JP3454722B2 - Polymer electrolyte fuel cell - Google Patents

Description

Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a portable power supply,
The present invention relates to a room temperature operation type polymer electrolyte fuel cell used for an electric vehicle power supply, a home cogeneration system, and the like. 2. Description of the Related Art In a polymer electrolyte fuel cell, a fuel gas such as hydrogen and an oxidizing gas such as air are electrochemically reacted in a gas diffusion electrode to generate electricity and heat simultaneously. . An example of a polymer electrolyte fuel cell will be described with reference to FIG. On both surfaces of a polymer electrolyte membrane 3 for selectively transporting hydrogen ions, a catalytic reaction layer 2 mainly composed of a carbon powder carrying a platinum-based metal catalyst is arranged in close contact. On the outer surface of the catalytic reaction layer 2, a diffusion layer 1 having both gas permeability and electronic conductivity is disposed in close contact. An electrode 9 is constituted by the catalytic reaction layer 2 and the diffusion layer 1. The electrode 9 and the polymer electrolyte membrane 3 are integrated in advance and constitute an electrode electrolyte membrane assembly (hereinafter referred to as MEA) 10. Further, a gas seal material or a gasket is disposed around the electrode 9 with the polymer electrolyte membrane 3 interposed therebetween so that the supplied fuel gas and the oxidizing gas do not leak outside or mix with each other. These are ME
It may be integrated with A24. In the above-described fuel cell, as shown in FIG. 2, a sealing material is interposed between the electrodes 9 with the polymer electrolyte membrane 3 interposed therebetween so that hydrogen and air do not leak out or mix with each other. 17 and an O-ring 18. As another sealing method, as shown in FIG.
A gasket 19 made of resin or a metal plate and having the same thickness as the electrode 9 is provided.
There is also a structure in which the gap 9 is sealed with grease or an adhesive.
In recent years, as shown in FIG. 4, as the MEA 10, a resin 21 having a sealing effect is previously impregnated into a portion requiring gas sealing properties, and the resin 21 is solidified. There is also a proposal for a method for securing the same. Outside the MEA 10, a conductive separator plate 4 for mechanically fixing the MEA 10 and electrically connecting adjacent MEAs 10 to each other in series is provided.
Is arranged. A gas passage 5 for supplying a fuel gas and an oxidizing gas to the surface of the electrode 9 and carrying away a gas generated by the reaction and an excess gas is formed in a portion of the separator plate 4 which comes into contact with the MEA 10. . Gas flow path 5
Can be provided separately from the separator plate 4, but FIG.
As shown in (1), a method is generally used in which a groove is formed on the surface of the separator plate 4 to form a gas flow path 5. [0004] Many fuel cells have a stacked structure in which a number of cells are stacked. In the case of a fuel cell, a cooling plate is provided for every one or two cells of a unit cell in order to discharge heat generated together with electric power to the outside of the cell. The cooling plate generally has a structure in which a heat medium such as cooling water flows through a thin metal plate. This keeps the battery temperature constant and uses the generated thermal energy in the form of hot water. There is also a method in which a flow path is formed on the back surface of the separator plate 4 constituting the unit cell, that is, on the surface where cooling water is to flow, and the separator plate 4 itself functions as a cooling plate. At this time, an O-ring or gasket is also required to seal the heat medium such as cooling water, but this seal must completely crush the O-ring to ensure sufficient conductivity between the top and bottom of the cooling plate. There is. [0005] In such a stacked battery, a supply and discharge hole for fuel gas and cooling water to each unit cell called a manifold is required. These manifolds are classified into an internal manifold type and an external manifold type according to the arrangement form. The so-called internal manifold type, in which supply and discharge holes for fuel gas and cooling water are secured inside the stacked battery, is generally used. However,
In the case of operating a battery using actual gas obtained by reforming city gas and hydrogenating, the electrode is poisoned by CO as a result of an increase in the CO concentration in the downstream region of the fuel gas flow path. And the decrease in the temperature may further promote electrode poisoning. In order to mitigate such a phenomenon that lowers the performance of the battery, as a structure that takes the frontage of the gas supply / discharge unit from the manifold to each cell as wide as possible
The external manifold type has been reviewed. In both the internal manifold type and the external manifold type, a plurality of cells including a cooling unit are stacked in one direction, a pair of end plates are arranged at both ends, and the both end plates are fixed with fastening rods. It is necessary to. As for the tightening method, it is desirable that the unit cells be tightened as uniformly as possible within the plane. From the viewpoint of mechanical strength, a metal material such as stainless steel is usually used for the end plate and the fastening rod. These end plates and fastening rods and the stacked battery are electrically insulated by an insulating plate so that current does not leak out through the end plates. As for the fastening rod, a method of passing through a through hole inside the separator and a method of fastening the entire lamination pond with a metal belt over an end plate have been proposed. Further, in any of the sealing methods shown in FIGS. 2, 3 and 4, a constant tightening pressure is required in order to maintain the sealing property and keep the contact resistance between the electrode and the separator plate or between the separator plates small. It is. Therefore, a configuration is adopted in which a screw spring or a disc spring is inserted between the fastening rod and the end plate. By this tightening pressure, electrical contact between components of the battery such as the separator plate, the electrode, and the electrolyte membrane is secured. [0007] In order for the stacked battery to exhibit stable performance, it is necessary that the fuel gas, the oxidizing gas, and the cooling water supplied to the cells be uniformly distributed to each of the cells. In general, it is devised to increase the cross-sectional area of the manifold through which each fluid to be supplied flows, reduce the flow velocity in the manifold of each fluid, and reduce the influence of the pressure gradient generated due to the dynamic pressure of the fluid. However, in order to reduce the size and weight of the fuel cell, the cross-sectional area of the manifold must be as small as possible. Conventionally, electricity generated in a stacked battery has been collected by a current collector and output to an external device connected to an end thereof. Further, in a laminated battery using a current collecting plate in which a part of the current collecting plate protrudes from the outer shape of the laminated battery, the protruding portion is connected to an external device. For this reason, the electrical connection portion has a shape that protrudes larger than the outer shape of the laminated battery, so that the entire battery is increased in size and the degree of freedom in mounting the device is reduced. SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and has as its object to provide a polymer electrolyte fuel cell which is small and lightweight, and has a high degree of freedom in equipment mounting. And The present invention provides a solid polymer electrolyte.
A dissolving membrane, and a touch panel disposed with the solid polymer electrolyte membrane interposed therebetween.
A pair of electrodes having a medium reaction layer, and hydrogen on one of the electrodes.
Of fuel gas containing oxygen and the other containing oxygen
Cell with means for supplying the agent gas
A plurality of fuel cells are stacked with a separator
Distribute and supply gas, oxidizer gas and cooling water
Supply manifold and the fuel cell from each of the cells.
Exhaust gas from which feed gas, oxidant gas and cooling water are discharged.
Collects electricity generated from the stack and the stacked cells.
Polymer electrolyte fuel cell having a current collector
As the cross-sectional area of the supply manifold becomes downstream,
And the cross-sectional area of the exhaust manifold is downstream
Polymer electrolyte fuel cells
You. In a polymer electrolyte fuel cell, fuel, oxidizing gas, and cooling water flow in from the ends of the unit cells in the stacking direction, and after flowing through each unit cell, flow out in a direction opposite to the flowing direction. Let it. Further, the current collector plate for collecting current of the unit cells, the end plates to provide a clamping pressure to the polymer electrolyte fuel cell, via an insulation means, even if the through-configuration
No. DETAILED DESCRIPTION OF THE INVENTION A polymer electrolyte fuel cell according to the present invention comprises: a solid polymer electrolyte membrane; a pair of electrodes having a catalytic reaction layer interposed between the solid polymer electrolyte membrane; Means for supplying a fuel gas containing hydrogen to one of them and a means for supplying an oxidizing gas containing oxygen to the other,
A polymer electrolyte fuel cell in which a plurality of fuel cells are stacked with a conductive separator interposed therebetween, wherein a fuel gas is supplied from a unit cell at one end of the unit cells to a unit cell at the other end in the stacking order. A supply manifold for distributing and supplying the oxidizing gas and the cooling water, respectively, and a discharge manifold for discharging the fuel gas, the oxidizing gas and the cooling water from the unit cells at the other end in the stacking order. Another polymer electrolyte fuel cell according to the present invention comprises a solid polymer electrolyte membrane, a pair of electrodes having a catalytic reaction layer disposed with the solid polymer electrolyte membrane interposed therebetween, and hydrogen being applied to one of the electrodes. A plurality of cells, each of which is provided with a means for supplying a contained fuel gas and supplying an oxidizing gas containing oxygen to the other, are stacked with a conductive separator interposed therebetween, and the fuel cells, the oxidizing gas and A polymer electrolyte fuel cell including a supply manifold for supplying cooling water, and a discharge manifold for discharging fuel gas, oxidizing gas and cooling water from each of the cells, wherein the supply manifold is The cross-sectional area decreases as it goes downstream, and the cross-sectional area of the exhaust manifold increases as it goes downstream . According to the present invention, instead of the conventional fluid uniform distribution method in which the manifold cross-sectional area is increased to reduce the pressure gradient generated by the dynamic pressure of the fluid, the flow direction of each fluid flows from the end of the laminated battery in the laminating direction. Then, after passing through each unit cell, a fluid uniform distribution method in which the fluid is discharged in the opposite direction to the inflow direction is used. Thereby, the polymer electrolyte fuel cell of the present invention is an electrolyte membrane, an electrode having a catalytic reaction layer, a unit cell composed of battery components such as a separator, a fuel gas required for operation of a stacked battery in which a plurality of stacked cells, The flow direction of each fluid of the oxidizing gas and the cooling water is caused to flow from the end of the stacked battery in the stacking direction, and after flowing through each unit cell, is caused to flow out in a direction opposite to the flow direction of the stacked battery. This makes it possible to change the length of the flow path through which each fluid passes through each cell. Therefore, by balancing the pressure gradient caused by the dynamic pressure generated in each fluid and the pressure loss caused by a change in the flow path length, each fluid can be made uniform in each cell. The adjustment of the pressure gradient by the dynamic pressure is performed by reducing the cross-sectional area of the manifold, so that a fuel cell having a lightweight and compact configuration can be obtained. Further, in the present invention, a structure is used in which the current collecting member is extended from the current collecting plate in the stacking direction of the stacked batteries, and the current collecting member penetrates the end plate via the insulating means. The polymer electrolyte fuel cell of the present invention is an electrolyte membrane, an electrode having a catalytic reaction layer, a unit cell composed of battery components such as a separator,
From a current collecting plate that electrically contacts the plurality of stacked batteries and collects electricity generated from the stacked batteries, an end plate that applies a tightening force to the stacked batteries and the current collecting plate via an electrical insulating means. The power collection is performed by extending the penetrating current collection member. As a result, electrical connection with external devices can be made without protruding from the outer shape of the stacked battery, and miniaturization and improvement in the degree of freedom of device mounting can be realized. Embodiments of the present invention will be described with reference to the drawings. Example 1 A carbon powder having a particle size of several microns or less was immersed in an aqueous chloroplatinic acid solution, and a platinum catalyst was supported on the surface of the carbon powder by a reduction treatment. At this time, the weight ratio of carbon to the supported platinum was 1: 1.
Next, the carbon powder carrying platinum was dispersed in an alcohol solution of a polymer electrolyte to form a slurry. On the other hand, a 400 μm thick carbon paper serving as an electrode is
After impregnating in an aqueous dispersion of a fluororesin (NEOFLON ND-1 manufactured by Daikin Industries, Ltd.), this was dried and subjected to heat treatment at 400 ° C. for 30 minutes to impart water repellency to the carbon paper. Next, a slurry containing carbon powder was uniformly applied to one surface of the water-repellent carbon paper to form a catalyst layer 2, thereby obtaining an electrode 9.
A pair of the obtained electrodes 9 is placed on both sides of the polymer electrolyte membrane 3,
After the surfaces provided with the catalyst layers 2 were superposed so as to face the polymer electrolyte membranes 3 respectively, they were dried to obtain an electrode electrolyte membrane assembly (hereinafter referred to as MEA) 10. Here, the silicon rubber functions as a gasket for preventing gas supplied to the battery from leaking or mixing with each other. The obtained MEA 10 was sandwiched between both sides of the separator plate 4 made of airtight carbon to assemble a unit cell. The separator plate 4 has a thickness of 4 mm.
The surface is cut by 2mm in width and 1mm in depth
The gas passage 5 is cut, and a manifold hole 6 for gas and a manifold hole 7 for cooling water are arranged around the gas passage 5. When the MEA 10 was sandwiched between separator plates, a gasket 8 having an EPDM sheet attached to both surfaces of a polyethylene terephthalate (PET) sheet having the same outer dimensions as the carbon separator plate 4 was disposed around the electrode 9. After stacking two such cells, a separator plate 4 having a cooling channel through which cooling water flows was stacked. Thus, a battery constituent unit was obtained. Note that no O-ring was used for sealing the cooling channel. A fuel cell as shown in FIG. 2 was assembled by laminating a plurality of the obtained cell constituent units. First, the same battery constituent unit as 25
(Ie, 50 cells), and a metal current collector 100 and an insulating plate 10 made of an electrically insulating material are provided on both end surfaces.
1, and the end plate 102 were arranged. Then, fastening rod 1
At 03, the end plates 102 were connected to each other, and a laminated battery (not shown) sandwiched therebetween was fixed. Each fluid of the fuel gas, the oxidizing gas, and the cooling water flows toward the fuel cell, and a fuel gas supply pipe 103 provided on the upper end plate 102.
The gas is supplied from the oxidizing gas supply pipe 104 and the cooling water supply pipe 105 in the direction of the arrow in the figure. These supply pipes 10
3, 104 and 105 are connected to respective manifold holes (not shown) of the stacked battery. The manifold hole of each fluid has its cross-sectional area gradually decreasing downward. Each fluid that has passed through the stacked battery is discharged from the fuel gas discharge pipe 106, the oxidizing gas discharge pipe 107 and the cooling water discharge pipe 108 to the outside of the battery in the direction of the arrow in the figure.
Here, the manifold holes (not shown) of the respective fluids connected to the respective discharge pipes 106, 107 and 108 are configured such that the cross-sectional area thereof gradually decreases upward. In this way, each fluid that has passed through each unit cell and each cooling plate through the inflow-side manifold passes through the outflow-side manifold, and is discharged out of the battery from the end plate side where each fluid has flowed. With this configuration, it is possible to change the flow path length of each fluid passing through each unit cell. This makes it possible to balance the pressure gradient caused by the dynamic pressure generated in each fluid and the pressure loss caused by a change in the flow path length, thereby enabling each fluid to be uniformly supplied to each cell. Furthermore, since the pressure gradient due to dynamic pressure is adjusted by reducing the manifold cross-sectional area, it becomes possible to reduce the external dimensions,
A lightweight and compact fuel cell configuration can be obtained. Example 2 A fuel cell shown in FIG. 6 was assembled by using a stacked battery in which 25 cells similar to those used in Example 1 were stacked. A metal current collecting plate 601 and an insulating plate 602 were overlapped on both stacked surfaces of the stacked battery 605, and an end plate 603 was further stacked on the surface thereof. The pair of end plates 603 each have a recess 60 on its side.
3a. The stacked battery 605 was fixed by fastening the fastening rod 604 to the concave portion 603a. The insulating plate 602 and the end plate 603 are provided with through holes 602a and 602, respectively.
03a. A pair of current collecting members 600 were mounted through the holes 602a and 603a. Current collecting member 60
The leading end of 0 is electrically connected to the current collecting plate 601 and functions as an output terminal. Note that the current collecting member 600 and the end plate 603 are insulated by an electrically insulating material. The electrical insulating material that insulates the end plate 603 and the current collecting member 600 is the insulating plate 60
The same effect can be obtained even if the unit 2 is integrated. With this configuration, when electricity is taken out of the stacked battery, the connecting member for connecting the stacked battery and the device or the like can be compactly fitted without protruding from the outer shape of the stacked battery, and the degree of freedom in mounting the device can be improved. According to the present invention, it is possible to eliminate the deterioration of the distribution of each fluid due to the pressure gradient due to the dynamic pressure generated in each fluid, instead of adjusting the manifold cross-sectional area, and to reduce the manifold cross-sectional area. This contributes to downsizing .

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a partially cutaway perspective view showing a configuration of a cell member of a polymer electrolyte fuel cell. FIG. 2 is a longitudinal sectional view of an essential part showing an example of a fluid sealing method in a polymer electrolyte fuel cell. FIG. 3 is a longitudinal sectional view of a main part showing another example. FIG. 4 is a longitudinal sectional view of a main part showing still another example. FIG. 5 is a schematic perspective view showing the configuration of a polymer electrolyte fuel cell according to one embodiment of the present invention. FIG. 6 is a longitudinal sectional view showing a configuration of a polymer electrolyte fuel cell according to another embodiment of the present invention. DESCRIPTION OF SYMBOLS 1 Diffusion layer 2 Catalytic reaction layer 3 Polymer electrolyte membrane 4 Separator plate 5 Gas flow path 6 Gas manifold hole 7 Cooling water manifold hole 8, 19 Gasket 9 Electrode 10 Electrode electrolyte assembly 17 Sealing material 18 O-ring 21 Resin 100, 601 Current collector plate 101, 602 Insulating plate 102, 603 End plate 104 Fuel gas supply tube 105 Oxidant gas supply tube 106 Cooling water supply tube 107 Fuel gas discharge tube 108 Oxidant gas discharge tube 109 Cooling water Discharge pipe 110, 605 Stacked battery 600 Current collector 602a, 603a Hole 604 Fastening rod

──────────────────────────────────────────────────の Continuing on the front page (72) Inventor Kazufumi Nishida 1006 Kadoma Kadoma, Kadoma City, Osaka Prefecture Inside Matsushita Electric Industrial Co., Ltd. In-house (72) Inventor Eiichi Yasumoto 1006 Kadoma, Kadoma, Osaka Prefecture Inside Matsushita Electric Industrial Co., Ltd. (72) Inventor Yasushi Yasushi 1006 Odaka, Kazuma, Kadoma, Osaka Pref. Inventor Teruhisa Kamihara 1006 Kadoma Kadoma, Kadoma City, Osaka Prefecture (72) Inside Matsushita Electric Industrial Co., Ltd. (72) Inventor Toshihiro Matsumoto 1006 Kadoma Kadoma, Kadoma City, Osaka Prefecture Matsushita Electric Industrial Co., Ltd. 4-3555061 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) H01M 8/10 H01M 8/24

Claims (1)

(57) [Claim 1] A solid polymer electrolyte membrane, a pair of electrodes having a catalytic reaction layer disposed with the solid polymer electrolyte membrane interposed therebetween, and hydrogen applied to one of the electrodes. single cell and means for supplying an oxidant gas containing oxygen a fuel gas containing the feed to and the other is a plurality stacked via conductive separators, fuel gas, oxidant gas to the single cell And cold
A supply manifold for distributing and supplying recirculated water,
The fuel gas, oxidant gas and
A discharge manifold cooling water is discharged, the electricity generated from the laminated unit cells comprising a polymer electrolyte fuel cell having a current collector plate to the current collector, the supply manifold
As the cross-sectional area decreases as it goes downstream,
Solid polymer fuel cells ing large as the cross-sectional area of the Nihorudo is downstream.