JP4287292B2 - Improved moisture-sensitive breathability - Google Patents

Description

  The present invention relates to a moisture-sensitive and breathable improvement garment that senses humidity such as sweat from the skin and reversibly improves the breathability without changing the size of the garment.

  Conventionally, when a woven or knitted fabric made of synthetic fiber or natural fiber is used as sportswear or innerwear, there has been a problem that stuffiness or stickiness is generated due to sweating from the skin.

  As a method for eliminating the stuffiness and stickiness caused by perspiration, for example, Patent Literature 1 and Patent Literature 2 propose clothing having side portions and side body portions made of mesh fabric with good ventilation. However, such a garment has a problem that it is cold because of its good breathability even when the appearance is impaired or when it is not sweating. For these reasons, there has been a demand for a garment that has good breathability only when sweating and reversibly reduces breathability when not sweating.

  On the other hand, in Japanese Patent Application No. 2003-177663, the present inventors use a water-absorbing self-stretching yarn and a non-self-stretching yarn to produce a woven or knitted fabric that has improved air permeability when wet and reversibly decreases air permeability when dried. Proposed. However, it has been found that if the garment is sewn using only such a woven or knitted fabric, the garment size when wet is slightly larger than the garment size when dry.

JP 2003-13301 A JP 2003-239101 A

The present invention has been made in view of the above background, and its purpose is to detect moisture such as perspiration from the skin, and to improve moisture permeability and breathability that reversibly improve without changing the size of clothes. To provide clothes.

  As a result of intensive studies to achieve the above-mentioned problems, the inventors of the present invention have reversible breathability due to wetting in places that are made of woven or knitted fabric that do not improve breathability with respect to wetting. As a result, it was found that a desired garment with improved moisture sensitivity and air permeability can be obtained by using a woven or knitted fabric that can be improved, and the present invention has been completed by intensive studies.

Thus, according to the present invention, “a garment mainly composed of a woven or knitted fabric that does not improve air permeability against moisture, partially having a portion where the air permeability is reversibly improved by moisture , and is wet. The part where the air permeability is reversibly improved by the knitted fabric is composed of a woven or knitted fabric composed of a water-absorbing self-stretching yarn and a non-self-stretching yarn, and the water-absorbing self-stretching in the knitting or knitting in an atmosphere at a temperature of 20 ° C. and a humidity of 65% RH. A moisture-sensitive and air-permeable improvement garment characterized in that A / B is 0.9 or less, where (A) is the yarn length of the yarn and (B) is the yarn length of the non-self-stretching yarn . Provided.

In that case, it is preferable that the site | part which air permeability improves reversibly by wet is 1 site | part or 2 or more site | parts selected from a side part, a side body part, a chest part, a back part, and a shoulder part .

  As a woven or knitted fabric composed of such a water-absorbing self-stretching yarn and a non-self-stretching yarn, a knitting in which a water-absorbing self-stretching yarn and a non-self-stretching yarn form a composite loop of a circular knitted structure, a water-absorbing self-stretching yarn and a non-self-stretching yarn. A woven fabric in which warps and / or wefts of a woven structure are formed by aligning yarns, a water-absorbing self-stretching yarn and a non-self-stretching yarn, each as a constituent yarn of a woven or knitted fabric, one alternately or a plurality of yarns Examples of the knitted or knitted fabric that are alternately arranged, and a woven or knitted fabric that includes a water-absorbing self-stretching yarn and a non-self-stretching yarn as a composite yarn.

  As the water-absorbing self-stretching yarn, a polyether ester fiber made of a polyether ester elastomer having polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment is suitable. On the other hand, polyester fibers are suitable as the non-self-stretching yarn.

  In the portion where the breathability is reversibly improved by wetting of the moisture-sensitive breathability-improving clothes of the present invention, the rate of change in breathability is preferably 30% or more when wet and when dry. Moreover, it is preferable that the woven or knitted fabric whose air permeability is not changed with respect to moisture is mainly composed of polyester fibers. The moisture-sensitive air-permeable improvement garment of the present invention is suitable as an inner garment or a sports garment.

  According to the present invention, it is possible to obtain a moisture-sensitive and breathable improved garment that senses humidity such as perspiration from the skin and reversibly improves the breathability without changing the size of the garment.

Hereinafter, embodiments of the present invention will be described in detail.
The moisture-sensitive and air-permeable improved garment of the present invention is mainly composed of a woven or knitted fabric that does not improve air permeability with respect to moisture, and partially has a portion where the air permeability is reversibly improved by being wet.

Here, in the present invention, “the air permeability is not improved with respect to wetness” and “the air permeability is improved with respect to wetness” are properties defined below. That is, after the woven or knitted fabric is left in an environment of a temperature of 20 ° C. and a humidity of 65 RH for 24 hours (hereinafter referred to as drying), the air permeability is measured to obtain the air permeability during drying. On the other hand, after the woven or knitted fabric is immersed in water having a water temperature of 20 ° C. for 5 minutes (hereinafter referred to as “wet”), the sample is sandwiched between two filter papers at a pressure of 490 N / m ² (50 kgf / m ² ). After weighting for 1 minute to remove moisture present between the fibers, the air permeability is measured to obtain the air permeability when wet. When the air permeability change rate defined by the following formula is less than 5%, “the air permeability is not improved with respect to wetness”, while when the air permeability change rate is 5% or more, “the air permeability with respect to the wetness is not improved”. To improve. " The case where the air permeability is lowered with respect to wetness is also included in “the air permeability does not improve”. The air permeability is measured according to JIS L 1096-1998, 6.27.1, Method A (Fragile type air permeability tester method), and measured with n number of 5 for both dry and wet conditions. The average value is obtained.
Air permeability change rate (%) = ((wet breathability when wet) − (breathability when dried)) / (breathability when dried) × 100

  The woven or knitted fabric that does not improve the air permeability with respect to the wetness may be a conventional woven or knitted fabric made of conventional normal fibers. For example, the types of fibers include organic natural fibers such as cotton, wool and hemp, organic synthetic fibers such as polyester, nylon and polyolefin fibers, organic semi-synthetic fibers such as cellulose acetate fibers, and organic materials such as viscose rayon fibers. It is selected from recycled fibers, and the type is not particularly limited.

  Of these, polyester fibers are preferred in terms of fiber strength and handleability. The polyester fiber is produced from a dicarboxylic acid component and a diglycol component. As the dicarboxylic acid component, terephthalic acid is preferably used mainly, and as the diglycol component, it is preferable to use one or more alkylene glycols selected from ethylene glycol, trimethylene glycol and tetramethylene glycol. Further, the polyester may contain a third component in addition to the dicarboxylic acid component and the glycol component. As the third component, cationic dye dyeable anion components such as sodium sulfoisophthalic acid; dicarboxylic acids other than terephthalic acid such as isophthalic acid, naphthalenedicarboxylic acid, adipic acid, sebacic acid; and glycol compounds other than alkylene glycol, For example, one or more of diethylene glycol, polyethylene glycol, bisphenol A, and bisphenol sulfone can be used.

  For such fibers, a matting agent (titanium dioxide), a micropore forming agent (organic sulfonic acid metal salt), a coloring inhibitor, a heat stabilizer, a flame retardant (antimony trioxide), and a fluorescent whitening agent as necessary. , A coloring pigment, an antistatic agent (sulfonic acid metal salt), a hygroscopic agent (polyoxyalkylene glycol), an antibacterial agent, and other inorganic particles may be contained.

  The form of the fiber is not particularly limited, and may be either a long fiber (multifilament) or a short fiber, but a long fiber is preferable for obtaining a soft texture. Furthermore, normal false twist crimping, twisting, and interlaced air processing may be applied. The fineness of the fiber is not particularly limited, but in order to obtain a soft texture, the single fiber fineness is preferably 0.1 to 3 dtex, the number of filaments is 20 to 150, and the total fineness is preferably 30 to 300 dtex. The cross-sectional shape of the single fiber is not limited, and may have a triangular, flat, cross, hexagonal, or hollow cross-sectional shape in addition to a normal circular cross-section.

  The structure of the woven or knitted fabric in which the air permeability does not improve against wetness is not particularly limited, and may be a normal one. For example, the woven structure of the woven fabric is a three-layer structure such as plain weave, oblique weave, satin weave, etc., altered structure, altered structure such as altered oblique weave, single duplex structure such as vertical double weave, weft double weave, etc. And fresh velvet. The type of knitted fabric may be a weft knitted fabric or a newly knitted fabric. Preferred examples of the weft knitting structure include flat knitting, rubber knitting, double-sided knitting, pearl knitting, tuck knitting, float knitting, one-sided knitting, lace knitting, bristle knitting, and the like. Single atlas knitting, double cord knitting, half tricot knitting, back hair knitting, jacquard knitting and the like are exemplified.

The moisture-sensitive and air-permeable improved garment of the present invention is mainly composed of a woven or knitted fabric that does not improve air permeability with respect to the above-mentioned wetness, and partially has a portion where the air-permeability is reversibly improved by the wetness. As such a part, a part with relatively much sweating is suitable, for example, a side part schematically shown in FIG. 1, a side body part schematically shown in FIG. 2, a chest part schematically shown in FIG. 3, and FIG. A back portion schematically shown in FIG. 5, a shoulder portion schematically shown in FIG. 5, and a combination thereof are suitable. The area of the portion where the air permeability is reversibly improved by the wetting is preferably 500 to 10,000 cm ² , and the area ratio is preferably 5 to 70% with respect to the total area of the clothes. When the area ratio is less than 5%, there is a fear that sufficient improvement in air permeability as clothing total is insufficient when wet and sufficient comfort cannot be obtained. Conversely, if the area ratio is greater than 70%, the dimensions of the clothes may change when wet.

  Although it does not specifically limit as a fabric which comprises the site | part which air permeability improves reversibly by wetness, The woven / knitted fabric proposed by Japanese Patent Application No. 2003-177663 is suitable.

  That is, it is composed of a woven or knitted fabric composed of a water-absorbing self-stretching yarn and a non-self-stretching yarn, and the yarn length of the water-absorbing self-stretching yarn in the woven or knitting in an atmosphere of temperature 20 ° C. and humidity 65% RH is (A), When the yarn length of the non-self-stretching yarn is (B), A / B is 0.9 or less (preferably 0.9 to 0.2, particularly preferably 0.8 to 0.3). is there.

Here, the water-absorbing self-stretching yarn and the non-self-stretching yarn are yarns defined below. That is, using a rewind frame with a frame circumference of 1.125 m, a load of 0.88 mN / dtex (0.1 g / de) was applied and the rewind was performed at a constant speed, and the number of turns: 10 skeins were made and cut off. The yarn is allowed to stand in an environment of a temperature of 20 ° C. and a humidity of 65 RH% for 24 hours. The yarn length (mm) measured by applying a load of de) is defined as the yarn length at the time of drying. The yarn is dipped in water at a water temperature of 20 ° C. for 5 minutes and then pulled up from the water. The yarn length (mm) measured by applying a load of 0088 mN / dtex (1 mg / de) is defined as the wet yarn length. The inelastic yarn is a yarn having a breaking elongation of 200% or less, and the elastic yarn is a yarn having a breaking elongation higher than 200%. And a thing whose swelling rate of the fiber axis direction calculated | required by the following formula is 5% or more is defined as a water absorption self-extension thread | yarn. On the other hand, those having a swelling ratio of less than 5% are defined as non-self-stretching yarns.
Swell ratio (%) = ((wet yarn length) − (dry yarn length)) / (dry yarn length) × 100

  The yarn length is measured by the following method. First, after leaving the woven or knitted fabric to stand in an atmosphere of a temperature of 20 ° C. and a humidity of 65% RH for 24 hours, a 30 cm × 30 cm small piece is cut from the woven or knitted fabric (n number = 5). Subsequently, one water-absorbing self-stretching yarn and one non-self-stretching yarn are taken out from each piece, and the yarn length A (mm) of the water-absorbing self-stretching yarn and the yarn length B (mm) of the non-self-stretching yarn are measured. At that time, in the case of an inelastic yarn, the load is 1.76 mN / dtex (200 mg / de), and in the case of an elastic yarn, a load of 0.0088 mN / dtex (1 mg / de) is applied. Then, (average value of yarn length A) / (average value of yarn length B) is defined as A / B. Here, the water-absorbing self-stretching yarn and the non-self-stretching yarn taken out from the small piece need to be in the same direction in the woven or knitted fabric. For example, when the water-absorbing self-stretching yarn is taken out from the warp (weft) of the fabric, the other non-self-stretching yarn needs to be taken out from the warp (weft). When the water-absorbing self-stretching yarn and the non-self-stretching yarn constitute a woven or knitted fabric as a composite yarn, the composite yarn is taken out from the cut pieces (30 cm × 30 cm) (n number = 5), and further the composite yarn The water-absorbing self-stretching yarn and the non-self-stretching yarn are taken out of the yarn and measured in the same manner as described above.

  The water-absorbing self-stretching yarn is not particularly limited as long as it has the above swelling ratio, but preferably has a swelling ratio of 6% or more (more preferably 8 to 30%).

  Examples of such water-absorbing self-stretching yarns include polyether ester fibers made of a polyether ester elastomer having polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment, polyacrylic acid metal salts, polyacrylic acid and the like. Copolymer, polymethacrylic acid and its copolymer, polyvinyl alcohol and its copolymer, polyacrylamide and its copolymer, polyester fiber blended with polyoxyethylene polymer, 5-sulfoisophthalic acid component Examples include polymerized polyester fibers. Among these, as the water-absorbing self-stretching yarn, a polyether ester fiber made of a polyether ester elastomer having polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment is preferably exemplified.

  The polybutylene terephthalate preferably contains at least 70 mol% of butylene terephthalate units. The content of butylene terephthalate is more preferably 80 mol% or more, and still more preferably 90 mol% or more. The acid component is mainly composed of terephthalic acid, but a small amount of other dicarboxylic acid components may be copolymerized. The glycol component is mainly composed of tetramethylene glycol, but other glycol components are copolymerized. It may be added as a component.

  Examples of dicarboxylic acids other than terephthalic acid include naphthalenedicarboxylic acid, isophthalic acid, diphenyldicarboxylic acid, diphenyloxyethanedicarboxylic acid, β-hydroxyethoxybenzoic acid, p-oxybenzoic acid, adipic acid, sebacic acid, and 1,4- Examples thereof include aromatic and aliphatic dicarboxylic acid components such as cyclohexanedicarboxylic acid. Further, a tricarboxylic or higher polycarboxylic acid such as trimellitic acid or pyromellitic acid may be used as a copolymerization component as long as the achievement of the object of the present invention is not substantially impaired.

  Examples of diol components other than tetramethylene glycol include aliphatic, alicyclic and aromatic diol compounds such as trimethylene glycol, ethylene glycol, cyclohexane-1,4-dimethanol, and neopentyl glycol. Can do. Furthermore, a trifunctional or higher functional polyol such as glycerin, trimethylolpropane, or pentaerythritol may be used as a copolymerization component as long as the achievement of the object of the present invention is not substantially impaired.

  On the other hand, the polyoxyethylene glycol preferably contains at least 70 mol% or more of oxyethylene glycol units. The content of oxyethylene glycol is more preferably 80 mol% or more, and still more preferably 90 mol% or more. In addition to oxyethylene glycol, propylene glycol, tetramethylene glycol, glycerin and the like may be copolymerized within a range where the achievement of the object of the present invention is not substantially impaired.

  The number average molecular weight of such polyoxyethylene glycol is preferably 400 to 8000, and particularly preferably 1000 to 6000.

  The polyether ester elastomer is obtained, for example, by subjecting a raw material containing dimethyl terephthalate, tetramethylene glycol and polyoxyethylene glycol to a transesterification reaction in the presence of a transesterification catalyst to produce bis (ω-hydroxybutyl) terephthalate and / or Alternatively, it can be obtained by forming an oligomer and then performing melt polycondensation under high temperature and reduced pressure in the presence of a polycondensation catalyst and a stabilizer.

  The ratio of hard segment / soft segment is preferably 30/70 to 70/30 based on weight.

  It is preferable that a known organic sulfonic acid metal salt is contained in such a polyether ester because a further excellent water absorption self-extension performance is obtained.

  The polyether ester fiber is obtained by melting and extruding the polyether ester from a normal melt spinneret, and taking it out at a take-up speed of 300 to 1200 m / min (preferably 400 to 980 m / min). It can manufacture by winding at 1.0-1.2 (preferably 1.0-1.1) of taking-up speed.

  On the other hand, non-self-stretched yarns include natural fibers such as cotton and linen, cellulosic chemical fibers such as rayon and acetate, and polyesters such as polyethylene terephthalate and polytrimethylene terephthalate, polyamide, polyacrylonitrile, and polypropylene. These synthetic fibers are exemplified. Especially, a normal polyester fiber is illustrated preferably.

  The fiber form of the water-absorbing self-stretching yarn and the non-self-stretching yarn is not particularly limited, and may be a short fiber or a long fiber. The cross-sectional shape of the fiber is not particularly limited, and a known cross-sectional shape such as a circle, a triangle, a flat shape, or a hollow shape can be employed. The total fineness, single yarn fineness, and number of filaments of the water-absorbing self-stretched yarn and non-self-stretched yarn are not particularly limited, but the total fineness is 30 to 300 dtex, the single yarn fineness is 0.6 to 10 dtex, and the number of filaments is 1 in terms of texture and productivity. A range of ˜300 is preferred.

  The weight ratio of the water-absorbing self-stretching yarn and the non-self-stretching yarn is 10:90 to 60:40 (more preferably 20:80 to 50: in the former: the latter) in order to effectively improve the air permeability when wet. 50) is preferable.

  As the structure of the woven or knitted fabric whose breathability is reversibly improved by wetting, the woven or knitted structure and the number of layers are not particularly limited. For example, woven structures such as plain weave, twill weave, and satin, and knitted structures such as tengu, smooth, milling, kanoko, denby, and tricot are preferably exemplified, but not limited thereto. The number of layers may be a single layer or a multilayer of two or more layers.

The yarn arrangement of the water-absorbing self-stretching yarn and the non-self-stretching yarn is not particularly limited, but the following yarn arrangement is preferably exemplified.
First, the hygroscopic self-stretching yarn and the non-self-stretching yarn are aligned to form a needle loop of a knitted fabric and a yarn arrangement constituting a warp and / or weft of a woven fabric. For example, as shown in FIG. 6, a hygroscopic self-stretching yarn and a non-self-stretching yarn form a circular loop knitted composite loop (two yarns form a needle loop at the same time, also called splicing yarn). As shown in FIG. 7, the formed yarn arrangement and the yarn arrangement in which the water-absorbing self-stretching yarn and the non-self-stretching yarn are aligned and arranged on the warp and / or the weft of the woven structure are exemplified.

  As part 2, hygroscopic self-stretching yarn and non-self-stretching yarn are arranged alternately (1: 1) or plural (2: 2, 3: 3, etc.) in the warp and / or weft of the woven or knitted fabric. Thread arrangement. For example, as shown in FIG. 8, a yarn arrangement in which a water-absorbing self-stretching yarn and a non-self-stretching yarn are arranged 1: 1 in a circular knitted fabric, and as shown in FIG. Examples thereof include a yarn arrangement in which self-stretching yarns are arranged 1: 1 on warps and wefts.

  As a third example, there is an embodiment in which a water-absorbing self-stretching yarn and a non-self-stretching yarn constitute a woven or knitted fabric as a composite yarn such as a mixed yarn, a composite false twist crimped yarn, a combined twist yarn, or a covering yarn.

  In these yarn arrangements, the following method is exemplified as a method of creating a difference in yarn length between the water-absorbing self-stretching yarn and the non-self-stretching yarn.

For example, as one of the above, when knitting or weaving the woven or knitted fabric, the polyether ester fiber having elasticity is used as a water-absorbing self-stretching yarn, and the polyether ester fiber is not self-stretched while being drafted (stretched). There is a method of knitting and weaving by aligning with yarn and feeding to the same yarn feeder. At that time, the draft rate of the polyetherester fiber is preferably 10% or more (preferably 20% or more and 300% or less). The draft rate (%) is obtained by the following formula.
Draft rate (%) = (((take-off speed) − (supply speed)) / (supply speed)) × 100
Since polyetherester fibers usually have elastic performance, in woven and knitted fabrics, the polyetherester fibers are elastically recovered and their yarn length is shortened, resulting in a difference in yarn length from the other non-self-stretching yarn. I can make it.

  As a second method, when the woven or knitted fabric is knitted or woven, the boiling water shrinkage rate of the water-absorbing self-stretching yarn is made larger than that of the non-self-stretching yarn. By subjecting such a woven or knitted fabric to a normal dyeing process, the yarn length of the water-absorbing self-stretching yarn is shortened, and a yarn length difference from the other non-self-stretching yarn can be obtained.

  As part 3, the non-self-stretched yarn is aligned with the water-absorbing self-stretched yarn while overfeeding (oversupply) to obtain a composite yarn from ordinary air-mixing, twisting, and covering processing, and the composite yarn is used. And a method of knitting and knitting the knitted fabric.

  By selecting the woven or knitted fabric whose air permeability is reversibly improved by the above-mentioned wet as the fabric constituting the portion where the air permeability is reversibly improved by wetting, for example, the woven or knitted fabric can be separated from the water-absorbing self-stretching yarn. In the case of a circular knitted fabric in which the self-stretching yarn forms a composite loop of a circular knitted structure, the loop made of non-self-stretching yarn in the composite loop of the circular knitted fabric as shown in FIG. It's slack. When wet, the water-absorbing self-stretching yarn self-extends as shown in (2) of FIG. 6 and the loop swells and becomes large. At the same time, the loop made of the loose non-self-stretching yarn is stretched and stretched. The air gap becomes larger and the air permeability is improved.

  In the woven or knitted fabric whose breathability is reversibly improved by wetting, the rate of change in breathability between dry and wet is preferably 30% or more (more preferably 50 to 300%). If the air permeability change rate is less than 30%, there is a possibility that dullness and stickiness cannot be sufficiently eliminated when moisture is sensed.

  In the moisture-sensitive breathable garment of the present invention, the portion where the breathability is reversibly improved by the above-mentioned wetting is preferably attached by sewing, but the woven or knitted fabric does not improve the breathability with respect to the wetting. Thus, the knitted or knitted fabric may be integrated with the portion where the air permeability is reversibly improved.

  Wearing the moisture-sensitive and air-improving garment of the present invention improves the breathability of the part where breathability is reversibly improved by sweating, so that it can eliminate stuffiness and stickiness and has excellent wearing comfort can get. At the same time, since the garment is mainly composed of a woven or knitted fabric that does not improve air permeability against moisture, there is no fear that the dimensions of the garment will change when sweating. Such clothes are suitable for inner clothing such as underwear, sports clothing such as sweaters, shirts, and trainers.

  In addition, the dyeing finishing process of a usual method may be given to the moisture-sensitive air-permeable improvement clothes of this invention. In addition, various processes that provide functions such as conventional water-repellent processing, brushed processing, ultraviolet shielding or antibacterial agents, deodorants, insect repellents, phosphorescent agents, retroreflective agents, and negative ion generators are additionally applied. Also good.

Next, although the Example and comparative example of this invention are explained in full detail, this invention is not limited by these. In addition, each measurement item in an Example was measured with the following method.
<Measurement of yarn length> After leaving the woven or knitted fabric in an atmosphere at a temperature of 20 ° C. and a humidity of 65% RH for 24 hours, a small piece of 30 cm × 30 cm is cut from the woven or knitted fabric so that the direction of the weft is the same as that of the woven or knitted fabric (N number = 5). Subsequently, one water-absorbing self-stretching yarn and one non-self-stretching yarn are taken out from each piece, and a load of 0.0088 mN / dtex (1 mg / de) is applied to the water-absorbing self-stretching yarn, which is an elastic yarn. A load of 1.76 mN / dtex (200 mg / de) is applied to the non-self-stretching yarn, which is a yarn, and the yarn length A (mm) of the water-absorbing self-stretching yarn and the yarn length B (mm) of the non-self-stretching yarn are measured. . Then, (average value of yarn length A) / (average value of yarn length B) is defined as A / B.
<Breathability> Breathability was measured according to JIS L 1096-1998, 6.27.1, Method A (Fragile Breathability Tester Method). Then, the air permeability is measured for each of dry time and wet time (n number = 5), and the air permeability change rate (%) is calculated by the following formula.
Air permeability change rate (%) = ((wet breathability when wet) − (breathability when dried)) / (breathability when dried) × 100

[Example 1]
Polyetherene terephthalate (49.8 parts by weight) as a hard segment and polyether ester (50.2 parts by weight of polyoxyethylene glycol having a number average molecular weight of 4000 as a soft segment) are melted at 230 ° C. and discharged from a predetermined spinneret. Extruded at 3.05 g / min. The polymer was drawn through two godet rolls at 705 m / min and further wound at 750 m / min (winding draft 1.06) to obtain a water-absorbing self-stretching yarn having elasticity of 44 dtex / 1 filament. The swelling rate of the water-absorbing self-stretching yarn in the fiber axis direction when wet was 10%, and the boiling water shrinkage rate was 8%.

  In addition, a normal polyethylene terephthalate multifilament yarn (84 dtex / 24 filament) having a boiling water shrinkage of 10% and a wet expansion rate of 1% or less was prepared as a non-self-stretching yarn.

Next, using a 28-gauge single circular knitting machine, the water-absorbing self-stretching yarn was drafted at a draft rate of 50% and fed to the knitting machine simultaneously with the non-self-stretching yarn to obtain 47 course / 2.54 cm. A circular knitted fabric with a tengu structure was knitted at a knitting density of 40 wales / 2.54 cm. Subsequently, this circular knitted fabric was processed by a conventional dyeing finishing method to obtain a knitted fabric having improved air permeability when wet. In the obtained knitted fabric, as schematically shown in FIG. 6, a composite loop of a circular knitted structure was formed by the water-absorbing self-stretching yarn and the non-self-stretching yarn, and A / B was 0.7. Further, at circle knit obtained, in the drying is a breathable 210cc / ^cm 2 / s, at the time of wet, breathable 380cc / ^cm 2 / s (change in air permeability 81%), breathable when wet is It was a big improvement.

  On the other hand, with a 28 gauge double circular knitting machine, 45 course / 2 using ordinary polyethylene terephthalate multifilament false twist crimped yarn (56 dtex / 72 filament) with an expansion rate of 1% or less when wet. After knitting a smooth knitted fabric with a knitting density of .54cm, 41 wale / 2.54cm, the fabric is processed by a conventional dyeing finishing method, and the knitted fabric has the same air permeability when wet (rate of change in air permeability) Was less than 5%). Then, the knitted fabric was cut and sewn to prepare a half sleeve shirt.

Subsequently, only the both side portions of the half sleeve were cut, and a knitted fabric having improved air permeability when wet as shown in FIG. 1 was sewn to the side portions to obtain a moisture-sensitive breathable half sleeve shirt. In the obtained moisture-sensitive breathable half sleeve shirt, the total area of the portions where the breathability was reversibly improved was 1050 cm ² , and the area ratio was 10% with respect to the total area of the clothes. When the tester ran and sweated while wearing the shirt with the improved moisture-sensitive air permeability, the side portions with much sweating were less stuffy and comfortable, and the dimensions of the shirt did not change.

[Comparative Example 1]
In Example 1, the tester wears a half sleeve shirt (normal polyethylene terephthalate multifilament false twisted crimped yarn (56 dtex / 72 filament) 100%) before cutting both sides and sweats. As the amount of sweat increased, the side stuffiness increased and was uncomfortable.

  ADVANTAGE OF THE INVENTION According to this invention, the moisture-sensitive air-permeability improvement clothes which perceive humidity, such as perspiration from skin, reversibly improve without changing the dimension of clothes are provided. Such clothing is suitable for sports clothing and inner clothing, and its industrial value is extremely large.

In the moisture-sensitive air-improving garment of the present invention, the case where the part where the air-permeability is reversibly improved by wetting is a side part is schematically shown. In the moisture-sensitive air-improving garment of the present invention, the case where the part where the air permeability is reversibly improved by wetting is a side body part is schematically shown. In the moisture-sensitive air-improving garment of the present invention, the case where the part where the air permeability is reversibly improved by wetting is the chest is schematically shown. In the moisture-sensitive air-improving garment of the present invention, the case where the portion where the air-permeability is reversibly improved by wetting is the back is schematically shown. In the moisture-sensitive air-improving garment of the present invention, the case where the part where the air permeability is reversibly improved by wetting is the shoulder is schematically shown. In the moisture-sensitive and air-permeable improved garment of the present invention, it is an example of a fabric constituting a portion where the air permeability is reversibly improved by wetting, and the water-absorbing self-stretching yarn and the non-self-stretching yarn form a composite loop of a circular knitted structure The yarn arrangement to be shown is schematically shown. (1) When dry, (2) When wet. The moisture-sensitive breathable garment of the present invention is an example of a fabric constituting a portion where breathability is reversibly improved by wetting. The water-absorbing self-stretching yarn and the non-self-stretching yarn are aligned to form a woven structure. FIG. 2 schematically shows a yarn arrangement constituting warps and wefts. (1) When dry, (2) When wet. The moisture-sensitive breathable garment of the present invention is an example of a fabric constituting a part where breathability is reversibly improved by wetting. A water-absorbing self-stretching yarn and a non-self-stretching yarn are arranged in a 1: 1 and round. The yarn arrangement | sequence which comprises a knitted fabric is shown typically. (1) When dry, (2) When wet. The moisture-sensitive breathable garment of the present invention is an example of a fabric that constitutes a portion where the breathability is reversibly improved by wetting. A water-absorbing self-stretching yarn and a non-self-stretching yarn are 1: 1 schematically shows an array of yarns that are arranged in 1 and constitute a woven fabric. (1) When dry, (2) When wet.

Explanation of symbols

1-1, 1-2, 1-3, 1-4, 1-5 Sites where air permeability is reversibly improved by wetting 2-1, 2-2, 4-1, 4-2, 6-1, 6-2,8-1,8-2 Water-absorbing self-stretching yarn 3-1,3-2,5-1,5-2,7-1,7-2,9-1,9-2 Non-self-stretching yarn

Claims (12)

It is a garment mainly composed of woven or knitted fabric that does not improve air permeability when wet. It has a part where air permeability is reversibly improved by wetting , and air permeability is reversibly improved by wetting. The portion to be formed is composed of a woven or knitted fabric composed of a water-absorbing self-stretching yarn and a non-self-stretching yarn, and the yarn length of the water-absorbing self-stretching yarn in the woven or knitting fabric in an atmosphere at a temperature of 20 ° C. and a humidity of 65% RH is (A) On the other hand, when the yarn length of the non-self-stretching yarn is (B), A / B is 0.9 or less .   The moisture-sensitive breathable improvement garment according to claim 1, wherein the portion where the breathability is reversibly improved by wetting is one portion or two or more portions selected from the side part, the side body part, the chest part, the back part, and the shoulder part. . 2. The moisture-sensitive and air-permeable improved garment according to claim 1, wherein the portion where the air permeability is reversibly improved by wetting comprises a knitted fabric in which a water-absorbing self-stretching yarn and a non-self-stretching yarn form a composite loop of a circular knitted structure. . The site where the breathability is reversibly improved by wetting comprises a woven fabric in which a water-absorbing self-stretching yarn and a non-self-stretching yarn are aligned to form a warp and / or a weft of a woven structure. Clothing that improves moisture and breathability. The part where the breathability is reversibly improved by wetting is from a knitted or knitted fabric in which water-absorbing self-stretching yarns and non-self-stretching yarns are each arranged as one or more alternately as constituent yarns of the woven or knitted fabric. The moisture-sensitive air-permeable improvement garment according to claim 1. 2. The moisture-sensitive and air-permeable improved garment according to claim 1, wherein the portion where the air permeability is reversibly improved by wetting is composed of a woven or knitted fabric including a water-absorbing self-stretching yarn and a non-self-stretching yarn as a composite yarn. The moisture-sensitive air-permeable property according to any one of claims 1 to 6, wherein the water-absorbing self-stretching yarn is a polyether ester fiber comprising a polyether ester elastomer having polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment. Improve clothing. The moisture-sensitive breathable garment according to any one of claims 1 to 7, wherein the non-self-stretching yarn is a polyester fiber. The moisture-sensitive air-permeable improvement garment according to any one of claims 1 to 8, wherein a rate of change in air-permeability is 30% or more when wet and when dry at a site where the air-permeability is reversibly improved. The garment or knitted fabric that does not improve air permeability against moisture is made of polyester fiber. 11. The moisture-sensitive and air-improving garment according to claim 1, wherein the garment is an inner garment. 11. The moisture-sensitive and air-improving garment according to claim 1, wherein the garment is a sports garment.

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