JP4179306B2 - Curable fluorine-containing polymer, curable resin composition and antireflection film using the same - Google Patents

Description

  The present invention relates to a novel curable fluorine-containing polymer, a curable resin composition using the same, and a cured product and a cured film obtained by curing the curable fluorine-containing polymer, and further, an antireflection film using the cured film and the same The present invention also relates to an antireflective article that has been subjected to anti-reflection treatment.

  Along with the development of multimedia, it is becoming increasingly important to improve the visibility of various display devices (because of less reflection when viewed from an angle, also called “visibility”). Even in a large display device, it is required to make it easier to see, and this characteristic is a technical problem.

  Conventionally, in order to improve the visibility of a display device, an antireflection film made of a low refractive index material is coated on the substrate of the display device. As a method of forming the antireflection film, for example, a method of forming a thin film of a fluorine compound by vapor deposition is known. However, in the vapor deposition method, it is difficult to form a film on a large-screen substrate, and a vacuum apparatus is required, which increases the cost.

  Under such circumstances, a method of forming an antireflection film by preparing a liquid composition in which a fluorine-containing polymer having a low refractive index is dissolved in an organic solvent and applying it to the surface of a substrate has been studied (for example, Patent Document 1).

  However, in the method of applying the fluoropolymer solution, since the coating film hardness is insufficient, the coating film is scratched or peeled off due to wear, and the appearance of the display screen is impaired.

  Thus, in addition to the low refractive index fluorine-containing polymer, after applying a composition in which a photocurable acrylic monomer such as a fluorine-containing acrylic monomer and a fluorine-containing polyfunctional acrylic compound is mixed, an acrylic monomer is applied. It has been studied to photocure the polymer (Patent Document 2, Patent Document 3, Patent Document 4, etc.).

  However, these are still insufficient in terms of hardness because the fluoropolymer itself, which is the main component, is uncrosslinked. In order to further improve the hardness, the amount of the acrylic monomer or polyfunctional acrylic compound may be increased. However, if this is done, the refractive index of the cured coating will be increased, and the intended antireflection effect will be reduced. Moreover, in this method, unreacted acrylic monomers and polyfunctional acrylic compounds are likely to remain in the coating film, which deteriorates the physical properties of the coated film after curing.

  It has also been studied to apply a photopolymerizable functional group introduced into the side chain of a fluoropolymer with a mixture of an acrylic monomer or polyfunctional acrylic compound and photo-cured (patent) Document 5, Patent Document 6). However, the fluorine-containing polymers described in these documents themselves have a high refractive index, so that they are not sufficient for the performance of an antireflection film, and the higher the number of cured parts of the fluorine-containing polymer, the higher the hardness. Since the refractive index is increased, the antireflection effect is further reduced.

Japanese Patent Application Laid-Open No. 6-1115023 JP-A-7-126552 Japanese Unexamined Patent Publication No. 7-188588 JP-A-8-48935 Japanese Patent No. 2527186 Japanese Patent No. 2543903

  An object of the present invention is to provide a curable fluorine-containing polymer that can achieve high hardness in a polymer by photocuring while maintaining a low refractive index.

  It is another object of the present invention to provide an antireflection film having improved scratch resistance and wear resistance while maintaining an antireflection effect, and an antireflection article coated with such an antireflection film.

  As a result of intensive studies to achieve the above object, the present inventors have found a novel curable fluorine-containing polymer having an ethylenic carbon-carbon double bond in the side chain, and when these are used, low refractive index properties are obtained. It was found that a cured product having a high hardness can be obtained without deteriorating.

  Furthermore, it has been found that a cured film of a specific fluorine-containing polymer having a carbon-carbon unsaturated bond at the side chain terminal is useful as an antireflection film having both low reflection and high hardness.

  Based on this knowledge, the present inventors have completed the following present invention.

  The first of the present invention relates to a curable fluorine-containing polymer having an ethylenic carbon-carbon double bond in the side chain.

  The curable fluorine-containing polymer of the present invention has the formula (1):

[In the formula, the structural unit M represents the formula (M):

Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf is a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having an ether bond having 2 to 100 carbon atoms; Y ¹ (Y ¹ is a carbon atom having 2 to 2 carbon atoms having an ethylenic carbon-carbon double bond at the terminal; An organic group in which 1 to 3 monovalent organic groups of 10 are bonded; a is an integer of 0 to 3; b and c are the same or different and 0 or 1) The structural unit derived from the body, the structural unit A is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M)], and the structural unit M is 0.1 to 100 mol% and 0 to 99.9 mol% of structural unit A, Molecular weight of the curable fluorine-containing polymer is 500 to 1,000,000.

  The second of the present invention relates to a method for producing a curable fluorine-containing polymer. The production method is represented by the formula (2):

[In the formula, the structural unit N represents the formula (N):

Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf ¹ is a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having an ether bond having 2 to 100 carbon atoms, and Y ⁵ (Y ⁵ is a monovalent group having 1 to 10 carbon atoms having a hydroxyl group or a hydroxyl group. A) is an integer of 0 to 3; b and c are the same or different and are derived from the fluorine-containing ethylenic monomer represented by 0 or 1) The hydroxyl group-containing structural unit and the structural unit B are structural units derived from a monomer copolymerizable with the hydroxyl group-containing fluorinated ethylenic monomer represented by the formula (N)]. 0.1-100 mol% N and structure A hydroxyl group-containing fluoropolymer containing 0 to 99.9 mol% of the unit B;
formula:

(Wherein R ¹ is a divalent organic group having 1 to 7 carbon atoms which may be substituted with a fluorine atom; X ⁶ is H, F, CH ₃ or CF ₃ ; X ⁷ and X ⁸ are the same or Unlike, H or F; and f unsaturated carboxylic acid or a derivative thereof having 3 to 10 carbon atoms represented by 0 or 1) (provided that the total number of carbon atoms of Y ³ is 3 to 10)
And an esterification reaction (1a):

[Wherein, the structural unit M4 represents the formula (M4):

Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf ² is the formula to a fluorine-containing alkyl group having ether bond of the fluorine-containing alkyl group or a 2 to 100 carbon atoms 40 carbon atoms:

(Wherein R ¹ , X ⁶ , X ⁷ , X ⁸ and f are the same as above; R ² is a divalent organic group having 1 to 7 carbon atoms which may be substituted with a fluorine atom; a is an integer of 0 to 3; organic radical Y ⁶ of 3 to 10 carbon atoms are bonded 1-3 represented by 1) Unlike the b and c the same or, free represented by 0 or 1) The structural unit derived from the fluorine ethylenic monomer, the structural unit A is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M4)] This is a method for producing a curable fluorinated polymer having 0.1 to 100 mol% of structural unit M4 and 0 to 99.9 mol% of structural unit A and having a number average molecular weight of 500 to 1,000,000.

The third aspect of the present invention is
(A) the curable fluorine-containing polymer or the curable fluorine-containing polymer according to any one of claims 2 to 14,
(B) an active energy ray curing initiator,
(C) The present invention relates to a fluorine-containing resin composition for coating comprising a solvent, a cured product thereof, particularly a photocured product and a cured film.

  The fourth of the present invention relates to an antireflection film.

As an antireflection film,
An antireflection film comprising a cured coating of a fluorine-containing prepolymer, wherein the fluorine-containing prepolymer is
(I) has a carbon-carbon unsaturated bond at the end of the side chain, and (ii) has a refractive index of 1.40 or less,
An antireflection film having a cured film thickness of 0.03 to 0.5 μm;
(D) the fluorine-containing prepolymer,
(E) a cured film obtained by photocuring a film formed by applying a coating composition comprising an active energy ray curing initiator and (f) a solvent,
An antireflection film having a cured film thickness of 0.03 to 0.5 μm; or (d) the fluorine-containing prepolymer,
(E) an active energy ray curing initiator,
(F) a cured film obtained by photocuring a film formed by applying a coating composition comprising a solvent and (g) a curing agent,
Examples thereof include an antireflection film having a cured film thickness of 0.03 to 0.5 μm.

  5th of this invention is related with the anti-reflective processing goods which gave these anti-reflective films to the base material.

The sixth aspect of the present invention relates to a novel fluorine-containing unsaturated compound. The novel compound has the formula (4-1):
^{CX 1 X 2 = CX 3 -} (CX 4 X 5) a - (O) c -Rf '(4-1)
Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf ′ is a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having an ether bond having 2 to 100 carbon atoms, and Y ³ (Y ³ is a carbon atom having 2 ethylenic carbon-carbon double bonds at the terminal). 10 is an organic group in which 1 to 3 monovalent organic groups are bonded; a is an integer of 0 to 3; c is 0 or 1), and Y ³ is formula:
-(O) _d- (C = O) -Y ⁴
(Wherein Y ⁴ is an organic group represented by an alkenyl group having 2 to 5 carbon atoms or a fluorine-containing alkenyl group having an ethylenic carbon-carbon double bond at the end; d is 0 or 1). A compound.

  ADVANTAGE OF THE INVENTION According to this invention, the curable fluorine-containing polymer which can implement | achieve high hardness to a polymer by photocuring can be provided, maintaining a low refractive index.

  Furthermore, it is possible to provide an antireflection film with improved scratch resistance and wear resistance while maintaining an antireflection effect, and an antireflection article coated with such an antireflection film.

  The curable fluorine-containing polymer which is the first of the present invention is represented by the formula (1):

[In the formula, the structural unit M represents the formula (M):

Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf ethylenic carbon Y ¹ (Y ¹ is terminated in the fluorine-containing alkyl group having ether bond of the fluorine-containing alkyl group or a 2 to 100 carbon atoms 40 carbon atoms - 2 carbon atoms having a carbon-carbon double bond An organic group in which 1 to 3 monovalent organic groups of 10 are bonded; a is an integer of 0 to 3; b and c are the same or different, and 0 or 1). Is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M)], and the structural unit M is 0.1 to 100 mol% and the structural unit A contains 0 to 99.9 mol%, and the number average molecular weight is 500 to 1,000,000. That is a curable fluorine-containing polymer.

Structural formula M is represented by formula (3):
^{CX 1 X 2 = CX 3 -} (CX 4 X 5) a - (C = O) b - (O) c -Rf (3)
(Wherein, X ¹ , X ² , X ³ , X ⁴ , X ⁵ , Rf, a, b and c are the same as those in the formula (M)). is there.

  That is, a homopolymer of a fluorine-containing ethylenic monomer having an ethylenic carbon-carbon double bond curable by reaction in the above side chain, or a copolymer having the fluorine-containing ethylenic monomer as an essential component It is a coalescence.

At least one of Y ¹ is preferably bonded to the end of Rf.

  In the curable fluorine-containing polymer of the formula (1) of the present invention, the structural unit M is preferably M1, and M1 is

Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf is a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having an ether bond having 2 to 100 carbon atoms; Y ¹ (Y ¹ is a carbon atom having 2 to 2 carbon atoms having an ethylenic carbon-carbon double bond at the terminal; An organic group in which 1 to 3 monovalent organic groups of 10 are bonded; a is an integer of 0 to 3; c is a structural unit represented by 0 or 1).

The structural unit M1 is represented by the formula (4):
^{CX 1 X 2 = CX 3 -} (CX 4 X 5) a - (O) c -Rf (4)
^{(Wherein, X 1, X 2, X} 3, X 4, X 5, Rf, a and c of the formula (3)) to a structural unit derived from the fluorine-containing ethylenic monomer represented by. Among the fluorine-containing unsaturated compounds represented by the formula (4), the formula (4-1):
^{CX 1 X 2 = CX 3 -} (CX 4 X 5) a - (O) c -Rf '(4-1)
(In the formula, X ¹ , X ² , X ³ , X ⁴ , X ⁵ , a and c are the same as in formula (4); Rf ′ is a fluorine-containing alkyl group having 1 to 40 carbon atoms or 2 to 100 carbon atoms. An organic group in which 1 to ³ Y ³ (Y ³ is a monovalent organic group having 2 to 10 carbon atoms having an ethylenic carbon-carbon double bond) is bonded to a fluorine-containing alkyl group having an ether bond. ) a fluorine-containing unsaturated compound represented by by, Y ³ has the formula:
-(O) _d- (C = O) -Y ⁴
(Wherein Y ⁴ is an organic group represented by an alkenyl group having 2 to 5 carbon atoms or a fluorine-containing alkenyl group having an ethylenic carbon-carbon double bond at the end; d is 0 or 1). The compound is a novel compound not described in any literature.

  The polymer containing the structural unit M1 has a particularly low refractive index, and is particularly preferable because the refractive index can be lowered even in a homopolymer of M1 or a polymer having an increased M1.

  A more preferable specific example of M1 is the structural unit M2, and the structural unit M2 is

(Wherein, Rf is ethylenic carbon Y ¹ (Y ¹ is terminated in the fluorine-containing alkyl group having ether bond of the fluorine-containing alkyl group or a 2 to 100 carbon atoms 40 carbon atoms - carbon double bonds It is a structural unit represented by (an organic group in which 1 to 3 monovalent organic groups having 2 to 10 carbon atoms are bonded).

The structural unit M2 has the formula (4-2):
_{CH 2 = CF-CF 2 -O} -Rf (4-2)
(Wherein Rf is the same as the formula (3)) and is a structural unit derived from a fluorine-containing ethylenic monomer. Among the fluorine-containing unsaturated compounds represented by the formula (4-2), the formula (4-3):
CH ₂ = CFCF ₂ ORf ′ (4-3)
The fluorine-containing unsaturated compound represented by the formula (wherein Rf ′ is the same as in formula (4-1)) is a novel compound not described in any literature.

  That is, the above M2 is a fluorine-containing allyl ether structural unit having an ethylenic carbon-carbon double bond at the end, and not only has a low refractive index, but also has good polymerizability, particularly homopolymerization, fluorine-containing. This is preferable because of good copolymerizability with an ethylene monomer.

  Another preferred specific example of M1 is the structural unit M3, and the structural unit M3 is

(Wherein, Rf is ethylenic carbon Y ¹ (Y ¹ is terminated in the fluorine-containing alkyl group having ether bond of the fluorine-containing alkyl group or a 2 to 100 carbon atoms 40 carbon atoms - carbon double bonds It is a structural unit represented by (an organic group in which 1 to 3 monovalent organic groups having 2 to 10 carbon atoms are bonded).

The structural unit M3 has the formula (4-4):
_{CF 2 = CF-O-Rf} (4-4)
(Wherein Rf is the same as the formula (3)) and is a structural unit derived from a fluorine-containing ethylenic monomer. Of the fluorine-containing unsaturated compounds represented by formula (4-4), formula (4-5):
CF ₂ = CFORf ′ (4-5)
The fluorine-containing unsaturated compound represented by the formula (wherein Rf ′ is the same as in formula (4-1)) is a novel compound not described in any literature.

  M3 is a structural unit of a fluorinated vinyl ether having an ethylenic carbon-carbon double bond at its end, which is preferable in that the refractive index can be lowered and the copolymerization with a fluorinated ethylene monomer is good. .

An organic group having 2 to 10 carbon atoms having a carbon-carbon double bond - curable fluorine-containing polymer structural units in M, M1, Y ¹ contained in the M2 and M3 ends ethylenic carbon of formula (1) of the present invention is there.

That is, the carbon-carbon double bond in Y ¹ has the ability to cause a polycondensation reaction, a cyclization reaction, an addition reaction, and the like, and a cured (crosslinked) product can be obtained. Specifically, for example, a polymerization reaction or a condensation reaction is performed between the curable fluorine-containing polymer molecules of the present invention by contact with radicals or cations, or between the curable fluorine-containing polymer and a curing (crosslinking) agent added as necessary. A cured (crosslinked) product can be obtained.

In the curable fluorine-containing polymer of the formulas (1) and (2) of the present invention, Y ¹ is preferably

Wherein Y ² is an alkenyl group having 2 to 5 carbon atoms having an ethylenic carbon-carbon double bond at the terminal, or a fluorine-containing alkenyl group, and d and e are the same or different, and 0 or 1; ² is preferably -CX ⁶ = CX ⁷ X ⁸
(Wherein X ⁶ is H, F, CH ₃ or CF ₃ , X ⁷ and X ⁸ are H or F) and is preferable because of high curing reactivity due to contact with radicals or cations.

Y ⁴ in the novel fluorine-containing unsaturated compounds represented by (4-1), (4-3) and (4-5) of the present invention is preferably the same as Y ² described above.

As preferred specific examples of Y ² and Y ⁴ ,

Y ¹ and Y ³ are more preferably
^{-O (C = O) CX 6} = CX 7 X 8
(Wherein X ⁶ is H, F, CH ₃ or CF ₃ , X ⁷ and X ⁸ are H or F), and is particularly preferable in terms of higher curing reactivity due to contact with radicals. It is preferable at the point which can obtain hardened | cured material easily.

More specific examples of Y ¹ and Y ³ are as follows:

Etc.

Other Y ¹

Etc.

Other Y ³

Can be given.

Among these, those having a structure of —O (C═O) CF═CH ₂ are preferable in that the refractive index can be lowered, and the curing (crosslinking) reactivity is particularly high, and a cured product can be obtained efficiently.

Rf contained in the structural units M, M1, M2 and M3 in the curable fluorine-containing polymer of the formula (1) of the present invention, novel fluorine-containing compounds of the formulas (4-1), (4-3) and (4-5) Rf ′ contained in the unsaturated compound, Rf ¹ contained in the structural unit N of the hydroxyl group-containing fluoropolymer of the formula (2), and further the structural unit of the curable fluoropolymer of the formula (1-1) (A -1) and RRf ⁴ contained in (A-2), and preferred organic groups excluding the functional groups Y ¹ , Y ³ , Y ⁵ , Z ¹ and Z ² are particularly functional groups Y ¹ and Y ^3. , Y ⁵ is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having an ether bond having 2 to 100 carbon atoms. These organic groups only need to have a fluorine atom bonded to the carbon atom contained, and are generally a fluorine-containing alkylene group in which a fluorine atom and a hydrogen atom or a chlorine atom are bonded to a carbon atom, or a fluorine-containing alkylene group having an ether bond. However, those containing more fluorine atoms (high fluorine content) are preferred, and the fluorine content is 50% or more, preferably 70% or more, relative to the molecular weight excluding oxygen atoms of the organic group excluding the functional group, More preferred is a perfluoroalkylene group or a perfluoroalkylene group having an ether bond. These make it possible to lower the refractive index of the curable fluorinated polymer. In particular, the refractive index can be kept low even if the degree of curing (crosslinking density) is increased for the purpose of increasing the hardness of the cured product.

  If the number of carbon atoms is too large, in the case of a fluorine-containing alkylene group, the solubility in a solvent may be lowered or the transparency may be lowered. In the case of a fluorine-containing alkylene group having an ether bond, the polymer itself or its curing may be caused. This is not preferable because the hardness and mechanical properties of the article may be lowered. Carbon number of a fluorine-containing alkylene group becomes like this. Preferably it is 1-20, More preferably, it is 1-10. The carbon number of the fluorine-containing alkylene group having an ether bond is preferably 2 to 30, more preferably 2 to 20.

  Preferred examples are

(X ⁹ and X ^{9 ′} are F or CF ₃ ; X ¹⁰ and X ^{10 ′} are H or F;
o + p + q is 1-30; r is 0 or 1; s, t is 0 or 1)
It is.

  The structure of the structural unit M constituting the curable fluorine-containing polymer of the present invention and specific examples of the novel fluorine-containing unsaturated compound will be described.

  As a preferable specific example of the monomer that gives the structural unit M2,

For more details,

Etc.

Examples of the novel fluorine-containing unsaturated compound of the formula (4-3) include those in which Y ¹ is replaced with Y ³ in the examples of the monomer that gives the structural unit M2.

  More details

Etc.

  As a preferable specific example of the monomer that gives the structural unit M3,

Etc.

  For more details,

Etc.

Examples of the novel fluorine-containing unsaturated compound of the formula (4-5) include those in which Y ¹ is replaced with Y ³ in the examples of the monomer giving the structural unit M3.

  More details

Etc.

  As preferable specific examples of the monomer constituting the structural unit M of the curable fluorinated polymer of the present invention other than M2 and M3, for example,

Etc.

  More specifically,

Etc.

In the novel fluorine-containing unsaturated compound of the formula (4-1) of the present invention, examples of the fluorine-containing unsaturated compound other than the above-described formulas (4-3) and (4-5) include the structural units M2 and M3. Other preferred specific examples in which Y ¹ is replaced by Y ³ in the preferred specific examples of the monomer that gives the structural unit M other than the above.

  In the curable fluorinated polymer of the present invention, the structural unit A is an optional component and is not particularly limited as long as it is a monomer that can be copolymerized with the structural units M, M1, M2, or M3. What is necessary is just to select suitably according to the use of a polymer or its hardened | cured material, a required characteristic, etc.

  For example, the following structural units can be exemplified.

(I) Structural unit derived from a fluorine-containing ethylenic monomer having a functional group (A1)
These are preferable in that they can provide adhesion to a substrate and solubility in a solvent, particularly a general-purpose solvent while maintaining the refractive index of the curable fluorine-containing polymer and its cured product low, and other than that Y is involved. It is preferable at the point which can provide functions, such as crosslinkability. The structural unit of a preferred fluorine-containing ethylenic monomer having a functional group is represented by the general formula (A1):

(In the formula, X ¹¹ , X ¹² and X ¹³ are H or F, X ¹⁴ is H, F, CF ₃ , h is 0 to 2, i is 0 or 1, and Rf ⁴ is fluorine containing 1 to 40 carbon atoms. An alkylene group, a fluorine-containing alkylene group having an ether bond having 2 to 100 carbon atoms, Z ¹ is —OH, —CH ₂ OH, —COOH, carboxylic acid derivative, —SO ₃ H, sulfonic acid derivative, epoxy group, cyano group A structural unit represented by formula (A1-1):

Is preferred.

  More specifically,

A structural unit derived from a fluorine-containing ethylenic monomer such as is preferred.

  Formula (A1-2):

The structural unit represented by can also be preferably exemplified, and more specifically,

And structural units derived from monomers such as

In addition, as the functional group-containing fluorine-containing ethylenic monomer,
_{CF 2 = CFCF 2 -O-Rf} -Z 1, CF 2 = CF-Rf-Z 1,
_{CH 2 = CH-Rf-Z} 1, CH 2 = CHO-Rf-Z 1
(Rf is the same as Rf in formula (M))
And more specifically,

Etc.

(Ii) Structural unit derived from a fluorine-containing ethylenic monomer containing no functional group (A2)
These are preferable in that the refractive index of the curable fluorinated polymer or the cured product thereof can be kept low, and further in that the refractive index can be further reduced. Further, by selecting a monomer, the mechanical properties of the polymer, the glass transition point, etc. can be adjusted. Particularly, the copolymerization with the structural unit M can increase the glass transition point, which is preferable.

  The structural unit of the fluorine-containing ethylenic monomer is represented by the general formula (A2):

(Wherein X ¹⁵ , X ¹⁶ and X ¹⁸ are H or F, X ¹⁷ is H, F or CF ₃ , h1, i1, j is 0 or 1, Z ² is H, F or Cl, and Rf ⁵ is carbon. A fluorine-containing alkylene group having 1 to 20 carbon atoms or a fluorine-containing alkylene group containing an ether bond having 2 to 100 carbon atoms is preferable.

  As a specific example,

Preferred are structural units derived from monomers such as

(Iii) Aliphatic cyclic structural unit having fluorine (A3)
When these structural units are introduced, the transparency can be increased, the refractive index can be further lowered, and a curable fluorine-containing polymer having a high glass transition point can be obtained, and the cured product can be expected to have higher hardness. This is preferable.

  As the fluorine-containing aliphatic cyclic structural unit, the formula (A3):

Wherein X ¹⁹ , X ²⁰ , X ²³ , X ²⁴ , X ²⁵ , X ²⁶ are the same or different H or F; X ²¹ , X ²² are the same or different H, F, Cl or CF ₃ ; Rf ⁶ is a fluorine-containing alkylene group having 1 to 10 carbon atoms or a fluorine-containing alkylene group having an ether bond having 2 to 10 carbon atoms; n2 is an integer of 0 to 3; n1, n3, n4 and n5 are the same or different and 0 or An integer of 1 is preferable.

  For example,

(Wherein Rf ⁶ , X ²¹ and X ²² are the same as those described above).

  In particular,

Etc.

(Iv) Structural units derived from ethylenic monomers that do not contain fluorine Introducing structural units derived from ethylenic monomers that do not contain fluorine to the extent that the refractive index is not deteriorated (higher refractive index). Also good.

  Thereby, the solubility in a general-purpose solvent is improved, and the compatibility with an additive such as a photocatalyst or a curing agent added as necessary is preferable.

Specific examples of non-fluorinated ethylenic monomers include
α-olefins:
Vinyl ether or vinyl ester monomers such as ethylene, propylene, butene, vinyl chloride, vinylidene chloride:
Allyl monomers such as CH ₂ = CHOR, CH ₂ = CHOCOR (R: hydrocarbon group having 1 to 20 carbon atoms):
Allyl ether monomers such as CH ₂ = CHCH ₂ Cl, CH ₂ = CHCH ₂ OH, CH ₂ = CHCH ₂ COOH, CH ₂ = CHCH ₂ Br, etc .:
CH ₂ = CHCH ₂ OR (R: a hydrocarbon group having 1 to 20 carbon atoms),
_{CH 2 = CHCH 2 OCH 2 CH} 2 COOH,

Acrylic or methacrylic monomers such as:
In addition to acrylic acid, methacrylic acid, acrylic esters and methacrylic esters, maleic anhydride, maleic acid, maleic esters and the like can be mentioned.

(V) Structural unit derived from alicyclic monomer As the copolymer component of structural unit M, structural unit M and the aforementioned fluorine-containing ethylenic monomer or non-fluorine ethylenic monomer (described above) are more preferable. In addition to the structural units of (iii) and (iv)), an alicyclic monomer structural unit may be introduced as the third component, thereby increasing the glass transition point and increasing the hardness. preferable.

  Specific examples of alicyclic monomers include

A norbornene derivative represented by (m: 0 to 3, A, B, C, D is H, F, Cl, COOH, CH ₂ OH, C 1-5 perfluoroalkyl, etc.),

And alicyclic monomers such as these, and derivatives obtained by introducing substituents into these.

  In the curable fluorine-containing polymer of the present invention, the combination and composition ratio of the structural unit M (M1, M2, M3) and A are the intended use, physical properties (especially, glass transition point, hardness, etc.), function, and function. Various selections can be made depending on (transparency, refractive index) and the like.

  In the curable fluorine-containing polymer of the present invention, the structural unit M (M1, M2, M3) is contained as an essential component, and the structural unit M itself maintains a low refractive index and imparts transparency and curing. Therefore, the cured product has a feature that can provide hardness, abrasion resistance, scratch resistance and solvent resistance. Accordingly, the curable fluorinated polymer of the present invention can maintain a low refractive index even if it is a polymer containing a large amount of structural units M, extremely a polymer consisting of only structural units M (100 mol%). At the same time, a cured product having a high cured (crosslinked) density is obtained, which is preferable in that a film having high hardness, abrasion resistance, and scratch resistance is obtained.

  Furthermore, in the case of a copolymer comprising the structural unit M of the present invention and a structural unit A of a monomer that can be copolymerized, by selecting the structural unit A from the above-mentioned examples, it is possible to further increase the hardness (high glass transition). Point) or a polymer that gives a cured product having a low refractive index.

  In the copolymer of the structural unit M and the structural unit A, the content ratio of the structural unit M may be 0.1 mol% or more with respect to all monomers constituting the curable fluorinated polymer. In order to obtain a cured product having high hardness, excellent wear resistance and scratch resistance, and excellent chemical resistance and solvent resistance by crosslinking, it is 2.0 mol% or more, preferably 5 mol% or more, more preferably It is preferable to set it as 10 mol% or more.

  In particular, in the use of an antireflection coating that requires the formation of a cured coating having excellent scratch resistance and scratch resistance, it is preferably contained in an amount of 10 mol% or more, preferably 20 mol% or more, and more preferably 50 mol% or more.

  The curable fluorinated polymer of the present invention is particularly preferable for use in an antireflection film because the antireflection effect does not decrease even if the proportion of the structural unit M is increased (even if the curing site is increased).

  Further, when transparency is required such as for use in an antireflection film, it is preferable that the combination of the structural unit M and the structural unit A is a curable fluorine-containing polymer having a combination and composition that can be amorphous.

Especially, as a preferable form of the fluorine-containing polymer for coating compositions aiming at a low refractive index and high hardness, Formula (1-1):
-(M)-(A1)-(A2)-(1-1)
Is a curable fluorine-containing polymer.

  The structural unit M in the formula (1-1) is a structural unit having the above-described ethylenic carbon-carbon double bond in the side chain, and is the above-described formula (M1), (M2), or (M3). A thing similar to a preferable example is applicable.

  The structural unit A1 is a structural unit derived from a fluorine-containing ethylenic monomer having a functional group in the side chain. Specifically, the structural unit A1 is represented by the formula (A1):

(In the formula, X ¹¹ , X ¹² and X ¹³ are H or F, X ¹⁴ is H, F, CF ₃ , h is 0 to 2, i is 0 or 1, and Rf ⁴ is fluorine containing 1 to 40 carbon atoms. An alkylene group, a fluorine-containing alkylene group having an ether bond having 2 to 100 carbon atoms, Z ¹ is —OH, —CH ₂ OH, —COOH, carboxylic acid derivative, —SO ₃ H, sulfonic acid derivative, epoxy group, cyano group Specific examples of the structural unit A1 derived from the above-mentioned fluorine-containing ethylenic monomer having a functional group are also preferably applicable.

  The structural unit A2 is a structural unit derived from a fluorine-containing ethylenic monomer having no functional group. Specifically, the structural unit A2 is represented by the formula (A2):

^{(Wherein, X 15, X 16, X} 18 is H or F, X ¹⁷ is H, F or CF _3, h1, i1, j is 0 or 1, Z ² is H, F or Cl, Rf ⁵ carbon Derived from a fluorine-containing ethylenic monomer having no functional group as described above, which is a structural unit represented by a fluorine-containing alkylene group having 1 to 20 carbon atoms or a fluorine-containing alkylene group having an ether bond having 2 to 100 carbon atoms. Specific examples of the structural unit A2 to be used can be preferably applied similarly. Among these, a structural unit derived from at least one monomer selected from the group consisting of tetrafluoroethylene, chlorotrifluoroethylene, vinylidene fluoride, and hexafluoropropylene is preferable.

  The respective abundance ratios of the structural units M, A1 and A2 are M = 0 to 90 mol%, A1 = 0 to 99.9 mol% and A2 = 0 to 99.9 mol%, and A1 + A2 = 10 to 99 It is preferably 9 mol%. Especially, it is preferable that they are M = 10-80 mol%, A1 = 1-60 mol% and A2 = 20-85 mol%, and A1 + A2 = 20-90 mol%. When the structural unit M is too small, the hardness of the film after curing tends to be low or the strength tends to be insufficient. When the amount of A1 is too small, adhesion to a substrate, coating property, solvent solubility, etc. tend to be insufficient. If the amount of A2 is too small, the coating property to the substrate, the leveling property, and the solvent solubility tend to be insufficient.

  The fluorine-containing polymer composed of these structural units M, A1, and A2 can impart hardness, mechanical strength, and dissolution resistance to the coating film and the like by the curable site of the structural unit M. The functional group of the structural unit A1 can provide adhesion to the substrate, solvent solubility, and good coatability (wetability and leveling property) to the substrate. Furthermore, the structural unit A2 can impart mechanical strength, solvent solubility, and good coatability to the base material to the fluoropolymer.

  Further, since the structural units M, A1, and A2 all contain a large number of fluorine atoms, the above functions can be imparted while maintaining a low refractive index. It is a fluoropolymer.

  The molecular weight of the curable fluorinated polymer of the present invention can be selected, for example, from the range of 500 to 1,000,000 in terms of the number average molecular weight, preferably from 1,000 to 500,000, particularly preferably from 2,000 to 200,000.

  If the molecular weight is too low, mechanical properties are likely to be insufficient even after curing, and in particular, the cured product and the cured film tend to be brittle and insufficient in strength. When the molecular weight is too high, the solvent solubility is deteriorated, the film formability and leveling property are liable to be deteriorated particularly during the formation of a thin film, and the storage stability of the curable fluorine-containing polymer is liable to be unstable. As a coating application, the number average molecular weight is most preferably selected from the range of 5000 to 100,000.

  The curable fluorinated polymer of the present invention can be variously determined depending on the type and content of the structural unit M, and the type of the copolymer structural unit A used as necessary, but the refraction of the curable fluorinated polymer itself (before curing). The rate is preferably 1.45 or less, more preferably 1.40 or less, and particularly preferably 1.38 or less. Although it changes depending on the type of the base material or the base, it can be preferable as a base polymer for an antireflection film by maintaining these low refractive indexes and allowing curing (crosslinking).

  Further, the curable fluorine-containing polymer is preferably soluble in a general-purpose solvent. For example, it is soluble in at least one of a ketone-based solvent, an acetate-based solvent, an alcohol-based solvent, and an aromatic solvent, or the above-mentioned general-purpose solvent. It is preferably soluble in a mixed solvent containing at least one kind.

  It is preferable to be soluble in a general-purpose solvent because it is excellent in film formability and homogeneity when it is formed on various transparent films and display substrates for antireflection films that require coating use, particularly about 0.1 μm, This is also advantageous in terms of productivity in forming the antireflection film.

In order to obtain the curable fluorine-containing polymer of the present invention, generally (i) a method obtained by previously synthesizing and polymerizing a monomer having Y ¹ (ii) once a polymer having another functional group synthesized, and converts the functional group by a polymer reaction to the polymer, any method of a method of introducing a functional group Y ¹ can be adopted.

  However, the method (i) is used to obtain the curable fluorine-containing polymer of the present invention having a carbon-carbon double bond in the side chain without reacting (curing) the carbon-carbon double bond at the end of the side chain. By changing the reactivity of two types of double bonds (double bond as main chain and double bond as side chain) in (co) polymerizable monomer, only one double bond is involved in polymerization. In such a method, it is difficult to select the polymerization conditions for obtaining the curable fluorine-containing polymer having a double bond in the side chain of the present invention, and the double side chain in the resulting curable polymer is difficult to select. It is difficult to use a bond having a very high curing reactivity.

  On the other hand, the method (ii) is easy to obtain the curable fluorine-containing polymer of the present invention without causing a curing reaction, and a carbon-carbon double bond having a high curing reactivity can also be introduced into the side chain. This is a preferable method.

Among the methods (ii), for example, a structural unit N of a fluorine-containing monomer once having a hydroxyl group or an organic group Y ³ having a hydroxyl group, and a structural unit of a monomer copolymerizable with N if necessary. After synthesizing the fluorine-containing polymer comprising B, an unsaturated carboxylic acid or a derivative thereof is reacted to introduce a carbon-carbon double bond to the end of the side chain of the polymer to obtain the curable fluorine-containing polymer of the present invention. The method can be preferably adopted.

  Therefore, the second of the present invention is the formula (2):

[In the formula, the structural unit N represents the formula (N):

Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf ¹ is a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having an ether bond having 2 to 100 carbon atoms, and Y ⁵ (Y ⁵ is a monovalent group having 1 to 10 carbon atoms having a hydroxyl group or a hydroxyl group. A) is an integer of 0 to 3; b and c are the same or different and are derived from the fluorine-containing ethylenic monomer represented by 0 or 1) The hydroxyl group-containing structural unit and the structural unit B are structural units derived from a monomer copolymerizable with the hydroxyl group-containing fluorinated ethylenic monomer represented by the formula (N)]. 0.1-100 mol% N and structure The present invention relates to a method for producing a curable fluorine-containing polymer obtained by esterifying a hydroxyl group-containing fluorine-containing polymer containing 0 to 99.9 mol% of a unit B with an unsaturated carboxylic acid or a derivative thereof.

In the above method for producing a curable fluorinated polymer of the present invention, in the hydroxyl group-containing fluorinated polymer of the precursor represented by the formula (2), the structural unit N is a specific example of the curable fluorinated polymer described above. Corresponding to each of the specific examples of the structural unit M of the fluoropolymer, those having a structure in which a site Y ¹ containing a carbon-carbon double bond is replaced with a site Y ⁵ containing an OH group can be preferably used. The same structural units as those described above can be preferably used.

  The unsaturated carboxylic acid or derivative thereof to be reacted with the hydroxyl group-containing fluoropolymer may be any carboxylic acid or derivative thereof having a carbon-carbon double bond at the terminal. Among them, α, β-unsaturated carboxylic acid may be used. Acid or its derivative (f = 0) is preferred.

  For example,

A carboxylic acid represented by or an anhydride thereof, or

And maleic acid, maleic anhydride, maleic acid monoalkyl ester and the like.

  Among these, when an unsaturated carboxylic acid halide is employed, the reaction can be performed at room temperature, and gelation of the resulting polymer can be prevented, which is preferable.

  In particular,

Is particularly preferred.

  The method for reacting the α, β-unsaturated carboxylic acid halide with the hydroxyl group-containing fluoropolymer is not particularly limited, but usually, the hydroxyl group-containing fluoropolymer is dissolved in a solvent and then α, β -It is obtained by stirring and mixing an unsaturated carboxylic acid halide at a temperature of about -20 ° C to 40 ° C and reacting.

  In this reaction, HCl and HF are by-produced by the reaction, but it is desirable to add an appropriate base for the purpose of capturing them. Examples of the base include tertiary amines such as pyridine, N, N-dimethylaniline, tetramethylurea and triethylamine, and magnesium metal. In addition, an inhibitor for inhibiting the polymerization reaction of the raw material α, β-unsaturated carboxylic acid and the carbon-carbon double bond in the obtained curable fluorine-containing polymer is allowed to coexist. Also good.

  Examples of the inhibitor include hydroquinone, t-butyl hydroquinone, hydroquinone monomethyl ether and the like.

  The hydroxyl group-containing fluorine-containing polymer before reacting with the unsaturated carboxylic acid or its derivative is an ethylenic monomer (N) having a hydroxyl group corresponding to each structural unit, and a single amount that becomes a copolymerization component when used. It can be obtained by (co) polymerizing the body (B) by a known method. As the polymerization method, a radical polymerization method, an anionic polymerization method, a cationic polymerization method or the like can be used. Among them, the monomers exemplified for obtaining the polymer having a hydroxyl group of the present invention have good radical polymerizability, and are easy to control quality such as composition and molecular weight, and are easy to industrialize. Legal methods are preferably used.

  In order to start radical polymerization, the means is not limited as long as it proceeds radically, but for example, it is started by organic or inorganic radical polymerization initiator, heat, light, or ionizing radiation. As the polymerization mode, solution polymerization, bulk polymerization, suspension polymerization, emulsion polymerization and the like can be used. The molecular weight is controlled by the concentration of the monomer used for the polymerization, the concentration of the polymerization initiator, the concentration of the chain transfer agent, the temperature, and the like. The copolymer composition can be controlled by the monomer composition of the charged monomers.

The third of the present invention relates to a composition using a curable fluorine-containing polymer. One of the compositions of the present invention is
A curable fluorine-containing resin composition comprising (a) a curable fluorine-containing polymer and (b) an active energy ray curing initiator.

  The curable fluorinated polymer (a) in the composition of the present invention is a curable fluorinated polymer having a carbon-carbon double bond in the above-mentioned side chain, and the same specific examples as described above are preferably used. it can.

  The active energy ray curing initiator (b), for example, generates radicals and cations only when irradiated with electromagnetic waves in a wavelength region of 350 nm or less, that is, ultraviolet rays, electron beams, X rays, γ rays, etc., and is curable. It functions as a catalyst for initiating the curing (crosslinking reaction) of the carbon-carbon double bond of the fluorine-containing polymer. Usually, those that generate radicals and cations with ultraviolet light, particularly those that generate radicals are used.

  According to this curable fluorine-containing resin composition, a curing reaction can be easily started by the active energy ray, and there is no need for heating at a high temperature, and a curing reaction is possible at a relatively low temperature. This is preferable in that it can be applied to a base material that is easily deformed, decomposed or colored by heat, such as a transparent resin base material.

  The active energy ray curing initiator (b) in the composition of the present invention is a type of carbon-carbon double bond (radical reactive or cationic reactive) of the side chain in the curable fluorine-containing polymer (a), A curable fluorine-containing polymer having a radical-reactive carbon-carbon double bond, which is generally selected depending on the type (wavelength range, etc.) of the active energy ray to be used and the irradiation intensity. Examples of the initiator for curing (a) include the following.

Acetophenone acetophenone, chloroacetophenone, diethoxyacetophenone, hydroxyacetophenone, α-aminoacetophenone, hydroxypropiophenone, 2-methyl-1- [4- (methylthio) phenyl] -2-morpholinepropan-1-one, etc.
Benzoin benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, benzyldimethyl ketal, etc.
Benzophenone benzophenone, benzoyl benzoate, methyl benzoyl benzoate, 4-phenyl benzophenone, hydroxybenzophenone, hydroxypropyl - propyl benzophenone, acrylated benzophenone, Michler's ketone, etc.
Chi Oki Sanson such thioxanthone, chloro thioxanthone, methyl cyclohexane Son, diethyl thioxanthone, dimethyl thioxanthone, etc.
Other benzyl, α-acyl oxime ester, acyl phosphine oxide, glyoxy ester, 3-ketocoumarin, 2-ethylanthraquinone, camphorquinone, anthraquinone, etc.

  Depending on the type of the fluorine-containing polymer and depending on the type of the active energy ray initiator described above, the compatibility may be lost, and the coating composition itself or the coated film may become cloudy, resulting in transparency and curing reaction. May decrease (Experimental Example 21 (1)).

  The present inventors have found that compatibility with a fluorine-containing polymer can be improved by introducing a fluorine atom or a fluorine-containing organic group into the active energy ray initiator itself.

  Specifically, it is preferable that the initiator contains a fluorine-containing alkyl group, a fluorine-containing alkylene group, a fluorine-containing alkyl group having an ether bond, or a fluorine-containing alkylene group having an ether bond, for example, an initiator having an OH group. One having a structure in which a fluorine-containing carboxylic acid having a fluorine-containing organic group (polyvalent carboxylic acid) or the like is introduced by an ester bond (Experimental Example 18), a fluorine-containing carboxylic acid (polyvalent carboxylic acid) as an initiator having an amino group And a structure in which is introduced through an amide bond.

  By introducing a fluorine-containing organic group into the initiator, even in a fluorine-containing polymer having a high fluorination rate, compatibility is good, which is preferable in terms of improving curing reactivity and film transparency (Experimental Example 21 (1 )).

  Moreover, you may add photoinitiator adjuvants, such as amines, sulfones, and sulfines, as needed.

  Moreover, the following can be illustrated as an initiator which hardens the curable fluorine-containing polymer (a) which has a cation reactive carbon-carbon double bond.

Onium salt iodonium salt, sulfonium salt, phosphonium salt, diazonium salt, ammonium salt, pyridinium salt, etc.
Sulfone compounds β-ketoesters, β-sulfonylsulfones and their α-diazo compounds, etc.
Sulfonic acid esters Alkyl sulfonic acid esters, haloalkyl sulfonic acid esters, aryl sulfonic acid esters, imino sulfonates, etc.
Other sulfonimide compounds, diazomethane compounds, etc.

  Also in these cation-reactive active energy ray initiators, compatibility with the fluorine-containing polymer can be improved in the same manner as described above by introducing a fluorine atom or a fluorine-containing organic group.

  Another embodiment of the curable fluorine-containing resin composition of the present invention is an embodiment using a solvent, and can be coated on various substrates by dissolving or dispersing in the solvent to form a coating film. After formation, it is preferable in that it can be efficiently cured by irradiation with an active energy ray or the like, and a cured film can be obtained.

That is, the fluorine-containing resin composition for coating of the present invention is
It is a composition comprising (a) a curable fluorine-containing polymer (b) an active energy ray curing initiator, and (c) a solvent.

  As the curable fluorinated polymer (a) and the active energy ray curing initiator (b), the same curable fluorinated resin composition as that described above can be preferably used.

  In the solvent (c), the curable fluorine-containing polymer (a), the active energy ray curing initiator (b), and additives such as a curing agent, a leveling agent, and a light stabilizer that are added as necessary are uniformly dissolved or dispersed. If it does, there will be no restriction | limiting in particular, Especially the thing which melt | dissolves a curable fluorine-containing polymer (a) uniformly is preferable. The mode of using this solvent is particularly preferable in the field where a thin layer coating (around 0.1 μm) is required, such as an antireflection coating, and is highly transparent so that a uniform coating can be obtained with high productivity.

  Examples of the solvent (c) include cellosolv solvents such as methyl cellosolve, ethyl cellosolve, methyl cellosolve acetate, and ethyl cellosolve acetate; diethyl oxalate, ethyl pyruvate, ethyl-2-hydroxybutyrate, ethyl acetoacetate, butyl acetate , Ester solvents such as amyl acetate, ethyl butyrate, butyl butyrate, methyl lactate, ethyl lactate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 2-hydroxyisobutyrate, ethyl 2-hydroxyisobutyrate; propylene Glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether Propylene glycol solvents such as rubacetate, propylene glycol monobutyl ether acetate, dipropylene glycol dimethyl ether; ketone solvents such as 2-hexanone, cyclohexanone, methylaminoketone, 2-heptanone; methanol, ethanol, propanol, isopropanol, butanol, etc. Examples of the alcohol solvent include aromatic hydrocarbons such as toluene and xylene, or a mixed solvent of two or more of these.

  Furthermore, in order to improve the solubility of the curable fluorine-containing polymer (a), a fluorine-based solvent may be used as necessary.

Examples of the fluorine-based solvent include CH ₃ CCl ₂ F (HCFC-141b), CF ₃ CF ₂ CHCl ₂ / CClF ₂ CF ₂ CHClF mixture (HCFC-225), perfluorohexane, perfluoro (2-butyltetrahydrofuran). , Methoxy-nonafluorobutane, 1,3-bistrifluoromethylbenzene,

Fluorine alcohols such as
Examples thereof include benzotrifluoride, perfluorobenzene, perfluoro (tributylamine), ClCF ₂ CFClCF ₂ CFCl _{2 and the} like.

  These fluorinated solvents may be used singly or as a mixed solvent of fluorinated solvents or one or more of non-fluorinated and fluorinated solvents.

  Of these, ketone solvents, acetate solvents, alcohol solvents, aromatic solvents, and the like are preferable in terms of paintability and coating productivity.

  In addition, when dissolving the curable fluorinated polymer, the present inventors can improve the leveling of the polymer film after coating and drying on the base material by mixing the fluorinated alcohol solvent together with these general-purpose solvents. I found it.

  This leveling improvement effect is high for resin substrates, particularly acrylic resins, cellulosic resins, polyethylene terephthalate, polycarbonate, and polyolefin, and particularly remarkable for polyethylene terephthalate substrates (Experimental Examples 44 and 45). .

  The fluorine-containing alcohol to be added may be one having a boiling point of 50 ° C. or higher, preferably 80 ° C. or higher and capable of dissolving the curable fluorine-containing polymer.

  For example,

Etc. are preferable specific examples.

  The fluorinated alcohol may be used as a solvent by itself, but it is also effective when used in addition to general-purpose solvents such as the above-mentioned ketone solvents, acetate ester solvents, non-fluorine alcohol solvents, and aromatic solvents. It is.

  When used in combination, the addition amount is 1% by weight or more, preferably 5% by weight or more, more preferably 10% by weight or more, and particularly preferably 10 to 30% by weight, based on the whole solvent.

  Further required for the curable fluorinated resin composition of the present invention comprising the curable fluorinated polymer (a) and the active energy ray curing initiator (b), and further for the coating fluorinated resin composition including the solvent (c). Depending on the case, a curing agent may be added.

  As the curing agent, those having at least one carbon-carbon unsaturated bond and capable of being polymerized with radicals or acids are preferable. Specifically, radical polymerizable monomers such as acrylic monomers, vinyl ether monomers and the like are used. And cationically polymerizable monomers. These monomers may be monofunctional having one carbon-carbon double bond or polyfunctional monomers having two or more carbon-carbon double bonds.

  These so-called curing agents having a carbon-carbon unsaturated bond react with radicals and cations generated by the reaction of the active energy ray curing initiator (b) in the composition of the present invention with active energy rays such as light, The curable fluorinated polymer (a) in the composition of the present invention can be cross-linked by copolymerization with a carbon-carbon double bond in the side chain.

  Monofunctional acrylic monomers include acrylic acid, acrylic esters, methacrylic acid, methacrylic esters, α-fluoroacrylic acid, α-fluoroacrylic esters, maleic acid, maleic anhydride, maleic acid In addition to esters, (meth) acrylic acid esters having an epoxy group, a hydroxyl group, a carboxyl group, and the like are exemplified.

  Among them, in order to keep the refractive index of the cured product low, an acrylate monomer having a fluoroalkyl group is preferable.

A compound represented by (X is H, CH ₃ or F, and Rf is a fluorine-containing alkyl group having 2 to 40 carbon atoms or a fluorine-containing alkyl group having an ether bond having 2 to 100 carbon atoms) is preferable.

  In particular,

Etc.

  As polyfunctional acrylic monomers, compounds in which the hydroxyl groups of polyhydric alcohols such as diols, triols, and tetraols are replaced with acrylate groups, methacrylate groups, or α-fluoroacrylate groups are generally known. .

  Specifically, each of 1,3-butanediol, 1,4-butanediol, 1,6-hexanediol, diethylene glycol, tripropylene glycol, neopentyl glycol, trimethylolpropane, pentaerythritol, dipentaerythritol, etc. Examples thereof include compounds in which two or more hydroxyl groups of polyhydric alcohols are replaced with any one of an acrylate group, a methacrylate group, and an α-fluoroacrylate group.

  Further, two or more hydroxyl groups of a polyhydric alcohol having a fluorine-containing alkyl group, a fluorine-containing alkyl group containing an ether bond, a fluorine-containing alkylene group or a fluorine-containing alkylene group containing an ether bond are converted into an acrylate group, a methacrylate group, α A polyfunctional acrylic monomer substituted with a fluoroacrylate group can also be used, and is particularly preferable in that the refractive index of the cured product can be kept low.

  As a specific example

(Rf ′ is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group containing an ether bond, R is H or an alkyl group having 1 to 3 carbon atoms)
Preferred are those having a structure in which two or more hydroxyl groups of fluorine-containing polyhydric alcohols represented by the general formulas such as are replaced with acrylate groups, methacrylate groups or α-fluoroacrylate groups.

  In addition, when these exemplified monofunctional and polyfunctional acrylic monomers are used in the composition of the present invention as a curing agent, an α-fluoroacrylate compound is particularly preferable in terms of good curing reactivity.

  In the composition of the present invention, the addition amount of the active energy ray curing initiator (b) is the content of the carbon-carbon double bond in the curable fluorinated polymer (a), whether or not the curing agent is used, and curing. Depending on the amount of the agent used, and further, the initiator used, the type of active energy rays, and the amount of irradiation energy (strength and time, etc.) are appropriately selected. When no curing agent is used, the curable fluorine-containing polymer (a ) 0.01 to 30 parts by weight, more preferably 0.05 to 20 parts by weight, and most preferably 0.1 to 10 parts by weight with respect to 100 parts by weight.

  Specifically, it is 0.05 to 50 mol%, preferably 0.1 to 20 mol%, most with respect to the content (number of moles) of the carbon-carbon double bond contained in the curable fluorine-containing polymer (a). Preferably, it is 0.5 to 10 mol%.

  When a curing agent is used, the total number of moles of the carbon-carbon double bond content (number of moles) contained in the curable fluorine-containing polymer (a) and the number of moles of carbon-carbon unsaturated bonds of the curing agent. 0.05 to 50 mol%, preferably 0.1 to 20 mol%, and most preferably 0.5 to 10 mol%.

  When a curing agent is used, the amount of curing agent used is appropriately selected according to the target hardness and refractive index, the type of curing agent, the content of the curable group of the curable fluorinated polymer used, and preferably curable. It is 1 to 80% by weight, preferably 5 to 70% by weight, more preferably 10 to 50% by weight based on the fluorine-containing polymer. If the addition amount of the curing agent is too large, the refractive index tends to increase, which is not preferable.

  As content of the solvent (c) in the fluorine-containing resin composition for coating of the present invention, the type of solid content to be dissolved, the presence or absence and use ratio of a curing agent, the type of substrate to be applied, and the target film thickness The total solid content in the composition is preferably 0.5 to 70% by weight, and preferably 1 to 50% by weight.

  The composition of the present invention may contain various additives as necessary in addition to the above-mentioned compounds.

  Examples of such additives include leveling agents, viscosity modifiers, light stabilizers, moisture absorbers, pigments, dyes, and reinforcing agents.

  The composition of the present invention can also contain inorganic compound fine particles for the purpose of increasing the hardness of the cured product.

  The inorganic compound fine particles are not particularly limited, but compounds having a refractive index of 1.5 or less are preferable. Specifically, magnesium fluoride (refractive index 1.38), silicon oxide (refractive index 1.46), aluminum fluoride (refractive index 1.33-1.39), calcium fluoride (refractive index 1.44) Fine particles such as lithium fluoride (refractive index 1.36 to 1.37), sodium fluoride (refractive index 1.32 to 1.34), thorium fluoride (refractive index 1.45 to 1.50) are desirable. . The particle diameter of the fine particles is desirably sufficiently smaller than the wavelength of visible light in order to ensure the transparency of the low refractive index material. Specifically, it is preferably 100 nm or less, particularly 50 nm or less.

  When using inorganic compound fine particles, it should be used in the form of an organic sol dispersed in advance in an organic dispersion medium in order not to lower the dispersion stability in the composition and the adhesion in the low refractive index material. Is desirable. Furthermore, in order to improve the dispersion stability of the inorganic compound fine particles and the adhesion in the low refractive index material in the composition, the surface of the inorganic fine particle compound may be modified in advance using various coupling agents. it can. Examples of various coupling agents include organically substituted silicon compounds; metal alkoxides such as aluminum, titanium, zirconium, antimony or mixtures thereof; salts of organic acids; coordination compounds bonded to coordination compounds, and the like. .

  The fluorinated resin composition for coating of the present invention may be a dispersion-like or solution-like fluorinated polymer (a) or additive with respect to the solvent (c). In order to form the film and to enable film formation at a relatively low temperature, a uniform solution is preferable.

  As the coating method, a known coating method can be adopted as long as the film thickness can be controlled.

  For example, roll coating method, gravure coating method, micro gravure coating method, flow coating method, bar coating method, spray coating method, die coating method, spin coating method, dip coating method, etc. can be adopted. Can be selected considering the controllability and controllability of the film thickness.

  A curable resin composition comprising the curable fluorinated polymer (a) of the present invention and an active energy ray curing initiator (b), and the fluorinated resin composition for coating of the present invention applied to a substrate by the method described above Then, the film obtained by drying can be photocured by irradiating active energy rays such as ultraviolet rays, electron beams or radiation.

  When photocured, the carbon-carbon double bonds in the curable fluorine-containing polymer (a) of the present invention are polymerized between molecules, and the carbon-carbon double bonds in the polymer are reduced or eliminated. As a result, the resin hardness is increased, the mechanical strength is improved, the wear resistance, the scratch resistance is improved, and further, the resin becomes insoluble in the solvent dissolved before curing, It becomes insoluble in many other types of solvents.

  The fourth of the present invention relates to an antireflection film.

That is, it consists of a cured film having a film thickness of 0.03 to 0.5 μm, and the fluorine-containing prepolymer has (1) a carbon-carbon unsaturated bond at the end of the side chain,
(2) An antireflection film having a refractive index of 1.40 or less.

  In this invention, the fluorine-containing polymer itself has a carbon-carbon unsaturated bond that can be cured (crosslinked), and by itself using a low refractive index, it is applied to a transparent substrate with a predetermined film thickness, It was completed based on the knowledge of the present inventors that an antireflection film having both an antireflection effect and high hardness, wear resistance, and scratch resistance can be obtained by curing. When such a prepolymer is used, the paintability (smoothness, film thickness uniformity) is also good, and low molecular weight monomer components are not likely to remain in the cured film, and there is no surface tackiness. Excellent coating film performance.

  Curing can take measures such as heat and light (in a system containing an initiator), but when an antireflection film is applied to a transparent resin substrate, applying a high temperature may cause thermal degradation or thermal deformation of the substrate. It is not preferable because it is easy to cause. Accordingly, curing by photocuring is preferable, and the fluorine-containing prepolymer used in the present invention is preferably a carbon-carbon unsaturated bond capable of photocuring (for example, photopolymerization).

Usually, as a method of photocuring the fluorine-containing prepolymer to obtain an antireflection film,
(D) the above-mentioned fluorine-containing prepolymer,
(E) A coating composition comprising an active energy ray curing initiator and (f) a solvent is prepared, applied to a substrate, and a film (uncured) is formed by drying or the like, followed by ultraviolet rays, electron beams, radiation A method of obtaining a cured film by irradiating active energy rays such as the above is adopted, and the light irradiation may be performed under any condition of air or an inert gas stream such as nitrogen. Especially, the method of irradiating light in inert gas stream is preferable at the point with favorable curing reactivity, and the film of higher hardness is obtained.

  Any fluorine-containing prepolymer (d) for use in the antireflection film of the present invention can be used as long as it has a reactive side chain carbon-carbon unsaturated bond. Is preferably a carbon-carbon double bond.

  In particular, it is a polymerization reaction to use a fluorine-containing prepolymer (d1) having a radical polymerizable ethylenic carbon-carbon double bond in combination with an initiator (e) that generates radicals by irradiation with active energy rays. Is preferred in that it occurs promptly, has a high degree of polymerization, and can be easily cured.

  Further, the fluorine-containing prepolymer (d2) having an acid-polymerizable carbon-carbon double bond can be used in combination with an initiator that generates an acid upon irradiation with active energy rays. ) And the like, and is preferable in that a curing reaction can be achieved.

  The fluorine-containing prepolymer used in the antireflection film of the present invention is preferably the same as the above-described curable fluorine-containing polymer. Among the specific examples described above, the curable polymer itself has high transparency and is amorphous. And a refractive index of 1.40 or less, preferably 1.38 or less. Furthermore, among them, it is preferable to select and use as appropriate according to the target hardness, type of substrate, coating method, conditions, film thickness, uniformity, adhesion to the substrate, and the like.

  The active energy ray curing initiator (e) used in the antireflection film of the present invention can be the same as that exemplified for the curable fluorinated resin composition described above, and is carbon-carbon unsaturated in the fluorinated prepolymer. In consideration of the type of bond (reactivity, content), curing conditions, pot life of paint, etc., the type, amount used, etc. can be appropriately selected from the above ranges.

  As the solvent (f), the same solvents as those described above for the curable resin composition for coating can be used, and the type can be selected according to the target paintability, film formability, film thickness uniformity, and paint productivity. The amount used is appropriately selected from the above-described examples, but among them, a solvent that dissolves or swells the transparent resin substrate is not preferable.

  Particularly preferred are those selected from ketones, acetates, alcohols and aromatic hydrocarbon solvents.

  In the antireflection film of the present invention, as a matter of course, the same curing agent (g) as described above may be used together with the curable fluorine-containing polymer (d). By using a curing agent in combination, the hardness of the cured coating can be further increased.

  As for the type and amount of the curing agent (g) to be used, the curing agents described with respect to the above-mentioned fluorine-containing resin composition for coating can be preferably used as well.

  After applying these coating compositions, the cured product (coating) after curing the fluorine-containing prepolymer has a refractive index of 1.49 or less, preferably 1.45 or less, and further 1.40 or less. It is preferable. Most preferably, it is 1.38 or less, and the lower one is more advantageous as an antireflection effect.

  The preferable film thickness of the antireflection film applied to various substrates varies depending on the refractive index of the film and the refractive index of the base, but is selected from the range of 0.03 to 0.5 μm, preferably 0.07 to 0.2 μm. More preferably, it is 0.08 to 0.12 μm. If the film thickness is too low, the reduction in reflectance due to light interference in visible light will be insufficient, and if it is too high, the reflectance will depend only on the reflection at the interface between the air and the film. There is a tendency that the reduction of the reflectance due to is insufficient. In particular, it is preferable to set the film thickness so that the wavelength that indicates the minimum value of the reflectance of the article after applying the antireflection film is usually 420 to 720 nm, preferably 520 to 620 nm.

  A fifth aspect of the present invention relates to an antireflection-treated article obtained by applying this antireflection film to a base material.

  The article to which the antireflection film of the present invention is applied, that is, the type of the substrate is not particularly limited. For example, inorganic materials such as glass, stone, concrete, tile; cellulose resins such as vinyl chloride resin, polyethylene terephthalate, triacetyl cellulose, polycarbonate resin, polyolefin resin, acrylic resin, phenol resin, xylene resin, urea resin, melamine Synthetic resins such as resin, diallyl phthalate resin, furan resin, amino resin, alkyd resin, urethane resin, vinyl ester resin, polyimide resin; metal such as iron, aluminum, copper; wood, paper, printed matter, photographic paper, painting, etc. I can give you. In addition, the decorativeness of the article can be improved by applying an antireflection film to a part other than the specific part of the article and causing the shape of the specific part to be raised by reflected light.

  Among the base materials, it is preferably applied to a transparent resin base material such as acrylic resin, polycarbonate, cellulose resin, polyethylene terephthalate, and polyolefin resin, and can effectively exhibit an antireflection effect.

The present invention is effective when applied to an article having the following form.
Optical components such as prisms, lens sheets, polarizing plates, optical filters, lenticular lenses, Fresnel lenses, rear projection display screens, optical fibers and optical couplers;
Transparent protective plates such as show window glass, showcase glass, advertising covers, photo stand covers, etc .;
Protection plates such as CRT, liquid crystal display, plasma display, rear projection display;
Optical recording media represented by magneto-optical disks, read-only optical disks such as CD / LD / DVD, phase transition optical disks such as PD, hologram recording, etc .;
Photolithography-related members during semiconductor manufacturing, such as photoresists, photomasks, pellicles, and reticles;
Protective covers for illuminants such as halogen lamps, fluorescent lamps and incandescent lamps;
A sheet or film for attaching to the article.

  The antireflection film of the present invention may be formed by directly applying a solution of the fluorine-containing prepolymer (d) to a substrate, irradiating with light, and forming a cured film having a thickness of about 0.1 μm. One or a plurality of layers may be formed as an undercoat, and an antireflection film may be formed thereon as a topcoat.

  The effect of the undercoat is roughly divided into three, and is to enhance the antireflection effect by increasing the scratch resistance of the topcoat, protecting the base material, and adding a layer having a higher refractive index than the base material. . In order to improve the scratch resistance of the top coat, a self-repairing undercoat as exemplified in JP-A-7-168005 may be used. Further, a paint generally called a hard coat may be used for protecting the substrate. Examples of the hard coat include curable acrylic resins and epoxy resins, cured products of silicon alkoxide compounds, and cured products of metal alkoxide compounds. The thermosetting method can be applied to all of these. For acrylic resins and epoxy resins, the light (ultraviolet) curing method is preferred in terms of productivity.

In a CRT or plasma display, static electricity tends to accumulate on the surface as a characteristic of the device. Therefore, it is preferable to mix an additive for imparting conductivity to the undercoat layer and / or the topcoat layer as described above. Examples of the additive include —COO—, —NH ₂ , —NH ₃ ⁺ , —NR ¹¹ R ¹² R ¹³ (where R ¹¹ , R ¹² and R ¹³ are, for example, a methyl group, an ethyl group, and an n-propyl group. , N-butyl group, etc.), polymers containing ionic groups such as —SO ₃ —, silicone compounds, inorganic electrolytes (eg NaF, CaF ₂ etc.) and the like.

  Further, for the purpose of preventing the adhesion of dust, it is preferable to add an antistatic agent to the undercoat layer and / or the topcoat layer of the antireflection film. Examples of additives include metal oxide fine particles, fluoroalkoxysilanes, surfactants (anionic, cationic, amphoteric, nonionic, etc.) in addition to the above-mentioned additives that impart conductivity.

  As an antistatic agent added to the undercoat layer, the effect is permanent, the effect is not easily affected by humidity, the antistatic effect is high, the transparency and the refractive index are high, and the refractive index of the substrate is For the reason that the antireflection effect can be enhanced because it can be adjusted, fine particles of metal oxide, specifically, antimony-doped tin oxide (ATO) and indium-containing tin oxide (ITO) are preferable. ATO is preferable in terms of transparency, and ITO is preferable in terms of antistatic effect or conductivity. Further, even when the antistatic effect is not required, the refractive index can be easily adjusted, so that the antireflection effect can be enhanced by using these additives.

  In addition, since ATO and ITO easily scatter and absorb light, the thickness of the undercoat layer is preferably about submicron so as not to prevent light transmission. In order to reduce the wavelength dependency of the antireflection effect and enhance the antireflection effect over all wavelengths, the film thickness is preferably 0.05 to 0.3 μm, although it depends on the refractive index of the fluorinated prepolymer cured product. The optimum refractive index also depends on the refractive index of the fluorine-containing polymer, but is preferably 1.55 to 1.95.

  If antistatic properties are imparted to the fluorine-containing prepolymer cured coating, an alkoxysilane-based antistatic agent is preferred from the viewpoint that the refractive index is difficult to increase and the antireflection effect is less adverse. Fluoroalkoxysilane is more preferable because the action of increasing the refractive index is further reduced and the effect of improving the surface characteristics can be expected.

  Further, as a method completely different from the method of modifying a part of the film as described above, a surfactant having a film thickness that does not adversely affect the antireflection performance as disclosed in JP-A-8-142280. There is a method of forming the layer. When applied to the present invention, there is an effect of improving antifouling properties such as prevention of dust adhesion. The same effect can be obtained when a hard coat layer is formed.

  The hard coat layer can be formed by a method in which an alkoxysilane or polysilazane solution is applied and then heated and cured. Further, an ultraviolet curable acrylic paint or a cured film of melamine crosslinking can be used.

  Furthermore, the antireflection film of the present invention may be applied on a base film (for example, a TAC film) treated with a coating agent mixed with fine particles as a matting agent, that is, an antiglare (AG) treatment. . Thereby, an antireflection film with low gloss and low reflection can be obtained, and it is preferable to use it for an LCD or the like because a clearer image can be obtained.

  The antireflection film of the present invention has a high fluorine content and a low surface contact angle, and itself has water repellency, non-adhesiveness, and antifouling properties, and can have both antireflection and antifouling layers. .

  Furthermore, a fluorine-containing polyether compound can be added to impart antifouling properties to the antireflection layer. In that case, it is necessary to determine the addition amount in consideration of deterioration of mechanical properties and white turbidity due to phase separation from the fluorine-containing polymer. If the terminal is a carboxyl group, a blocked carboxyl group, a hydroxyl group, an epoxy group, an alkoxysilane group, a (meth) acryloyl group or an α-fluoroacryloyl group, it becomes easy to be fixed in the coating (Experimental Examples 33 and 34, 35). The same effect can be obtained by applying the same polyether compound to the surface of an antireflection film (a film before or after curing) formed in advance.

  As a method of forming a thin film of a curable fluorinated polymer, a dispersion of a curable fluorinated polymer is applied, dried, and then fired as necessary to form a film, and a solution (uniform solution) is applied. There is a way to dry. Solution coating is preferred because it is easy to form a thin film. At that time, a known coating method can be employed if the film thickness can be sufficiently controlled. For example, a roll coating method, a micro gravure coating method, a gravure coating method, a flow coating method, a bar coating method, a spray coating method, a die coating method, a spin coating method, or a dip coating method can be employed. Among these methods, an optimum coating method is determined in consideration of the balance of productivity, film thickness controllability, yield, and the like. After an antireflection film is formed on a film, sheet, etc., it may be attached to a substrate.

  Also in the present invention, a silane compound may be added to improve the adhesion of the antireflection film to the substrate. The amount of the silane compound added to the coating may be about several weight percent. In addition, treating the substrate surface with a silane compound is also effective for improving adhesion. In any case in the present invention, since the silane compound hardly increases the refractive index of the cured film, the adverse effect on the antireflection effect is very small.

  Next, the present invention will be described with reference to experimental examples, but the present invention is not limited to such experimental examples.

Synthesis Example 1 (Synthesis of fluorinated allyl ether homopolymer having OH group)
In a 100 ml glass four-necked flask equipped with a stirrer and a thermometer, perfluoro- (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonenol) was added.

20.4g

After adding 21.2 g of the 8.0 wt% perfluorohexane solution and sufficiently purging with nitrogen, the mixture was stirred at 20 ° C. for 24 hours under a nitrogen stream to produce a highly viscous solid.

  The obtained solid dissolved in diethyl ether was poured into perfluorohexane, separated and vacuum dried to obtain 17.6 g of a colorless and transparent polymer.

When this polymer was analyzed by ¹⁹ F-NMR, ¹ H-NMR analysis, and IR analysis, it was a fluorine-containing polymer comprising only the structural unit of the fluorine-containing allyl ether and having a hydroxyl group at the end of the side chain. The number average molecular weight measured by GPC analysis using tetrahydrofuran (THF) as a solvent was 9000, and the weight average molecular weight was 22,000.

Experimental Example 1 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
In a 200 ml four-necked flask equipped with a reflux condenser, thermometer, stirrer, and dropping funnel, 80 ml of diethyl ether, 5.0 g of the hydroxyl group-containing fluorinated allyl ether homopolymer obtained in Synthesis Example 1, and pyridine 1 0.0 g was charged and ice-cooled to 5 ° C or lower.

While stirring under a nitrogen stream, 1.0 g of α-fluoroacrylic acid fluoride: CH ₂ ═CFCOF dissolved in 20 ml of diethyl ether was added dropwise over about 30 minutes.

  After completion of the dropwise addition, the temperature was raised to room temperature and stirring was continued for 4.0 hours.

  The ether solution after the reaction was put in a separatory funnel, washed with water, washed with 2% hydrochloric acid, washed with 5% NaCl, and further washed with water, dried over anhydrous magnesium sulfate, and the ether solution was separated by filtration.

When this ether solution was examined by ¹⁹ F-NMR analysis,

It was a copolymer.

Was applied to NaCl plate, was IR analysis what was cast film at room temperature, carbon - absorption of a carbon-carbon double bonds in 1661Cm ^-1, absorption of C = O group was observed at 1770 cm ^-1.

Experimental Example 2 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
α-Fluoroacrylic acid fluoride: A fluorine-containing curable polymer (ether solution) was synthesized in the same manner as in Experimental Example 1 except that 0.65 g of CH ₂ ═CFCOF and 1.0 g of pyridine were used.

^{By 19} F-NMR

It was a copolymer.

  In the IR analysis, the absorption of the carbon-carbon double bond and the C═O group was confirmed at the same positions as in Experimental Example 1.

Experimental Example 3 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
α-Fluoroacrylic acid fluoride: A fluorine-containing curable polymer (ether solution) was synthesized in the same manner as in Experimental Example 1 except that 0.35 g of CH ₂ ═CFCOF and 0.3 g of pyridine were used.

^{By 19} F-NMR

It was a copolymer.

  In the IR analysis, both the carbon-carbon double bond and the C═O group absorption were observed at the same positions as in Experimental Example 1.

Experimental Example 4
(1) Preparation of fluorine-containing resin composition for coating After adding methyl ethyl ketone (MEK) to the fluorine-containing polymer (ether solution) having an α-fluoroacryloyl group obtained in Experimental Example 1, the ether was distilled off by an evaporator. The polymer concentration was adjusted to 8.0% by weight.

  1.7 g of a solution in which 2-hydroxy-2-methylpropiophenone was dissolved in MEK at a concentration of 1% by weight as an active energy ray curing initiator was added to 10 g of the obtained polymer solution.

(2) Preparation of antireflection film The coating composition was coated on an untreated acrylic plate at 1000 to 2000 revolutions at room temperature with a spin coater and dried at 50 ° C for 5 minutes. At this time, the rotation speed of the spin coater was adjusted so that the film thickness after drying was 90 to 110 nm.

(Light irradiation)
A high-pressure mercury lamp was used for the dried film, and ultraviolet rays were irradiated at an intensity of 3000 mJ / cm ² U at room temperature.

(3) Measurement of refractive index of fluorine-containing curable polymer 8% MEK solution of fluorine-containing curable polymer (polymer solution before adding a curing catalyst in the above (1)) is applied onto a PET film using an applicator. After drying, the film was applied to a thickness of about 100 μm, dried at 50 ° C. for 10 minutes, then the cast film obtained from the PET film was peeled off, and the refractive index for light having a wavelength of 550 nm at 25 ° C. using an Abbe refractometer Was measured. The results are shown in Table 1.

(4) Measurement of refractive index of cured film The coating composition prepared in (1) was applied on an aluminum foil using an applicator so that the film thickness was about 100 μm, and dried at 50 ° C. for 10 minutes. After irradiating light in the same manner as in (2), the aluminum foil was dissolved in dilute hydrochloric acid to obtain a sample film. The refractive index of the obtained cured film was measured in the same manner as in the above (4).

(5) Measurement of single-sided reflectance The acrylic plate on which the antireflection film obtained in (2) was applied was set in a visible ultraviolet spectrometer equipped with a 5 ° regular reflection unit, and the reflectance was measured for light having a wavelength of 550 nm.

(6) Evaluation of physical properties of antireflection film The following physical properties of the antireflection film obtained in (2) were evaluated.

(I) Dryness to touch The presence or absence of stickiness was evaluated by touch according to JIS K4500.

Evaluation,
○: No stickiness
X: There was stickiness.

(Ii) Pencil hardness Measured according to JIS K5400.

(Iii) Solvent resistance The state (dissolution or peeling) of the coating film surface after rubbing the coating film surface with a cotton cloth impregnated with ethyl acetate was evaluated.

  No change was indicated by ○, and dissolution or peeling was indicated by ×.

  The case where acetone was used as a solvent was evaluated in the same manner.

(Iv) Abrasion resistance A cotton cloth (BEMCOT (registered trademark) M-3 manufactured by Asahi Chemical Co., Ltd.) was attached to a rubbing tester, and 100 reciprocal antireflection films were rubbed with a load of 100 gf / cm ² . The state of the film at that time was observed.

Evaluation,
○: No change
Δ: Some scratches,
X: The film was peeled off and there was a portion where the base was visible.

Experimental Examples 5-6
Coating was conducted in the same manner as in Experimental Example 4 except that Experimental Example 2 (Experimental Example 5) and Experimental Example 3 (Experimental Example 6) were used in place of the fluoropolymer having an α-fluoroacryloyl group obtained in Experimental Example 1. Preparation of the composition, preparation of an antireflection film, and evaluation of the coating film were performed. The results are shown in Table 1.

Experimental Example 7
In the production of the antireflection film of Experimental Example 4, an antireflection film was produced and evaluated for physical properties in the same manner as in Experimental Example 4 except that light irradiation was not performed. The results are shown in Table 1.

Experimental Example 8
The single-sided reflectance was measured for an unpainted acrylic board. The results are shown in Table 1.

Experimental Examples 9 to 12 (Confirmation of curing reactivity by IR analysis)
(1) Preparation of coating fluorine-containing resin composition Using the fluorine-containing curable polymer obtained in Experimental Example 1, the same operation as in Experimental Example 4 was performed, and the polymer concentrations and active energy ray curing initiators shown in Table 2 were used. Each coating composition was prepared to an amount.

(2) Production of IR analysis film The coating composition described above was applied to a PET film using an applicator so that the film thickness after drying was about 100 μm, dried at 50 ° C. for 5 minutes, and then obtained from the PET film. The film was peeled off to obtain a cast film.

(3) Measurement of curing reactivity by IR analysis When IR analysis of the above film was performed, absorption of a carbon-carbon double bond in the polymer was observed at 1661 cm ^-1 .

  Focusing on the absorption of this carbon-carbon double bond, the change in absorption intensity after light irradiation was observed. The curing reaction rate was measured according to the following formula.

  Using a high-pressure mercury lamp, ultraviolet irradiation was performed at room temperature at the irradiation dose shown in Table 2, and the curing reaction rate represented by the above formula was calculated by changing the irradiation dose. The results are shown in Table 2.

Experimental Example 13 (Synthesis of fluorine-containing curable polymer having α-fluoroacryl group)
A fluorine-containing curable polymer (ether solution) was synthesized in the same manner as in Experimental Example 1 except that 2.0 g of α-fluoroacrylic acid fluoride (CH ₂ = CFCOF) and 2.0 g of pyridine were used.

When this ether solution was examined by ¹⁹ F-NMR analysis,

It was a copolymer.

  In the IR analysis, the absorption of the carbon-carbon double bond and the C═O group was confirmed at the same positions as in Experimental Example 1.

Experimental Examples 14 to 16 (Confirmation of curing reactivity by IR analysis)
(1) Preparation of coating fluorine-containing resin composition Using the fluorine-containing curable polymer obtained in Experimental Example 13, the same operation as in Experimental Example 4 was performed, and the polymer concentrations and active energy ray curing initiators shown in Table 3 were used. Coating compositions were prepared so as to have the same amount of active energy ray curing initiator.

(2) Production of IR analysis film The film was produced in the same manner as in Experimental Example 9.

(3) Measurement of curing reactivity by IR analysis In the same manner as in Experimental Example 9, the curing reaction rate when irradiated with a light irradiation amount of 1500 mJ / cm ² was calculated. The results are shown in Table 3.

Experimental Example 17
In addition to the coating composition obtained in Experimental Example 14, as a curing agent

Was added so that it might become 20 weight% with respect to a polymer, and the fluorine-containing resin composition for a coating was manufactured.

  Using this resin composition, an IR analysis film was prepared in the same manner as in Experimental Example 14, and the curing reactivity was measured. The results are shown in Table 3.

Synthesis Example 2 (Synthesis of fluorinated allyl ether homopolymer having OH group)
In Synthesis Example 1, 20.0 g of perfluoro- (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonenol) was obtained.

The obtained polymer was purified in the same manner as in Synthesis Example 1 except that 10.0 g of an 8.0 wt% perfluorohexane solution was used to obtain 18.2 g of a colorless and transparent polymer.

When this polymer was analyzed by ¹⁹ F-NMR, ¹ H-NMR analysis, and IR analysis, it was a fluorine-containing polymer comprising only the structural unit of the fluorine-containing allyl ether and having a hydroxyl group at the end of the side chain. The number average molecular weight measured by GPC analysis using tetrahydrofuran (THF) as a solvent was 30000, and the weight average molecular weight was 59000.

Synthesis Example 3 (Synthesis of OH-containing fluorinated allyl ether and vinylidene fluoride copolymer)
Perfluoro (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonel) was added to a 300 ml stainless steel autoclave equipped with a valve, pressure gauge and thermometer. .2 g, 200 g of CH ₃ CCl ₂ F (HCFC-141b) and 0.16 g of 50% by weight methanol solution of dinormalpropyl peroxycarbonate (NPP) were added, and the system was cooled while cooling with a dry ice / methanol solution. The gas was sufficiently replaced with raw gas. Next, 5.8 g of vinylidene fluoride (VdF) was charged from the valve, and the reaction was performed while shaking at 40 ° C. With the progress of the reaction was reduced to 12 hours after the gauge pressure in the system from the previous reaction 4.4MPaG (4.5kgf / cm ² G) to ^{0.98MPaG (1.0kgf / cm 2 G)} .

  At this point, the unreacted monomer was released, the precipitated solid was taken out, dissolved in acetone, and then reprecipitated with a mixed solvent of hexane and toluene (50/50) to separate the copolymer. This copolymer was vacuum-dried to a constant weight to obtain 31.2 g of copolymer.

The composition ratio of this copolymer was analyzed by ¹ H-MNR analysis and ¹⁹ F-NMR analysis, whereby VdF / OH group-containing fluorine-containing allyl ether was 38/62 (mol%). Moreover, the number average molecular weight measured by GPC analysis using THF as a solvent was 12000, and the weight average molecular weight was 18000.

Experimental Example 18 (Synthesis of fluorine-containing active energy ray curing initiator)
In a 200 ml four-necked flask equipped with a reflux condenser, thermometer, stirrer and dropping funnel, 2.0 g of 2-hydroxy-2-methylpropiophenone, 1.0 g of pyridine, CF ₃ CF ₂ CHCl / CCIF ₂ g of ₂ CF ₂ CHClF mixture (HCFC-225) was charged and cooled to 5 ° C. or lower with ice.

  While stirring under a nitrogen stream,

Was added dropwise over 1 hour. After completion of the dropwise addition, stirring was continued for 4.0 hours.

  The ether solution after the reaction is put into a separatory funnel, washed with 2% hydrochloric acid and 5% NaCl, and the organic layer is separated, dried over anhydrous magnesium sulfate, and then 2.6 g of product is isolated by distillation. (62% yield).

The obtained product was examined by ¹ H-NMR analysis, ¹⁹ F-NMR analysis and IR analysis.

Met.

Experimental Example 19 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
In a 200 ml four-necked flask equipped with a reflux condenser, a thermometer, a stirring device, and a dropping funnel, methyl ethyl ketone (MEK) 40 ml, 5.0 g of the hydroxyl group-containing fluorine-containing allyl ether homopolymer obtained in Synthesis Example 2, 2.0 g of pyridine was charged and cooled to 5 ° C. or lower with ice.

  While stirring under a nitrogen stream, 1.2 g of α-fluoroacrylic acid fluoride was further added dropwise over about 30 minutes. After completion of the dropwise addition, the temperature was raised to room temperature and stirring was continued for 4.0 hours.

  The MEK solution after the reaction was put into a separatory funnel, washed with water, washed with 2% hydrochloric acid, washed with 5% NaCl, and further washed with water. The organic layer was separated, and dried over anhydrous magnesium sulfate. The polymer concentration after filtration was 10.7% by weight.

When this MEK solution was examined by ¹⁹ F-NMR analysis,

Met.

The IR analysis was carried out in the same manner as in Experimental Example 1, a carbon - absorption of a carbon-carbon double bonds to 1660 cm ^-1, absorption of C = O was observed at 1770 cm ^-1.

Experimental Example 20 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
Similar to Experimental Example 19, except that 5.0 g of the OH group-containing fluorine-containing allyl ether and VdF copolymer obtained in Synthesis Example 3 were used, 1.1 g of pyridine and 1.0 g of α-fluoroacrylic acid fluoride were used. Thus, a fluorine-containing curable polymer (MEK solution) was synthesized. The polymer concentration was 9.9% by weight.

^{By 19} F-NMR

It was a copolymer.

Experimental Example 21
(1) Preparation of coating fluorine-containing resin composition MEK was further added to the curable fluorine-containing polymer (MEK solution) obtained in Experimental Example 19 to adjust the polymer concentration to 8% by weight.

  When 2-hydroxy-2-methylpropiophenone was added to the MEK solution of the curable fluorine-containing polymer as an active energy ray curing initiator to 2.0% by weight based on the polymer, it became cloudy and compatible. I did not.

  Therefore, when the fluorine-containing active energy ray curing initiator obtained in Experimental Example 18 instead of 2-hydroxy-2-methylpropiophenone was added to 3.6% by weight based on the polymer, it was colorless and transparent. It became a solution and became compatible.

(2) Evaluation of coating composition As described in (2) to (6) of Experimental Example 4 using a coating composition containing a fluorine-containing active energy ray curing initiator (however, in (2), 1500 mJ / cm ² And the curing reaction rate at the time of light irradiation of 1500 mJ / cm ² was measured in the same manner as in Experimental Example 10. The results are shown in Table 4.

Experimental Example 22
(1) Preparation of coating fluorine-containing resin composition MEK was further added to the curable fluorine-containing polymer (MEK solution) obtained in Experimental Example 20 to adjust the polymer concentration to 8% by weight.

  When 2-hydroxy-2-methylpropiophenone was added to the MEK solution of the curable fluorine-containing polymer as an active energy ray curing initiator so as to be 6.7% by weight based on the polymer, a colorless transparent solution was obtained. It was compatible.

(2) Evaluation of coating composition The same evaluation as in Experimental Example 21 was performed using the obtained coating composition. The results are shown in Table 4.

Synthesis Example 4 (Synthesis of homopolymer of fluorine-containing allyl ether having OH group)
In a 100 ml glass four-necked flask equipped with a stirrer and a thermometer, perfluoro- (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonenol) was added. 20.8g

After adding 2.2 g of an 8.0 wt% perfluorohexane solution and thoroughly purging with nitrogen, the mixture was stirred at 20 ° C. for 24 hours under a nitrogen stream to produce a highly viscous solid.

  A solution obtained by dissolving the obtained solid in diethyl ether was poured into perfluorohexane, separated and vacuum dried to obtain 19.2 g of a colorless and transparent polymer.

When this polymer was analyzed by ¹⁹ F-NMR, ¹ H-NMR analysis, and IR analysis, it was a fluorine-containing polymer comprising only the structural unit of the fluorine-containing allyl ether and having a hydroxyl group at the end of the side chain. The number average molecular weight measured by GPC analysis using tetrahydrofuran (THF) as a solvent was 72,000, and the weight average molecular weight was 118,000.

Experimental Example 23 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
In a 200 ml four-necked flask equipped with a reflux condenser, thermometer, stirrer, and dropping funnel, 50 ml of methyl ethyl ketone (MEK), 5.0 g of the hydroxyl group-containing fluorine-containing allyl ether homopolymer obtained in Synthesis Example 4, 2.5 g of pyridine was charged and ice-cooled to 5 ° C. or lower.

While stirring under a nitrogen stream, 2.5 g of α-fluoroacrylic acid fluoride: CH ₂ = CFCOF dissolved in 10 ml of MEK was added dropwise over about 10 minutes.

  After completion of the dropwise addition, the temperature was raised to room temperature and stirring was continued for 2.0 hours.

  After the reaction, the MEK solution is put into a separatory funnel, washed with water, washed with 2% hydrochloric acid, washed with 5% NaCl, and further washed with water, dried over anhydrous magnesium sulfate, and then separated by filtration. Got. The polymer concentration was 13% by weight.

As a result of analyzing this MEK solution by ¹⁹ F-NMR,

It was a copolymer.

Was applied to NaCl plate, was IR analysis what was cast film at room temperature, carbon - absorption of a carbon-carbon double bonds in 1661Cm ^-1, absorption of C = O group was observed at 1770 cm ^-1.

Experimental Example 24
(1) Preparation of coating fluorine-containing resin composition MEK was added to the fluorine-containing polymer solution having an α-fluoroacryloyl group obtained in Experimental Example 23 to dilute it, and the polymer concentration was adjusted to 5.0 wt%.

  1.2 g of a solution obtained by dissolving 2-hydroxy-2-methylpropiophenone in MEK at a concentration of 1% by weight as an active energy ray curing initiator was added to 10 g of the obtained polymer solution to obtain a uniform solution.

(2) Preparation of antireflection film The coating composition was coated on an untreated acrylic plate at 1000 to 2000 revolutions at room temperature with a spin coater and dried at 50 ° C for 5 minutes. At this time, the rotation speed of the spin coater was adjusted so that the film thickness after drying was 90 to 110 nm.

(Light irradiation)
A high-pressure mercury lamp was used for the dried film, and the film was irradiated with ultraviolet rays at an intensity of 1500 mJ / cm ² U at room temperature.

(3) Measurement of refractive index of fluorine-containing curable polymer The fluorine-containing polymer solution having an α-fluoroacryloyl group obtained in Experimental Example 23 was concentrated to obtain a 50% solution on a PET film using an applicator. The film thickness after drying is about 100 μm, dried at 50 ° C. for 10 minutes, then the cast film obtained from the PET film is peeled off, and light having a wavelength of 550 nm at 25 ° C. using an Abbe refractometer The refractive index was measured. The results are shown in Table 5.

(4) Measurement of refractive index of cured film The fluoropolymer solution having an α-fluoroacryloyl group obtained in Experimental Example 23 was concentrated to give a 50% solution to 2 g of 2-hydroxy- as an active energy ray curing initiator. 0.01 g of 2-methylpropiophenone was added, and this was applied on an aluminum foil using an applicator so that the film thickness after drying was about 100 μm, and dried at 50 ° C. for 10 minutes. After irradiating light in the same manner as in (2), the aluminum foil was dissolved in dilute hydrochloric acid to obtain a sample film. The refractive index of the obtained cured film was measured in the same manner as (3) above. The results are shown in Table 5.

(5) Measurement of single-sided reflectance The acrylic plate on which the antireflection film obtained in (2) was applied was set in a visible ultraviolet spectrometer equipped with a 5 ° regular reflection unit, and the reflectance was measured for light having a wavelength of 550 nm. The results are shown in Table 5.

(6) Evaluation of physical properties of antireflection film The following physical properties of the antireflection film obtained in (2) were evaluated. The results are shown in Table 5.

(I) Pencil hardness Measured according to JIS K5400.

(Ii) Solvent resistance The state (dissolution or peeling) of the coating film surface after rubbing the coating film surface with a cotton cloth impregnated with ethyl acetate was evaluated.

  No change was indicated by ○, and dissolution or peeling was indicated by ×.

  The case where acetone was used as a solvent was evaluated in the same manner.

(Iii) Abrasion resistance A cotton cloth (BEMCOT (registered trademark) M-3 manufactured by Asahi Chemical Co., Ltd.) was attached to a rubbing tester, and 100 reciprocal antireflection films were rubbed with a load of 100 gf / cm ² . The state of the film at that time was observed.

Evaluation,
○: No change
Δ: Some scratches,
X: The film was peeled off and there was a portion where the base was visible.

(Iv) Scratch resistance The state of the coating film surface after rubbing the coating film surface with steel wool # 0000 was observed.

Evaluation,
○: No change
△: Some scratches are seen,
X: A lot of large scratches are formed, or the film is peeled off and the base is visible.
It was.

Experimental Examples 25-27
The coating composition obtained in (1) of Experimental Example 24 was used as a curing agent.

Was added so as to be 10% by weight (Experimental Example 25), 30% by weight (Experimental Example 26), and 50% by weight (Experimental Example 27). Using each coating composition, an antireflection film was produced in the same manner as in Experiment Example 24 (2), (4) measurement of the refractive index of the cured film, (5) measurement of single-sided reflectance (6) antireflection The physical properties of the antireflection film were evaluated in the same manner as the physical properties of the film. The results are shown in Table 5.

Experimental Example 28
(1) Preparation of coating fluorine-containing resin composition Curing agent used in Experimental Example 25

To 0.5 g, 10 g of MEK was added and dissolved, and 1.2 g of a solution in which 2-hydroxy-2-methylpropiophenone was dissolved in MEK at a concentration of 1% by weight was added thereto as an active energy ray curing initiator. A homogeneous solution was obtained. Using this coating composition, an antireflection film was produced in the same manner as in Experiment Example 24 (2), (4) measurement of the refractive index of the cured film, (5) measurement of single-sided reflectance, and (6) antireflection. The physical properties of the antireflection film were evaluated in the same manner as the physical properties of the film. The results are shown in Table 5.

Experimental Example 29
As a curing agent

The coating fluorine-containing resin composition obtained in the same manner as in Experimental Example 17 except that 30 wt% was added to the polymer to add MEK to obtain a 5 wt% MEK solution. Using this, an antireflection film was produced in the same manner as (2) of Experimental Example 24, (4) measurement of the refractive index of the cured film, (5) measurement of the single-sided reflectance, and (6) physical property evaluation of the antireflection film. In the same manner as above, physical properties of the antireflection film were evaluated. The results are shown in Table 5.

Experimental Example 30 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
In a 200 ml four-necked flask equipped with a reflux condenser, thermometer, stirrer, and dropping funnel, 50 ml of MEK, 5.0 g of the OH group-containing fluorinated allyl ether and VdF copolymer obtained in Synthesis Example 3, and pyridine were added. The mixture was charged with 2.2 g and cooled to 5 ° C. or lower.

While stirring under a nitrogen stream, 2.0 g of α-fluoroacrylic acid fluoride: CH ₂ ═CFCOF dissolved in 10 ml of MEK was added dropwise over about 10 minutes.

  After completion of dropping, the temperature was raised to room temperature and stirring was continued for 3.0 hours.

  After the reaction, the MEK solution was put into a separatory funnel, washed with water, washed with 2% hydrochloric acid, washed with 5% NaCl, and further washed with water, dried over anhydrous magnesium sulfate, and then separated by filtration. The polymer concentration was 13.0% by weight.

The MEK solution was examined by ¹⁹ F-NMR analysis.

It was a copolymer.

Was applied to NaCl plate, was IR analysis what was cast film at room temperature, carbon - absorption of a carbon-carbon double bonds in 1661Cm ^-1, absorption of C = O group was observed at 1770 cm ^-1.

Experimental Example 31
Instead of the fluorine-containing polymer having an α-fluoroacryloyl group obtained in Experimental Example 23, Experimental Example 30 was used, and instead of 2-hydroxy-2-methylpropiophenone as an active energy ray curing initiator, Experimental Example (1) Preparation of coating composition, (2) Preparation of antireflection film, evaluation of coating film were carried out in the same manner as in Experimental Example 24 except that the fluorine-containing energy ray curing initiator obtained in 18 was used. . The results are shown in Table 5.

Experimental Example 32
The coating composition obtained in (1) of Experimental Example 31 was used as a curing agent.

Was added so that it might become 10 weight% with respect to a polymer, and the composition for coating was manufactured. Using this coating composition, an antireflection film was produced in the same manner as in Experiment Example 24 (2), (4) measurement of the refractive index of the cured film, (5) measurement of single-sided reflectance, and (6) antireflection. The physical properties of the film were evaluated in the same manner. The results are shown in Table 5.

1) Cross-linking agent (tetrafunctional)

2) Fluorine-containing energy ray curing initiator

3) Cross-linking agent (bifunctional)

Experimental Example 33 (Synthesis of perfluoropolyether α-fluoroacrylate)
In a 500 ml four-necked flask equipped with a reflux condenser, a thermometer, a stirrer, and a dropping funnel, a linear perfluoropolyether alcohol CF ₃ CF ₂ CF ₂ O (CF ₂ CF ₂ CF ₂ O) having an average molecular weight of 3800 was added. _n CF ₂ CF ₂ CH ₂ OH (n≈20)
18 g, 1.0 g of pyridine, 125 g of 1,1,1,3,3,3-hexafluorometaxylene were charged and cooled to 5 ° C. or lower with ice.

While stirring in a nitrogen stream, about 10 was prepared by further dissolving 0.84 g of α-fluoroacrylic acid fluoride: CH ₂ ═CFCOF in 5 ml of 1,1,1,3,3,3-hexafluorometaxylene. Added dropwise over a period of minutes.

  After completion of dropping, raise the temperature to room temperature. Stirring was continued for 4 hours.

  The ether solution after the reaction was put into a separatory funnel, washed with water, washed with 2% hydrochloric acid, washed with 5% NaCl, and further washed with water, dried over anhydrous magnesium sulfate, and then separated by filtration. After the solvent was distilled off from the filtrate by an evaporator, it was further dried for 6 hours in a vacuum while being heated to 70 ° C. to obtain a colorless and transparent liquid having a high viscosity.

The obtained product was examined by ¹ H-NMR analysis, ¹⁹ F-NMR analysis and IR analysis.

Met.

Experimental Examples 34 and 35 (Improvement of surface properties by perfluoropolyether group (PFPE) -containing compound)
(1) Preparation of fluorinated resin composition for coating The MEK solutions of the fluorinated polymer having α-fluoroacryloyl groups obtained in Experimental Example 23 (Experimental Example 34) and Experimental Example 30 (Experimental Example 35) were respectively concentrated. ₃ g of a CF ₃ CF ₂ CHCl / CClF ₂ CF ₂ CHClF mixture (HCFC-225), 4 g of MIBK and 6 g of ClCF ₂ CClFCF ₂ CCl ₂ F (CFC-316) were added to 2 g of MEK solution adjusted to a concentration of 50% by weight. . Further, 1.0 g of a solution in which the perfluoropolyether α-fluoroacrylate obtained in Experimental Example 33 was dissolved in HCFC225 at a concentration of 1.0% by weight was added.

  1 g of a solution in which a fluorine-containing active energy ray curing initiator was dissolved in HCFC225 at a concentration of 10% by weight as an active energy ray curing initiator was added to the obtained polymer solution to obtain a uniform solution.

(2) Production of antireflection film The coating composition was coated on an untreated acrylic plate at 2000 to 5000 revolutions at room temperature with a spin coater and dried at 50 ° C for 5 minutes. At this time, the rotation speed of the spin coater was adjusted so that the film thickness after drying was 90 to 110 nm.

(Light irradiation)
A high-pressure mercury lamp was used for the dried film, and the film was irradiated with ultraviolet rays at an intensity of 1500 mJ / cm ² U at room temperature.

(3) Measurement of single-sided reflectance The acrylic plate on which the antireflection film obtained in (2) was applied was set in a visible ultraviolet spectrometer equipped with a 5 ° regular reflection unit, and the reflectance was measured for light having a wavelength of 550 nm. The results are shown in Table 6.

(4) Evaluation of physical properties of antireflection film The following physical properties of the antireflection film obtained in (2) were evaluated. The results are shown in Table 6.

(I) Pencil hardness Measured according to JIS K5400.

(Ii) Contact angle Using a contact angle meter, the contact angles of pure water and n-hexadecane were measured.

Experimental Examples 36 and 37
The antireflection film after light irradiation obtained in (2) (Experimental Example 36) of Experimental Example 24 and (2) (Experimental Example 37) of Experimental Example 31 was contacted in the same manner as in (4) of Experimental Example 34. The corner was measured. The results are shown in Table 6.

Synthesis Example 5 (Synthesis of fluorinated allyl ether homopolymer (long side chain) having OH group)
In a 100 ml glass four-necked flask equipped with a stirrer and a thermometer,
CH ₂ = CFCF ₂ (OCF (CF ₃ ) CF ₂ ) ₃ OCF (CF ₃ ) CH ₂ OH
10.0g

After adding 6.2 g of an 8.0 wt% perfluorohexane solution and thoroughly purging with nitrogen, the mixture was stirred at 20 ° C. for 15 hours under a nitrogen stream to produce a highly viscous solid.

  The obtained solid dissolved in diethyl ether was poured into perfluorohexane, separated and vacuum dried to obtain 7.3 g of a colorless and transparent polymer.

When this polymer was analyzed by ¹⁹ F-NMR, ¹ H-NMR analysis, and IR analysis, it was a fluorine-containing polymer comprising only the structural unit of the fluorine-containing allyl ether and having a hydroxyl group at the end of the side chain. The number average molecular weight measured by GPC analysis using tetrahydrofuran (THF) as a solvent was 24,000, and the weight average molecular weight was 79000.

Experimental Example 38 (Synthesis of fluorine-containing curable polymer (long side chain) having α-fluoroacryloyl group)
In a 200 ml four-necked flask equipped with a reflux condenser, a thermometer, a stirrer, and a dropping funnel, 50 ml of methyl ethyl ketone, 3.0 g of the hydroxyl group-containing fluorinated allyl ether homopolymer obtained in Synthesis Example 5, 4 g was charged and cooled to 5 ° C. or lower with ice.

While stirring under a nitrogen stream, a solution of 0.55 g of α-fluoroacrylic acid fluoride: CH ₂ ═CFCOF dissolved in 10 ml of methyl ethyl ketone was added dropwise over about 10 minutes.

  After completion of the dropwise addition, the temperature was raised to room temperature and stirring was continued for 2.0 hours.

  The ether solution after the reaction was put into a separatory funnel, washed with water, washed with 2% hydrochloric acid, washed with 5% NaCl, and further washed with water, dried over anhydrous magnesium sulfate, and the methyl ethyl ketone solution was separated by filtration.

When this methyl ethyl ketone solution was examined by ¹⁹ F-NMR analysis,

It was a copolymer.

  In the IR analysis, absorption of the carbon-carbon double bond and the C═O group was confirmed at the same positions as in Experimental Example 23.

Experimental Example 39
An antireflection film was prepared in the same manner as in Experimental Examples 24 (1) and (2) except that Experimental Example 38 was used instead of the fluoropolymer having an α-fluoroacryloyl group obtained in Experimental Example 23. The physical properties of the antireflection film were evaluated in the same manner as in Experimental Examples 34 (3) and (4). The results are shown in Table 6.

Synthesis Example 6 (Synthesis of copolymer of fluorine-containing allyl ether having OH group and fluorine-containing allyl ether having a methyl ester structure at the terminal)
In a 100 ml glass four-necked flask equipped with a stirrer and a thermometer, perfluoro- (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonenol) was added. 9.6 g and CH ₂ ═CFCF ₂ OCF (CF ₃ ) CF ₂ OCF (CF ₃ ) COOCH ₃
9.6g, and stir well,

After adding 2.0 g of an 8.0 wt% perfluorohexane solution and thoroughly purging with nitrogen, the mixture was stirred at 20 ° C. for 20 hours under a nitrogen stream to produce a highly viscous solid.

  A solution obtained by dissolving the obtained solid in acetone was poured into an HCFC225 / n-hexane = 1/1 solution, separated and vacuum dried to obtain 15.5 g of a colorless and transparent polymer.

This polymer was analyzed by ¹⁹ F-NMR, ¹ H-NMR analysis, and IR analysis. As a result, the fluorine-containing allyl ether having a hydroxyl group and the fluorine-containing allyl ether having a methyl ester terminal were 42/58 mol%. It was. Moreover, the number average molecular weight measured by GPC analysis using tetrahydrofuran (THF) as a solvent was 72000, and the weight average molecular weight was 117000.

Experimental Example 40 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
In a 200 ml four-necked flask equipped with a reflux condenser, thermometer, stirrer, and dropping funnel, 50 ml of methyl ethyl ketone, 3.0 g of the hydroxyl group-containing fluorine-containing allyl ether obtained in Synthesis Example 6, and 0.6 g of pyridine were added. In the same manner as in Experimental Example 23, 1.0 g of α-fluoroacrylic acid fluoride: CH ₂ = CFCOF dissolved in 10 ml of MEK was added dropwise to synthesize a fluorinated curable polymer (MEK solution).

^{By 19} F-NMR

It was a copolymer.

  In the IR analysis, absorption of the carbon-carbon double bond and the C═O group was confirmed at the same positions as in Experimental Example 23.

Experimental Example 41
An antireflection film was prepared in the same manner as in Experimental Examples 31 (1) and (2) except that Experimental Example 40 was used instead of the fluoropolymer having an α-fluoroacryloyl group obtained in Experimental Example 30. Were evaluated in the same manner as in Experimental Example 34 (3) and (4). The results are shown in Table 6.

1) PFPE compound

2) Fluorine-containing energy ray curing initiator

Experimental Examples 42 and 43 (Preparation of fluororesin composition with improved coating properties on PET film)
The MEK solutions of fluoropolymers having α-fluoroacryloyl groups obtained in Experimental Example 23 (Experimental Example 42) and Experimental Example 30 (Experimental Example 43) were each concentrated and adjusted to a concentration of 50% by weight. 14 g of MIBK and 4 g of 2,2,3,3, tetrafluoropropanol (HCF ₂ CF ₂ CH ₂ OH) were added to 2 g of these MEK solutions, respectively, and fluorine-containing active energy ray curing was started as an active energy ray curing initiator. 1.0 g of a solution in which the agent was dissolved in HCFC225 at a concentration of 10% by weight was added to obtain a uniform solution.

Experimental Examples 44 and 45 (Evaluation of applicability to PET film)
The coating composition obtained in Experimental Example 42 (Experimental Example 44) and Experimental Example 43 (Experimental Example 45) was applied to an untreated PET film to a thickness of 2 μm using a doctor blade and allowed to air dry at room temperature. The state was observed.
Evaluation,
○: Dried in a uniform film thickness and no interference fringes are observed after drying. Δ: Dried in a uniform film thickness, but some interference fringes are observed after drying. It was repelled and many concentric interference fringes were found after drying. The results are shown in Table 7.

Experimental Examples 46 and 47
MEK is added to the fluoropolymer solution having α-fluoroacryloyl groups obtained in Experimental Example 23 (Experimental Example 46) and Experimental Example 30 (Experimental Example 47) to dilute the polymer concentration to 5.0% by weight. did.

  To 20 g of the obtained polymer solution, 1.0 g of a solution obtained by dissolving the fluorine-containing energy ray curing initiator obtained in Experimental Example 18 in MEK at a concentration of 10% by weight as an active energy ray curing initiator was added, and uniform. Into solution. Using these solutions, the same evaluation as in Experimental Example 44 was performed. The results are shown in Table 7.

1) Fluorine-containing energy ray curing initiator

Synthesis Example 7 (Synthesis of copolymer of fluorinated allyl ether having OH group and tetrafluoroethylene)
10 perfluoro (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonel) was added to a 100 ml stainless steel autoclave equipped with a valve, pressure gauge and thermometer. 0.0 g, 50 g of CH ₃ CCl ₂ F (HCFC-141b) and 0.1 g of a 50 wt% methanol solution of dinormalpropyl peroxycarbonate (NPP) were added, and the system was cooled while cooling with a dry ice / methanol solution. The gas was sufficiently replaced with raw gas. Next, 8.0 g of tetrafluoroethylene (TFE) was charged from the valve and reacted for 14 hours while shaking at 40 ° C., after which the unreacted monomer was released to complete the reaction.

  The precipitated solid was taken out, dissolved in acetone, and then reprecipitated with a mixed solvent of hexane and HCFC-225 (20/80) to separate the copolymer. This copolymer was vacuum-dried until a constant weight was obtained, to obtain 9.3 g of a copolymer.

The composition ratio of this copolymer was analyzed by ¹ H-MNR analysis and ¹⁹ F-NMR analysis, whereby the TFE / OH group-containing fluorine-containing allyl ether was 48/52 (mol%). The number average molecular weight measured by GPC analysis using THF as a solvent was 24,000, and the weight average molecular weight was 36100.

Synthesis Example 8 (Synthesis of OH-containing fluorine-containing allyl ether and chlorotrifluoroethylene copolymer)
10 perfluoro (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonel) was added to a 100 ml stainless steel autoclave equipped with a valve, pressure gauge and thermometer. 0.0 g, 50 g of CH ₃ CCl ₂ F (HCFC-141b) and 0.1 g of a 50 wt% methanol solution of dinormalpropyl peroxycarbonate (NPP) were added, and the system was cooled while cooling with a dry ice / methanol solution. The gas was sufficiently replaced with raw gas. Next, 5.8 g of chlorotrifluoroethylene (CTFE) was charged from the valve and reacted for 20 hours while shaking at 40 ° C., and then the unreacted monomer was released to complete the reaction.

  The precipitated solid was taken out, dissolved in acetone, and then reprecipitated with a mixed solvent of hexane and HCFC-141b (50/50) to separate the copolymer. This copolymer was vacuum-dried until a constant weight was obtained, to obtain 5.7 g of a copolymer.

The composition ratio of this copolymer was analyzed by ¹ H-MNR analysis and ¹⁹ F-NMR analysis, whereby the CTFE / OH group-containing fluorine-containing allyl ether was 35/65 (mol%). The number average molecular weight measured by GPC analysis using THF as a solvent was 10500, and the weight average molecular weight was 7200.

Experimental Example 48 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
In a 200 ml four-necked flask equipped with a reflux condenser, thermometer, stirrer, and dropping funnel, 50 ml of diethyl ether, 2.0 g of the hydroxyl group-containing fluorine-containing allyl ether copolymer obtained in Synthesis Example 7, and 0.9 g of pyridine In the same manner as in Experimental Example 23, a solution of 0.9 g of α-fluoroacrylic acid fluoride: CH ₂ = CFCOF dissolved in 10 ml of diethyl ether was added dropwise to synthesize a fluorine-containing curable polymer (diethyl ether solution). did.

^{By 19} F-NMR

It was a copolymer.

  In the IR analysis, absorption of the carbon-carbon double bond and the C═O group was confirmed at the same positions as in Experimental Example 23.

Experimental Example 49 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
In a 200 ml four-necked flask equipped with a reflux condenser, a thermometer, a stirrer, and a dropping funnel, 30 ml of methyl isobutyl ketone, 3.0 g of the hydroxyl group-containing fluorine-containing allyl ether obtained in Synthesis Example 8, and 0. 7 g was charged, and in the same manner as in Experimental Example 23, 0.8 g of α-fluoroacrylic acid fluoride: CH ₂ = CFCOF dissolved in 10 ml of methyl isobutyl ketone was dropped, and a fluorine-containing curable polymer (methyl isobutyl ketone solution) was added. ) Was synthesized.

^{By 19} F-NMR

It was a copolymer.

  In the IR analysis, absorption of the carbon-carbon double bond and the C═O group was confirmed at the same positions as in Experimental Example 23.

Experimental Examples 50 and 51
Instead of the fluorine-containing curable polymer obtained in Experimental Example 23, each of the fluorine-containing polymers having an α-fluoroacryloyl group obtained in Experimental Example 48 (Experimental Example 50) and Experimental Example 49 (Experimental Example 51) was used. The refractive index of the fluorine-containing curable polymer before and after curing was measured in the same manner as in (3) and (4) of Experimental Example 24. The results are shown in Table 8.

Experimental Example 52 (Synthesis of a novel fluorine-containing unsaturated compound)
Perfluoro (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanol) was added to a 200 ml four-necked flask equipped with a reflux condenser, a thermometer, a stirrer, and a dropping funnel. :

20.4 g, diethyl ether 80 ml and pyridine 4.3 g were charged and ice-cooled to 5 ° C. or lower.

While stirring under a nitrogen stream, a solution of 5.1 g of α-fluoroacrylic acid fluoride: CH ₂ ═CFCOF dissolved in 20 ml of diethyl ether was added dropwise over about 30 minutes.

  After completion of the dropwise addition, the temperature was raised to room temperature and stirring was continued for 4.0 hours.

  The ether solution after the reaction was poured into a large excess of water, and the organic matter was extracted with ether. The ether layer was washed with water, 2% hydrochloric acid, 5% NaCl aqueous solution, and further with water. The ether layer was dried over anhydrous magnesium sulfate, and then the ether was distilled off to obtain 23 g of an organic substance.

The obtained product was analyzed by ¹ H-NMR analysis, ¹⁹ F-NMR analysis and GC-Mass analysis.

It was confirmed that it was a novel fluorine-containing fusowa compound represented by In addition, as a result of IR analysis, two carbon - absorption of carbon double bonds 1661Cm ^-1, to 1,695 cm ^-1, the absorption of C = O group was observed at 1770 cm ^-1.

Synthesis Example 9
To a 300 ml four-necked flask equipped with a reflux condenser, a thermometer, a stirrer, and a dropping funnel, 2,3,3,5,6,6,8-pentafluoro-4,7,10-trioxa-5,8 -Bistrifluoromethyl-12,13-epoxytridec-1-ene:

46.4 g, 20 g of acetic acid and 1.0 g of triethylamine were added, and the mixture was stirred with heating at 95 to 105 ° C. for 4 hours.

  After cooling to room temperature, a solution prepared by mixing 10.0 g of 85% potassium hydroxide and 80 ml of methanol was added dropwise over about 30 minutes from the dropping funnel at room temperature. After completion of dropping, the mixture was stirred at room temperature for 5 hours.

  After completion of the reaction, 44 ml of 17% aqueous hydrochloric acid was added, the mixture was released into a large amount of water, and sodium bicarbonate was added until the aqueous layer became aqueous.

After neutralization, 5% NaHCO ₃ washing with water and further washing with water were repeated. The ether layer was dried over anhydrous magnesium sulfate, and then the ether was distilled off to obtain 29 g of an organic substance.

The obtained product was analyzed by ¹ H-NMR analysis, ¹⁹ F-NMR analysis, IR analysis, and Mass analysis according to the formula:

It was a fluorine-containing allyl ether compound which has two hydroxyl groups shown by these.

Experimental Example 53 (Synthesis of a novel fluorine-containing unsaturated compound)
In Experimental Example 52, in place of perfluoro (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanol), a mixture containing two hydroxyl groups obtained in Synthesis Example 9 was used. Fluorine allyl ether compound:

24.1 g of pyridine, 8.3 g of pyridine, and 10.2 g of α-fluoroacrylic acid fluoride: CH ₂ ═CFCOF were used in the same manner as in Experimental Example 52 to carry out the reaction and isolation procedures. Obtained.

The obtained product was analyzed by ¹ H-NMR analysis, ¹⁹ F-NMR analysis, and GC-Mass analysis.

It was the novel fluorine-containing unsaturated compound shown by these. In addition, as a result of IR analysis, two carbon - absorption of carbon double bonds 1661Cm ^-1, to 1,695 cm ^-1, the absorption of C = O group was observed at 1770 cm ^-1.

Synthesis Example 10 (Synthesis of fluorinated allyl ether homopolymer having a hydroxyl group)
In Synthesis Example 1, in place of perfluoro (1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanol), the product contains two hydroxyl groups obtained in Synthesis Example 9. Fluorine allyl ether compound:

Polymerization and polymer purification were carried out in the same manner as in Synthesis Example 1 except that 24.1 g of was used, and 13.5 g of a colorless and transparent polymer was obtained.

This polymer was analyzed by ¹ H-NMR analysis, ¹⁹ F-NMR analysis, and IR analysis. As a result, the polymer was composed of only the above-mentioned fluorine-containing allyl ether structural unit, and each side chain had two OH groups. there were.

Experimental Example 54 (Synthesis of fluorine-containing curable polymer having α-fluoroacryloyl group)
In Experimental Example 1, instead of the hydroxyl group-containing fluorine-containing allyl ether polymer obtained in Synthesis Example 1, 4.8 g of the fluorine-containing allyl ether homopolymer having an OH group in each side chain obtained in Synthesis Example 10 was used. The fluorine-containing curable polymer was synthesized in the same manner as in Experimental Example 1, except that 3.1 g of pyridine and 2.0 g of α-fluoroacrylic acid fluoride were used.

When the solution obtained by the obtained polymer was examined by ¹⁹ F-NMR analysis, the formula:

It was a polymer consisting only of structural units derived from the fluorine-containing allyl ether.

This polymer was applied to NaCl plate, was IR analysis what was cast film at room temperature, carbon - absorption of a carbon-carbon double bonds to 1660 cm ^-1, absorption of C = O group was observed at 1770 cm ^-1 However, no absorption of OH groups was observed.

Claims (24)

An antireflection film comprising a cured coating of a fluorine-containing prepolymer, wherein the fluorine-containing prepolymer is
(I) having a carbon-carbon unsaturated bond at the end of the side chain ;
( Ii) the refractive index is 1.40 or less, and
(Iii) Formula (1):

[In the formula, the structural unit M represents the formula (M):

Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf is a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having an ether bond having 2 to 100 carbon atoms; Y ¹ (Y ¹ is a carbon atom having 2 to 2 carbon atoms having an ethylenic carbon-carbon double bond at the terminal; An organic group in which 1 to 3 monovalent organic groups of 10 are bonded; a is an integer of 0 to 3; b and c are the same or different and 0 or 1) The structural unit derived from the body, the structural unit A is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M)], and the structural unit M is 0.1 to 100 mol% and 0 to 99.9 mol% of structural unit A, Molecular weight of the curable fluorine-containing polymer is 500 to 1,000,000,
An antireflection film having a cured film thickness of 0.03 to 0.5 μm. (D) The fluorine-containing prepolymer according to claim 1,
(E) a cured film obtained by photocuring a film formed by applying a coating composition comprising an active energy ray curing initiator and (f) a solvent,
An antireflection film having a cured film thickness of 0.03 to 0.5 μm. (D) The fluorine-containing prepolymer according to claim 1,
(E) an active energy ray curing initiator,
(F) a cured film obtained by photocuring a film formed by applying a coating composition comprising a solvent and (g) a curing agent,
An antireflection film having a cured film thickness of 0.03 to 0.5 μm. 4. The antireflection film according to claim 2, wherein the solvent (f) is at least one selected from the group consisting of a ketone solvent, an acetate ester solvent, an alcohol solvent and an aromatic hydrocarbon solvent. The antireflection film according to any one of claims 1 to 4, wherein the carbon-carbon unsaturated bond at the terminal of the fluorine-containing prepolymer is an ethylenic carbon-carbon double bond. 6. The antireflection film according to claim 5, wherein the carbon-carbon unsaturated bond at the terminal of the fluorine-containing prepolymer is a radical polymerizable carbon-carbon double bond. The fluorine-containing prepolymer has the formula (1-1):
-(M)-(A1)-(A2)-(1-1)
[Wherein, the structural unit M is the same structural unit as the above formula (M), and the structural unit A1 is represented by the formula (A1):

(In the formula, X ¹¹ , X ¹² and X ¹³ are H or F, X ¹⁴ is H, F, CF ₃ , h is 0 to 2, i is 0 or 1, and Rf ⁴ is fluorine containing 1 to 40 carbon atoms. An alkylene group, a fluorine-containing alkylene group having an ether bond having 2 to 100 carbon atoms, Z ¹ is —OH, —CH ₂ OH, —COOH, carboxylic acid derivative, —SO ₃ H, sulfonic acid derivative, epoxy group, cyano group A structural unit represented by formula (A2):

(Wherein X ¹⁵ , X ¹⁶ and X ¹⁸ are H or F, X ¹⁷ is H, F or CF ₃ , h1, i1, j is 0 or 1, Z ² is H, F or Cl, and Rf ⁵ is carbon. A structural unit represented by the formula (1) to (20) fluorine-containing alkylene group, a fluorine-containing alkylene group containing an ether bond having 2 to 100 carbon atoms), the structural unit M is 0.1 to 90 mol%, and the structural unit A1 Is a curable fluorine-containing polymer having a number average molecular weight of 500 to 1,000,000, comprising 0 to 99.9 mol%, structural unit A2 of 0 to 99.9 mol%, and A1 + A2 of 10 to 99.9 mol% The antireflection film according to claim 1. The antireflection film according to claim 1 or 7 , wherein at least one of Y ¹ is bonded to an end of Rf. In formula (1) or (1-1), structural unit M is represented by formula (M1):

Wherein X ¹ and X ² are the same or different and H or F; X ³ is H, F, CH ₃ or CF ₃ ; X ⁴ and X ⁵ are the same or different and H, F or CF ₃ ; Rf is a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having an ether bond having 2 to 100 carbon atoms; Y ¹ (Y ¹ is a carbon atom having 2 to 2 carbon atoms having an ethylenic carbon-carbon double bond at the terminal; An organic group in which 1 to 3 monovalent organic groups of 10 are bonded; a is an integer of 0 to 3; and c is 0 or 1). The antireflection film according to claim 1, 7 or 8 . In the formula (1) or (1-1), the structural unit M is the formula (M2):

(Wherein, Rf is ethylenic carbon Y ¹ (Y ¹ is terminated in the fluorine-containing alkyl group having ether bond of the fluorine-containing alkyl group or a 2 to 100 carbon atoms 40 carbon atoms - carbon double bonds a monovalent organic group) is 1 to 3 bound to have a structural unit M2 derived from a fluorine-containing ethylenic monomer represented by the organic group) according to claim 1, 7 or 8, wherein 2 to 10 carbon atoms Antireflection film. In the formula (1) or (1-1), the structural unit M is the formula (M3):

(Wherein, Rf is ethylenic carbon Y ¹ (Y ¹ is terminated in the fluorine-containing alkyl group having ether bond of the fluorine-containing alkyl group or a 2 to 100 carbon atoms 40 carbon atoms - carbon double bonds a monovalent organic group) is 1 to 3 bound to have a structural unit M3 derived from a fluorine-containing ethylenic monomer represented by the organic group) according to claim 1, 7 or 8, wherein 2 to 10 carbon atoms anti-reflection film. Y ¹ is the formula:

(Wherein Y ² is an alkenyl group having 2 to 5 carbon atoms or a fluorine-containing alkenyl group having an ethylenic carbon-carbon double bond at the terminal; d and e are the same or different, and 0 or 1) antireflection film according to any one of claims 1 or 7 to 11 a group. Y ¹ is the formula:
^{-O (C = O) CX 6} = CX 7 X 8
(Wherein, X ⁶ is H, F, CH ₃ or CF _3; X ⁷ and X ⁸ are the same or different, H or F) antireflective according to any one of claims 1 or 7 to 11 represented by film. In formula (1-1), the structural unit (A1) is represented by formula (A1-1):

The antireflection film according to claim 7 , wherein Rf ⁴ and Z ¹ are the same as those in the formula (A1). In formula (1-1), the structural unit (A1) is represented by formula (A1-2):

The antireflection film according to claim 7 , wherein Rf ⁴ and Z ¹ are the same as those in the formula (A1). The structural unit (A2) is tetrafluoroethylene in the formula (1-1), vinylidene fluoride, at least one of claims 7 to a structural unit derived from a monomer selected from chlorotrifluoroethylene and hexafluoropropylene The antireflection film according to any one of 15 . The structural unit M is 10 to 80 mol% in the formula (1-1), claim and a structural unit A1 1 to 60 mol% and a structural unit A2 20 to 85 mol% A1 + A2 contains 20 to 90 mol% 7 The antireflection film according to any one of to 15 . The antireflective film according to any one of claims 7 to 17 , which has a refractive index of 1.40 or less. The reflection according to claim 1 or 7 to 18 , which is soluble in at least one solvent selected from the group consisting of ketone solvents, acetate solvents, alcohol solvents and aromatic hydrocarbon solvents. Prevention film. Polyfunctional acrylate or ether in which two or more hydroxyl groups of the polyhydric alcohol having a fluorinated alkyl group which may contain an ether bond or a fluorinated alkylene group which may contain an ether bond are replaced with an acrylate group in the curing agent (g) A polyfunctional methacrylate in which two or more hydroxyl groups of a polyhydric alcohol having a fluorine-containing alkyl group which may contain a bond or a fluorine-containing alkylene group which may contain an ether bond are replaced with a methacrylate group, may contain an ether bond It is at least one selected from polyfunctional α-fluoroacrylates in which two or more hydroxyl groups of a polyhydric alcohol having a fluorine-containing alkyl group or a fluorine-containing alkylene group which may contain an ether bond are replaced with α-fluoroacrylate groups. claim 3-19 Antireflection film according to any one. 21. The antireflection film according to claim 20, wherein the curing agent (g) is at least one of polyfunctional α-fluoroacrylates. The antireflective film according to any one of claims 1 to 21 , wherein the cured film has a refractive index of 1.45 or less. An antireflection-treated article obtained by applying the antireflection film according to any one of claims 1 to 22 to a base material. The antireflective article according to claim 23 , wherein the material of the base material is one selected from the group consisting of acrylic resin, polycarbonate, polyethylene terephthalate, polyolefin, and triacetylcellulose.