JP3488648B2 - Diatom and disease control agent for seaweed cultivation and its control method - Google Patents
Diatom and disease control agent for seaweed cultivation and its control methodInfo
- Publication number
- JP3488648B2 JP3488648B2 JP34862898A JP34862898A JP3488648B2 JP 3488648 B2 JP3488648 B2 JP 3488648B2 JP 34862898 A JP34862898 A JP 34862898A JP 34862898 A JP34862898 A JP 34862898A JP 3488648 B2 JP3488648 B2 JP 3488648B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- seaweed
- diatom
- iodate
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Cultivation Of Seaweed (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、海苔の養殖課程におい
て発生するケイソウ・病害を駆除する方法もしくは駆除
剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method or an exterminating agent for exterminating diatoms and diseases which occur in a seaweed cultivation process.
【0002】[0002]
【従来の技術】海苔養殖において、雑藻(アオノリ)の
駆除及び赤腐れ病等の細菌の駆除を行うために酸性の液
に浸漬する方法が採用されている。使用する酸として
は、主にクエン酸が使用されている。種付後、海苔が摘
採出来るようになるまでの間に、海苔よりもアオノリの
生育が早いためにアオノリが混生し海苔よりも長くなり
海苔の生長をさまたげてしまう。従って、摘採が始まる
前に酸処理を行いアオノリを駆除するのである。即ち、
アオノリの駆除を目的としては、摘採を開始する前の1
回のみとなる。2. Description of the Related Art In seaweed aquaculture, a method of immersing in an acidic liquid has been adopted for the control of algae and the control of bacteria such as red rot. Citric acid is mainly used as the acid. After seeding, before the seaweed can be harvested, the seaweed grows faster than the seaweed, so that the seaweed mixes and becomes longer than the seaweed, which hinders the growth of the seaweed. Therefore, acid treatment is carried out before the start of plucking to exterminate the aonori. That is,
For the purpose of exterminating Aonori, 1 before the start of plucking
Only once.
【0003】もう1つの酸性処理の目的に、赤腐れ病の
予防・駆除があげられる。赤腐れ病は、ピチウム属乃至
は類縁の水かび類の寄生であるといわれ、主として水温
15℃前後で生育してくる。海苔養殖は、22〜8℃の
水温で行われ15℃前後の赤腐れ病が発生する時期に酸
処理による駆除を行っている。しかし、赤腐れ病が大量
発生した場合には、酸処理での効果がなく、腐敗して漁
期が終了することが多い。Another purpose of acid treatment is prevention and control of red rot disease. Red rot is said to be a parasite of fungi of the genus Pythium and related species, and grows mainly at a water temperature of around 15 ° C. Nori culture is carried out at a water temperature of 22 to 8 ° C, and is exterminated by acid treatment at the time when red rot of about 15 ° C occurs. However, when a large amount of red rot occurs, the acid treatment has no effect, and it often spoils to end the fishing season.
【0004】海苔養殖において全漁期にわたり海苔の生
産に大きな被害を与えるものにケイソウがある。種々の
ケイソウが、漁期中常に発生し、海苔網又は海苔に付着
し海苔の生長を抑制する。ひどい時は、海苔の生産がで
きなくなることがある。酸性処理によりケイソウを少し
は駆除することができるが、効果が不十分である。海苔
又は海苔網に付着するケイソウには、リクモフォラ(L
icmophora)、タベラリア(Tabellar
ia)、シネドラ(Synedra)、バシラリア(B
acillaria)、ニッチア(Nitzchi
a)、ナビキュラ(Navicula)、メロシラ(M
elosira)、アクナンラス(Achnanthe
s)等がある。これらの中のタベラリア・ニッチアとい
うケイソウは、酸性処理では全く効果がなく、このケイ
ソウが大量に発生したら海苔の生産ができなくなってし
まう。従って、タベラリア・ニッチアというケイソウを
駆除でき、種々のケイソウに対しても駆除効果の高い薬
剤の開発が切望されている。[0004] In seaweed aquaculture, diatom is one that causes great damage to seaweed production over the entire fishing season. Various diatoms occur all the time during the fishing season and adhere to the seaweed net or seaweed to suppress the growth of seaweed. When it is terrible, it may not be possible to produce seaweed. Although a little diatom can be exterminated by the acid treatment, its effect is insufficient. For diatoms that adhere to seaweed or seaweed nets, Lichmophora (L
icmophora), tabellaria
ia), Synedra, Basilaria (B)
acilaria), Nichia (Nitzchi
a), Navicula, Merosilla (M)
elosira), Achnanthe (Achnanthe)
s) etc. Among these, the diatom called Taberaria niche is completely ineffective in acid treatment, and if a large amount of this diatom is produced, nori can not be produced. Therefore, there is a strong demand for the development of a drug that can exterminate diatoms such as Taberaria niche and that is highly effective against various diatoms.
【0005】[0005]
【問題を解決するための手段】前記の課題を解決するた
めに鋭意研究を行った結果、ヨウ素化合物を含むpH
3.0以下の酸性の処理液中にて、海苔養殖網を浸漬処
理することによりケイソウ・病害を駆除できることを見
いだした。[Means for Solving the Problems] As a result of intensive studies to solve the above-mentioned problems, it was found that pH containing iodine compounds
It was found that diatom and disease can be eliminated by dipping the seaweed culture net in an acidic treatment solution of 3.0 or less.
【0006】本発明の海苔養殖用のケイソウ・病害の駆
除剤及びその駆除方法は、下記のとおりである。
(1) ヨウ化カリウム、ヨウ化カルシウム、ヨウ化ナトリ
ウム、ヨウ素酸、ヨウ素酸カリウム、ヨウ素酸ナトリウ
ム、ヨウ素酸水素カリウム、ヨード酢酸およびヨード酢
酸ナトリウムから選ばれる少なくとも1種のヨウ素化合
物と、酸とを含有し、かつ、pHを3.0以下に調整し
た処理液からなることを特徴とする海苔養殖用のケイソ
ウ・病害の駆除剤。
(2) 酸が、リンゴ酸、クエン酸、乳酸、酢酸、フマル
酸、グルコン酸、マレイン酸、マロン酸、ギ酸、プロピ
オン酸、酒石酸、アクリル酸、フィチン酸、イタコン
酸、ケトグルタル酸、グルタル酸、イタコン酸、メタン
スルホン酸、アジピン酸、硫酸、硝酸、塩酸およびリン
酸よりなる群から選ばれた1種または2種以上である上
記(1)記載の海苔養殖用のケイソウ・病害の駆除剤。
(3) ヨウ化カリウム、ヨウ化カルシウム、ヨウ化ナトリ
ウム、ヨウ素酸、ヨウ素酸カリウム、ヨウ素酸ナトリウ
ム、ヨウ素酸水素カリウム、ヨード酢酸およびヨード酢
酸ナトリウムから選ばれる少なくとも1種のヨウ素化合
物を含む液に酸を加えてpHを3.0以下に調整した処
理液に、海苔養殖網を浸漬処理することを特徴とする海
苔養殖用のケイソウ・病害の駆除方法。
(4) 酸が、リンゴ酸、クエン酸、乳酸、酢酸、フマル
酸、グルコン酸、マレイン酸、マロン酸、ギ酸、プロピ
オン酸、酒石酸、アクリル酸、フィチン酸、イタコン
酸、ケトグルタル酸、グルタル酸、イタコン酸、メタン
スルホン酸、アジピン酸、硫酸、硝酸、塩酸およびリン
酸よりなる群から選ばれた1種または2種以上である上
記(3)記載の海苔養殖用のケイソウ・病害の駆除方法。The diatom and disease control agent for cultivating seaweed of the present invention and its control method are as follows. (1) At least one iodine compound selected from potassium iodide, calcium iodide, sodium iodide, iodic acid, potassium iodate, sodium iodate, potassium hydrogen iodate, iodoacetic acid and sodium iodoacetate, and an acid A disinfectant for diatom and disease for seaweed aquaculture, which comprises a treatment liquid containing the above and having a pH adjusted to 3.0 or less. (2) acid is malic acid, citric acid, lactic acid, acetic acid, fumaric acid, gluconic acid, maleic acid, malonic acid, formic acid, propionic acid, tartaric acid, acrylic acid, phytic acid, itaconic acid, ketoglutaric acid, glutaric acid, The diatom and disease control agent for seaweed cultivation according to (1) above, which is one or more selected from the group consisting of itaconic acid, methanesulfonic acid, adipic acid, sulfuric acid, nitric acid, hydrochloric acid and phosphoric acid. (3) To a liquid containing at least one iodine compound selected from potassium iodide, calcium iodide, sodium iodide, iodic acid, potassium iodate, sodium iodate, potassium hydrogen iodate, iodoacetic acid and sodium iodoacetate A method for controlling diatoms and diseases for seaweed cultivation, which comprises dipping a seaweed cultivation net in a treatment solution in which an acid is added to adjust the pH to 3.0 or less. (4) acid is malic acid, citric acid, lactic acid, acetic acid, fumaric acid, gluconic acid, maleic acid, malonic acid, formic acid, propionic acid, tartaric acid, acrylic acid, phytic acid, itaconic acid, ketoglutaric acid, glutaric acid, The method for controlling diatom and disease for seaweed cultivation according to (3) above, which is one or more selected from the group consisting of itaconic acid, methanesulfonic acid, adipic acid, sulfuric acid, nitric acid, hydrochloric acid and phosphoric acid.
【0007】試験1よりわかるように、ヨウ化カリウム
単独もしくは酸性処理剤のpH1.6の処理液で処理し
てもタベラリアは駆除できないが、ヨウ化カリウムと酸
を含有するpH1.5〜1.6の処理液で処理すること
により、海苔を傷めることなくケイソウ(タベラリア)
を駆除することができた。試験1及び試験4よりヨウ素
化合物と酸との併用によりケイソウを駆除することがで
きることがわかった。試験2より、ヨウ素化合物を含有
する液のpHを3以下に調整することによりケイソウを
駆除することができ、4以上になると全く効果を示さな
くなることを示している。試験3の赤腐れ菌駆除試験
は、酸性処理剤にヨウ素化合物を併用することにより、
より短時間で赤腐れ菌を駆除することができることを示
している。以上より、ヨウ素化合物を含むpH3.0以
下の処理液で処理することにより、酸性処理剤で駆除す
ることができなかったケイソウを駆除することができ、
かつ、赤腐れ菌の駆除効果を高めることができることが
わかった。As can be seen from Test 1, taberaria cannot be exterminated by treatment with potassium iodide alone or a treatment liquid of an acidic treatment agent having a pH of 1.6, but potassium iodide and an acid-containing pH of 1.5-1. By treating with the treatment liquid of No. 6, diatom (Taberaria) without damaging seaweed
Was able to get rid of. From Test 1 and Test 4, it was found that diatom can be exterminated by the combined use of an iodine compound and an acid. Test 2 shows that diatoms can be exterminated by adjusting the pH of the liquid containing the iodine compound to 3 or less, and no effect is exhibited at 4 or more. The test for red-rot fungus extermination in Test 3 was carried out by using an iodine compound in combination with an acidic treating agent.
It shows that the red-rot fungus can be eliminated in a shorter time. From the above, by treating with a treatment liquid containing an iodine compound and having a pH of 3.0 or less, it is possible to eliminate diatoms that could not be eliminated by the acidic treatment agent,
Moreover, it was found that the effect of exterminating the red-rot fungus can be enhanced.
【0008】(試験1)酸性処理剤「ダッシュ」(扶桑
化学工業(株)製)の100倍海水希釈液に、ヨウ化カ
リウムを添加溶解し、各濃度の処理液を調整した。対照
として、「ダッシュ」の100倍希釈液単独及びヨウ化
カリウム単独の試験区を設けた。処理水温10℃で、ケ
イソウ(タベラリア)が付着している海苔葉体を一定時
間(10、20、30、40、50、60、90、12
0、150、180、210、240、270、300
秒)浸漬処理を行った。その後海水で洗浄し、シャーレ
中にて静置培養した。太陽光を1時間照射した後ケイソ
ウの駆除効果を顕微鏡下で観察した。ケイソウが脱色さ
れたものを死滅したと判定した。結果を表1に、ダッシ
ュの組成を表2に示す。(Test 1) Potassium iodide was added to and dissolved in a 100-fold diluted seawater of an acidic treatment agent "Dash" (manufactured by Fuso Chemical Industry Co., Ltd.) to prepare treatment solutions having various concentrations. As a control, a test section containing a 100-fold diluted “dash” alone and potassium iodide alone was provided. At the treated water temperature of 10 ° C, the seaweed leaf bodies to which the diatom (Taberaria) adheres are kept for a certain time (10, 20, 30, 40, 50, 60, 90, 12
0, 150, 180, 210, 240, 270, 300
Second) Immersion treatment was performed. Thereafter, the plate was washed with seawater and statically cultured in a petri dish. After irradiating with sunlight for 1 hour, the control effect of diatom was observed under a microscope. The decolorized diatom was judged to be dead. The results are shown in Table 1, and the composition of dashes is shown in Table 2.
【0009】[0009]
【表1】 [Table 1]
【0010】[0010]
【表2】 [Table 2]
【0011】(試験2)ヨウ化カリウム100ppmの
海水溶液に、酸性処理剤「ダッシュ」を添加してpH値
を1.5、2.0、2.5、3.0、4.0、5.0に
調整した。他は試験1と同様にしてケイソウ(タベラリ
ア)の駆除試験を行った。結果を表3に示す。(Test 2) An acidic treating agent "Dash" was added to a seawater solution containing 100 ppm of potassium iodide to adjust pH values to 1.5, 2.0, 2.5, 3.0, 4.0, and 5. Adjusted to 0.0. Except for the above, a diatom (Tabelaria) extermination test was conducted in the same manner as in Test 1. The results are shown in Table 3.
【0012】[0012]
【表3】 [Table 3]
【0013】(試験3)
下記に示す各種のヨウ素化合物を用い、試験1と同様に
してケイソウ(ニッチア)駆除試験を行なった。結果を
表4に示す。 (Test 3) Using various iodine compounds shown below, a diatom (Nicha) extermination test was conducted in the same manner as in Test 1. The results are shown in Table 4 .
【0014】[0014]
【表4】 [Table 4]
【0015】[0015]
【0016】(試験4)
酸性処理剤「たから1号」(第一製網(株)製)の10
0倍又は150倍希釈液に、ヨウ化カリウムを添加溶解
し、200ppm又は400ppmになるように調整し
た。処理水温10℃にて赤腐れ菌に感染している海苔葉
体を一定時間(10、20、30、40、50、60、
90、120、150、180、210、240、27
0、300秒)浸漬処理を行なった。その後、海水で洗
浄しシャーレ中にて静置培養した。2日後に赤腐れ菌の
駆除効果を顕微鏡下で確認した。結果を表5に示す。(Test 4) Acid treatment agent "Takara No. 1" (manufactured by Daiichi Seimitsu Co., Ltd.) 10
Potassium iodide was added and dissolved in a 0-fold or 150-fold diluted solution to adjust the concentration to 200 ppm or 400 ppm. Nori leaves infected with red rot fungus at treated water temperature of 10 ℃ for a certain period of time (10, 20, 30, 40, 50, 60,
90, 120, 150, 180, 210, 240, 27
Immersion treatment was performed. Then, the plate was washed with seawater and statically cultured in a petri dish. After 2 days, the control effect of the red-rot fungus was confirmed under a microscope. The results are shown in Table 5 .
【0017】[0017]
【表5】 [Table 5]
【0018】[0018]
【発明の効果】本発明によれば、ヨウ素化合物と酸とを
含有し、かつ、pHを3.0以下に調整した処理剤で、
海苔養殖網を処理することにより、従来の酸処理剤で駆
除することができない種々のケイソウを駆除することが
でき、かつ、赤腐れ病等の病害の駆除効果を高めること
ができる海苔養殖用のケイソウ・病害の駆除剤及びその
駆除方法が提供される。According to the present invention, a treatment agent containing an iodine compound and an acid and having a pH adjusted to 3.0 or less,
By treating the seaweed aquaculture net, various diatoms that cannot be removed by conventional acid treatment agents can be removed, and the effect of removing diseases such as red rot can be enhanced. Disinfectants for diatom and disease and methods for exterminating the same are provided.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭58−10509(JP,A) 特開 昭54−160680(JP,A) 特開 昭60−224607(JP,A) 特開 平9−278609(JP,A) 特開 平10−243751(JP,A) 特開 昭63−68508(JP,A) 特開 昭56−77209(JP,A) 特開 昭48−83654(JP,A) 特開 昭58−32806(JP,A) (58)調査した分野(Int.Cl.7,DB名) A01N 59/12 A01G 33/02 A01N 25/02 CA(STN) REGISTRY(STN) JOIS(JICSTファイル)─────────────────────────────────────────────────── ─── Continuation of the front page (56) Reference JP-A-58-10509 (JP, A) JP-A-54-160680 (JP, A) JP-A-60-224607 (JP, A) JP-A-9- 278609 (JP, A) JP 10-243751 (JP, A) JP 63-68508 (JP, A) JP 56-77209 (JP, A) JP 48-83654 (JP, A) JP-A-58-32806 (JP, A) (58) Fields investigated (Int.Cl. 7 , DB name) A01N 59/12 A01G 33/02 A01N 25/02 CA (STN) REGISTRY (STN) JOIS (JICST File)
Claims (4)
ウ化ナトリウム、ヨウ素酸、ヨウ素酸カリウム、ヨウ素
酸ナトリウム、ヨウ素酸水素カリウム、ヨード酢酸およ
びヨード酢酸ナトリウムから選ばれる少なくとも1種の
ヨウ素化合物と、酸とを含有し、かつ、pHを3.0以
下に調整した処理液からなることを特徴とする海苔養殖
用のケイソウ・病害の駆除剤。1. At least one iodine compound selected from potassium iodide, calcium iodide, sodium iodide, iodic acid, potassium iodate, sodium iodate, potassium hydrogen iodate, iodoacetic acid and sodium iodoacetate, A disinfectant for diatom and disease for seaweed aquaculture, comprising a treatment liquid containing an acid and having a pH adjusted to 3.0 or less.
酸、フマル酸、グルコン酸、マレイン酸、マロン酸、ギ
酸、プロピオン酸、酒石酸、アクリル酸、フィチン酸、
イタコン酸、ケトグルタル酸、グルタル酸、イタコン
酸、メタンスルホン酸、アジピン酸、硫酸、硝酸、塩酸
およびリン酸よりなる群から選ばれた1種または2種以
上である請求項1記載の海苔養殖用のケイソウ・病害の
駆除剤。2. The acid is malic acid, citric acid, lactic acid, acetic acid, fumaric acid, gluconic acid, maleic acid, malonic acid, formic acid, propionic acid, tartaric acid, acrylic acid, phytic acid,
The seaweed aquaculture according to claim 1, which is one or more selected from the group consisting of itaconic acid, ketoglutaric acid, glutaric acid, itaconic acid, methanesulfonic acid, adipic acid, sulfuric acid, nitric acid, hydrochloric acid and phosphoric acid. Disinfectant for diatom and disease.
ウ化ナトリウム、ヨウ素酸、ヨウ素酸カリウム、ヨウ素
酸ナトリウム、ヨウ素酸水素カリウム、ヨード酢酸およ
びヨード酢酸ナトリウムから選ばれる少なくとも1種の
ヨウ素化合物を含む液に酸を加えてpHを3.0以下に
調整した処理液に、海苔養殖網を浸漬処理することを特
徴とする海苔養殖用のケイソウ・病害の駆除方法。3. At least one iodine compound selected from potassium iodide, calcium iodide, sodium iodide, iodic acid, potassium iodate, sodium iodate, potassium hydrogen iodate, iodoacetic acid and sodium iodoacetate. A method for controlling diatoms and diseases for seaweed cultivation, which comprises dipping a seaweed cultivation net in a treatment solution in which an acid is added to the solution to adjust the pH to 3.0 or less.
酸、フマル酸、グルコン酸、マレイン酸、マロン酸、ギ
酸、プロピオン酸、酒石酸、アクリル酸、フィチン酸、
イタコン酸、ケトグルタル酸、グルタル酸、イタコン
酸、メタンスルホン酸、アジピン酸、硫酸、硝酸、塩酸
およびリン酸よりなる群から選ばれた1種または2種以
上である請求項3記載の海苔養殖用のケイソウ・病害の
駆除方法。4. The acid is malic acid, citric acid, lactic acid, acetic acid, fumaric acid, gluconic acid, maleic acid, malonic acid, formic acid, propionic acid, tartaric acid, acrylic acid, phytic acid,
The seaweed aquaculture according to claim 3, which is one or more selected from the group consisting of itaconic acid, ketoglutaric acid, glutaric acid, itaconic acid, methanesulfonic acid, adipic acid, sulfuric acid, nitric acid, hydrochloric acid and phosphoric acid. How to get rid of diatom and disease.
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JP34862898A JP3488648B2 (en) | 1998-12-08 | 1998-12-08 | Diatom and disease control agent for seaweed cultivation and its control method |
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JP34862898A JP3488648B2 (en) | 1998-12-08 | 1998-12-08 | Diatom and disease control agent for seaweed cultivation and its control method |
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Publication Number | Publication Date |
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JP2000169315A JP2000169315A (en) | 2000-06-20 |
JP3488648B2 true JP3488648B2 (en) | 2004-01-19 |
Family
ID=18398280
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JP34862898A Expired - Lifetime JP3488648B2 (en) | 1998-12-08 | 1998-12-08 | Diatom and disease control agent for seaweed cultivation and its control method |
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JP2005272802A (en) * | 2004-02-23 | 2005-10-06 | Nemoto Kikaku Kogyo Kk | Antifouling ship-bottom paint and method for preventing organism from attaching to submerged structure, etc., using the same |
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1998
- 1998-12-08 JP JP34862898A patent/JP3488648B2/en not_active Expired - Lifetime
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