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JP2017101273A - Toll shaft member in melting metal plating bath and its production method, and production method of melting metal plating steel plate - Google Patents

Toll shaft member in melting metal plating bath and its production method, and production method of melting metal plating steel plate Download PDF

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JP2017101273A
JP2017101273A JP2015234065A JP2015234065A JP2017101273A JP 2017101273 A JP2017101273 A JP 2017101273A JP 2015234065 A JP2015234065 A JP 2015234065A JP 2015234065 A JP2015234065 A JP 2015234065A JP 2017101273 A JP2017101273 A JP 2017101273A
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build
layer
shaft member
roll shaft
molten metal
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JP6227618B2 (en
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貴文 金谷
Takafumi Kanaya
貴文 金谷
隼 渡辺
Hayato Watanabe
隼 渡辺
裕三 中澁
Yuzo Nakashibu
裕三 中澁
水津 竜夫
Tatsuo Minazu
竜夫 水津
義孝 渡辺
Yoshitaka Watanabe
義孝 渡辺
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JFE Steel Corp
Tocalo Co Ltd
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Tocalo Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a roll shaft member in a long life melting meta plating bath.SOLUTION: The roll shaft member in melting metal plating bath of the invention, includes: a first padding weld layer comprising cobalt base alloy; and a second padding weld layer comprising cobalt base alloy, which is formed on the first padding weld layer. The second padding weld layer has higher hardness than that of the first padding layer, and a plurality of carbonized tungsten particles are included in the second padding weld layer. At least a part of particles in the plurality of carbonized tungsten particles included is particles made by melting at least a part of particles in the plurality of carbonized tungsten particles added to a weld material for forming the second padding layer in the cobalt base alloy once and precipitated later.SELECTED DRAWING: Figure 1

Description

本発明は、溶融亜鉛めっき浴などの溶融金属めっき浴中に浸漬して使用されるロール軸部材及びその製造方法、並びに溶融金属めっき鋼板の製造方法に関する。   The present invention relates to a roll shaft member used by being immersed in a molten metal plating bath such as a hot dip galvanizing bath, a method for manufacturing the roll shaft member, and a method for manufacturing a molten metal plated steel sheet.

溶融亜鉛めっき鋼板に代表される溶融金属めっき鋼板は、図4に示すように、焼鈍された鋼帯Pが、スナウト30の内部を通過して、ポット32に収容された溶融金属浴34中に連続的に進入し、その後、シンクロール36によって通板方向を上向きに変更された後、サポートロール38に導かれて溶融金属浴34から出て行き、ガスワイピングノズルで所定のめっき厚みに調整された後に、冷却されて、製造される。   As shown in FIG. 4, a hot-dip galvanized steel sheet typified by a hot-dip galvanized steel sheet has an annealed steel strip P that passes through the inside of the snout 30 and enters a molten metal bath 34 accommodated in a pot 32. After entering continuously, the sheet passing direction is changed upward by the sink roll 36, and then guided to the support roll 38, exits the molten metal bath 34, and adjusted to a predetermined plating thickness by the gas wiping nozzle. After that, it is cooled and manufactured.

ここで、溶融金属中に浸漬して配置されるシンクロールは、駆動装置を持たず、ロールの軸が軸受と接触しながら回転する。よって、ロール軸部材は溶融金属中において軸受から摺動抵抗を受けるため、長期間使用するためには、溶融金属に対する耐食性、耐摩耗性、高靭性等の性能が要求される。そのため、溶融金属めっき浴中に配置されるロール軸部材には、従来から様々な検討が行われてきた。   Here, the sink roll disposed by being immersed in the molten metal does not have a driving device, and rotates while the roll shaft is in contact with the bearing. Accordingly, since the roll shaft member receives sliding resistance from the bearing in the molten metal, performance such as corrosion resistance, wear resistance, and high toughness with respect to the molten metal is required for long-term use. For this reason, various studies have been made on roll shaft members disposed in a molten metal plating bath.

特許文献1には、母材金属の表面に、溶融Alに対して熱力学的に安定的なセラミックスと耐熱耐食性金属とからなる緻密質サーメット層を、溶射法、肉盛り溶接法、熱間静水圧プレス法等により形成した溶融金属めっき浴中ロール軸部材が記載されている。特許文献2には、ロール軸部の表面に、Co基合金からなる下肉盛り層と、Co基合金にCr32又はW2Cを含有させた上肉盛り層とを形成した溶融金属めっき浴中ロール軸部材が記載されている。 Patent Document 1 discloses that a dense cermet layer made of ceramic and heat-resistant and corrosion-resistant metal that is thermodynamically stable against molten Al is applied to the surface of a base metal by a thermal spraying method, a build-up welding method, a hot static method. A roll shaft member in a molten metal plating bath formed by a hydraulic press method or the like is described. Patent Document 2 discloses a molten metal in which a lower build-up layer made of a Co-based alloy and an upper build-up layer containing a Co-based alloy containing Cr 3 C 2 or W 2 C are formed on the surface of a roll shaft portion. A roll shaft member in the plating bath is described.

特開平11−61369号公報Japanese Patent Laid-Open No. 11-61369 実開平5−69155号公報Japanese Utility Model Publication No. 5-69155

しかし、特許文献1の技術では、溶融金属に対する耐食性や耐摩耗性は良好であっても、母材金属の上に耐摩耗性が良好な緻密質サーメットを直接形成しているため、ロール軸部材に高荷重が作用した際に緻密質サーメット層に摩耗や割れが発生しやすいという問題がある。   However, in the technique of Patent Document 1, since the dense cermet having good wear resistance is directly formed on the base metal even though the corrosion resistance and wear resistance to the molten metal are good, the roll shaft member There is a problem that the dense cermet layer is likely to be worn or cracked when a high load is applied.

特許文献2の技術では、ロール軸部と高硬度の上肉盛り層との間に、上肉盛り層よりも低硬度の下肉盛り層が配置されるため、特許文献1よりは割れの発生は抑えられるものと思われる。しかし、実機使用時にロール軸部材が軸受から強い摺動抵抗を受けた場合には、肉盛り層の摩耗や割れの抑制が不十分であった。   In the technique of Patent Document 2, since a lower overlay layer having a lower hardness than the upper overlay layer is disposed between the roll shaft portion and the upper overlay layer having a high hardness, the occurrence of cracking is greater than that of Patent Document 1. Seems to be suppressed. However, when the roll shaft member receives a strong sliding resistance from the bearing during actual use, the build-up layer is not sufficiently suppressed from being worn or cracked.

このようにロール軸部材の被覆層に割れが発生した場合、割れの中に溶融金属が浸入してロール軸の基材と反応し、基材を損傷させ、ロールの回転不良が発生して、鋼板の生産及び品質に悪影響を及ぼす。そのため、実機使用時にロール軸部材が軸受から強い摺動抵抗を受けた場合にも被覆層に摩耗や割れが発生しにくいロール軸部材が求められていた。   Thus, when a crack occurs in the coating layer of the roll shaft member, the molten metal penetrates into the crack and reacts with the base material of the roll shaft, damaging the base material, causing a rotation failure of the roll, It adversely affects the production and quality of steel sheets. Therefore, there has been a demand for a roll shaft member that is less likely to be worn or cracked in the coating layer even when the roll shaft member receives a strong sliding resistance from the bearing during actual use.

そこで本発明は、上記課題に鑑み、被覆層の摩耗や割れを抑制した長寿命の溶融金属めっき浴中ロール軸部材及びその製造方法を提供することを目的とする。また、本発明は、長期の安定生産が可能な溶融金属めっき鋼板の製造方法を提供することを目的とする。   In view of the above problems, an object of the present invention is to provide a roll shaft member in a long-life molten metal plating bath in which wear and cracking of a coating layer are suppressed, and a method for manufacturing the roll shaft member. Moreover, an object of this invention is to provide the manufacturing method of the molten metal plating steel plate in which long-term stable production is possible.

上記課題を解決する本発明の要旨構成は以下のとおりである。
(1)金属基材と、
該金属基材上に形成された、コバルト基合金からなる第1の肉盛り溶接層と、
該第1の肉盛り溶接層上に形成された、コバルト基合金からなる第2の肉盛り溶接層と、
を有する溶融金属めっき浴中ロール軸部材であって、
前記第2の肉盛り溶接層は、前記第1の肉盛り溶接層よりも高い硬度を有し、
前記第2の肉盛り溶接層には複数の炭化タングステン粒子が含まれ、
前記第2の肉盛り溶接層に含まれる複数の炭化タングステン粒子のうち少なくとも一部の粒子は、前記第2の肉盛り層を形成する溶接材に添加された複数の炭化タングステン粒子のうち少なくとも一部の粒子の少なくとも一部分が前記コバルト基合金中に一度溶解し、その後析出したものであることを特徴とする溶融金属めっき浴中ロール軸部材。
The gist configuration of the present invention for solving the above-described problems is as follows.
(1) a metal substrate;
A first build-up weld layer made of a cobalt-based alloy formed on the metal substrate;
A second build-up weld layer made of a cobalt-based alloy formed on the first build-up weld layer;
A roll shaft member in a molten metal plating bath having:
The second build-up weld layer has a higher hardness than the first build-up weld layer,
The second build-up weld layer includes a plurality of tungsten carbide particles,
At least some of the plurality of tungsten carbide particles included in the second build-up weld layer are at least one of the plurality of tungsten carbide particles added to the welding material forming the second build-up layer. A roll shaft member in a molten metal plating bath, wherein at least a part of the particles of the portion is once dissolved in the cobalt-based alloy and then precipitated.

(2)前記第1の肉盛り溶接層がHRC40未満の硬度を有し、前記第2の肉盛り溶接層がHRC40以上の硬度を有する、上記(1)に記載の溶融金属めっき浴中ロール軸部材。   (2) The roll shaft in the molten metal plating bath according to (1), wherein the first build-up weld layer has a hardness of less than HRC40, and the second build-up weld layer has a hardness of HRC40 or higher. Element.

(3)前記第2の肉盛り溶接層中の炭化タングステン粒子の含有量が50質量%以下である上記(1)又は(2)に記載の溶融金属めっき浴中ロール軸部材。   (3) The roll shaft member in the molten metal plating bath according to (1) or (2), wherein the content of tungsten carbide particles in the second build-up weld layer is 50% by mass or less.

(4)前記第2の肉盛り溶接層がロール軸方向に施工されたものである上記(1)〜(3)のいずれかに記載の溶融金属めっき浴中ロール軸部材。   (4) The roll shaft member in the molten metal plating bath according to any one of (1) to (3), wherein the second build-up weld layer is constructed in the roll axis direction.

(5)前記第2の肉盛り溶接層上に、前記第2の肉盛り溶接層よりも硬度が高い溶射層を有する上記(1)〜(4)のいずれかに記載の溶融金属めっき浴中ロール軸部材。   (5) In the molten metal plating bath according to any one of the above (1) to (4), having a thermal spray layer having a higher hardness than the second build-up weld layer on the second build-up weld layer. Roll shaft member.

(6)前記溶射層は、炭化タングステン系サーメット材又は硼化タングステン系サーメット材からなる上記(5)に記載の溶融金属めっき浴中ロール軸部材。   (6) The sprayed layer is a roll shaft member in a molten metal plating bath according to (5), wherein the sprayed layer is made of a tungsten carbide cermet material or a tungsten boride cermet material.

(7)金属基材上に、コバルト基合金からなる溶接材を肉盛り溶接し、第1の肉盛り溶接層を形成する第一工程と、
前記第1の肉盛り溶接層上に、コバルト基合金からなり、かつ複数の炭化タングステン粒子を含む溶接材を肉盛り溶接し、第2の肉盛り溶接層を形成する第二工程と、
を有する溶融金属めっき浴中ロール軸部材の製造方法であって、
前記第二工程において、複数の炭化タングステン粒子のうち少なくとも一部の粒子は、その少なくとも一部分が前記コバルト基合金中に一度溶解し、その後析出させられる
ことを特徴とする溶融金属めっき浴中ロール軸部材の製造方法。
(7) a first step of overlay welding a welding material made of a cobalt-based alloy on a metal base material to form a first overlay weld layer;
On the first build-up weld layer, a second step of build-up welding a welding material made of a cobalt-based alloy and containing a plurality of tungsten carbide particles to form a second build-up weld layer;
A method for producing a roll shaft member in a molten metal plating bath having
In the second step, at least a part of the plurality of tungsten carbide particles, at least a part of which is once dissolved in the cobalt-based alloy and then precipitated, and then a roll shaft in a molten metal plating bath, Manufacturing method of member.

(8)前記第二工程において、肉盛り溶接は2周以上施工する上記(7)に記載の溶融金属めっき浴中ロール軸部材の製造方法。   (8) The manufacturing method of the roll shaft member in the molten metal plating bath according to (7), wherein the build-up welding is performed two or more times in the second step.

(9)前記第二工程において、肉盛り溶接はロール軸方向に施工する上記(7)又は(8)に記載の溶融金属めっき浴中ロール軸部材の製造方法。   (9) In the second step, build-up welding is performed in the roll axis direction. The method for manufacturing a roll shaft member in a molten metal plating bath according to (7) or (8).

(10)前記第1の肉盛り溶接層がHRC40未満の硬度を有し、前記第2の肉盛り溶接層がHRC40以上の硬度を有する、上記(7)〜(9)のいずれか一項に記載の溶融金属めっき浴中ロール軸部材の製造方法。   (10) In any one of the above (7) to (9), the first build-up weld layer has a hardness of less than HRC40, and the second build-up weld layer has a hardness of HRC40 or higher. A method for producing a roll shaft member in the molten metal plating bath as described.

(11)前記第2の肉盛り溶接層中の炭化タングステン粒子の含有量が50質量%以下である上記(7)〜(10)のいずれか一項に記載の溶融金属めっき浴中ロール軸部材の製造方法。   (11) The roll shaft member in the molten metal plating bath according to any one of (7) to (10), wherein the content of tungsten carbide particles in the second build-up weld layer is 50% by mass or less. Manufacturing method.

(12)前記第二工程後、前記第2の肉盛り溶接層上に、前記第2の肉盛り溶接層よりも硬度が高い溶射層を形成する第三工程をさらに有する上記(7)〜(11)のいずれか一項に記載の溶融金属めっき浴中ロール軸部材の製造方法。   (12) The above (7) to (7) further including a third step of forming a sprayed layer having a hardness higher than that of the second build-up weld layer on the second build-up weld layer after the second step. The manufacturing method of the roll shaft member in the molten metal plating bath as described in any one of 11).

(13)前記第三工程における溶射材は、炭化タングステン系サーメット材又は硼化タングステン系サーメット材である上記(12)に記載の溶融金属めっき浴中ロール軸部材の製造方法。   (13) The method for producing a roll shaft member in a molten metal plating bath according to (12), wherein the thermal spray material in the third step is a tungsten carbide cermet material or a tungsten boride cermet material.

(14)上記(1)〜(6)のいずれか一項に記載の溶融金属めっき浴中ロール軸部材を溶融金属めっき浴中で用いて、溶融金属めっき鋼板を製造することを特徴とする溶融金属めっき鋼板の製造方法。   (14) Molten metal-plated steel sheet is produced using the roll shaft member in the molten metal plating bath according to any one of (1) to (6) above in a molten metal plating bath. A method for producing a metal-plated steel sheet.

本発明の溶融金属めっき浴中ロール軸部材は、被覆層の摩耗や割れが抑制されるため長寿命である。また、本発明の溶融金属めっき浴中ロール軸部材の製造方法によれば、被覆層の摩耗や割れを抑制した長寿命の溶融金属めっき浴中ロール軸部材を得ることができる。また、本発明の溶融金属めっき鋼板の製造方法によれば、長期の安定生産が可能である。   The roll shaft member in the molten metal plating bath of the present invention has a long life because wear and cracking of the coating layer are suppressed. Moreover, according to the manufacturing method of the roll shaft member in the molten metal plating bath of the present invention, it is possible to obtain a roll shaft member in the molten metal plating bath having a long life in which wear and cracking of the coating layer are suppressed. Moreover, according to the manufacturing method of the molten metal plating steel plate of this invention, long-term stable production is possible.

本発明の一実施形態によるロール軸部材100の模式断面図である。It is a schematic cross section of the roll shaft member 100 by one Embodiment of this invention. 図1における第2の肉盛り溶接層中の炭化タングステン粒子の状態を説明する図である。It is a figure explaining the state of the tungsten carbide particle in the 2nd build-up weld layer in FIG. 本発明の一実施形態における、ロール軸方向の肉盛り溶接の施工方法を示す図である。It is a figure which shows the construction method of the overlay welding of the roll axial direction in one Embodiment of this invention. 溶融金属めっき設備の模式図である。It is a schematic diagram of a molten metal plating facility. (A),(B)は、それぞれ図4におけるシンクロール36の端部の構成を示す断面図及び斜視図である。(A), (B) is sectional drawing and perspective view which respectively show the structure of the edge part of the sink roll 36 in FIG. 発明例1における、第2の肉盛り溶接層の断面のSEM写真である。It is a SEM photograph of the section of the 2nd build-up welding layer in example 1 of an invention.

本発明の一実施形態によるロール軸部材は、例えば、図4に示すシンクロール36の端部に用いられるスリーブである。図4を参照して、焼鈍された鋼帯Pは、スナウト30の内部を通過して、ポット32に収容された溶融金属浴34中に連続的に進入し、その後、シンクロール36によって通板方向を上向きに変更された後、サポートロール38に導かれて溶融金属浴34から出て行き、ガスワイピングノズルで所定のめっき厚みに調整された後に、冷却される。   The roll shaft member according to the embodiment of the present invention is, for example, a sleeve used at the end of the sink roll 36 shown in FIG. Referring to FIG. 4, the annealed steel strip P passes through the inside of the snout 30 and continuously enters the molten metal bath 34 accommodated in the pot 32, and then passes through the sink roll 36. After the direction is changed upward, it is guided to the support roll 38 and exits from the molten metal bath 34, adjusted to a predetermined plating thickness by a gas wiping nozzle, and then cooled.

図5を参照して、溶融金属中に浸漬して配置されるシンクロール36の端部の構成を説明する。シンクロール36の軸の端部が、筒状のスリーブ40に挿入され、さらに軸受42を介して、ハンガー44で支持される。シンクロール36は駆動装置を持たず、鋼帯Pの通板に伴い回転する。その際は、スリーブ40が軸受42と接触しており、スリーブ40は軸受42から摺動抵抗を受ける。よって、本発明の一実施形態によるロール軸部材は、スリーブ40に適用できる。   With reference to FIG. 5, the structure of the edge part of the sink roll 36 arrange | positioned by being immersed in molten metal is demonstrated. The end portion of the shaft of the sink roll 36 is inserted into the cylindrical sleeve 40 and further supported by the hanger 44 through the bearing 42. The sink roll 36 does not have a driving device, and rotates with the passing of the steel strip P. At that time, the sleeve 40 is in contact with the bearing 42, and the sleeve 40 receives sliding resistance from the bearing 42. Therefore, the roll shaft member according to the embodiment of the present invention can be applied to the sleeve 40.

溶融金属としては、溶融亜鉛、溶融アルミニウム、溶融Zn−Al、溶融Al−Siなどを挙げることができ、特に限定されない。   Examples of the molten metal include molten zinc, molten aluminum, molten Zn—Al, and molten Al—Si, and are not particularly limited.

本発明者らは、溶融亜鉛めっき浴中のロール軸部材の損傷形態を詳細に観察した。その結果、鉄基ロール基材の比重が溶融亜鉛の比重よりも小さいため、溶融亜鉛浴中ではロールに浮力が生じ、鋼帯の張力と合わせて、ロール軸部材には強い曲げ応力が作用し、さらに軸受から受ける強い摺動抵抗にも起因して被覆層の摩耗や割れが発生する。また、被覆層の割れの中に溶融亜鉛が浸入して、耐食性に劣る基材を溶損させることで、割れが進展して最終的にロール軸部材の損傷に至ることが判明した。   The present inventors have observed in detail the damage form of the roll shaft member in the hot dip galvanizing bath. As a result, the specific gravity of the iron-based roll base material is smaller than the specific gravity of molten zinc, so buoyancy occurs in the roll in the molten zinc bath, and a strong bending stress acts on the roll shaft member in combination with the tension of the steel strip. Furthermore, the coating layer is worn and cracked due to the strong sliding resistance received from the bearing. Further, it was found that the molten zinc penetrates into the cracks of the coating layer and melts the base material having poor corrosion resistance, so that the cracks progress and finally the roll shaft member is damaged.

これらの結果から、ロール軸部材に作用する曲げ応力に対し耐割れ性を有する肉盛り材の選定や、施工条件等に関する被覆材の開発を鋭意努力して行い、本発明を完成するに至った。   From these results, the present invention was completed by intensively developing a covering material related to the selection of a build-up material having crack resistance against bending stress acting on the roll shaft member and construction conditions, etc. .

図1を参照して、本発明の一実施形態による溶融金属めっき浴中ロール軸部材100は、金属基材10と、この金属基材の上に形成された第1の肉盛り溶接層12と、この第1の肉盛り溶接層の上に形成された第2の肉盛り溶接層14と、この第2の肉盛り溶接層の上に形成された、炭化タングステン系サーメット材又は硼化タングステン系サーメット材からなる溶射層16と、を有する。なお、本明細書では金属基材上の肉盛り溶接層及び溶射層を「被覆層」と総称する。   Referring to FIG. 1, a roll shaft member 100 in a molten metal plating bath according to an embodiment of the present invention includes a metal base 10 and a first build-up weld layer 12 formed on the metal base. The second build-up weld layer 14 formed on the first build-up weld layer and the tungsten carbide cermet material or tungsten boride system formed on the second build-up weld layer And a sprayed layer 16 made of a cermet material. In the present specification, the build-up weld layer and the sprayed layer on the metal substrate are collectively referred to as “coating layer”.

金属基材10は、例えばSUS316L鋼、SUS410鋼、SUS420鋼等の材質からなる。金属基材10の硬度は、HRC22以下が好ましく、HRC11以下がより好ましい。金属基材の硬さがHRC22を超えると、硬すぎて使用中に割れやすくなるためである。金属基材10の硬度は、HRC10以上とすることが好ましい。   The metal base material 10 consists of materials, such as SUS316L steel, SUS410 steel, SUS420 steel, for example. The hardness of the metal substrate 10 is preferably HRC22 or less, and more preferably HRC11 or less. This is because if the hardness of the metal substrate exceeds HRC22, the metal substrate is too hard and easily cracks during use. The hardness of the metal substrate 10 is preferably HRC10 or higher.

ここで、本実施形態では、金属基材10よりも上側に形成された、コバルト基合金からなる肉盛り溶接層を「第1の肉盛り溶接層」とし、第1の肉盛り溶接層よりも上側に形成された、コバルト基合金からなり、炭化タングステン粒子を含み、かつ第1の肉盛り溶接層12よりも高い硬度を有する肉盛り溶接層を「第2の肉盛り溶接層」と定義する。金属基材10上に形成される肉盛り溶接層はこれら2層に限定されず、他の肉盛り溶接層が形成されていてもよい。金属基材10上に第1の肉盛り溶接層12及び第2の肉盛り溶接層14以外の肉盛り溶接層が形成される場合は、各肉盛り溶接層が金属基材から離れるほど高い硬度を有することが好ましい。このように、ロール軸部材の金属基材から表面に向けて、漸変的に硬度を高くすることで、ロール軸部材が受ける曲げ応力を緩和し、被覆層の割れを抑制することができる。   Here, in this embodiment, the build-up weld layer made of a cobalt-based alloy formed on the upper side of the metal base material 10 is referred to as a “first build-up weld layer”, and is more than the first build-up weld layer. The build-up weld layer made of a cobalt-based alloy, including tungsten carbide particles, and having a hardness higher than that of the first build-up weld layer 12 is defined as a “second build-up weld layer”. . The build-up weld layer formed on the metal substrate 10 is not limited to these two layers, and other build-up weld layers may be formed. When a build-up weld layer other than the first build-up weld layer 12 and the second build-up weld layer 14 is formed on the metal substrate 10, the hardness increases as the build-up weld layers are separated from the metal substrate. It is preferable to have. Thus, by gradually increasing the hardness from the metal base material of the roll shaft member to the surface, the bending stress received by the roll shaft member can be relaxed and cracking of the coating layer can be suppressed.

肉盛り溶接層は2層でも十分な割れ抑制の効果を有する。肉盛り溶接層を3層以上にしてもいいが、多層になると施工性に劣るため、2層又は3層にするのが好ましい。肉盛り溶接は、母材表面に硬化、耐食、補修、再生などの目的に応じた金属を溶着する、母材の表面処理技術であり、溶射やめっきに比べて厚い層を形成できる。   Even if the build-up weld layer has two layers, it has an effect of suppressing cracking sufficiently. Although the build-up weld layer may be three or more layers, since it is inferior in workability when it becomes a multilayer, it is preferable to use two or three layers. Overlay welding is a surface treatment technique for a base material in which a metal is deposited on the surface of the base material according to the purpose of hardening, corrosion resistance, repair, regeneration, etc., and a thicker layer can be formed compared to spraying or plating.

本実施形態において、複数層の肉盛り溶接層は全てコバルト基合金からなることが好ましい。肉盛り材料としてはニッケル基合金もあるが、溶融亜鉛浴中における耐食性はコバルト基合金が優れているからである。   In this embodiment, it is preferable that all the build-up weld layers of a plurality of layers are made of a cobalt-based alloy. This is because there is a nickel-based alloy as the build-up material, but the cobalt-based alloy is superior in corrosion resistance in the molten zinc bath.

各肉盛り溶接層を形成するための肉盛り材料は、各肉盛り溶接層の硬度が上記の条件を満たすように、各種肉盛り用合金の市販材(例えば、ステライト合金、トリバロイ合金等)から適宜選び、組み合わせればよい。   The build-up material for forming each build-up weld layer is made from commercially available materials for various build-up alloys (for example, stellite alloy, trivalloy alloy, etc.) so that the hardness of each build-up weld layer satisfies the above conditions. Select and combine as appropriate.

このとき、第1の肉盛り溶接層12がHRC40未満の硬度を有し、第2の肉盛り溶接層14がHRC40以上の硬度を有することが好ましい。第2の肉盛り溶接層14をHRC40以上の高硬度とすることで、耐摩耗性が高まる。第2の肉盛り溶接層14の硬度は、HRC45以上とすることがより好ましく、上限はHRC53程度とすることが好ましい。HRC53を超えると、耐摩耗性には優れるが割れが入りやすくなるからである。第1の肉盛り溶接層12の硬度は、HRC35以上とすることが好ましい。   At this time, it is preferable that the first build-up weld layer 12 has a hardness of less than HRC40, and the second build-up weld layer 14 has a hardness of HRC40 or more. Wear resistance is enhanced by setting the second build-up weld layer 14 to a high hardness of HRC40 or higher. The hardness of the second build-up weld layer 14 is more preferably HRC45 or higher, and the upper limit is preferably about HRC53. If it exceeds HRC53, it is excellent in wear resistance, but cracks easily enter. The hardness of the first build-up weld layer 12 is preferably HRC35 or higher.

図1を参照して、第2の肉盛り溶接層14は複数の炭化タングステン粒子20A,20Bを含むものとする。第2の肉盛り溶接層14中の炭化タングステンの含有量は、50質量%以下であることが好ましく、40質量%以下がより好ましい。50質量%を超えると、肉盛り溶接層の施工時に割れが発生する可能性があるからである。第2の肉盛り溶接層14中の炭化タングステンの含有量は、炭化タングステン粒子添加の効果を確保するために、25質量%以上であることが好ましい。炭化タングステン粒子を第2の肉盛り溶接層14に含ませることで、溶融金属に対する耐溶損性と耐摩耗性が向上する。なお、本発明において、「炭化タングステン粒子」とは、WC粒子、W2C粒子、及び、WCとW2Cの両方を含む粒子のいずれも含む概念である。 Referring to FIG. 1, second build-up weld layer 14 is assumed to include a plurality of tungsten carbide particles 20A and 20B. The content of tungsten carbide in the second build-up weld layer 14 is preferably 50% by mass or less, and more preferably 40% by mass or less. It is because a crack may generate | occur | produce at the time of construction of a build-up weld layer when it exceeds 50 mass%. The content of tungsten carbide in the second build-up weld layer 14 is preferably 25% by mass or more in order to ensure the effect of adding tungsten carbide particles. By including the tungsten carbide particles in the second build-up weld layer 14, resistance to melting and wear resistance to the molten metal is improved. In the present invention, “tungsten carbide particles” is a concept including all of WC particles, W 2 C particles, and particles containing both WC and W 2 C.

ここで、図1及び図2を参照して、第2の肉盛り溶接層14中に含まれる複数の炭化タングステン粒子のうち少なくとも一部の粒子は、第2の肉盛り層14を形成する溶接材に添加された複数の炭化タングステン粒子のうち少なくとも一部の粒子の少なくとも一部分がコバルト基合金中に一度溶解し、その後析出したものである。図1及び図2中、コバルト基合金中に少なくとも一部分が一度溶解し、その後析出した炭化タングステン粒子は符号20Bで示し、それ以外の炭化タングステン粒子は符号20Aで示した。炭化タングステン粒子は、コバルト基合金中に一度溶解すると、その後析出する過程で分散析出する。硬質な炭化タングステン粒子が第2の肉盛り溶接層14中に離散的に位置すると、その硬さが均一になるため、第2の肉盛り溶接層14の耐摩耗性が向上する。また、硬さが均一になると、第2の肉盛り溶接層14上に溶射層を形成することが可能になり、さらなる長寿命化が可能になる。炭化タングステン粒子20Aは、コバルト基合金中に溶解しなかった粒子か、コバルト基合金中に該粒子の表面から一部分のみが溶解し、中心部のみが残った粒子である。   Here, with reference to FIG. 1 and FIG. 2, at least some of the plurality of tungsten carbide particles contained in the second build-up weld layer 14 are welded to form the second build-up layer 14. At least a part of at least some of the plurality of tungsten carbide particles added to the material is once dissolved in the cobalt-based alloy and then precipitated. In FIGS. 1 and 2, tungsten carbide particles at least partially dissolved in the cobalt-based alloy and then precipitated are indicated by reference numeral 20B, and other tungsten carbide particles are indicated by reference numeral 20A. Once the tungsten carbide particles are once dissolved in the cobalt-based alloy, they are dispersed and precipitated in the subsequent precipitation process. When the hard tungsten carbide particles are discretely positioned in the second build-up weld layer 14, the hardness thereof becomes uniform, so that the wear resistance of the second build-up weld layer 14 is improved. Further, when the hardness becomes uniform, it becomes possible to form a sprayed layer on the second build-up weld layer 14 and to further extend the life. Tungsten carbide particles 20A are particles that did not dissolve in the cobalt-based alloy, or particles in which only a portion of the surface of the particles was dissolved in the cobalt-based alloy and only the central portion remained.

ここで、第2の肉盛り溶接層中の炭化タングステン粒子の状態は、第2の肉盛り溶接層の断面を走査型電子顕微鏡(SEM)で観察することにより、把握できる。図6は、第2の肉盛り溶接層に相当する部分のSEM写真である。図6における第2の肉盛り溶接層中の複数の炭化タングステン粒子は、第2の肉盛り層を形成する溶接材に添加された炭化タングステン粒子の表面から、コバルト基合金中に少なくとも一部分または全部が一度溶解し、その後析出したものである。各析出物の形状は異形状であり、一部はデンドライト状となっている。炭化タングステン粒子がコバルト基合金中に一度溶解し、析出したものであるか否かは、SEM写真における当該粒子の形状から判別できる。   Here, the state of the tungsten carbide particles in the second build-up weld layer can be grasped by observing the cross section of the second build-up weld layer with a scanning electron microscope (SEM). FIG. 6 is an SEM photograph of a portion corresponding to the second build-up weld layer. The plurality of tungsten carbide particles in the second build-up weld layer in FIG. 6 are at least partially or entirely in the cobalt-based alloy from the surface of the tungsten carbide particles added to the welding material forming the second build-up layer. Is dissolved once and then precipitated. Each of the precipitates has a different shape, and a part thereof has a dendrite shape. Whether or not the tungsten carbide particles are once dissolved and precipitated in the cobalt-based alloy can be determined from the shape of the particles in the SEM photograph.

コバルト基合金の融点(1270〜1300℃)よりも高温で一定時間溶接材を保持し、その後一定時間かけて冷却すると、コバルト基合金中への炭化タングステン粒子の溶解−析出現象が起きる。そのような状況を簡易的に実現する方法として、第2の肉盛り溶接層を形成する際に、2周以上の肉盛り施工を行う方法が挙げられる。   When the welding material is held for a certain time at a temperature higher than the melting point (1270 to 1300 ° C.) of the cobalt-based alloy and then cooled for a certain time, a dissolution-precipitation phenomenon of tungsten carbide particles in the cobalt-based alloy occurs. As a method of simply realizing such a situation, there is a method of performing build-up construction of two or more rounds when forming the second build-up weld layer.

溶接材中に含ませる炭化タングステン粒子のサイズとしては、平均粒径80〜280μmが好ましく、形状としては、球状又はブロック状のものが好ましい。   The size of the tungsten carbide particles contained in the welding material is preferably an average particle size of 80 to 280 μm, and the shape is preferably spherical or block-shaped.

本実施形態において第2の肉盛り溶接層は、図3に示すようにロール軸方向Cに施工されたものであることが望ましい。肉盛り溶接は通常、円筒形状の部材に対して円周方向にスパイラル状に施工するが、曲げ応力が作用する溶融金属めっき浴中ロール軸部材では、肉盛りの重ね合わせ部の損傷が起点となり、割れが発生することが多い。これに対し、ロール軸方向に肉盛り溶接を施工すると、仮に肉盛り溶接層の重ね合わせ部が損傷しても、ロール軸方向の損傷であるから、ロール軸部材に曲げ応力が作用しても直ちに割れを形成することはない。なお、第1の肉盛り溶接層は、ロール軸方向に施工しても、ロールの周方向に施工しても構わない。   In this embodiment, it is desirable that the second build-up weld layer is constructed in the roll axial direction C as shown in FIG. Overlay welding is usually performed on a cylindrical member in a spiral shape in the circumferential direction. However, in roll shaft members in hot metal plating baths where bending stress acts, damage to the overlay of the overlay is the starting point. In many cases, cracks occur. On the other hand, if build-up welding is performed in the roll axis direction, even if the overlapped portion of the build-up weld layer is damaged, even if bending stress acts on the roll shaft member, it is damage in the roll axis direction. There is no immediate crack formation. The first build-up weld layer may be applied in the roll axial direction or in the circumferential direction of the roll.

また、本実施形態では、第2の肉盛り溶接層14上に溶射層16を形成する。溶射材としては、炭化タングステン系サーメット材又は硼化タングステン系サーメット材が好ましく、具体的には、WC−12Co、WC−17Co、WB−30%CoCrなどが挙げられる。炭化タングステン系サーメット又は硼化タングステン系サーメットの溶射層は非常に高い硬度(HRC68以上)と高い耐食性を有するが、金属基材上へ直接溶射施工すると、当該溶射層に割れが発生しやすい。しかし、本実施形態では、溶射層16の下に、炭化タングステン粒子を一度溶解し、析出することで硬さが均一となった第2の肉盛り溶接層14があるため、溶射層16に割れが発生せず、ロール軸部材の寿命を大幅に延ばすことができる。   In the present embodiment, the thermal spray layer 16 is formed on the second build-up weld layer 14. As the thermal spray material, a tungsten carbide cermet material or a tungsten boride cermet material is preferable, and specific examples include WC-12Co, WC-17Co, and WB-30% CoCr. The sprayed layer of tungsten carbide cermet or tungsten boride cermet has a very high hardness (HRC 68 or higher) and high corrosion resistance, but when directly sprayed onto a metal substrate, the sprayed layer tends to crack. However, in the present embodiment, since there is the second build-up weld layer 14 in which the hardness is made uniform by dissolving and depositing the tungsten carbide particles once under the thermal spray layer 16, the thermal spray layer 16 is cracked. Does not occur, and the life of the roll shaft member can be greatly extended.

第1の肉盛り溶接層12の厚さ、第2の肉盛り溶接層14の厚さは特に限定されないが、それぞれ1〜2mm、2〜4mm程度とすることができる。また、溶射皮膜16の厚さも特に限定されないが、50〜200μm程度とすることができる。   Although the thickness of the 1st build-up weld layer 12 and the thickness of the 2nd build-up weld layer 14 are not specifically limited, It can be about 1-2 mm and 2-4 mm, respectively. Further, the thickness of the thermal spray coating 16 is not particularly limited, but can be about 50 to 200 μm.

本実施形態のロール軸部材100を溶融金属めっき浴中で用いて、溶融金属めっき鋼板を製造すれば、当該部材が長寿命であることから、長期の安定生産が可能である。   If the roll shaft member 100 of the present embodiment is used in a molten metal plating bath to produce a molten metal plated steel sheet, the member has a long life, and thus long-term stable production is possible.

以下に、本発明の発明例及び比較例を記載する。   The invention examples and comparative examples of the present invention will be described below.

(発明例1)
スリーブ基材(SUS316L鋼)の外周上に、コバルト基合金(ステライト合金)を溶接材として、PTA法で周方向に肉盛り溶接を行い、基材表面に1mm厚の第1の肉盛り溶接層を形成した。プラズマアーク電流は150〜180A、プラズマアーク電圧は22〜26V、送り速度は9〜13cpm、パス間温度は150〜200℃とした。肉盛り溶接(周方向)は、表面全体が施工されるように、ロール軸方向に徐々にずらしながら施工した。
(Invention Example 1)
On the outer periphery of the sleeve base material (SUS316L steel), a weld welding is performed in the circumferential direction by a PTA method using a cobalt-based alloy (Stellite alloy) as a welding material, and a first build-up weld layer having a thickness of 1 mm is formed on the surface of the base material. Formed. The plasma arc current was 150 to 180 A, the plasma arc voltage was 22 to 26 V, the feed rate was 9 to 13 cpm, and the interpass temperature was 150 to 200 ° C. Overlay welding (circumferential direction) was applied while gradually shifting in the roll axis direction so that the entire surface was applied.

続いて、第1の肉盛り溶接層の外周上に、炭化タングステン粒子を35質量%含むコバルト基合金(トリバロイ合金)を溶接材として、PTA法でロール軸方向に肉盛り溶接を行い、第1の肉盛り溶接層の表面に2mm厚の第2の肉盛り溶接層を形成した。プラズマアーク電流は130〜170A、プラズマアーク電圧は22〜26V、送り速度は12〜16cpm、パス間温度は600〜700℃とした。炭化タングステン粒子は、粒径45〜150μm(平均粒径約100μm)のものを使用した。肉盛り溶接(ロール軸方向)は、表面全体が施工されるように、周方向に徐々にずらしながら施工し、かつ、それを2周行った。   Subsequently, on the outer periphery of the first build-up weld layer, build-up welding is performed in the roll axis direction by the PTA method using a cobalt-based alloy (Trivalloy alloy) containing 35% by mass of tungsten carbide particles as a welding material. A second build-up weld layer having a thickness of 2 mm was formed on the surface of the build-up weld layer. The plasma arc current was 130 to 170 A, the plasma arc voltage was 22 to 26 V, the feed rate was 12 to 16 cpm, and the interpass temperature was 600 to 700 ° C. Tungsten carbide particles having a particle size of 45 to 150 μm (average particle size of about 100 μm) were used. Overlay welding (in the roll axis direction) was applied while gradually shifting in the circumferential direction so that the entire surface was applied, and was performed twice.

第1の肉盛り溶接層の硬さは、HRC38であり、第2の肉盛り溶接層の硬さは、HRC49であった。また、第2の肉盛り溶接層の断面をSEMで観察したところ、複数の炭化タングステン粒子のうち少なくとも一部の粒子が、前記コバルト基合金中に一度溶解し、その後析出したものであることが確認された。SEM写真を図6に示す。   The hardness of the first build-up weld layer was HRC38, and the hardness of the second build-up weld layer was HRC49. Further, when the cross section of the second build-up weld layer was observed with an SEM, it was found that at least some of the plurality of tungsten carbide particles were once dissolved in the cobalt-based alloy and then precipitated. confirmed. An SEM photograph is shown in FIG.

(比較例1)
発明例1と同様に第1の肉盛り溶接層を形成し、さらに発明例1と同様の溶接材を用いて周方向の肉盛り溶接を1周だけ施工して第2の肉盛り溶接層を形成した。第2の肉盛り溶接層の断面をSEMで観察したところ、前記コバルト基合金中に一度溶解し、析出したと思われる炭化タングステン粒子は確認されなかった。
(Comparative Example 1)
The first build-up weld layer is formed in the same manner as in Invention Example 1, and the build-up weld layer in the circumferential direction is applied only once by using the same welding material as in Invention Example 1, and the second build-up weld layer is formed. Formed. When the cross section of the second build-up weld layer was observed with an SEM, tungsten carbide particles that were once dissolved and precipitated in the cobalt-based alloy were not confirmed.

(比較例2)
発明例1と同様に第1の肉盛り溶接層を形成し、さらに発明例1と同様の溶接材を用いてロール軸方向の肉盛り溶接を1周だけ施工して第2の肉盛り溶接層を形成した。第2の肉盛り溶接層の断面をSEMで観察したところ、前記コバルト基合金中に一度溶解し、析出したと思われる炭化タングステン粒子は確認されなかった。
(Comparative Example 2)
The first build-up weld layer is formed in the same manner as in Invention Example 1, and the build-up welding in the roll axis direction is applied only once by using the same welding material as in Invention Example 1. Formed. When the cross section of the second build-up weld layer was observed with an SEM, tungsten carbide particles that were once dissolved and precipitated in the cobalt-based alloy were not confirmed.

(発明例2)
発明例1と同様に第1の肉盛り溶接層及び第2の盛り溶接層を形成し、さらに第2の肉盛り溶接層の外周上に、WC−17Coサーメットを溶射材として大気圧プラズマ溶射を行い、第2の肉盛り溶接層の表面に100μm厚の溶射層を形成した。WC−17Coサーメット溶射層の硬さは、HRC70であった。また、第2の肉盛り溶接層の断面をSEMで観察したところ、複数の炭化タングステン粒子のうち少なくとも一部の粒子が、前記コバルト基合金中に一度溶解し、その後析出したものであることが確認された。
(Invention Example 2)
The first build-up weld layer and the second build-up weld layer are formed in the same manner as in Invention Example 1, and atmospheric pressure plasma spraying is performed on the outer periphery of the second build-up weld layer using WC-17Co cermet as a spraying material. A 100 μm thick sprayed layer was formed on the surface of the second build-up weld layer. The hardness of the WC-17Co cermet sprayed layer was HRC70. Further, when the cross section of the second build-up weld layer was observed with an SEM, it was found that at least some of the plurality of tungsten carbide particles were once dissolved in the cobalt-based alloy and then precipitated. confirmed.

(比較例3)
発明例1と同様に第1の肉盛り溶接層を形成し、さらに発明例1と同様の溶接材を用いてロール軸方向の肉盛り溶接を1周だけ施工して第2の肉盛り溶接層を形成した。続いて、発明例2と同様の方法で溶射を行った。しかし、溶射層の表面が割れて、使用可能なものが作製できなかった。第2の肉盛り溶接層の断面をSEMで観察したところ、前記コバルト基合金中に一度溶解し、析出したと思われる炭化タングステン粒子は確認されなかった。
(Comparative Example 3)
The first build-up weld layer is formed in the same manner as in Invention Example 1, and the build-up welding in the roll axis direction is applied only once by using the same welding material as in Invention Example 1. Formed. Subsequently, thermal spraying was performed in the same manner as in Invention Example 2. However, the surface of the sprayed layer was cracked and could not be used. When the cross section of the second build-up weld layer was observed with an SEM, tungsten carbide particles that were once dissolved and precipitated in the cobalt-based alloy were not confirmed.

(ロール軸部材の寿命の評価方法)
各発明例及び比較例で作製したロール軸部材を、図4に示す溶融亜鉛めっき設備のシンクロールの端部に取り付け、溶融亜鉛めっきラインで30日間使用した。その後、ロール軸部材の摩耗及び割れの目視確認を行った。
(Evaluation method of life of roll shaft member)
The roll shaft member produced in each invention example and comparative example was attached to the end of the sink roll of the hot dip galvanizing facility shown in FIG. 4 and used for 30 days in the hot dip galvanizing line. Thereafter, the roll shaft member was visually checked for wear and cracks.

(評価結果)
発明例1のロール軸部材には、磨耗は見られたが割れは発生しなかったので、少なくとも30日の寿命があることが確認された。一方、比較例1及び比較例2のロール軸部材には使用後割れが発生しており、30日を越える使用は困難であることが分かった。発明例2のロール軸部材には磨耗及び割れの発生がないことから30日以上に寿命を延ばせることが確認できた。
(Evaluation results)
It was confirmed that the roll shaft member of Invention Example 1 had a lifetime of at least 30 days because no abrasion occurred but no cracks occurred. On the other hand, the roll shaft members of Comparative Example 1 and Comparative Example 2 were cracked after use, and it was found difficult to use over 30 days. It was confirmed that the roll shaft member of Invention Example 2 could extend its life to 30 days or more since there was no wear or cracking.

本発明の溶融金属めっき浴中ロール軸部材は、実機使用時に軸受から強い摺動抵抗を受けても摩耗や割れの発生を抑制できるため、ロール軸部材が長寿命化し、溶融金属めっき鋼板の安定生産を行うことができる。   The roll shaft member in the molten metal plating bath of the present invention can suppress the occurrence of wear and cracks even when subjected to strong sliding resistance from the bearing when using the actual machine. Production can be done.

100 ロール軸部材
10 金属基材
12 第1の肉盛り溶接層
14 第2の肉盛り溶接層
16 溶射層
20A 炭化タングステン粒子
20B 一度溶解後析出した炭化タングステン粒子
30 スナウト
32 ポット
34 溶融金属浴
36 シンクロール
38 サポートロール
40 スリーブ
42 軸受
44 ハンガー
C ロール軸方向
P 鋼帯
DESCRIPTION OF SYMBOLS 100 Roll shaft member 10 Metal base material 12 1st build-up weld layer 14 2nd build-up weld layer 16 Thermal spray layer 20A Tungsten carbide particle 20B Tungsten carbide particle which precipitated once melt | dissolved 30 Snout 32 Pot 34 Molten metal bath 36 Sink Roll 38 Support roll 40 Sleeve 42 Bearing 44 Hanger C Roll axial direction P Steel strip

Claims (14)

金属基材と、
該金属基材上に形成された、コバルト基合金からなる第1の肉盛り溶接層と、
該第1の肉盛り溶接層上に形成された、コバルト基合金からなる第2の肉盛り溶接層と、
を有する溶融金属めっき浴中ロール軸部材であって、
前記第2の肉盛り溶接層は、前記第1の肉盛り溶接層よりも高い硬度を有し、
前記第2の肉盛り溶接層には複数の炭化タングステン粒子が含まれ、
前記第2の肉盛り溶接層に含まれる複数の炭化タングステン粒子のうち少なくとも一部の粒子は、前記第2の肉盛り層を形成する溶接材に添加された複数の炭化タングステン粒子のうち少なくとも一部の粒子の少なくとも一部分が前記コバルト基合金中に一度溶解し、その後析出したものであることを特徴とする溶融金属めっき浴中ロール軸部材。
A metal substrate;
A first build-up weld layer made of a cobalt-based alloy formed on the metal substrate;
A second build-up weld layer made of a cobalt-based alloy formed on the first build-up weld layer;
A roll shaft member in a molten metal plating bath having:
The second build-up weld layer has a higher hardness than the first build-up weld layer,
The second build-up weld layer includes a plurality of tungsten carbide particles,
At least some of the plurality of tungsten carbide particles included in the second build-up weld layer are at least one of the plurality of tungsten carbide particles added to the welding material forming the second build-up layer. A roll shaft member in a molten metal plating bath, wherein at least a part of the particles of the portion is once dissolved in the cobalt-based alloy and then precipitated.
前記第1の肉盛り溶接層がHRC40未満の硬度を有し、前記第2の肉盛り溶接層がHRC40以上の硬度を有する、請求項1に記載の溶融金属めっき浴中ロール軸部材。   The roll shaft member in a molten metal plating bath according to claim 1, wherein the first build-up weld layer has a hardness of less than HRC40, and the second build-up weld layer has a hardness of HRC40 or higher. 前記第2の肉盛り溶接層中の炭化タングステン粒子の含有量が50質量%以下である請求項1又は2に記載の溶融金属めっき浴中ロール軸部材。   The roll shaft member in a molten metal plating bath according to claim 1 or 2, wherein the content of tungsten carbide particles in the second build-up weld layer is 50% by mass or less. 前記第2の肉盛り溶接層がロール軸方向に施工されたものである請求項1〜3のいずれか一項に記載の溶融金属めっき浴中ロール軸部材。   The roll shaft member in the molten metal plating bath according to any one of claims 1 to 3, wherein the second build-up weld layer is constructed in the roll axis direction. 前記第2の肉盛り溶接層上に、前記第2の肉盛り層よりも硬度が高い溶射層を有する請求項1〜4のいずれか一項に記載の溶融金属めっき浴中ロール軸部材。   The roll shaft member in the molten metal plating bath according to any one of claims 1 to 4, further comprising a thermal spray layer having a hardness higher than that of the second build-up layer on the second build-up weld layer. 前記溶射層は、炭化タングステン系サーメット材又は硼化タングステン系サーメット材からなる請求項5に記載の溶融金属めっき浴中ロール軸部材。   6. The roll shaft member in a molten metal plating bath according to claim 5, wherein the sprayed layer is made of a tungsten carbide cermet material or a tungsten boride cermet material. 金属基材上に、コバルト基合金からなる溶接材を肉盛り溶接し、第1の肉盛り層を形成する第一工程と、
前記第1の肉盛り層上に、コバルト基合金からなり、かつ複数の炭化タングステン粒子を含む溶接材を肉盛り溶接し、第2の肉盛り層を形成する第二工程と、
を有する溶融金属めっき浴中ロール軸部材の製造方法であって、
前記第二工程において、複数の炭化タングステン粒子のうち少なくとも一部の粒子は、その少なくとも一部分が前記コバルト基合金中に一度溶解し、その後析出させられる
ことを特徴とする溶融金属めっき浴中ロール軸部材の製造方法。
A first step of depositing a welding material made of a cobalt-based alloy on a metal base material to form a first overlay layer;
On the first build-up layer, a second step of build-up welding a welding material made of a cobalt-based alloy and containing a plurality of tungsten carbide particles to form a second build-up layer;
A method for producing a roll shaft member in a molten metal plating bath having
In the second step, at least a part of the plurality of tungsten carbide particles, at least a part of which is once dissolved in the cobalt-based alloy and then precipitated, and then a roll shaft in a molten metal plating bath, Manufacturing method of member.
前記第二工程において、肉盛り溶接は2周以上施工する請求項7に記載の溶融金属めっき浴中ロール軸部材の製造方法。   In the said 2nd process, build-up welding is a manufacturing method of the roll shaft member in the hot-dip metal-plating bath of Claim 7 which constructs more than 2 rounds. 前記第二工程において、肉盛り溶接はロール軸方向に施工する請求項7又は8に記載の溶融金属めっき浴中ロール軸部材の製造方法。   The method for producing a roll shaft member in a molten metal plating bath according to claim 7 or 8, wherein build-up welding is performed in the roll axis direction in the second step. 前記第1の肉盛り溶接層がHRC40未満の硬度を有し、前記第2の肉盛り溶接層がHRC40以上の硬度を有する、請求項7〜9のいずれか一項に記載の溶融金属めっき浴中ロール軸部材の製造方法。   The molten metal plating bath according to any one of claims 7 to 9, wherein the first build-up weld layer has a hardness of less than HRC40, and the second build-up weld layer has a hardness of HRC40 or higher. Manufacturing method of middle roll shaft member. 前記第2の肉盛り溶接層中の炭化タングステン粒子の含有量が50質量%以下である、請求項7〜10のいずれか一項に記載の溶融金属めっき浴中ロール軸部材の製造方法。   The manufacturing method of the roll shaft member in the molten metal plating bath as described in any one of Claims 7-10 whose content of the tungsten carbide particle in a said 2nd build-up weld layer is 50 mass% or less. 前記第二工程後、前記第2の肉盛り溶接層上に、前記第2の肉盛り層よりも硬度が高い溶射層を形成する第三工程をさらに有する請求項7〜11のいずれか一項に記載の溶融金属めっき浴中ロール軸部材の製造方法。   12. The method according to claim 7, further comprising a third step of forming a sprayed layer having a hardness higher than that of the second build-up layer on the second build-up weld layer after the second step. A method for producing a roll shaft member in a molten metal plating bath according to claim 1. 前記第三工程における溶射材は、炭化タングステン系サーメット又は硼化タングステン系サーメットである請求項12に記載の溶融金属めっき浴中ロール軸部材の製造方法。   The method for producing a roll shaft member in a molten metal plating bath according to claim 12, wherein the thermal spray material in the third step is a tungsten carbide cermet or a tungsten boride cermet. 請求項1〜6のいずれか一項に記載の溶融金属めっき浴中ロール軸部材を溶融金属めっき浴中で用いて、溶融金属めっき鋼板を製造することを特徴とする溶融金属めっき鋼板の製造方法。   A method for producing a molten metal plated steel sheet, comprising producing a molten metal plated steel sheet using the roll shaft member in the molten metal plating bath according to any one of claims 1 to 6 in the molten metal plating bath. .
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Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61262467A (en) * 1985-05-17 1986-11-20 Hitachi Metals Ltd Welding method for fine particle build up
JPS63101012A (en) * 1986-10-15 1988-05-06 Kubota Ltd Production of build-up sleeve for roll for rolling steel bar
JPS6425962A (en) * 1987-07-20 1989-01-27 Tokushu Denkyoku Kk Hearth roller
JPH0433795A (en) * 1990-05-30 1992-02-05 Fuji Oozx Kk Composite hard facing by welding material and engine valve and valve seat welded therewith
JPH0433796A (en) * 1990-05-30 1992-02-05 Fuji Oozx Kk Composite hard facing by welding material, engine valve and valve seat welded therewith
JPH0446674A (en) * 1990-06-13 1992-02-17 Fuji Oozx Kk Method for cladding by welding with build-up material to engine valve or the like
JPH0471781A (en) * 1990-07-10 1992-03-06 Fuji Oozx Kk Method for cladding by welding with build-up material on engine valve or the like
JPH0484670A (en) * 1990-07-26 1992-03-17 Fuji Oozx Kk Method for build-up welding with build-up material on engine valve or the like
JPH0484671A (en) * 1990-07-26 1992-03-17 Fuji Oozx Kk Method for cladding by welding with build-up material on engine valve or the like
JPH0569155U (en) * 1992-02-28 1993-09-17 住友金属工業株式会社 Roller bearing device in molten metal plating bath
JPH0813116A (en) * 1994-06-29 1996-01-16 Ofic Co Surface treatment for metallic parts
JPH08325698A (en) * 1995-05-26 1996-12-10 Nittetsu Hard Kk Coating material for roll shaft member in continuous hot-dip metal plating bath
JPH1180917A (en) * 1997-09-05 1999-03-26 Nippon Steel Hardfacing Co Ltd Immersion member for molten metal bath, excellent in resistance to corrosion and wear
JP2000033512A (en) * 1998-07-16 2000-02-02 Toshiba Mach Co Ltd Cemented carbide tool and surface treatment method therefor
JP2003105511A (en) * 2001-09-28 2003-04-09 Kawatetsu Galvanizing Co Ltd In-plating bath split bearing
JP2003277861A (en) * 2002-03-27 2003-10-02 Mitsubishi Heavy Ind Ltd Rotor for rubber kneading machine
JP2005305449A (en) * 2004-04-16 2005-11-04 Sumitomo Metal Ind Ltd Tool for hot working
WO2007114524A1 (en) * 2006-03-30 2007-10-11 Komatsu Ltd. Wear-resistant particle and wear-resistant structural member

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61262467A (en) * 1985-05-17 1986-11-20 Hitachi Metals Ltd Welding method for fine particle build up
JPS63101012A (en) * 1986-10-15 1988-05-06 Kubota Ltd Production of build-up sleeve for roll for rolling steel bar
JPS6425962A (en) * 1987-07-20 1989-01-27 Tokushu Denkyoku Kk Hearth roller
JPH0433795A (en) * 1990-05-30 1992-02-05 Fuji Oozx Kk Composite hard facing by welding material and engine valve and valve seat welded therewith
JPH0433796A (en) * 1990-05-30 1992-02-05 Fuji Oozx Kk Composite hard facing by welding material, engine valve and valve seat welded therewith
JPH0446674A (en) * 1990-06-13 1992-02-17 Fuji Oozx Kk Method for cladding by welding with build-up material to engine valve or the like
JPH0471781A (en) * 1990-07-10 1992-03-06 Fuji Oozx Kk Method for cladding by welding with build-up material on engine valve or the like
JPH0484670A (en) * 1990-07-26 1992-03-17 Fuji Oozx Kk Method for build-up welding with build-up material on engine valve or the like
JPH0484671A (en) * 1990-07-26 1992-03-17 Fuji Oozx Kk Method for cladding by welding with build-up material on engine valve or the like
JPH0569155U (en) * 1992-02-28 1993-09-17 住友金属工業株式会社 Roller bearing device in molten metal plating bath
JPH0813116A (en) * 1994-06-29 1996-01-16 Ofic Co Surface treatment for metallic parts
JPH08325698A (en) * 1995-05-26 1996-12-10 Nittetsu Hard Kk Coating material for roll shaft member in continuous hot-dip metal plating bath
JPH1180917A (en) * 1997-09-05 1999-03-26 Nippon Steel Hardfacing Co Ltd Immersion member for molten metal bath, excellent in resistance to corrosion and wear
JP2000033512A (en) * 1998-07-16 2000-02-02 Toshiba Mach Co Ltd Cemented carbide tool and surface treatment method therefor
JP2003105511A (en) * 2001-09-28 2003-04-09 Kawatetsu Galvanizing Co Ltd In-plating bath split bearing
JP2003277861A (en) * 2002-03-27 2003-10-02 Mitsubishi Heavy Ind Ltd Rotor for rubber kneading machine
JP2005305449A (en) * 2004-04-16 2005-11-04 Sumitomo Metal Ind Ltd Tool for hot working
WO2007114524A1 (en) * 2006-03-30 2007-10-11 Komatsu Ltd. Wear-resistant particle and wear-resistant structural member
US20090019783A1 (en) * 2006-03-30 2009-01-22 Masaharu Amano Wear Resisting Particle and Wear Resisting Structure Member

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