JP2681445B2 - Gas discharge display tube - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gas discharge display tube, and more particularly to a gas discharge display tube in which a cathode and an anode are arranged opposite to each other across a discharge gap in an airtight container, and an ultraviolet radiating gas and a phosphor are filled in the airtight container. The present invention relates to a sealed gas discharge display tube.

[0002]

2. Description of the Related Art As an example of a conventional gas discharge display tube, there is a flat type gas discharge display tube 70 shown in FIG. The gas discharge display tube 70 includes a back substrate 74 made of an insulating material such as flat glass having a plurality of strip-shaped cathodes 72 arranged in parallel on one surface, and a flat glass having a plurality of strip-shaped transparent anodes 76 arranged in parallel on one surface. A front substrate 78 made of a transparent insulating material is arranged so that the cathode 72 and the transparent anode 76 intersect with each other with a predetermined gap, and the peripheral edges of both substrates are sealed with a sealing material to form an airtight container 80. Airtight container 80
A discharge gas containing Xe (xenon) gas for ultraviolet radiation is sealed in the inner space of the.

The internal space is evenly divided by front side barrier ribs 82 formed in a grid pattern on the opposite surface of the front substrate 78, and discharge cells are formed at each intersection of the cathode 72 and the transparent anode 76.
84 is formed. Further, spacers 86 are formed on the end faces of the front-side barrier ribs 82 at predetermined intervals,
As a result, a gap having a height corresponding to the height of the spacer 86 is provided between the front barrier rib 82 and the surface of the rear substrate 74.
88 is formed. The discharge cells 84 communicate with each other through the gap 88. Further, on the front surface of the rear substrate 74 and the side surface of the front barrier rib 82, a phosphor 90 corresponding to a desired emission color is formed.
Is applied. The cathode 72 is not shown,
An emitter material is deposited on the surface of a cathode substrate made of Ag / Pd (silver / palladium) paste or the like by a plasma spraying method. This emitter material is deposited in order to lower the discharge starting voltage and improve the spatter resistance.

However, by selectively applying a DC voltage between the transparent anode 76 and the cathode 72, a desired discharge cell can be obtained.
A discharge is generated in 84, the ultraviolet rays generated by the discharge excite the phosphor 90, and light having an emission color according to the type of the phosphor 90 is transmitted through the transparent anode 76 and the front substrate 78 to the outside. Is emitted to. As a result, arbitrary characters, figures, etc. are displayed on the front substrate 78 as a display surface. The gap
Via 88, the flow of ions between the discharge cells 84 is secured.

[0005]

As the emitter material, LaB ₆ (lanthanum hexaboride), which belongs to a boride of a rare earth element, is excellent in terms of discharge characteristics, spatter resistance, and the like. Also, a substance mainly containing LaB ₆ is adopted.

However, in the gas discharge display tube having the above-described structure, there arises a problem that its luminance is reduced with time and the luminescent color is changed in some cases.
As a result of various studies to investigate the cause, the inventors have found that Xe, which is an ultraviolet radiation gas, is gradually adsorbed by LaB ₆ which constitutes the emitter material.
This was demonstrated using A (X-ray microanalyzer). That is, since the amount of Xe decreases and the amount of generated ultraviolet light decreases, the amount of light emission from the phosphor itself decreases, and the luminance of the display tube decreases. It should be noted that the emission color may change because of the decrease in phosphor emission accompanying the decrease in Xe.
This is because the influence of other components (for example, Ar, Ne, etc.) in the sealed gas increases.

The present invention has been made in view of the above-mentioned drawbacks of the prior art, and it is an object of the present invention that Xe does not decrease over time, so that the luminance and the emission color do not decrease. An object of the present invention is to realize a gas discharge display tube that does not change.

[0008]

In order to achieve the above object, the inventors of the present invention have sought a substance which has excellent emitter characteristics equivalent to those of LaB ₆ and which does not adsorb Xe which is an ultraviolet radiation gas. As a result of repeated experiments, it was found that MoB (molybdenum boride) meets the above conditions, and the present invention has been completed. That is, in the gas discharge display tube according to the present invention, the anode and the cathode having the emitter material exposed at least on the surface thereof are arranged to face each other with a discharge gap therebetween, and the discharge gas containing at least Xe (xenon) and the fluorescent light are used. In a gas discharge display tube which is enclosed together with a body in an airtight container, the emitter material is made of a material containing MoB (molybdenum boride).

The airtight container has a front substrate made of a transparent insulating material having a plurality of transparent anodes formed on one surface and a back substrate made of an insulating material having a plurality of cathodes formed on one surface, and electrodes of each substrate are predetermined. Are formed so as to face each other with a gap therebetween, and the peripheral edges of both substrates are sealed to form a discharge gas containing at least Xe (xenon) and a phosphor in the airtight container, and at least the cathode. The emitter material containing MoB (molybdenum boride) may be exposed on the surface.

A cathode lead-out pattern, a cathode holding layer covering the surface of the cathode lead-out pattern, and a base end portion standing on the surface of the cathode lead-out pattern on the opposite surface of the back substrate. A columnar cathode having a tip portion protruding outside the cathode holding layer is formed while being buried in, and an emitter material containing MoB (molybdenum boride) is exposed on at least the tip portion surface of the columnar cathode. Good. Also,
On the surface of the cathode holding layer, a back side barrier rib having a plurality of holes is formed, the tip of the columnar cathode is arranged in the hole, and the hole diameter of the hole is from the cathode holding layer side. You may comprise so that it may expand gradually toward the front substrate side. Further, the entire columnar cathode may be made of an emitter material containing MoB (molybdenum boride).

As the emitter material, for example, MoB
It is desirable to use a substance in which (molybdenum boride) is mixed with BaAl ₂ O ₄ (barium aluminate).

[0012]

In the above-mentioned conventional example, Xe is adsorbed to LaB _{6 because} the radius of the La atom (La ion) and the radius of the Xe atom (Xe ion) are relatively close to each other. Xe ions are in a high energy state in La
It is considered that it is caused by collision with B ₆ and replacement with La ions and incorporation. On the other hand, since the Mo atom (Mo ion) of MoB constituting the emitter material of the present invention has a smaller radius than the Xe atom (Xe ion), Xe, which is an ultraviolet radiation gas, may be adsorbed to the emitter material. The gas discharge display tube becomes extremely stable in brightness and emission color. Also, Mo
Since B belongs to the same rare earth element boride as LaB ₆ , even if the emitter material is formed of MoB, the characteristics as a display tube (discharge start voltage, sputtering resistance, etc.) are comparable.

According to the present invention, as described above, a front substrate having a transparent anode and a rear substrate having a cathode are arranged to face each other, and the peripheral edges of both substrates are sealed to form an airtight container. Type gas discharge display tube can also be applied. In this case, the surface area of the cathode that contributes to the discharge can be increased by making the cathode shape columnar as described above and by configuring the tip end of the columnar cathode so as to project outside the cathode holding layer. As a result, a discharge is generated in a wide range, and the amount of generated ultraviolet light increases, so that the display luminance can be improved.

Further, the tip end of the columnar cathode is arranged in the hole portion of the back side barrier rib formed on the surface of the cathode holding layer, and the hole diameter of the hole portion is gradually expanded from the cathode holding layer side to the front substrate side. By forming it in a so-called funnel shape, the light generated by the discharge is efficiently reflected to the front substrate side.
The light can be condensed, and the display brightness can be further improved.

The above BaAl ₂ O ₄ has a small work function and has a remarkable function of lowering the discharge start voltage, but it itself lacks conductivity. Therefore, by mixing this BaAl ₂ O ₄ with MoB having conductivity to form an emitter material, more excellent emitter characteristics can be realized.

[0016]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of a gas discharge display tube according to the present invention will be described below with reference to the accompanying drawings. FIG. 1 is a schematic cross-sectional view showing a flat type gas discharge display tube. In this first gas discharge display tube 10, a rear substrate 12 made of an insulating material such as flat glass and a front substrate 14 made of a transparent insulating material such as flat glass are arranged to face each other with a predetermined gap therebetween. The basic structure is such that the periphery of the substrate is sealed with a sealing material (not shown) such as low melting point glass to form an airtight container 16, and the discharge gas is enclosed in the internal space of the airtight container 16. This discharge gas is composed of a mixture of Xe gas for ultraviolet radiation and He, Ar, Ne gas or the like.

On the opposite surface of the rear substrate 12, the rear substrate
As shown in FIG. 2, which is a partial perspective view of 12, strip-shaped cathode extraction patterns 18 made of Ag / Pd-based paste or the like are arranged in a plurality of rows. Further, on the upper surface of each cathode extraction pattern 18, a plurality of cylindrical columnar cathodes 20 made of an emitter material in which MoB and BaAl ₂ O ₄ are mixed at a ratio of about 2: 1 are erected at regular intervals. ing. This columnar cathode 20
Has its base end 20a buried in the cathode holding layer 22 covering the opposite surface of the rear substrate 12 and the cathode extraction pattern 18, and its tip 20b projects outside the cathode holding layer 22. There is. The cathode holding layer 22 is made of an insulating material such as glass.

On the opposite surface of the front substrate 14, the front substrate
As shown in FIG. 3, which is a partial perspective view of 14, a plurality of strip-shaped transparent anodes 24 made of a NESA film (SnO ₂ ) or an ITO film (In ₂ O ₃ .SnO ₂ ) are arranged in parallel. In addition, the first partition wall 26a for partitioning the transparent anodes 24 and the transparent anodes 24
Lattice-shaped front-side barrier ribs 26 having second partition walls 26b that divide the partition wall at predetermined intervals in the lengthwise direction are formed. The front side barrier rib 26 is made of an insulating material such as glass. Furthermore, the first partition wall of the front side barrier rib 26
A spacer 28 made of an insulating material such as glass is formed at the intersection of the 26a and the second partition wall 26b.

As shown in FIG. 1, a rear substrate 12 and a front substrate
14 is a cathode extraction pattern formed on each facing surface
18 and the transparent anode 24 intersect with each other with a predetermined gap, and the columnar cathode 20 is partitioned by the first partition wall 26a and the second partition wall 26b of the front side barrier rib 26 formed on the facing surface of the front substrate 14. It is arranged to be done. At this time, the end surface of each spacer 28 formed on the front side barrier rib 26 has a rear substrate.
The cathode supporting layer 22 is brought into contact with the surface. The tip portion 20b of each columnar cathode faces the transparent anode 24 with a predetermined gap. As a result, the first partition wall 26 is provided for each columnar cathode 20.
A discharge cell 30 surrounded by a, the second partition wall 26b, the front substrate 14, and the cathode holding layer 22 is formed.

The tip portion 20 of the columnar cathode in each discharge cell 30
A phosphor 32 corresponding to a desired emission color is attached near b. To be more precise, the phosphor 32 is formed on the surface of the cathode holding layer 22 around the tip portion 20b of the columnar cathode, the spacer 28
Of the first barrier ribs 26a and the second barrier ribs 26b of the barrier ribs on the front side (the vicinity of the cathode holding layer 22). Note that the phosphor is attached to the side surface portion of the spacer 28 and the lower portions of the first partition wall 26a and the second partition wall 26b of the front side barrier rib in the state of FIG. 3 (the state in which the front substrate 14 is down). A phosphor coating is printed on the spacer 28, the first partition 26a and the second partition 26b in a pattern slightly wider than the lateral width of each end face, and the protruding phosphor coating is allowed to hang down naturally on the side surface. Is realized by

Therefore, a transparent anode is supplied from a power source (not shown).
When a DC voltage is applied between the cathode 24 and the columnar cathode 20, the discharge cell
Electric discharge is generated within 30 and ultraviolet rays are generated. This ultraviolet ray excites the phosphor 32 in the discharge cell 30, and light having a predetermined emission color passes through the transparent anode 24 and the front substrate 14 and is emitted to the outside. By selectively executing this voltage application via a control / drive circuit (not shown), a desired discharge cell 30 is obtained.
It is possible to generate discharge light emission and to display arbitrary characters and figures on the front substrate 14.

By the way, in the case of a conventional flat type gas discharge display tube, as shown in FIG. 15, the cathode shape is a flat band shape and the thickness thereof is relatively thin, so that the discharge cell There is a drawback that discharge can be generated only in a limited portion of the inside and the display brightness becomes insufficient. On the other hand, in the display tube according to the present embodiment, the columnar cathode is used, and since the tip end portion 20b of the columnar cathode is projected to the outside of the cathode holding layer 22, not only the top surface but also the side peripheral surface is formed. It will contribute to the discharge. Therefore, the ultraviolet light generated by the discharge is the phosphor 32 adhered to the surface of the cathode holding layer 22.
Since it is sufficiently illuminated, extremely high brightness display is possible. Thus, the phosphor adhered to the surface of the cathode holding layer 22
Since 32 can be effectively used for discharge light emission, a large adhered area of the phosphor 32 can be secured.

As shown in FIG. 4, the base end portion 20a of the columnar cathode is shown.
Adheres to the cathode holding layer 22 and is securely held by the cathode holding layer 22. Therefore, simply the cathode extraction pattern
As compared with the case where the bottom surface of the columnar cathode 20 is connected to the surface of the column 18, the connection strength to the cathode extraction pattern 18 is remarkably high, and it is difficult to easily pull out. For this reason, even if the columnar cathode 20 is formed thin to correspond to the miniaturization of the discharge cells 30, sufficient connection strength can be secured. Further, the peripheral portion of the columnar cathode 20 on the surface of the cathode holding layer 22 is recessed as shown,
A groove 34 is formed between it and the columnar cathode 20. Therefore, as shown in FIG. 5, the phosphor 32 deposited on the surface of the cathode holding layer 22 flows into the groove 34. As a result, the columnar cathode
It is possible to secure a sufficient thickness of the phosphor 32 at the root portion of 20. Further, the groove 34 also plays a role of regulating the disordered flow of the phosphor 32.

As described above, since the end surface of the spacer 28 formed on the front side barrier rib 26 is in contact with the surface of the cathode holding layer 22, the end surfaces of the first partition wall 26a and the second partition wall 26b are different from each other. A gap 35 corresponding to the height of the spacer 28 is formed between the cathode holding layer 22 and the cathode holding layer 22 (FIG. 1). Therefore, the flow of ions is ensured between the discharge cells 30 through the gap 35. The height of the gap 35 is sufficiently smaller than the protruding height of the tip portion 20b of the columnar cathode, and most of the sputter material generated by the discharge is scattered to the front substrate 14 side. There is no possibility that the metal will enter into the adjacent discharge cells 30 through the gaps 35 and the insulation between the columnar cathodes 20 will be hindered.

The display color of the first gas discharge display tube 10 is
Although it largely depends on the type of the phosphor 32, it is also affected by components other than Xe mixed in the discharge gas. Therefore, a desired display color can be realized by selecting the phosphor 32 and appropriately adjusting the components and mixing ratio of the discharge gas. Further, the necessary display colors can be realized by setting the above-mentioned conditions so that white light can be obtained by discharging and by bonding a color filter to the surface or the inner surface of the front substrate 14.

Next, a method of manufacturing the cathode holding layer 22 and the columnar cathode 20 will be described with reference to FIGS.
First, a band-shaped cathode lead-out pattern 18 is adhered and formed on one surface of the rear substrate 12 by printing Ag / Pd-based paste, and an insulating material such as glass paste or ceramic paste is thick-film printed. Thus, the base material of the cathode holding layer provided with the mold holes 36 corresponding to the outer shape of the columnar cathode 20.
38 is formed in advance (FIG. 6). In addition to this, MoB and Ba
An emitter material 40 consisting of a mixture with Al ₂ O ₄ is sprayed by plasma spraying (FIG. 7). As a result, the mold material 36 is filled with the emitter material 40. Although BaAl ₂ O ₄ forming the emitter material 40 is an insulator itself, Ba is liberated in the material by this plasma spraying, so that a certain degree of conductivity appears.

Thereafter, the emitter material 40 deposited on the surface of the base material 38 of the cathode holding layer is polished and removed (FIG. 8). As a result, the emitter material filled in the mold cavity 36 is
Only 40 will be left. Finally, by firing the base material 38 of the cathode holding layer at a predetermined temperature, the cathode holding layer 22
Is formed. At this time, by setting the temperature higher than the normal firing temperature, the base material 38 of the cathode holding layer shrinks as a whole. Then, the contraction of the base material 38 of the cathode holding layer causes the emitter material 40 filled in the mold cavity 36 to protrude from the surface of the cathode holding layer 22, and as a result, the columnar cathode 20 is formed. (FIG. 9). In addition, during the firing / contraction, the gap 34 between the cathode holding layer 22 and the columnar cathode 20 is formed.
Is also formed. The shrinkage rate of the base material 38 of the cathode holding layer is determined in consideration of the material and melting point of the insulating material and the firing temperature.
Therefore, the protrusion degree of the columnar cathode 20 can be adjusted by appropriately selecting these conditions.

In the above manufacturing method, the columnar cathode
Although an example in which the emitter material 40 serving as the element of 20 is sprayed onto the base material 38 of the cathode holding layer by plasma spraying is not limited to this, for example, by printing, in the mold hole 36 of the base material 38 of the cathode holding layer. The emitter material 40 may be filled.

Further, as the material of the columnar cathode 20, instead of using the emitter material 40 over the entire surface, a cylindrical base portion is formed by using an ordinary conductive material such as Ni paste, and the emitter material is formed on the tip surface. May be coated.

Further, in the above manufacturing method, the tip end portion 20b of the columnar cathode is made to relatively project by contracting the base material 38 of the cathode holding layer, but the present invention is not limited to this. For example, the cathode holding layer 22 having a required height is completed in advance, and then the material of the columnar cathode 20 is formed to a required height using a means such as printing or plasma spraying, and thus the tip of the columnar cathode is formed. The portion 20b may be configured to project.

Next, another embodiment according to the present invention will be described with reference to FIGS. As shown in FIG. 10, the second gas discharge display tube 50 is characterized in that a back side barrier rib 52 is formed on the surface of the cathode holding layer 22.
The back-side barrier rib 52 is made of an insulating material such as glass and has a plurality of holes 54 surrounding each columnar cathode 20. The hole 54 has a so-called funnel shape formed such that the hole diameter gradually increases from the lower side (cathode holding layer 22 side) to the upper side (front substrate 14 side).
The tip portion 20b of the columnar cathode is housed in the approximate center thereof.
Further, as shown in FIG. 11, the back side barrier rib 52 is a three-layered structure including a first layer 52a adhered to the surface of the cathode holding layer 22, a second layer 52b and a third layer 52c which are sequentially stacked. Each layer has a through hole having a different hole diameter. Then, the through hole 54a of the first layer having the smallest hole diameter, the through hole 54b of the second layer having the next smallest hole diameter,
The through holes 54c of the third layer having the largest hole diameter are positioned so as to be concentrically continuous, so that the hole portion 54 having the hole diameter gradually expanding from the lower side to the upper side is formed.

A light reflecting layer 56 is formed on the inner surface of the hole 54 by depositing a metal such as Al or Ni as shown in FIG. Further, on the surface of the light reflecting layer 56 and the portion of the surface of the cathode holding layer 22 not covered by the back side barrier rib 52 (the root portion of the columnar cathode 20), the phosphor 32 corresponding to a desired emission color is provided. It is applied by spray painting.

FIG. 13 is a perspective view showing the front substrate 14,
On the opposite surface of the front substrate 14, a plurality of strip-shaped transparent anodes 24 are arranged side by side. Also, the first partition between the transparent anodes 24
Of the barrier ribs 26a and the second barrier ribs 26b for partitioning the transparent anodes 24 at predetermined intervals in the lengthwise direction are formed on the grid-like front side barrier ribs 26. Further, a spacer 28 is formed at the intersection of the first partition wall 26a and the second partition wall 26b on the end surface of the front side barrier rib 26.

That is, the structure of the front substrate 14 is almost the same as the front substrate shown in FIG.
The only difference is that the height of the front barrier rib 26 is low. This is because the back side barrier rib 52 in this embodiment takes over most of the role of surrounding each discharge cell 30.

Since the end surface of each spacer 28 formed on the front barrier rib 26 is in contact with the surface of the rear barrier rib 52, each end surface of the first partition wall 26a and the second partition wall 26b and the rear wall surface of the second partition wall 26b are not in contact with each other. A spacer is formed between the surface of the barrier rib 52.
A gap 35 corresponding to the height of 28 is formed. Therefore,
The flow of ions is ensured between the discharge cells 30 through the gap 35.

In the second gas discharge display tube 50,
The hole 54 of the back side barrier rib 52 has a funnel shape in which the hole diameter gradually increases from the lower side to the upper side, and the light generated by the discharge is reflected on the inner surface of the hole 54 and the front substrate 14
Since the light is condensed on the side, extremely high brightness display is possible. Further, since the light reflection layer 56 is formed on the inner surface of the hole 54, this reflection / condensation can be realized more effectively.

The back side barrier rib 52 is formed by printing a thick film of an insulating material such as a glass paste or a ceramic paste on the surface of the cathode holding layer 22 and firing it. Alternatively, the back side barrier ribs 52 are formed by laminating thin glass sheets.
May be formed. In addition, the hole 54 of the rear barrier rib 52
Instead of depositing the light reflecting layer 56 on the inner surface of the above, the back side barrier rib 52 itself may be formed of a light reflecting substance. Furthermore, the back-side barrier rib 52 does not necessarily have to have a multi-layer structure, and may have a single-layer structure.

In the above, the flat type gas discharge display tube has been exemplified, but the present invention is not limited to this. That is, a gas discharge display tube having a structure in which a pair of electrodes are opposed to each other with a predetermined gap, the emitter material is exposed on the surface of at least one of the electrodes, and a discharge gas containing Xe and a phosphor are enclosed in an airtight container. It can be widely applied to, and its shape is not particularly limited. For example,
Like a third gas discharge display tube 60 shown in FIG. 14, the upper and lower ends of a cylindrical glass tube are fused to form an airtight container 61,
A pair of rod-shaped discharge electrodes 62 and a Xe-containing gas are sealed in the airtight container 61, the phosphor 32 is applied to the inner wall of the airtight container 61, and the lead terminals 64 are led out of the airtight container 61. The emitter material 40 containing MoB may be deposited on the surface of 62.

[0039]

In the gas discharge display tube according to the present invention, since the emitter material on the cathode side is made of a material containing MoB, Xe for ultraviolet radiation is not adsorbed on the emitter material. Therefore, there is no decrease in luminance or change in emission color due to a decrease in the amount of ultraviolet radiation, and extremely stable display characteristics can be realized.

[Brief description of the drawings]

FIG. 1 is a schematic sectional view showing one embodiment of a gas discharge display tube according to the present invention.

FIG. 2 is a schematic perspective view showing a part on the back substrate side according to the embodiment.

FIG. 3 is a schematic perspective view showing a part of the front substrate side according to the embodiment.

FIG. 4 is a schematic enlarged cross-sectional view showing the periphery of a columnar cathode according to the example.

FIG. 5 is a schematic enlarged cross-sectional view showing the periphery of a columnar cathode according to the example.

FIG. 6 is a schematic cross-sectional view showing a manufacturing process of the cathode holding layer and the columnar cathode according to the same example.

FIG. 7 is a schematic cross-sectional view showing a manufacturing process of the cathode holding layer and the columnar cathode according to the example.

FIG. 8 is a schematic cross-sectional view showing a process of manufacturing the cathode holding layer and the columnar cathode according to the same example.

FIG. 9 is a schematic cross-sectional view showing the manufacturing process of the cathode holding layer and the columnar cathode according to the example.

FIG. 10 is a schematic sectional view showing another embodiment of the gas discharge display tube according to the present invention.

FIG. 11 is a schematic perspective view showing a part on the rear substrate side according to the embodiment.

FIG. 12 is a schematic enlarged cross-sectional view showing the periphery of a columnar cathode according to the example.

FIG. 13 is a schematic perspective view showing a part on the front substrate side according to the embodiment.

FIG. 14 is a schematic sectional view showing another embodiment of the gas discharge display tube according to the present invention.

FIG. 15 is a schematic cross-sectional view showing a conventional example.

[Explanation of symbols]

 10 First gas discharge display tube 12 Rear substrate 14 Front substrate 16 Airtight container 18 Cathode extraction pattern 20 Columnar cathode 20a Columnar cathode base end 20b Columnar cathode tip 22 Cathode holding layer 24 Transparent anode 32 Phosphor 40 Emitter material 50 Second gas discharge display tube 52 Rear barrier rib 54 Hole of rear barrier rib 60 Third gas discharge display tube 61 Airtight container 62 Rod-shaped discharge electrode

Claims (6)

(57) [Claims] 1. An anode and a cathode, at least the surface of which the emitter material is exposed, are arranged to face each other with a discharge gap, and this is enclosed in an airtight container together with a discharge gas containing at least Xe (xenon) and a phosphor. A gas discharge display tube comprising the above, wherein the emitter material is composed of a material containing MoB (molybdenum boride). 2. A front substrate made of a transparent insulating material having a plurality of transparent anodes formed on one surface thereof, and a back substrate made of an insulating material having a plurality of cathodes formed on one surface thereof. The two substrates are arranged so as to be opposed to each other, and the peripheral edges of both substrates are sealed to form an airtight container.
The gas according to claim 1, wherein a discharge gas containing (xenon) and a phosphor are enclosed, and the emitter material containing MoB (molybdenum boride) is exposed on at least the surface of the cathode. Discharge display tube. 3. A cathode lead-out pattern, a cathode holding layer covering the surface of the cathode lead-out pattern, and a base end portion standing on the surface of the cathode lead-out pattern on the surface of the back substrate facing the cathode lead-out pattern. A columnar cathode was formed which was embedded in the layer and had a tip protruding outside the cathode holding layer, and an emitter material containing MoB (molybdenum boride) was exposed on at least the tip surface of the columnar cathode. The gas discharge display tube according to claim 2, wherein: 4. A back side barrier rib having a plurality of holes is formed on the surface of the cathode holding layer, the tip of the columnar cathode is arranged in the hole, and the hole diameter of the hole is the above. The gas discharge display tube according to claim 3, wherein the gas discharge display tube is configured to gradually expand from the cathode holding layer side toward the front substrate side. 5. The gas discharge display tube according to claim 3, wherein the entire columnar cathode is made of an emitter material containing MoB (molybdenum boride). 6. The emitter material is MoB (molybdenum boride).
Baden) to BaAl _TwoO_Four(Barium aluminate) mixed
2. It is composed of a substance that
5. The gas discharge display tube according to any one of items 5 to 5.