JP4180533B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
- Publication number
- JP4180533B2 JP4180533B2 JP2004047387A JP2004047387A JP4180533B2 JP 4180533 B2 JP4180533 B2 JP 4180533B2 JP 2004047387 A JP2004047387 A JP 2004047387A JP 2004047387 A JP2004047387 A JP 2004047387A JP 4180533 B2 JP4180533 B2 JP 4180533B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- product name
- manufactured
- oil
- amine oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003676 hair preparation Substances 0.000 title description 13
- 229920005989 resin Polymers 0.000 claims description 23
- 239000011347 resin Substances 0.000 claims description 23
- 150000001412 amines Chemical class 0.000 claims description 21
- 239000002537 cosmetic Substances 0.000 claims description 18
- -1 long-chain fatty acid acrylic ester Chemical class 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 6
- RJECHNNFRHZQKU-UHFFFAOYSA-N Oelsaeurecholesterylester Natural products C12CCC3(C)C(C(C)CCCC(C)C)CCC3C2CC=C2C1(C)CCC(OC(=O)CCCCCCCC=CCCCCCCCC)C2 RJECHNNFRHZQKU-UHFFFAOYSA-N 0.000 claims description 4
- RJECHNNFRHZQKU-RMUVNZEASA-N cholesteryl oleate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)C1 RJECHNNFRHZQKU-RMUVNZEASA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- ODOJGQVXHIPDLF-UHFFFAOYSA-N ethyl(oxido)azanium;2-methylprop-2-enoic acid Chemical compound CC[NH2+][O-].CC(=C)C(O)=O ODOJGQVXHIPDLF-UHFFFAOYSA-N 0.000 claims 1
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 14
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- 239000004166 Lanolin Substances 0.000 description 3
- CRJGESKKUOMBCT-VQTJNVASSA-N N-acetylsphinganine Chemical compound CCCCCCCCCCCCCCC[C@@H](O)[C@H](CO)NC(C)=O CRJGESKKUOMBCT-VQTJNVASSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
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- ZVEQCJWYRWKARO-UHFFFAOYSA-N ceramide Natural products CCCCCCCCCCCCCCC(O)C(=O)NC(CO)C(O)C=CCCC=C(C)CCCCCCCCC ZVEQCJWYRWKARO-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
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- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 description 3
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- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002270 gangliosides Chemical class 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 150000002339 glycosphingolipids Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 210000002569 neuron Anatomy 0.000 description 1
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- KZJWDPNRJALLNS-VJSFXXLFSA-N sitosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]1(C)CC2 KZJWDPNRJALLNS-VJSFXXLFSA-N 0.000 description 1
- 229950005143 sitosterol Drugs 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- WWUZIQQURGPMPG-KRWOKUGFSA-N sphingosine Chemical compound CCCCCCCCCCCCC\C=C\[C@@H](O)[C@@H](N)CO WWUZIQQURGPMPG-KRWOKUGFSA-N 0.000 description 1
- HCXVJBMSMIARIN-PHZDYDNGSA-N stigmasterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)/C=C/[C@@H](CC)C(C)C)[C@@]1(C)CC2 HCXVJBMSMIARIN-PHZDYDNGSA-N 0.000 description 1
- 229940032091 stigmasterol Drugs 0.000 description 1
- 235000016831 stigmasterol Nutrition 0.000 description 1
- BFDNMXAIBMJLBB-UHFFFAOYSA-N stigmasterol Natural products CCC(C=CC(C)C1CCCC2C3CC=C4CC(O)CCC4(C)C3CCC12C)C(C)C BFDNMXAIBMJLBB-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、毛髪化粧料に関するものであり、より詳しくは、べたつき感が少なく、毛髪になめらかさや艶を与え、セット性に優れた毛髪化粧料に関する。 The present invention relates to a hair cosmetic, and more particularly to a hair cosmetic that is less sticky, imparts smoothness and luster to hair, and is excellent in setting properties.
従来、毛髪のスタイルを整えるために毛髪化粧料として、ヘアージェル、ヘアークリーム、ヘアーフォーム、セットローション等が使用されており、これらの毛髪化粧料は一般的に毛髪をセットするために高分子化合物、シリコーン油、高分子シリコーン、エステル油、炭化水素油などの油分を可溶化、溶解又は乳化して配合されている。これらの毛髪化粧料は、様々なスタイルに合わせて、セット力や使用感（艶やまとまり）などの多様な機能を付与している。また、毛髪化粧料には、整髪力を付与する目的で、ワックスが配合されることがあるが、塗布部分のべたつきが著しく、またギラツキ等を生じることもあるため、各種エマルションとして用いることが多い。このような該組成物の例として、ワックスと油分と特定の乳化剤からなる構成（例えば、特許文献１、特許文献２参照。）が開示され、また、ワックスとシリコーンと特定の乳化剤とからなる構成（例えば、特許文献３参照。）が開示されている。しかしながら、前者の従来の毛髪化粧料では整髪力が不充分であり、後者のワックスの微細分散物を含有した毛髪化粧料においては、ワックスのべたつき感、なめらかさに関する改善がまだ不充分であった。また、固形または半固形の油分と水と界面活性物質を含有する水中油型乳化組成物（例えば、特許文献４参照。）が開示されているが、これらについても、ワックスのべたつき感、なめらかさに関する改善がまだ不充分であった。 Conventionally, hair gels, hair creams, hair foams, set lotions, and the like have been used as hair cosmetics to adjust the hair style, and these hair cosmetics are generally polymeric compounds for setting hair. Oils such as silicone oil, polymer silicone, ester oil and hydrocarbon oil are blended by solubilizing, dissolving or emulsifying. These hair cosmetics have various functions such as setting power and feeling of use (gloss and unity) according to various styles. In addition, the hair cosmetics may be mixed with wax for the purpose of imparting hair-styling power, but the application part is extremely sticky and may cause glare and the like, so it is often used as various emulsions. . As an example of such a composition, a composition comprising a wax, an oil component and a specific emulsifier is disclosed (for example, see Patent Document 1 and Patent Document 2), and a composition comprising a wax, silicone and a specific emulsifier. (For example, refer to Patent Document 3). However, the former conventional hair cosmetics have insufficient hair styling power, and the latter hair cosmetics containing a fine dispersion of waxes still have insufficient improvements in the stickiness and smoothness of the wax. . In addition, oil-in-water emulsion compositions containing a solid or semi-solid oil, water, and a surfactant (for example, see Patent Document 4) have been disclosed, but these also have a sticky feeling and smoothness of wax. There was still insufficient improvement regarding.
一方、アミンオキシド基含有樹脂（例えば、特許文献５、特許文献６、非特許文献１参照。）は、セット力や艶の付与、コンディショニング効果などの目的で開発された樹脂である。このアミンオキシド基含有樹脂を応用した例としては、アミンオキシド基含有樹脂とシリコーン化合物と組合せることによって、セット力に優れ、べたつきがなく、滑らかな感触と艶を与える毛髪化粧料（例えば、特許文献７参照。）、が開示されている。しかし、これらの方法により、アミンオキシド基含有樹脂とシリコーンを組み合わせた場合、高いコンディショニング性等を付与することは出来るが、艶やセット性という点においては限界があり、十分満足するレベルには至らなかった。 On the other hand, an amine oxide group-containing resin (see, for example, Patent Document 5, Patent Document 6, and Non-Patent Document 1) is a resin developed for the purpose of imparting setting power, gloss, conditioning effects, and the like. As an example of application of this amine oxide group-containing resin, a hair cosmetic (for example, patents) that combines a combination of an amine oxide group-containing resin and a silicone compound to give a smooth feel and gloss without stickiness. Reference 7)) is disclosed. However, when these methods are used in combination with an amine oxide group-containing resin and silicone, high conditioning properties and the like can be imparted, but there are limitations in terms of gloss and setability, and the level is sufficiently satisfactory. There wasn't.
したがって、本発明の目的は、べたつき感が少なく、毛髪になめらかさや艶を与え、セット性等の感触や機能に優れた毛髪化粧料を提供することにある。 Accordingly, an object of the present invention is to provide a hair cosmetic that has less stickiness, gives the hair smoothness and gloss, and is excellent in touch and function such as setability.
本発明者等は、本発明の目的達成するために鋭意研究した結果、アミンオキシド基含有樹脂とスフィンゴ脂質、セラミド、コレステロール類およびフィトステロール類の群から選ばれる一種以上を組合せて配合した毛髪化粧料によって上記課題が改善されることを見出し、本発明を完成した。即ち、本発明は、（Ａ）アミンオキシド基含有樹脂と、（Ｂ）スフィンゴ脂質、セラミド、コレステロール類およびフィトステロール類からなる群より選ばれる一種以上とを含有することを特徴とする毛髪化粧料である。 As a result of diligent research to achieve the object of the present invention, the present inventors have determined that hair cosmetics are formulated by combining an amine oxide group-containing resin and one or more selected from the group of sphingolipids, ceramides, cholesterols and phytosterols. As a result, the present invention has been completed. That is, the present invention is a hair cosmetic comprising (A) an amine oxide group-containing resin and (B) one or more selected from the group consisting of sphingolipids, ceramides, cholesterols and phytosterols. is there.
本発明の毛髪化粧料は、べたつき感が少なく、毛髪になめらかさや艶を与え、かつセット性などの使用時の感触や仕上りの機能に優れた毛髪化粧料を提供することができる。 The hair cosmetic composition of the present invention can provide a hair cosmetic composition that is less sticky, gives the hair smoothness and luster, and has excellent touch and finish functions such as setability.
以下、本発明の構成について詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明の（Ａ）成分であるアミンオキシド基含有樹脂は、長鎖脂肪酸アクリルエステルとメタクリル酸エチルアミンオキシドとアクリル酸及び／またはメタクリル酸を構成成分に有する共重合体であり、構造単位としてアミンオキシド基を含有したものである。具体的には、Ａｃｒｙｌａｔｅｓ／ＬａｕｒｙｌＡｃｒｙｌａｔｅ／ＳｔｅａｒｙｌＡｃｒｙｌａｔｅ／Ｅｔｈｌａｍｉｎｅ Ｏｘｉｄｅ Ｍｅｔｈａｃｒｙｌａｔｅ ｃｏｐｏｌｙｍｅｒ、Ａｃｒｙｌａｔｅｓ／ＳｔｅａｒｙｌＡｃｒｙｌａｔｅ／Ｅｔｈｌａｍｉｎｅ Ｏｘｉｄｅ Ｍｅｔｈａｃｒｙｌａｔｅ ｃｏｐｏｌｙｍｅｒ、Ａｃｒｙｌａｔｅｓ／ＬａｕｒｙｌＡｃｒｙｌａｔｅ／Ｅｔｈｌａｍｉｎｅ Ｏｘｉｄｅ Ｍｅｔｈａｃｒｙｌａｔｅ ｃｏｐｏｌｙｍｅｒ等が挙げられ、これらの中でも、Ａｃｒｙｌａｔｅｓ／ＳｔｅａｒｙｌＡｃｒｙｌａｔｅ／Ｅｔｈｌａｍｉｎｅ Ｏｘｉｄｅ Ｍｅｔｈａｃｒｙｌａｔｅ ｃｏｐｏｌｙｍｅｒが特に好適に使用される。これらのアミンオキシド基含有樹脂は、「Ｔｈｅ Ｃｏｓｍｅｔｉｃ Ｔｏｉｌｅｔｒｙ ａｎｄ Ｆｒａｇｒａｎｃｅ Ａｓｓｏｃｉａｔｉｏｎ発行のＩｎｔｅｒｎａｔｉｏｎａｌ Ｃｏｓｍｅｔｉｃ Ｉｎｇｒｅｄｉｅｎｔ Ｄｉｃｔｉｏｎａｒｙ ａｎｄ Ｈａｎｄｂｏｏｋ」に記載されており、また、これらのアミンオキシド基含有樹脂は市販されている。例えば、クラリアント（株）から販売されているＤｉａｆｏｒｍｅｒ Ｚ７１１、Ｄｉａｆｏｒｍｅｒ Ｚ７１２、Ｄｉａｆｏｒｍｅｒ Ｚ７３１、Ｄｉａｆｏｒｍｅｒ Ｚ７５１、三菱化学（株）から販売されているダイヤフォーマーＺ７１１、ダイヤフォーマーＺ７１２、ダイヤフォーマーＺ６３１、ダイヤフォーマーＺ７３２、ダイヤフォーマーＺ６５１、ダイヤフォーマーＺ７３１、ダイヤフォーマーＺ７５１等が挙げられる。 The amine oxide group-containing resin which is the component (A) of the present invention is a copolymer having, as structural units, a long-chain fatty acid acrylic ester, ethyl methacrylate amine oxide, acrylic acid and / or methacrylic acid as structural units. It contains a group. Specifically, Acrylates / LaurylAcrylate / StearylAcrylate / Ethlamine Oxide Methacrylate copolymer, Acrylates / StearylAcrylate / Ethlamine Oxide Methacrylate copolymer, Acrylates / LaurylAcrylate / Ethlamine Oxide Methacrylate copolymer and the like, and among these, Acrylates / StearylAcrylate / Ethlamine Oxide Methacrylate copolymer Is particularly preferably used. These amine oxide group-containing resins are described in “International Cosmetic Ingredient Dictionary and Handbook” published by The Cosmetic Toiletry and Fragrance Association, and these amine oxide group-containing resins are commercially available. For example, Diaformer Z711, Diaformer Z712, Diaformer Z731, Diaformer Z751, Diaformer Z711, Diaformer Z712, Diaformer Z631, which are sold by Clariant Co., Ltd. Mar Z732, Diamond former Z651, Diamond former Z731, Diamond former Z751, etc. are mentioned.
本発明における上記アミンオキシド基含有樹脂は、それぞれ単独でまたは２種以上を混合して使用する事ができ、その配合量としては、毛髪化粧料の全量に対して０．１〜１０質量％（以下、％と略す）が好ましく、更に好ましくは０．５〜５％である。０．１％未満ではセット性およびその保持力に限界があり、１０％を超えると充填容器に目詰まりが生じたりする場合がある。 The said amine oxide group containing resin in this invention can be used individually or in mixture of 2 or more types, respectively, As the compounding quantity, it is 0.1-10 mass% with respect to the whole quantity of hair cosmetics ( Hereinafter, it is abbreviated as%), and more preferably 0.5 to 5%. If it is less than 0.1%, the setability and its holding power are limited, and if it exceeds 10%, the filling container may be clogged.
本発明の（Ｂ）成分は、スフィンゴ脂質、セラミド、コレステロール類およびフィトステロール類からなる群より選ばれる一種以上である。スフィンゴ脂質としては、スフィンゴミエリン等のスフィンゴリン脂質、セレブロシド、ガングリオシド等のスフィンゴ糖脂質が挙げられ、また、トウモロコシ、コムギ胚芽、米フスマ、ほうれん草、スエヒロタケ、マツヨイグサなどの植物中から抽出される各種植物性スフィンゴ脂質が挙げられる。 The component (B) of the present invention is at least one selected from the group consisting of sphingolipids, ceramides, cholesterols and phytosterols. Examples of sphingolipids include sphingophospholipids such as sphingomyelin, glycosphingolipids such as cerebroside and ganglioside, and various plants extracted from plants such as corn, wheat germ, rice bran, spinach, Shirohirotake and evening primrose. Sex sphingolipids.
セラミドは、スフィンゴシンに脂肪酸がアミド結合したものであり、セラミド１、セラミド２、セラミド３、セラミド４、セラミド５、セラミド６が天然セラミドとして挙げられ、また、化学合成により製造される擬似セラミド等が挙げられる。 Ceramide is a sphingosine in which a fatty acid is amide-bonded. Ceramide 1, ceramide 2, ceramide 3, ceramide 4, ceramide 5, ceramide 6 are listed as natural ceramides, and pseudo-ceramides produced by chemical synthesis, etc. Can be mentioned.
コレステロール類としては、コレステロールおよびコレステロール誘導体が挙げられる。コレステロールは、遊離または脂肪酸エステルとして動物の皮脂、神経細胞、副腎腺、卵黄などの組織に多く存在している物質であり、工業的にはラノリンからケン化分解したり、魚肝油や軟体動物の内臓から抽出される。コレステロール誘導体としては、水素添加したジヒドロコレステロール、低級または高級脂肪酸とのエステル体が挙げられ、例えば、ヒドロキシステアリン酸コレステリル、オレイン酸コレステリル、イソステアリン酸コレステリル、ラノリン脂肪酸コレステリル、マカデミアナッツ油脂肪酸コレステリル、ノナン酸コレステリル、ステアリン酸コレステリル、酪酸コレステリルなどが市販されている。 Cholesterols include cholesterol and cholesterol derivatives. Cholesterol is a substance that is abundantly present in tissues such as sebum, nerve cells, adrenal glands, and egg yolk as free or fatty acid esters. Industrially, it is saponified and decomposed from lanolin, and fish liver oil and mollusc viscera. Extracted from Cholesterol derivatives include hydrogenated dihydrocholesterol, esters with lower or higher fatty acids, such as cholesteryl hydroxystearate, cholesteryl oleate, cholesteryl isostearate, lanolin fatty acid cholesteryl, macadamia nut oil fatty acid cholesteryl, cholesteryl nonanoate In addition, cholesteryl stearate, cholesteryl butyrate, and the like are commercially available.
フィトステロール類としては、β−シトステロール、スチグマステロール、カンペステロール、およびこれらの水素添加した化合物や低級または高級脂肪酸とのエステル体が挙げられ、例えば、フィトステロール、オレイン酸フィトステロール、ノナン酸フィトステロール、ステアリン酸フィトステロール、酪酸フィトステロールなどが市販されている。 Phytosterols include β-sitosterol, stigmasterol, campesterol, and their hydrogenated compounds and esters with lower or higher fatty acids, such as phytosterol, phytosterol oleate, phytosterol nonanoate, stearic acid. Phytosterol and phytosterol butyrate are commercially available.
これらの（Ｂ）成分の中でも、コレステロールおよびその誘導体、フィトステロールおよびその誘導体が、経済性と効果の面で特に好ましい。また、これら（Ｂ）成分はそれぞれ単独でまたは２種以上を混合して使用する事ができ、その配合量としては、毛髪化粧料の全量に対して０．０１〜１０％が好ましく、更に好ましくは０．１〜５％である。０．０１％未満ではなめらかさやツヤを向上させる効果に劣る場合があり、１０％を超えるとのびが悪くなり使用感に劣る場合があり好ましくない。 Among these (B) components, cholesterol and derivatives thereof, phytosterol and derivatives thereof are particularly preferable in terms of economy and effect. These components (B) can be used alone or in admixture of two or more, and the blending amount is preferably 0.01 to 10%, more preferably based on the total amount of the hair cosmetic. Is 0.1 to 5%. If it is less than 0.01%, the effect of improving the smoothness and gloss may be inferior, and if it exceeds 10%, the spread becomes worse and the feeling in use may be inferior.
また、本発明の毛髪化粧料には、上記スフィンゴ脂質、セラミド、コレステロール類およびフィトステロール類を溶解するために、液状油分を配合することもできる。液状油分として具体的には、流動パラフィン、スクワラン等の液状炭化水素、オリーブ油、マカデミアナッツ油、ホホバ油、液状ラノリン等の液状動植物抽出油、シリコーン油、パーフルオロ化油、脂肪酸および高級アルコールを反応させて得られる液状エステル油等が挙げられる。 Moreover, in order to dissolve the sphingolipid, ceramide, cholesterols and phytosterols, the hair cosmetic composition of the present invention may be mixed with a liquid oil. Specifically, liquid oil such as liquid paraffin and squalane, olive oil, macadamia nut oil, jojoba oil, liquid lanolin and other liquid animal and plant extract oil, silicone oil, perfluorinated oil, fatty acid and higher alcohol are reacted as liquid oil. And liquid ester oils obtained.
本発明の毛髪化粧料には、上記必須成分の他に、必要により、一般に化粧料に用いられている成分、例えば、他の界面活性剤、高分子化合物、油脂類、粉体、シリコーン類、ｐＨ調整剤、保湿剤、紫外線吸収剤、紫外線分散剤、色素、液状アルコール、植物エキス、殺菌剤、防腐剤、酸化防止剤、キレート剤、薬剤、香料等を、本発明の効果を損なわない範囲で用いることができる。 In addition to the above essential components, the hair cosmetic of the present invention, if necessary, components generally used in cosmetics, for example, other surfactants, polymer compounds, fats and oils, powders, silicones, pH adjusting agent, moisturizing agent, ultraviolet absorber, ultraviolet dispersing agent, pigment, liquid alcohol, plant extract, bactericidal agent, preservative, antioxidant, chelating agent, drug, perfume, etc., within the range not impairing the effect of the present invention Can be used.
本発明の毛髪化粧料の剤型は、特に限定されることはなく、通常毛髪化粧料として使用される液状、乳液状、クリーム状、油状、ゲル状、エアゾール、固形製剤、スティック製剤の剤型とすることができ、具体的には、ヘアローション、ヘアリキッド、ヘアトニック、ヘアクリーム、ヘアオイル、ヘアジェル、ヘアミスト、カラークレヨン、シャンプー、
ヘアリンス、ヘアトリートメント、ヘアーフォーム、ヘアスプレー、ヘアワックスなどがあげられる。
The dosage form of the hair cosmetic of the present invention is not particularly limited, and the dosage form of liquid, emulsion, cream, oil, gel, aerosol, solid preparation, and stick preparation that are usually used as hair cosmetics. Specifically, hair lotion, hair liquid, hair tonic, hair cream, hair oil, hair gel, hair mist, color crayon, shampoo,
Hair rinse, hair treatment, hair foam, hair spray, hair wax and so on.
次に、本発明を実施例を以って詳細に説明するが、本発明はこれにより限定されるものではない。 EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited by this.
実施例に記載のセット性、べたつきのなさ、なめらかさ、および、艶に関する試験法について以下に示す。また、以下の表に示す毛髪化粧料の組成物の配合量は、それぞれ質量％で示す。 Test methods relating to setability, non-stickiness, smoothness, and gloss described in Examples are shown below. Moreover, the compounding quantity of the composition of hair cosmetics shown in the following table | surfaces is each shown by the mass%.
１０名の専門パネルを用いて、実施例および比較例で示した毛髪化粧料を使用して、セット性、べたつきのなさ、なめらかさ、艶の項目について官能評価した。尚、評価基準は以下の通りである。
◎：非常に良好〔良いと答えた被験者が８名以上〕
○：良好〔良いと答えた被験者が６名以上８名未満〕
△：やや悪い〔良いと答えた被験者が４名以上６名未満〕
×：悪い〔良いと答えた被験者が４名未満〕
Using the hair cosmetics shown in the examples and comparative examples, sensory evaluation was performed on the items of setability, non-stickiness, smoothness, and gloss using 10 professional panels. The evaluation criteria are as follows.
◎: Very good [more than 8 subjects answered good]
○: Good [6 or more and less than 8 subjects answered that it was good]
△: Slightly bad [4 or more and less than 6 subjects answered good]
×: Bad [less than 4 subjects answered good]
実施例１〜８及び比較例１〜４
表１に記載の配合組成よりなる毛髪化粧料を常法により調製し、前記各試験実施した。その結果を表１に併せて示す。
Examples 1-8 and Comparative Examples 1-4
A hair cosmetic composition having the composition shown in Table 1 was prepared by a conventional method, and the above tests were conducted. The results are also shown in Table 1.
表１より明らかなように、本発明の成分を用いた実施例１〜８はいずれも優れた性能を示していた。一方、比較例１〜４では、セット力、セット保持力、官能評価（べたつきのなさ、なめらかさ、艶）のいずれかの点で劣っており、本発明の目的を達成できなかった
。
As apparent from Table 1, Examples 1 to 8 using the components of the present invention all showed excellent performance. On the other hand, Comparative Examples 1 to 4 were inferior in any of setting power, set holding power, and sensory evaluation (no stickiness, smoothness, gloss), and the object of the present invention could not be achieved.
以下、本発明の毛髪化粧料のその他の処方例を実施例として挙げる。なお、これらの実施例の毛髪化粧料についても、セット力、セット保持力、官能評価（べたつきのなさ、なめらかさ、艶）に関する試験を検討したところ、いずれの実施例においても、優れた特性を有しており良好であった。 Hereinafter, other formulation examples of the hair cosmetic composition of the present invention will be given as examples. In addition, for the hair cosmetics of these examples, examinations on setting power, set holding power, and sensory evaluation (non-stickiness, smoothness, gloss) were conducted. It had and was good.
実施例９（スタイリングフォーム）
配合量（％）
＜原液＞
（１）アミンオキシド基含有樹脂 ２．０
（商品名：ダイヤフォーマーＺ７３２、三菱化学社製）
（２）オレイン酸コレステリル ０．５
（商品名：ＹＯＦＣＯ ＬＣ−ＣＯ、吉川精油社製）
（３）ポリオキシエチレン変性シリコーン ０．５
（商品名：ＫＦ−６０１１、信越化学工業社製）
（４）９５度エタノール １５．０
（５）塩化ステアリルトリメチルアンモニウム ０．１
（６）セトステアリルアルコール ０．２
（７）ＰＯＥ（６０）硬化ヒマシ油 ０．３
（８）モノオレイン酸ＰＯＥ（２０）ソルビタン ０．３
（９）ヤシ油脂肪酸ジエタノールアミド ０．２
（１０）メチルパラベン ０．１
（１１）シルク抽出液 ０．５
（１２）香料 ０．１
（１３）精製水 残 部
＜ガス充填＞
原液 ９０．０
噴射剤 液化石油ガス（０．４ＭＰａ，２５℃） ８．０
噴射剤 ジメチルエーテル ２．０
Example 9 (styling foam)
Compounding amount (%)
<Undiluted solution>
(1) Amine oxide group-containing resin 2.0
(Product name: Diaformer Z732, manufactured by Mitsubishi Chemical Corporation)
(2) Cholesteryl oleate 0.5
(Product name: YOFCO LC-CO, manufactured by Yoshikawa Seiko)
(3) Polyoxyethylene-modified silicone 0.5
(Product name: KF-6011, manufactured by Shin-Etsu Chemical Co., Ltd.)
(4) 95 degree ethanol 15.0
(5) Stearyltrimethylammonium chloride 0.1
(6) Cetostearyl alcohol 0.2
(7) POE (60) hydrogenated castor oil 0.3
(8) Monooleic acid POE (20) sorbitan 0.3
(9) Palm oil fatty acid diethanolamide 0.2
(10) Methylparaben 0.1
(11) Silk extract 0.5
(12) Fragrance 0.1
(13) Purified water balance <Gas filling>
Stock solution 90.0
Propellant Liquefied petroleum gas (0.4 MPa, 25 ° C.) 8.0
Propellant Dimethyl ether 2.0
（製法）（２）、（３）および（５）〜（１０）を（４）に均一に混合し、次いで（１２）、（１３）、（１１）、（１）の順序で投入して原液を調製した。ついで原液と噴射剤をエアゾール耐圧容器に充填しスタイリングフォームを得た。 (Manufacturing method) (2), (3) and (5) to (10) are uniformly mixed in (4), and then charged in the order of (12), (13), (11), (1) Stock solutions were prepared. The stock solution and propellant were then filled into an aerosol pressure-resistant container to obtain a styling foam.
実施例１０（ミストスプレー）
配合量（％）
＜原液＞
（１）アミンオキシド基含有樹脂 ４．０
（商品名：ダイヤフォーマーＺ７３２、三菱化学社製）
（２）オレイン酸ジヒドロコレステリル ０．５
（商品名：ＹＯＦＣＯ ＬＣ−ＤＯ、吉川精油社製）
（３）両性イオン性樹脂 ２．０
（商品名：ユカフォーマーＡＭ７５ＲＦＮ、三菱化学社製）
（４）エタノール ２０．０
（５）ＰＯＥ（２５）ステアリルエーテル ０．５
（６）ヤシ油脂肪酸ジエタノールアミド ０．５
（７）ジプロピレングリコール ３．０
（８）精製水 残 部
＜ガス充填＞
原液 ６０．０
噴射剤 液化石油ガス（０．３ＭＰａ，２５℃） ４０．０
Example 10 (mist spray)
Compounding amount (%)
<Undiluted solution>
(1) Amine oxide group-containing resin 4.0
(Product name: Diaformer Z732, manufactured by Mitsubishi Chemical Corporation)
(2) Dihydrocholesteryl oleate 0.5
(Product name: YOFCO LC-DO, manufactured by Yoshikawa Seiko)
(3) Zwitterionic resin 2.0
(Product name: Yuka Former AM75RFN, manufactured by Mitsubishi Chemical Corporation)
(4) Ethanol 20.0
(5) POE (25) stearyl ether 0.5
(6) Palm oil fatty acid diethanolamide 0.5
(7) Dipropylene glycol 3.0
(8) Purified water balance <Gas filling>
Stock solution 60.0
Propellant Liquefied petroleum gas (0.3 MPa, 25 ° C.) 40.0
（製法）（１）〜（８）を均一に混合溶解した後、エアゾール耐圧容器に原液および噴射剤を充填し、ミストスプレーを得た。 (Production method) After uniformly mixing and dissolving (1) to (8), an aerosol pressure-resistant container was filled with a stock solution and a propellant to obtain a mist spray.
実施例１１（セットローション）
配合量（％）
（１）アミンオキシド基含有樹脂 ４．０
（商品名：ダイヤフォーマーＺ７３２、三菱化学社製）
（２）マカデミアナッツ油フィトステリル ０．３
（商品名：ＹＯＦＣＯ ＭＡＳ、日本精化社製）
（３）ジプロピレングリコール ０．３
（４）ポリオキシエチレン変性シリコーン ０．３
（商品名：ＫＦ−６０１１、信越化学工業社製）
（５）ポリオキシエチレン（６０）硬化ヒマシ油 ０．１
（６）エタノール ５５．０
（７）真珠タンパク抽出液 ０．５
（８）パラメトキシケイ皮酸オクチル ０．０２
（９）香料 ０．０５
（１０）精製水 残 部
Example 11 (Set Lotion)
Compounding amount (%)
(1) Amine oxide group-containing resin 4.0
(Product name: Diaformer Z732, manufactured by Mitsubishi Chemical Corporation)
(2) Macadamia nut oil phytosteryl 0.3
(Product name: YOFCO MAS, manufactured by Nippon Seika Co., Ltd.)
(3) Dipropylene glycol 0.3
(4) Polyoxyethylene-modified silicone 0.3
(Product name: KF-6011, manufactured by Shin-Etsu Chemical Co., Ltd.)
(5) Polyoxyethylene (60) hydrogenated castor oil 0.1
(6) Ethanol 55.0
(7) Pearl protein extract 0.5
(8) Octyl paramethoxycinnamate 0.02
(9) Fragrance 0.05
(10) Purified water balance
（製法）（１）〜（６）、および（９）を均一に混合溶解し、ついで（１０）、（７）、（８）の順に成分を混合し、均一に溶解してセットローションを得た。 (Manufacturing method) (1) to (6) and (9) are uniformly mixed and dissolved, then the components are mixed in the order of (10), (7) and (8), and uniformly dissolved to obtain a set lotion. It was.
実施例１２（ヘアスプレー）
配合量（％）
＜原液＞
（１）アミンオキシド基含有樹脂 ２．０
（商品名：ダイヤフォーマーＺ７３２、三菱化学社製）
（２）アミンオキシド基含有樹脂 ０．５
（商品名：Ｄｉａｆｏｒｍｅｒ Ｚ７３１、クラリアント社製）
（３）コレステロール ０．２
（商品名：コレステリン、日本精化社製）
（４）メチルフェニルポリシロキサン ０．１
（商品名：ＳＨ５５６、東レ・ダウコーニング・シリコーン社製）
（５）加水分解コムギタンパク／ＰＶＰクロスポリマー ０．３
（６）香料 ０．０５
（８）エタノール 残 部
＜ガス充填＞
原液 ５０．０
噴射剤 ジメチルエーテル ５０．０
Example 12 (hair spray)
Compounding amount (%)
<Undiluted solution>
(1) Amine oxide group-containing resin 2.0
(Product name: Diaformer Z732, manufactured by Mitsubishi Chemical Corporation)
(2) Amine oxide group-containing resin 0.5
(Product name: Diaformer Z731, manufactured by Clariant)
(3) Cholesterol 0.2
(Product name: cholesterol, manufactured by Nippon Seika Co., Ltd.)
(4) Methylphenylpolysiloxane 0.1
(Product name: SH556, manufactured by Toray Dow Corning Silicone)
(5) Hydrolyzed wheat protein / PVP crosspolymer 0.3
(6) Fragrance 0.05
(8) Ethanol balance
<Gas filling>
Stock solution 50.0
Propellant Dimethyl ether 50.0
（製法）（１）〜（８）を均一に混合溶解した後、エアゾール耐圧容器に原液および噴射剤を充填し、ヘアスプレーを得た。 (Production method) After uniformly mixing and dissolving (1) to (8), an aerosol pressure-resistant container was filled with a stock solution and a propellant to obtain a hair spray.
実施例１３（ヘアクリーム）
配合量（％）
（１）アミンオキシド基含有樹脂 ２．０
（商品名：ダイヤフォーマーＺ７３２、三菱化学社製）
（２）アミンオキシド基含有樹脂 ０．５
（商品名：Ｄｉａｆｏｒｍｅｒ Ｚ７３１、クラリアント社製）
（３）コレステロール ０．５
（商品名：コレステリン、日本精化社製）
（４）セラミド ０．２
（商品名：セラミド３、デグサ社製）
（５）コメヌカロウ ３．０
（６）流動パラフィン ２０．０
（７）スクワラン １０．０
（８）ＰＯＥ（６０）セチルエーテル ２．５
（９）ジメチルポリシロキサン（１００ｃｓ） ０．５
（１０）ステアリン酸 １．０
（１１）エデト酸二ナトリウム ０．０５
（１２）パラベン ０．２
（１３）香料 ０．０５
（１４）精製水 残 部
Example 13 (Hair Cream)
Compounding amount (%)
(1) Amine oxide group-containing resin 2.0
(Product name: Diaformer Z732, manufactured by Mitsubishi Chemical Corporation)
(2) Amine oxide group-containing resin 0.5
(Product name: Diaformer Z731, manufactured by Clariant)
(3) Cholesterol 0.5
(Product name: cholesterol, manufactured by Nippon Seika Co., Ltd.)
(4) Ceramide 0.2
(Product name: Ceramide 3, manufactured by Degussa)
(5) Rice bran 3.0
(6) Liquid paraffin 20.0
(7) Squalane 10.0
(8) POE (60) cetyl ether 2.5
(9) Dimethylpolysiloxane (100 cs) 0.5
(10) Stearic acid 1.0
(11) Edetate disodium 0.05
(12) Paraben 0.2
(13) Fragrance 0.05
(14) Purified water balance
（製法）（５）〜（１０）を８０℃にて均一に混合溶解し、ついで（３）、（４）、（１１）〜（１２）および（１４）を８０℃にて混合溶解したものを投入して乳化する。ホモミキサーを用いて分散後、次いで冷却を行い、６０℃で（１３）を入れ、３０℃で（１）〜（２）を入れ、混合分散し、室温まで冷却してヘアクリームを得た。 (Production method) (5) to (10) are uniformly mixed and dissolved at 80 ° C., and then (3), (4), (11) to (12) and (14) are mixed and dissolved at 80 ° C. To emulsify. After dispersing using a homomixer, cooling was then performed, (13) was added at 60 ° C., (1) to (2) were added at 30 ° C., mixed and dispersed, and cooled to room temperature to obtain a hair cream.
実施例１４（ヘアワックス）
配合量（％）
（１）アミンオキシド基含有樹脂 １．０
（商品名：ダイヤフォーマーＺ７３２、三菱化学社製）
（２）アミンオキシド基含有樹脂 １．０
（商品名：Ｄｉａｆｏｒｍｅｒ Ｚ７３１、クラリアント社製）
（３）フィロステロール ０．５
（商品名：フィトステロール、タマ生化学社製）
（４）マカデミアナッツ油フィトステリル ３．０
（商品名：ＹＯＦＣＯ ＭＡＳ、日本精化社製）
（５）流動パラフィン ５．０
（６）ポリオキシプロピレン（３０）ブチルエーテル １０．０
（７）セチルアルコール ５．０
（８）ステアリン酸モノグリセリド ２．５
（９）ジメチルポリシロキサン（１００ｃｓ） ０．５
（１０）ステアリン酸 ５．０
（１１）エデト酸二ナトリウム ０．０５
（１２）パラベン ０．２
（１３）トリエタノールアミン ０．５
（１４）香料 ０．２
（１５）精製水 残 部
Example 14 (hair wax)
Compounding amount (%)
(1) Amine oxide group-containing resin 1.0
(Product name: Diaformer Z732, manufactured by Mitsubishi Chemical Corporation)
(2) Amine oxide group-containing resin 1.0
(Product name: Diaformer Z731, manufactured by Clariant)
(3) Philosterol 0.5
(Product name: Phytosterol, manufactured by Tama Seikagaku)
(4) Macadamia nut oil phytosteryl 3.0
(Product name: YOFCO MAS, manufactured by Nippon Seika Co., Ltd.)
(5) Liquid paraffin 5.0
(6) Polyoxypropylene (30) Butyl ether 10.0
(7) Cetyl alcohol 5.0
(8) Stearic acid monoglyceride 2.5
(9) Dimethylpolysiloxane (100 cs) 0.5
(10) Stearic acid 5.0
(11) Edetate disodium 0.05
(12) Paraben 0.2
(13) Triethanolamine 0.5
(14) Fragrance 0.2
(15) Balance of purified water
（製法）（３）〜（１０）を８０℃にて均一に混合溶解し、（１５）に（１１）〜（１３）を８０℃にて混合溶解したものを投入して乳化する。ホモミキサーを用いて分散後、次いで冷却を行い、６０℃で（１４）を入れ、３０℃で（１）〜（２）を入れ、混合分散し、室温まで冷却してヘアワックスを得た。 (Production method) (3) to (10) are uniformly mixed and dissolved at 80 ° C., and (15) is mixed and dissolved at (11) to (13) at 80 ° C. to emulsify. After dispersion using a homomixer, cooling was then performed, (14) was added at 60 ° C., (1) to (2) were added at 30 ° C., mixed and dispersed, and cooled to room temperature to obtain a hair wax.
実施例１５（ヘアジェル）
配合量（％）
（１）アミンオキシド基含有樹脂 ２．０
（商品名：ダイヤフォーマーＺ７３２、三菱化学社製）
（２）フィロステロール ０．２
（商品名：フィトステロール、タマ生化学社製）
（３）オレイン酸コレステリル ０．２
（商品名：ＹＯＦＣＯ ＬＣ−ＣＯ、吉川精油社製）
（４）カルボキシビニルポリマー ０．６
（商品名：カーボポール９４０、
Ｂ．Ｆ．ＧＯＯＤＲＩＣＨ社製）
（５）エタノール ２０．０
（６）流動パラフィン ３．０
（７）ジメチルポリシロキサン（１００ｃｓ） ２．０
（８）イソステアリン酸イソプロピル ２．０
（９）トリエタノールアミン ０．５
（１０）ＰＯＥ（６０）硬化ヒマシ油 ０．５
（１１）エデト酸二ナトリウム ０．０５
（１２）パラベン ０．１
（１３）香料 ０．１
（１４）精製水 残 部
Example 15 (hair gel)
Compounding amount (%)
(1) Amine oxide group-containing resin 2.0
(Product name: Diaformer Z732, manufactured by Mitsubishi Chemical Corporation)
(2) Filosterol 0.2
(Product name: Phytosterol, manufactured by Tama Seikagaku)
(3) Cholesteryl oleate 0.2
(Product name: YOFCO LC-CO, manufactured by Yoshikawa Seiko)
(4) Carboxyvinyl polymer 0.6
(Product name: Carbopol 940,
B. F. GOODRICH)
(5) Ethanol 20.0
(6) Liquid paraffin 3.0
(7) Dimethylpolysiloxane (100 cs) 2.0
(8) Isopropyl isostearate 2.0
(9) Triethanolamine 0.5
(10) POE (60) hydrogenated castor oil 0.5
(11) Edetate disodium 0.05
(12) Paraben 0.1
(13) Fragrance 0.1
(14) Purified water balance
（製法）（４）、（１１）および（１２）を（１４）に入れて均一に混合したものに、（１）、（２）、（３）、（５）〜（１０）および（１３）を混合したものを添加して、ホモミキサーを用いて混合分散し、ヘアジェルを得た。
(Manufacturing method) (1), (2), (3), (5) to (10) and (13) are obtained by uniformly mixing (4), (11) and (12) in (14). ) Was added and mixed and dispersed using a homomixer to obtain a hair gel.
尚、上記各処方にて用いた香料は下記のものである。
本発明により、べたつき感が少なく、毛髪になめらかさや艶を与え、かつセット性などの使用時の感触や仕上りの機能に優れた毛髪化粧料を提供することができる。 According to the present invention, it is possible to provide a hair cosmetic that has little stickiness, gives the hair smoothness and gloss, and is excellent in touch and finish functions such as setability.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004047387A JP4180533B2 (en) | 2004-02-24 | 2004-02-24 | Hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| JP2004047387A JP4180533B2 (en) | 2004-02-24 | 2004-02-24 | Hair cosmetics |
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| JP2005239556A JP2005239556A (en) | 2005-09-08 |
| JP4180533B2 true JP4180533B2 (en) | 2008-11-12 |
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| JP2004047387A Expired - Lifetime JP4180533B2 (en) | 2004-02-24 | 2004-02-24 | Hair cosmetics |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5110797B2 (en) * | 2006-02-22 | 2012-12-26 | 花王株式会社 | Hair cosmetics |
| JP5502290B2 (en) * | 2008-06-23 | 2014-05-28 | 花王株式会社 | Hair cosmetics |
| JP5138478B2 (en) * | 2008-06-27 | 2013-02-06 | クラシエホームプロダクツ株式会社 | Hair cosmetics |
| JP5138477B2 (en) * | 2008-06-27 | 2013-02-06 | クラシエホームプロダクツ株式会社 | Hair cosmetics |
| US20100247474A1 (en) | 2009-03-25 | 2010-09-30 | Shin-Etsu Chemical Co., Ltd. | Cosmetic hair preparation |
| JP2011219367A (en) * | 2010-04-02 | 2011-11-04 | Mitsubishi Chemicals Corp | Cosmetic composition |
| JP6353939B1 (en) * | 2017-02-15 | 2018-07-04 | 横関油脂工業株式会社 | Oily composition, process for producing the same, oily base and external preparation for skin |
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2004
- 2004-02-24 JP JP2004047387A patent/JP4180533B2/en not_active Expired - Lifetime
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| JP2005239556A (en) | 2005-09-08 |
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