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JP2022116388A - Bottled smoke-flavor acidic emulsion-state seasoning and production method thereof, and method of retaining smoke odor - Google Patents

Bottled smoke-flavor acidic emulsion-state seasoning and production method thereof, and method of retaining smoke odor Download PDF

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Publication number
JP2022116388A
JP2022116388A JP2021012254A JP2021012254A JP2022116388A JP 2022116388 A JP2022116388 A JP 2022116388A JP 2021012254 A JP2021012254 A JP 2021012254A JP 2021012254 A JP2021012254 A JP 2021012254A JP 2022116388 A JP2022116388 A JP 2022116388A
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emulsified liquid
liquid seasoning
egg yolk
acidic emulsified
mass
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JP2021012254A
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JP7349461B2 (en
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大樹 市田
Hiroki Ichida
智砂 渡辺
Chisa Watanabe
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Kewpie Corp
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QP Corp
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Abstract

To provide a bottled smoke-flavor acidic emulsion-state seasoning which can retain a smoke odor and maintain an emulsion state even after long-term storage.SOLUTION: A bottled smoke-flavor acidic emulsion-state seasoning at least contains edible fat and oil, vinegar, and egg yolk. At least some of the vinegar is smoked vinegar, The egg yolk includes enzyme-untreated egg yolk and enzyme-treated egg yolk. In the acidic emulsion-state seasoning, the content of the enzyme-treated egg yolk in raw equivalent is from 0.08 pt.mass to 20 pts.mass inclusive per pt.mass of the enzyme-untreated egg yolk in raw equivalent.SELECTED DRAWING: None

Description

特許法第30条第2項適用申請有り https://www.kewpie.co.jp/products/product/mayonnaise/mayonnaise/4901577082849/ https://www.kewpie.com/newsrelease/2021/1986/ https://www.kewpie.co.jp/karashi_kunsei/ https://www.kewpie.co.jp/recipes/products/mayonnaise/mayonnaise/mayonnaise/4901577082849/ https://www.kewpie.co.jp/recipes/products/mayonnaise/mayonnaise/mayonnaise/4901577082849/?p=2 https://www.kewpie.co.jp/recipes/recipe/QP10005676/ https://www.kewpie.co.jp/recipes/recipe/QP10005678/ https://www.kewpie.co.jp/recipes/recipe/QP10006356/ https://www.kewpie.co.jp/recipes/recipe/QP10006348/ https://www.kewpie.co.jp/recipes/recipe/QP10006347/ https://www.kewpie.co.jp/recipes/recipe/QP10006346/ https://www.kewpie.co.jp/recipes/recipe/QP10006345/ https://www.kewpie.co.jp/recipes/recipe/QP10006344/ https://www.kewpie.co.jp/recipes/recipe/QP10006343/ https://www.kewpie.co.jp/recipes/recipe/QP10006341/ https://www.kewpie.co.jp/recipes/recipe/QP10006329/ https://www.kewpie.co.jp/recipes/recipe/QP10006328/There is an application for the application of Article 30, Paragraph 2 of the Patent Law https://www. kewpie. co. jp/products/product/mayonnaise/mayonnaise/4901577082849/ https://www. kewpie. com/newsrelease/2021/1986/https://www. kewpie. co. jp/karashi_kunsei/ https://www. kewpie. co. jp/recipes/products/mayonnaise/mayonnaise/mayonnaise/4901577082849/ https://www. kewpie. co. jp/recipes/products/mayonnaise/mayonnaise/mayonnaise/4901577082849/? p=2 https://www. kewpie. co. jp/recipes/recipe/QP10005676/https://www. kewpie. co. jp/recipes/recipes/QP10005678/https://www. kewpie. co. jp/recipes/recipe/QP10006356/https://www. kewpie. co. jp/recipes/recipe/QP10006348/https://www. kewpie. co. jp/recipes/recipe/QP10006347/https://www. kewpie. co. jp/recipes/recipe/QP10006346/https://www. kewpie. co. jp/recipes/recipe/QP10006345/https://www. kewpie. co. jp/recipes/recipe/QP10006344/https://www. kewpie. co. jp/recipes/recipe/QP10006343/https://www. kewpie. co. jp/recipes/recipe/QP10006341/https://www. kewpie. co. jp/recipes/recipe/QP10006329/https://www. kewpie. co. jp/recipes/recipe/QP10006328/

特許法第30条第2項適用申請有り https://www.kewpie.co.jp/recipes/recipe/QP10005679/ https://www.kewpie.co.jp/recipes/recipe/QP10005677/ 食品新聞 令和3年1月13日付 朝刊3面 日経MJ 令和3年1月13日付 010ページ フード・ウイークリー 令和3年1月15日付 第2486号 小売経済新聞 令和3年1月15日付 日経産業新聞 令和3年1月19日付 012ページ 鶏鳴新聞 令和3年1月25日付 信濃毎日新聞 令和3年1月28日付 朝刊8面 千葉日報 令和3年1月28日付 朝刊4面 ゲットナビ 2021年3月号 136頁 https://entabe.jp/36678/kiwpie-smoked-mayonnaise https://prtimes.jp/main/html/rd/p/000000116.000044559.html https://www.atpress.ne.jp/news/242469 https://www.nikkei.com/article/DGXLRSP602687_W1A100C2000000/ https://www.mylifenews.net/food/2021/01/post-4121.html https://kireistyle-woman.com/news/life/contents/299234 https://news.livedoor.com/article/detail/19493474/ https://fv1.jp/73833/ http://www.jpubb.com/press/2617243/ https://b2b-ch.infomart.co.jp/news/detail.page?IMNEWS1=2340644 https://www.foods-ch.com/news/press_1280670/ http://machi.jpubb.com/jpr/2617243 https://kaden.watch.impress.co.jp/docs/news/1298571.htmlThere is an application for the application of Article 30, Paragraph 2 of the Patent Law https://www. kewpie. co. jp/recipes/recipe/QP10005679/https://www. kewpie. co. jp/recipes/recipe/QP10005677/ Food Newspaper January 13, 3rd year of Reiwa morning edition page 3 Nikkei MJ January 13th, 3rd year of Reiwa page 010 Food Weekly January 15th, 3rd year of Reiwa No. 2486 Retail economic newspaper January 15, 2021 Nikkei Sangyo Shimbun January 19, 2021 Page 012 Keimei Shimbun January 25, 2021 Shinano Mainichi Shimbun January 28, 2021 morning edition page 8 Chiba Nippo January 2021 January 28, 2020 morning edition page 4 Get Navi March 2021, page 136 https://entabe. jp/36678/kiwpie-smoked-mayonnaise https://prtimes. jp/main/html/rd/p/000000116.000044559. html https://www. at press. ne. jp/news/242469 https://www. nikkei. com/article/DGXLRSP602687_W1A100C2000000/https://www. mylifenews. net/food/2021/01/post-4121. html https://kirestyle-woman. com/news/life/contents/299234 https://news. live door. com/article/detail/19493474/https://fv1. jp/73833/http://www. jpubb. com/press/2617243/https://b2b-ch. infomart. co. jp/news/detail. page? IM NEWS1=2340644 https://www. foods-ch. com/news/press_1280670/ http://machi. jpubb. com/jpr/2617243 https://kaden. watch. impress. co. jp/docs/news/1298571. html

特許法第30条第2項適用申請有り http://topics.smt.docomo.ne.jp/article/kaden_watch/trend/kaden_watch-1298571?fm=latestnews https://news.goo.ne.jp/article/kaden_watch/trend/kaden_watch-1298571.html https://news.yahoo.co.jp/articles/059144633d0d5c319719bd3f8dd93fdd9f238d6b https://netafull.net/neta-eat/064493.html https://www.work-master.net/2021207831 https://www.nikkei.com/article/DGXZQODZ0692M0W1A100C2000000 http://www.jpackworld.com/newsflash/2021/01/post-5435.html https://www.jacom.or.jp/ryutsu/news/2021/01/210108-48729.php https://www.nomooo.jp/column/172185/ https://gunosy.com/articles/ePt6I https://www.excite.co.jp/news/article/Nomooo_172185/ https://www.bcnretail.com/news/detail/20210108_208204.html http://topics.smt.docomo.ne.jp/article/bcnretail/trend/bcnretail-208204?fm=latestnews https://news.goo.ne.jp/article/bcnretail/trend/bcnretail-208204.html http://jp.news.gree.net/news/entry/3886111 https://gunma.ikuze.net/detail?id=720815979009474560 https://gunosy.com/articles/eCowtThere is an application for the application of Article 30, Paragraph 2 of the Patent Law http://topics. smt. docomo. ne. jp/article/kaden_watch/trend/kaden_watch-1298571? fm=latestnews https://news. goo. ne. jp/article/kaden_watch/trend/kaden_watch-1298571. html https://news. Yahoo. co. jp/articles/059144633d0d5c319719bd3f8dd93fdd9f238d6b https://netafull. net/neta-eat/064493. html https://www. work-master. net/2021207831 https://www. nikkei. com/article/DGXZQODZ0692M0W1A100C2000000 http://www. jpack world. com/newsflash/2021/01/post-5435. html https://www. jacom. or. jp/ryutsu/news/2021/01/210108-48729. php https://www. nomooo. jp/column/172185/https://gunosy. com/articles/ePt6I https://www. excite. co. jp/news/article/Nomooo_172185/https://www. bcnretail. com/news/detail/20210108_208204. html http://topics. smt. docomo. ne. jp/article/bcnretail/trend/bcnretail-208204? fm=latestnews https://news. goo. ne. jp/article/bcnretail/trend/bcnretail-208204. html http://jp. news. gree. net/news/entry/3886111 https://gunma. ikuze. net/detail? id=720815979009474560 https://gunosy. com/articles/eCowt

特許法第30条第2項適用申請有り https://kanagawa.ikuze.net/detail?id=720815979009474560 http://news.line.me/article/feed/a1a8cb3ce2c7 https://news.livedoor.com/article/detail/19511893/ https://mellow.ismyprecious.jp/detail?id=720815979009474560 https://news.mixi.jp/view_news.pl?id=6372195&media_id=87 https://news.ismyprecious.jp/detail?id=720815979009474560 https://oita.ikuze.net/detail?id=720815979009474560 https://okayama.ikuze.net/detail?id=720815979009474560 https://okinawa.ikuze.net/detail?id=720815979009474560 https://shimane.ikuze.net/detail?id=720815979009474560 https://this.kiji.is/720815979009474560 https://workout.ismyprecious.jp/detail?id=720815979009474560 https://news.yahoo.co.jp/articles/c6ea974cb0bc132e0ba1d9a978b8d2dd116b4a7d https://ure.pia.co.jp/articles/-/926714 https://www.excite.co.jp/news/article/BcnRetail_208204/ https://kimetsu.ismyprecious.jp/detail?id=720815979009474560 https://news.nicovideo.jp/watch/nw8777044?news_ref=search_searchThere is an application for the application of Article 30, Paragraph 2 of the Patent Law https://kanagawa. ikuze. net/detail? id=720815979009474560 http://news. line. me/article/feed/a1a8cb3ce2c7 https://news. live door. com/article/detail/19511893/https://mellow. ismyprecious. jp/detail? id=720815979009474560 https://news. mixi. jp/view_news. pl? id=6372195&media_id=87 https://news. ismyprecious. jp/detail? id=720815979009474560 https://oita. ikuze. net/detail? id=720815979009474560 https://okayama. ikuze. net/detail? id=720815979009474560 https://okinawa. ikuze. net/detail? id=720815979009474560 https://shimane. ikuze. net/detail? id=720815979009474560 https://this. kiji. is/720815979009474560 https://workout. ismyprecious. jp/detail? id=720815979009474560 https://news. Yahoo. co. jp/articles/c6ea974cb0bc132e0ba1d9a978b8d2dd116b4a7d https://ure. pia. co. jp/articles/-/926714 https://www. excite. co. jp/news/article/BcnRetail_208204/ https://kimetsu. ismyprecious. jp/detail? id=720815979009474560 https://news. nico video. jp/watch/nw8777044? news_ref = search_search

特許法第30条第2項適用申請有り https://literacy.ismyprecious.jp/detail?id=720815979009474560 https://bungaku.ismyprecious.jp/detail?id=720815979009474560 https://jinsei.ismyprecious.jp/detail?id=720815979009474560 https://oshiro-tenshu.net/detail?id=720815979009474560 https://ekiden-news.net/detail?id=720815979009474560 https://shokuhin.net/39337/2021/01/13/kakou/choumi/ https://news.nifty.com/article/economy/business/12308-927194/ https://news.livedoor.com/article/detail/19528434/ https://gigazine.net/news/20210114-kewpie-smoked-mayonnaise/ https://news.headlines.auone.jp/stories/series/general/14107500 https://gunosy.com/articles/eOXQ8 https://news.livedoor.com/article/detail/19535409/ https://antenna.jp/articles/12296307 http://news.line.me/article/feed/db9e396ebc3c https://www.olive-hitomawashi.com/news/2021/01/post-1048.html https://straightpress.jp/20210117/468336 https://news.ameba.jp/entry/20210117-459/ https://kireistyle-woman.com/news/life/contents/300594There is an application for the application of Article 30, Paragraph 2 of the Patent Law https://literacy. ismyprecious. jp/detail? id=720815979009474560 https://bungaku. ismyprecious. jp/detail? id=720815979009474560 https://jinsei. ismyprecious. jp/detail? id=720815979009474560 https://oshiro-tenshu. net/detail? id=720815979009474560 https://ekiden-news. net/detail? id=720815979009474560 https://shokuhin. net/39337/2021/01/13/kakou/choumi/ https://news. nifty. com/article/economy/business/12308-927194/ https://news. live door. com/article/detail/19528434/https://gigazine. net/news/20210114-kewpie-smoked-mayonnaise/ https://news. headlines. au one. jp/stories/series/general/14107500 https://gunosy. com/articles/eOXQ8 https://news. live door. com/article/detail/19535409/https://antenna. jp/articles/12296307 http://news. line. me/article/feed/db9e396ebc3c https://www. olive-hitomawashi. com/news/2021/01/post-1048. html https://straightpress. jp/20210117/468336 https://news. ameba. jp/entry/20210117-459/ https://kirestyle-woman. com/news/life/contents/300594

特許法第30条第2項適用申請有り https://news.livedoor.com/article/detail/19548355/ https://michill.jp/author/articles/72589 https://getnews.jp/archives/2907570 https://news.prcm.jp/article/258529 https://mdpr.jp/gourmet/detail/2398928 http://keimei.ne.jp/article/%e3%80%8c%e7%87%bb%e8%a3%bd%e3%83%9e%e3%83%a8%e3%83%8d%e3%83%bc%e3%82%ba%e3%80%8d%e3%80%80%e3%82%ad%e3%83%a6%e3%83%bc%e3%83%94%e3%83%bc%e3%81%8c%e6%96%b0%e7%99%ba%e5%a3%b2.html https://macaro-ni.jp/95637 https://www.shinmai.co.jp/news/article/CNTS2021012700465 https://www.saga-s.co.jp/articles/-/626702 https://www.oita-press.co.jp/1002000000/2021/01/27/NP2021012701001498 https://www.amazon.co.jp/dp/B08TWWDVQZ https://no-vice.jp/article/7994/ https://www.toonippo.co.jp/articles/-/468009 https://www.jiji.com/jc/article?k=000000116.000044559&g=prt https://www.zakzak.co.jp/eco/news/210106/prl2101060089-p1.html https://www.zakzak.co.jp/eco/news/210106/prl2101060089-n1.html https://webun.jp/item/7728619 https://antenna.jp/articles/12218610There is an application for the application of Article 30, Paragraph 2 of the Patent Law https://news. live door. com/article/detail/19548355/https://michill.com/article/detail/19548355/ jp/author/articles/72589 https://getnews. jp/archives/2907570 https://news. prcm. jp/article/258529 https://mdpr. jp/gourmet/detail/2398928 http://keimei. ne. jp/article/%e3%80%8c%e7%87%bb%e8%a3%bd%e3%83%9e%e3%83%a8%e3%83%8d%e3%83%bc%e3%82 %ba%e3%80%8d%e3%80%80%e3%82%ad%e3%83%a6%e3%83%bc%e3%83%94%e3%83%bc%e3%81%8c %e6%96%b0%e7%99%ba%e5%a3%b2. html https://macaro-ni. jp/95637 https://www. shinmai. co. jp/news/article/CNTS2021012700465 https://www. saga-s. co. jp/articles/-/626702 https://www. oita-press. co. jp/1002000000/2021/01/27/NP2021012701001498 https://www. amazon. co. jp/dp/B08TWWDVQZ https://no-vice. jp/article/7994/https://www. toonippo. co. jp/articles/-/468009 https://www. jiji. com/jc/article? k=000000116.000044559&g=prt https://www. zakzak. co. jp/eco/news/210106/prl2101060089-p1. html https://www. zakzak. co. jp/eco/news/210106/prl2101060089-n1. html https://web. jp/item/7728619 https://antenna. jp/articles/12218610

本発明は、容器詰め燻製風味酸性乳化液状調味料に関し、より詳細には、少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料に関する。また、本発明は、容器詰め燻製風味酸性乳化液状調味料の製造方法にも関する。さらに、本発明は、容器詰め燻製風味酸性乳化液状調味料の燻製香の保持方法に関する。 TECHNICAL FIELD The present invention relates to a packaged smoked-flavored acidic emulsified liquid seasoning, and more particularly to a packaged smoked-flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk. The present invention also relates to a method for producing a container-packed smoked flavored acidic emulsified liquid seasoning. Furthermore, the present invention relates to a method for retaining the smoky aroma of a packaged smoked-flavored acidic emulsified liquid seasoning.

マヨネーズ等の酸性乳化液状調味料は、程よい酸味と乳化によるコクが好ましく、お酒のおつまみと相性が良いため、様々な食材と合わせて食されてきた。また、燻製された食品も、口の中に残る燻製香が酒との相性が良いため、同じくおつまみとして好まれてきた。燻製された食品としては、例えば、ゆで卵を燻煙処理した燻製ゆで卵等が製造されてきた(例えば、特許文献1参照)。さらに、燻製された食品は、酸性乳化液状調味料とも非常に相性がよく、例えば燻製ゆで卵等に酸性乳化液状調味料を付して食されることも通常行われてきた。 Acidic emulsified liquid seasonings such as mayonnaise are preferred for their moderate sourness and richness due to emulsification, and because they go well with alcoholic beverages, they have been eaten together with various foodstuffs. Smoked foods have also been favored as snacks because the smoked aroma that lingers in the mouth goes well with sake. As smoked foods, for example, smoked boiled eggs obtained by smoking boiled eggs have been produced (see, for example, Patent Document 1). Furthermore, smoked foods are very compatible with acidic emulsified liquid seasonings, and for example, smoked boiled eggs and the like are usually eaten with acidic emulsified liquid seasonings.

また、近年、食材ではなく、マヨネーズ等の酸性乳化液状調味料自体に燻製風味を付与することが試みられている。例えば、家庭では、市販の酸性乳化液状調味料を購入し、それを燻製処理することが行われている。しかしながら、酸性乳化液状調味料を工業的に大量に燻煙処理して、燻煙風味酸性乳化液状調味料を生産することは実現されていない。別の方法として、予め燻製した食用油脂を用いて酸性乳化液状調味料を製造する方法も存在するが、燻製した食用油脂の風味と本来の乳化によるコクとの相性が悪く、酸性乳化液状調味料全体の風味が好ましくなかった。 Also, in recent years, attempts have been made to impart smoked flavor not to foodstuffs but to acidic emulsified liquid seasonings such as mayonnaise. For example, at home, commercially available acidic emulsified liquid seasonings are purchased and smoked. However, it has not been realized to industrially smoke a large amount of an acidic emulsified liquid seasoning to produce a smoked flavored acidic emulsified liquid seasoning. As another method, there is a method of producing an acidic emulsified liquid seasoning using pre-smoked edible oil. I didn't like the overall flavor.

特開2007-37486号公報JP-A-2007-37486

そこで、本発明者らは、燻製処理した食酢を酸性乳化液状調味料に含有させることで、好ましい燻製風味を付与した酸性乳化液状調味料を製造することを試みたが、保存後期に燻製香が著しく減少してしまい、数カ月の賞味期限まで燻製香を維持できなかったり、また、乳化状態を安定的に維持できずに分離してしまうという課題を新たに知見した。 Therefore, the present inventors tried to produce an acidic emulsified liquid seasoning imparting a preferable smoked flavor by adding smoked vinegar to the acidic emulsified liquid seasoning. We have newly discovered the problems that the smoked aroma cannot be maintained until the expiration date of several months, and the emulsified state cannot be stably maintained and separates.

本発明は、上記の背景技術及び新たに知見した課題に鑑みてなされたものであり、長期間の保存後であっても、燻製香を保持し、かつ乳化状態を維持できる容器詰め燻製風味酸性乳化液状調味料を提供することを目的とする。 The present invention has been made in view of the above-described background art and newly discovered problems. An object of the present invention is to provide an emulsified liquid seasoning.

本発明者等は鋭意検討した結果、驚くべきことに、少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料において、卵黄として酵素未処理卵黄及び酵素処理卵黄を含有させ、酸性乳化液状調味料中の酵素未処理卵黄及び酵素処理卵黄の含有量を調節することで、上記の技術的課題を解決できることを知見し、本発明を完成するに至った。 As a result of intensive studies by the present inventors, surprisingly, a packaged smoked-flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk contains an enzyme-untreated egg yolk and an enzyme-treated egg yolk as the egg yolk. The present inventors have found that the above technical problems can be solved by adjusting the contents of enzyme-untreated egg yolk and enzyme-treated egg yolk in the acidic emulsified liquid seasoning, and have completed the present invention.

すなわち、本発明の一態様によれば、
少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料であって、
前記食酢の少なくとも一部が燻製酢であり、
前記卵黄として酵素未処理卵黄及び酵素処理卵黄を含有し、
前記酸性乳化液状調味料中の酵素処理卵黄の含有量が、生換算で、前記酵素未処理卵黄の生換算での1質量部に対して0.08質量部以上20質量部以下であることを特徴とする、
酸性乳化液状調味料が提供される。
That is, according to one aspect of the present invention,
A container-packed smoked flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk,
At least part of the vinegar is smoked vinegar,
Containing an enzyme-untreated egg yolk and an enzyme-treated egg yolk as the egg yolk,
The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.08 parts by mass or more and 20 parts by mass or less in terms of raw equivalent per 1 part by mass of the enzyme-untreated egg yolk in raw equivalent. characterized by
An acidic emulsified liquid seasoning is provided.

本発明の態様においては、前記酸性乳化液状調味料中の酵素処理卵黄の含有量が、生換算で、前記酸性乳化液状調味料全量に対して0.1質量%以上30質量%以下であることが好ましい。 In the aspect of the present invention, the content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.1% by mass or more and 30% by mass or less based on the total amount of the acidic emulsified liquid seasoning in raw conversion. is preferred.

本発明の態様においては、前記酵素処理卵黄が、ホスホリパーゼA処理卵黄であることが好ましい。 In the aspect of the present invention, the enzyme-treated egg yolk is preferably phospholipase A-treated egg yolk.

本発明の態様においては、前記酸性乳化液状調味料は、水相中に油相が油滴状に分散しており、油滴のメジアン径が10.0μm以下であることが好ましい。 In the aspect of the present invention, the acidic emulsified liquid seasoning preferably has an oil phase dispersed in an aqueous phase in the form of oil droplets, and the oil droplets preferably have a median diameter of 10.0 μm or less.

本発明の態様においては、前記調味料がマヨネーズ様調味料であることが好ましい。 In the aspect of this invention, it is preferable that the said seasoning is a mayonnaise-like seasoning.

本発明の態様においては、前記酵素未処理卵黄の含有量が、生換算で、前記酸性乳化液状調味料全量に対して0.1質量%以上であることが好ましい。 In the aspect of the present invention, it is preferable that the content of the enzyme-untreated egg yolk is 0.1% by mass or more in raw conversion with respect to the total amount of the acidic emulsified liquid seasoning.

本発明の態様においては、前記食用油脂の含有量が、前記酸性乳化液状調味料全量に対して30質量%以上90質量%以下であることが好ましい。 In the aspect of this invention, it is preferable that content of the said edible fats and oils is 30 mass % or more and 90 mass % or less with respect to the said acidic emulsified liquid seasoning whole quantity.

本発明の態様においては、前記燻製酢の含有量が、前記酸性乳化液状調味料全量に対して1.0質量%以上20.0質量%以下であることが好ましい。 In an aspect of the present invention, the content of the smoked vinegar is preferably 1.0% by mass or more and 20.0% by mass or less with respect to the total amount of the acidic emulsified liquid seasoning.

本発明の態様においては、前記酸性乳化液状調味料の25℃における粘度が5Pa・s以上2000Pa・s以下であることが好ましい。 In the aspect of the present invention, it is preferable that the acidic emulsified liquid seasoning has a viscosity at 25° C. of 5 Pa·s or more and 2000 Pa·s or less.

また、本発明の別の態様によれば、
少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料の製造方法であって、
食酢の少なくとも一部として燻製酢を用い、
前記卵黄として酵素未処理卵黄及び酵素処理卵黄を用い、
前記酸性乳化液状調味料中の前記酵素処理卵黄の含有量が、生換算で、前記酵素未処理卵黄の生換算での1質量部に対して0.08質量部以上20質量部以下であることを特徴とする、
酸性乳化液状調味料の製造方法が提供される。
Also, according to another aspect of the present invention,
A method for producing a container-packed smoked-flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk,
Using smoked vinegar as at least part of the vinegar,
Using an enzyme-untreated egg yolk and an enzyme-treated egg yolk as the egg yolk,
The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.08 parts by mass or more and 20 parts by mass or less, in terms of raw, per 1 part by mass of the enzyme-untreated egg yolk in terms of raw. characterized by
A method for producing an acidic emulsified liquid seasoning is provided.

また、本発明の別の態様によれば、
少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料の燻製香を保持する方法であって、
食酢の少なくとも一部として燻製酢を用い、
前記卵黄として酵素未処理卵黄及び酵素処理卵黄を用い、
前記酸性乳化液状調味料中の前記酵素処理卵黄の含有量が、生換算で、前記酵素未処理卵黄の生換算での1質量部に対して0.08質量部以上20質量部以下であることを特徴とする、
燻製香の保持方法が提供される。
Also, according to another aspect of the present invention,
A method for retaining a smoked aroma of a packaged smoked-flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk, comprising:
Using smoked vinegar as at least part of the vinegar,
Using an enzyme-untreated egg yolk and an enzyme-treated egg yolk as the egg yolk,
The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.08 parts by mass or more and 20 parts by mass or less, in terms of raw, per 1 part by mass of the enzyme-untreated egg yolk in terms of raw. characterized by
A method for retaining smoked aroma is provided.

本発明によれば、長期間の保存後であっても、燻製香を保持し、かつ乳化状態を維持できる容器詰め燻製風味酸性乳化液状調味料を提供することができる。また、本発明によれば、このような容器詰め燻製風味酸性乳化液状調味料の製造方法を提供することができる。さらに、本発明によれば、容器詰め燻製風味酸性乳化液状調味料の燻製香の保持方法を提供することができる。このような容器詰め燻製風味酸性乳化液状調味料は消費者の食欲を惹起することができ、容器詰め燻製風味酸性乳化液状調味料のさらなる市場拡大が期待できる。 According to the present invention, it is possible to provide a packaged smoked-flavored acidic emulsified liquid seasoning that retains the smoked aroma and maintains the emulsified state even after long-term storage. Further, according to the present invention, it is possible to provide a method for producing such a container-packed smoked-flavored acidic emulsified liquid seasoning. Furthermore, according to the present invention, it is possible to provide a method for retaining the smoky flavor of a packaged smoked-flavored acidic emulsified liquid seasoning. Such a packaged smoked-flavored acidic emulsified liquid seasoning can arouse the appetite of consumers, and further expansion of the market for packaged smoked-flavored acidic emulsified liquid seasoning can be expected.

<容器詰め燻製風味酸性乳化液状調味料>
本発明の酸性乳化液状調味料は、燻製香を有し、少なくとも、食用油脂、食酢、及び卵黄を含有するものであり、水及び他の原料等をさらに含んでもよい。酸性乳化液状調味料は容器に充填された状態で、長期間の保存後でも燻製香を保持している。
<Container packed smoked flavor acidic emulsified liquid seasoning>
The acidic emulsified liquid seasoning of the present invention has a smoked flavor and contains at least edible oil, vinegar and egg yolk, and may further contain water and other ingredients. The acidic emulsified liquid seasoning is packed in a container and retains its smoky flavor even after long-term storage.

酸性乳化液状調味料は、水中油型(O/W型)エマルションやW/O/W型複合エマルションの構成を有してもよく、水中油型(O/W型)エマルションの構成が好ましい。例えば、酸性乳化液状調味料は、水中油型(O/W型)エマルションのマヨネーズ様調味料であることが好適である。マヨネーズ様調味料としては、マヨネーズやドレッシング等を挙げることができる。消費者庁が定める「食品表示基準」では、ドレッシングのうち粘度が30Pa・s以上が半固体状ドレッシングと呼ばれる。その中で卵黄等決められた原料を用い、水分含量が30質量%以下、油脂含量が65質量%以上のものがマヨネーズである。本発明におけるマヨネーズ様調味料には、食品表示基準で定めるマヨネーズと類似の性状(例えば、味、外観、主原料等)を有しながら成分組成が食品表示基準に合致しない類似商品群も含まれる。 The acidic emulsified liquid seasoning may have a configuration of an oil-in-water (O/W) emulsion or a W/O/W composite emulsion, preferably an oil-in-water (O/W) emulsion. For example, the acidic emulsified liquid seasoning is preferably an oil-in-water (O/W) emulsion mayonnaise-like seasoning. Examples of mayonnaise-like seasonings include mayonnaise and dressings. According to the Food Labeling Standards established by the Consumer Affairs Agency, dressings with a viscosity of 30 Pa·s or more are called semi-solid dressings. Among them, mayonnaise is one that uses predetermined raw materials such as egg yolk and has a water content of 30% by mass or less and a fat content of 65% by mass or more. The mayonnaise-like seasoning in the present invention includes a group of similar products that have similar properties (e.g., taste, appearance, main ingredients, etc.) to mayonnaise defined by food labeling standards but whose component composition does not meet food labeling standards. .

(酸性乳化液状調味料の水分含量)
酸性乳化液状調味料の水分含量は、特に限定されずに他の成分の含有量に応じて適宜設定することができる。酸性乳化液状調味料の水分含量は、好ましくは1質量%以上60質量%以下であり、下限値はより好ましくは5質量%以上であり、さらに好ましくは10質量%以上であり、また、上限値はより好ましくは50質量%以下であり、さらに好ましくは40質量%以下であり、さらにより好ましくは30質量%以下である。
(Water content of acidic emulsified liquid seasoning)
The water content of the acidic emulsified liquid seasoning is not particularly limited and can be appropriately set according to the content of other ingredients. The water content of the acidic emulsified liquid seasoning is preferably 1% by mass or more and 60% by mass or less, and the lower limit is more preferably 5% by mass or more, still more preferably 10% by mass or more. is more preferably 50% by mass or less, still more preferably 40% by mass or less, and still more preferably 30% by mass or less.

(酸性乳化液状調味料のpH)
酸性乳化液状調味料のpHは、好ましくは3.0以上4.8以下であり、下限値はより好ましくは3.3以上であり、さらに好ましくは3.5以上であり、また、上限値はより好ましくは4.7以下であり、さらに好ましくは4.6以下である。酸性液状調味料のpHが上記範囲内であれば、酸性乳化液状調味料の微生物発生を制御して保存性を高めながら、酸性乳化液状調味料の風味を良好にすることができる。なお、酸性乳化液状調味料のpHの値は、1気圧、品温20℃とした時に、市販のpH測定器(例えば、株式会社堀場製作所製卓上型pHメータF-72)を用いて測定した値である。
(pH of acidic emulsified liquid seasoning)
The pH of the acidic emulsified liquid seasoning is preferably 3.0 or more and 4.8 or less, the lower limit is more preferably 3.3 or more, still more preferably 3.5 or more, and the upper limit is It is more preferably 4.7 or less, still more preferably 4.6 or less. If the pH of the acidic liquid seasoning is within the above range, it is possible to improve the flavor of the acidic emulsified liquid seasoning while controlling the growth of microorganisms in the acidic emulsified liquid seasoning to improve the storage stability. The pH value of the acidic emulsified liquid seasoning was measured using a commercially available pH measuring instrument (for example, desktop pH meter F-72 manufactured by Horiba, Ltd.) at 1 atm and 20°C product temperature. is a value.

(酸性乳化液状調味料の粘度)
酸性乳化液状調味料の粘度は、特に限定されないが、例えば5Pa・s以上2000Pa・s以下であり、下限値は好ましくは15Pa・s以上であり、より好ましくは20Pa・s以上であり、さらに好ましくは25Pa・s以上であり、また、上限値は好ましくは1500Pa・s以下であり、より好ましくは1000Pa・s以下であり、さらに好ましくは500Pa・s以下である。酸性乳化液状調味料に上記範囲内の粘度を付与することで、酸性乳化液状調味料の風味をより感じることができる。
なお、粘度の測定方法は、BH形粘度計を使用し、品温25℃、回転数2rpmの条件で、粘度が5Pa・s未満のとき:ローターNo.5、粘度が5Pa・s以上500Pa・s未満のとき:ローターNo.6、500Pa・s以上のとき:ローターNo.7を使用し、測定開始後ローターが2回転した時の示度により算出した値である。
(Viscosity of acidic emulsified liquid seasoning)
The viscosity of the acidic emulsified liquid seasoning is not particularly limited, but is, for example, 5 Pa·s or more and 2000 Pa·s or less, and the lower limit is preferably 15 Pa·s or more, more preferably 20 Pa·s or more, and still more preferably is 25 Pa·s or more, and the upper limit is preferably 1500 Pa·s or less, more preferably 1000 Pa·s or less, and still more preferably 500 Pa·s or less. By imparting a viscosity within the above range to the acidic emulsified liquid seasoning, the flavor of the acidic emulsified liquid seasoning can be felt more.
The viscosity was measured using a BH viscometer under the conditions of a product temperature of 25°C and a rotation speed of 2 rpm, and when the viscosity was less than 5 Pa·s: Rotor No. 5. When the viscosity is 5 Pa·s or more and less than 500 Pa·s: Rotor No. 6, 500 Pa·s or more: Rotor No. 7, and calculated from the reading when the rotor rotates twice after the start of measurement.

(酸性乳化液状調味料のL値)
酸性乳化液状調味料のL値は、好ましくは60以上98以下であり、下限値は好ましくは65以上であり、さらに好ましくは70以上である。酸性乳化液状調味料のL値が上記範囲内であることで、燻製風味酸性乳化液状調味料として好ましい色調を得ることができる。
なお、色の明度を示すL値は、物質が有する色の明度を規定する値であり、0から100の間の数値で表される。L値が100である場合、最も明るい状態(完全な白色)を示し、一方、L値が0である場合最も暗い状態(完全な黒色)を示す。
(L value of acidic emulsified liquid seasoning)
The L value of the acidic emulsified liquid seasoning is preferably 60 or more and 98 or less, and the lower limit is preferably 65 or more, more preferably 70 or more. When the L value of the acidic emulsified liquid seasoning is within the above range, it is possible to obtain a preferable color tone as the smoked flavor acidic emulsified liquid seasoning.
Note that the L value, which indicates the lightness of a color, is a value that defines the lightness of a color possessed by a substance, and is represented by a numerical value between 0 and 100. An L value of 100 indicates the lightest state (perfectly white), while an L value of 0 indicates the darkest state (perfectly black).

(油滴のメジアン径)
酸性乳化液状調味料中の油滴のメジアン径(累積頻度が50%になる粒子径)は、上限値は好ましくは10.0μm以下であり、より好ましくは7.0μm以下であり、より好ましくは5.0μm以下であり、また、下限値は好ましくは1.0μm以上である。酸性乳化液状調味料中の油滴のメジアン径が前記上限値以下であれば、保存中の酸性乳化液状調味料の褐変を抑制することができる。
なお、本発明における油滴のメジアン径(累積頻度が50%になる粒子径)は、レーザー回折式粒度分布測定装置「粒度分布計MT3300EXII(日機装株式会社製)」を用いて、分析条件:体積基準、非球形、屈折率1.6、粒子径測定範囲:0.021μm以上2000μm以下、粒子径区分:132chで測定される値である。また、累積頻度とは、当該範囲の粒子径区分に入る粒子の割合が全体の何%に該当するかを表す値である。
(median diameter of oil droplets)
The upper limit of the median diameter of the oil droplets in the acidic emulsified liquid seasoning (the particle diameter at which the cumulative frequency is 50%) is preferably 10.0 μm or less, more preferably 7.0 μm or less, and more preferably It is 5.0 μm or less, and the lower limit is preferably 1.0 μm or more. If the median diameter of the oil droplets in the acidic emulsified liquid seasoning is equal to or less than the upper limit, browning of the acidic emulsified liquid seasoning during storage can be suppressed.
The median diameter of the oil droplets (the particle diameter at which the cumulative frequency is 50%) in the present invention is measured using a laser diffraction particle size distribution analyzer "particle size distribution meter MT3300EXII (manufactured by Nikkiso Co., Ltd.)" under the analysis conditions: volume Standard, non-spherical, refractive index 1.6, particle size measurement range: 0.021 μm or more and 2000 μm or less, particle size division: 132 ch. Also, the cumulative frequency is a value that indicates what percentage of the total particles belong to the particle size category of the range.

(食用油脂)
酸性乳化液状調味料に用いる食用油脂は、特に限定されず従来公知の食用油脂を用いることができる。具体的には、食用油脂として、例えば、菜種油、大豆油、コーン油、パーム油、綿実油、ひまわり油、サフラワー油、胡麻油、オリーブ油、亜麻仁油、米油、椿油、荏胡麻油、グレープシードオイル、ピーナッツオイル、アーモンドオイル、アボカドオイル等の植物油脂、魚油、牛脂、豚脂、鶏脂、又はMCT(中鎖脂肪酸トリグリセリド)、ジグリセリド、硬化油、エステル交換油等のような化学的あるいは酵素的処理等を施して得られる油脂等を用いることができる。これらの中でも植物油脂を用いることが好ましく、菜種油、大豆油、コーン油、パーム油、またはこれらの混合油を用いることがより好ましい。
(Edible oils and fats)
Edible oils and fats used in acidic emulsified liquid seasonings are not particularly limited, and conventionally known edible oils and fats can be used. Specifically, edible oils and fats include, for example, rapeseed oil, soybean oil, corn oil, palm oil, cottonseed oil, sunflower oil, safflower oil, sesame oil, olive oil, linseed oil, rice oil, camellia oil, perilla sesame oil, grapeseed oil, Vegetable oils such as peanut oil, almond oil, avocado oil, fish oil, beef tallow, lard, chicken fat, or chemical or enzymatic treatments such as MCT (medium chain triglycerides), diglycerides, hydrogenated oils, transesterified oils, etc. Fats and oils obtained by applying such as can be used. Among these, it is preferable to use vegetable oils and fats, and it is more preferable to use rapeseed oil, soybean oil, corn oil, palm oil, or mixed oils thereof.

(食用油脂の含有量)
食用油脂の含有量は、酸性乳化液状調味料全体に対して、好ましくは30質量%以上90質量%以下であり、下限値はより好ましくは40質量%以上であり、さらに好ましくは50質量%以上であり、さらにより好ましくは60質量%以上であり、また、上限値はより好ましくは85質量%以下であり、さらに好ましくは80質量%以下である。酸性乳化液状調味料中の油脂の含有量が上記範囲内であれば、油由来のコク味を十分に感じながら、長期間の保存後であっても、燻製香を保持し、かつ乳化状態を維持することができる。
(Content of edible oil)
The content of the edible oil is preferably 30% by mass or more and 90% by mass or less, and the lower limit is more preferably 40% by mass or more, and still more preferably 50% by mass or more, relative to the entire acidic emulsified liquid seasoning. is more preferably 60% by mass or more, and the upper limit is more preferably 85% by mass or less, still more preferably 80% by mass or less. If the content of fats and oils in the acidic emulsified liquid seasoning is within the above range, the seasoning retains the smoky aroma and maintains the emulsified state even after long-term storage, while fully feeling the richness derived from the oil. can be maintained.

(食酢)
酸性乳化液状調味料に用いる食酢は、水及び酢酸を主成分とするものである。本発明における食酢としては、消費者庁が定める「食品表示基準」に列挙される食酢が挙げられるが、これに類似する酸味調味料も含まれる。より詳細には、食酢としては、たとえば、米、麦芽、酒粕等の穀類もしくはそれらの加工品、ぶどう、りんご等の果実、タマネギ、ニンジン、トマト等の野菜、その他農産物、アルコール等を酢酸発酵させたものや、別途酢酸を添加したもの、又はこれらを混合したものが挙げられる。糖類、有機酸、アミノ酸、食塩等を加えたものもこれに含まれる。このような食酢としては、例えば、米酢、黒酢、五穀酢、ワインビネガー、りんご酢、トマト酢、もろみ酢、及び梅酢等が挙げられる。これらの食酢は、1種単独で用いてもよいし、2種以上を併用してもよい。
(vinegar)
The vinegar used for the acidic emulsified liquid seasoning contains water and acetic acid as main ingredients. Vinegars in the present invention include vinegars listed in the "Food Labeling Standards" established by the Consumer Affairs Agency, but also include sour seasonings similar thereto. More specifically, vinegar is produced by acetic acid fermentation of grains such as rice, malt and sake lees or their processed products, fruits such as grapes and apples, vegetables such as onions, carrots and tomatoes, other agricultural products, and alcohol. , acetic acid added separately, or a mixture thereof. Those to which saccharides, organic acids, amino acids, salt, etc. are added are also included. Examples of such vinegar include rice vinegar, black vinegar, five grain vinegar, wine vinegar, apple vinegar, tomato vinegar, moromi vinegar, and plum vinegar. These vinegars may be used individually by 1 type, and may use 2 or more types together.

(燻製酢)
本発明においては、食酢の少なくとも一部に燻製酢を用いる。酸性乳化液状調味料に燻製酢を配合することで、燻製風味を付与することができる。燻製酢としては、例えば、上記の食酢を従来公知の方法により燻煙処理したものが挙げられる。燻煙処理としては、例えば、一般的な燻煙装置を用いて行うことができる。燻煙処理に用いる燻煙材は特に限定されず、例えば、サクラ、ブナ、ナラ、リンゴ、ヒッコリー、クルミ、カシ等のスモークチップやスモークウッドが挙げられる。
(smoked vinegar)
In the present invention, smoked vinegar is used as at least part of vinegar. A smoked flavor can be imparted to the acidic emulsified liquid seasoning by blending smoked vinegar. Examples of smoked vinegar include those obtained by smoking the above vinegar by a conventionally known method. The smoking treatment can be performed using, for example, a general smoking device. The smoking material used for smoking treatment is not particularly limited, and examples thereof include smoked chips of cherry, beech, oak, apple, hickory, walnut, and oak, and smoked wood.

酸性乳化液状調味料中の燻製酢の含有量は、酸性乳化液状調味料の全量に対して、好ましくは1.0質量%以上20.0質量%以下であり、下限値はより好ましくは3.0質量%以上であり、さらに好ましくは5.0質量%以上であり、また、上限値はより好ましくは18.0質量%以下であり、さらに好ましくは15.0質量%以下であり、さらにより好ましくは12.0質量%以下である。燻製酢の含有量が上記範囲内であれば、長期間の保存後であっても、燻製香を保持し、かつ乳化状態を維持することができる。また、酸性乳化液状調味料中の燻製酢以外の食酢の含有量は、酸性乳化液状調味料全体のpHや燻製酢の含有量に応じて、適宜、調節することができる。 The content of smoked vinegar in the acidic emulsified liquid seasoning is preferably 1.0% by mass or more and 20.0% by mass or less with respect to the total amount of the acidic emulsified liquid seasoning, and the lower limit is more preferably 3.0% by mass. It is 0% by mass or more, more preferably 5.0% by mass or more, and the upper limit is more preferably 18.0% by mass or less, further preferably 15.0% by mass or less, and still more Preferably, it is 12.0% by mass or less. If the content of the smoked vinegar is within the above range, the smoked flavor can be retained and the emulsified state can be maintained even after long-term storage. In addition, the content of vinegar other than smoked vinegar in the acidic emulsified liquid seasoning can be appropriately adjusted according to the pH of the whole acidic emulsified liquid seasoning and the content of smoked vinegar.

(卵黄)
酸性乳化液状調味料には、卵黄として酵素未処理卵黄及び酵素処理卵黄を用いる。酵素未処理卵黄としては、例えば、液卵黄や生卵黄、当該液卵黄や生卵黄に殺菌処理、冷凍処理、脱糖処理、スプレードライ又はフリーズドライ等の乾燥処理、超臨界二酸化炭素処理等の脱コレステロール処理、食塩又は糖質等の混合処理等の1種又は2種以上の処理を施したもの等が挙げられる。
(egg yolk)
For the acidic emulsified liquid seasoning, enzyme-untreated egg yolk and enzyme-treated egg yolk are used as the egg yolk. Enzyme-untreated egg yolks include, for example, liquid egg yolk and raw egg yolk, sterilization treatment, freezing treatment, desugaring treatment, drying treatment such as spray drying or freeze drying, desulfurization treatment such as supercritical carbon dioxide treatment. Examples include those subjected to one or two or more treatments such as cholesterol treatment, mixed treatment with salt, sugar, or the like.

酵素処理卵黄とは、上記の酵素未処理卵黄に酵素処理を施すことによりリン脂質を加水分解した卵黄である。酵素処理卵黄は、ホスホリパーゼA1またはホスホリパーゼA2の酵素処理を施したホスホリパーゼA処理卵黄であることが好ましい。酵素処理卵黄のリゾ化率は、特に限定されないが、好ましくは10%以上80%以下であり、下限値は好ましくは15%以上であり、より好ましくは20%以上であり、また、上限値は好ましくは70%以下であり、より好ましくは60%以下である。卵黄全体のリゾ化率が上記数値範囲内であれば、酸性乳化液状調味料中の保存後でも安定した乳化状態を維持することができる。なお、酵素処理卵黄のリゾ化率とは、リン脂質のリゾリン脂質への変換率のことであり、すなわち、全リン脂質に対するリゾリン脂質の質量百分率のことである。酵素処理卵黄のリゾ化率は、TLC-FID法(イアトロスキャン)で測定することができる。酵素処理卵黄のリゾ化率は、酵素処理の条件を変更することで調節したり、酵素処理卵黄と酵素未処理卵黄とを混合することで調節したりすることができる。 The enzyme-treated egg yolk is an egg yolk obtained by subjecting the enzyme-untreated egg yolk to an enzyme treatment to hydrolyze the phospholipids. The enzyme-treated egg yolk is preferably a phospholipase A-treated egg yolk enzymatically treated with phospholipase A1 or phospholipase A2. The lyso-synthesis rate of the enzyme-treated egg yolk is not particularly limited, but is preferably 10% or more and 80% or less, the lower limit is preferably 15% or more, more preferably 20% or more, and the upper limit is It is preferably 70% or less, more preferably 60% or less. If the lyso conversion rate of the entire egg yolk is within the above numerical range, a stable emulsified state can be maintained even after storage in the acidic emulsified liquid seasoning. The lyso-formation rate of the enzyme-treated egg yolk is the conversion rate of phospholipids to lysophospholipids, that is, the mass percentage of lysophospholipids relative to the total phospholipids. The lysolysis rate of the enzyme-treated egg yolk can be measured by the TLC-FID method (Iatroscan). The lysolysis rate of the enzyme-treated egg yolk can be adjusted by changing the enzyme treatment conditions or by mixing the enzyme-treated egg yolk and the enzyme-untreated egg yolk.

酸性乳化液状調味料中の酵素処理卵黄の含有量は、生換算で、酵素未処理卵黄の生換算での1質量部に対して0.08質量部以上20質量部以下であり、下限値は好ましくは0.10質量部以上であり、より好ましくは0.15質量部以上であり、さらにより好ましくは0.20質量部以上であり、また、上限値は好ましくは10質量部以下であり、より好ましくは4.0質量部以下であり、さらに好ましくは2.0質量部以下であり、さらにより好ましくは1.5質量部以下であり、最も好ましくは1.0質量部以下である。また、酸性乳化液状調味料中の酵素処理卵黄の含有量は、生換算で、酸性乳化液状調味料の全量に対して、下限値は好ましくは0.1質量%以上であり、より好ましくは0.5質量%以上であり、さらに好ましくは1.0質量%以上であり、さらにより好ましくは1.5質量%以上であり、また、上限値は好ましくは30質量%以下であり、より好ましくは20質量%以下であり、さらに好ましくは10質量%以下であり、さらにより好ましくは8.0質量%以下であり、最も好ましくは4.0質量%以下である。酸性乳化液状調味料中の酵素処理卵黄の含有量を上記範囲内に調節することで、長期間の保存後であっても、燻製香を保持し、かつ乳化状態を維持することができる。 The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.08 parts by mass or more and 20 parts by mass or less, in raw terms, relative to 1 part by mass of enzyme-untreated egg yolks in raw terms, and the lower limit is It is preferably 0.10 parts by mass or more, more preferably 0.15 parts by mass or more, still more preferably 0.20 parts by mass or more, and the upper limit is preferably 10 parts by mass or less, It is more preferably 4.0 parts by mass or less, still more preferably 2.0 parts by mass or less, even more preferably 1.5 parts by mass or less, and most preferably 1.0 parts by mass or less. In addition, the lower limit of the content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is preferably 0.1% by mass or more, more preferably 0, based on the total amount of the acidic emulsified liquid seasoning in raw conversion. .5% by mass or more, more preferably 1.0% by mass or more, still more preferably 1.5% by mass or more, and the upper limit is preferably 30% by mass or less, more preferably It is 20% by mass or less, more preferably 10% by mass or less, even more preferably 8.0% by mass or less, and most preferably 4.0% by mass or less. By adjusting the content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning within the above range, it is possible to retain the smoky flavor and maintain the emulsified state even after long-term storage.

酸性乳化液状調味料中の酵素未処理卵黄の含有量は、生換算で、酸性乳化液状調味料の全量に対して、下限値は好ましくは0.1質量%以上であり、より好ましくは1.0質量%以上であり、さらに好ましくは3.0質量%以上であり、さらにより好ましくは5.0質量%以上であり、また、上限値は好ましくは30質量%以下であり、より好ましくは25質量%以下であり、さらに好ましくは20質量%以下である。酸性乳化液状調味料中の酵素未処理卵黄の含有量が上記範囲内であれば、酸性乳化液状調味料は保存後でも安定した乳化状態を維持することができる。 The lower limit of the content of the enzyme-untreated egg yolk in the acidic emulsified liquid seasoning is preferably 0.1% by mass or more, and more preferably 1.0% by mass, based on the total amount of the acidic emulsified liquid seasoning. It is 0% by mass or more, more preferably 3.0% by mass or more, and even more preferably 5.0% by mass or more, and the upper limit is preferably 30% by mass or less, more preferably 25% by mass. % by mass or less, more preferably 20% by mass or less. If the content of the enzyme-untreated egg yolk in the acidic emulsified liquid seasoning is within the above range, the acidic emulsified liquid seasoning can maintain a stable emulsified state even after storage.

酸性乳化液状調味料中の酵素処理卵黄と酵素未処理卵黄の合計含有量は、生換算で、酸性乳化液状調味料の全量に対して、下限値は好ましくは0.2質量%以上であり、より好ましくは1.5質量%以上であり、さらに好ましくは4.0質量%以上であり、さらにより好ましくは5.5質量%以上であり、最も好ましくは7.0質量%以上であり、また、上限値は好ましくは40質量%以下であり、より好ましくは30質量%以下であり、さらに好ましくは15質量%以下である。酸性乳化液状調味料中の酵素処理卵黄と酵素未処理卵黄の合計含有量が上記範囲内であれば、酸性乳化液状調味料は保存後でも安定した乳化状態を維持することができる。 The lower limit of the total content of the enzyme-treated egg yolk and the enzyme-untreated egg yolk in the acidic emulsified liquid seasoning is preferably 0.2% by mass or more, based on the total amount of the acidic emulsified liquid seasoning, in raw conversion. More preferably 1.5% by mass or more, still more preferably 4.0% by mass or more, even more preferably 5.5% by mass or more, most preferably 7.0% by mass or more, and , the upper limit is preferably 40% by mass or less, more preferably 30% by mass or less, and even more preferably 15% by mass or less. If the total content of enzyme-treated egg yolk and enzyme-untreated egg yolk in the acidic emulsified liquid seasoning is within the above range, the acidic emulsified liquid seasoning can maintain a stable emulsified state even after storage.

(他の原料)
酸性乳化液状調味料は、上述した原料以外に、本発明の効果を損なわない範囲で酸性乳化液状調味料に通常用いられている各種原料を適宜選択し含有させることができる。例えば、醤油、みりん、食塩、胡麻、グルタミン酸ナトリウム、ブイヨン等の調味料、ぶどう糖、果糖、蔗糖、麦芽糖、オリゴ糖、トレハロース等の糖類、からし粉、胡椒等の香辛料、レシチン、リゾレシチン、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル等の乳化剤、キサンタンガム、カラギーナン、コンニャクガム、グアーガム、タマリンドシードガム、ローカストビーンガム、アラビアガム、及びジェランガム等の増粘剤、アセチル化アジピン酸架橋澱粉、アセチル化リン酸架橋澱粉、アセチル化酸化澱粉、及びオクテニルコハク酸澱粉ナトリウム等の加工澱粉、アスコルビン酸、ビタミンE等の酸化防止剤、静菌剤等が挙げられる。
(other ingredients)
In addition to the raw materials described above, the acidic emulsified liquid seasoning can contain various raw materials commonly used in acidic emulsified liquid seasonings, as appropriate, as long as the effects of the present invention are not impaired. For example, seasonings such as soy sauce, mirin, salt, sesame, monosodium glutamate, and bouillon; sugars such as glucose, fructose, sucrose, maltose, oligosaccharides and trehalose; spices such as mustard powder and pepper; lecithin, lysolecithin, glycerin fatty acid emulsifiers such as esters, polyglycerol fatty acid esters, and sucrose fatty acid esters; thickeners such as xanthan gum, carrageenan, konjac gum, guar gum, tamarind seed gum, locust bean gum, arabic gum, and gellan gum; acetylated adipic acid cross-linked starch; Processed starches such as acetylated phosphate cross-linked starch, acetylated oxidized starch, and sodium starch octenylsuccinate, antioxidants such as ascorbic acid and vitamin E, and bacteriostatic agents.

(容器)
酸性乳化液状調味料を充填する容器は、材質や形状等は特に制限されず、従来公知の酸性乳化液状調味料用容器を用いることができる。容器としては、例えば、プラスチック製やガラス製の硬質容器、ポリエチレン製、ポリプロピレン製、及びビニル製等の軟質容器等が挙げられる。また、これらの容器の形状としては、例えば、円筒状、ボトル状等が挙げられる。
(container)
The container filled with the acidic emulsified liquid seasoning is not particularly limited in material, shape, etc., and conventionally known containers for acidic emulsified liquid seasoning can be used. Examples of containers include hard containers made of plastic or glass, and soft containers made of polyethylene, polypropylene, vinyl, and the like. Further, examples of the shape of these containers include a cylindrical shape and a bottle shape.

<容器詰め燻製風味酸性乳化液状調味料の製造方法>
本発明の容器詰め燻製風味酸性乳化液状調味料の製造方法は、少なくとも、食用油脂、食酢、及び卵黄を含有する酸性乳化液状調味料において、食酢の少なくとも一部として燻製酢を用い、卵黄として酵素未処理卵黄及び酵素処理卵黄を用い、酸性乳化液状調味料中の酵素未処理卵黄及び酵素処理卵黄の含有量を調節するものである。酸性乳化液状調味料中の酵素未処理卵黄及び酵素処理卵黄の含有量については上述の通りである。
<Method for producing container-packed smoked flavor acidic emulsified liquid seasoning>
The method for producing a container-packed smoked-flavored acidic emulsified liquid seasoning of the present invention is an acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk, wherein smoked vinegar is used as at least a portion of the vinegar, and an enzyme is used as the egg yolk. Using untreated egg yolk and enzyme-treated egg yolk, the content of enzyme-untreated egg yolk and enzyme-treated egg yolk in the acidic emulsified liquid seasoning is adjusted. The contents of enzyme-untreated egg yolk and enzyme-treated egg yolk in the acidic emulsified liquid seasoning are as described above.

本発明の容器詰め燻製風味酸性乳化液状調味料の製造方法の一例について説明する。例えば、まず、燻製酢、必要に応じて食酢(燻製香無し)、及び調味料等の他の水相原料を混合して、水相を調製する。その後、調整した水相に酵素未処理卵黄及び酵素処理卵黄を加える。続いて、この水相をミキサー等で撹拌しながら、油相原料である食用油脂を注加して粗乳化し、次にせん断力に優れた処理機等で均質化して、水相中に油相を乳化分散させた酸性乳化液状調味料を得ることができる。 An example of the method for producing the container-packed smoked-flavored acidic emulsified liquid seasoning of the present invention will be described. For example, first, the water phase is prepared by mixing smoked vinegar, optionally vinegar (without smoked flavor), and other water phase ingredients such as seasonings. Then, enzyme-untreated egg yolk and enzyme-treated egg yolk are added to the adjusted aqueous phase. Subsequently, while stirring this aqueous phase with a mixer or the like, edible oils and fats, which are the raw materials of the oil phase, are added to coarsely emulsify. An acidic emulsified liquid seasoning in which the phase is emulsified and dispersed can be obtained.

また、本発明の容器詰め燻製風味酸性乳化液状調味料の製造方法の別の例について説明する。例えば、まず、食酢(燻製香無し)及び調味料等の他の水相原料を混合して、水相を調製する。その後、調整した水相に酵素未処理卵黄及び酵素処理卵黄を加える。続いて、この水相をミキサー等で撹拌しながら、油相原料である食用油脂を注加して粗乳化し、次にせん断力に優れた処理機等で均質化して、水相中に油相を乳化分散させた乳化物を得ることができる。その後、別途調製した燻製酢及び/又は燻製酢含有調味料を、乳化物に添加することで、酸性乳化液状調味料を得ることができる。 Further, another example of the method for producing the container-packed smoked-flavored acidic emulsified liquid seasoning of the present invention will be described. For example, first, a water phase is prepared by mixing vinegar (without smoked flavor) and other water phase ingredients such as seasonings. Then, enzyme-untreated egg yolk and enzyme-treated egg yolk are added to the adjusted aqueous phase. Subsequently, while stirring this aqueous phase with a mixer or the like, edible oils and fats, which are the raw materials of the oil phase, are added to coarsely emulsify. An emulsion in which the phase is emulsified and dispersed can be obtained. Thereafter, separately prepared smoked vinegar and/or smoked vinegar-containing seasoning are added to the emulsion to obtain an acidic emulsified liquid seasoning.

続いて、得られた酸性乳化液状調味料を容器に充填することで、容器詰め燻製風味酸性乳化液状調味料を製造することができる。酸性乳化液状調味料の容器への充填方法は特に限定されず、従来公知の方法により行うことができる。 Subsequently, by filling a container with the obtained acidic emulsified liquid seasoning, a packaged smoked-flavored acidic emulsified liquid seasoning can be produced. The method for filling the container with the acidic emulsified liquid seasoning is not particularly limited, and a conventionally known method can be used.

(製造装置)
本発明の酸性乳化液状調味料の製造には、通常の酸性乳化液状調味料の製造に使われる装置を用いることができる。このような装置としては、例えば、一般的な撹拌機、スティックミキサー、スタンドミキサー、ホモミキサー、ホモディスパー等が挙げられる。撹拌機の撹拌羽形状としては、例えばプロペラ翼、タービン翼、パドル翼、アンカー翼等が挙げられる。
(manufacturing device)
For the production of the acidic emulsified liquid seasoning of the present invention, an apparatus used for producing ordinary acidic emulsified liquid seasonings can be used. Examples of such devices include general stirrers, stick mixers, stand mixers, homomixers, homodispers, and the like. Examples of the shape of the stirring blades of the stirrer include propeller blades, turbine blades, paddle blades, and anchor blades.

(燻製香の保持方法)
本発明の燻製香の保持方法は、少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料において、食酢の少なくとも一部として燻製酢を用い、卵黄として酵素未処理卵黄及び酵素処理卵黄を用い、酸性乳化液状調味料中の酵素未処理卵黄及び酵素処理卵黄の含有量を調節することで、酸性乳化液状調味料を長期保存後であっても、燻製香を保持することができる。
(How to retain smoked incense)
The method for retaining a smoked aroma of the present invention is a packaged smoked-flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk, wherein smoked vinegar is used as at least a portion of the vinegar, and enzyme-untreated egg yolk is used as the egg yolk. and the enzyme-treated egg yolk, and by adjusting the contents of the enzyme-untreated egg yolk and the enzyme-treated egg yolk in the acidic emulsified liquid seasoning, the acidic emulsified liquid seasoning retains its smoky aroma even after long-term storage. be able to.

酸性乳化液状調味料中の酵素処理卵黄の含有量は、生換算で、酵素未処理卵黄の生換算での1質量部に対して0.08質量部以上20質量部以下であり、下限値は好ましくは0.10質量部以上であり、より好ましくは0.15質量部以上であり、さらにより好ましくは0.20質量部以上であり、また、上限値は好ましくは10質量部以下であり、より好ましくは4.0質量部以下であり、さらに好ましくは2.0質量部以下であり、さらにより好ましくは1.5質量部以下であり、最も好ましくは1.0質量部以下である。酸性乳化液状調味料中の酵素処理卵黄の含有量を上記範囲内に調節することで、長期間の保存後であっても、燻製香を保持し、かつ乳化状態を維持することができる。 The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.08 parts by mass or more and 20 parts by mass or less, in raw terms, relative to 1 part by mass of enzyme-untreated egg yolks in raw terms, and the lower limit is It is preferably 0.10 parts by mass or more, more preferably 0.15 parts by mass or more, still more preferably 0.20 parts by mass or more, and the upper limit is preferably 10 parts by mass or less, It is more preferably 4.0 parts by mass or less, still more preferably 2.0 parts by mass or less, even more preferably 1.5 parts by mass or less, and most preferably 1.0 parts by mass or less. By adjusting the content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning within the above range, it is possible to retain the smoky flavor and maintain the emulsified state even after long-term storage.

以下に、実施例と比較例を挙げて本発明をさらに詳細に説明するが、本発明は以下の実施例の内容に限定して解釈されるものではない。 EXAMPLES The present invention will be described in more detail below with reference to examples and comparative examples, but the present invention should not be construed as being limited to the contents of the following examples.

<酸性乳化液状調味料の製造例1>
[実施例1]
表1に記載の配合割合に準じて、酸性乳化液状調味料を製造した。具体的には、まず、食酢(燻製香無し、酸度5%)、燻製酢、食塩、グルタミン酸ナトリウム、香辛料、及び清水を均一になるように混合して、水相を調整した。その後、調整した水相に、酵素未処理卵黄及びホスホリパーゼA処理卵黄(リゾ化率20~80%のもの)を加えた後、食用植物油脂を注加し、乳化処理を行って、酸性乳化液状調味料を調製した。
<Production Example 1 of Acidic Emulsified Liquid Seasoning>
[Example 1]
An acidic emulsified liquid seasoning was produced according to the blending ratio shown in Table 1. Specifically, first, vinegar (without smoked aroma, acidity 5%), smoked vinegar, salt, sodium glutamate, spices, and fresh water were uniformly mixed to prepare an aqueous phase. After that, enzyme-untreated egg yolk and phospholipase A-treated egg yolk (with a lysation rate of 20 to 80%) are added to the adjusted aqueous phase, and then edible vegetable oil is added and emulsified to form an acidic emulsified liquid. A seasoning was prepared.

[実施例2及び3、比較例1及び2]
表1に記載の配合割合に準じて、酵素未処理卵黄及びホスホリパーゼA処理卵黄の添加量を変更した以外は、実施例1と同様にして酸性乳化液状調味料を調製した。
[Examples 2 and 3, Comparative Examples 1 and 2]
An acidic emulsified liquid seasoning was prepared in the same manner as in Example 1, except that the added amounts of enzyme-untreated egg yolk and phospholipase A-treated egg yolk were changed according to the blending ratios shown in Table 1.

<pHの測定>
上記で得られた酸性乳化液状調味料について、1気圧、品温20℃とした時に、pH測定器(株式会社堀場製作所製卓上型pHメータF-72)を用いて、pHを測定した。酸性乳化液状調味料のpHは、いずれも3.5以上4.6以下であった。
<Measurement of pH>
The pH of the acidic emulsified liquid seasoning obtained above was measured using a pH measuring device (desktop pH meter F-72 manufactured by Horiba, Ltd.) at 1 atm and 20° C. product temperature. All of the acidic emulsified liquid seasonings had a pH of 3.5 or more and 4.6 or less.

<粘度測定>
上記で得られた酸性乳化液状調味料について、BH形粘度計を使用し、品温25℃、回転数2rpmの条件で、ローターNo. 6を使用し、測定開始後ローターが2回転した時の示度により、粘度を算出した。測定結果を表1に示した。
<Viscosity measurement>
For the acidic emulsified liquid seasoning obtained above, a BH viscometer was used at a product temperature of 25 ° C. and a rotation speed of 2 rpm, using a rotor No. 6. After the start of measurement, the rotor rotated twice. Viscosity was calculated from the reading. Table 1 shows the measurement results.

<官能評価>
上記で得られた酸性乳化液状調味料について、複数の訓練されたパネルにより、下記の基準で、「製造直後の酸性乳化液状調味料の燻製香」及び「保存後期の酸性乳化液状調味料の燻製香」を官能評価した。保存後期の酸性乳化液状調味料の燻製香の評価には、容器に充填した後に暗所にて25℃で1か月保存後の酸性乳化液状調味料を用いた。また、保存後期の酸性乳化液状調味料の燻製香の評価における対照区とは、製造直後の酸性乳化液状調味料である。評価結果の平均値を表1に示した。各評価結果の平均値が2点以上であれば、合格である。
[製造直後の酸性乳化液状調味料の燻製香の評価基準]
3:燻製香を良く感じた。
2:燻製香を感じた。
1:燻製香を感じたが、弱かった。
[保存後期の酸性乳化液状調味料の燻製香の評価基準]
4:対照区と比較し、燻製香が殆ど低下していなかった。
3:対照区と比較し、燻製香がわずかに低下していた。
2:対照区と比較し、燻製香が低下していたが、問題のない範囲であった。
1:対照区と比較し、燻製香が著しく低下していた。
<Sensory evaluation>
Regarding the acidic emulsified liquid seasoning obtained above, according to the following criteria, "smoked aroma of acidic emulsified liquid seasoning immediately after production" and "smoked acidic emulsified liquid seasoning in the later stage of storage" scent” was sensory evaluated. For the evaluation of the smoked flavor of the acidic emulsified liquid seasoning in the later stage of storage, the acidic emulsified liquid seasoning was stored in a dark place at 25° C. for one month after being filled in a container, and the acidic emulsified liquid seasoning was used. In addition, the control section in the evaluation of the smoked flavor of the acidic emulsified liquid seasoning in the later stage of storage is the acidic emulsified liquid seasoning immediately after production. Table 1 shows the average values of the evaluation results. If the average value of each evaluation result is 2 points or more, it is acceptable.
[Evaluation criteria for smoked aroma of acidic emulsified liquid seasoning immediately after production]
3: The smoked aroma was felt well.
2: Smoked aroma was felt.
1: A smoked aroma was felt, but weak.
[Evaluation Criteria for Smoked Flavor of Acidic Emulsified Liquid Seasoning in Late Storage]
4: Compared to the control plot, the smoked aroma was hardly reduced.
3: Compared with the control plot, the smoked aroma was slightly reduced.
2: Compared to the control plot, the smoked aroma was reduced, but within a range without problems.
1: Compared to the control section, the smoked aroma was remarkably reduced.

<乳化状態の評価>
上記で得られた酸性乳化液状調味料について、下記の基準で、「保存後期の酸性乳化液状調味料の乳化状態」について評価した。評価には、容器に充填した後に暗所にて25℃で1か月保存後の酸性乳化液状調味料を用いた。評価結果を表1に示した。
[保存後期の酸性乳化液状調味料の乳化状態の評価基準]
〇:酸性乳化液状調味料は、上記期間の保存後であっても、分離が生じていなかった。
×:酸性乳化液状調味料は、上記期間の保存後には、分離が生じていた。
<Evaluation of emulsified state>
The acidic emulsified liquid seasoning obtained above was evaluated for "the emulsified state of the acidic emulsified liquid seasoning in the later stage of storage" according to the following criteria. For the evaluation, the acidic emulsified liquid seasoning was used after being stored in a dark place at 25° C. for one month after being filled in a container. The evaluation results are shown in Table 1.
[Evaluation Criteria for Emulsified State of Acidic Emulsified Liquid Seasoning in Late Storage]
◯: No separation occurred in the acidic emulsified liquid seasoning even after storage for the above period.
x: Separation occurred in the acidic emulsified liquid seasoning after storage for the above period.

Figure 2022116388000001
Figure 2022116388000001

表1に示す通り、実施例1~3の酸性乳化液状調味料はいずれも、長期間の保存後であっても、燻製香を保持し、かつ乳化状態を維持することができた。
一方、比較例1の酸性乳化液状調味料は、保存後に分離が生じてしまった。また、比較例2の酸性乳化液状調味料は、製造直後の燻製香が弱く、さらに保存後期の燻製香が著しく低下していた。
なお、実施例1~3の酸性乳化液状調味料における製造直後のL値は全て、70以上98以下であった。
As shown in Table 1, all of the acidic emulsified liquid seasonings of Examples 1 to 3 were able to retain the smoky flavor and maintain the emulsified state even after long-term storage.
On the other hand, the acidic emulsified liquid seasoning of Comparative Example 1 caused separation after storage. In addition, the acidic emulsified liquid seasoning of Comparative Example 2 had a weak smoky flavor immediately after production, and the smoky flavor was remarkably reduced in the latter stage of storage.
All the acidic emulsified liquid seasonings of Examples 1 to 3 had an L value of 70 or more and 98 or less immediately after production.

<酸性乳化液状調味料の製造例2>
実施例1~3の酸性乳化液状調味料の製造の際に、乳化処理の条件を変更して、酸性乳化液状調味料中の油滴のメジアン径が表2に記載の通りになるように調節した。
<Production Example 2 of Acidic Emulsified Liquid Seasoning>
When producing the acidic emulsified liquid seasonings of Examples 1 to 3, the emulsification conditions were changed so that the median diameter of the oil droplets in the acidic emulsified liquid seasonings was adjusted as shown in Table 2. did.

<油滴のメジアン径の測定>
上記で得られた酸性乳化液状調味料中の油滴のメジアン径(頻度の累積が50%になる粒子径)を、下記の測定条件でレーザー回折式粒度分布測定装置を用いて測定した。測定結果を表2に示した。
(測定条件)
・測定機器:日機装株式会社製、粒度分布計MT3300EXII
・測定基準:体積
・分析条件:非球形、屈折率1.6
・粒子径測定範囲:0.021μm以上2000μm以下
・粒子径区分:132ch
<Measurement of median diameter of oil droplets>
The median diameter of the oil droplets in the acidic emulsified liquid seasoning obtained above (the particle diameter at which the cumulative frequency is 50%) was measured using a laser diffraction particle size distribution analyzer under the following measurement conditions. Table 2 shows the measurement results.
(Measurement condition)
・Measurement equipment: Particle size distribution meter MT3300EXII manufactured by Nikkiso Co., Ltd.
・Measurement standard: volume ・Analysis conditions: non-spherical shape, refractive index 1.6
・Particle size measurement range: 0.021 μm or more and 2000 μm or less ・Particle size division: 132ch

<保存前後のL値変化量の測定>
上記で得られた酸性乳化液状調味料の製造直後のL値および上記で得られた酸性乳化液状調味料を容器に充填した後に暗所にて25℃で1か月保存後のL値を、下記の測定条件で分光測色計を用いて測定した。得られた測定結果から、下記式により保存前後のL値変化量を算出し、表2に示した。保存前後のL値変化量が小さい方が、酸性乳化液状調味料の褐変が抑制されていることを示す。
(測定条件)
・測定機器:コニカミノルタ社製、型番:CM5
・正反射光処理:SCE
・測定径:30mm
・測定方法:反射率測定
・基準光源:D65
・視野:2°
(保存前後のL値変化量)
L値変化量=(L1-L2)/L1
L1:酸性乳化液状調味料の製造直後のL値
L2:酸性乳化液状調味料の暗所にて25℃で1か月保存後のL値
<Measurement of L value change before and after storage>
The L value immediately after production of the acidic emulsified liquid seasoning obtained above and the L value after storing the acidic emulsified liquid seasoning obtained above in a container for one month at 25°C in a dark place, It was measured using a spectrophotometer under the following measurement conditions. From the obtained measurement results, the amount of change in L value before and after storage was calculated by the following formula, and shown in Table 2. A smaller change in L value before and after storage indicates that browning of the acidic emulsified liquid seasoning is suppressed.
(Measurement condition)
・Measuring equipment: manufactured by Konica Minolta, model number: CM5
・Regular reflection light processing: SCE
・Measurement diameter: 30mm
・Measurement method: reflectance measurement ・Reference light source: D65
・Field of view: 2°
(L value change amount before and after storage)
L value change = (L1-L2)/L1
L1: L value immediately after production of the acidic emulsified liquid seasoning L2: L value of the acidic emulsified liquid seasoning after storage at 25°C for 1 month in the dark

Figure 2022116388000002
Figure 2022116388000002

表2に示す通り、実施例1~3の酸性乳化液状調味料はいずれも、油滴のメジアン径が小さいほどL値変化量が低く、酸性乳化液状調味料の保存後の褐変が抑制された。 As shown in Table 2, in all of the acidic emulsified liquid seasonings of Examples 1 to 3, the smaller the median diameter of the oil droplets, the lower the amount of change in the L value, and the browning of the acidic emulsified liquid seasoning after storage was suppressed. .

<酸性乳化液状調味料の製造例3>
[実施例4~8、比較例3]
表3に記載の配合割合に準じて、酸性乳化液状調味料を製造した。具体的には、まず、食酢(燻製香無し、酸度5%)、燻製酢、食塩、グルタミン酸ナトリウム、香辛料、及び清水、さらに必要に応じてキサンタンガム及び加工澱粉を均一になるように混合して、水相を調整した。その後、調整した水相に、酵素未処理卵黄及びホスホリパーゼA処理卵黄(リゾ化率20~80%のもの)を加えた後、食用植物油脂を注加し、乳化処理を行って、酸性乳化液状調味料を調製した。
<Production Example 3 of Acidic Emulsified Liquid Seasoning>
[Examples 4 to 8, Comparative Example 3]
An acidic emulsified liquid seasoning was produced according to the blending ratio shown in Table 3. Specifically, first, vinegar (without smoked aroma, acidity 5%), smoked vinegar, salt, sodium glutamate, spices, and fresh water, and if necessary, xanthan gum and processed starch are uniformly mixed, Aqueous phase was adjusted. After that, enzyme-untreated egg yolk and phospholipase A-treated egg yolk (with a lysation rate of 20 to 80%) are added to the adjusted aqueous phase, and then edible vegetable oil is added and emulsified to form an acidic emulsified liquid. A seasoning was prepared.

<pHの測定>
上記で得られた酸性乳化液状調味料について、上記の<酸性乳化液状調味料の製造例1>と同様にして、pHを測定した。酸性乳化液状調味料のpHは、いずれも3.5以上4.6以下であった。
<Measurement of pH>
The pH of the acidic emulsified liquid seasoning obtained above was measured in the same manner as in <Production Example 1 of acidic emulsified liquid seasoning>. All of the acidic emulsified liquid seasonings had a pH of 3.5 or more and 4.6 or less.

<粘度測定>
上記で得られた酸性乳化液状調味料について、上記の<酸性乳化液状調味料の製造例1>と同様にして、粘度を測定した。測定結果を表3に示した。
<Viscosity measurement>
The viscosity of the acidic emulsified liquid seasoning obtained above was measured in the same manner as in <Production Example 1 of acidic emulsified liquid seasoning>. Table 3 shows the measurement results.

<官能評価>
上記で得られた酸性乳化液状調味料について、上記の<酸性乳化液状調味料の製造例1>と同様にして、「製造直後の酸性乳化液状調味料の燻製香」及び「保存後期の酸性乳化液状調味料の燻製香」を官能評価した。評価結果を表3に示した。
<Sensory evaluation>
Regarding the acidic emulsified liquid seasoning obtained above, in the same manner as in <Production Example 1 of acidic emulsified liquid seasoning>, "smoked aroma of acidic emulsified liquid seasoning immediately after production" and "acidic emulsified seasoning after storage" A sensory evaluation was conducted on the "smoked flavor of the liquid seasoning". Table 3 shows the evaluation results.

<乳化状態の評価>
上記で得られた酸性乳化液状調味料について、上記の<酸性乳化液状調味料の製造例1>と同様にして、「保存後期の酸性乳化液状調味料の乳化状態」について評価した。評価結果を表3に示した。
<Evaluation of emulsified state>
The acidic emulsified liquid seasoning obtained above was evaluated for "the emulsified state of the acidic emulsified liquid seasoning in the later stage of storage" in the same manner as in <Production Example 1 of Acidic Emulsified Liquid Seasoning>. Table 3 shows the evaluation results.

Figure 2022116388000003
Figure 2022116388000003

表3に示す通り、実施例4~8の酸性乳化液状調味料はいずれも、長期間の保存後であっても、燻製香を保持し、かつ乳化状態を維持することができた。
一方、比較例3の酸性乳化液状調味料は、保存後に分離が生じてしまった。
なお、得られた実施例4~8の酸性乳化液状調味料における製造直後のL値は全て、70以上98以下であった。
As shown in Table 3, all of the acidic emulsified liquid seasonings of Examples 4 to 8 were able to retain the smoky flavor and maintain the emulsified state even after long-term storage.
On the other hand, the acidic emulsified liquid seasoning of Comparative Example 3 caused separation after storage.
All of the acidic emulsified liquid seasonings obtained in Examples 4 to 8 had an L value of 70 or more and 98 or less immediately after production.

Claims (11)

少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料であって、
前記食酢の少なくとも一部が燻製酢であり、
前記卵黄として酵素未処理卵黄及び酵素処理卵黄を含有し、
前記酸性乳化液状調味料中の酵素処理卵黄の含有量が、生換算で、前記酵素未処理卵黄の生換算での1質量部に対して0.08質量部以上20質量部以下であることを特徴とする、
酸性乳化液状調味料。
A container-packed smoked flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk,
At least part of the vinegar is smoked vinegar,
Containing an enzyme-untreated egg yolk and an enzyme-treated egg yolk as the egg yolk,
The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.08 parts by mass or more and 20 parts by mass or less in terms of raw equivalent per 1 part by mass of the enzyme-untreated egg yolk in raw equivalent. characterized by
Acidic emulsified liquid seasoning.
前記酸性乳化液状調味料中の酵素処理卵黄の含有量が、生換算で、前記酸性乳化液状調味料全量に対して0.1質量%以上30質量%以下であることを特徴とする、
請求項1に記載の酸性乳化液状調味料。
The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.1% by mass or more and 30% by mass or less with respect to the total amount of the acidic emulsified liquid seasoning in raw conversion,
The acidic emulsified liquid seasoning according to claim 1.
前記酵素処理卵黄が、ホスホリパーゼA処理卵黄であることを特徴とする、
請求項1または2に記載の酸性乳化液状調味料。
The enzyme-treated egg yolk is a phospholipase A-treated egg yolk,
The acidic emulsified liquid seasoning according to claim 1 or 2.
前記調味料がマヨネーズ様調味料であることを特徴とする、
請求項1~3のいずれか一項に記載の酸性乳化液状調味料。
characterized in that the seasoning is a mayonnaise-like seasoning,
The acidic emulsified liquid seasoning according to any one of claims 1 to 3.
前記酸性乳化液状調味料は、水相中に油相が油滴状に分散しており、油滴のメジアン径が10.0μm以下であることを特徴とする、
請求項1~4のいずれか一項に記載の酸性乳化液状調味料。
The acidic emulsified liquid seasoning is characterized in that the oil phase is dispersed in the water phase in the form of oil droplets, and the median diameter of the oil droplets is 10.0 μm or less.
The acidic emulsified liquid seasoning according to any one of claims 1 to 4.
前記酵素未処理卵黄の含有量が、生換算で、前記酸性乳化液状調味料全量に対して0.1質量%以上であることを特徴とする、
請求項1~5のいずれか一項に記載の酸性乳化液状調味料。
The content of the enzyme-untreated egg yolk is 0.1% by mass or more in raw conversion with respect to the total amount of the acidic emulsified liquid seasoning,
The acidic emulsified liquid seasoning according to any one of claims 1 to 5.
前記食用油脂の含有量が、前記酸性乳化液状調味料全量に対して30質量%以上90質量%以下であることを特徴とする、
請求項1~6のいずれか一項に記載の酸性乳化液状調味料。
The content of the edible oil is 30% by mass or more and 90% by mass or less with respect to the total amount of the acidic emulsified liquid seasoning,
The acidic emulsified liquid seasoning according to any one of claims 1 to 6.
前記燻製酢の含有量が、前記酸性乳化液状調味料全量に対して1.0質量%以上20.0質量%以下であることを特徴とする、
請求項1~7のいずれか一項に記載の酸性乳化液状調味料。
The content of the smoked vinegar is 1.0% by mass or more and 20.0% by mass or less with respect to the total amount of the acidic emulsified liquid seasoning,
The acidic emulsified liquid seasoning according to any one of claims 1 to 7.
前記酸性乳化液状調味料の25℃における粘度が5Pa・s以上2000Pa・s以下であることを特徴とする、
請求項1~8のいずれか一項に記載の酸性乳化液状調味料。
The acidic emulsified liquid seasoning has a viscosity at 25° C. of 5 Pa s or more and 2000 Pa s or less,
The acidic emulsified liquid seasoning according to any one of claims 1 to 8.
少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料の製造方法であって、
食酢の少なくとも一部として燻製酢を用い、
前記卵黄として酵素未処理卵黄及び酵素処理卵黄を用い、
前記酸性乳化液状調味料中の前記酵素処理卵黄の含有量が、生換算で、前記酵素未処理卵黄の生換算での1質量部に対して0.08質量部以上20質量部以下であることを特徴とする、
酸性乳化液状調味料の製造方法。
A method for producing a container-packed smoked-flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk,
Using smoked vinegar as at least part of the vinegar,
Using an enzyme-untreated egg yolk and an enzyme-treated egg yolk as the egg yolk,
The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.08 parts by mass or more and 20 parts by mass or less, in terms of raw, per 1 part by mass of the enzyme-untreated egg yolk in terms of raw. characterized by
A method for producing an acidic emulsified liquid seasoning.
少なくとも、食用油脂、食酢、及び卵黄を含有する容器詰め燻製風味酸性乳化液状調味料の燻製香を保持する方法であって、
食酢の少なくとも一部として燻製酢を用い、
前記卵黄として酵素未処理卵黄及び酵素処理卵黄を用い、
前記酸性乳化液状調味料中の前記酵素処理卵黄の含有量が、生換算で、前記酵素未処理卵黄の生換算での1質量部に対して0.08質量部以上20質量部以下であることを特徴とする、
燻製香の保持方法。
A method for retaining a smoked aroma of a packaged smoked-flavored acidic emulsified liquid seasoning containing at least edible oil, vinegar, and egg yolk, comprising:
Using smoked vinegar as at least part of the vinegar,
Using an enzyme-untreated egg yolk and an enzyme-treated egg yolk as the egg yolk,
The content of the enzyme-treated egg yolk in the acidic emulsified liquid seasoning is 0.08 parts by mass or more and 20 parts by mass or less, in terms of raw, per 1 part by mass of the enzyme-untreated egg yolk in terms of raw. characterized by
How to retain smoked incense.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006126472A1 (en) * 2005-05-23 2006-11-30 San-Ei Gen F.F.I., Inc. Acidic oil droplet-in-water type emulsion and application thereof to foods
WO2014083663A1 (en) * 2012-11-29 2014-06-05 キユーピー 株式会社 Mayonnaise-like food
JP2017029103A (en) * 2015-08-04 2017-02-09 キユーピー株式会社 Acidic oil-in-water emulsion food product

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006126472A1 (en) * 2005-05-23 2006-11-30 San-Ei Gen F.F.I., Inc. Acidic oil droplet-in-water type emulsion and application thereof to foods
WO2014083663A1 (en) * 2012-11-29 2014-06-05 キユーピー 株式会社 Mayonnaise-like food
JP2017029103A (en) * 2015-08-04 2017-02-09 キユーピー株式会社 Acidic oil-in-water emulsion food product

Non-Patent Citations (1)

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Title
CLUB SMOKE 燻製マヨネーズの作り方, [ONLINE], 2020, [検索日:2021年7 月9日], <URL:HTTPS://WEB.ARCHIVE, JPN6021027651, ISSN: 0004813021 *

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