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JP2973305B2 - Pressurized oxygen dissolution method - Google Patents

Pressurized oxygen dissolution method

Info

Publication number
JP2973305B2
JP2973305B2 JP2656598A JP2656598A JP2973305B2 JP 2973305 B2 JP2973305 B2 JP 2973305B2 JP 2656598 A JP2656598 A JP 2656598A JP 2656598 A JP2656598 A JP 2656598A JP 2973305 B2 JP2973305 B2 JP 2973305B2
Authority
JP
Japan
Prior art keywords
oxygen
water
tank
pressurized
dissolved
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2656598A
Other languages
Japanese (ja)
Other versions
JPH11207162A (en
Inventor
浩史 山本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yamahiro Co Ltd
Original Assignee
Yamahiro Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yamahiro Co Ltd filed Critical Yamahiro Co Ltd
Priority to JP2656598A priority Critical patent/JP2973305B2/en
Priority to KR1019990001601A priority patent/KR100306790B1/en
Publication of JPH11207162A publication Critical patent/JPH11207162A/en
Application granted granted Critical
Publication of JP2973305B2 publication Critical patent/JP2973305B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、排水処理における
曝気施設や、河川・湖沼における水中の溶存酸素不足
を、空気と純酸素を併用した加圧溶解によって高い効率
で水中に酸素を溶解させる方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for dissolving oxygen in water with high efficiency by pressurized dissolution of air and pure oxygen together with aeration facilities in wastewater treatment, and the lack of dissolved oxygen in water in rivers and lakes. It is about.

【0002】[0002]

【従来の技術】排水処理施設や汚れた河川・湖沼等にお
いて、酸素を用いたエアレーションを行うことにより、
微生物の活動を維持し汚水を処理する方法が知られてい
る。
2. Description of the Related Art Aeration using oxygen is performed in wastewater treatment facilities and dirty rivers and lakes.
Methods for maintaining the activity of microorganisms and treating wastewater are known.

【0003】この方法は、通常の空気によるエアレーシ
ョンに比べ、少風量で高い溶存酸素濃度を維持できるた
め、高濃度の下水や工場排水の処理に適し、また施設の
敷地面積が少なくて済むことから、過負荷となっている
処理場の改善にも利用できるメリットがある。
[0003] This method can maintain a high dissolved oxygen concentration with a small air volume compared to ordinary air aeration, so that it is suitable for treating high-concentration sewage and industrial wastewater, and requires a small site area of the facility. In addition, there is a merit that can be used for improvement of an overloaded treatment plant.

【0004】[0004]

【発明が解決しようとする課題】ところで、従来のエア
レーションを行うに際しては、水底に沈めた吹出口から
空気や酸素を気泡として放出し、この気泡を浮上させな
がら水中の溶存酸素を増加させているが、このような方
法では、酸素の溶解効率が低いことから、高負荷時にお
ける高い酸素供給速度の要求に応じきれないという問題
を招来する。
When performing conventional aeration, air or oxygen is released as air bubbles from an outlet submerged in the water bottom, and the dissolved oxygen in the water is increased while floating the air bubbles. However, such a method causes a problem that the efficiency of dissolving oxygen is low, so that a demand for a high oxygen supply rate under a high load cannot be satisfied.

【0005】本発明は叙上の如き実状に対処し、特に少
なくとも酸素ガスの水中への混合溶解方式を見いだすこ
とにより、処理水と酸素を加圧したのち大気放するこ
とにより、処理水における溶存酸素量を大きく増大させ
ることを目的とするものである。
The present invention addresses the such circumstances on ordination, in particular by finding mixed and dissolved scheme in water of at least oxygen gas, by releasing air solutions then pressurized treated water and oxygen, in the treated water The purpose is to greatly increase the amount of dissolved oxygen.

【0006】[0006]

【課題を解決するための手段】すなわち上記目的に適合
する本発明の加圧式酸素溶解方法は、加圧ポンプ等によ
り汲み上げた水を加圧用タンクに入れ、このタンク内に
加圧した酸素を供給することによりこの酸素を加圧状態
で水に溶解させ、のちこの水を大気解放することにより
上記溶存した酸素を微細気泡となし、この微細気泡を水
に浮遊させることによりこの気泡の酸素を水中に溶解
させるに際し、上記加圧用タンクを立直した筒状に形成
し、この加圧用タンクの外周部上部に、液面の斜め上
方からタンクの接線方向に水を噴射するノズル部を形成
して、該ノズル部より噴射した水によりタンク上部の酸
素を巻き込みながら上記加圧用タンク内に渦流を発生さ
タンク内で回転させて酸素を水に溶解させることを特
徴とする。
According to the pressurized oxygen dissolving method of the present invention which meets the above-mentioned object, water pumped by a pressurizing pump or the like is put into a pressurizing tank, and pressurized oxygen is supplied into the tank. was dissolved in water the oxygen under pressure by, later oxygen microbubbles and without the above-mentioned dissolved by the water to release the air, by floating Yu the fine bubbles in the water of oxygen of the bubble When dissolving in water, the above-mentioned pressurizing tank is formed in a vertical cylindrical shape, and a nozzle portion is formed in the upper part of the outer peripheral portion of the pressurizing tank , which injects water in a tangential direction of the tank from obliquely above the liquid level.
To, characterized Rukoto oxygen is rotated in a tank to generate a vortex in the pressurizing tank while entrained oxygen tank top by the water jetted from the nozzle portion is dissolved in water.

【0007】[0007]

【作用】上記本発明の酸素溶解方法では、加圧状態とす
ることにより水に多くの酸素を溶解させると共に、大気
放により通常気圧では溶解されなかった余分な酸素を
微細な気泡となし、この微細気泡が水中に長時間浮遊す
ることにより、2次的な酸素移動が起こって高い効率の
酸素溶解が行われるが、このとき、加圧用タンク内の水
に酸素を溶解させるに際し、液面の斜め上方からタンク
の接線方向に水がタンク上部の酸素を巻き込みながらタ
ンク内に渦流を起こすように噴射されることから、タン
ク内で回転し水の深層までエアレーションを可能にして
酸素の導入拡散効果を高め、その溶解効率を大幅に向上
させることができ、これにより水中に高効率で酸素供給
ラップ盤行い、大気放時における微細気泡の量を大き
く増大させることが可能となる。
According to the oxygen dissolving method of the present invention, a large amount of oxygen is dissolved in water by applying pressure,
-Released by excess oxygen fine bubbles and without that was not dissolved in the normal atmospheric pressure, by the fine bubbles float long in the water, secondary oxygen transfer oxygen dissolution of high efficiency is performed happening However, at this time, the water in the pressurizing tank
When dissolving the oxygen in the tank,
Since tangentially water is jetted to cause a vortex flow in the tank while entrained oxygen tank top of Tan
Rotates in click to allow aeration deep layer of water enhances the introduction diffusion effect of oxygen, the dissolution efficiency can be greatly improved, thereby performs oxygenation lapping machine with high efficiency in water, release air solutions It is possible to greatly increase the amount of fine bubbles at the time.

【0008】[0008]

【発明の実施の形態】以下さらに添付図面を参照して、
本発明の実施の形態を説明する。
BRIEF DESCRIPTION OF THE DRAWINGS FIG.
An embodiment of the present invention will be described.

【0009】図1は本発明実施形態の酸素溶解方法に使
用する装置を示すブロック図、図2は図1のA−A線断
面図、図3は同B−B線断面図であり、1は導水用加圧
ポンプ、2は加圧用タンク、3は空気を加圧するコンプ
レッサー、4は酸素ボンベ(または酸素発生装置)を夫
々示している。
FIG. 1 is a block diagram showing an apparatus used in the oxygen dissolving method according to the embodiment of the present invention, FIG. 2 is a sectional view taken along line AA of FIG. 1, and FIG. 3 is a sectional view taken along line BB of FIG. Denotes a pressurizing pump for introducing water, 2 denotes a tank for pressurizing, 3 denotes a compressor for pressurizing air, and 4 denotes an oxygen cylinder (or oxygen generator).

【0010】上記加圧ポンプ1は導水管1aによってプ
ールPの水を加圧用タンク2に供給するようになってお
り、導水管1aのタンク側端部にはノズル部1bが設け
られている。上記ノズル部1bは、図2、図に示すよ
うに、立直した円筒状に設けられた上記加圧用タンク2
の外周部付近に設置され、水面の上方からタンク2の
接線方向斜め下方に水を噴射し、この噴射される水は、
前記加圧ポンプ1によって2kg/cm〜5kg/c
に加圧される。
The pressurizing pump 1 supplies water from the pool P to the pressurizing tank 2 by a water guide pipe 1a, and a nozzle 1b is provided at an end of the water guide pipe 1a on the tank side. As shown in FIGS. 2 and 3 , the nozzle portion 1b is provided with the pressurizing tank 2 provided in an upright cylindrical shape.
Is installed near the outer periphery of the inside , and injects water obliquely downward in the tangential direction of the tank 2 from above the water surface,
2 kg / cm 2 to 5 kg / c by the pressure pump 1
It is pressurized to the m 2.

【0011】一方、上記加圧用タンク2には、水面検知
センサー5、圧力計6、排水用電磁弁7および圧力調整
弁8が設けられており、上記加圧ポンプ1から供給され
た水の量や圧力を自動調整できるようになっている。ま
た、上記エアーコンプレッサー3は通気管3aによって
外気(空気)を加圧用タンク2の上部に圧搾して送るも
のであり、上記通気管3aには電磁弁7とレギュレータ
9とが設けられている。
On the other hand, the pressurizing tank 2 is provided with a water level detecting sensor 5, a pressure gauge 6, a drainage solenoid valve 7 and a pressure regulating valve 8, and the amount of water supplied from the pressurizing pump 1 is provided. And pressure can be automatically adjusted. The air compressor 3 squeezes and sends outside air (air) to the upper part of the pressurizing tank 2 by a ventilation pipe 3a. The ventilation pipe 3a is provided with a solenoid valve 7 and a regulator 9.

【0012】そして、上記酸素ボンベ4は通気管4aに
よって純酸素を加圧用タンク2上部に送るものであり、
この例では上記通気管4aはエアーコンプレッサー3の
通気管3aに接続されている。この酸素ボンベ4の通気
管4aにはレギュレータ9、酸素流量計10、電磁弁7
が夫々設けられており、酸素の量をコントロールするこ
とにより、任意の酸素濃度の空気を上記エアーコンプレ
ッサー3によって加圧状態で加圧用タンク2に供給しう
るようになっている。
The oxygen cylinder 4 sends pure oxygen to the upper part of the pressurizing tank 2 through a vent pipe 4a.
In this example, the ventilation pipe 4a is connected to the ventilation pipe 3a of the air compressor 3. A regulator 9, an oxygen flow meter 10, a solenoid valve 7 are provided in the ventilation pipe 4 a of the oxygen cylinder 4.
By controlling the amount of oxygen, air having an arbitrary oxygen concentration can be supplied to the pressurizing tank 2 in a pressurized state by the air compressor 3.

【0013】すなわち、本発明実施形態の加圧式酸素溶
解方法では、このような装置を利用するものであり、先
ず上記加圧ポンプ1によって汲み上げた水を加圧用タン
ク2に供給すると共に、上記コンプレッサー3によって
空気と共に加圧した酸素をタンク2内に供給して、加圧
状態で酸素を水に溶解させる。そして、上記加圧用タン
ク2の圧力調整弁8を開くことによってタンク2内の圧
力を大気開放状態となし、これにより上記加圧状態で水
に溶存した酸素を水中で微細気泡となす。
That is, the pressurized oxygen dissolving method according to the embodiment of the present invention utilizes such an apparatus. First, water pumped by the pressurizing pump 1 is supplied to the pressurizing tank 2 and the compressor Oxygen pressurized together with air by 3 is supplied into the tank 2 to dissolve oxygen in water under pressurized state. Then, by opening the pressure adjusting valve 8 of the pressurizing tank 2, the pressure in the tank 2 is made open to the atmosphere, whereby oxygen dissolved in the water in the pressurized state is formed into fine bubbles in the water.

【0014】このようにして発生した酸素(空気)の微
細気泡は直径が5〜10μmと非常に小さいものであ
り、発生後から長時間にわたって水中を浮遊する。そし
て、この微細気泡の長時間の浮遊によって2次的な酸素
移動が起こり、その過程で再び高い効率の酸素溶解が行
われる。また、前記実施形態の装置では、前記ノズル部
1bから水が加圧用タンク2上部の酸素を巻き込みなが
らこのタンク2内に渦流を起こすように噴射されること
から、水の深層までエアレーションを可能にして酸素の
導入拡散効果を高め、その溶解効率を大幅に向上させる
ことができ、これにより水中に高効率で酸素供給を行
い、大気開放時における水中の微細気泡の量を大きく増
大させることが可能となる。
The microbubbles of oxygen (air) thus generated are very small, having a diameter of 5 to 10 μm, and float in water for a long time after generation. Then, secondary oxygen transfer occurs due to the long-time floating of the fine bubbles, and high-efficiency oxygen dissolution is performed again in the process. Further, in the apparatus of the embodiment, since the water is injected from the nozzle portion 1b so as to generate a vortex inside the tank 2 while entraining the oxygen in the upper portion of the pressurizing tank 2, aeration to a deep layer of the water is enabled. To increase the effect of introducing and diffusing oxygen and greatly improve its dissolving efficiency, thereby enabling high-efficiency oxygen supply to water and greatly increasing the amount of microbubbles in the water when it is open to the atmosphere. Becomes

【0015】[0015]

【発明の効果】以上説明したように、本発明の加圧式酸
素溶解方法は、水を加圧用タンクに入れると共に、この
タンク内に加圧した酸素を供給することによりこの酸素
を加圧状態で水に充分に溶解させ、のちこの水を大気解
放することにより上記融存した酸素を微細気泡となし、
この微細気泡を水中に浮遊させることによりこの気泡の
酸素を再び水中に溶解させるものであり、加圧状態で液
面の斜め上方からタンクの接線方向に水を噴射して酸素
を巻き込んで回転させることにより水に多くの酸素を
率よく溶解させると共に、大気放により通常気圧では
溶解されなかった余分な酸素を微細な気泡となし、この
ピサ引用例気泡を水中に長時間浮遊させることにより、
2次的な酸素移動が起こって高い効率の酸素溶解を行わ
しめることが可能であり、これにより高負荷での酸素供
給速度に充分対応し、かつ処理施設の小型化や稼働効率
の向上に寄与するとの顕著な効果を奏するのである。
As described above, according to the pressurized oxygen dissolving method of the present invention, water is put into a pressurizing tank, and pressurized oxygen is supplied into the tank to reduce the oxygen in a pressurized state. The dissolved oxygen is converted into fine bubbles by dissolving it sufficiently in water and then releasing this water to the atmosphere.
By flotation the fine bubbles in the water and can dissolve a oxygen of the bubble again in water, the liquid under pressure
Water is sprayed from diagonally above the surface in the tangential direction of the tank to
Effect more oxygen in water by Rukoto rotated by involving
Together to rate well dissolved, excess oxygen fine bubbles and without that was not dissolved in the normal pressure by release air solution, by long float this Pisa reference example bubbles in the water,
It is possible to perform high-efficiency oxygen dissolution by secondary oxygen transfer, which sufficiently responds to the oxygen supply rate under high load, and contributes to downsizing of treatment facilities and improvement of operation efficiency. This has a remarkable effect.

【0016】しかも、特に本発明は、ノズル部から水が
タンク上部の酸素を巻き込みながらタンク内に渦流を起
こすように噴射されることから、巻き込まれた酸素渦流
に随伴して共に回転し、水の深層までエアレーションを
可能にして酸素の導入拡散効果を高め、その溶解効率を
大幅に向上させることができ、これにより水中に高効率
で酸素供給を行い、大気放時における水中の微細気泡
の量を大きく増大させることが可能となる。
[0016] Moreover, in particular the present invention, since the water is injected to cause a vortex flow in the tank while entrainment of oxygen of the upper part the tank from the nozzle portion, entrained oxygen vortex
It rotates together with the air, enabling aeration to the deep water layer, enhancing the effect of introducing and diffusing oxygen, and greatly improving the dissolving efficiency. it is possible to greatly increase the amount of fine bubbles in the water at the time-released.

【0017】特に、一般の加圧装置では加圧用タンク内
圧力が4〜8Kg/cm2 と高い圧力で空気を溶解させ
るのに対し、上記本発明では上記渦流による空気混合に
よって、タンク内圧力が2〜3Kg/cm2 の比較的低
圧でも充分な溶解効率を得ることができる。つまり、上
記低圧で気液溶解が可能であるため、同じ電力消費量の
場合は2.2kwポンプで5Kg/cm2 ・・・50リ
ットル/分、2Kg/cm2 ・・・150リットル/分
となり、吐出量に対する電力消費を大幅に削減すること
が可能となる。
In particular, in a general pressurizing apparatus, air is dissolved at a high pressure in the pressurizing tank of 4 to 8 kg / cm 2 , whereas in the present invention, the pressure in the tank is reduced by the mixing of air by the vortex. Sufficient dissolution efficiency can be obtained even at a relatively low pressure of 2-3 kg / cm 2 . That is, since gas-liquid dissolution can be performed at the above low pressure, the same power consumption results in 5 kg / cm 2 ··· 50 l / min with a 2.2 kW pump and 2 kg / cm 2 ··· 150 l / min. In addition, it is possible to greatly reduce the power consumption with respect to the discharge amount.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明実施形態の水の加圧式酸素溶解方法に使
用する装置を示すブロック図である。
FIG. 1 is a block diagram showing an apparatus used for a pressurized oxygen dissolution method of water according to an embodiment of the present invention.

【図2】図1のA−A線断面図である。FIG. 2 is a sectional view taken along line AA of FIG.

【図3】図1のB−B線断面図である。FIG. 3 is a sectional view taken along line BB of FIG. 1;

【符号の説明】[Explanation of symbols]

1 加圧用ポンプ 1a 導水管 1b ノズル部 2 加圧用タンク 3 コンプレッサー 3a 通気管 4 酸素ボンべ 4a 通気管 5 水面検知センサー 6 圧力計 7 電磁弁 8 圧力調整弁 9 レギュレータ 10 酸素流量計 P プール DESCRIPTION OF SYMBOLS 1 Pressurizing pump 1a Water pipe 1b Nozzle part 2 Pressurizing tank 3 Compressor 3a Vent pipe 4 Oxygen cylinder 4a Vent pipe 5 Water level detection sensor 6 Pressure gauge 7 Solenoid valve 8 Pressure regulating valve 9 Regulator 10 Oxygen flow meter P Pool

フロントページの続き (58)調査した分野(Int.Cl.6,DB名) B01F 1/00 - 5/26 C02F 1/24 Continuation of front page (58) Field surveyed (Int.Cl. 6 , DB name) B01F 1/00-5/26 C02F 1/24

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】加圧ポンプ等により汲み上げた水を加圧タ
ンクに入れ、このタンク内に加圧した酸素を供給するこ
とによりこの酸素を加圧状態で水に溶解させ、のちこの
水を大気解放することにより上記溶存した酸素を微細気
泡となし、この微細気泡を水中に浮遊させることにより
この気泡の酸素を水中に溶解させるに際し、上記加圧用
タンクを立直した筒状に形成し、この加圧用タンク
外周部上部に、液面の斜め上方からタンクの接線方向に
前記水を噴射するノズルを配して、このノズル部より
射した水によりタンク上部の酸素を巻き込みながら上記
加圧タンク内に酸素を含む渦流を発生させタンク内で回
転させて酸素を水に溶解させることを特徴とする加圧式
酸素溶解方法。
1. Water pumped by a pressurizing pump or the like is put into a pressurized tank, and pressurized oxygen is supplied into the tank to dissolve the oxygen in water under a pressurized state. By releasing the dissolved oxygen into fine bubbles by releasing the bubbles, the pressurizing tank is formed into an upright cylindrical shape when the oxygen of the bubbles is dissolved in water by floating the fine bubbles in water. A nozzle for spraying the water in a tangential direction of the tank from obliquely above the liquid level is disposed above the outer peripheral portion in the pressure tank , and the water sprayed from the nozzle portion entrains oxygen in the upper portion of the tank. while rotating in a tank to generate a vortex stream comprising oxygen in the pressure tank
Pressurized oxygen dissolution method of by rolling oxygen wherein Rukoto dissolved in water.
JP2656598A 1998-01-22 1998-01-22 Pressurized oxygen dissolution method Expired - Lifetime JP2973305B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2656598A JP2973305B2 (en) 1998-01-22 1998-01-22 Pressurized oxygen dissolution method
KR1019990001601A KR100306790B1 (en) 1998-01-22 1999-01-20 Oxygen fusion method by the compression

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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US7008535B1 (en) * 2000-08-04 2006-03-07 Wayne State University Apparatus for oxygenating wastewater
JP4005407B2 (en) * 2002-04-26 2007-11-07 横河電機株式会社 Muddy water treatment system and muddy water treatment vehicle equipped with the same
JP2004008889A (en) * 2002-06-05 2004-01-15 Marutaka Co Ltd Apparatus for making oxygen-dissolved water
JP4231249B2 (en) * 2002-07-01 2009-02-25 大成建設株式会社 High oxygen water production apparatus and bottom purification method
CN100457244C (en) 2004-02-03 2009-02-04 松江土建株式会社 Gas-liquid dissolution apparatus
JP2006136777A (en) * 2004-11-11 2006-06-01 Maruwa Biochemical Co Ltd Mixing apparatus for fine bubble
JP4559289B2 (en) * 2005-04-28 2010-10-06 株式会社荏原製作所 Oxygen dissolving apparatus and oxygen dissolving method
JP2007021341A (en) * 2005-07-14 2007-02-01 Lwj Kk Oxygen enriched water production device, and water quality improvement device
JP2007245013A (en) * 2006-03-16 2007-09-27 Ngk Insulators Ltd Leachate treatment method
KR100858278B1 (en) * 2007-02-26 2008-09-11 오승환 A method for making an alcoholic liquor distiluted with water micro-nano-bubble-processed
JP5113552B2 (en) * 2008-02-20 2013-01-09 パナソニック株式会社 Water purification device
KR100843970B1 (en) 2008-03-20 2008-07-03 유정호 Apparatus of generating microbubble
JP2010264384A (en) * 2009-05-14 2010-11-25 Matsue Doken Kk Method for removing water bloom
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CN102985172B (en) 2010-07-15 2015-07-01 韩国机械研究院 Micro bubble generation device based on rotating unit
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JP5689453B2 (en) * 2012-12-25 2015-03-25 株式会社アンレット Water purification equipment
JP6317680B2 (en) 2013-01-31 2018-04-25 株式会社横田製作所 Gas-liquid dissolution tank and fine bubble generator

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JPH11207162A (en) 1999-08-03
KR100306790B1 (en) 2001-09-24

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