JP4031070B2 - Heavy aggregate - Google Patents
Heavy aggregate Download PDFInfo
- Publication number
- JP4031070B2 JP4031070B2 JP19137196A JP19137196A JP4031070B2 JP 4031070 B2 JP4031070 B2 JP 4031070B2 JP 19137196 A JP19137196 A JP 19137196A JP 19137196 A JP19137196 A JP 19137196A JP 4031070 B2 JP4031070 B2 JP 4031070B2
- Authority
- JP
- Japan
- Prior art keywords
- heavy
- specific gravity
- aggregate
- high specific
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000005484 gravity Effects 0.000 claims description 13
- 239000002893 slag Substances 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 239000000155 melt Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/02—Making special pig-iron, e.g. by applying additives, e.g. oxides of other metals
- C21B5/023—Injection of the additives into the melting part
- C21B5/026—Injection of the additives into the melting part of plastic material
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Iron (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Processing Of Solid Wastes (AREA)
Description
【0001】
【発明の属する技術分野】
本発明はセメント、プラスチック、ゴム等に添加される重量細骨材や重量粗骨材等に使用される重量骨材に関するものである。
【0002】
【従来の技術】
従来、細骨材として川砂、ケイ砂、砕砂等の天然資源が用いられて来たが、上記天然資源の確保が次第に困難となり、それに代えて電気炉酸化スラグ粒化物を細骨材として使用することが検討されている。
上記電気炉酸化スラグ粒化物は不安定な遊離石灰、遊離マグネシア、あるいは鉱物を含まず、耐久性および耐蝕性を有し、また重量が大であるから製品に制振遮音性を与える。
【0003】
【発明が解決しようとする課題】
最近、制振性、遮音性、放射線シールド性、透磁性等を有するコンクリート製品、プラスチック製品、ゴム製品、粘土製品等が脚光を浴びており、更に大重量高比重の骨材に対するニーズが高まっている。
【0004】
【課題を解決するための手段】
本発明は上記課題を解決するための手段として、電気炉酸化スラグに高比重元素およびまたは高比重元素化合物を添加溶解し、冷却化そして粒化した重量骨材を提供するものである。
【0005】
本発明において使用する高比重元素とは比重が7以上の元素であり、このような元素としては、Fe,Co,Cu,Zn,Pb等が例示され、該高比重元素の化合物としては上記元素の酸化物、水酸化物、塩化物等が例示される。望ましい高比重元素またはその化合物としては鉄、銅、鉄スクラップ、鉄酸化物、鉛ドロス等がある。
【0006】
本発明の重量骨材を製造するには、図1に示すように電気炉酸化スラグ(1) と高比重元素および/または高比重元素化合物を電気溶解炉(2) に投入し、電極(3) に通電して該スラグ(1) と高比重元素および/または高比重元素化合物を溶解し、所望なれば酸素および/または空気を吹込んで該溶解物を冷却固化粉砕する。この場合該溶解物を鋼板製の皿型容器内に通常80mm厚に注入し、水冷後クラッシャーで粉砕すれば重量粗骨材が製造される。
【0007】
また該溶解物から重量細骨材を製造するには、通常該溶解物を高速回転する羽根付きドラムに注入し、該溶解物を該羽根付きドラムによって破砕粒状化し、粒状化した該溶融物を水ミスト雰囲気中で急冷処理する方法が採られる。該羽根付きドラムは複数個配置して複数段の破砕粒状化を行なってもよい。
このようにして得られる重量細骨材は通常5mm以下の粒径を有し、粒径2.5mm以下のものは略球状であり、表面に微細な凹凸を有する優れた形状のもので粒度分布はJIS−A5005コンクリート用砕砂の規格範囲にある。
【0008】
【発明の実施の形態】
〔実施例〕
4.5トンの電気炉酸化スラグ(1) を図1に示す電気溶解炉(2) に投入し、更に鉄スクラップとして1.5トンの銑ダライを加えてランス管(4) から酸素を吹精しつつ加熱溶解し、得られた溶解物(1A)を図2に示すように取鍋(5) からシューター(6) に移し、該シューター(6) から高速回転する羽根付きドラム(7,8) に注入する。該溶解物(1A)は該羽根付きドラム(7,8) によって細破砕されて粒状化し、該溶解物(1A)の粒化物(1B)は急冷チャンバー(9) 内にスプレー装置(10)からスプレーされる水ミストによって急冷される。そしてこのようにして得られた重量細骨材(11)は備蓄容器(12)内に備蓄される。該重量細骨材(11)は略球状であり平均粒径が1.2mmである。該重量細骨材の主要な鉱物組成はウスタイトおよびマグネタイトであり、不安定な鉱物が含まれないから耐久性がありかつ耐蝕性もある。
該重量細骨材(11)の化学組成を表1に示す。
【表1】
【0009】
該重量細骨材(11)の物理的性質を表2に示す。
【表2】
該重量細骨材(11)の粒度分布を図3に示す。
【0010】
【発明の効果】
本発明の重量骨材は高比重を有し、かつ耐久性、耐蝕性、耐磨耗性があるから、コンクリート製品、ゴム製品、プラスチック製品、粘土製品等に大重量を付し、かつ制振性、遮音性、放射線シールド性、透磁性等を付与するために使用されて極めて有用である。
【図面の簡単な説明】
【図1】電気溶解炉説明図
【図2】骨材製造装置の説明図
【図3】重量細骨材の粒度分布図
【符号の説明】
1 電気炉酸化スラグ
2 電気溶解炉
11 重量細骨材[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a heavy aggregate used for heavy fine aggregates, heavy coarse aggregates and the like added to cement, plastic, rubber and the like.
[0002]
[Prior art]
Conventionally, natural resources such as river sand, silica sand, and crushed sand have been used as fine aggregates, but it becomes increasingly difficult to secure the above natural resources, and instead, electric furnace oxidation slag granulation is used as fine aggregates. It is being considered.
The electric furnace oxidized slag granulated product does not contain unstable free lime, free magnesia, or minerals, has durability and corrosion resistance, and is heavy in weight, and thus imparts vibration damping and sound insulation to the product.
[0003]
[Problems to be solved by the invention]
Recently, concrete products, vibration control, sound insulation, radiation shielding, magnetic permeability, etc., plastic products, rubber products, clay products, etc. have been in the spotlight, and there is a growing need for aggregates with high weight and specific gravity. Yes.
[0004]
[Means for Solving the Problems]
As a means for solving the above-mentioned problems, the present invention provides a heavy aggregate obtained by adding and dissolving a high specific gravity element and / or a high specific gravity element compound in an electric furnace oxidation slag, and cooling and granulating it.
[0005]
The high specific gravity element used in the present invention is an element having a specific gravity of 7 or more. Examples of such elements include Fe, Co, Cu, Zn, Pb, and the like. Examples thereof include oxides, hydroxides, chlorides, and the like. Desirable high specific gravity elements or compounds thereof include iron, copper, iron scrap, iron oxide, lead dross and the like.
[0006]
In order to produce the heavy aggregate of the present invention, as shown in FIG. 1, an electric furnace oxidation slag (1) and a high specific gravity element and / or a high specific gravity element compound are put into an electric melting furnace (2) and an electrode (3 The slag (1) and high specific gravity element and / or high specific gravity element compound are dissolved, and if desired, oxygen and / or air is blown to cool and solidify and pulverize the dissolved product. In this case, when the melt is poured into a plate-shaped container made of steel plate to a thickness of usually 80 mm, and then cooled with water and pulverized with a crusher, a coarse coarse aggregate is produced.
[0007]
In order to produce heavy fine aggregate from the melt, the melt is usually poured into a bladed drum that rotates at high speed, the melt is crushed and granulated by the bladed drum, and the granulated melt is A method of quenching in a water mist atmosphere is employed. A plurality of bladed drums may be arranged to perform a plurality of stages of crushing and granulating.
The heavy aggregate obtained in this way usually has a particle size of 5 mm or less, and those having a particle size of 2.5 mm or less are substantially spherical, and have an excellent shape with fine irregularities on the surface, and a particle size distribution. Is in the standard range of crushed sand for JIS-A5005 concrete.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
〔Example〕
4.5 tons of electric furnace oxidation slag (1) was put into the electric melting furnace (2) shown in Fig. 1, and 1.5 tons of slag was added as iron scrap, and oxygen was blown from the lance pipe (4). As shown in FIG. 2, the melt (1A) obtained by heating and melting while being refined is transferred from the ladle (5) to the shooter (6), and from the shooter (6), a bladed drum (7, 8) Inject. The melt (1A) is pulverized and granulated by the bladed drum (7, 8), and the granulate (1B) of the melt (1A) is fed from the spray device (10) into the quenching chamber (9). Quenched by sprayed water mist. The heavy fine aggregate (11) thus obtained is stored in the storage container (12). The heavy fine aggregate (11) is substantially spherical and has an average particle size of 1.2 mm. The main mineral composition of the heavy fine aggregate is wustite and magnetite, and since they are free of unstable minerals, they are durable and corrosion resistant.
The chemical composition of the heavy fine aggregate (11) is shown in Table 1.
[Table 1]
[0009]
Table 2 shows the physical properties of the heavy fine aggregate (11).
[Table 2]
The particle size distribution of the heavy fine aggregate (11) is shown in FIG.
[0010]
【The invention's effect】
Since the heavy aggregate of the present invention has a high specific gravity and has durability, corrosion resistance, and wear resistance, it gives heavy weight to concrete products, rubber products, plastic products, clay products, etc. It is extremely useful when used for imparting properties, sound insulation, radiation shielding, magnetic permeability, and the like.
[Brief description of the drawings]
[Fig. 1] Electrolytic furnace explanatory diagram [Fig. 2] Aggregate production device illustration [Fig. 3] Grain size distribution diagram of heavy fine aggregate [Explanation of symbols]
1 Electric furnace oxidation slag
2 Electric melting furnace
11 Heavy fine aggregate
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19137196A JP4031070B2 (en) | 1996-07-01 | 1996-07-01 | Heavy aggregate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19137196A JP4031070B2 (en) | 1996-07-01 | 1996-07-01 | Heavy aggregate |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH1015523A JPH1015523A (en) | 1998-01-20 |
JP4031070B2 true JP4031070B2 (en) | 2008-01-09 |
Family
ID=16273483
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP19137196A Expired - Lifetime JP4031070B2 (en) | 1996-07-01 | 1996-07-01 | Heavy aggregate |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4031070B2 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19809641C2 (en) | 1998-03-06 | 2002-09-05 | Abc Engineering Gmbh Flums | Amusement track, especially for fairs and amusement parks |
JP2003147708A (en) * | 2001-11-14 | 2003-05-21 | Hoshino Sansho:Kk | Asphalt mixture |
JP4880625B2 (en) * | 2008-01-30 | 2012-02-22 | 太平洋セメント株式会社 | Counterweight including heavy aggregate |
JP5313514B2 (en) * | 2008-02-05 | 2013-10-09 | 太平洋セメント株式会社 | Counterweight manufacturing method |
JP5727778B2 (en) * | 2010-12-20 | 2015-06-03 | 日新製鋼株式会社 | Method for producing stainless steel electric furnace oxidation slag |
JP5759163B2 (en) * | 2010-12-20 | 2015-08-05 | 日新製鋼株式会社 | Method for producing stainless steel electric furnace oxidation slag |
JP5535094B2 (en) * | 2011-01-11 | 2014-07-02 | 株式会社星野産商 | Magnetic sensor |
JP6299964B2 (en) * | 2013-03-22 | 2018-03-28 | 愛知製鋼株式会社 | High-strength concrete and bioactive materials using magnetized materials |
-
1996
- 1996-07-01 JP JP19137196A patent/JP4031070B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH1015523A (en) | 1998-01-20 |
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