JP2018027658A5 - - Google Patents
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- Publication number
- JP2018027658A5 JP2018027658A5 JP2016160962A JP2016160962A JP2018027658A5 JP 2018027658 A5 JP2018027658 A5 JP 2018027658A5 JP 2016160962 A JP2016160962 A JP 2016160962A JP 2016160962 A JP2016160962 A JP 2016160962A JP 2018027658 A5 JP2018027658 A5 JP 2018027658A5
- Authority
- JP
- Japan
- Prior art keywords
- mass
- polyol
- diisocyanate
- molecular weight
- polyurethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920002635 polyurethane Polymers 0.000 claims 8
- 239000004814 polyurethane Substances 0.000 claims 8
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 7
- 229920005862 polyol Polymers 0.000 claims 7
- 150000003077 polyols Chemical class 0.000 claims 7
- 229920001228 Polyisocyanate Polymers 0.000 claims 5
- 229920002396 Polyurea Polymers 0.000 claims 5
- 239000000853 adhesive Substances 0.000 claims 5
- 230000001070 adhesive Effects 0.000 claims 5
- 239000005056 polyisocyanate Substances 0.000 claims 5
- 229920005989 resin Polymers 0.000 claims 5
- 239000011347 resin Substances 0.000 claims 5
- 230000001588 bifunctional Effects 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N Diphenylmethane p,p'-diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 3
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 claims 3
- 239000000047 product Substances 0.000 claims 3
- UQAIMZSFWBGBTN-UHFFFAOYSA-L 1,2-xylene;dicyanate Chemical compound [O-]C#N.[O-]C#N.CC1=CC=CC=C1C UQAIMZSFWBGBTN-UHFFFAOYSA-L 0.000 claims 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N Isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000005058 Isophorone diisocyanate Substances 0.000 claims 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N Toluene diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 2
- 239000004202 carbamide Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 2
- 229920000570 polyether Polymers 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N Hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 230000035699 permeability Effects 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 229920005906 polyester polyol Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Claims (1)
インキ層についての下記（１）〜（５)、および接着剤層についての下記（１１）〜（１７）の条件を全て満たす積層体。
（１）前記インキ層が、ポリウレタンポリウレア樹脂、塩化ビニル−酢酸ビニル共重合体、顔料、および有機溶剤を含有するインキ組成物の乾燥物ないし硬化物である。
（２）前記ポリウレタンポリウレア樹脂と前記塩化ビニル−酢酸ビニル共重合体との合計１００質量％中に、前記塩化ビニル−酢酸ビニル共重合体を５〜４０質量％含有する。
（３）前記ポリウレタンポリウレア樹脂は、数平均分子量４００〜５０００の高分子ポリオール由来の構造単位と、ポリイソシアネート化合物由来の構造単位を有するポリウレタンブロックと、アミノ基を有する化合物由来の鎖延長ユニットとを有し、前記ポリウレタンブロックと前記鎖延長ユニットは、ウレア結合により結合されており前記数平均分子量４００〜５０００の高分子ポリオール１００質量％中ポリエステルポリオールを５質量％以上含む。
（４）前記ポリウレタンポリウレア樹脂の質量平均分子量が１５０００〜７００００である。
（５）前記ポリウレタンポリウレア樹脂１ｇ中に含まれるウレタン結合及びウレア結合の合計濃度が１．３〜２．４ｍｍｏｌ／ｇである。
（１１）前記接着剤層が、ポリイソシアネート成分（Ａ）とポリオール成分（Ｂ）とを含有する接着剤組成物の硬化物である。
（１２）前記ポリイソシアネート成分（Ａ）が、イソシアネート基を有するウレタンプレポリマー（ａ）と４，４’−ジフェニルメタンジイソシアネートとを含む。
（１３）前記ポリイソシアネート成分（Ａ）が、２官能のイソシアネートモノマーの三量体、２官能のイソシアネートモノマーに水が付加したビュレット体、および２官能のイソシアネートモノマーにモノアルコールが付加したアダクト体からなる群より選ばれる少なくとも１種の２官能のイソシアネートモノマーの変性体をさらに含む。
（１４）前記ポリイソシアネート成分（Ａ）が、２，４’−ジフェニルメタンジイソシアネート、ヘキサメチレンジイソシアネート、トリレンジイソシアネート、イソホロンジイソシアネート、およびキシレンジイソシアネートからなる群より選ばれる少なくとも１種のイソシアネート成分をさらに含み得る。
（１５）前記イソシアネート基を有するウレタンプレポリマー（ａ）が、４，４’−ジフェニルメタンジイソシアネートと、ポリエーテルポリオールを必須とするポリオールとの反応生成物である。
（１６）前記ポリオール成分（Ｂ）１００質量％中、数平均分子量２００以上、３０００以下のポリエーテルポリウレタンポリオールを７０〜１００質量％含む。
（１７）前記接着剤組成物１００質量％中に含まれる、４，４’−ジフェニルメタンジイソシアネート、２，４’−ジフェニルメタンジイソシアネート、トリレンジイソシアネート、イソホロンジイソシアネート、およびキシレンジイソシアネートの合計量が１０〜３４質量％である。 A laminate comprising a transparent substrate 1, an ink layer, an adhesive layer, and a substrate 2 having an oxygen permeability of 100 CC (m 2 , 24 hr, 1 atm, 25 ° C.) or less in this order,
The laminated body which satisfy | fills all the conditions of following (1)-(5) about an ink layer, and following (11)- (17) about an adhesive bond layer.
(1) The ink layer is a dried or cured product of an ink composition containing a polyurethane polyurea resin, a vinyl chloride-vinyl acetate copolymer, a pigment, and an organic solvent.
(2) The total content of 100% by mass of the polyurethane polyurea resin and the vinyl chloride-vinyl acetate copolymer contains 5 to 40% by mass of the vinyl chloride-vinyl acetate copolymer.
(3) The polyurethane polyurea resin comprises a structural unit derived from a high molecular weight polyol having a number average molecular weight of 400 to 5,000, a polyurethane block having a structural unit derived from a polyisocyanate compound, and a chain extending unit derived from a compound having an amino group. And the polyurethane block and the chain extension unit contain 5% by mass or more of a polyester polyol in 100% by mass of the polymer polyol having a number average molecular weight of 400 to 5,000 which is bonded by a urea bond.
(4) The mass average molecular weight of the polyurethane polyurea resin is 15,000 to 70,000.
(5) The total concentration of urethane bonds and urea bonds contained in 1 g of the polyurethane polyurea resin is 1.3 to 2.4 mmol / g.
(11) The adhesive layer is a cured product of an adhesive composition containing a polyisocyanate component (A) and a polyol component (B).
(12) The polyisocyanate component (A) contains a urethane prepolymer (a) having an isocyanate group and 4,4′-diphenylmethane diisocyanate.
(13) From a trimer of a bifunctional isocyanate monomer, a biuret in which water is added to a bifunctional isocyanate monomer, and an adduct in which a monoalcohol is added to a bifunctional isocyanate monomer as the polyisocyanate component (A) The present invention further includes a modified product of at least one bifunctional isocyanate monomer selected from the group consisting of
(14) The polyisocyanate component (A) may further contain at least one isocyanate component selected from the group consisting of 2,4'-diphenylmethane diisocyanate, hexamethylene diisocyanate, tolylene diisocyanate, isophorone diisocyanate, and xylene diisocyanate. .
(15) The urethane prepolymer (a) having an isocyanate group is a reaction product of 4,4′-diphenylmethane diisocyanate and a polyol essentially containing a polyether polyol.
(16) In 100% by mass of the polyol component (B), 70 to 100% by mass of polyether polyurethane polyol having a number average molecular weight of 200 or more and 3000 or less is contained.
(17) The total amount of 4,4′-diphenylmethane diisocyanate, 2,4′-diphenylmethane diisocyanate, tolylene diisocyanate, isophorone diisocyanate, and xylene diisocyanate contained in 100% by mass of the adhesive composition is 10 to 34 mass. %.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016160962A JP6664846B2 (en) | 2016-08-19 | 2016-08-19 | Laminate and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016160962A JP6664846B2 (en) | 2016-08-19 | 2016-08-19 | Laminate and manufacturing method thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018027658A JP2018027658A (en) | 2018-02-22 |
| JP2018027658A5 true JP2018027658A5 (en) | 2019-06-06 |
| JP6664846B2 JP6664846B2 (en) | 2020-03-13 |
Family
ID=61248082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016160962A Active JP6664846B2 (en) | 2016-08-19 | 2016-08-19 | Laminate and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6664846B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110475835B (en) * | 2017-04-06 | 2021-12-03 | Dic株式会社 | Curing agent for two-component adhesive, laminated film, and package |
| JP7230445B2 (en) * | 2018-11-13 | 2023-03-01 | 東洋インキＳｃホールディングス株式会社 | Solvent-free adhesive composition and laminate |
| JP7563170B2 (en) | 2020-12-24 | 2024-10-08 | ａｒｔｉｅｎｃｅ株式会社 | Polyol-based adhesives, polyurethane adhesives, and laminates |
| CN117098664A (en) | 2021-03-29 | 2023-11-21 | 东丽株式会社 | Method for producing film laminate |
| CN117897462A (en) * | 2021-09-16 | 2024-04-16 | Dic株式会社 | Adhesive, laminate, and packaging material |
| JP7442562B2 (en) * | 2022-03-25 | 2024-03-04 | ロックペイント株式会社 | Solvent-free polyurethane adhesive for lamination |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009073936A (en) * | 2007-09-20 | 2009-04-09 | Toyo Ink Mfg Co Ltd | Printing ink composition |
| CA2803158C (en) * | 2010-06-29 | 2020-02-04 | E. I. Du Pont De Nemours And Company | Printing ink having enhanced gloss and lower viscosity |
| JP6019911B2 (en) * | 2012-08-09 | 2016-11-02 | 東洋インキＳｃホールディングス株式会社 | Packaging material made by laminating printing ink and adhesive for heat-shrinkable film |
| JP5472525B1 (en) * | 2013-01-22 | 2014-04-16 | 東洋インキＳｃホールディングス株式会社 | Adhesive composition, laminate and method for producing the same |
| JP6405917B2 (en) * | 2014-11-12 | 2018-10-17 | 東洋インキＳｃホールディングス株式会社 | Heat-sealing lid material with excellent adhesive strength |
| JP5975189B1 (en) * | 2016-02-01 | 2016-08-23 | 東洋インキＳｃホールディングス株式会社 | Laminated body and manufacturing method thereof |
| JP6090522B1 (en) * | 2016-03-29 | 2017-03-08 | 東洋インキＳｃホールディングス株式会社 | Laminated body and manufacturing method thereof |
-
2016
- 2016-08-19 JP JP2016160962A patent/JP6664846B2/en active Active
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