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JP2947867B2 - Method for forming composite material and method for forming mold - Google Patents

Method for forming composite material and method for forming mold

Info

Publication number
JP2947867B2
JP2947867B2 JP2104526A JP10452690A JP2947867B2 JP 2947867 B2 JP2947867 B2 JP 2947867B2 JP 2104526 A JP2104526 A JP 2104526A JP 10452690 A JP10452690 A JP 10452690A JP 2947867 B2 JP2947867 B2 JP 2947867B2
Authority
JP
Japan
Prior art keywords
prepreg
thin plate
composite material
forming
bag film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2104526A
Other languages
Japanese (ja)
Other versions
JPH044112A (en
Inventor
利夫 冨川
近藤  清
久夫 秋山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Subaru Corp
Original Assignee
Fuji Jukogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Jukogyo KK filed Critical Fuji Jukogyo KK
Priority to JP2104526A priority Critical patent/JP2947867B2/en
Publication of JPH044112A publication Critical patent/JPH044112A/en
Application granted granted Critical
Publication of JP2947867B2 publication Critical patent/JP2947867B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/10Isostatic pressing, i.e. using non-rigid pressure-exerting members against rigid parts or dies
    • B29C43/12Isostatic pressing, i.e. using non-rigid pressure-exerting members against rigid parts or dies using bags surrounding the moulding material or using membranes contacting the moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/20Making multilayered or multicoloured articles
    • B29C43/203Making multilayered articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • B29C43/3642Bags, bleeder sheets or cauls for isostatic pressing
    • B29C2043/3644Vacuum bags; Details thereof, e.g. fixing or clamping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2309/00Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
    • B29K2309/08Glass

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulding By Coating Moulds (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、航空機等の構造部材に利用される繊維強化
樹脂複合材の成形方法およびこれに使用する成形型の成
形方法に関する。
Description: TECHNICAL FIELD The present invention relates to a method for forming a fiber-reinforced resin composite material used for structural members of aircraft and the like, and a method for forming a mold used for the same.

〔従来の技術〕[Conventional technology]

繊維強化樹脂複合材(以下、複合材という。)は、比
強度、比剛性に優れているため、航空機機体の構造部材
への適用が近年著しく進んでいる。
BACKGROUND ART A fiber-reinforced resin composite (hereinafter, referred to as a composite) has excellent specific strength and specific rigidity, and thus has been significantly applied to structural members of an aircraft body in recent years.

一般に、この種の構造部材の成形では、所定寸法に裁
断したプリプレグを所要枚数分一枚ずつその繊維方向を
変えながら成形治具上に積層し、まず、真空引きによっ
てプリプレグ積層体に外圧をかけた後、オートクレーブ
内での加圧、加熱下に接着硬化せしめて所定形状の成形
品を得ている。
Generally, in the molding of this type of structural member, prepregs cut to a predetermined size are laminated on a molding jig while changing the fiber direction one by one for a required number of sheets, and first, an external pressure is applied to the prepreg laminate by evacuation. After that, the adhesive is cured under pressure and heat in an autoclave to obtain a molded product having a predetermined shape.

〔発明が解決しようとする課題〕[Problems to be solved by the invention]

このような複合材の成形方法では、硬化反応の過程で
プリプレグ積層体の板厚が変化し、特に、角となってい
る部分の板厚が他の部分に較べて薄くなり易い欠点があ
った。
In such a method of forming a composite material, the thickness of the prepreg laminate changes in the course of the curing reaction, and in particular, there is a disadvantage that the thickness of the corner portion tends to be thinner than the other portions. .

また、最近では、耐熱性が要求される構造部材をポリ
イミド系などの熱硬化性樹脂を用いて成形している。こ
の種の複合材を内部品質良好に成形するためには、複合
材中に含まれる強化繊維の割合、繊維体積含有率Vfを適
正にする必要があるが、このコントロールが難点であっ
た。すなわち、この種の複合材の成形温度は300℃を越
えるため、樹脂の流出量をコントロールするための部材
の耐熱性に問題があった。
Recently, structural members requiring heat resistance have been molded using a thermosetting resin such as a polyimide resin. In order to form this kind of composite material with good internal quality, it is necessary to make the ratio of the reinforcing fibers contained in the composite material and the fiber volume content Vf appropriate, but this control is a difficult point. That is, since the molding temperature of this type of composite material exceeds 300 ° C., there is a problem in the heat resistance of the member for controlling the outflow amount of the resin.

そこで、本発明の目的は、上述した従来の技術が有す
る問題点を解消し、寸法精度および内部品質とも優れた
成形品を高い成形温度でも成形することのできる複合材
の成形方法を提供することを目的とし、また、この成形
方法に使用する成形型の成形方法を提供することを目的
とするものである。
Accordingly, an object of the present invention is to solve the above-mentioned problems of the conventional technology and to provide a method of forming a composite material capable of forming a molded product having excellent dimensional accuracy and internal quality even at a high molding temperature. It is another object of the present invention to provide a molding method for a molding die used in this molding method.

〔課題を解決するための手段〕[Means for solving the problem]

上記目的を達成するために、本発明は、プリプレグの
積層体に通気性シートを被せ、その上に複数の孔を有し
成形品に対応した形状の金属製薄板を載せ、この金属製
薄板に真空バッグフィルムを被せてその内側を真空吸引
し、プリプレグを加圧した状態下にオートクレーブ内で
加熱、加圧してプリプレグ積層体を硬化させることを特
徴とするものである。
In order to achieve the above object, the present invention covers a permeable sheet on a prepreg laminate, places a metal sheet having a plurality of holes thereon and a shape corresponding to a molded article, and places the metal sheet on the metal sheet. The method is characterized in that a vacuum bag film is placed over the inside, vacuum suction is performed on the inside thereof, and the prepreg is heated and pressurized in an autoclave while pressurizing the prepreg, thereby curing the prepreg laminate.

また、本発明は、定盤上のマンドレルの上に載せられ
たプリプレグの積層体の上に複数の孔を有する金属製薄
板を載せ、この金属製薄板の上に真空バッグフィルムを
被せ、この真空バッグフィルムの内側を真空吸引し、金
属製薄板を成形型に加工することを特徴とするものであ
る。
The present invention also provides a metal sheet having a plurality of holes on a laminate of prepregs mounted on a mandrel on a surface plate, and a vacuum bag film placed on the metal sheet, The inside of the bag film is subjected to vacuum suction, and the thin metal plate is processed into a molding die.

〔作 用〕(Operation)

本発明によれば、金属製薄板がプリプレグ積層体の硬
化時の厚さ変化に追従するとともに、プリプレグ積層体
にかかる圧力を均一にする。また、金属製薄板の孔が硬
化反応時に生成するガス、余剰樹脂を通す役割をする。
ADVANTAGE OF THE INVENTION According to this invention, while a metal thin plate follows the thickness change at the time of hardening of a prepreg laminated body, the pressure applied to a prepreg laminated body is made uniform. Further, the holes of the metal thin plate serve to pass gas generated during the curing reaction and excess resin.

また、本発明によれば、金属製薄板が、真空圧によっ
てプリプレグ積層体になじむ成形型として簡易に成形さ
れる。
Further, according to the present invention, a thin metal plate is easily formed as a forming die that conforms to a prepreg laminate by vacuum pressure.

〔実施例〕〔Example〕

以下、本発明の一実施例を添付の図面を参照して説明
する。
Hereinafter, an embodiment of the present invention will be described with reference to the accompanying drawings.

第1図において、符号1は、定盤を示し、この定盤1
には、成形品の内側の形状寸法を出すためのマンドレル
2が設置されるとともに、吸引口3が設けられており、
この吸引口3には、図示しない真空回路が接続されてい
る。
In FIG. 1, reference numeral 1 denotes a surface plate.
Is provided with a mandrel 2 for obtaining the shape and dimensions inside the molded product, and a suction port 3 is provided.
A vacuum circuit (not shown) is connected to the suction port 3.

そこで、先ず、第1図(a)に示されるように、マン
ドレル2の上には、通気性のシートとしてガラスクロス
4を被せ、このガラスクロス4を介しポリイミド樹脂の
プリプレグ5を所要枚数分一枚一枚積み重ねる。さら
に、積層したプリプレグ5の上にはガラスクロス4を重
ねた後、金属製薄板、本実施例では、アルミ合金を材質
とする板厚0.3〜0.6mmの薄板を6を重ね、この薄板6を
成形型に成形する。薄板6は、第3図に示されるよう
に、孔7が所定の孔密度で形成されており、この孔7の
孔径、孔密度は、成形品の形状、成形条件等に応じて設
定されるものである。薄板6には、予め成形前に、例え
ば、シリコーン系の離型剤を塗布しておく。なお、薄板
6の加工前の形状は、箱形を展開したもの(第4図
(a))また、扇状の薄板6を継ぎ合わせて加工後半球
状にするもの(第4図(b))等、成形品の形状に応じ
て種種のバリェーションが可能である。
Therefore, first, as shown in FIG. 1 (a), a glass cloth 4 is put on the mandrel 2 as a breathable sheet, and a prepreg 5 of a polyimide resin is divided by the required number of sheets through the glass cloth 4. Stack one by one. Furthermore, after the glass cloth 4 is stacked on the laminated prepreg 5, a thin metal plate, in this embodiment, a thin plate having a thickness of 0.3 to 0.6 mm made of an aluminum alloy is stacked, and the thin plate 6 is stacked. Mold into a mold. As shown in FIG. 3, the thin plate 6 has holes 7 formed with a predetermined hole density, and the hole diameter and hole density of the holes 7 are set according to the shape of the molded product, molding conditions, and the like. Things. The thin plate 6 is coated with, for example, a silicone-based release agent before molding. In addition, the shape of the thin plate 6 before processing is a box shape developed (FIG. 4 (a)), or a fan-shaped thin plate 6 joined to form a second half spherical shape (FIG. 4 (b)). Various variations are possible according to the shape of the molded article.

次いで、薄板6の上から、全体を覆うようにして真空
バッグフィルム8を定盤1にセットし、シーラント9に
よって真空バックフィルム8内部の気密性を確保してお
く。
Next, the vacuum bag film 8 is set on the platen 1 so as to cover the whole of the thin plate 6, and the airtightness inside the vacuum back film 8 is secured by the sealant 9.

第1図(b)に示されるように、吸引口3からの真空
吸引によって真空バッグフィルム8内側の空間10の真空
度が高まってくると、大気圧の作用によって薄板6は、
折曲されて成形型として成形される。
As shown in FIG. 1 (b), when the degree of vacuum in the space 10 inside the vacuum bag film 8 increases due to the vacuum suction from the suction port 3, the thin plate 6 becomes
It is bent and molded as a mold.

次に、以上のように成形した薄板6を使用した複合材
の成形方法について説明する。
Next, a method of forming a composite material using the thin plate 6 formed as described above will be described.

上記と同様に第2図(a)に示されるように、マンド
レル2に対して、ガラスクロス4、プリプレグ5、ガラ
スクロス4、薄板6、ガラスクロス4の順で重ね真空バ
ッグフィルム8で覆った後、吸引口3から真空吸引を行
ないプリプレグ5に薄板6を介して大気圧を負荷し、こ
のプリプレグ5の形状をマンドル2と薄板6の間で整え
る。
Similarly to the above, as shown in FIG. 2 (a), the mandrel 2 was overlaid in the order of glass cloth 4, prepreg 5, glass cloth 4, thin plate 6, and glass cloth 4 and covered with the vacuum bag film 8. Thereafter, vacuum suction is performed from the suction port 3 to apply atmospheric pressure to the prepreg 5 via the thin plate 6, and the shape of the prepreg 5 is adjusted between the mandrel 2 and the thin plate 6.

次いで、プリプレグ5をオートクレーブ内で加圧、加
熱して成形する(第2図(b))。この時、加熱温度32
0℃、加圧力14気圧の成形条件で実施したものである。
Next, the prepreg 5 is pressurized and heated in an autoclave and molded (FIG. 2 (b)). At this time, heating temperature 32
The molding was performed under the molding conditions of 0 ° C. and a pressure of 14 atm.

プリプレグ5には、硬化中、薄板6を介して均一な圧
力が負荷され、また、薄板6は、その材質が軟らかいア
ルミ合金であるので、積層したプリプレグ5の角部にな
じむとともに、接着硬化に伴うプリプレグ5の板厚の変
化に追従しやすいので、この部分の板厚不良を防止する
ことができる。
During the curing, a uniform pressure is applied to the prepreg 5 via the thin plate 6, and since the material of the thin plate 6 is a soft aluminum alloy, the thin plate 6 fits into the corners of the laminated prepreg 5 and is cured by adhesive. Since the change in the thickness of the prepreg 5 can be easily followed, it is possible to prevent the thickness of the prepreg 5 from being defective.

一方、プリプレグ5が硬化する過程で生成されるガス
は薄板6の孔7を通して排出され、残留ガスによるボイ
ドの発生を防止することができる。
On the other hand, the gas generated in the process of curing the prepreg 5 is exhausted through the holes 7 of the thin plate 6, and the generation of voids due to the residual gas can be prevented.

また、余剰樹脂も薄板6の孔7を通して外部に流出す
るが、その流出量は薄板6の孔7の孔径、孔密度に関係
してくるので、これらを適宜変えて調整するによって、
繊維体積含有率Vfの値を適正な値にコントロールするこ
とができる。実際、上記の成形条件で、薄板6の孔7の
孔径が1.0mm〜1.8mm、孔密度が1cm2あたり0.5〜1個の
範囲が繊維体積含有率Vfの値を適切に保つ上で好適であ
った。
Also, the excess resin flows out through the holes 7 of the thin plate 6 to the outside, but the amount of the outflow depends on the hole diameter and the hole density of the holes 7 of the thin plate 6.
The value of the fiber volume content Vf can be controlled to an appropriate value. In fact, the molding conditions described above, the preferred pore diameter of the hole 7 of the thin plate 6 is 1.0Mm~1.8Mm, range pore density 0.5-1 pieces per 1 cm 2 is in keeping appropriate values of the fiber volume content ratio V f Met.

このようにして、薄板6自体は、一般にポリイミド樹
脂を成形するのに要求される300℃成形温度下でも耐熱
性があり、各種複合材に広く適用することができる。
In this manner, the thin plate 6 itself has heat resistance even at a molding temperature of 300 ° C. generally required for molding a polyimide resin, and can be widely applied to various composite materials.

〔発明の効果〕〔The invention's effect〕

以上の説明から明らかなように、本発明によれば、孔
を明けた金属製薄板を成形型として使用しているので、
寸法精度および繊維体積含有率Vfを適正な値として内部
品質とも優れた成形品を高い温度でも成形することので
きる。
As is clear from the above description, according to the present invention, since a thin metal plate with a hole is used as a mold,
By setting the dimensional accuracy and the fiber volume content Vf to appropriate values, it is possible to mold a molded article having excellent internal quality even at a high temperature.

また、上記薄板は、真空圧によって成形品の成形工程
において簡易にしかもプリプレグになじむように成形す
ることできる等の効果を奏する。
In addition, the above-mentioned thin plate has effects such as being able to be easily formed in a molding process of a molded product by vacuum pressure so as to conform to a prepreg.

【図面の簡単な説明】[Brief description of the drawings]

第1図は本発明による複合材の成形型の成形方法の工程
を表した説明図、 第2図は本発明による複合材の成形方法の工程を表した
説明図、 第3図は成形型として用いる薄板の一部省略斜視図、 第4図は成形型として用いる薄板の変形例を表した斜視
図である。 1……定盤、2……マンドレル、3……吸引口、4……
ガラスクロス、5……プリプレグ、6……薄板、7……
孔、8……真空バッグフィルム、9……シーラント。
FIG. 1 is an explanatory view showing the steps of a method for forming a composite material mold according to the present invention, FIG. 2 is an explanatory view showing steps of a method for forming a composite material according to the present invention, and FIG. FIG. 4 is a perspective view showing a modified example of a thin plate used as a molding die. 1 ... surface plate, 2 ... mandrel, 3 ... suction port, 4 ...
Glass cloth, 5: prepreg, 6: thin plate, 7:
Holes, 8 ... vacuum bag film, 9 ... sealant.

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】プリプレグの積層体の上に真空バッグフィ
ルムを被せ、この真空バッグフィルムの内側を真空吸引
し、積層体を加圧し加熱してオートクレーブで硬化させ
るようにした複合材の成形方法において、プリプレグの
積層体に通気性シートを被せ、その上に複数の孔を有し
成形品に対応した形状の金属製薄板を載せ、この金属製
薄板に真空バッグフィルムを被せてその内側を真空吸引
し、プリプレグを加圧した状態下にオートクレーブ内で
加熱、加圧してプリプレグ積層体を硬化させることを特
徴とする複合材の成形方法。
1. A method of molding a composite material, wherein a vacuum bag film is put on a laminate of prepregs, the inside of the vacuum bag film is vacuum-evacuated, and the laminate is pressurized and heated to be cured in an autoclave. A permeable sheet is placed on the laminate of prepregs, a thin metal plate having a plurality of holes and having a shape corresponding to a molded product is placed thereon, and a vacuum bag film is placed on the thin metal plate, and the inside of the thin metal plate is evacuated. And heating the prepreg in an autoclave while applying pressure to the prepreg, thereby curing the prepreg laminate.
【請求項2】定盤上のマンドレルの上に載せられたプリ
プレグの積層体の上に複数の孔を有する金属製薄板を載
せ、この金属製薄板の上に真空バッグフィルムを被せ、
この真空バッグフィルムの内側を真空吸引し、金属製薄
板を成形型に加工することを特徴とする複合材の成形型
の成形方法。
2. A metal thin plate having a plurality of holes is placed on a prepreg laminated body placed on a mandrel on a surface plate, and a vacuum bag film is put on the metal thin plate.
A method of forming a composite material forming die, wherein the inside of the vacuum bag film is vacuum-evacuated and the thin metal plate is processed into a forming die.
JP2104526A 1990-04-20 1990-04-20 Method for forming composite material and method for forming mold Expired - Fee Related JP2947867B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2104526A JP2947867B2 (en) 1990-04-20 1990-04-20 Method for forming composite material and method for forming mold

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US7306450B2 (en) * 2004-09-29 2007-12-11 The Boeing Company Apparatuses, systems, and methods for manufacturing composite parts
GB0816114D0 (en) * 2008-09-04 2008-10-15 Airbus Uk Ltd Assembling and shaping laminate panel
CN102390159A (en) * 2011-07-20 2012-03-28 沈阳飞机工业(集团)有限公司 Process for curing tough material part with uniform-thickness complicated curved surface
CN103057128A (en) * 2012-12-25 2013-04-24 天津三爻航空航天科技发展有限公司 Automatic heating and pressurization production process for composite material specially used for small-sized unmanned plane
CN103342039A (en) * 2013-06-14 2013-10-09 南京工程学院 Composite covering part prepreg apparatus and forming method thereof
CN109986860B (en) * 2019-04-10 2020-05-05 中南大学 Fiber metal composite laminate and forming die and forming method thereof
CN113844126B (en) * 2021-09-27 2023-03-07 秦皇岛玻璃工业研究设计院有限公司 Manufacturing method of bulletproof glass for vehicle and bulletproof glass

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Publication number Priority date Publication date Assignee Title
US20220411338A1 (en) * 2021-06-25 2022-12-29 Mitsubishi Heavy Industries, Ltd. Processing method for ceramic-based composite material

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