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JP2017026701A5 - - Google Patents

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Publication number
JP2017026701A5
JP2017026701A5 JP2015142927A JP2015142927A JP2017026701A5 JP 2017026701 A5 JP2017026701 A5 JP 2017026701A5 JP 2015142927 A JP2015142927 A JP 2015142927A JP 2015142927 A JP2015142927 A JP 2015142927A JP 2017026701 A5 JP2017026701 A5 JP 2017026701A5
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Japan
Prior art keywords
phase shift
film
layer
shift film
reflectance
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JP2015142927A
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Japanese (ja)
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JP2017026701A (en
JP6352224B2 (en
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Priority claimed from JP2015142927A external-priority patent/JP6352224B2/en
Priority to JP2015142927A priority Critical patent/JP6352224B2/en
Priority to TW107135068A priority patent/TWI677437B/en
Priority to TW105119339A priority patent/TWI641493B/en
Priority to KR1020160080783A priority patent/KR101935448B1/en
Priority to CN201610520850.3A priority patent/CN106353963B/en
Publication of JP2017026701A publication Critical patent/JP2017026701A/en
Publication of JP2017026701A5 publication Critical patent/JP2017026701A5/ja
Publication of JP6352224B2 publication Critical patent/JP6352224B2/en
Application granted granted Critical
Priority to KR1020180172159A priority patent/KR102003650B1/en
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Description

(構成8)
構成7に記載の製造方法によって製造された位相シフトマスクを露光装置のマスクステージに載置する工程と、
前記位相シフトマスクに露光光を照射して、表示装置基板上に形成されたレジスト膜に前記位相シフト膜パターンを転写する工程と
を有することを特徴とする表示装置の製造方法。

(Configuration 8)
Placing the phase shift mask manufactured by the manufacturing method according to Configuration 7 on a mask stage of an exposure apparatus;
Irradiating the phase shift mask with exposure light, and transferring the phase shift film pattern to a resist film formed on the display device substrate.

Claims (9)

透明基板上にクロム系材料からなる位相シフト膜を備える位相シフトマスクブランクであって、
前記位相シフト膜は、主に露光光に対する透過率と位相差とを調整する機能を有する位相シフト層と、該位相シフト層の上側に配置され、前記位相シフト膜側より入射される光に対する反射率を低減させる機能を有する反射率低減層と、前記位相シフト層と前記反射率低減層との間に配置され、350nm〜436nmの波長域において、前記反射率低減層の消衰係数よりも高い消衰係数を有するメタル層とを有し、
前記位相シフト層、前記メタル層および前記反射率低減層の積層構造により、露光光に対する前記位相シフト膜の透過率と位相差とが所定の光学特性を有し、かつ、前記位相シフト膜側より入射される光に対する前記位相シフト膜の膜面反射率が、350nm〜436nmの波長域において10%以下であることを特徴とする位相シフトマスクブランク。
A phase shift mask blank comprising a phase shift film made of a chromium-based material on a transparent substrate,
The phase shift film is disposed mainly on the upper side of the phase shift layer and has a function of adjusting the transmittance and phase difference with respect to exposure light, and reflects light incident from the phase shift film side. A reflectance reduction layer having a function of reducing the reflectance, and is disposed between the phase shift layer and the reflectance reduction layer, and is higher than the extinction coefficient of the reflectance reduction layer in a wavelength region of 350 nm to 436 nm. A metal layer having an extinction coefficient,
Due to the laminated structure of the phase shift layer, the metal layer, and the reflectance reduction layer, the transmittance and phase difference of the phase shift film with respect to exposure light have predetermined optical characteristics, and from the phase shift film side A phase shift mask blank, wherein a film surface reflectance of the phase shift film with respect to incident light is 10% or less in a wavelength region of 350 nm to 436 nm.
透明基板上にクロム系材料からなる位相シフト膜を備える位相シフトマスクブランクであって、
前記位相シフト膜は、主に露光光に対する透過率と位相差とを調整する機能を有する位相シフト層と、該位相シフト層の上側に配置され、前記位相シフト膜側より入射される光に対する反射率を低減させる機能を有する反射率低減層と、前記位相シフト層と前記反射率低減層との間に配置され、前記反射率低減層のクロム含有率よりも高いクロム含有率を有するメタル層とを有し、
前記位相シフト層、前記メタル層および前記反射率低減層の積層構造により、露光光に対する前記位相シフト膜の透過率と位相差とが所定の光学特性を有し、かつ、前記位相シフト膜側より入射される光に対する前記位相シフト膜の膜面反射率が、350nm〜436nmの波長域において10%以下であることを特徴とする位相シフトマスクブランク。
A phase shift mask blank comprising a phase shift film made of a chromium-based material on a transparent substrate,
The phase shift film is disposed mainly on the upper side of the phase shift layer and has a function of adjusting the transmittance and phase difference with respect to exposure light, and reflects light incident from the phase shift film side. A reflectance reduction layer having a function of reducing the reflectance, and a metal layer disposed between the phase shift layer and the reflectance reduction layer and having a chromium content higher than the chromium content of the reflectance reduction layer; Have
Due to the laminated structure of the phase shift layer, the metal layer, and the reflectance reduction layer, the transmittance and phase difference of the phase shift film with respect to exposure light have predetermined optical characteristics, and from the phase shift film side A phase shift mask blank, wherein a film surface reflectance of the phase shift film with respect to incident light is 10% or less in a wavelength region of 350 nm to 436 nm.
前記位相シフト膜の膜面反射率の変動幅が、350nm〜436nmの波長域において5%以下であることを特徴とする請求項1又は2に記載の位相シフトマスクブランク。   The phase shift mask blank according to claim 1 or 2, wherein a fluctuation range of the film surface reflectance of the phase shift film is 5% or less in a wavelength region of 350 nm to 436 nm. 前記位相シフト膜の膜面反射率が、313nm〜436nmの波長域において13%以下であることを特徴とする請求項1又は2に記載の位相シフトマスクブランク。   The phase shift mask blank according to claim 1 or 2, wherein a film surface reflectance of the phase shift film is 13% or less in a wavelength range of 313 nm to 436 nm. 前記位相シフト膜の膜面反射率の変動幅が、313nm〜436nmの波長域において10%以下であることを特徴とする請求項4に記載の位相シフトマスクブランク。   5. The phase shift mask blank according to claim 4, wherein the fluctuation range of the film surface reflectance of the phase shift film is 10% or less in a wavelength range of 313 nm to 436 nm. 前記透明基板と前記位相シフト膜との間に、遮光性膜パターンを備えることを特徴とする請求項1乃至5のいずれか一項に記載の位相シフトマスクブランク。   The phase shift mask blank according to any one of claims 1 to 5, further comprising a light-shielding film pattern between the transparent substrate and the phase shift film. 請求項1乃至6のいずれか一項に記載の位相シフトマスクブランクの前記位相シフト膜上に、350nm〜436nmの波長域から選択されるいずれかの波長を有するレーザー光を用いた描画処理、および現像処理により、レジスト膜パターンを形成する工程と、
該レジスト膜パターンをマスクにして前記位相シフト膜をエッチングして、前記透明基板上に位相シフト膜パターンを形成する工程と
を有することを特徴とする位相シフトマスクの製造方法。
Drawing process using a laser beam having any wavelength selected from a wavelength range of 350 nm to 436 nm on the phase shift film of the phase shift mask blank according to claim 1, and A step of forming a resist film pattern by development processing;
Etching the phase shift film using the resist film pattern as a mask to form a phase shift film pattern on the transparent substrate.
請求項7に記載の製造方法によって製造された位相シフトマスクを露光装置のマスクステージに載置する工程と、
前記位相シフトマスクに露光光を照射して、表示装置基板上に形成されたレジスト膜に前記位相シフト膜パターンを転写する工程と
を有することを特徴とする表示装置の製造方法。
Placing the phase shift mask manufactured by the manufacturing method according to claim 7 on a mask stage of an exposure apparatus;
Irradiating the phase shift mask with exposure light, and transferring the phase shift film pattern to a resist film formed on the display device substrate.
前記露光光は、313nm〜436nmの波長域から選択される複数の波長の光を含む複合光であることを特徴とする請求項8に記載の表示装置の製造方法。   9. The method for manufacturing a display device according to claim 8, wherein the exposure light is composite light including light having a plurality of wavelengths selected from a wavelength range of 313 nm to 436 nm.
JP2015142927A 2015-07-17 2015-07-17 Phase shift mask blank, method of manufacturing phase shift mask using the same, and method of manufacturing display device Active JP6352224B2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2015142927A JP6352224B2 (en) 2015-07-17 2015-07-17 Phase shift mask blank, method of manufacturing phase shift mask using the same, and method of manufacturing display device
TW107135068A TWI677437B (en) 2015-07-17 2016-06-20 Phase shift mask base, manufacturing method of phase shift mask, and display device manufacturing method
TW105119339A TWI641493B (en) 2015-07-17 2016-06-20 Phase shift mask base, manufacturing method of phase shift mask, and display device manufacturing method
KR1020160080783A KR101935448B1 (en) 2015-07-17 2016-06-28 A phase shift mask blank and a method for manufacturing phase shift mask using the same, and a method for manufacturing the display device
CN201610520850.3A CN106353963B (en) 2015-07-17 2016-07-05 Phase shift mask semi-finished product, phase shift mask manufacturing method, and display device manufacturing method
KR1020180172159A KR102003650B1 (en) 2015-07-17 2018-12-28 A phase shift mask blank and a method for manufacturing phase shift mask using the same, and a method for manufacturing the display device

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JP2015142927A JP6352224B2 (en) 2015-07-17 2015-07-17 Phase shift mask blank, method of manufacturing phase shift mask using the same, and method of manufacturing display device

Related Child Applications (1)

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JP2017026701A5 true JP2017026701A5 (en) 2017-06-15
JP6352224B2 JP6352224B2 (en) 2018-07-04

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KR (2) KR101935448B1 (en)
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