性が良好で外管への水の浸透が防止され、且つ内管と外管の隙間が大きくならないように容易に製作できる繊維混入モルタル製の外管を備えた耐火二層管を提供することを課題とするものである。  The present invention provides a fireproof double layer including an outer tube made of fiber-mixed mortar that has good sound insulation, prevents water penetration into the outer tube, and can be easily manufactured so that the gap between the inner tube and the outer tube does not increase. The object is to provide a tube.

本発明では、上記課題を解決するため、合成樹脂製の内管の外周に繊維混入モルタル製の外管をスライド可能に装着し、該外管の外周面に、アルミ箔の外皮と遮音性を有する樹脂シートと難燃性フェルトの吸音シートとを順次に貼着した構成の防水遮音シートを巻き付けて接合した耐火二層管において、該防水遮音シートの巻き付け開始側と巻き終わり側に、樹脂シートおよび吸音シートよりも上記アルミ箔をせり出させ、外管に巻き付けた防水遮音シートの耐熱性接着剤を塗布するためと、樹脂シートおよび吸音シートの端部を封入して防水するための封入代を形成した。防水遮音シートの外皮の樹脂シート側の全面に難燃性繊維のメッシュを重合貼着することが好ましい。     In the present invention, in order to solve the above problems, an outer tube made of fiber-mixed mortar is slidably mounted on the outer periphery of the inner tube made of synthetic resin, and the outer skin of the aluminum foil and sound insulation are provided on the outer peripheral surface of the outer tube. A fireproof two-layer pipe in which a waterproof soundproof sheet having a structure in which a resin sheet and a sound absorbing sheet of a flame-retardant felt are sequentially attached are joined to each other on the winding start side and the winding end side of the waterproof soundproof sheet In addition, the aluminum foil is protruded from the sound-absorbing sheet and the heat-resistant adhesive of the waterproof sound-insulating sheet wrapped around the outer tube is applied, and the resin sheet and the end of the sound-absorbing sheet are sealed for waterproofing. Formed. It is preferable that a flame retardant fiber mesh is adhered to the entire surface of the outer surface of the waterproof sound insulating sheet on the resin sheet side.

本発明の耐火二層管は、アルミ箔の外皮と遮音性を有する樹脂シートと難燃性フェルトの吸音シートとを順次に貼着した構成の防水遮音シートを繊維混入モルタル製の外管の外周面に巻き付け接合したので、アルミ箔の外皮により水分が遮断されて外管へ浸透することがなく、外管を乾燥状態に維持できるからカビの発生を防止でき、遮音性を有する樹脂シートと吸音シートをアルミ箔の外皮に貼着して一体の防水遮音シートに構成してあるから、これを外管に巻き付け接合することで遮音性と防水性を一挙に加工することができる。また、表面がアルミ箔であるから熱反射性と難燃性および撥水性があり、汚れにくくカビなども発生しないという効果が得られる。耐火二層管の外管の周面に防水遮音シートを接合するので、内管と外管の間の隙間に従来と同様に内管と外管のスライドを制御する部材を介在させることができ、運搬時や施工時に内管のすべりを防止することができる。防水遮音シートの巻き付け開始側と巻き終わり側のアルミ箔をせり出させて封入代を形成しておくことで、外管に巻き付けた樹脂シートおよび吸音シートの端部をアルミ箔の内部へ封入できる。さらに、防水遮音シートのアルミ箔の樹脂シート側の全面にガラス繊維等の難燃性繊維のメッシュを貼着しておくことで引っ張りや破損に耐える丈夫なものが得られる。  The fireproof double-layered pipe of the present invention is an outer periphery of an outer tube made of mortar mixed with a fiber, which is a waterproof sound-insulating sheet having a structure in which an aluminum foil outer shell, a sound-insulating resin sheet, and a flame-retardant felt sound-absorbing sheet are sequentially attached Since it is wrapped around the surface and the moisture is blocked by the outer skin of the aluminum foil and does not penetrate into the outer tube, the outer tube can be maintained in a dry state, so that generation of mold can be prevented, and a sound-insulating resin sheet and sound absorption Since the sheet is affixed to the outer skin of the aluminum foil to form an integral waterproof sound insulation sheet, the sound insulation and waterproof properties can be processed at once by wrapping the sheet around the outer tube and joining. Further, since the surface is an aluminum foil, there are obtained effects that it has heat reflectivity, flame retardancy, and water repellency, is hardly soiled and does not generate mold. Since the waterproof sound-insulating sheet is joined to the peripheral surface of the outer tube of the fireproof two-layer tube, a member for controlling the sliding of the inner tube and the outer tube can be interposed in the gap between the inner tube and the outer tube as in the past. Sliding of the inner pipe can be prevented during transportation and construction. The end of the resin sheet and the sound absorbing sheet wound around the outer tube can be sealed inside the aluminum foil by forming the sealing allowance by protruding the aluminum foil on the winding start side and the winding end side of the waterproof sound insulation sheet. . Furthermore, by attaching a mesh of flame retardant fiber such as glass fiber to the entire surface of the resin sheet side of the aluminum foil of the waterproof sound insulating sheet, a durable material that can withstand pulling and breakage can be obtained.

本発明の実施の形態を図面に基づき説明すると、図1および図2において、符号1は合成樹脂製の内管2の外周に繊維混入モルタル製の外管3を挿通した構成を有する耐火二層管を示す。この耐火二層管1の内管2と外管3の間には隙間4が設けられ、この隙間4に内管2と外管3の軸方向へのスライドを可能にするためのスライド制御部材5が介在される。スライド制御部材5は、内管2の外周にかけた輪ゴムや外周に線状に塗布したホットメルトゴムなどの弾性体を外管3で押しつぶされるような状態で設けた構成を有し、内管2と外管3を相対的にスライドさせるためにスライド力を加えたとき、輪ゴムのスライド制御部材5の場合は、コロのように隙間4内で回転してスライドが行なわれる。  DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring to the drawings, an embodiment of the present invention will be described. In FIGS. 1 and 2, reference numeral 1 denotes a fireproof double layer having a configuration in which an outer tube 3 made of fiber-mixed mortar is inserted into the outer periphery of an inner tube 2 made of synthetic resin. Show the tube. A gap 4 is provided between the inner tube 2 and the outer tube 3 of the refractory double-layer tube 1, and a slide control member for enabling the inner tube 2 and the outer tube 3 to slide in the gap 4 in the axial direction. 5 is interposed. The slide control member 5 has a configuration in which an elastic body such as a rubber band applied to the outer periphery of the inner tube 2 or a hot melt rubber applied linearly to the outer periphery is crushed by the outer tube 3. When a sliding force is applied to slide the outer tube 3 relatively, the rubber rubber slide control member 5 rotates within the gap 4 and slides like a roller.

前記したように、耐火二層管の内管の中を流れる排水の騒音を、従来のような遮音シートで耐火二層管を覆ったり、内管と外管の間に遮音材を設けることで遮音すると、施工時間が掛かり、内管と外管のスライド制御ができないなどの不都合を伴うが、本発明ではこの不都合を解消するとともに繊維混入モルタルの外管に水分が浸入する欠点を解消するため、図3および図4に例示したような、アルミ箔からなる外皮6と遮音性を有する樹脂シート7と難燃加工したレジンなどの市販の難燃性フェルトからなる吸音シート8とを、例えば耐熱性の接着剤により一体に貼着して防水遮音シート9を作製し、これを耐熱性の接着剤を塗布して該外管3の外周面に巻き付け接合した。耐熱性の接着剤としては、アクリル系接着剤などが使用される。  As described above, the noise of the drainage flowing through the inner pipe of the fireproof double-layer pipe is covered with a conventional sound insulation sheet, or a sound insulation material is provided between the inner pipe and the outer pipe. When sound insulation is used, it takes time for construction and is accompanied by inconveniences such as inability to control sliding of the inner tube and outer tube.In the present invention, this inconvenience is solved and the disadvantage that moisture enters the outer tube of the fiber-mixed mortar is eliminated. As shown in FIGS. 3 and 4, a skin 6 made of aluminum foil, a resin sheet 7 having a sound insulating property, and a sound absorbing sheet 8 made of a commercially available flame retardant felt such as a flame retardant resin are used, for example. A waterproof sound-insulating sheet 9 was prepared by integrally sticking with a heat-resistant adhesive, and this was coated with a heat-resistant adhesive, wrapped around the outer peripheral surface of the outer tube 3 and joined. An acrylic adhesive or the like is used as the heat resistant adhesive.

該遮音性を有する樹脂シート7としては、例えば塩化ビニール樹脂に可塑剤と高比重の金属材を添加した厚さ1.5mmのシートが使用され、吸音シート8には、例えば厚さ5mm、205g/mの難燃性フェルトが使用される。これら樹脂シート7と吸音シート8は、予め耐熱性の接着剤で貼着し、これをアルミ箔の外皮6に耐熱性の接着剤で接合した。As the resin sheet 7 having a sound insulation property, for example, a 1.5 mm thick sheet obtained by adding a plasticizer and a high specific gravity metal material to vinyl chloride resin is used. For the sound absorbing sheet 8, for example, a thickness of 5 mm, 205 g is used. A flame retardant felt of / m 2 is used. The resin sheet 7 and the sound absorbing sheet 8 were pasted in advance with a heat-resistant adhesive, and this was joined to the aluminum foil outer skin 6 with a heat-resistant adhesive.

外皮6のアルミ箔には、柔軟性を備え且つ容易に破損しない厚さ20ミクロン程度のものが適当であり、その強度を増すために、外皮6の樹脂シート7側の全面に、ガラス繊維などの引張強度が大きく且つ難燃性の繊維からなるメッシュ10を貼着した。  The aluminum foil of the outer skin 6 is suitable to have a thickness of about 20 microns which is flexible and does not easily break. In order to increase the strength, glass fiber or the like is provided on the entire surface of the outer skin 6 on the resin sheet 7 side. A mesh 10 made of a flame-retardant fiber having a high tensile strength was attached.

繊維混入モルタル製の外管3の製法は、従来の耐火二層管の外管の製法と同様であり、例えば、普通ポルトランドセメント64%、骨材21%、無機質繊維10%、有機質繊維5%からなる原料を含水率28%になるように混練して製作した繊維混入モルタルの生乾きのシートを心棒に巻き付け、心棒をつけたまま乾燥硬化させて製作される。この外管3を周面にスライド制御部材5を設けた内管2に嵌めることで耐火二層管1が出来上がり、この耐火二層管1を図5および図6に示すようにロール11、12で回転させながら接着剤を外皮6から吸音シート8にわたる内面に塗布した防水遮音シート9を巻き付けする。この巻き付けを容易にするためと樹脂シート7および吸音シート8の巻き込み方向の端部を外部へ開放させず外皮6で封入した状態にするために、防水遮音シート9の巻き付け開始側と巻き終わり側の両方に外皮6のアルミ箔をせり出させて封入代13、13を形成した。この構成により、耐火二層管1の配管施工後に、難燃性フェルトからなる水分が蒸発しにくい吸音シート8へ管の両端部以外から水分が浸入することがなくなり、この両端部は通常は目地材でシールされるので吸音シート8を封鎖して製作時の乾燥状態を維持することができ、その結果、外管3に水分が浸入することの不都合を解消できる。図5、図6の符号14は防水遮音シート9を載せるテーブルである。  The manufacturing method of the outer tube 3 made of fiber-mixed mortar is the same as the manufacturing method of the conventional outer tube of the fireproof double-layered tube, for example, 64% ordinary portland cement, 21% aggregate, 10% inorganic fiber, 5% organic fiber. It is manufactured by winding a raw sheet of fiber-mixed mortar prepared by kneading a raw material made of the above to a moisture content of 28% and winding it around a mandrel and drying and curing it with the mandrel attached. The outer tube 3 is fitted to the inner tube 2 provided with the slide control member 5 on the peripheral surface to complete the fire-resistant double-layer tube 1, and the fire-resistant double-layer tube 1 is rolled into rolls 11, 12 as shown in FIGS. The waterproof sound-insulating sheet 9 in which the adhesive is applied to the inner surface extending from the outer skin 6 to the sound-absorbing sheet 8 is wound around while rotating. The winding start side and the winding end side of the waterproof sound-insulating sheet 9 are used for facilitating the winding and for enclosing the resin sheet 7 and the sound-absorbing sheet 8 in the enveloping direction 6 without opening them to the outside. The aluminum foil of the outer skin 6 was protruded to both, and the sealing allowances 13 and 13 were formed. With this configuration, after the pipe construction of the fireproof double-layer tube 1, moisture does not enter the sound-absorbing sheet 8 made of flame-retardant felt from which the moisture hardly evaporates from other than both ends of the tube. Since it is sealed with the material, the sound absorbing sheet 8 can be sealed and the dry state at the time of manufacture can be maintained. As a result, the inconvenience of moisture entering the outer tube 3 can be eliminated. Reference numeral 14 in FIGS. 5 and 6 is a table on which the waterproof sound insulation sheet 9 is placed.

硬質塩化ビニール製の長さ2100mm、外径114mm、肉厚6.6mmの内管2に嵌合した、長さ2000mm、内径115.5mm、肉厚6.5mmの繊維混入モルタル製の耐火二層管1の外管3の外周に、耐熱性のアクリル系接着剤を使用して防水遮音シート9を巻き付け接合した。該防水遮音シート9は、厚さ20ミクロンのアルミ箔の外皮6に、柔軟なガラス繊維製のメッシュ10を介して鉄粉を混入させた塩化ビニール製の遮音性を有する厚さ1.5mmの樹脂シート7とレジン製の200g/m、厚さ5mmの難燃性のフェルトからなる吸音シート8とを順次に耐熱性の接着剤で貼着した構成のもので、その巻き付け開始側と巻き終わり側にそれぞれ50mmの封入代13を形成した。Two layers of fire-resistant mortar made of fiber-mixed mortar with a length of 2000 mm, an inner diameter of 115.5 mm, and a thickness of 6.5 mm, which is fitted to the inner tube 2 made of hard vinyl chloride with a length of 2100 mm, an outer diameter of 114 mm, and a thickness of 6.6 mm A waterproof and sound-insulating sheet 9 was wrapped around and joined to the outer periphery of the outer tube 3 of the tube 1 using a heat-resistant acrylic adhesive. The waterproof and sound-insulating sheet 9 has a thickness of 1.5 mm and has a sound insulating property made of vinyl chloride in which iron powder is mixed with a skin 10 made of aluminum foil having a thickness of 20 microns through a flexible glass fiber mesh 10. A resin sheet 7 and a resin-made sound absorbing sheet 8 made of 200 g / m 2 , 5 mm thick flame-retardant felt are sequentially attached with a heat-resistant adhesive. A sealing allowance 13 of 50 mm was formed on each end side.

この耐火二層管1から防水遮音シート9を除外した構成の耐火二層管は、従来の耐火二層管であり、防火区画貫通部の耐火性能試験において、1,200℃でも被加熱側区画へ延焼することがないものである。図7に示した構成の騒音測定室にこの耐火二層管1を設け、1リットル/秒の水量を流して10cm離れた位置のマイク16で騒音を測定したところ、36.9dbの騒音が測定された。水量を2リットル/秒に増やしたときの騒音は41.5dbであった。いずれの場合も、暗騒音は30.4dbであった。さらに、比較のために、防水遮音シート9を取り除いた耐火二層管をこの騒音測定室に設けて2リットル/秒の水量を流したところ、46.3dbの騒音が測定された。このときの暗騒音は27.3dbであった。これより、本発明の耐火二層管は十分な遮音性能を有することがわかる。  The fireproof double-layer pipe having a structure excluding the waterproof sound insulation sheet 9 from the fireproof double-layer pipe 1 is a conventional fireproof double-layer pipe. It does not spread to the fire. This fireproof double-layer tube 1 is installed in the noise measurement chamber having the configuration shown in FIG. 7, and when measuring the noise with the microphone 16 at a position 10 cm away by flowing 1 liter / second of water, a noise of 36.9 db is measured. It was done. The noise when the amount of water was increased to 2 liters / second was 41.5 db. In any case, the background noise was 30.4 db. Further, for comparison, when a fireproof double-layer pipe from which the waterproof sound-insulating sheet 9 was removed was provided in this noise measurement chamber and a water amount of 2 liters / second was flowed, a noise of 46.3 db was measured. The background noise at this time was 27.3 db. From this, it can be seen that the fireproof double-layer tube of the present invention has sufficient sound insulation performance.

さらに、上記騒音測定室内を高温多湿状態とし、30日間放置したのち分解して内部を観察したが、吸音シート8や外管3は製作時の状態と変わりがなかった。内管2と外管3の隙間4にはスライド制御部材5が設けられているから、外管3に適度なスライド力を与えたときにのみ内管2に対してスライドさせることができ、運搬時や施工時のスライド力を与えていないときに外管3がスライドすることはなかった。  Further, the inside of the noise measurement chamber was kept in a high temperature and humidity state, left for 30 days, and then decomposed to observe the inside. However, the sound absorbing sheet 8 and the outer tube 3 were not different from those at the time of manufacture. Since the slide control member 5 is provided in the gap 4 between the inner tube 2 and the outer tube 3, it can be slid with respect to the inner tube 2 only when an appropriate sliding force is applied to the outer tube 3. The outer tube 3 did not slide when no sliding force was applied at the time or during construction.

本発明の実施の形態を示す一部截断側面図Partially cutaway side view showing an embodiment of the present invention 要部の詳細を付記した図1の拡大縦断面図Fig. 1 is an enlarged longitudinal sectional view with details of the main part. 防水遮音シートの断面図Cross section of waterproof sound insulation sheet 図3の要部の拡大斜視図3 is an enlarged perspective view of the main part of FIG. 防水遮音シートの巻き付け接合状態の平面図Plan view of the wound and joined state of the waterproof sound insulation sheet 図5の側面図Side view of FIG. 騒音測定状態の説明図Illustration of noise measurement status

符号の説明Explanation of symbols

1 耐火二層管、2 内管、3 外管、4 隙間、5 スライド制御部材、6 アルミ箔からなる外皮、7 樹脂シート、8 吸音シート、9 防水遮音シート、10 メッシュ、13 封入代、  1 fireproof double-layer pipe, 2 inner pipe, 3 outer pipe, 4 gap, 5 slide control member, 6 outer shell made of aluminum foil, 7 resin sheet, 8 sound absorbing sheet, 9 waterproof sound insulating sheet, 10 mesh, 13 encapsulation allowance,

Claims (2)

合成樹脂製の内管の外周に繊維混入モルタル製の外管をスライド可能に装着し、該外管の外周面に、アルミ箔の外皮と遮音性を有する樹脂シートと難燃性フェルトの吸音シートとを順次に貼着した構成の防水遮音シートを巻き付けて接合した耐火二層管において、該防水遮音シートの巻き付け開始側と巻き終わり側に、樹脂シートおよび吸音シートよりも上記アルミ箔をせり出させ、外管に巻き付けた防水遮音シートの耐熱性接着剤を塗布するためと、樹脂シートおよび吸音シートの端部を封入して防水するための封入代を形成したことを特徴とする耐火二層管。   A fiber-mixed mortar outer tube is slidably mounted on the outer periphery of the synthetic resin inner tube, and an outer surface of the outer tube is made of an aluminum foil skin and a sound insulating resin sheet and a flame retardant felt sound absorbing sheet. In the fireproof two-layer pipe, which is wound and joined with a waterproof sound insulation sheet having a structure in which the waterproof sound insulation sheet is sequentially attached, the above aluminum foil protrudes from the resin sheet and the sound absorbing sheet on the winding start side and the winding end side of the waterproof sound insulation sheet. Fireproof two-layer characterized by forming a sealing allowance for waterproofing by enclosing the ends of the resin sheet and the sound-absorbing sheet and applying the heat-resistant adhesive of the waterproof sound-insulating sheet wound around the outer tube tube. 上記防水遮音シートの外皮の樹脂シート側の全面に難燃性繊維のメッシュを貼着したことを特徴とする請求項1に記載の耐火二層管。   The fireproof double-layer tube according to claim 1, wherein a mesh of flame retardant fibers is attached to the entire surface of the outer surface of the waterproof sound insulation sheet on the resin sheet side.
JP2004307421A 2004-09-22 2004-09-22 Refractory double-layer pipe Expired - Fee Related JP4463073B2 (en)

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JP4889453B2 (en) * 2006-10-17 2012-03-07 フネンアクロス株式会社 Fireproof double-layer pipe or fireproof double-layer pipe joint for penetration
FR2943397B1 (en) * 2009-03-17 2016-06-03 Daher Aerospace THERMAL INSULATION PROTECTION ELEMENT FOR PIPING
JP5351727B2 (en) * 2009-04-24 2013-11-27 積水化学工業株式会社 Fireproof sound insulation pipe
JP5404749B2 (en) * 2011-11-21 2014-02-05 株式会社エーアンドエーマテリアル Manufacturing method of fireproof double-layer pipe
JP5955572B2 (en) * 2012-02-02 2016-07-20 昭和電工建材株式会社 Refractory double-layer tube and method for producing the same
CN104364077B (en) 2012-06-07 2017-03-15 陶氏环球技术有限责任公司 The polymeric foam insulation system of pipe
JP6576711B2 (en) * 2015-06-30 2019-09-18 株式会社小島製作所 Drainage pipe fitting

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