JP2556422B2 - Painted surface cleaning composition - Google Patents
Painted surface cleaning compositionInfo
- Publication number
- JP2556422B2 JP2556422B2 JP4226206A JP22620692A JP2556422B2 JP 2556422 B2 JP2556422 B2 JP 2556422B2 JP 4226206 A JP4226206 A JP 4226206A JP 22620692 A JP22620692 A JP 22620692A JP 2556422 B2 JP2556422 B2 JP 2556422B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- cleaning
- hydrogen fluoride
- oil
- vehicle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、乗用車の塗装面を洗浄
し光沢表面を形成する塗装面洗浄剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a paint surface cleaning composition for cleaning a paint surface of a passenger car to form a glossy surface.
【0002】[0002]
【従来の技術】通常、車輌に付着した汚染物は、水性汚
れと油性汚れに大別される。2. Description of the Related Art Usually, contaminants attached to a vehicle are roughly classified into water-based stains and oil-based stains.
【0003】この中、水性汚れは多量の水を使用しブラ
シや布で拭き取る等、機械的な方法で洗い流することが
できるが、そのための水の使用量は膨大な量になる。Among these, the water-based stains can be washed away by a mechanical method such as wiping with a brush or cloth using a large amount of water, but the amount of water used for that purpose becomes enormous.
【0004】近年都市水道の節水が唱えられ、また、住
宅事情からも、車輌洗浄に多量の水を使用することが制
限されるようになって、従来、多くの特許等の公報に汚
れの掃払性が高く、保水性の良いブラシを使用した、所
謂、節水型の洗浄手段が種々提案されている。In recent years, the water saving of city water supply has been advocated, and due to the housing situation, the use of a large amount of water for vehicle cleaning has been restricted. Various so-called water-saving type cleaning means using a brush having high dispersibility and good water retention have been proposed.
【0005】しかしながら、水の使用量を少なくする
と、炎天下で水分の蒸発が速くなり、水量不足により塗
装面に傷を付けたり、汚れの再付着を生じ、充分な洗浄
ができなくなる。However, if the amount of water used is reduced, the evaporation of water becomes faster under hot weather, and the paint surface may be scratched or stains may be redeposited due to insufficient amount of water, resulting in insufficient cleaning.
【0006】また、油性汚れの中、軽度の油性汚れは、
洗浄剤による洗浄やエマルジョン洗浄法により洗浄し、
ピッチ、タールによる強固な汚れは研磨剤や溶剤が使用
されているが、水性汚れの洗浄には不適当である。Among the oily stains, mild oily stains are
Cleaning with a cleaning agent or emulsion cleaning method,
Abrasives and solvents are used for strong stains caused by pitch and tar, but they are not suitable for cleaning water-based stains.
【0007】また、光沢と撥水性を与えるための光沢剤
としては、固形、練り状、エマルジョン状のカルナバワ
ックスやシリコンオイルを洗浄後の塗装表面に塗布して
いるが、その作業のための労力は相当なものである。As a brightening agent for imparting luster and water repellency, solid, paste-like, or emulsion-like carnauba wax or silicone oil is applied to the painted surface after washing. Is considerable.
【0008】また、これらの改良方法として、水性汚れ
と油性汚れを同時に除去し塗装面に光沢を付与する、ワ
ックスやシリコンのエマルジョンによる洗浄方法も多く
提案されている。As a method for improving these, there have been proposed many washing methods using wax or silicone emulsion, which simultaneously removes water-based stains and oil-based stains to impart gloss to the coated surface.
【0009】しかしながら、この多くは、拭きむらが生
じたり、組成中の油分が、ガラス面に付着して、油膜に
よる視界不良を生じ、洗浄後の雨中における車輌運行に
危険があり、洗浄後、ガラス面の油膜を拭き取る作業を
余儀なくされている。However, in many of these cases, uneven wiping occurs, and oil components in the composition adhere to the glass surface to cause poor visibility due to an oil film, which is dangerous for vehicle operation in the rain after washing. There is no choice but to wipe off the oil film on the glass surface.
【0010】[0010]
【発明が解決しようとする課題】本発明の目的は、車輌
等の塗装面を傷めないこと、少量の水を用いての洗浄で
も汚れが再付着することがなく、炎天下での使用にも乾
燥が遅く、拭きむらを生じることがなく、洗浄に際して
ガラス面に付着しても油膜形成による視界不良を生じな
いこと等、車輌の塗装面の洗浄に必要な条件を充足し、
その上5リットル程度の水で、充分な洗浄とワツクス掛
同様の光沢表面を得ることができる洗浄剤を提供するこ
とにある。DISCLOSURE OF THE INVENTION The object of the present invention is not to damage the painted surface of a vehicle or the like, to prevent dirt from being redeposited even when washed with a small amount of water, and to dry it even under hot weather. Satisfies the conditions necessary for cleaning the painted surface of the vehicle, such as slow cleaning, no uneven wiping, and no poor visibility due to oil film formation even if it adheres to the glass surface during cleaning.
In addition, it is to provide a cleaning agent which can sufficiently wash and obtain a glossy surface similar to waxing with about 5 liters of water.
【0011】[0011]
【課題を解決するための手段】本発明の車輛用の塗装面
洗浄剤組成物は、シリコンオイルエマルジョン、フッ素
樹脂エマルジョン、鉱物油エマルジョン及び動植物油エ
マルジョンからなる群から選ばれる少なくとも1種のエ
マルジョンと、分子量50〜5,000のポリオール
と、フッ化フ素あるいはフッ化水素のアルカリ金属塩と
を含有する車輛用の塗装面洗浄剤組成物において、エマ
ルジョン中の油分に対してポリオールが1〜30重量
%、フッ化水素あるいはフッ化水素のアルカリ金属塩が
0.001〜1重量%含有されていることを特徴とする
ものである。 A paint surface cleaner composition for vehicles according to the present invention is at least one selected from the group consisting of silicone oil emulsions, fluororesin emulsions, mineral oil emulsions and animal and vegetable oil emulsions.
Marujon and polyol with molecular weight of 50 to 5,000
And an alkali metal salt of fluorine fluoride or hydrogen fluoride
In a paint surface cleaning composition for vehicles containing
1 to 30 parts by weight of polyol based on oil content
%, Hydrogen fluoride or an alkali metal salt of hydrogen fluoride
The content is 0.001 to 1% by weight .
【0012】また、本発明の洗浄剤組成物中のエマルジ
ョン油分に対して、フッ化水素あるいはフッ化水素のア
ルカリ金属塩を0.001〜1重量%の添加配合は、シ
リコンオイルやフッ素樹脂の塗装面の付着性を向上し、
長期にわたり、撥水効果を持続させることができ、ま
た、ガラス面への吸着により、油膜障害を回避すること
ができる。[0012] Further, 0.001 to 1% by weight of hydrogen fluoride or an alkali metal salt of hydrogen fluoride is added to the emulsion oil in the detergent composition of the present invention. Improves adhesion on the painted surface,
The water-repellent effect can be maintained for a long period of time, and the oil film can be prevented from being damaged by adsorption on the glass surface.
【0013】さらに、本発明の洗浄剤に、ポリオキシエ
チレンアルキルエーテルやアルキルベンゼンスルフォン
酸ソーダ、第四級アルキルアミン塩等の界面活性剤を配
合し、洗浄助剤としてトリポリ燐酸ソーダ、炭酸ソーダ
のようなアルカリビルダーを添加することにより、洗浄
効果を一層向上させることができる。Further, a surfactant such as polyoxyethylene alkyl ether, sodium alkylbenzene sulfonate, quaternary alkylamine salt, etc. is added to the detergent of the present invention, and it is used as a cleaning aid such as sodium tripolyphosphate and sodium carbonate. The cleaning effect can be further improved by adding an alkaline builder.
【0014】また、EDTAのようなキレート剤の配合
が、不溶性金属の洗浄および地下水等の硬水による洗浄
には望ましい。The addition of a chelating agent such as EDTA is desirable for washing insoluble metals and washing with hard water such as groundwater.
【0015】上記の洗浄剤は、水5,000ccに20
cc程度分散せしめた洗浄水を、ブラシ、布、スポンジ
等を用いて、車輌の塗装面に使用する。The above cleaning agent is used in 5,000 cc of water for 20 times.
The washing water dispersed in about cc is used on the painted surface of the vehicle by using a brush, cloth, sponge, or the like.
【0016】[0016]
【作用】本発明の洗浄剤組成は、シリコンオイル等のエ
マルジョンは、洗浄作業中の塗膜面に滑性を付与し、
砂、汚物等に起因する傷を最小限にすると共に、洗浄後
の車輌塗装面に非油性の撥水コーティング膜を形成す
る。In the cleaning composition of the present invention, the emulsion such as silicone oil imparts lubricity to the coating film surface during cleaning,
Minimize scratches caused by sand, dirt, etc., and form a non-oil water-repellent coating film on the painted surface of the vehicle after washing.
【0017】[0017]
実施例 1 東レダウコーニングシリコーン(株)製シリコーンエマ
ルジョンSH−490を30gと、ポリエチレングリコ
ール(mw=400)5gを混合し洗浄光沢剤を得る。Example 1 30 g of silicone emulsion SH-490 manufactured by Toray Dow Corning Silicone Co., Ltd. and 5 g of polyethylene glycol (mw = 400) are mixed to obtain a cleaning brightener.
【0018】この洗浄光沢剤を、水で1,000倍に薄
めた溶液5リットルで車輌を洗浄した結果、塗装面は光
沢があり、炎天下の洗浄でも、洗浄面の乾燥も遅く、拭
きむらも生じなかった。As a result of washing the vehicle with 5 liters of a solution prepared by diluting this cleaning brightener 1,000 times with water, the coated surface is glossy, and even when it is washed in the hot sun, the drying of the washed surface is slow and even the uneven wiping is caused. Did not happen.
【0019】実施例 2 鉱物油10gに乳化剤として、ポリオキシエチレンノニ
ルフェニールエーテル(n=5)1gを混合し、水を加
えフッ化水素0.1gを添加混合攪拌後、東レダウコー
ニングシリコーン(株)製シリコーンエマルジョンSH
−490を30g配合すると、洗浄光沢剤を得る。Example 2 10 g of mineral oil was mixed with 1 g of polyoxyethylene nonylphenyl ether (n = 5) as an emulsifier, water was added, and 0.1 g of hydrogen fluoride was added and mixed and stirred. ) Silicone emulsion SH
Addition of 30 g of -490 gives a cleansing brightener.
【0020】この洗浄光沢剤を水で1000倍に薄めた
溶液5リットルで車輛を洗浄した結果、塗装面は光沢が
あり、フロントガラス面の水滴除去効果も十分であっ
た。As a result of cleaning the vehicle with 5 liters of a solution prepared by diluting this cleaning brightener 1000 times with water, the coated surface was glossy and the effect of removing water droplets on the windshield surface was sufficient.
【0021】実施例3 鉱物油15gにラウリルジエタノールアマイド1gを混
合し、水50gを加え、次いでフッ化ナトリウム0.1
g、ポリエチレングリコール(mw=400)5g、ト
リポリ燐酸ソーダ1g、エチレンジアミンテトラアセテ
ート0.5g、ドデシルベンゼンスルフォン酸ソーダを
添加混合攪拌後、東レダウコーニングシリコーン(株)
製シリコーンエマルジョンSH−490を30g、フッ
素樹脂エマルジョンを混合すると、洗浄光沢剤を得る。Example 3 15 g of mineral oil was mixed with 1 g of lauryl diethanol amide, 50 g of water was added, and then 0.1% of sodium fluoride was added.
g, polyethylene glycol (mw = 400) 5 g, sodium tripolyphosphate 1 g, ethylenediamine tetraacetate 0.5 g, and sodium dodecylbenzene sulfonate were added, mixed and stirred, and then Toray Dow Corning Silicone Co., Ltd.
A cleaning brightener is obtained by mixing 30 g of a silicone emulsion SH-490 and a fluororesin emulsion.
【0022】この洗浄光沢剤を水で1000倍に薄めた
溶液5リットルで車輛を洗浄したものは、水性、油性汚
れとも完全に除去され、塗装面は光沢があり、フロント
ガラス面の水滴除去効果も十分で、油膜障害も生じなか
った。When the vehicle was washed with 5 liters of a solution of this cleaning brightener diluted 1000 times with water, both water-based and oily stains were completely removed, and the coated surface was glossy and the effect of removing water drops on the windshield surface was obtained. Was sufficient, and no oil film damage occurred.
【0023】[0023]
【発明の効果】 (1) 5リットル程度の水によって、普通乗用車を完
全に洗浄することができる。EFFECTS OF THE INVENTION (1) A normal passenger car can be completely washed with about 5 liters of water.
【0024】(2)洗浄後の塗装面に滑性を付与し、固
形ワックス並の光沢と撥水性の被膜を形成する。(2) The coated surface after washing is provided with lubricity to form a coating having gloss and water repellency comparable to those of solid wax.
【0025】(3)洗浄に際し、塗装面を傷付ける事が
なく、ガラス面に洗浄水が付着しても、後除去を必要と
しない。(3) The surface to be painted is not damaged during cleaning, and even if cleaning water adheres to the glass surface, it does not need to be removed later.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C11D 7:40) (56)参考文献 特開 昭63−248897(JP,A) 特開 昭63−51499(JP,A)─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Internal reference number FI technical display location C11D 7:40) (56) References JP-A-63-248897 (JP, A) JP-A-63 -51499 (JP, A)
Claims (1)
脂エマルジョン、鉱物油エマルジョン及び動植物油エマ
ルジョンからなる群から選ばれる少なくとも1種のエマ
ルジョンと、分子量50〜5,000のポリオールと、
フッ化水素あるいはフッ化水素のアルカリ金属塩とを含
有する車輌用の塗装面洗浄剤組成物において、エマルジ
ョン中の油分に対してポリオールが1〜30重量%、フ
ッ化水素あるいはフッ化水素のアルカリ金属塩が0.0
01〜1重量%含有されていることを特徴とする車輌用
の塗装面洗浄剤組成物。1. At least one emma selected from the group consisting of silicone oil emulsions, fluororesin emulsions, mineral oil emulsions and animal and vegetable oil emulsions.
Rougeon and a polyol having a molecular weight of 50 to 5,000 ,
Containing hydrogen fluoride or an alkali metal salt of hydrogen fluoride
In a paint surface cleaner composition for a vehicle having
1 to 30% by weight of polyol based on the oil content
Alkali metal salt of hydrogen fluoride or hydrogen fluoride is 0.0
For vehicles characterized by containing 0 to 1% by weight
Painted surfaces cleaner compositions.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4226206A JP2556422B2 (en) | 1992-08-25 | 1992-08-25 | Painted surface cleaning composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4226206A JP2556422B2 (en) | 1992-08-25 | 1992-08-25 | Painted surface cleaning composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0673400A JPH0673400A (en) | 1994-03-15 |
JP2556422B2 true JP2556422B2 (en) | 1996-11-20 |
Family
ID=16841560
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4226206A Expired - Fee Related JP2556422B2 (en) | 1992-08-25 | 1992-08-25 | Painted surface cleaning composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2556422B2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4430818C2 (en) * | 1994-08-30 | 1998-04-16 | Hoffmann Sonax Kg | Care emulsion for automatic vehicle washes |
JP2010007262A (en) * | 2008-06-24 | 2010-01-14 | Panasonic Electric Works Co Ltd | Toilet bowl system |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0672239B2 (en) * | 1986-08-21 | 1994-09-14 | タイホ−工業株式会社 | Polishing cleaning method |
JPH0672240B2 (en) * | 1987-04-02 | 1994-09-14 | タイホ−工業株式会社 | Polish cleaner |
-
1992
- 1992-08-25 JP JP4226206A patent/JP2556422B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0673400A (en) | 1994-03-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |