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JP4066199B2 - Cooking utensil and electromagnetic induction heating cooker equipped with the cooking utensil - Google Patents

Cooking utensil and electromagnetic induction heating cooker equipped with the cooking utensil Download PDF

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JP4066199B2
JP4066199B2 JP2005240256A JP2005240256A JP4066199B2 JP 4066199 B2 JP4066199 B2 JP 4066199B2 JP 2005240256 A JP2005240256 A JP 2005240256A JP 2005240256 A JP2005240256 A JP 2005240256A JP 4066199 B2 JP4066199 B2 JP 4066199B2
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cooking
pores
sintered body
electromagnetic induction
induction heating
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JP2007054124A (en
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朋生 小林
賢一 伊藤
政次 久木野
清 八木田
滋之 永田
昭彦 小林
正博 山崎
久夫 井坂
奈穂 美寿美
剛志 前田
芳夫 西本
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Mitsubishi Electric Corp
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Description

本発明は、調理具およびこの調理具を備えた電磁誘導加熱調理器に関するものである。   The present invention relates to a cooking utensil and an electromagnetic induction heating cooker equipped with the cooking utensil.

電磁誘導加熱調理器は、インバータ回路から供給された高周波電流により高周波磁界が発生して励磁されることによって渦電流が誘起され、この渦電流と調理具の持つ抵抗によってジュール熱が発生して調理具の底面が発熱する。従来の調理具の基材である磁性金属材料に代えて炭素を主体とする焼結体を使用することによって調理具の熱伝導性能を高めたので、均一加熱を主体とする調理性能を向上させるとともに、鍋表面にフッ素樹脂コーティングを施して具材の固着を防止していた(例えば、特許文献1参照)。   In an electromagnetic induction heating cooker, a high frequency magnetic field is generated and excited by a high frequency current supplied from an inverter circuit to induce eddy current, and Joule heat is generated by the resistance of the eddy current and the cooking utensil to cook. The bottom of the tool generates heat. Since the heat conduction performance of the cooking utensil has been improved by using a sintered body mainly composed of carbon instead of the magnetic metal material that is the base material of conventional cooking utensils, the cooking performance mainly of uniform heating is improved. At the same time, a fluororesin coating was applied to the pan surface to prevent the ingredients from sticking (for example, see Patent Document 1).

特開平9−75211号公報(第6頁、図2)JP-A-9-75211 (6th page, FIG. 2)

特許文献1の電磁誘導加熱調理器は、調理具の基材に炭素を主体とする焼結体にフッ素樹脂などのコーティングを施して用いるものであるから、熱伝導性や励磁の容易性、耐腐食性などを勘案した複数種の金属を複素化したクラッド材を用いることなく、単一種の材料のみで構成することが可能になる。反面、使用する炭素材は均質で緻密な成形処理を施して調理具を製造することによって調理具の硬度を高めていた。このため、調理具の硬度を高めることになり、静的な力に対する強度は強くなるが、落下や衝突などの衝撃に対する強度はさほど強くならず、破損しやすいという問題があった。   Since the electromagnetic induction heating cooker of Patent Document 1 is used by applying a coating such as a fluororesin to a sintered body mainly composed of carbon on a base material of a cooking tool, thermal conductivity, ease of excitation, It is possible to configure only a single type of material without using a clad material obtained by complexing a plurality of types of metals in consideration of corrosivity. On the other hand, the carbon material used has been subjected to a uniform and dense molding process to produce the cooking utensil, thereby increasing the hardness of the cooking utensil. For this reason, although the hardness of a cooking utensil will be raised and the intensity | strength with respect to a static force will become strong, the intensity | strength with respect to impacts, such as a fall and a collision, is not so strong, and there existed a problem that it was easy to break.

本発明は、上記のような課題を解決するためになされたもので、熱伝導性能の高い炭素を主体とする焼結体を使用し、しかも落下や衝突などの衝撃に対して破損しにくい調理具と、この調理具を用いた電磁誘導加熱調理器を得ることを目的とする。   The present invention has been made in order to solve the above-described problems, and uses a sintered body mainly composed of carbon having a high thermal conductivity, and is not easily damaged by an impact such as a drop or a collision. An object is to obtain a tool and an electromagnetic induction heating cooker using the cooker.

本発明の調理具は、炭素の粉粒物を主体とする焼結体であって、気体を混入しながら液状の結合材と混練することによって細孔を含有させた基材から成る成形品であることを特徴とする。   The cooking utensil according to the present invention is a sintered body mainly composed of carbon particles, and is a molded article made of a base material containing pores by kneading with a liquid binder while mixing gas. It is characterized by being.

調理具の基材に熱伝導性の高い炭素材質の焼結体を使用し、基材の内部に細孔を有する構造としたので、加熱時に調理具が短時間で均一に温度上昇することによる調理性能の向上を確保しながら、基材の内部に設けた細孔が基材の落下や衝突などの衝撃を受けた際に基材が変形する力を吸収、分散させるため、破損しにくくなる。   Because the base material of the cooking utensil uses a sintered body of carbon material with high thermal conductivity and has a structure with pores inside the base material, the temperature of the cooking utensil rises uniformly in a short time during heating While ensuring improved cooking performance, the pores inside the substrate absorb and disperse the force that deforms the substrate when subjected to impacts such as dropping or collision of the substrate, making it difficult to break .

実施の形態1.
図1は本発明の実施の形態1に係る電磁誘導加熱調理器の縦断面図、図2は図1に示す電磁誘導加熱調理器の調理鍋内側の一部を拡大した断面図、図3は図2に示す調理鍋の断面の一部を撮影した顕微鏡写真である。
図1及び図2に示すように、電磁誘導加熱調理器の本体1には、底中央部に孔部2aを備えた調理鍋収納部2が内装固着され、調理鍋収納部2の外壁部には電磁誘導加熱用の加熱コイル3が設けられている。この加熱コイル3は、調理鍋収納部2の外底部に設けられた第1の加熱コイル3aと、外底部からコーナー部にかけて設けられた第2の加熱コイル3bとによって構成され、各々のコイル3a,3bはスパイラル状に旋回されて直列に接続され、高周波電流が供給されるようになっている。
Embodiment 1 FIG.
1 is a longitudinal sectional view of an electromagnetic induction heating cooker according to Embodiment 1 of the present invention, FIG. 2 is an enlarged sectional view of a part of the inside of a cooking pan of the electromagnetic induction heating cooker shown in FIG. 1, and FIG. It is the microscope picture which image | photographed a part of cross section of the cooking pan shown in FIG.
As shown in FIGS. 1 and 2, the main body 1 of the electromagnetic induction heating cooker has a cooking pot storage portion 2 provided with a hole 2 a in the center of the bottom, and is fixed to the outer wall portion of the cooking pot storage portion 2. Is provided with a heating coil 3 for electromagnetic induction heating. This heating coil 3 is comprised by the 1st heating coil 3a provided in the outer bottom part of the cooking pot accommodating part 2, and the 2nd heating coil 3b provided from the outer bottom part to the corner part, and each coil 3a. , 3b are swirled spirally and connected in series so that a high-frequency current is supplied.

調理鍋収納部2の底中央部に形成した孔部2aには温度センサ4が貫通して設けられており、圧縮バネ4aにより下方から支持されている。調理鍋収納部2には調理鍋(調理具)5が着脱自在に収納されており、調理鍋5の底部には温度センサ4が圧着されている。
この調理鍋5は、炭素含有量が90%以上の焼結体5aを基材とし、この基材内部に、基材に対する空孔率が5%〜15%であって、幅が200μm程度の細孔5bを有している。
調理鍋5の内側表面、すなわち食品等を収容する側に位置する表面には、厚み約40μmの皮膜よりなるフッ素コーティング層5dが形成されており、これによって炭素焼結体5aが調理時に剥がれることがないようにしてある。なお、フッ素コーティング層5dは、図3の顕微鏡写真に示すように、焼結体5aの内側表面部に開口した幅約200μmの細孔5cを覆っている。以下に詳細な調理鍋の製造方法を記す。
A temperature sensor 4 is provided through the hole 2a formed at the bottom center of the cooking pot storage unit 2, and is supported from below by a compression spring 4a. A cooking pot (cooking tool) 5 is detachably stored in the cooking pot storage section 2, and a temperature sensor 4 is pressure-bonded to the bottom of the cooking pot 5.
This cooking pan 5 uses a sintered body 5a having a carbon content of 90% or more as a base material, and the porosity of the base material is 5% to 15% and the width is about 200 μm inside the base material. It has a pore 5b.
A fluorine coating layer 5d made of a film having a thickness of about 40 μm is formed on the inner surface of the cooking pan 5, that is, the surface located on the side containing food or the like, whereby the carbon sintered body 5a is peeled off during cooking. There is no way. As shown in the micrograph of FIG. 3, the fluorine coating layer 5d covers the pores 5c having a width of about 200 μm that are opened in the inner surface portion of the sintered body 5a. A detailed cooking pot manufacturing method is described below.

炭素の高含有物であるコークスを100μm以下に粉砕し、これを高温で溶融して生成した液状の結合材であるタールチップと混合する。この時、混連には高い剪断力を得て均一の混合が可能なバンバリーミキサーの如く、回転する2軸の押出スクリューと同様の混練装置を用いることが好ましい。また、コークスとタールチップの比率は2:1程度とし、高温での混練時に十分に粘調な液状を確保できることが肝要である。   Coke, which is a high carbon content, is pulverized to 100 μm or less, and this is mixed with tar chips, which are liquid binders produced by melting at a high temperature. At this time, it is preferable to use a kneading apparatus similar to a rotating biaxial extrusion screw, such as a Banbury mixer capable of obtaining a high shearing force and uniform mixing. In addition, it is important that the ratio of coke to tar chips is about 2: 1, and a sufficiently viscous liquid can be secured during kneading at a high temperature.

次に、混練中に窒素ガスを吹き込むことによって気孔を形成する。このとき、見掛けの体積が15〜20%程度の増加を来すまで行い、その後、20分程度の混練を継続して気孔の均一分散と微細化を達成する。この混練したカーボン材は円筒状の金型に封入した後、固化するまで冷却した後に取り出した後、1000℃以上の高温、好ましくは3000℃で焼成することによってコークスの微粉粒を焼結させる。焼成に際しては、円筒状の成型物が過度に変形しないように、また、酸素を遮断する目的で外周をコークスの微粉末で覆うようにして2℃/Hr程度の昇温および降温速度を確保して、内部に焼結時の収縮による応力を残存させないように配慮することが好ましい。   Next, pores are formed by blowing nitrogen gas during kneading. At this time, the apparent volume is increased to about 15 to 20%, and then kneading is continued for about 20 minutes to achieve uniform dispersion and refinement of the pores. The kneaded carbon material is sealed in a cylindrical mold, cooled until solidified, taken out, and then fired at a high temperature of 1000 ° C. or higher, preferably 3000 ° C., to sinter fine coke particles. During firing, a temperature rise and fall rate of about 2 ° C / Hr is secured so that the cylindrical molded product is not excessively deformed and the outer periphery is covered with fine coke powder for the purpose of blocking oxygen. Therefore, it is preferable to take care not to leave stress due to shrinkage during sintering inside.

円筒状の成形品が含む微細な気孔は、内部に不活性ガスである窒素が封入されているので、高温で焼結する際に、気孔内壁の損傷によって発生する微細なクラックなどの衝撃強度を低下させる欠陥の発生を抑制することができる。その後、コークスやタールピッチが含む不純物を飛散させるとともに、微細な気孔を構成する隔壁を連通させることができるので、調理鍋が高温になり気孔内の空気が膨張した場合であっても、連通する他の気孔を介して、膨張した空気は確実に外に排出される。その結果、膨張した空気によって気孔内が高圧になることを防止でき、割れ難い調理鍋を得ることができる。   The fine pores contained in the cylindrical molded product are filled with nitrogen, which is an inert gas, so that when sintered at high temperatures, impact strength such as fine cracks generated by damage to the pore inner walls is obtained. Generation | occurrence | production of the defect to reduce can be suppressed. After that, impurities contained in the coke and tar pitch are scattered and the partition walls forming the fine pores can be communicated, so even if the cooking pot becomes hot and the air in the pores expands, it communicates. The expanded air is reliably discharged outside through the other pores. As a result, the inside of the pores can be prevented from becoming high pressure due to the expanded air, and a cooking pot that is difficult to break can be obtained.

以上の工程を経て得た焼結体を切削加工によって任意形状の成型することができ、本実施の形態に係る調理鍋を確保した。   The sintered body obtained through the above steps can be formed into an arbitrary shape by cutting, and the cooking pot according to the present embodiment is secured.

調理鍋5は、収納部2の上方に形成されたフランジ部の例えば3箇所には凸状の支持部6が形成され、この支持部6によって支持されている。調理鍋5は内蓋7によって覆われており、内蓋7の周縁部にはシール材である蓋パッキン8が配置され、この蓋パッキン8によって調理鍋5のフランジ部との間に密閉性が確保されている。内蓋7は係止材10により連結された外蓋9によって覆われており、本体1に開閉自在に支持されている。内蓋7及び外蓋9にはこれらを貫通して蒸気口11が設けられており、この蒸気口11は調理鍋内弁11aと外弁11bとによって構成されている。なお、外蓋9の一部には操作表示部12が設けられている。   In the cooking pot 5, convex support portions 6 are formed at, for example, three locations of the flange portion formed above the storage portion 2, and are supported by the support portions 6. The cooking pan 5 is covered with an inner lid 7, and a lid packing 8, which is a sealing material, is disposed on the peripheral portion of the inner lid 7, and the lid packing 8 provides a sealing property between the cooking pot 5 and the flange portion. It is secured. The inner lid 7 is covered by an outer lid 9 connected by a locking member 10 and is supported by the main body 1 so as to be freely opened and closed. The inner lid 7 and the outer lid 9 are provided with a steam port 11 penetrating them, and the steam port 11 is constituted by a cooking pan inner valve 11a and an outer valve 11b. An operation display unit 12 is provided on a part of the outer lid 9.

次に動作を説明する。まず、所定量の米を調理鍋5内に入れ、その後、米量に応じた水を入れる。次に、調理鍋5を調理鍋収納部2に収納し外蓋9を閉めると、内蓋7の蓋パッキン8が調理鍋5のフランジ部に圧接されて調理鍋5が密閉シールされる。そして操作表示部12の炊飯工程スイッチをオンして、炊飯工程をスタートさせる。   Next, the operation will be described. First, a predetermined amount of rice is put into the cooking pan 5, and then water corresponding to the amount of rice is added. Next, when the cooking pan 5 is stored in the cooking pan storage portion 2 and the outer lid 9 is closed, the lid packing 8 of the inner lid 7 is pressed against the flange portion of the cooking pan 5 and the cooking pan 5 is hermetically sealed. And the rice cooking process switch of the operation display part 12 is turned ON, and the rice cooking process is started.

第1、第2の加熱コイル3a、3bには、インバータ回路(図示せず)から高周波電流が供給されて高周波磁界が発生し、第1、第2の加熱コイル3a,3bと磁気結合した調理鍋5の加熱コイル3a,3bとの対向面が励磁され、調理鍋5の底面に渦電流が誘起される。この渦電流と調理鍋5の持つ抵抗によってジュール熱が発生し、調理鍋5の底面が発熱する。調理鍋5は、抵抗率ほぼ7.2×10-7以上の高抵抗を有しているため、電磁誘導加熱が可能となる。炭素で構成された調理鍋5は、従来の複数種の金属を積層した電磁誘導加熱を可能とする調理鍋に比較して高い熱伝導特性を持つため、短時間に調理鍋5の温度が均一に上昇し、その結果、具材を均一かつ効率的に加熱する。なお、上記の説明では、加熱コイル3を第1のコイル3aと第2のコイル3bに分割して設置した場合を示したが、外底面からコーナ部にかけて一括して設置してもよい。   The first and second heating coils 3a and 3b are supplied with a high-frequency current from an inverter circuit (not shown) to generate a high-frequency magnetic field and cooked magnetically coupled to the first and second heating coils 3a and 3b. The surface of the pan 5 facing the heating coils 3 a and 3 b is excited, and an eddy current is induced on the bottom surface of the cooking pan 5. Joule heat is generated by the eddy current and the resistance of the cooking pan 5, and the bottom surface of the cooking pan 5 generates heat. Since the cooking pot 5 has a high resistivity of about 7.2 × 10 −7 or more, electromagnetic induction heating is possible. The cooking pan 5 made of carbon has higher heat conduction characteristics than the conventional cooking pan capable of electromagnetic induction heating in which a plurality of types of metals are laminated, so the temperature of the cooking pan 5 is uniform in a short time. As a result, the ingredients are heated uniformly and efficiently. In the above description, the heating coil 3 is divided into the first coil 3a and the second coil 3b. However, the heating coil 3 may be collectively installed from the outer bottom surface to the corner portion.

本実施の形態1によれば、調理鍋5は炭素含有量が99%以上の焼結体5aによって構成され、基材内に細孔5bを有しているために落下や衝突などの衝撃を受けても基材が変形する力を吸収して衝撃が分散する。このため、調理鍋5に強い外力が加わっても、基材を均質で緻密に成形した場合に比べて破損しにくくなる。この場合、基材の空孔率が5%〜15%の間で、破損に対する強度が特に強くなる。調理鍋にはフッ素コーティング層5dは、焼結体5aの内側表面部に開口した細孔5cを覆っているため、調理鍋5の内側からの水分の漏れを防止する。
なお、上記の説明では、フッ素コーティング層5dを調理鍋5の内側表面に形成した場合を示したが、さらに外側表面に形成してもよく、この場合は調理鍋5の内外側表面を調理鍋の洗浄などの際に生じる摩耗などの挙動から保護する効果を得ることができる(本実施の形態2,3についても同様)。
According to the first embodiment, the cooking pan 5 is composed of the sintered body 5a having a carbon content of 99% or more and has the pores 5b in the base material. Even if it receives, the force which deform | transforms a base material will be absorbed and an impact will disperse | distribute. For this reason, even if a strong external force is applied to the cooking pan 5, it is less likely to be damaged than when the base material is molded uniformly and densely. In this case, the strength against breakage is particularly strong when the porosity of the substrate is between 5% and 15%. In the cooking pan, the fluorine coating layer 5 d covers the pores 5 c opened in the inner surface portion of the sintered body 5 a, thereby preventing moisture from leaking from the inside of the cooking pan 5.
In the above description, the case where the fluorine coating layer 5d is formed on the inner surface of the cooking pan 5 has been shown. However, it may be formed on the outer surface, and in this case, the inner and outer surfaces of the cooking pan 5 may be formed on the cooking pan. Thus, it is possible to obtain an effect of protecting against the behavior such as wear that occurs during cleaning or the like (the same applies to the second and third embodiments).

本実施の形態に基づいて製造した調理鍋であるジャ−炊飯器の内釜を用いて、従来の磁性金属である鉄と高熱伝導性のアルミ、耐腐食性に優れるステンレスを積層したクラッド材から成る同形状の内釜との炊飯特性を比較した。同一入力と時間の関係を確保した条件で釜内部に同量の水を入れた状態で同一のジャー炊飯器を用いて炊飯条件で加温し、そのときの温度変化を観察した。その結果を図4に示す。   Using the inner pot of a jar rice cooker that is a cooking pot manufactured based on the present embodiment, from a clad material in which iron, which is a conventional magnetic metal, aluminum with high thermal conductivity, and stainless steel with excellent corrosion resistance are laminated. We compared rice cooking characteristics with the same shape inner pot. The same amount of water was put inside the kettle with the same input and time ensured, and the same jar rice cooker was used for heating under the rice cooking conditions, and the temperature change at that time was observed. The result is shown in FIG.

図4に示すように、100℃までの昇温試験の結果、従来のクラッド材から成る同形状の内釜に対し、内部の貯水温度に明確な差異が観察された。本実施の形態による炭素剤を用いた内釜は、従来のクラッド材から成る同形状の内釜と比較して、コイル側表面で発生するジュール熱が釜の厚さ方向に伝導し易いことから、内釜内部に貯蔵した水を速やかに加温できることが確認された。   As shown in FIG. 4, as a result of the temperature rise test up to 100 ° C., a clear difference was observed in the internal water storage temperature with respect to the same shape inner pot made of the conventional clad material. In the inner pot using the carbon agent according to the present embodiment, the Joule heat generated on the coil side surface is easily conducted in the thickness direction of the hook as compared with the inner pot of the same shape made of the conventional clad material. It was confirmed that the water stored in the inner pot could be quickly heated.

つまり、本実施の形態に基づく内釜を搭載したジャー炊飯器は、入力に対して釜の内面部分が敏感に反応して上昇し、より高い炊飯温度と安定した温度保持を確保していることが示唆された。   In other words, the jar rice cooker equipped with the inner pot according to the present embodiment is sensitive to the inner surface portion of the pot rising to the input and rising, ensuring a higher rice cooking temperature and stable temperature holding. Was suggested.

また、上記内釜の実用上の耐衝撃性について評価した。ガスを混入した状態で混練を行うことによって微細な気孔を備えた本実施の形態による内釜Aと、単なる混連のみで炭素材を用いた同形状の内釜Bについて、側部に200gの鋼球を落下させて耐えうる最大高さで表現する落球衝撃強さを求めた。その結果、内釜Bの密度が1.88g/mlであるのに対して内釜Aの密度が1.74g/mlと軽量であるにもかかわらず、落球衝撃強さは内釜Bの40cmに対して内釜Aは55cmと強いうえ、実用上に起こりうる他の食器の衝突などに耐えうることが分かった。   Moreover, the practical impact resistance of the inner hook was evaluated. For the inner pot A according to the present embodiment having fine pores by kneading in a gas-mixed state and the inner pot B having the same shape using a carbon material only in a mixed manner, 200 g on the side portion The falling ball impact strength expressed by the maximum height that can be withstood by dropping the steel ball was obtained. As a result, although the density of the inner hook B is 1.88 g / ml, the density of the inner hook A is 1.74 g / ml, and the falling ball impact strength is 40 cm of the inner pot B. On the other hand, the inner pot A was as strong as 55 cm, and it was found that it could withstand collisions of other tableware that could occur in practice.

このように、本実施の形態であれば、実用上、十分な強度が確保され、破損し難い調理鍋が得られる。
なお、本発明に係る調理具は、本実施の形態で説明した調理鍋5に限定されることなく、例えば、フライパンや焼肉用プレートなどのように、調理に用いることが可能なあらゆる種類の器具が対象となる。
Thus, according to the present embodiment, a cooking pan that is practically sufficient in strength and hard to break can be obtained.
Note that the cooking utensil according to the present invention is not limited to the cooking pan 5 described in the present embodiment, and for example, all kinds of utensils that can be used for cooking such as a frying pan and a grilled meat plate. Is the target.

実施の形態2.
図5は、本発明の実施の形態2に係る電磁誘導加熱調理器の調理鍋内側の一部を拡大した断面図である。
本実施の形態2は、焼結体5aの内側表面に開口した細孔5cにアルミニウム20を充填したものである。
その他の構成については、実施の形態1に示した場合と実質的に同様なので、説明を省略する。
Embodiment 2. FIG.
FIG. 5 is an enlarged cross-sectional view of a part of the inside of the cooking pan of the electromagnetic induction heating cooker according to Embodiment 2 of the present invention.
In the second embodiment, the pores 5c opened on the inner surface of the sintered body 5a are filled with aluminum 20.
Other configurations are substantially the same as those shown in the first embodiment, and thus description thereof is omitted.

上記のように構成した電磁誘導加熱調理器の調理鍋5を製造するには、炭素の微粉体を押出成形し、炭素含有量が90%以上となる焼結体5aを形成する。この押出成形の際に、基材内部に、空孔率が5%〜15%であって、幅が200μm程度の細孔5bを生じるような圧力と温度設定を行う。こうして焼結体5aが成形された後に、細孔5bよりも粒径が小さいアルミニウムの微粉体を焼結体5aの内側表面部に開口した細孔5cに充填し、660℃以上の温度で加熱して溶融させる。こののち、調理鍋5の内側表面にフッ素のコーティング処理を施して、厚みが約40μmのフッ素コーティング層5dを形成する。   In order to manufacture the cooking pot 5 of the electromagnetic induction heating cooker configured as described above, a fine powder of carbon is extruded to form a sintered body 5a having a carbon content of 90% or more. During this extrusion molding, pressure and temperature are set so that pores 5b having a porosity of 5% to 15% and a width of about 200 μm are formed inside the substrate. After the sintered body 5a is formed in this way, fine aluminum powder having a particle size smaller than that of the pores 5b is filled in the pores 5c opened on the inner surface of the sintered body 5a, and heated at a temperature of 660 ° C. or higher. And melt. After that, a fluorine coating process is performed on the inner surface of the cooking pan 5 to form a fluorine coating layer 5d having a thickness of about 40 μm.

焼結体5aを構成する炭素の焼成温度に対し、アルミニウムの微粉体はこれよりも融点が低いので、焼結体5aの内側表面部に開口した細孔5c内にはアルミニウムの微粉体が溶融して保持される。このため、フッ素コーティング層5dと焼結体5aの間に空気層がなくなるうえ、調理鍋の表面にある焼結した炭素粉粒が剥離することに伴う見掛けの接着強度に比較して強固な接着強度を得ることができるため、調理時の調理鍋5の温度上昇や冷却に伴う空気層の膨張収縮の影響による剥離挙動からフッ素コーティング層5dが容易に剥離するのを防止することができる。
つまり、基材である炭素材表面に下地処理剤の耐熱性樹脂とフッ素樹脂の混合物、その上面にフッ素樹脂をコーティングして炭素材の付着を防止する場合、本実施の形態のアルミニウム溶融物で表面を処理したものであれば、前記処理を行わないもののテープ剥離試験が1〜5回で剥離するのに対して、20回以上でも剥離を来すことがなく、強固な接着性を確保できる。
Since the melting point of the aluminum fine powder is lower than the firing temperature of the carbon constituting the sintered body 5a, the aluminum fine powder is melted in the pores 5c opened in the inner surface portion of the sintered body 5a. Held. For this reason, there is no air layer between the fluorine coating layer 5d and the sintered body 5a, and the adhesion is stronger compared to the apparent adhesion strength associated with peeling of the sintered carbon powder particles on the surface of the cooking pan. Since strength can be obtained, it is possible to prevent the fluorine coating layer 5d from being easily peeled off due to the peeling behavior due to the expansion and contraction of the air layer accompanying the temperature rise and cooling of the cooking pan 5 during cooking.
In other words, when the surface of the carbon material, which is a base material, is coated with a mixture of a heat-resistant resin and a fluororesin as a base treatment agent and the top surface thereof is coated with a fluororesin to prevent the carbon material from adhering, As long as the surface is treated, the tape peeling test peels off 1 to 5 times without performing the above treatment, but it does not come off even 20 times or more, and strong adhesiveness can be secured. .

実施の形態3.
図6は本発明の実施の形態3に係る電磁誘導加熱調理器の調理鍋内側の一部を拡大した断面図である。
本実施の形態3は、細孔5cに充填する微粉体を焼結体5aと同一の材料によって構成したもので、焼結体5aの内側表面部に開口した細孔5cに炭素の微粉体を充填し、これを再度加熱焼成して、炭素の焼成体21を構成したものである。
その他の構成については実施の形態1に示した場合と実質的に同様なので、説明を省略する。
Embodiment 3 FIG.
FIG. 6 is an enlarged cross-sectional view of a part of the inside of the cooking pan of the electromagnetic induction heating cooker according to Embodiment 3 of the present invention.
In the third embodiment, the fine powder filling the pores 5c is made of the same material as that of the sintered body 5a, and the fine carbon powder is placed in the pores 5c opened on the inner surface of the sintered body 5a. This is filled and fired again to constitute a carbon fired body 21.
Other configurations are substantially the same as those shown in the first embodiment, and a description thereof will be omitted.

上記のように構成した電磁誘導加熱調理器の調理鍋5を製造するには、炭素の微粉体を押出成形し、炭素含有量が90%以上となる焼結体5aを形成する。この押出成形の際に、基材内部に、空孔率が5%〜15%であって、幅が200μm程度の細孔5bを生じるような圧力と温度設定を行う。こうして焼結体5aが成形された後に、細孔5bよりも粒径が小さい炭素の微粉体を焼結体5aの内側表面部に開口した細孔5cに充填し、約3000℃の温度で再度加熱焼成して、炭素の焼成体21を形成する。こののち、調理鍋5の内側表面にフッ素のコーティング処理を施して、厚みが約40μmのフッ素コーティング層5dを形成する。   In order to manufacture the cooking pot 5 of the electromagnetic induction heating cooker configured as described above, a fine powder of carbon is extruded to form a sintered body 5a having a carbon content of 90% or more. During this extrusion molding, pressure and temperature are set so that pores 5b having a porosity of 5% to 15% and a width of about 200 μm are formed inside the substrate. After the sintered body 5a is formed in this way, fine powder of carbon having a particle diameter smaller than that of the pores 5b is filled in the pores 5c opened on the inner surface portion of the sintered body 5a, and again at a temperature of about 3000 ° C. A carbon fired body 21 is formed by heating and firing. After that, a fluorine coating process is performed on the inner surface of the cooking pan 5 to form a fluorine coating layer 5d having a thickness of about 40 μm.

このため、フッ素コーティング層5dと焼結体5aの間の空気層が減少するため、調理時の調理鍋5の温度上昇や冷却に伴う空気層の膨張収縮の影響がなくなり、フッ素コーティング層5dが細孔5c部分から劣化するのを防止することができる。このように、調理鍋5は、内側表面まで炭素の焼成体で構成されるため、熱伝導性の高い調理鍋5を得ることができる。   For this reason, since the air layer between the fluorine coating layer 5d and the sintered body 5a is reduced, there is no influence of the expansion and contraction of the air layer accompanying the temperature rise or cooling of the cooking pan 5 during cooking, and the fluorine coating layer 5d It is possible to prevent deterioration from the pore 5c portion. Thus, since the cooking pot 5 is comprised by the sintered body of carbon to the inner surface, the cooking pot 5 with high heat conductivity can be obtained.

調理鍋5の製造時に使用する炭素の微粉体は、焼結体5aの内側表面を研磨して生成してもよく、この場合は、焼結体5aが成形された後に、内側表面を研磨する工程、および余剰微粉体を除去する工程を加えることになる。   The fine carbon powder used for manufacturing the cooking pot 5 may be produced by polishing the inner surface of the sintered body 5a. In this case, the inner surface is polished after the sintered body 5a is formed. A process and a process of removing excess fine powder will be added.

本発明の実施の形態1に係る電磁誘導加熱調理器の縦断面図である。It is a longitudinal cross-sectional view of the electromagnetic induction heating cooking appliance which concerns on Embodiment 1 of this invention. 図1に示す電磁誘導加熱調理器の調理鍋の内側の一部を拡大した断面図である。It is sectional drawing to which a part of inner side of the cooking pan of the electromagnetic induction heating cooking appliance shown in FIG. 1 was expanded. 図2に示す調理鍋の断面の一部を撮影した顕微鏡写真である。It is the microscope picture which image | photographed a part of cross section of the cooking pan shown in FIG. 本実施の形態に係る調理鍋と従来の磁性金属からなる調理鍋との炊飯特性を比較した図である。It is the figure which compared the rice cooking characteristic of the cooking pot which concerns on this Embodiment, and the cooking pot which consists of the conventional magnetic metal. 本発明の実施の形態2に係る電磁誘導加熱調理器の調理鍋の内側の一部を拡大した断面図である。It is sectional drawing to which a part of inner side of the cooking pot of the electromagnetic induction heating cooking appliance concerning Embodiment 2 of this invention was expanded. 本発明の実施の形態3に係る電磁誘導加熱調理器の調理鍋内側の一部を拡大した断面図である。It is sectional drawing to which a part of cooking pot inner side of the electromagnetic induction heating cooking appliance concerning Embodiment 3 of this invention was expanded.

符号の説明Explanation of symbols

5 調理鍋、5a 焼結体、5b 細孔、5c 焼結体の内側表面部に開口した細孔、5d フッ素コーティング層、20 アルミニウム、21 炭素の焼成体。
5 Cooking pot, 5a sintered body, 5b pore, 5c pores opened on the inner surface of the sintered body, 5d fluorine coating layer, 20 aluminum, 21 carbon fired body.

Claims (6)

炭素の粉粒物を主体とする焼結体であって、気体を混入しながら液状の結合材と混練することによって細孔を含有させた基材から成る成形品である調理具。   A cooking tool, which is a sintered body mainly composed of carbon powder, and is a molded article made of a base material containing pores by kneading with a liquid binder while mixing gas. 基材の表面に開口した細孔内に該細孔よりも小径であって前記基材よりも融点の低い微粉体を充填して溶融又は焼成したことを特徴とする請求項1記載の調理具。   2. The cooking tool according to claim 1, wherein fine powder having a smaller diameter than the fine pores and having a melting point lower than that of the base material is filled in the fine pores opened on the surface of the base material and melted or baked. . 基材の表面に開口した細孔内に該細孔よりも小径であって前記基材と同一の材料で構成した微粉体を充填して焼成したことを特徴とする請求項1記載の調理具。   The cooking utensil according to claim 1, wherein fine powders having a diameter smaller than the pores and made of the same material as that of the substrate are filled in the pores opened on the surface of the substrate and baked. . 前記微粉体は、前記焼結体を研磨して生成されることを特徴とする請求項3記載の調理具。   The cooking tool according to claim 3, wherein the fine powder is produced by polishing the sintered body. 前記焼結体の表面にフッ素コーティングを施したことを特徴とする請求項1〜4のいずれかに記載の調理具。   The cooking tool according to any one of claims 1 to 4, wherein a surface of the sintered body is coated with fluorine. 請求項1〜5のいずれかに記載の調理具を備えたことを特徴とする電磁誘導加熱調理器。
An electromagnetic induction heating cooker comprising the cooking tool according to any one of claims 1 to 5.
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