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JP4031070B2 - Heavy aggregate - Google Patents

Heavy aggregate Download PDF

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Publication number
JP4031070B2
JP4031070B2 JP19137196A JP19137196A JP4031070B2 JP 4031070 B2 JP4031070 B2 JP 4031070B2 JP 19137196 A JP19137196 A JP 19137196A JP 19137196 A JP19137196 A JP 19137196A JP 4031070 B2 JP4031070 B2 JP 4031070B2
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Japan
Prior art keywords
heavy
specific gravity
aggregate
high specific
melt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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JP19137196A
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Japanese (ja)
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JPH1015523A (en
Inventor
榮治 渕上
安喜 岩部
熊夫 星野
Original Assignee
中部鋼鈑株式会社
株式会社星野産商
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/02Making special pig-iron, e.g. by applying additives, e.g. oxides of other metals
    • C21B5/023Injection of the additives into the melting part
    • C21B5/026Injection of the additives into the melting part of plastic material

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Iron (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Processing Of Solid Wastes (AREA)

Description

【0001】
【発明の属する技術分野】
本発明はセメント、プラスチック、ゴム等に添加される重量細骨材や重量粗骨材等に使用される重量骨材に関するものである。
【0002】
【従来の技術】
従来、細骨材として川砂、ケイ砂、砕砂等の天然資源が用いられて来たが、上記天然資源の確保が次第に困難となり、それに代えて電気炉酸化スラグ粒化物を細骨材として使用することが検討されている。
上記電気炉酸化スラグ粒化物は不安定な遊離石灰、遊離マグネシア、あるいは鉱物を含まず、耐久性および耐蝕性を有し、また重量が大であるから製品に制振遮音性を与える。
【0003】
【発明が解決しようとする課題】
最近、制振性、遮音性、放射線シールド性、透磁性等を有するコンクリート製品、プラスチック製品、ゴム製品、粘土製品等が脚光を浴びており、更に大重量高比重の骨材に対するニーズが高まっている。
【0004】
【課題を解決するための手段】
本発明は上記課題を解決するための手段として、電気炉酸化スラグに高比重元素およびまたは高比重元素化合物を添加溶解し、冷却化そして粒化した重量骨材を提供するものである。
【0005】
本発明において使用する高比重元素とは比重が7以上の元素であり、このような元素としては、Fe,Co,Cu,Zn,Pb等が例示され、該高比重元素の化合物としては上記元素の酸化物、水酸化物、塩化物等が例示される。望ましい高比重元素またはその化合物としては鉄、銅、鉄スクラップ、鉄酸化物、鉛ドロス等がある。
【0006】
本発明の重量骨材を製造するには、図1に示すように電気炉酸化スラグ(1) と高比重元素および/または高比重元素化合物を電気溶解炉(2) に投入し、電極(3) に通電して該スラグ(1) と高比重元素および/または高比重元素化合物を溶解し、所望なれば酸素および/または空気を吹込んで該溶解物を冷却固化粉砕する。この場合該溶解物を鋼板製の皿型容器内に通常80mm厚に注入し、水冷後クラッシャーで粉砕すれば重量粗骨材が製造される。
【0007】
また該溶解物から重量細骨材を製造するには、通常該溶解物を高速回転する羽根付きドラムに注入し、該溶解物を該羽根付きドラムによって破砕粒状化し、粒状化した該溶融物を水ミスト雰囲気中で急冷処理する方法が採られる。該羽根付きドラムは複数個配置して複数段の破砕粒状化を行なってもよい。
このようにして得られる重量細骨材は通常5mm以下の粒径を有し、粒径2.5mm以下のものは略球状であり、表面に微細な凹凸を有する優れた形状のもので粒度分布はJIS−A5005コンクリート用砕砂の規格範囲にある。
【0008】
【発明の実施の形態】
〔実施例〕
4.5トンの電気炉酸化スラグ(1) を図1に示す電気溶解炉(2) に投入し、更に鉄スクラップとして1.5トンの銑ダライを加えてランス管(4) から酸素を吹精しつつ加熱溶解し、得られた溶解物(1A)を図2に示すように取鍋(5) からシューター(6) に移し、該シューター(6) から高速回転する羽根付きドラム(7,8) に注入する。該溶解物(1A)は該羽根付きドラム(7,8) によって細破砕されて粒状化し、該溶解物(1A)の粒化物(1B)は急冷チャンバー(9) 内にスプレー装置(10)からスプレーされる水ミストによって急冷される。そしてこのようにして得られた重量細骨材(11)は備蓄容器(12)内に備蓄される。該重量細骨材(11)は略球状であり平均粒径が1.2mmである。該重量細骨材の主要な鉱物組成はウスタイトおよびマグネタイトであり、不安定な鉱物が含まれないから耐久性がありかつ耐蝕性もある。
該重量細骨材(11)の化学組成を表1に示す。
【表1】

Figure 0004031070
【0009】
該重量細骨材(11)の物理的性質を表2に示す。
【表2】
Figure 0004031070
該重量細骨材(11)の粒度分布を図3に示す。
【0010】
【発明の効果】
本発明の重量骨材は高比重を有し、かつ耐久性、耐蝕性、耐磨耗性があるから、コンクリート製品、ゴム製品、プラスチック製品、粘土製品等に大重量を付し、かつ制振性、遮音性、放射線シールド性、透磁性等を付与するために使用されて極めて有用である。
【図面の簡単な説明】
【図1】電気溶解炉説明図
【図2】骨材製造装置の説明図
【図3】重量細骨材の粒度分布図
【符号の説明】
1 電気炉酸化スラグ
2 電気溶解炉
11 重量細骨材[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a heavy aggregate used for heavy fine aggregates, heavy coarse aggregates and the like added to cement, plastic, rubber and the like.
[0002]
[Prior art]
Conventionally, natural resources such as river sand, silica sand, and crushed sand have been used as fine aggregates, but it becomes increasingly difficult to secure the above natural resources, and instead, electric furnace oxidation slag granulation is used as fine aggregates. It is being considered.
The electric furnace oxidized slag granulated product does not contain unstable free lime, free magnesia, or minerals, has durability and corrosion resistance, and is heavy in weight, and thus imparts vibration damping and sound insulation to the product.
[0003]
[Problems to be solved by the invention]
Recently, concrete products, vibration control, sound insulation, radiation shielding, magnetic permeability, etc., plastic products, rubber products, clay products, etc. have been in the spotlight, and there is a growing need for aggregates with high weight and specific gravity. Yes.
[0004]
[Means for Solving the Problems]
As a means for solving the above-mentioned problems, the present invention provides a heavy aggregate obtained by adding and dissolving a high specific gravity element and / or a high specific gravity element compound in an electric furnace oxidation slag, and cooling and granulating it.
[0005]
The high specific gravity element used in the present invention is an element having a specific gravity of 7 or more. Examples of such elements include Fe, Co, Cu, Zn, Pb, and the like. Examples thereof include oxides, hydroxides, chlorides, and the like. Desirable high specific gravity elements or compounds thereof include iron, copper, iron scrap, iron oxide, lead dross and the like.
[0006]
In order to produce the heavy aggregate of the present invention, as shown in FIG. 1, an electric furnace oxidation slag (1) and a high specific gravity element and / or a high specific gravity element compound are put into an electric melting furnace (2) and an electrode (3 The slag (1) and high specific gravity element and / or high specific gravity element compound are dissolved, and if desired, oxygen and / or air is blown to cool and solidify and pulverize the dissolved product. In this case, when the melt is poured into a plate-shaped container made of steel plate to a thickness of usually 80 mm, and then cooled with water and pulverized with a crusher, a coarse coarse aggregate is produced.
[0007]
In order to produce heavy fine aggregate from the melt, the melt is usually poured into a bladed drum that rotates at high speed, the melt is crushed and granulated by the bladed drum, and the granulated melt is A method of quenching in a water mist atmosphere is employed. A plurality of bladed drums may be arranged to perform a plurality of stages of crushing and granulating.
The heavy aggregate obtained in this way usually has a particle size of 5 mm or less, and those having a particle size of 2.5 mm or less are substantially spherical, and have an excellent shape with fine irregularities on the surface, and a particle size distribution. Is in the standard range of crushed sand for JIS-A5005 concrete.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
〔Example〕
4.5 tons of electric furnace oxidation slag (1) was put into the electric melting furnace (2) shown in Fig. 1, and 1.5 tons of slag was added as iron scrap, and oxygen was blown from the lance pipe (4). As shown in FIG. 2, the melt (1A) obtained by heating and melting while being refined is transferred from the ladle (5) to the shooter (6), and from the shooter (6), a bladed drum (7, 8) Inject. The melt (1A) is pulverized and granulated by the bladed drum (7, 8), and the granulate (1B) of the melt (1A) is fed from the spray device (10) into the quenching chamber (9). Quenched by sprayed water mist. The heavy fine aggregate (11) thus obtained is stored in the storage container (12). The heavy fine aggregate (11) is substantially spherical and has an average particle size of 1.2 mm. The main mineral composition of the heavy fine aggregate is wustite and magnetite, and since they are free of unstable minerals, they are durable and corrosion resistant.
The chemical composition of the heavy fine aggregate (11) is shown in Table 1.
[Table 1]
Figure 0004031070
[0009]
Table 2 shows the physical properties of the heavy fine aggregate (11).
[Table 2]
Figure 0004031070
The particle size distribution of the heavy fine aggregate (11) is shown in FIG.
[0010]
【The invention's effect】
Since the heavy aggregate of the present invention has a high specific gravity and has durability, corrosion resistance, and wear resistance, it gives heavy weight to concrete products, rubber products, plastic products, clay products, etc. It is extremely useful when used for imparting properties, sound insulation, radiation shielding, magnetic permeability, and the like.
[Brief description of the drawings]
[Fig. 1] Electrolytic furnace explanatory diagram [Fig. 2] Aggregate production device illustration [Fig. 3] Grain size distribution diagram of heavy fine aggregate [Explanation of symbols]
1 Electric furnace oxidation slag
2 Electric melting furnace
11 Heavy fine aggregate

Claims (1)

電気炉酸化スラグに高比重元素および/または高比重元素化合物を添加溶解し、冷却固化そして粒化したことを特徴とする重量骨材Heavy aggregate characterized by adding high specific gravity element and / or high specific gravity element compound to electric furnace oxidation slag, dissolving, cooling and granulating
JP19137196A 1996-07-01 1996-07-01 Heavy aggregate Expired - Lifetime JP4031070B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19137196A JP4031070B2 (en) 1996-07-01 1996-07-01 Heavy aggregate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19137196A JP4031070B2 (en) 1996-07-01 1996-07-01 Heavy aggregate

Publications (2)

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JPH1015523A JPH1015523A (en) 1998-01-20
JP4031070B2 true JP4031070B2 (en) 2008-01-09

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19809641C2 (en) 1998-03-06 2002-09-05 Abc Engineering Gmbh Flums Amusement track, especially for fairs and amusement parks
JP2003147708A (en) * 2001-11-14 2003-05-21 Hoshino Sansho:Kk Asphalt mixture
JP4880625B2 (en) * 2008-01-30 2012-02-22 太平洋セメント株式会社 Counterweight including heavy aggregate
JP5313514B2 (en) * 2008-02-05 2013-10-09 太平洋セメント株式会社 Counterweight manufacturing method
JP5727778B2 (en) * 2010-12-20 2015-06-03 日新製鋼株式会社 Method for producing stainless steel electric furnace oxidation slag
JP5759163B2 (en) * 2010-12-20 2015-08-05 日新製鋼株式会社 Method for producing stainless steel electric furnace oxidation slag
JP5535094B2 (en) * 2011-01-11 2014-07-02 株式会社星野産商 Magnetic sensor
JP6299964B2 (en) * 2013-03-22 2018-03-28 愛知製鋼株式会社 High-strength concrete and bioactive materials using magnetized materials

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