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JP2967240B2 - Automatic continuous analyzer with alarm transmission function - Google Patents

Automatic continuous analyzer with alarm transmission function

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Publication number
JP2967240B2
JP2967240B2 JP8462591A JP8462591A JP2967240B2 JP 2967240 B2 JP2967240 B2 JP 2967240B2 JP 8462591 A JP8462591 A JP 8462591A JP 8462591 A JP8462591 A JP 8462591A JP 2967240 B2 JP2967240 B2 JP 2967240B2
Authority
JP
Japan
Prior art keywords
measurement
measured value
sample
analyzer
determination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP8462591A
Other languages
Japanese (ja)
Other versions
JPH05133959A (en
Inventor
信吉 束原
俊介 平沢
真一 赤沢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DKK Corp
Original Assignee
DKK Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DKK Corp filed Critical DKK Corp
Priority to JP8462591A priority Critical patent/JP2967240B2/en
Publication of JPH05133959A publication Critical patent/JPH05133959A/en
Application granted granted Critical
Publication of JP2967240B2 publication Critical patent/JP2967240B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、水質,大気等の自動連
続分析装置に関し、更に詳しくは、試料の測定値が予め
定められた許容範囲を外れたときに警報信号を出力する
警報発信機能付の自動連続分析装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an automatic continuous analyzer for water quality, air, and the like, and more particularly, to an alarm transmission function for outputting an alarm signal when a measured value of a sample falls outside a predetermined allowable range. The present invention relates to an automatic continuous analyzer attached.

【0002】[0002]

【従来の技術】水処理工場等において水質を連続的に監
視する場合、一般に、図2に示す構成の警報発信機能付
の自動連続分析装置が使用されている。すなわち、図2
に示す装置において、aは試料導入管,bは電磁バル
ブ,cは検出部,dは変換器,eは制御部である。本装
置では、通常、試料水の濁度,色度,pH,残留塩素濃
度,電気伝導率,水圧,水温等の測定が行なわれる。上
記装置によって水質の分析を行なう場合、制御部eの制
御によってバルブbを開き、試料を検出部cに導入す
る。そして、検出部cにおいて上述した各項目の測定を
行ない、その信号を必要なものは変換器dで濁度,色度
などの各測定値に変換した後、測定値fとして出力す
る。また、測定値fが予め定めておいた許容範囲を外れ
た場合は、異常が発生したことを知らせる警報信号gを
出力する。
2. Description of the Related Art In the case of continuously monitoring water quality in a water treatment plant or the like, an automatic continuous analyzer having an alarm transmission function having a configuration shown in FIG. 2 is generally used. That is, FIG.
In the apparatus shown in (1), a is a sample introduction tube, b is an electromagnetic valve, c is a detection unit, d is a converter, and e is a control unit. In this apparatus, turbidity, chromaticity, pH, residual chlorine concentration, electric conductivity, water pressure, water temperature and the like of a sample water are usually measured. When water quality is analyzed by the above device, the valve b is opened under the control of the control unit e, and the sample is introduced into the detection unit c. Then, the detection unit c measures the above-described items, and the necessary signals are converted into respective measured values such as turbidity and chromaticity by the converter d, and then output as the measured values f. When the measured value f is out of the predetermined allowable range, an alarm signal g notifying that an abnormality has occurred is output.

【0003】[0003]

【発明が解決しようとする課題】しかし、図2の装置
は、警報信号が出力されたとき、すなわち測定値が許容
範囲を超えたときに、その異常が水質の異常に起因する
ものなのか、装置の異常に起因するものなのかを判断す
る機能を有していない。したがって、図2の測定装置で
測定を行なっている場合、警報信号が発せられたときに
は、人が別の計器を用いて水質の良否を判断すると共
に、測定装置を点検してその良否を調べた後、その結果
に基づいて警報の原因が水質にあるのか装置にあるのか
を判断しなけらばならず、この判断に非常に時間がかか
る。このため、警報信号が発せられた後、それへの対応
措置、すなわち水処理系統あるいは測定装置の点検,保
守等を行なうまでに長時間を要し、水質の管理を十分満
足に行なうことができなかった。
However, when the alarm signal is output, that is, when the measured value exceeds the allowable range, the apparatus shown in FIG. 2 determines whether the abnormality is caused by an abnormality in water quality. It does not have a function to determine whether the cause is an abnormality of the device. Therefore, when performing the measurement with the measuring device of FIG. 2, when an alarm signal is issued, a person judges the quality of the water using another meter and inspects the measuring device to check the quality. Thereafter, it is necessary to determine whether the cause of the alarm is due to the water quality or the device based on the result, and this determination takes a very long time. For this reason, it takes a long time after an alarm signal is issued until the countermeasures, that is, inspection and maintenance of the water treatment system or the measuring device, are performed, and the water quality can be sufficiently managed. Did not.

【0004】これに対し、従来より、一定周期で自動的
に校正を行なわせ、前もって装置の異常の有無を判別す
る手段はある。しかし、この手段は、警報信号が発せら
れたとき「送水停止」などの重大決定を行なうためには
再確認が必要であること、校正液の補給頻度が高いこ
と、自動校正を行なうため変換器の構成が複雑になるこ
と等の実用上の問題点を有する。
[0004] On the other hand, conventionally, there is a means for automatically performing calibration at regular intervals and determining in advance whether or not the apparatus is abnormal. However, this means requires a reconfirmation to make a critical decision such as "water stoppage" when an alarm signal is issued, the need for frequent replenishment of the calibration solution, and the use of a converter to perform automatic calibration. Has a practical problem such as that the configuration becomes complicated.

【0005】本発明は、上記事情に鑑みなされたもの
で、測定値が予め定められた許容範囲を逸脱したときに
警報を発し、かつその警報が測定対象物質に起因するの
か装置自体に起因するのかを自動的に判定する自動連続
分析装置を提供することを目的とする。
The present invention has been made in view of the above circumstances, and issues an alarm when a measured value deviates from a predetermined allowable range, and whether the alarm is caused by the substance to be measured or by the apparatus itself. It is an object of the present invention to provide an automatic continuous analyzer for automatically judging whether or not there is no difference.

【0006】[0006]

【課題を解決するための手段及び作用】本発明は、上記
目的を達成するため、試料の測定値が予め定められた許
容範囲を外れたときに警報信号を出力する自動連続分析
装置において、上記警報信号が外部へ出力される前に、
一定の測定値が得られる判定用物質の測定を自動的に試
料の測定に代えて行ない、この判定用物質の実測値が該
判定用物質によって得られるべき測定値と一定量以上異
なるときに装置が異常であることを示す装置異常信号を
出力するよう構成したことを特徴とする警報発信機能付
自動連続分析装置を提供する。
According to the present invention, there is provided an automatic continuous analyzer for outputting an alarm signal when a measured value of a sample is out of a predetermined allowable range. Before the alarm signal is output to the outside,
The measurement of the determination substance that can obtain a certain measurement value is automatically performed instead of the measurement of the sample, and the apparatus is used when the actual measurement value of the determination substance differs from the measurement value to be obtained by the determination substance by a certain amount or more. An automatic continuous analyzer with an alarm transmission function is configured to output a device abnormality signal indicating that the device is abnormal.

【0007】本装置においては、試料測定中に警報信号
が発せられたときに、判定用物質の測定を行なう。この
判定用物質は、予め一定の測定値が得られるように調製
されているので、その実測値が予め定められた範囲に入
っている場合、すなわち測定誤差の範囲内である場合に
は、装置は正常であると判定され、したがって試料が異
常であると判定されて警報信号が出力される。また、判
定用物質の実測値が予め定められた範囲から外れている
場合には、装置自体に異常があると判定され、装置異常
信号が出力される。
In the present apparatus, when an alarm signal is issued during the measurement of a sample, the determination substance is measured. Since this determination substance is prepared in advance so that a constant measured value is obtained, if the actual measured value is within a predetermined range, that is, if the measured value is within the range of the measurement error, the apparatus is used. Is determined to be normal, and therefore, the sample is determined to be abnormal, and an alarm signal is output. If the measured value of the determination substance is out of the predetermined range, it is determined that there is an abnormality in the apparatus itself, and an apparatus abnormality signal is output.

【0008】この場合、本発明装置は、水質分析装置,
大気分析装置等の任意の分析装置に構成することができ
る。また、本発明装置は、1項目の測定を行なう分析装
置及び複数項目の測定を行なう分析装置のいずれにも構
成することができる。複数項目の測定を行なう分析装置
としたときには、すべての測定項目についてそれぞれ警
報信号の出力及び判定用物質による判定を行うようにし
てもよく、一部の項目についてのみこれらを行なうよう
してもよい。さらに、本発明において、判定物質として
は、一定の測定値が得られるように調製されたものであ
ればいずれのものでも用いることができる。例えば、液
体では標準液,ゼロ液、気体では標準ガス,ゼロガス等
を用いることができるが、これらに限られるもではな
い。
In this case, the apparatus of the present invention is a water quality analyzer,
It can be configured in any analyzer such as an air analyzer. Further, the apparatus of the present invention can be configured as any of an analyzer that performs measurement of one item and an analyzer that performs measurement of a plurality of items. When the analyzer is configured to measure a plurality of items, the output of the alarm signal and the determination by the determination substance may be performed for all the measured items, or the determination may be performed for only some of the items. . Further, in the present invention, any substance can be used as the determination substance, as long as it is prepared so as to obtain a constant measured value. For example, a standard liquid and a zero liquid can be used for a liquid, and a standard gas and a zero gas can be used for a gas, but are not limited thereto.

【0009】[0009]

【実施例】次に、実施例により本発明を具体的に示す
が、本発明は下記実施例に限定されるものではない。図
1は本発明の一実施例に係る水質自動連続分析装置を示
す。図中1は試料導入管、2は試料導入管1に介装され
た電磁バルブ、3は判定液タンク、4は判定液タンク3
に連結された判定液導入管、5は判定液導入管4に介装
された電磁バルブ、6は試料導入管1及び判定液導入管
4に連結された検出部で、この検出部6においては、濁
度,色度,pH,残留塩素濃度,電気伝導率,水圧及び
水温の測定がそれぞれ対応する検出器によって行なわれ
るようになっている。また、7は検出部6と連絡し、検
出部からの信号を各測定値に変換する変換器、8は測定
動作の制御及び測定値の制御、比較演算を行なう制御・
比較演算部を示す。
EXAMPLES Next, the present invention will be specifically described by way of examples, but the present invention is not limited to the following examples. FIG. 1 shows an automatic continuous water quality analyzer according to one embodiment of the present invention. In the figure, 1 is a sample introduction pipe, 2 is an electromagnetic valve interposed in the sample introduction pipe 1, 3 is a determination liquid tank, 4 is a determination liquid tank 3
Is an electromagnetic valve interposed in the determination liquid introduction pipe 4, and 6 is a detection unit connected to the sample introduction pipe 1 and the determination liquid introduction pipe 4. In this detection unit 6, , Turbidity, chromaticity, pH, residual chlorine concentration, electric conductivity, water pressure and water temperature are measured by corresponding detectors. Reference numeral 7 denotes a converter which communicates with the detection unit 6 and converts a signal from the detection unit into each measured value.
3 shows a comparison operation unit.

【0010】本装置によって水質の連続分析を行なう場
合、バルブ2を開、バルブ5を閉にとして試料を検出部
6に導入し、検出部6において濁度,色度,pH,残留
塩素,電気伝導率,水温,水圧の測定を行なう。そし
て、必要なものはその信号を変換器7で各測定値に変換
し、測定値9として出力する。本装置においては、通常
は上記状態で測定が続けられるが、1以上の測定項目の
測定値が予め定めた許容範囲を超えた場合、その測定項
目についての警報信号10Aが変換器7から出力され
る。
When the water quality is continuously analyzed by the present apparatus, the valve 2 is opened and the valve 5 is closed, and the sample is introduced into the detecting section 6, where the turbidity, chromaticity, pH, residual chlorine, electric Conduct conductivity, water temperature and water pressure measurements. If necessary, the signal is converted into each measured value by the converter 7 and output as the measured value 9. In this device, the measurement is normally continued in the above state, but if the measured value of one or more measurement items exceeds a predetermined allowable range, an alarm signal 10A for the measurement item is output from the converter 7. You.

【0011】そして、このように警報信号10Aが発せ
られたときに、制御・比較演算部8の制御によって次の
〜に示す測定操作が行なわれる。 変換器7から警報信号10Aが出力された後、予め
定めた一定の時間(例えば3分間)そのまま試料の測定
を行なう。 この一定時間内に測定値が許容範囲内に戻れば、警報の
原因は水質の一時的な異常であると判定され、そのまま
試料の測定が続行される。 で試料の測定を一定時間行なった後に測定値が依
然として許容範囲を外れているときには、バルブ2を
閉、バルブ5を開にして判定液を検出器6を導入し、一
定時間(例えば10分間)判定液の測定を行なう。この
判定液(判定用物質)は、所用の測定項目についてそれ
ぞれ一定の測定値(ゼロあるいは特定の測定値)が得ら
れるように調製されたものである。そして、制御・比較
演算部8で判定液によって得られるべき測定値と判定液
の実測値とを比較し、上記実測値が上記得られるべき測
定値に基づいて定めた一定の許容範囲内にある場合に
は、装置は正常であると判定される。したがって、水質
が異常であると判定され、外部に警報信号10Bが出力
される。また、上記実測値が上記許容範囲を外れている
場合には、装置が異常であると判定され、外部への警報
信号10Bは出力せずに代わりに装置異常信号11が送
出される。 次に、装置についての判定が正常である場合及び異常
である場合のいずれの場合も、バルブ2,5を切り換え
て試料の測定状態に戻る。装置が正常であると判定され
た場合は、試料の測定状態に戻り、警告信号10Bが出
力され、水質が異常であると確定的に判定される。ま
た、装置が異常であると判定された後、試料の測定状態
に戻った場合は、異常と判定された測定項目については
装置異常信号11を出力させたまま測定を続ける。これ
は、正常な測定項目については正常な測定値が継続して
得られるからである。
When the alarm signal 10A is thus issued, the following measurement operations are performed under the control of the control / comparison operation unit 8. After the output of the alarm signal 10A from the converter 7, the measurement of the sample is performed as it is for a predetermined period of time (for example, 3 minutes). If the measured value returns within the allowable range within this fixed time, it is determined that the cause of the alarm is a temporary abnormality in water quality, and the measurement of the sample is continued as it is. If the measured value is still outside the permissible range after performing the measurement of the sample for a certain period of time, the valve 2 is closed, the valve 5 is opened, and the determination liquid is introduced into the detector 6 for a certain period (for example, 10 minutes). Measure the determination liquid. The determination liquid (determination substance) is prepared so as to obtain a constant measurement value (zero or a specific measurement value) for each required measurement item. Then, the control / comparison operation unit 8 compares the measured value to be obtained with the judgment liquid with the actually measured value of the judgment liquid, and the actually measured value is within a certain allowable range determined based on the measured value to be obtained. In that case, the device is determined to be normal. Therefore, it is determined that the water quality is abnormal, and an alarm signal 10B is output to the outside. If the measured value is out of the allowable range, the apparatus is determined to be abnormal, and the apparatus does not output the alarm signal 10B to the outside, but instead transmits the apparatus abnormality signal 11. Next, in both cases where the determination of the apparatus is normal and abnormal, the valves 2 and 5 are switched to return to the sample measurement state. When it is determined that the device is normal, the process returns to the measurement state of the sample, a warning signal 10B is output, and it is definitely determined that the water quality is abnormal. When the apparatus returns to the measurement state of the sample after it is determined that the apparatus is abnormal, the measurement is continued with the apparatus abnormality signal 11 output for the measurement item determined to be abnormal. This is because normal measurement values are continuously obtained for normal measurement items.

【0012】そして、上記判定が終了した後は、判定結
果に基づいて適切な措置を採る。すなわち、水質異常と
判定された場合は、その異常原因の探知,改善等を行な
う。また、装置異常と判定された場合は、装置の点検,
修理等を行なう。したがって、本装置によれば、警告信
号10Aが発せられた場合に、その原因が装置にあるの
か、水質にあるのかを、速やかに自動的に判定すること
ができる。このため、警告信号10Bが出力されてから
対応措置を採るまでの時間を大幅に短縮することがで
き、水質の管理を効果的に行なうことができる。
After the above-mentioned judgment is completed, appropriate measures are taken based on the judgment result. That is, when it is determined that the water quality is abnormal, detection and improvement of the cause of the abnormality are performed. If it is determined that the equipment is abnormal, check the equipment,
Perform repairs, etc. Therefore, according to the present apparatus, when the warning signal 10A is issued, it is possible to quickly and automatically determine whether the cause is the apparatus or the water quality. Therefore, the time from when the warning signal 10B is output to when the countermeasure is taken can be greatly reduced, and water quality can be effectively managed.

【0013】[0013]

【発明の効果】以上説明したように、本発明の警報発信
機能付自動連続分析装置は、警報信号が発せられたとき
に、それが測定対象物質の異常に起因する警報なのか装
置の異常に基づく異常なのかを自動的に判定することが
できる。従って、本発明装置を用いれば、警報が発せら
れたときにそれへの対処を迅速に行なうことができ、水
質,大気等の連続自動連続監視を効果的に行なうことが
可能である。
As described above, the automatic continuous analyzer with an alarm transmission function of the present invention, when an alarm signal is issued, determines whether the alarm is caused by an abnormality in the substance to be measured or not. It is possible to automatically determine whether the abnormality is based on the abnormality. Therefore, by using the apparatus of the present invention, when an alarm is issued, it can be promptly dealt with, and continuous automatic continuous monitoring of water quality, atmosphere, and the like can be effectively performed.

【0014】[0014]

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施例に係る水質自動連続分析装置
を示す概略図である。
FIG. 1 is a schematic diagram showing an automatic continuous water quality analyzer according to one embodiment of the present invention.

【図2】従来の水質自動連続分析装置を示す概略図であ
る。
FIG. 2 is a schematic view showing a conventional automatic analyzer for water quality.

【0015】[0015]

【符号の説明】[Explanation of symbols]

1…試料導入管 4…判定液導入管 6…検出器 7…変換器 8…制御・比較演算部 9…測定値出力 10…警報信号 11…装置異常信号 DESCRIPTION OF SYMBOLS 1 ... Sample introduction pipe 4 ... Judgment liquid introduction pipe 6 ... Detector 7 ... Converter 8 ... Control / comparison operation part 9 ... Measured value output 10 ... Alarm signal 11 ... Equipment abnormal signal

フロントページの続き (56)参考文献 特開 平1−148964(JP,A) 特開 昭63−14289(JP,A) 実開 昭53−160327(JP,U) 特公 昭56−19909(JP,B2) (58)調査した分野(Int.Cl.6,DB名) G01N 35/00 - 35/10 Continuation of the front page (56) References JP-A-1-148964 (JP, A) JP-A-63-14289 (JP, A) JP-A-53-160327 (JP, U) JP-B-56-19909 (JP, A) , B2) (58) Field surveyed (Int. Cl. 6 , DB name) G01N 35/00-35/10

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 試料の測定値が予め定められた許容範囲
を外れたときに警報信号を出力する自動分析装置におい
て、上記警報信号が出力されたときに、一定の測定値が
得られる判定用物質の測定を自動的に試料の測定に代え
て行ない、この判定用物質の実測値が該判定用物質によ
って得られるべき測定値と一定量以上異なるときに装置
が異常であることを示す装置異常信号を出力するよう構
成したことを特徴とする警報発信機能付自動連続分析装
置。
1. An automatic analyzer for outputting an alarm signal when a measured value of a sample is out of a predetermined allowable range, wherein a predetermined measured value is obtained when the alarm signal is output. The measurement of a substance is automatically performed instead of the measurement of a sample, and when the actual measurement value of the determination substance differs from the measurement value to be obtained by the determination substance by a certain amount or more, it indicates that the apparatus is abnormal. An automatic continuous analyzer with an alarm transmission function, which is configured to output a signal.
JP8462591A 1991-03-25 1991-03-25 Automatic continuous analyzer with alarm transmission function Expired - Lifetime JP2967240B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8462591A JP2967240B2 (en) 1991-03-25 1991-03-25 Automatic continuous analyzer with alarm transmission function

Applications Claiming Priority (1)

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JP8462591A JP2967240B2 (en) 1991-03-25 1991-03-25 Automatic continuous analyzer with alarm transmission function

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JPH05133959A JPH05133959A (en) 1993-05-28
JP2967240B2 true JP2967240B2 (en) 1999-10-25

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Publication number Priority date Publication date Assignee Title
EP3153841B1 (en) 2007-02-01 2020-04-15 Sysmex Corporation Sample analyzer
JP4994920B2 (en) * 2007-02-01 2012-08-08 シスメックス株式会社 Sample analyzer
JP4920450B2 (en) * 2007-02-23 2012-04-18 株式会社東芝 Automatic analyzer and accuracy control method thereof
JP5161547B2 (en) * 2007-11-27 2013-03-13 株式会社東芝 Automatic analyzer
WO2020218689A1 (en) * 2019-04-25 2020-10-29 (주)엘티에이치 Automatic verification and cleaning method for large particle counter for cmp slurry analysis and verification device suitable therefor

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