JP4389718B2 - Insulating seal structure and fuel cell - Google Patents

Description

  The present invention relates to an insulating seal structure and a fuel cell.

  Conventionally, an anode electrode is disposed on one of the front and back surfaces of the electrolyte membrane, and a cathode electrode is disposed on the other, and a separator is disposed outside the gap with a gap serving as a gas passage. A multi-layered fuel cell (fuel cell stack) is known.

  In a fuel cell, it is important to keep the gas flowing through the inside, that is, the anode gas, the cathode gas, and the exhaust gas, airtight. It is necessary to ensure airtightness.

  On the other hand, for each unit cell, it is also important to prevent a short circuit between the anode electrode and the cathode electrode, but in the case of adopting the above laminated structure, it is necessary to ensure insulation between the laminated members. There is.

Therefore, in the fuel cell disclosed in Patent Document 1, a glassy sealing material having an insulating property is sandwiched between end portions of two separators (current collector plates) adjacent to each other and welded at a high temperature. Both airtightness and insulation are ensured (for example, see Patent Document 1).
JP-A-8-7903 (2nd page, FIG. 1)

  However, in the seal structure disclosed in Patent Document 1, the melted glass may ooze out or evaporate at the time of welding due to non-uniform temperature, and the sealing performance may be impaired. Moreover, as a countermeasure, when bismuth, boron, or the like is added to adjust the melting point of the glass, these additives become mobile ions at high temperatures, so that the insulation may be lowered during operation as a fuel cell. .

  Accordingly, an object of the present invention is to obtain an insulating seal structure that more reliably seals and insulates between two members facing each other.

In the present invention, an insulating gasket is sandwiched between a pair of opposing members to seal and insulate between the opposing members, and the insulating gasket has an insulating material as a main component. And a metal coating formed on the surface of the core by vapor deposition and in contact with the opposing member, and the metal coating is provided in a region in contact with the metal coating on the surface of the opposing member. The most important feature is that a convex seal portion that bites into the portion is formed .

According to the insulating seal structure of the present invention, an insulating property comprising: a core portion made of a material whose main component is an insulating material; and a metal covering portion formed on the surface of the core portion by vapor deposition and in contact with the opposing member. Since the gasket is narrowly sandwiched between a pair of opposing members, the melted glass oozes out and the sealing performance is not impaired, and the additive does not operate as movable ions, so that the opposing members can be more reliably connected. Can be sealed and insulated.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. In the following embodiment, the case where the insulating seal structure according to the present invention is applied to a fuel cell (solid oxide fuel cell) for an automobile will be exemplified.

  (First Embodiment: FIGS. 1 to 4) FIG. 1 is a schematic view showing a fuel cell stack according to a first embodiment of the present invention, in which (a) is a sectional view along the stacking direction, and (b). Is a cross-sectional view orthogonal to (a) along the stacking direction, and (c) is an enlarged view of region A in (a).

  The fuel cell stack 1 is configured by stacking a plurality of unit cells 2 each functioning as a fuel cell. Each unit cell 2 generates an electromotive force of about 1 V, and these are connected in series via a separator 3 as a conductor to generate a specified output voltage. In the fuel cell stack 1, the separator 3, the insulating gasket 4, and the fuel cell assembly 5 are repeatedly stacked in this order, and the portion sandwiched between the two separators 3 functions as the unit cell 2. These components stacked in the fuel cell stack 1 are fastened, for example, by sandwiching a pair of end plates (not shown) provided at both ends in the stacking direction using tension rods (not shown). The In the following description, for convenience, the upper and lower sides are defined according to FIG. That is, the stacking direction of the fuel cell stack 1 is defined as the vertical direction.

  2A and 2B are schematic views showing the fuel cell assembly, where FIG. 2A is a plan view and FIG. 2B is a cross-sectional view taken along line BB in FIG.

In the present embodiment, rectangular anode electrode 7 and cathode electrode 8 are arranged on the front and back surfaces of rectangular electrolyte section 6 in plan view as electrodes having a gas diffusion layer having a gas diffusion function to the catalyst surface, respectively. Thus, the fuel cell 9 is configured. Specifically, for example, the electrolyte part 6 is configured by a ceramic material (for example, stabilized zirconia added with 8 mol% yttria (Y ₂ O ₃ ); hereinafter referred to as 8YSZ) having a 10 cm square and a thickness of 100 μm. The The anode electrode 7 is mainly composed of NiO-8YSZ, while the cathode electrode 8 is mainly composed of LSC (lanthanum-cobalt composite oxide), both of which are 9 cm square and on the surface and the back surface of the electrolyte part 6, respectively. It is baked to a thickness of several tens to 100 μm.

  Then, the upper surface (region in which no electrode is formed) of the peripheral portion of the electrolyte portion 6 is fixed to the inner peripheral side of the lower surface of the rectangular frame-shaped support frame 10 by, for example, brazing, and the fuel cell assembly 5 is configured. The Each side of the support frame 10 is provided with strip-shaped openings 11a to 11d in plan view, of which the opening 11a is a cathode gas introduction side manifold 20a and the opening 11b is a cathode gas exhaust side manifold. 20b and the opening 11c serve as an anode gas inlet side manifold 20c, and the opening 11d serves as an anode gas exhaust side manifold 20d. The support frame 10 is preferably made of a ferritic stainless steel alloy having a heat expansion coefficient close to that of the electrolyte part 6 (8YSZ), and has a thickness of about 100 μm.

  3A and 3B are schematic views showing the separator 3, wherein FIG. 3A is a plan view, FIG. 3B is a sectional view taken along the line CC in FIG. 3A, and FIG. 3C is a sectional view taken along the line DD in FIG. .

  The separator 3 has a rectangular appearance in plan view, and includes an outer frame portion 3a and an inner partition wall portion 3b.

  The outer frame portion 3a is provided with openings 12a to 12d penetrating the strip-shaped front and back in plan view along each side edge of the separator 3, and the opening 12a is a cathode gas introduction side manifold. 20a (FIG. 1 (a)), the opening 12b is an exhaust-side manifold 20b for cathode gas, the opening 12c is an introduction-side manifold 20c for anode gas (FIG. 1 (b)), and the opening 12d is an exhaust-side manifold for anode gas. 20d.

  The partition wall portion 3b is a thin plate-like portion formed at a substantially central position in the stacking direction, and the cell 2 (FIG. 1) is divided by the partition wall portion 3b. The upper recess 13 on the upper side of the partition wall 3b extends in a trapezoidal shape at both ends in the vertical direction in FIGS. 3A and 3C and communicates with the openings 12c and 12d, while the lower recess 14 Is formed in a trapezoidal shape at both ends in the left-right direction in FIGS. 3A and 3B and communicates with the openings 12a and 12b, and the fuel cell stack 1 is constructed as shown in FIG. In this case, the upper recess 13 becomes the anode gas passage 15 and the lower recess 14 becomes the cathode gas passage 16. As shown in FIG. 1, in the present embodiment, a current collector 21 made of, for example, platinum mesh or alloy felt is disposed in the anode gas passage 15 and the cathode gas passage 16.

  The separator 3 needs to have high heat resistance and conductivity. Therefore, for example, it is preferable to use the same material as the support frame 10, that is, a ferritic stainless steel alloy having a heat expansion coefficient close to 8YSZ, and the partition wall portion 3b has a thickness of about 100 μm.

  4A and 4B are schematic views showing the insulating gasket 4, wherein FIG. 4A is a plan view, FIG. 4B is a cross-sectional view taken along line EE in FIG. 4A, and FIG. 4C is an enlarged view of a region F in FIG. It is.

  As shown in FIG. 4A, the insulating gasket 4 is formed in a rectangular frame shape and is provided with strip-shaped openings 19a to 19d in plan view, of which the opening 19a is a cathode. The gas introduction side manifold 20a (FIG. 1A), the opening 19b is the cathode gas exhaust side manifold 20b, the opening 19c is the anode gas introduction side manifold 20c (FIG. 1B), and the opening 19d is the anode. It becomes the gas exhaust side manifold 20d. The openings 19a to 19d, the openings 11a to 11d provided in the support frame 10, and the openings 12a to 12d provided in the separator 3 are formed when the fuel cell stack 1 is configured by stacking the respective components. Corresponding ones overlap each other, and manifolds 20a to 20d extending in the stacking direction are formed.

  As shown in FIG. 4B, the insulating gasket 4 includes a rectangular and thin plate-shaped core portion 17 and a metal covering portion 18 that covers the entire front and back surfaces of the core portion 17. Specifically, for example, a mica material is formed into a sheet having a thickness of 0.3 mm using silicon resin, and this is used as the core portion 17, and after punching and organic components are burned off by heat treatment, Silver (Ag) is deposited to a thickness of about 100 μm by a plating method (PVD [Physical Vapor Deposition] method) to form the metal cover 18.

  Thus, by forming the metal covering portion 18 by vapor deposition, as shown in FIG. 4C, the surface of the core portion 17 is formed without generating a gap between the core portion 17 and the metal covering portion 18. The minute irregularities on the back surface can be more reliably filled with the metal. In addition, familiarity on the surface where the metal covering portion 18 and the members with which the metal covering portion 18 abuts (the support frame 10 and the separator 3 in this embodiment) abuts is improved, compared with the case where an insulating member such as glass directly abuts. In addition, there is an advantage that the sealing performance becomes higher. Therefore, according to this embodiment, there exists an advantage that sealing performance becomes high compared with the case where insulating members, such as glass, are directly contacted and sealed.

  Then, the separator 3, the fuel cell assembly 5, and the insulating gasket 4 having the above-described configuration are stacked in multiple layers in this order and fastened to form the fuel cell stack 1 shown in FIG. 1. In the fuel cell stack 1, as shown in FIG. 1A, the cathode gas is distributed from the introduction side manifold 20a to each cathode gas passage 16, and the exhaust gas after the reaction is aggregated in the discharge side manifold 20b. On the other hand, as shown in FIG. 1B, the anode gas is distributed from the introduction side manifold 20c to each anode gas passage 15, and the exhaust gas after the reaction is collected and discharged by the discharge side manifold 20d. The In the fuel cell stack 1, the direction in which the cathode gas flows through the cathode gas passage 16 and the direction in which the anode gas flows through the anode gas passage 15 are orthogonal to each other.

  In the fuel cell stack 1, the insulating gasket 4 is provided between the upper surface of the separator 3 and the lower surface of the support frame 10 to insulate the separator 3 from the support frame 10. Here, the support frame 10 and the separator 3 on the upper side of the insulating gasket 4 are electrically connected to the cathode electrode 8 of the fuel cell 9, while the separator 3 on the lower side of the insulating gasket 4 is connected to the fuel cell 9. The anode electrode 7 is electrically connected. Therefore, in the present embodiment, the insulating gasket 4 can prevent a short circuit between the cathode electrode 8 and the anode electrode 7 of each fuel cell 9. In addition, another gasket (not shown) is interposed between the upper surface of the support frame 10 and the lower surface of the separator 3 (27 in FIG. 1C), and the airtightness is maintained between them. However, it is not always necessary to insulate the portion 27. This is because insulation between the separators 3 can be secured by the insulating gasket 4.

  The insulating gasket 4 seals between the upper surface of the separator 3 and the lower surface of the support frame 10. That is, as shown in FIGS. 1A and 1C, the insulating gasket 4 causes the cathode gas introduction side manifold 20a to be connected to the outside, between the introduction side manifold 20a and the anode gas passage 15, and to the cathode. The gas-exhaust manifold 20b and the outside, and the gas-exhaust manifold 20b and the anode gas passage 15 are kept airtight and, as shown in FIG. Airtightness is maintained between the outside and between the exhaust side manifold 20d and the outside.

  As described above, according to the present embodiment, the cathode gas, the anode gas, and the exhaust gas thereof are sealed with a relatively simple configuration using the insulating gasket 4, and the cathode electrode 8 and the anode electrode of the fuel cell 9 are sealed. By preventing a short circuit with 7, the output efficiency of the fuel cell can be improved.

  And according to this embodiment, like an insulating seal for welding conventionally used glass, the glass melted in a high temperature environment bleeds out and the sealing performance is lowered, or an additive for adjusting the melting point is added. Because it does not cause problems such as deterioration of insulation due to mobile ions, the sealing performance and insulation performance are higher than the glass-welded insulation seal, and the performance is improved over a longer period of time. There is an advantage that it can be secured.

  Further, the insulating gasket 4 according to the present embodiment is more flexible than a glass welding type insulating seal, can easily enter a minute recess on the contact surface, and can ensure sealing performance with a lower surface pressure. Therefore, there is an advantage that the fastening force of each component constituting the fuel cell stack 1 can be further reduced, and the structure for fastening can be simplified. Moreover, even if it does not make it a complicated shape such as a metal having a C cross section or a metal having an O cross section, it is possible to further reduce the size and weight because the high sealing performance can be ensured.

  In particular, when the member in contact with the insulating gasket 4 is a metal member as in the present embodiment, the familiarity between the metal member and the metal covering portion 18 is improved, and the sealing performance is further improved. There are advantages.

  Further, the metal cover 18 is as thin as several tens to several hundreds of nanometers, and it is possible to suppress an increase in the stacking length even when a large number of the metal coverings 18 are inserted like the fuel cell stack 1. Further, it can be formed by a mass production method such as vapor deposition or plating, which is advantageous in terms of cost.

  In the above embodiment, mica material is used as the insulating material of the core portion 17, but instead of this, other insulating ceramic materials, for example, oxides such as alumina, silica, magnesia, zirconia, calcia, Nitride such as boron nitride, silicon nitride, and aluminum nitride may be used.

  Moreover, the core part 17 may be comprised as what laminated | stacked the layer using the mica as an insulating material, and at least one layer among a metal and glass, and in order to improve a sealing performance, as an insulating material, You may comprise as what added at least any one of glass and mica to this ceramic fiber. In the latter case, it is more preferable to form the metal covering portion 18 after the core portion 17 is molded and subjected to predetermined heat treatment. Moreover, in order to facilitate the handling at the time of manufacturing assembly, a silicon resin may be added.

  Moreover, the metal coating | cover part 18 is good also as single-piece | units, such as aluminum, gold | metal | money, platinum, nickel, cobalt, tungsten, copper, magnesium, iron, chromium other than silver mentioned above, or an alloy which has it as a main component. In any case, it is preferable to use a material having a melting point higher than the temperature of the fluid to be sealed (in this case, anode gas, cathode gas, exhaust gas). In this way, it is possible to ensure sealing performance more reliably.

  In addition, it is preferable that the metal covering portion 18 has a multi-layered structure, and the layer closer to the abutting member (opposing member) has a thermal expansion coefficient closer to that of the opposing member. In this way, the familiarity on the contact surface is further improved and the generation of thermal stress can be suppressed. At this time, it is more preferable that the layer closer to the core portion 17 has a thermal expansion coefficient closer to that of the core portion 17.

  In addition, it is preferable that the metal covering portion 18 has a multilayer structure, and the hardness of the layer closer to the contacting member (opposing member) is lowered. By doing so, the familiarity on the contact surface is further improved. At this time, it is more preferable that the layer closer to the core portion 17 has a hardness closer to that of the core portion 17.

  Further, the metal coating portion 18 may be formed by a CVD (Chemical Vapor Deposition) method, a plating method, a sputtering method, or the like.

  Second Embodiment: FIG. 5 FIG. 5 is an enlarged cross-sectional view showing a portion where an insulating gasket is sandwiched between separators in a fuel cell stack according to a second embodiment of the present invention. The fuel cell stack according to the present embodiment has the same components as those in the first embodiment. Therefore, the same components are denoted by the same reference numerals, and detailed description thereof is omitted.

  In the present embodiment, a projecting seal portion 22 having a triangular cross section and biting into the metal coating portion 18 is formed in a region that contacts the metal coating portion 18 on the surface of the separator 3A. By making the metal-coated portion 18 bite into the protruding seal portion 22, the surface pressure can be increased and the sealing performance can be further improved. The projecting seal portion 22 is formed in an annular shape along the openings 12a to 12d formed in the separator 3A and the outer peripheral edge of the separator 3A, and the sealing performance is ensured over the entire periphery. Is preferred. In this case, it is preferable that the height of the protruding seal portion 22 is 1/10 to 3 times the thickness of the metal covering portion 18 and the width is within 3 times the height. Further, the cross section of the projecting seal portion 22 is not limited to a triangular shape, but may be a semicircular shape, a rectangular shape, or other various shapes.

  (Third Embodiment: FIG. 6) FIG. 6 is an enlarged cross-sectional view showing a portion where an insulating gasket is sandwiched between separators in a fuel cell stack according to a third embodiment of the present invention. The fuel cell stack according to the present embodiment has the same components as the fuel cell tack according to the first embodiment. Therefore, the same components are denoted by the same reference numerals, and detailed description thereof is omitted.

  In the present embodiment, a seal member 23 different from the insulating gasket 4 is sandwiched between the metal cover 18 and the separator 3. In this case, for example, the sealing member 23 has a semicircular cross section, and the surface pressure can be increased by causing the metal covering portion 18 to bite into the sealing member 23, thereby further improving the sealing performance. And it is suitable for this sealing member 23 to form in cyclic | annular form along the edge of the outer periphery of the opening parts 12a-12d formed in the separator 3, and the separator 3, and to ensure a sealing performance over the perimeter. is there. In this case as well, it is preferable that the height of the seal member 23 is 1/10 to 3 times the thickness of the metal cover 18 and the width is within 3 times the height. Further, the cross section of the seal member 23 is not limited to a semicircular shape, but may be a triangular shape, a rectangular shape, or other various shapes.

  The seal member 23 is made of the same material as that of the metal cover 18, that is, a simple substance such as aluminum, silver, gold, platinum, nickel, cobalt, tungsten, copper, magnesium, iron, and chromium, or the main component thereof. An alloy is preferred.

  (Fourth Embodiment: FIGS. 7 to 9) FIGS. 7 to 9 are schematic views of an insulating gasket attached to a fuel cell stack according to a fourth embodiment of the present invention. 8 (a) and FIG. 9 are plan views of the respective embodiments, FIG. 7 (b) is a sectional view taken along the line GG of FIG. 8 (a), and FIG. 8 (b) is the same drawing. It is HH sectional drawing of (a). The fuel cell stack according to the present embodiment has the same components as those in the first embodiment. Therefore, the same components are denoted by the same reference numerals, and detailed description thereof is omitted.

  The insulating gaskets 4A to 4C according to the present embodiment cover only a part of the front surface (or back surface) of the core portion 17 with the metal covering portions 24, 25, and 26, and are covered with the metal covering portions 24, 25, and 26. The front surface (or back surface) of the core portion 17 that is exposed without being exposed directly faces the separator 3. With such a configuration, the amount of metal used can be reduced and the manufacturing cost can be reduced, and the surface pressure of the metal covering portions 24, 25 and 26 can be increased to improve the sealing performance. In this case, the metal covering portions 24, 25, and 26 are formed in an annular shape along the openings 19a to 19d of the insulating gaskets 4A to 4C and the edges of the outer periphery, and the sealing performance is ensured over the entire periphery. Is preferred. That is, in the example of FIG. 7, only one row of rectangular frame-shaped metal coating portions 24 is formed, in the example of FIG. 8, the same rectangular frame-shaped metal coating portions 25 are formed, and in the example of FIG. Only one row of the metal-coated portions 26 is formed. Note that the embodiment of FIG. 9 has an advantage that the reliability is improved by the amount of thermal stress of the metal coating portion 26 being relaxed.

  (5th Embodiment: FIG. 10) (a) of FIG. 10 is sectional drawing which expands and shows the peripheral part of one single cell which comprises the fuel cell stack concerning 5th Embodiment of this invention, ( b) is an enlarged view of the region J of FIG. The fuel cell stack according to the present embodiment has the same components as those in the first embodiment. Therefore, the same components are denoted by the same reference numerals, and detailed description thereof is omitted.

  In the present embodiment, the support frame 10A is configured as a core portion of an insulating gasket. Further, as shown in (b), the separator 3 that contacts the metal covering portion 18 includes a protruding seal portion 22 that bites into the metal covering portion 18. In this case, the material of the support frame 10A (core part) is, for example, partially stabilized zirconia (3YSZ) added with 3 mol% yttria having a thickness of 100 μm from the viewpoint of strength and sealing properties, and the surface of the insulating gasket 10A. In addition, it is preferable to form the metal coating 18 mainly composed of a metal such as silver (Ag) by vapor deposition or the like. With this configuration, the number of components can be reduced to reduce the manufacturing cost, and the height of the fuel cell stack as a whole can be reduced in the stacking direction to reduce the size and weight.

  (6th Embodiment: FIG. 11) (a) of FIG. 11 is sectional drawing which expands and shows the peripheral part of one single cell which comprises the fuel cell stack concerning this embodiment, Moreover, (b) It is an enlarged view of the area | region K of (a). The fuel cell stack according to the present embodiment has the same components as those in the first embodiment. Therefore, the same components are denoted by the same reference numerals, and detailed description thereof is omitted.

  In the present embodiment, the electrolyte portion 6A is configured as a core portion of an insulating gasket. Further, as shown in (b), the separator 3 that contacts the metal covering portion 18 includes a protruding seal portion 22 that bites into the metal covering portion 18. In this case, the material of the electrolyte part 6A (core part) is, for example, partially stabilized zirconia (3YSZ) added with 3 mol% yttria having a thickness of 100 μm from the viewpoint of strength and sealability, and is formed on the surface of the electrolyte part 6A. It is preferable to form the metal coating portion 18 mainly composed of a metal such as silver (Ag) by vapor deposition or the like. With this configuration, the number of components can be reduced to reduce the manufacturing cost, and the height of the fuel cell stack as a whole can be reduced in the stacking direction to reduce the size and weight.

  The preferred embodiments of the present invention have been described above, but the present invention is not limited to the above embodiments, and various modifications can be made to the above embodiments without departing from the scope of the invention. For example, in the first embodiment, the case where the insulating gasket 4 is narrowly disposed between the lower surface of the support frame 10 and the upper surface of the separator 3 positioned below the support frame 10 is illustrated. The insulating gasket 4 may be narrowed between the upper surface of 10 and the lower surface of the separator 3 positioned above (10 in FIG. 1C). In the above-described embodiment, the insulating seal structure according to the present invention is exemplified for the case where rectangular fuel cells are stacked and used in the fuel cell stack. However, the fuel cell stack in which fuel cells other than the rectangle are stacked is illustrated. Of course, it can be used. In addition, the present invention can be implemented as an insulating seal structure of other types of fuel cell stacks such as a carbonated molten salt type and a phosphoric acid type. Of course, it can also be implemented as a structure. The present invention is particularly suitable for an insulating seal structure under a high temperature environment, but it goes without saying that the effect can be obtained even under no high temperature environment.

It is a schematic diagram (sectional view) of a fuel cell stack according to an embodiment of the present invention. It is the schematic diagram (a top view and sectional drawing) of the fuel cell included in the fuel cell stack concerning the embodiment of the present invention. It is the schematic diagram (a top view and sectional drawing) of the separator contained in the fuel cell stack concerning the embodiment of the present invention. It is the schematic diagram (a top view and sectional drawing) of the insulating gasket contained in the fuel cell stack concerning 1st Embodiment of this invention. It is a schematic diagram (sectional drawing) of the insulating gasket contained in the fuel cell stack concerning 2nd Embodiment of this invention. It is a schematic diagram (sectional drawing) of the insulating gasket contained in the fuel cell stack concerning 3rd Embodiment of this invention. It is a schematic diagram (plan view and sectional view) showing an example of an insulating gasket included in a fuel cell stack according to a fourth embodiment of the present invention. It is a schematic diagram (plan view and sectional view) showing another example of the insulating gasket included in the fuel cell stack according to the fourth embodiment of the present invention. It is a schematic diagram (top view) which shows another example of the insulating gasket contained in the fuel cell stack concerning 4th Embodiment of this invention. It is a schematic diagram (cross-sectional view) of a fuel cell included in a fuel cell stack according to a fifth embodiment of the present invention. It is a schematic diagram (sectional drawing) of the fuel cell contained in the fuel cell stack concerning 6th Embodiment of this invention.

Explanation of symbols

1 Fuel cell stack (fuel cell)
3,3A separator (opposing member)
4, 4A to 4C Insulating gasket 5 Fuel cell assembly 6 Electrolyte part 6A Electrolyte part (core part)
7 Anode electrode 8 Cathode electrode 9 Fuel cell 10 Support frame (opposing member)
10A Support frame (core part)
17 Core part 18, 24, 25, 26 Metal coating part 22 Protruding seal part 23 Seal member

Claims (19)

An insulating seal structure in which an insulating gasket is sandwiched between a pair of opposing members to seal and insulate between the opposing members,
The insulating gasket is
A core portion made of a material mainly composed of an insulating material;
A metal coating formed on the surface of the core by vapor deposition and in contact with the opposing member;
Equipped with a,
An insulating seal structure characterized in that a convex seal portion that bites into the metal coating portion is formed in a region that contacts the metal coating portion on the surface of the opposing member . An insulating seal structure in which an insulating gasket is sandwiched between a pair of opposing members to seal and insulate between the opposing members,
The insulating gasket is
A core portion made of a material mainly composed of an insulating material;
A metal coating formed on the surface of the core by vapor deposition and in contact with the opposing member;
With
An insulating seal structure characterized in that a seal member different from the insulating gasket is sandwiched between the metal covering portion and the opposing member . The insulating seal structure according to claim 1 or 2 , wherein the insulating gasket is formed with a portion where the core portion is not covered by the metal covering portion and is exposed to face the opposing member. Insulating sealing structure according to any one of claims 1-3, characterized in that an insulating ceramic as the insulating material. Insulating sealing structure according to any one of claims 1-3, characterized in that using a mica or ceramic fibers as the insulating material. 6. The insulating seal structure according to claim 5 , wherein the core portion is configured by adding at least one of silicon resin and glass to mica as an insulating material. The insulating seal structure according to claim 6 , wherein the metal coating portion is formed after the core portion is molded and subjected to a predetermined heat treatment. The insulating seal structure according to claim 5 , wherein the core portion is configured by laminating a layer using mica as an insulating material and at least one layer of metal and glass. The insulating seal structure according to claim 5 , wherein the core portion is configured by adding at least one of glass and mica to ceramic fibers as an insulating material. The insulating seal structure according to any one of claims 1 to 9 , wherein the metal covering portion is configured using a material having a melting point higher than a temperature of a fluid to be sealed. The main component of the metallization, aluminum, silver, gold, platinum, nickel, cobalt, any one of claims 1-10, characterized tungsten, copper, magnesium, iron, and that either of chromium The insulating seal structure according to one. The insulating seal structure according to claim 2 , wherein the seal member is made of metal. The insulating seal structure according to claim 12 , wherein a main component of the seal member is any one of aluminum, silver, gold, platinum, nickel, cobalt, tungsten, copper, magnesium, iron, and chromium. An insulating seal structure in which an insulating gasket is sandwiched between a pair of opposing members to seal and insulate between the opposing members,
The insulating gasket is
A core portion made of a material mainly composed of an insulating material;
A metal cover formed on the surface of the core portion and in contact with the opposing member;
With
An insulating seal structure characterized in that the metal cover portion has a multi-layer structure, and a layer closer to the opposing member has a thermal expansion coefficient closer to that of the opposing member. An insulating seal structure in which an insulating gasket is sandwiched between a pair of opposing members to seal and insulate between the opposing members,
The insulating gasket is
A core portion made of a material mainly composed of an insulating material;
A metal cover formed on the surface of the core portion and in contact with the opposing member;
With
An insulating seal structure characterized in that the metal cover portion has a multilayer structure, and the hardness of the layer closer to the opposing member is lowered. The insulating seal structure according to any one of claims 1 to 15 is used as an insulating seal structure that seals anode gas, cathode gas, or exhaust gas, and insulates the anode electrode from the cathode electrode. A fuel cell. One of the opposing members is a support frame that supports a fuel cell including an electrolyte part, an anode electrode, and a cathode electrode, and the other is a separator that isolates two fuel cells adjacent to each other. The fuel cell according to claim 16 . The fuel cell according to claim 16 , wherein a support frame that supports a fuel cell including an electrolyte part, an anode electrode, and a cathode electrode is configured as the insulating gasket. The fuel cell according to claim 16 , wherein the electrolyte part of the fuel cell including the electrolyte part, the anode electrode and the cathode electrode is configured as an insulating gasket.

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