JP2017203050A - Hairdressing agent - Google Patents
Hairdressing agent Download PDFInfo
- Publication number
- JP2017203050A JP2017203050A JP2017164051A JP2017164051A JP2017203050A JP 2017203050 A JP2017203050 A JP 2017203050A JP 2017164051 A JP2017164051 A JP 2017164051A JP 2017164051 A JP2017164051 A JP 2017164051A JP 2017203050 A JP2017203050 A JP 2017203050A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- oil
- styling
- hair styling
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000000843 powder Substances 0.000 claims abstract description 30
- 238000002156 mixing Methods 0.000 claims abstract description 28
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 26
- 239000003921 oil Substances 0.000 claims abstract description 21
- 239000005909 Kieselgur Substances 0.000 claims abstract description 18
- 239000007787 solid Substances 0.000 claims abstract description 18
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 17
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 17
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 17
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 239000000341 volatile oil Substances 0.000 claims abstract description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 24
- 235000019198 oils Nutrition 0.000 claims description 20
- 239000001993 wax Substances 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 3
- 229940086555 cyclomethicone Drugs 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- 238000011282 treatment Methods 0.000 abstract description 34
- 239000003795 chemical substances by application Substances 0.000 abstract description 12
- -1 dimethylsiloxane Chemical class 0.000 description 29
- 239000000463 material Substances 0.000 description 29
- 230000000052 comparative effect Effects 0.000 description 15
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
- 239000000194 fatty acid Substances 0.000 description 11
- 229930195729 fatty acid Natural products 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000004166 Lanolin Substances 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 229940039717 lanolin Drugs 0.000 description 4
- 235000019388 lanolin Nutrition 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical group CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 235000019271 petrolatum Nutrition 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000003871 white petrolatum Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 2
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 2
- 240000000912 Macadamia tetraphylla Species 0.000 description 2
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 2
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- VJZWIFWPGRIJSN-XRHABHTOSA-N dilinoleic acid Chemical class CCCCC\C=C/C\C=C/CCCCCCCC(O)=O.CCCCC\C=C/C\C=C/CCCCCCCC(O)=O VJZWIFWPGRIJSN-XRHABHTOSA-N 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- 239000008169 grapeseed oil Substances 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 229960004063 propylene glycol Drugs 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- RPOTYPSPQZVIJY-UHFFFAOYSA-N 1-aminopentan-3-ol Chemical compound CCC(O)CCN RPOTYPSPQZVIJY-UHFFFAOYSA-N 0.000 description 1
- RNHWYOLIEJIAMV-UHFFFAOYSA-N 1-chlorotetradecane Chemical compound CCCCCCCCCCCCCCCl RNHWYOLIEJIAMV-UHFFFAOYSA-N 0.000 description 1
- GKQHIYSTBXDYNQ-UHFFFAOYSA-M 1-dodecylpyridin-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+]1=CC=CC=C1 GKQHIYSTBXDYNQ-UHFFFAOYSA-M 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- OVYMWJFNQQOJBU-UHFFFAOYSA-N 1-octanoyloxypropan-2-yl octanoate Chemical compound CCCCCCCC(=O)OCC(C)OC(=O)CCCCCCC OVYMWJFNQQOJBU-UHFFFAOYSA-N 0.000 description 1
- GLXBPZNFNSLJBS-UHFFFAOYSA-N 11-methyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C GLXBPZNFNSLJBS-UHFFFAOYSA-N 0.000 description 1
- ABEXEQSGABRUHS-UHFFFAOYSA-N 16-methylheptadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C ABEXEQSGABRUHS-UHFFFAOYSA-N 0.000 description 1
- WGKHLTQBAAWSSR-UHFFFAOYSA-N 16-methylheptadecyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCCCCCCCCCCCCCCCC(C)C WGKHLTQBAAWSSR-UHFFFAOYSA-N 0.000 description 1
- WPIOBXGJZUSKGK-UHFFFAOYSA-N 16-methylheptadecyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C WPIOBXGJZUSKGK-UHFFFAOYSA-N 0.000 description 1
- SAMYFBLRCRWESN-UHFFFAOYSA-N 16-methylheptadecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C SAMYFBLRCRWESN-UHFFFAOYSA-N 0.000 description 1
- VRBHTEGUHVNKEA-UHFFFAOYSA-N 16-methylheptadecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C VRBHTEGUHVNKEA-UHFFFAOYSA-N 0.000 description 1
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- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 1
- FUTGDWNFCMWSJT-UHFFFAOYSA-N 2,3-bis(14-methylpentadecanoyloxy)propyl 14-methylpentadecanoate Chemical compound CC(C)CCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCC(C)C FUTGDWNFCMWSJT-UHFFFAOYSA-N 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- UMHYVXGZRGOICM-AUYXYSRISA-N 2-[(z)-octadec-9-enoyl]oxypropyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(C)OC(=O)CCCCCCC\C=C/CCCCCCCC UMHYVXGZRGOICM-AUYXYSRISA-N 0.000 description 1
- BTMZHHCFEOXAAN-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;2-dodecylbenzenesulfonic acid Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O BTMZHHCFEOXAAN-UHFFFAOYSA-N 0.000 description 1
- NFIHXTUNNGIYRF-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)OC(=O)CCCCCCCCC NFIHXTUNNGIYRF-UHFFFAOYSA-N 0.000 description 1
- NAGVKZOTMXGCCA-UHFFFAOYSA-N 2-ethylhexyl 7-methyloctanoate Chemical compound CCCCC(CC)COC(=O)CCCCCC(C)C NAGVKZOTMXGCCA-UHFFFAOYSA-N 0.000 description 1
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- NCLNAHJFXIKYBY-UHFFFAOYSA-N 2-hexyldecyl 16-methylheptadecanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C NCLNAHJFXIKYBY-UHFFFAOYSA-N 0.000 description 1
- WCAYFVDQSNFHOB-UHFFFAOYSA-N 2-hexyldecyl 2,2-dimethyloctanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)C(C)(C)CCCCCC WCAYFVDQSNFHOB-UHFFFAOYSA-N 0.000 description 1
- VDHIEQOYPSVNIM-UHFFFAOYSA-N 2-hexyldecyl 2-ethylhexanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)C(CC)CCCC VDHIEQOYPSVNIM-UHFFFAOYSA-N 0.000 description 1
- JVXJFNLEXLGQIO-UHFFFAOYSA-N 2-hexyldecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC JVXJFNLEXLGQIO-UHFFFAOYSA-N 0.000 description 1
- MWKPHOIHTLQZIY-UHFFFAOYSA-N 2-hexyldecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC MWKPHOIHTLQZIY-UHFFFAOYSA-N 0.000 description 1
- OGJDIJKJFYOENF-UHFFFAOYSA-N 2-hexyldecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC OGJDIJKJFYOENF-UHFFFAOYSA-N 0.000 description 1
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
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- QNJOVLAFLJQFBF-UHFFFAOYSA-N 2-octyldodecyl 16-methylheptadecanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C QNJOVLAFLJQFBF-UHFFFAOYSA-N 0.000 description 1
- OYRKAUXRSTZVFT-UHFFFAOYSA-N 2-octyldodecyl 2,2-dimethyloctanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)C(C)(C)CCCCCC OYRKAUXRSTZVFT-UHFFFAOYSA-N 0.000 description 1
- PTPDZZWUOHQSLG-UHFFFAOYSA-N 2-octyldodecyl 2,2-dimethylpropanoate Chemical compound CCCCCCCCCCC(COC(=O)C(C)(C)C)CCCCCCCC PTPDZZWUOHQSLG-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HBTAOSGHCXUEKI-UHFFFAOYSA-N 4-chloro-n,n-dimethyl-3-nitrobenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 HBTAOSGHCXUEKI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- ODMZDMMTKHXXKA-QXMHVHEDSA-N 8-methylnonyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCCCC(C)C ODMZDMMTKHXXKA-QXMHVHEDSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
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- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- RUTSRVMUIGMTHJ-UHFFFAOYSA-M sodium;tetradec-1-ene-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCC=CS([O-])(=O)=O RUTSRVMUIGMTHJ-UHFFFAOYSA-M 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- 229940105956 tea-dodecylbenzenesulfonate Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- SWZDQOUHBYYPJD-UHFFFAOYSA-N tridodecylamine Chemical compound CCCCCCCCCCCCN(CCCCCCCCCCCC)CCCCCCCCCCCC SWZDQOUHBYYPJD-UHFFFAOYSA-N 0.000 description 1
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、スタイリング性（スタイリングのしやすさ）が良好で、処理後の毛先のまとまりを良好にでき、かつ処理後の毛髪のべたつきを抑え得る整髪料に関するものである。 The present invention relates to a hair styling agent that has good styling properties (easy styling), that can improve the unitization of the hair ends after treatment, and that can suppress stickiness of the hair after treatment.
頭髪のスタイル形成を容易にしたり、形成したスタイルを維持したりするために使用される整髪料には、塗布後の毛髪のべたつきの抑制などを目的として、シリカなどの無機粉体を配合することが従来から行われている（特許文献１〜５など）。 In order to prevent hair stickiness after application, etc., inorganic powders such as silica should be added to the hair styling used to facilitate hair style formation and maintain the style. Is conventionally performed (Patent Documents 1 to 5 and the like).
ところが、塗布後の毛髪のべたつきを抑える効果を高めるために、整髪料への無機粉体の配合量を高めると、例えばスタイリングがし難くなったり、塗布後の毛先のまとまりが悪くなったりするといった問題があり、整髪料のスタイリング性や塗布後の毛先のまとまりのよさと、塗布後の毛髪のべたつきを抑える作用とを高いレベルで両立させることは容易ではない。 However, in order to increase the effect of suppressing the stickiness of the hair after application, increasing the blending amount of the inorganic powder in the hairdressing composition makes it difficult to style, for example, and the hair ends after application are not good. Therefore, it is not easy to achieve both a styling property of the hairdressing material, a good unity of the hair ends after application, and a function of suppressing the stickiness of the hair after application at a high level.
本発明は、上記事情に鑑みてなされたものであり、スタイリング性が良好で、処理後の毛先のまとまりを良好にでき、かつ処理後の毛髪のべたつきを抑え得る整髪料を提供することにある。 The present invention has been made in view of the above circumstances, and provides a hair styling agent that has good styling properties, can be well-organized after treatment, and can suppress stickiness of the hair after treatment. is there.
上記目的を達成し得た本発明の整髪料は、ケイソウ土、カオリンおよびシリカから選ばれる２種以上の無機粉体、揮発性油、２５℃で固体のロウまたは炭化水素、並びに２５℃で液体の油が配合されており、上記無機粉体の配合量が５〜１０質量％であることを特徴とするものである。 The hair styling composition of the present invention that has achieved the above object is composed of two or more inorganic powders selected from diatomaceous earth, kaolin and silica, volatile oil, wax or hydrocarbon solid at 25 ° C., and liquid at 25 ° C. The oil is blended, and the blending amount of the inorganic powder is 5 to 10% by mass.
本発明によれば、スタイリング性が良好で、処理後の毛先のまとまりを良好にでき、かつ処理後の毛髪のべたつきを抑え得る整髪料を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the styling property is favorable, the unit of the hair end after a process can be made favorable, and the hair-styling agent which can suppress the stickiness of the hair after a process can be provided.
本発明の整髪料は、ケイソウ土、カオリンおよびシリカから選ばれる２種以上の無機粉体を配合してなるものである。 The hairdressing material of the present invention is obtained by blending two or more inorganic powders selected from diatomaceous earth, kaolin and silica.
例えば上記の無機粉体の１種のみを使用した場合には、処理後の毛髪のべたつきを十分に抑えるには、無機粉体の配合量を非常に多くする必要があり、その結果、整髪料のスタイリング性が損なわれてしまい、他方、整髪料のスタイリング性を損なわない程度に無機粉体の配合量を抑えた場合には、処理後の毛髪のべたつきを十分に抑制し得ない。 For example, when only one of the above inorganic powders is used, it is necessary to increase the amount of the inorganic powder in order to sufficiently suppress the stickiness of the hair after the treatment. On the other hand, when the blending amount of the inorganic powder is suppressed to such an extent that the styling property of the hairdressing material is not impaired, the stickiness of the hair after the treatment cannot be sufficiently suppressed.
ところが、ケイソウ土、カオリンおよびシリカから選ばれる２種以上の無機粉体を配合して構成した整髪料であれば、理由は定かではないが、これらの無機粉体のいずれかを単独で配合した場合に比べて、処理後の毛髪のべたつきのなさを低下させることなく、スタイリングのしやすさと処理後の毛先のまとまりのよさのバランスが向上させることが可能となる。よって、本発明によれば、スタイリング性が良好で、処理後の毛先のまとまりを良好にでき、かつ処理後の毛髪のべたつきを抑え得る整髪料を提供することができる。 However, if the hair styling composition is composed of two or more inorganic powders selected from diatomaceous earth, kaolin and silica, the reason is not clear, but any one of these inorganic powders is blended alone. Compared to the case, it is possible to improve the balance between the ease of styling and the unity of the hair ends after the treatment without reducing the non-stickiness of the hair after the treatment. Therefore, according to the present invention, it is possible to provide a hair styling product that has good styling properties, can improve the unitization of the hair ends after the treatment, and can suppress the stickiness of the hair after the treatment.
また、無機粉体を配合した整髪料は、一般に、毛髪に絡んだり毛髪の指通りを悪くしたりするが、本発明の整髪料では、こうした問題の発生を抑えることもできる。 Further, hair styling blended with inorganic powder generally entangles the hair or makes the finger of the hair worse, but the hair styling of the present invention can also suppress the occurrence of such problems.
本発明の整髪料に配合する無機粉体は、ケイソウ土、カオリン、シリカのうちのいずれか２種であってもよく、３種全てであってもよい。これらの中でも、ケイソウ土と、カオリンおよびシリカのうちの少なくとも一方とを使用することがより好ましく、ケイソウ土、カオリンおよびシリカの全てを使用することが更に好ましい。 The inorganic powder to be blended in the hair styling composition of the present invention may be any two of diatomaceous earth, kaolin, and silica, or all three. Among these, it is more preferable to use diatomaceous earth and at least one of kaolin and silica, and it is more preferable to use all of diatomaceous earth, kaolin and silica.
本発明の整髪料で使用するシリカは、親水性シリカであってもよく、親油性シリカであってもよい。親油性シリカとしては、例えば、ジメチルジシクロシラン処理、ヘキサメチルジシラザン処理、アルキルシリル処理、ジメチルポリシロキサン処理、ジメチルシロキサン処理などの各種処理を施したシリカが挙げられる。 The silica used in the hair styling material of the present invention may be hydrophilic silica or lipophilic silica. Examples of the lipophilic silica include silica subjected to various treatments such as dimethyldicyclosilane treatment, hexamethyldisilazane treatment, alkylsilyl treatment, dimethylpolysiloxane treatment, and dimethylsiloxane treatment.
整髪料における無機粉体の配合量（ケイソウ土、カオリンおよびシリカの合計配合量。整髪料における無機粉体の配合量について、以下同じ。）は、処理後の毛髪のべたつきを抑制する効果を良好に確保する観点から、５質量％以上であり、６質量％以上であることがより好ましい。ただし、整髪料中の無機粉体の量が多すぎると、整髪料のスタイリング性や処理後の毛先のまとまりのよさが損なわれてしまう。よって、整髪料における無機粉体の配合量は、１０質量％以下であり、８質量％以下であることが好ましい。 The blending amount of inorganic powder in hair styling (total blending amount of diatomaceous earth, kaolin and silica; the same applies to the blending amount of inorganic powder in hair styling) is good for suppressing the stickiness of hair after treatment. From the viewpoint of ensuring the above, it is 5% by mass or more, and more preferably 6% by mass or more. However, if the amount of the inorganic powder in the hairdressing material is too large, the styling property of the hairdressing material and the unity of the hair ends after the treatment are impaired. Therefore, the blending amount of the inorganic powder in the hairdressing material is 10% by mass or less, and preferably 8% by mass or less.
なお、整髪料にケイソウ土を使用する場合、その配合量は、１〜８質量％であることが好ましい。また、整髪料にカオリンを使用する場合、その配合量は、０．１〜５質量％であることが好ましい。更に、整髪料にシリカを使用する場合、その配合量は、０．１〜２質量％であることが好ましい。 In addition, when using diatomaceous earth for a hairdressing material, it is preferable that the compounding quantity is 1-8 mass%. Moreover, when using kaolin for a hairdressing agent, it is preferable that the compounding quantity is 0.1-5 mass%. Furthermore, when using silica for a hairdressing agent, it is preferable that the compounding quantity is 0.1-2 mass%.
本発明の整髪料には、スタイリングを容易にしたり、毛先のまとまりを良好にするなど、形成したスタイルを良好に維持したりするための成分として、揮発性油、２５℃で固体のロウまたは炭化水素、および２５℃で液体の油を配合する。 The hair styling composition of the present invention includes a volatile oil, a wax that is solid at 25 ° C. as a component for maintaining a good style, such as facilitating styling and improving the unity of the hair tips. Blend hydrocarbon and oil liquid at 25 ° C.
揮発性油としては、例えば、シクロメチコン、重合度が１〜３のジメチコンなどのシリコーン；イソドデカン、イソヘキサデカン、イソパラフィンなどの炭化水素；などが挙げられ、これらのうちの１種のみを使用してもよく、２種以上を併用してもよい。上記例示の各揮発性油の中でも、シクロメチコンが特に好ましい。 Examples of the volatile oil include cyclomethicone, silicone such as dimethicone having a degree of polymerization of 1 to 3, hydrocarbons such as isododecane, isohexadecane, and isoparaffin; and only one of these is used. Or two or more of them may be used in combination. Of the volatile oils exemplified above, cyclomethicone is particularly preferred.
整髪料における揮発性油の配合量は、整髪料に要求される形態（剤型）によって変動し得るが、１質量％以上であることが好ましい。ただし、整髪料中の揮発性油の量が多すぎると、整髪料の安定性が低下して、分離や油浮きが生じやすくなる虞がある。よって、整髪料における揮発性油の配合量は、３０質量％以下であることが好ましい。なお、後述するように、本発明の整髪料はクリーム状の形態であることが好ましいが、この場合、揮発性油の配合量は、１０質量％以上２０質量％以下であることがより好ましい。 The blending amount of the volatile oil in the hairdressing composition may vary depending on the form (dosage form) required for the hairdressing composition, but is preferably 1% by mass or more. However, if the amount of the volatile oil in the hairdressing material is too large, the stability of the hairdressing material is lowered and there is a risk that separation and oil floating may easily occur. Therefore, it is preferable that the compounding quantity of the volatile oil in a hairdressing material is 30 mass% or less. As will be described later, the hair styling composition of the present invention is preferably in the form of a cream. In this case, the blending amount of the volatile oil is more preferably 10% by mass or more and 20% by mass or less.
２５℃で固体のロウとしては、例えば、カルナウバロウ、キャンデリラロウ、ミツロウ、コメヌカロウ、モクロウ、ラノリンなどが挙げられ、これらのうちの１種のみを使用してもよく、２種以上を併用してもよい。また、２５℃で固体の炭化水素としては、例えば、パラフィン、セレシン、マイクロクリスタリンワックスなどが挙げられ、これらのうちの１種のみを使用してもよく、複数種を併用してもよい。更に、本発明の整髪料には、２５℃で固体のロウ、および２５℃で固体の炭化水素のうちのいずれか一方のみを用いてもよく、２５℃で固体のロウの１種以上と２５℃で固体の炭化水素の１種以上とを併用してもよい。 Examples of the wax that is solid at 25 ° C. include carnauba wax, candelilla wax, beeswax, rice bran wax, mole crow, and lanolin. One of these may be used, or two or more of them may be used in combination. Also good. Examples of hydrocarbons that are solid at 25 ° C. include paraffin, ceresin, microcrystalline wax, and the like, and only one of them may be used, or a plurality of may be used in combination. Furthermore, in the hair styling of the present invention, only one of waxes that are solid at 25 ° C. and hydrocarbons that are solid at 25 ° C. may be used. You may use together 1 or more types of hydrocarbons solid at ° C.
整髪料における２５℃で固体のロウまたは炭化水素の配合量（整髪料に２５℃で固体のロウ、および２５℃で固体の炭化水素の両者が配合されている場合には、それらの合計量。整髪料における２５℃で固体のロウまたは炭化水素の配合量について、以下同じ。）は、処理後の毛先のまとまりのよさを、より良好にし得ることから、３質量％以上であることが好ましく、１０質量％以上であることがより好ましい。また、処理後の毛髪のべたつきを抑える効果を、より良好に確保する観点から、整髪料における２５℃で固体のロウまたは炭化水素の配合量は、２５質量％以下であることが好ましく、２０質量％以下であることがより好ましい。 The amount of wax or hydrocarbon that is solid at 25 ° C. in the hair styling (when the hair styling contains both solid wax at 25 ° C. and solid hydrocarbon at 25 ° C., the total amount thereof. The same applies to the blending amount of the wax or hydrocarbon solid at 25 ° C. in the hair styling agent, so that the unity of the hair ends after the treatment can be made better, and is preferably 3% by mass or more. More preferably, it is 10 mass% or more. Further, from the viewpoint of better ensuring the effect of suppressing the stickiness of the hair after the treatment, the blending amount of the wax or hydrocarbon solid at 25 ° C. in the hairdressing agent is preferably 25% by mass or less, and 20% by mass. % Or less is more preferable.
２５℃で液体の油としては、例えば、エステル、シリコーン（揮発性油に該当するもの以外のシリコーン）、植物油などが挙げられ、これらのうちの１種のみを用いてもよく、２種以上を併用してもよい。 Examples of oils that are liquid at 25 ° C. include esters, silicones (silicones other than those corresponding to volatile oils), vegetable oils, etc., and only one of them may be used. You may use together.
エステルとしては、例えば、ミリスチン酸イソプロピル、ミリスチン酸ブチル、パルミチン酸イソプロピル、オレイン酸エチル、リノール酸エチル、リノール酸イソプロピル、カプリル酸セチル、ラウリン酸ヘキシル、ミリスチン酸デシル、オレイン酸デシル、オレイン酸オレイル、ラウリン酸イソステアリル、ミリスチン酸イソトリデシル、ミリスチン酸２−ヘキシルデシル、ミリスチン酸イソステアリル、ミリスチン酸２−オクチルドデシル、パルミチン酸２−エチルヘキシル、パルミチン酸２−ヘキシルデシル、パルミチン酸イソステアリル、ステアリン酸２−ジエチルヘキシル、ステアリン酸２−ヘキシルデシル、オレイン酸イソデシル、オレイン酸オクチルドデシル、イソステアリン酸エチル、イソステアリン酸イソプロピル、２−エチルヘキサン酸セチル、２−エチルヘキサン酸セトステアリル、イソステアリン酸ヘキシル、ジ２−エチルヘキサン酸エチレングリコール、ジオレイン酸エチレングリコール、ジカプリル酸プロピレングリコール、ジ（カプリル・カプリン酸）プロピレングリコール、ジカプリン酸プロピレングリコール、ジオレイン酸プロピレングリコール、ジカプリン酸ネオペンチルグリコール、ジ２−エチルヘキサン酸ネオペンチルグリコール、トリカプリル酸グリセリル、トリ２−エチルヘキサン酸グリセリル、トリ（カプリル・カプリン酸）グリセリル、トリイソパルミチン酸グリセリル、トリイソステアリン酸グリセリル、トリ２−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ２−エチルヘキサン酸ペンタエリスリトール、テトライソステアリン酸ペンタエリスリトール、ネオペンタン酸２−オクチルドデシル、２−エチルヘキサン酸２−ヘキシルデシル、２−エチルヘキサン酸イソステアリル、イソノナン酸２−エチルヘキシル、ジメチルオクタン酸２−ヘキシルデシル、ジメチルオクタン酸２−オクチルドデシル、イソパルミチン酸２−エチルヘキシル、イソステアリン酸２−ヘキシルデシル、イソステアリン酸イソステアリル、イソステアリン酸２−オクチルドデシル、乳酸ラウリル、乳酸２−オクチルドデシル、炭酸ジカプリリル、リンゴ酸ジステアリル、コハク酸ジ２−エチルヘキシル、アジピン酸ジイソプロピル、アジピン酸ジイソブチル、アジピン酸ジ２−エチルヘキシル、セバシン酸ジエチル、セバシン酸ジイソプロピル、セバシン酸ジ２−エチルヘキシル、セバシン酸ジブチルオクチル、エチルヘキサン酸アルキル（Ｃ１４−１８）（括弧内の数値は、アルキル部分の炭素数）などが挙げられ、これらのうちの１種のみを使用してもよく、２種以上を併用してもよい。上記例示のエステルの中でも、コハク酸ジオクチルやエチルヘキサン酸アルキル（Ｃ１４−１
８）が特に好ましい。
Examples of esters include isopropyl myristate, butyl myristate, isopropyl palmitate, ethyl oleate, ethyl linoleate, isopropyl linoleate, cetyl caprylate, hexyl laurate, decyl myristate, decyl oleate, oleyl oleate, Isostearyl laurate, isotridecyl myristate, 2-hexyldecyl myristate, isostearyl myristate, 2-octyldodecyl myristate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, isostearyl palmitate, 2-stearic acid stearate Diethylhexyl, 2-hexyldecyl stearate, isodecyl oleate, octyldodecyl oleate, ethyl isostearate, isopropyl isostearate, 2 Cetyl ethylhexanoate, cetostearyl 2-ethylhexanoate, hexyl isostearate, ethylene glycol di-2-ethylhexanoate, ethylene glycol dioleate, propylene glycol dicaprylate, propylene glycol di (capryl / capric acid), propylene glycol dicaprate , Propylene glycol dioleate, neopentyl glycol dicaprate, neopentyl glycol di-2-ethylhexanoate, glyceryl tricaprylate, glyceryl tri-2-ethylhexanoate, glyceryl tri (capryl / caprate), glyceryl triisopalmitate, tri Glyceryl isostearate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, tetra-2-ethyl Pentaerythritol hexanoate, pentaerythritol tetraisostearate, 2-octyldodecyl neopentanoate, 2-hexyldecyl 2-ethylhexanoate, isostearyl 2-ethylhexanoate, 2-ethylhexyl isononanoate, 2-hexyldecyl dimethyloctanoate, 2-octyldodecyl dimethyloctanoate, 2-ethylhexyl isopalmitate, 2-hexyldecyl isostearate, isostearyl isostearate, 2-octyldodecyl isostearate, lauryl lactate, 2-octyl dodecyl lactate, dicaprylyl carbonate, distearyl malate , Di-2-ethylhexyl succinate, diisopropyl adipate, diisobutyl adipate, di-2-ethylhexyl adipate, diethyl sebacate, dii sebacate Examples include sopropyl, di-2-ethylhexyl sebacate, dibutyloctyl sebacate, alkyl hexanoate (C14-18) (the number in parentheses is the number of carbons in the alkyl moiety), and only one of these is used. You may use 2 or more types together. Among the esters exemplified above, dioctyl succinate and alkyl ethylhexanoate (C14-1
8) is particularly preferred.
シリコーンとしては、例えば、ジメチコノール、ジメチコン（重合度が１〜３以外のもの）、ポリオキシエチレン・メチルポリシロキサン共重合体、トリメチルシロキシケイ酸、フェニルプロピルジメチルシロキシケイ酸、メチルフェニルポリシロキサンなどが挙げられこれらのうちの１種のみを使用してもよく、２種以上を併用してもよい。 Examples of silicone include dimethiconol, dimethicone (with a polymerization degree other than 1 to 3), polyoxyethylene / methylpolysiloxane copolymer, trimethylsiloxysilicic acid, phenylpropyldimethylsiloxysilicic acid, methylphenylpolysiloxane, and the like. Only one of these may be used, or two or more may be used in combination.
植物油としては、例えば、アボカド油、アーモンド油、オリーブ油、ゴマ油、コメヌカ油、サフラワー油、大豆油、トウモロコシ油、ナタネ油、ローズヒップ油、マカデミアナッツ油、パーシック油、綿実油、月見草油、メドフォーム油、メドフォーム油誘導体（メドフォーム−６−ラクトンなど）、ヒマワリ油、ブドウ種子油、パーム油、ヒマシ油、グレープシード油、ヤシ油、シア脂（液状のもの）などが挙げられこれらのうちの１種のみを使用してもよく、２種以上を併用してもよい。 Examples of vegetable oils include avocado oil, almond oil, olive oil, sesame oil, rice bran oil, safflower oil, soybean oil, corn oil, rapeseed oil, rosehip oil, macadamia nut oil, persic oil, cottonseed oil, evening primrose oil, and medofoam oil , Medfoam oil derivatives (such as Medfoam-6-lactone), sunflower oil, grape seed oil, palm oil, castor oil, grape seed oil, coconut oil, shea fat (liquid), etc. Only 1 type may be used and 2 or more types may be used together.
整髪料における２５℃で液体の油の配合量（２５℃で液体の油を複数種使用する場合には、それらの合計量。整髪料における２５℃で液体の油の配合量について、以下同じ。）は、整髪料に要求される粘度が確保できる程度の量とすればよいが、具体的には、３質量％以上であることが好ましく、５質量％以上であることがより好ましい。また、特に処理後の毛先のまとまりのよさをより良好にする観点から、整髪料における２５℃で液体の油の配合量は、１５質量％以下であることが好ましく、１０質量％以下であることがより好ましい。 Blending amount of oil that is liquid at 25 ° C. in hair styling (the total amount thereof when using a plurality of liquid oils at 25 ° C. The same applies hereinafter for blending amount of oil that is liquid at 25 ° C. in hair styling. ) May be an amount that can ensure the viscosity required for the hairdressing material, but specifically, it is preferably 3% by mass or more, and more preferably 5% by mass or more. In particular, from the viewpoint of improving the unity of the bristles after the treatment, the blending amount of oil which is liquid at 25 ° C. in the hairdressing agent is preferably 15% by mass or less, and is preferably 10% by mass or less. It is more preferable.
本発明の整髪料には、界面活性剤を配合することが好ましい。界面活性剤には、カチオン性界面活性剤、アニオン性界面活性剤、ノニオン性界面活性剤、両性界面活性剤のいずれも使用することができる。 It is preferable to add a surfactant to the hair styling composition of the present invention. As the surfactant, any of a cationic surfactant, an anionic surfactant, a nonionic surfactant, and an amphoteric surfactant can be used.
カチオン性界面活性剤としては、例えば、ジ−２−エチルヘキシルアミン、ジメチルステアリルアミン、トリラウリルアミンなどのアルキルアミン；ステアリン酸ジメチルアミノエチルアミド、ステアリン酸ジメチルアミノプロピルアミドなどの脂肪族アミドアミン；エステル含有３級アミン；アーコベル型３級アミン；塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウム、塩化パルタミドプロピルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、臭化ベヘニルトリメチルアンモニウム、セチルトリメチルアンモニウムサッカリン、ステアリルトリメチルアンモニウムサッカリンなどのモノアルキル型４級アンモニウム塩；塩化ジココイルジメチルアンモニウム、塩化ジセチルジメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、塩化イソステアリルラウリルジメチルアンモニウムなどのジアルキル型４級アンモニウム塩；塩化ベンザルコニウム、塩化ミリスチルジメチルベンジルアンモニウム、塩化ラウリルジメチル（エチルベンジル）アンモニウム、塩化ステアリルジメチルベンジルアンモニウムなどのベンザルコニウム型４級アンモニウム塩；モノアルキルエーテル型４級アンモニウム塩；塩化ラウリルピリジニウム、塩化セチルピリジニウムなどのアルキルピリジニウム塩；などが挙げられる。 Examples of the cationic surfactant include alkylamines such as di-2-ethylhexylamine, dimethylstearylamine and trilaurylamine; aliphatic amidoamines such as dimethylaminoethylamide stearate and dimethylaminopropylamide stearate; Tertiary amine; Arcobel type tertiary amine; Lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, partamidopropyltrimethylammonium chloride, cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, odor Behenyltrimethylammonium chloride, cetyltrimethylammonium saccharin, stearyltrimethylammonium saccharide Monoalkyl quaternary ammonium salts such as dicocoyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride, isostearyl lauryl dimethyl ammonium chloride, etc .; benzalkonium chloride, myristyl chloride Benzalkonium-type quaternary ammonium salts such as dimethylbenzylammonium chloride, lauryldimethyl (ethylbenzyl) ammonium chloride, stearyldimethylbenzylammonium chloride; monoalkyl ether-type quaternary ammonium salts; alkylpyridinium salts such as laurylpyridinium chloride and cetylpyridinium chloride And so on.
アニオン性界面活性剤としては、例えば、ラウリル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ステアロイルメチルタウリンナトリウム、ドデシルベンゼンスルホン酸トリエタノールアミン、テトラデセンスルホン酸ナトリウムなどが挙げられる。また、アニオン性界面活性剤は、脂肪酸（ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、オレイン酸、ヒドロキシステアリン酸など）とアルカリ〔アミノエチルプロパノール、トリエタノールアミン、アルギニンなどの有機アルカリ；アルカリ金属の水酸化物（水酸化カリウム、水酸化ナトリウムなど）、アンモニアな
どの無機アルカリ；〕とを配合して形成される脂肪酸アルカリ塩（石ケン）であってもよい。
Examples of the anionic surfactant include sodium lauryl sulfate, sodium polyoxyethylene lauryl ether sulfate, sodium stearoylmethyl taurate, triethanolamine dodecylbenzenesulfonate, sodium tetradecenesulfonate, and the like. Anionic surfactants include fatty acids (such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, hydroxystearic acid) and alkalis (organic alkalis such as aminoethylpropanol, triethanolamine, arginine). A fatty acid alkali salt (sodium) formed by blending an alkali metal hydroxide (potassium hydroxide, sodium hydroxide, etc.), an inorganic alkali such as ammonia;
ノニオン性界面活性剤としては、例えば、ポリオキシエチレンアルキルエーテル類（ポリオキシエチレンステアリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンラウリルエーテルなど）、ポリオキシエチレンアルキルフェニルエーテル類、ポリオキシエチレンポリオキシプロピレンアルキルエーテル（ポリオキシエチレンポリオキシプロピレンセチルエーテル、ポリオキシエチレンポリオキシプロピレンベヘニルエーテルポリオキシエチレンポリオキシプロピレンブチルエーテル、ポリオキシエチレンポリオキシプロピレン水添ラノリン、ポリオキシエチレンポリオキシプロピレングリセリンエーテルなど）、ポリオキシエチレンポリオキシプロピレングリコール、グリセリン脂肪酸エステル、ＰＯＥグリセリン脂肪酸エステル（トリイソステアリン酸ＰＥＧ−２０グリセリンなど）、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、モノラウリン酸ポリオキシエチレンソルビタン、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンヒマシ油、ポリオキシエチレン硬化ヒマシ油、ショ糖脂肪酸エステル、デキストリン脂肪酸エステル〔（パルミチン酸／オクタン酸）デキストリンなど〕、アルキルポリグリコシド、Ｎ−アルキルジメチルアミンオキシド、ポリオキシエチレンプロピレングリコール脂肪酸エステルなどが挙げられる。 Nonionic surfactants include, for example, polyoxyethylene alkyl ethers (polyoxyethylene stearyl ether, polyoxyethylene cetyl ether, polyoxyethylene lauryl ether, etc.), polyoxyethylene alkylphenyl ethers, polyoxyethylene polyoxy Propylene alkyl ether (polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene polyoxypropylene behenyl ether polyoxyethylene polyoxypropylene butyl ether, polyoxyethylene polyoxypropylene hydrogenated lanolin, polyoxyethylene polyoxypropylene glycerin ether, etc.), Polyoxyethylene polyoxypropylene glycol, glycerin fatty acid ester, POE glycerin fat Esters (such as PEG-20 glycerin triisostearate), polyglycerol fatty acid esters, sorbitan fatty acid esters, monolauric acid polyoxyethylene sorbitan, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, sucrose Examples include fatty acid esters, dextrin fatty acid esters (such as (palmitic acid / octanoic acid) dextrin), alkyl polyglycosides, N-alkyldimethylamine oxides, and polyoxyethylene propylene glycol fatty acid esters.
両性界面活性剤としては、例えば、コカミドプロピルベタイン、ラウリルジメチルアミノ酢酸ベタイン、ラウラミドプロピルベタイン、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインなどが挙げられる。 Examples of the amphoteric surfactant include cocamidopropyl betaine, lauryldimethylaminoacetic acid betaine, lauramidopropyl betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine.
界面活性剤には、上記例示のもののうちの１種のみを用いてもよく、２種以上を併用してもよい。特に、毛髪に付着している整髪料を洗髪時に洗い流しやすくする観点からは、整髪料には、ノニオン性界面活性剤またはアニオン性界面活性剤を配合することが好ましい。 As the surfactant, only one of those exemplified above may be used, or two or more thereof may be used in combination. In particular, from the viewpoint of facilitating washing away the hairdressing material adhering to the hair at the time of washing the hair, it is preferable to incorporate a nonionic surfactant or an anionic surfactant in the hairdressing material.
整髪料における界面活性剤の配合量は、使用する界面活性剤の種類やイオン性、整髪料の形態によって変動し得るが、例えば、１〜２０質量％である。 The blending amount of the surfactant in the hairdressing material may vary depending on the type and ionicity of the surfactant to be used and the form of the hairdressing material, but is, for example, 1 to 20% by mass.
本発明の整髪料は水系の整髪料とすることができ、この場合、媒体として水を配合する。整髪料を例えばクリーム状とする場合における水の配合量は、３０〜９０質量％であることが好ましい。また、本発明の整髪料は、水を配合せずに非水系の整髪料とすることもできる。 The hair styling material of the present invention can be an aqueous hair styling material. In this case, water is blended as a medium. The amount of water in the case where the hairdressing material is made creamy, for example, is preferably 30 to 90% by mass. Moreover, the hairdressing material of this invention can also be made into a non-aqueous hairdressing material, without mix | blending water.
本発明の整髪料には、上記の各成分以外にも、例えば通常の毛髪化粧料に配合されている各種成分を、本発明の効果を損なわない範囲で適宜配合することができる。このような成分としては、ペースト状の油、多価アルコール、増粘剤、高級アルコール、低級アルコール、防腐剤、酸化防止剤、香料などが挙げられる。 In addition to the above-mentioned components, for example, various components blended in normal hair cosmetics can be appropriately blended in the hairdressing composition of the present invention within a range not impairing the effects of the present invention. Examples of such components include pasty oils, polyhydric alcohols, thickeners, higher alcohols, lower alcohols, preservatives, antioxidants, and fragrances.
ペースト状の油としては、例えば、ワセリンなどの炭化水素；ダイマージリノール酸ダイマージリノレイルビス（フィトステリル／ベヘニル／イソステアリル）、ダイマージリノール酸（フィトステリル／イソステアリル／セチル／ステアリル／ベヘニル）、ラノリン脂肪酸コレステリル、マカデミアナッツ脂肪酸フィトステリル、ヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、ペンタイソステアリン酸ジペンタエリスリチルなどのエステル；などが挙げられる。 Examples of pasty oils include hydrocarbons such as petrolatum; dimer dilinoleic acid dimer dilinoleyl bis (phytosteryl / behenyl / isostearyl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), Lanolin fatty acid cholesteryl, macadamia nut fatty acid phytosteryl, esters such as hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, pentaisostearic acid dipentaerythrityl; and the like.
多価アルコールとしては、例えば、エチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、グリセリン、ジグリセリン、１，３−ブ
チレングリコールなどが挙げられる。
Examples of the polyhydric alcohol include ethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, glycerin, diglycerin, 1,3-butylene glycol and the like.
増粘剤としては、例えば、カラギーナン、キサンタンガム、カルボキシメチルセルロースナトリウム、アルギン酸ナトリウム、ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー、ポリアクリル酸ナトリウム、ヒドロキシエチルセルロース、タマリンドシードガムなどが挙げられる。 Examples of the thickener include carrageenan, xanthan gum, sodium carboxymethylcellulose, sodium alginate, polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, sodium polyacrylate, hydroxyethylcellulose, tamarind seed gum and the like.
高級アルコールとしては、例えば、ラウリルアルコール、セタノール、セトステアリルアルコール、ステアリルアルコール、オレイルアルコール、ベヘニルアルコール、ラノリンアルコール、オクチルドデカノールなどが挙げられる。 Examples of the higher alcohol include lauryl alcohol, cetanol, cetostearyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol, lanolin alcohol, octyldodecanol and the like.
低級アルコールとしては、例えば、エタノール、イソプロパノールなどの炭素数が２〜４のアルコールが挙げられる。 Examples of the lower alcohol include alcohols having 2 to 4 carbon atoms such as ethanol and isopropanol.
防腐剤としては、例えば、安息香酸ナトリウム、パラオキシ安息香酸メチル、パラオキシ安息香酸プロピル、パラオキシ安息香酸ブチル、フェノキシエタノール、メチルクロロイソチアゾリノン・メチルイソチアゾリノン液、２−メチル−４−イソチアゾリン−３−オンなどが挙げられる。 Examples of the preservative include sodium benzoate, methyl paraoxybenzoate, propyl paraoxybenzoate, butyl paraoxybenzoate, phenoxyethanol, methylchloroisothiazolinone / methylisothiazolinone solution, 2-methyl-4-isothiazoline-3- ON etc. are mentioned.
酸化防止剤としては、例えば、ｄｌ−α−トコフェロール、ジブチルヒドロキシトルエン、エリソルビン酸などが挙げられる。 Examples of the antioxidant include dl-α-tocopherol, dibutylhydroxytoluene, erythorbic acid and the like.
本発明の整髪料の形態（剤型）については、特に制限はなく、例えば、ローション状（乳液状）、クリーム状、ワックス状などの形態とすることができるが、使用しやすさなどの点で、クリーム状であることがより好ましい。 The form (dosage form) of the hair styling composition of the present invention is not particularly limited. For example, it can be in the form of a lotion (milky liquid), cream, wax, etc., but it is easy to use. And it is more preferable that it is creamy.
本発明の整髪料は、例えば、それを適量手に取って毛髪に塗布するなどして使用することができる。 The hair styling agent of the present invention can be used, for example, by taking an appropriate amount of it and applying it to hair.
以下、実施例に基づいて本発明を詳細に述べる。ただし、下記実施例は、本発明を制限するものではない。なお、以下の表１〜表４では整髪料全体で、それぞれ１００％となるように各成分の配合量を％で示すが、その％はいずれも質量％であり、また、その％の表示を省略し、配合量を表す数値のみで表示する。また、本実施例において、「％」は、特に断らない限り、質量基準（質量％）である。 Hereinafter, the present invention will be described in detail based on examples. However, the following examples do not limit the present invention. In Tables 1 to 4 below, the total amount of the hair styling is indicated by% so that each component is 100%, but all the% is mass%, and the indication of% is shown. Omitted and displayed only as a numerical value representing the blending amount. In this example, “%” is based on mass (mass%) unless otherwise specified.
実施例１〜７および比較例１〜５
表１および表２に示す組成で実施例１〜７および比較例１〜５の整髪料（クリーム状の整髪料）を調製した。
Examples 1-7 and Comparative Examples 1-5
Hair styling of Examples 1-7 and Comparative Examples 1-5 (cream-like hair styling) was prepared with the compositions shown in Table 1 and Table 2.
実施例１〜７および比較例１〜５のそれぞれ２ｇを手に取って伸ばし、ウィッグの全頭の毛髪に塗布してスタイルを形成した時のスタイリングのしやすさ、毛先のまとまりのよさ、および毛髪のべたつきのなさを、専門の評価者５名のそれぞれが、良好と感じた場合を２点、よくも悪くもないと感じた場合を１点、悪いと感じた場合を０点として点数付けした。そして、全評価者の点数を合計して、各整髪料の評価とした。これらの評価結果を表１および表２に併記する。 2 g of each of Examples 1 to 7 and Comparative Examples 1 to 5 were taken and stretched, applied to the hair of the entire head of the wig, and ease of styling when forming a style; In addition, each of the five expert evaluators felt that the hair was not sticky: 2 points if it felt good, 1 point if it felt good or bad, and 0 points if it felt bad I attached. And the score of all the evaluators was totaled and it was set as evaluation of each hairdressing material. These evaluation results are also shown in Tables 1 and 2.
表１および表２における「水」の欄の「計１００とする」とは、整髪料を構成する水以外の各成分の合計量に、水の量を加えて１００％となるようにしたことを意味している（後記の表３においても同様である）。また、表１および表２に記載の「シリカ」は、親水性シリカである（後記の表３においても同様である）。 In Table 1 and Table 2, the column “water” is “total 100” means that the total amount of each component other than the water constituting the hairdressing material is 100% by adding the amount of water. (The same applies to Table 3 below). “Silica” described in Tables 1 and 2 is hydrophilic silica (the same applies to Table 3 described later).
表１および表２に示す通り、無機粉体としてケイソウ土、カオリンおよびシリカのうちの２種以上を特定量で配合し、更に、揮発性油、２５℃で固体のロウまたは炭化水素、および２５℃で液体の油を配合して構成した実施例１〜７の整髪料では、スタイリングのしやすさが良好で、処理後の毛先のまとまりがよく、毛髪のべたつきも抑えられている。 As shown in Tables 1 and 2, as inorganic powders, two or more of diatomaceous earth, kaolin and silica are blended in specific amounts, volatile oil, wax or hydrocarbon solid at 25 ° C., and 25 In the hair styling of Examples 1 to 7 constituted by blending liquid oil at ° C., the styling ease is good, the hair ends are well-organized after treatment, and the stickiness of the hair is also suppressed.
これに対し、無機粉体を１種だけ使用した比較例１〜３の整髪料のうち、ケイソウ土を用いた比較例１の整髪料は、処理後の毛先のまとまりのよさが劣っている。また、無機粉体にカオリンのみを用いた比較例２の整髪料は、スタイリングのしやすさが劣っている。 On the other hand, among the hair stylings of Comparative Examples 1 to 3 using only one kind of inorganic powder, the hair styling of Comparative Example 1 using diatomaceous earth is inferior in unity of the hair ends after treatment. . Moreover, the hair styling of Comparative Example 2 using only kaolin as the inorganic powder is inferior in styling.
更に、無機粉体にシリカのみを使用した比較例３の整髪料では、無機粉体の配合量を少なくしており、処理後の毛髪のべたつきを抑える機能も劣っているが、その一方でスタイリングのしやすさも劣っている。なお、例えば、比較例３の整髪料とシリカの配合量を同程度とした実施例４、５の整髪料では、スタイリングのしやすさ、処理後の毛先のまとまりのよさ、および処理後の毛髪のべたつきのなさのいずれもが、比較例３の整髪料よりも良好である。これらの結果の対比から、無機粉体としてケイソウ土、カオリンおよびシリカのうちの２種以上を使用することによって、スタイリング性の向上効果、処理後の毛先のまとまりの向上効果、および処理後の毛髪のべたつきの抑制効果のバランスが良好となることが分かる。 Furthermore, in the hair styling of Comparative Example 3 using only silica as the inorganic powder, the blending amount of the inorganic powder is reduced, and the function of suppressing the stickiness of the hair after the treatment is inferior. The ease of use is also inferior. In addition, for example, in the hair styling of Examples 4 and 5 in which the blending amount of the hair styling of Comparative Example 3 and silica is the same, ease of styling, ease of bundling after treatment, and after treatment Any non-stickiness of the hair is better than the hair styling of Comparative Example 3. From the comparison of these results, by using two or more of diatomaceous earth, kaolin and silica as the inorganic powder, the effect of improving styling, the effect of improving the bristles after treatment, and the effect after treatment It turns out that the balance of the inhibitory effect of the stickiness of hair becomes favorable.
更に、無機粉体の配合量が少なすぎる比較例４の整髪料は、処理後の毛髪のべたつきを抑える機能が劣っており、無機粉体の配合量が多すぎる比較例５の整髪料は、スタイリングのしやすさ、および処理後の毛先のまとまりのよさが劣っている。 Furthermore, the hair styling of Comparative Example 4 in which the blending amount of the inorganic powder is too small is inferior in the function of suppressing the stickiness of the hair after the treatment, and the hair styling of Comparative Example 5 in which the blending amount of the inorganic powder is too large is The ease of styling and the cohesion of the hair ends after treatment are inferior.
実施例８
実施例８の整髪料（クリーム状の整髪料）を表３に示す組成で調製し、実施例１の整髪料などと同じ方法で、ウィッグの全頭の毛髪に塗布しスタイルを形成した時のスタイリングのしやすさ、毛先のまとまりのよさ、および毛髪のべたつきのなさを評価した。その結果を表３に併記する。
Example 8
When the hair styling material of Example 8 (cream-like hair styling material) was prepared with the composition shown in Table 3, and applied to the entire hair of the wig in the same manner as the hair styling material of Example 1, the style was formed. The ease of styling, the cohesion of the hair tips, and the non-stickiness of the hair were evaluated. The results are also shown in Table 3.
実施例８の整髪料も、無機粉体としてケイソウ土、カオリンおよびシリカのうちの２種以上を特定量で配合し、更に、揮発性油、２５℃で固体のロウまたは炭化水素、および２５℃で液体の油を配合して構成したものであり、スタイリングのしやすさが良好で、処理後の毛先のまとまりがよく、毛髪のべたつきも抑えられている。 The hair styling of Example 8 also contains two or more types of diatomaceous earth, kaolin and silica as inorganic powders in specific amounts, volatile oil, wax or hydrocarbon solid at 25 ° C., and 25 ° C. In this composition, liquid oil is blended, the styling is easy, the hair ends are well-organized, and the hair is not sticky.
実施例９、１０、比較例６
実施例９、１０および比較例６の整髪料（ワックス状の整髪料）を表４に示す組成で調製し、実施例１の整髪料などと同じ方法で、ウィッグの全頭の毛髪に塗布しスタイルを形成した時のスタイリングのしやすさ、毛先のまとまりのよさ、および毛髪のべたつきのなさを評価した。その結果を表４に併記する。
Examples 9, 10 and Comparative Example 6
The hair styling materials (wax-like hair styling materials) of Examples 9 and 10 and Comparative Example 6 were prepared with the compositions shown in Table 4, and applied to the hair of all wigs in the same manner as the hair styling materials of Example 1. The ease of styling when the style was formed, the goodness of the bristles, and the non-stickiness of the hair were evaluated. The results are also shown in Table 4.
表４における「白色ワセリン」の欄の「計１００とする」とは、整髪料を構成する白色ワセリン以外の各成分の合計量に、白色ワセリンの量を加えて１００％となるようにしたことを意味している。 “Set to 100” in the column of “White petrolatum” in Table 4 means that the amount of white petrolatum is added to the total amount of each component other than white petrolatum constituting the hair dressing to be 100%. Means.
実施例９、１０および比較例６の整髪料は非水系の整髪料の例であるが、無機粉体としてケイソウ土、カオリンおよびシリカのうちの２種以上を特定量で配合し、更に、揮発性油、２５℃で固体のロウまたは炭化水素、および２５℃で液体の油を配合して構成した実施例９、１０の整髪料は、スタイリングのしやすさが良好で、処理後の毛先のまとまりがよく、毛髪のべたつきも抑えられている。 The hair styling of Examples 9, 10 and Comparative Example 6 is an example of a non-aqueous hair styling, but two or more of diatomaceous earth, kaolin and silica are blended in specific amounts as inorganic powders, and further volatilized. The hair styling composition of Examples 9 and 10, which is composed of a natural oil, a wax or hydrocarbon solid at 25 ° C., and a liquid oil at 25 ° C., has good styling and has a hair tip after treatment. It is well-organized and has less hair stickiness.
これに対し、無機粉体にケイソウ土のみを使用した比較例６の整髪料は、スタイリングのしやすさ、および処理後の毛髪のべたつきを抑える機能が劣っている。 In contrast, the hair styling of Comparative Example 6 using only diatomaceous earth as the inorganic powder is inferior in ease of styling and the function of suppressing the stickiness of the hair after treatment.
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