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JP2016222254A - Self-standing pressure-resistant bottle - Google Patents

Self-standing pressure-resistant bottle Download PDF

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JP2016222254A
JP2016222254A JP2015107225A JP2015107225A JP2016222254A JP 2016222254 A JP2016222254 A JP 2016222254A JP 2015107225 A JP2015107225 A JP 2015107225A JP 2015107225 A JP2015107225 A JP 2015107225A JP 2016222254 A JP2016222254 A JP 2016222254A
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bottle
self
supporting pressure
leg
resistant bottle
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JP6575011B2 (en
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久美子 長谷川
Kumiko Hasegawa
久美子 長谷川
平石 和弘
Kazuhiro Hiraishi
和弘 平石
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Mitsubishi Plastics Inc
Kirin Co Ltd
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Mitsubishi Plastics Inc
Kirin Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a self-standing pressure-resistant bottle which has a bottom assuming a shape different from a petaloid shape, the self-standing property of which is not deteriorated, and which has sufficient alkali-resistant performance.SOLUTION: A bottom 5 of a self-standing pressure-resistant bottle 1 comprising a plug part 2, a shoulder part 3, a trunk part 4 and the bottom 5 assumes a shape having a plane part 51 arranged in its central part, and assumes a shape in which a plurality of spherical legs 52 protruding downward are circumferentially arranged around the plane part 51.SELECTED DRAWING: Figure 1

Description

本発明は、ビールなどの炭酸ガスが溶け込んだ飲料を充填し包装するのに好適な合成樹脂製の自立性耐圧ボトルに関する。   The present invention relates to a self-supporting pressure-resistant bottle made of a synthetic resin suitable for filling and packaging a beverage in which carbon dioxide gas such as beer is dissolved.

炭酸ガスが含有された清涼飲料水などを充填し包装する自立型の容器として、ポリエチレンテレフタレートなどのポリエステル系樹脂からなる合成樹脂製の耐圧ボトルが用いられている。   As a self-supporting container for filling and packaging a soft drink containing carbon dioxide gas, a pressure-resistant bottle made of a synthetic resin made of a polyester-based resin such as polyethylene terephthalate is used.

従来、コンビニエンスストアなどの店頭に並べて販売される内容量500ml程度のガス含有清涼飲料水用の耐圧ボトルとしては、例えば図10に示されるように、下向き半球形状の底面101aの外周面に下方へ突出した複数の脚部102を放射状に配置して、底部101をペタロイド形状に設けた構成のものが広く使われている(例えば特許文献1参照)。   Conventionally, as a pressure-resistant bottle for gas-containing soft drinks with an internal volume of about 500 ml sold in a store such as a convenience store, as shown in FIG. 10, for example, downward on the outer peripheral surface of the bottom surface 101a having a downward hemisphere shape. The thing of the structure which has arrange | positioned the several leg part 102 which protruded radially and provided the bottom part 101 in the petaloid shape is widely used (for example, refer patent document 1).

また、10Lを超える大容量の飲料水などを充填して貯蔵したり運搬したりするための自立型の耐圧ボトルとして、例えば図11に示されるように、下向き半球状の輪郭を呈する底部111の中央部に下方突出部112を設け、この下方突出部112の周りに、上方へ凹んだ谷部113を挟んで複数の中空卵形の脚形成部114を、互いに等間隔を開けて設けた構成のものが知られている(例えば特許文献2参照)。   Moreover, as a self-supporting pressure-resistant bottle for filling and storing or transporting a large volume of drinking water exceeding 10 L, for example, as shown in FIG. 11, the bottom 111 having a downward hemispherical outline is shown. A structure in which a lower projecting portion 112 is provided at the center, and a plurality of hollow egg-shaped leg forming portions 114 are provided at equal intervals around the lower projecting portion 112 with a valley 113 recessed upward. Are known (for example, see Patent Document 2).

特許平9−315420号公報Japanese Patent No. 9-315420 特開2013−523549号公報JP2013-523549A

前記図10に示された、底部101をペタロイド形状に設けた耐圧ボトル100は、良好な自立性と耐圧性を備え、また、ボトル全体が高い剛性を有するため、自動販売機による販売もされ、飲料を携行するための容器として好適といえる。   The pressure-resistant bottle 100 provided with the bottom 101 in the petaloid shape shown in FIG. 10 has a good self-standing property and pressure resistance, and since the entire bottle has high rigidity, it is also sold by a vending machine. It can be said that it is suitable as a container for carrying a drink.

このような清涼飲料水の包装に利用されている耐圧ボトル100は、携行がし難い大容量の飲料水の包装、例えば店頭で購入した後は家庭の冷蔵庫に入れて保存されることが多い、1Lの容量を超えるビールなどの包装にも使用することは可能であるが、その場合、ボトルが大型化するのに伴って、ボトルの成形に使用する樹脂の量が多くなって成形コストが嵩張り、また、ボトル自体も重くなって使い勝手が悪くなる。使用樹脂量を抑制して軽量化を図ったのでは、ボトル全体の厚みが薄くなり、必然的に底部101の脚部102の厚みも薄くなり、ペタロイド形状の底部101全体の強度が低下したり、しわが発生するなどの成形不良を引き起こしたりするという問題がある。   The pressure-resistant bottle 100 used for packaging of such soft drinks is often stored in a refrigerator at home after being purchased at a store, for example, a large-capacity drinking water package that is difficult to carry. Although it can be used for packaging beer and the like exceeding a capacity of 1 L, in that case, as the size of the bottle increases, the amount of resin used for molding the bottle increases and the molding cost increases. Tensions and the bottle itself become heavier and unusable. By reducing the amount of resin used and reducing weight, the thickness of the entire bottle is reduced, inevitably the thickness of the leg portion 102 of the bottom 101 is reduced, and the strength of the entire petaloid-shaped bottom 101 is reduced. There is a problem of causing molding defects such as wrinkles.

また、清涼飲料水の包装には底部がペタロイド形状のボトル、ビールの包装にはペタロイド形状とは異なる外観デザインのボトルというように、ボトルに充填される飲料の種類や内容量、その購買層などに応じて使用するボトルの外観デザインを異ならせれば、充填された飲料の購入を予定している購買者に対する視覚的訴求力を高めることができ、また、清涼飲料水と間違えてビールを購入するような購入間違いの発生を防止できてより好ましい。   Also, bottles with a petaloid shape at the bottom for soft drink packaging, and bottles with an external appearance design different from petaloid shape for beer packaging, such as the type and content of the beverage filled in the bottle, its purchasing layer, etc. Depending on the appearance of the bottles used, the visual appeal to buyers who plan to purchase filled beverages can be enhanced, and beer can be purchased by mistake with soft drinks. It is more preferable to prevent the occurrence of such purchase mistakes.

ペタロイド形状とは異なる形状の底部を備えた前記図11に示された耐圧ボトル110は、底部111の中央部の下方突出部112の周囲に谷部113を配置し、さらに谷部113に脚形成部114を連ならせて、底部111全体が上下に波打った凹凸形状を呈しているため、耐圧ボトル110への炭酸ガス充填時、とりわけ苛酷環境保管時に、底部111にクリープが生じて変形したり脚形成部114の変形が生じたりして、自立性が損なわれ易いという問題がある。
また、耐圧ボトル110の底部111の中央に下方突出部112が配置してあるため、耐圧ボトル110が飲料の充填ラインのコンベアで搬送される際に、下方突出部112がライン上のアルカリ溶液に浸水して割れが発生し易いという問題もある。
The pressure-resistant bottle 110 shown in FIG. 11 provided with a bottom having a shape different from the petaloid shape has a trough 113 disposed around a downward projecting portion 112 at the center of the bottom 111, and legs are formed on the trough 113. Since the bottom part 111 has an uneven shape that is waved up and down by connecting the parts 114, creeping occurs in the bottom part 111 when the pressure-resistant bottle 110 is filled with carbon dioxide gas, especially during storage in a harsh environment. There is a problem that the leg forming portion 114 is deformed and the independence is easily impaired.
Moreover, since the downward protrusion part 112 is arrange | positioned in the center of the bottom part 111 of the pressure bottle 110, when the pressure bottle 110 is conveyed with the conveyor of the drink filling line, the downward protrusion part 112 turns into the alkaline solution on a line. There is also a problem that cracks are likely to occur due to water immersion.

本発明は従来技術の有するこのような問題点に鑑み、ペタロイド形状とは異なる形状の底部を備えていて、自立性が損なわれず、且つ十分な耐アルカリ性能を有する、比較的大容量の炭酸ガス含有飲料を充填し包装するのに適した自立性耐圧ボトルを構成することを課題とする。   In view of such a problem of the prior art, the present invention has a relatively large capacity carbon dioxide gas that has a bottom portion different from a petaloid shape, does not impair self-supporting properties, and has sufficient alkali resistance. It is an object to constitute a self-supporting pressure-resistant bottle suitable for filling and packaging a contained beverage.

前記課題を解決するにあたり本発明は、口栓部と肩部と胴部と底部とを備えた自立性耐圧ボトル(以下、単に「ボトル」ともいう。)において、
前記底部が、その中央部に平面部が設けられ、この平面部の周囲に、下方へ突出した球状の脚部が複数設けられた構成を有することを特徴とする。
In solving the above-mentioned problems, the present invention provides a self-supporting pressure-resistant bottle (hereinafter, also simply referred to as “bottle”) provided with a plug portion, a shoulder portion, a trunk portion, and a bottom portion.
The bottom portion has a configuration in which a flat portion is provided at a central portion thereof, and a plurality of spherical leg portions protruding downward are provided around the flat portion.

これによれば、少ない樹脂材料で自立性及び耐圧性が良好な、比較的大容量の飲料を充填可能なボトルを形成することができる。ボトルの底部はその中央部分に平坦な面である平面部、その周囲に平面部よりも下方へ突出した複数の球状の脚部が配置され、ボトルは各脚部を接地して自立するので、飲料の充填ラインでボトルを搬送する際に、底部のアルカリ溶液に浸される部分の面積が極めて小さく、割れの発生が抑えられる。
なお、底部に設ける球状の脚部は、ボトルが安定して自立するように、平面部の周囲に少なくとも三つ以上を設け、各々ボトル底部からの下方への突出幅を適宜に設定して、各脚部の先端を机上などの水平な接地面に接地させた状態で平面部が水平となるように設けることが好ましい。
脚部は、ボトルの自立性が保持されるのであれば、平面部の周囲に適宜な態様、例えば平面部の片側に複数、他側に一つ又は複数の脚部を設ける態様で配置可能であるが、底部全体に対して脚部が偏って配置されていると、自立性が不安定となって倒れやすくなるとともに、脚部を含む底部全面で肉厚が不均一となって賦形性も悪くなり、変形しやすく耐圧性が低下する。よって、球状の脚部は、平面部の周囲であって、底部の投影面内におけるボトルに軸心Oを中心とした同一円周上に、複数の脚部が周方向に沿って、隣接した脚部との間隔が等間隔となるように配置することが好ましい。この場合、各脚部のボトル底部からの下方への突出幅を同じとすることで、ボトルを立たせた状態で平面部が水平となり、ボトルを安定して自立させることができる。
According to this, the bottle which can be filled with a comparatively large capacity | capacitance drink with favorable self-supporting property and pressure resistance with few resin materials can be formed. The bottom part of the bottle is a flat part which is a flat surface at the center part, and a plurality of spherical leg parts projecting downward from the flat part are arranged around the bottle part, so that the bottle stands on each leg part and is self-supporting. When the bottle is transported on the beverage filling line, the area of the portion immersed in the alkaline solution at the bottom is extremely small, and the occurrence of cracks is suppressed.
In addition, the spherical leg portion provided on the bottom portion is provided with at least three or more around the flat portion so that the bottle can be stably self-supporting, and appropriately set the downward projecting width from the bottom portion of the bottle, It is preferable to provide the flat portion so that the flat portion is horizontal in a state where the tip of each leg portion is in contact with a horizontal ground surface such as a desktop.
The legs can be arranged in an appropriate manner around the flat portion, for example, a plurality of legs on one side of the flat portion and one or more legs on the other side as long as the bottle's independence is maintained. However, if the legs are biased with respect to the entire bottom part, the independence becomes unstable and the body tends to fall down, and the thickness of the bottom part including the legs part is uneven and the shape is good. The pressure resistance is reduced. Therefore, the spherical leg portion is adjacent to the bottle in the projection surface of the bottom portion on the same circumference centered on the axis O along the circumferential direction. It is preferable to arrange so that the distance from the leg is equal. In this case, by making the projecting widths of the legs downward from the bottom of the bottle the same, the flat portion becomes horizontal in a state where the bottle is erected, and the bottle can be stably made to stand by itself.

前記構成の自立性耐圧ボトルにおいて、ボトルの軸心Oから胴部の内面までの胴部の半径aと、球状の脚部の輪郭の半径を規定する中心点cとボトルの軸心Oの間の距離bが、以下の関係式を満たすように設けられていることが好ましい(図3参照)。
(関係式) a/b=1.5〜2.2
胴部の半径aと前記距離bとの比が前記関係式の数値範囲内であれば、飲料が充填されたボトルを、テーブル上などの接地面上に安定的に立たせておくことができる。
胴部の半径aと前記距離bとの比が、1.5より小さいと、底部の平面部の面積が大きくなって底部の中央部分の耐圧性が低下して変形を来し易くなり、また、2.2より大きく、脚部が底部の中央側に寄っていると、ボトルが倒れやすくなる。よって、前記比は1.5〜2.2の範囲であることが好ましく、1.6〜1.8であればより好ましい。
In the self-supporting pressure-resistant bottle having the above configuration, the radius a of the barrel from the bottle axis O to the inner surface of the barrel, and the center point c defining the radius of the contour of the spherical leg and the axis O of the bottle Is preferably provided so as to satisfy the following relational expression (see FIG. 3).
(Relational expression) a / b = 1.5 to 2.2
If the ratio between the radius a of the body part and the distance b is within the numerical range of the relational expression, the bottle filled with the beverage can be stably placed on the ground surface such as a table.
If the ratio of the radius a of the body part to the distance b is smaller than 1.5, the area of the flat part of the bottom part becomes large, the pressure resistance of the central part of the bottom part is lowered, and deformation is likely to occur. If it is larger than 2.2 and the leg portion is close to the center side of the bottom portion, the bottle tends to fall down. Therefore, the ratio is preferably in the range of 1.5 to 2.2, more preferably 1.6 to 1.8.

前記構成の自立性耐圧ボトルにおいて、胴部の半径aと、脚部の接地面から底部中央に設けられた平面部までの高さdが、以下の関係式を満たすように設けられていることが好ましい。
(関係式) a/d=5〜18
胴部の半径aと前記高さdとの比が前記関係式の数値範囲内であれば、飲料が充填されたボトルを安定的に立たせておくことができるとともに、飲料の充填ラインでアルカリ溶液が底部に接触する面積が小さくなり、割れの発生を抑えることができ、苛酷環境保管時にも底部が飛び出すことがなく、ボトルの自立性を保つことができる。
胴部の半径aと前記高さdとの比が、5より小さいと、脚部が長くなって成形不良を来たし易くなり、特に肉厚が不均一となって賦形性が悪化し、自立性が保てなくなる。また、18より大きいと、接地面と底部の距離が近くなって、苛酷環境保管時にボトルの底部が飛び出したときに、その飛び出した部分が接地面に当たって自立性が保てなくなることがある。よって、前記比は5〜18の範囲であることが好ましく、7〜11であればより好ましい。
In the self-supporting pressure-resistant bottle having the above-described configuration, the radius a of the trunk portion and the height d from the ground contact surface of the leg portion to the flat portion provided at the center of the bottom portion are provided so as to satisfy the following relational expression. Is preferred.
(Relational expression) a / d = 5-18
If the ratio between the radius a of the body part and the height d is within the numerical range of the relational expression, the bottle filled with the beverage can be erected stably, and the alkaline solution can be used in the beverage filling line. The area in contact with the bottom is reduced, the occurrence of cracks can be suppressed, the bottom does not pop out even when stored in a harsh environment, and the independence of the bottle can be maintained.
If the ratio of the radius a of the body part to the height d is smaller than 5, the leg part becomes long and the molding is liable to occur, and the thickness becomes uneven and the formability deteriorates. Sex cannot be maintained. On the other hand, when the ratio is larger than 18, the distance between the ground plane and the bottom becomes short, and when the bottom of the bottle pops out during storage in a harsh environment, the protruding part may hit the ground plane and be unable to maintain its independence. Therefore, the ratio is preferably in the range of 5 to 18, more preferably 7 to 11.

また、前記構成の自立性耐圧ボトルにおいて、底部の起点部の輪郭の曲率半径R1と、脚部の輪郭の外側部分の曲率半径R2及び内側部分の曲率半径R3が、以下の関係式を満たすように設けられていることが好ましい(図3参照)。
(関係式) R3<R2<R1
底部の起点部から脚部及び平面部に至る外周面が、前記各曲率半径の湾曲面を連ねて形成されていれば、成形性が良く、また、胴部から脚部に至る外観がすっきりとした見栄えの良いものとなる。
ボトルを、その全長を182mm〜300mm、胴部内径を106mm程度の寸法に設定し、満注容量が1L〜2Lの大きさに形成する場合、前記脚部の接地面から底部中央に設けられた平面部までの高さdを3mm〜10mmに設定するとともに、前記各曲率半径をR1が35mm〜45mm、R2が20mm〜45mm、R3が5mm〜15mmの範囲内に設定すれば、成形性が良くボトルの見栄えも良好なものとなり、且つ耐圧性能も良好なものとなる。
In the self-supporting pressure-resistant bottle having the above-described configuration, the curvature radius R1 of the contour of the starting portion of the bottom, the curvature radius R2 of the outer portion of the contour of the leg portion, and the curvature radius R3 of the inner portion satisfy the following relational expression. Is preferably provided (see FIG. 3).
(Relational expression) R3 <R2 <R1
If the outer peripheral surface from the starting point of the bottom part to the leg part and the flat part is formed by connecting the curved surfaces of the respective radii of curvature, the moldability is good and the appearance from the trunk part to the leg part is clean. Will look good.
When the bottle has a total length of 182 mm to 300 mm and a barrel inner diameter of about 106 mm and a full capacity is 1 L to 2 L, the bottle is provided at the center of the bottom from the ground contact surface of the leg. If the height d up to the flat surface is set to 3 mm to 10 mm, and the respective radii of curvature are set in the ranges of 35 mm to 45 mm for R1, 20 mm to 45 mm for R2, and 5 mm to 15 mm for R3, the moldability is good. The appearance of the bottle will be good, and the pressure resistance will be good.

また、前記構成の自立性耐圧ボトルにおいて、胴部の肉厚t1は0.2mm〜0.5mm、底部の中央の平面部の肉厚t2は1.3mm〜3.2mm、脚部の接地面の肉厚t3は0.3mm〜1.0mmの範囲に設けられていることが好ましい。
さらに、ボトルの底部の耐圧性を高めるとともに凹みなどの成形不良の発生を抑制するため、底部の中央の平面部内に、ボトルの軸心Oを中心とする円形の肉厚部が形成されていることが好ましい。
Further, in the self-supporting pressure-resistant bottle having the above-described configuration, the thickness t1 of the trunk portion is 0.2 mm to 0.5 mm, the thickness t2 of the central plane portion of the bottom portion is 1.3 mm to 3.2 mm, and the grounding surface of the leg portion It is preferable that the wall thickness t3 is in the range of 0.3 mm to 1.0 mm.
Furthermore, in order to increase the pressure resistance of the bottom of the bottle and suppress the occurrence of molding defects such as dents, a circular thick portion centered on the bottle axis O is formed in the central flat portion of the bottom. It is preferable.

さらに、前記構成の自立性耐圧ボトルにおいて、各脚部を成形する金型部分であって各脚部の球状の外側面が面する位置に複数の点状エアースリットが設けられた成形金型を用いて成形されていることが好ましい。
各脚部の外側面が面する位置の金型に点状にエアースリットが入っていれば、脚部の賦形性が良好となって各脚部の厚みが均等に揃えられ、脚部の高さに差が出るようなことはなく、脚部の高さの違いによって立てたボトルがぐらつくなどの自立性不良の発生を抑止することができる。金型に設けるエアースリットは、各脚部の球状の頂点を中心とし、この中心点とその周囲に等間隔開けた複数点とに配置されていることが好ましい。
Further, in the self-supporting pressure-resistant bottle having the above-described configuration, a molding die provided with a plurality of dot-like air slits at a position where the spherical outer surface of each leg portion faces is a mold portion for molding each leg portion. It is preferable that it is molded using.
If the air slits are in the form of dots in the mold where the outer surface of each leg faces, the leg shape will be good and the thickness of each leg will be equalized. There is no difference in height, and it is possible to prevent the occurrence of independence such as wobbling of the standing bottle due to the difference in the height of the legs. It is preferable that the air slits provided in the mold are arranged at the center point and a plurality of points at equal intervals around the center of the spherical apex of each leg.

また、前記構成の自立性耐圧ボトルにおいて、ボトルの内面にガスバリア性薄膜がコーティングされた構成を有することが好ましい。
なかでも、ボトル内面にダイヤモンドライクカーボン(以下、「DLC」という。)などの炭素を含む薄膜をコーティングしてガスバリア性を高めることで、ボトルに充填されるビールなどの炭酸ガスが溶け込んだ飲料の品質劣化を抑制し、適正な品質を保って保管したり運搬したりすることができる。
ボトル内面へのDLC成膜は、公知のプラズマ化学蒸着技術によって行うことができる。成膜は、ボトル内部の全面に均等に、且つ密着性良く行うことが肝要であり、酸素透過率が0.010cc/pkg/day/air以下であることが望ましい。
Moreover, the self-supporting pressure-resistant bottle having the above-described configuration preferably has a configuration in which a gas barrier thin film is coated on the inner surface of the bottle.
In particular, the inner surface of the bottle is coated with a thin film containing carbon such as diamond-like carbon (hereinafter referred to as “DLC”) to enhance the gas barrier property, thereby allowing the beverage containing carbon dioxide such as beer to be filled in the bottle to be dissolved. It can be stored and transported while suppressing the quality deterioration and maintaining proper quality.
DLC film formation on the inner surface of the bottle can be performed by a known plasma chemical vapor deposition technique. It is important to form the film evenly over the entire surface of the bottle and with good adhesion, and it is desirable that the oxygen transmission rate is 0.010 cc / pg / day / air or less.

なお、ボトルの成形に使用する樹脂としては、ポリエチレンテレフタレート系樹脂、主としてPET樹脂を使用することができる。エチレンテレフタレート単位を主体として、他のポリエステル単位を含む共重合ポリエステルを使用することもでき、耐熱性を向上させるために、ナイロン系樹脂や、ポリエチレンナフタレート樹脂などの樹脂を少量ブレンドして使用してもよい。   In addition, as resin used for shaping | molding of a bottle, a polyethylene terephthalate type-resin, mainly PET resin can be used. Copolyesters containing ethylene terephthalate units as the main component and other polyester units can also be used. In order to improve heat resistance, a small amount of resin such as nylon resin or polyethylene naphthalate resin is used. May be.

本発明の一実施形態の自立性耐圧ボトルの外観図である。It is an external view of the self-supporting pressure-resistant bottle of one embodiment of the present invention. 図1の自立性耐圧ボトルの底面図である。It is a bottom view of the self-supporting pressure-resistant bottle of FIG. 図1の自立性耐圧ボトルの要部を拡大した切断端面図である。It is the cut end view which expanded the principal part of the self-supporting pressure-resistant bottle of FIG. 図1の自立性耐圧ボトルの底部側を拡大した切断端面図である。It is the cut end view which expanded the bottom part side of the self-supporting pressure-resistant bottle of FIG. 図1の自立性耐圧ボトルの六面外観図である。It is a six-sided external view of the self-supporting pressure-resistant bottle of FIG. 本発明の他の実施形態の自立性耐圧ボトルの外観図である。It is an external view of the self-supporting pressure-resistant bottle of other embodiment of this invention. 比較例1の自立性耐圧ボトルの外観図(A)と要部拡大切断端面図(B)である。It is the external view (A) of the self-supporting pressure-resistant bottle of the comparative example 1, and a principal part expansion cut end view (B). 比較例2の自立性耐圧ボトルの外観図である。6 is an external view of a self-supporting pressure-resistant bottle of Comparative Example 2. FIG. 実施例と比較例の評価結果を示した表である。It is the table | surface which showed the evaluation result of the Example and the comparative example. 従来の一例の耐圧ボトルの外観図である。It is an external view of a conventional pressure bottle. 従来の他の例の耐圧ボトルの底側外観図(A)と底部側の切断端面拡大図(B)である。It is the bottom side external view (A) of the pressure bottle of other conventional examples, and the cut end surface enlarged view (B) of the bottom part side.

本発明の好適な実施の形態を図面に基づいて説明する。
図1と図2は本発明の一実施形態の自立性耐圧ボトルの外観と底面を、図5は六面外観を各々示しており、図示されたボトル1は、ポリエステル系樹脂からなるパリソンを二軸延伸ブロー成形してなる、口栓部2、肩部3、胴部4及び底部5を備えたプラスチックボトルであり、その全長(ボトルの高さ)を182mm程度、胴部4の内径を106mm程度の大きさに設けて、内部に1Lの飲料を充填して密封包装することができるように形成してある。
A preferred embodiment of the present invention will be described with reference to the drawings.
1 and 2 show the appearance and bottom of a self-supporting pressure-resistant bottle according to an embodiment of the present invention, and FIG. 5 shows the appearance of a six-faced bottle. The illustrated bottle 1 has two parisons made of polyester resin. It is a plastic bottle with a stopper part 2, a shoulder part 3, a body part 4 and a bottom part 5 formed by axial stretch blow molding. The overall length (bottle height) is about 182 mm, and the inner diameter of the body part 4 is 106 mm. It is provided so as to have a size of about 1 L so that it can be filled and sealed with 1 L of beverage.

図1に示されるように、自立性耐圧ボトル1は、キャップが取り付けられる口栓部2の下縁から周面が湾曲した略円錐状の肩部3が繋がり、肩部3の下縁に、円筒状の胴部4が連なり、胴部4の下部に当該胴部4から内方へ湾曲しつつ窄まった底部5を配した形状に設けてある。   As shown in FIG. 1, the self-supporting pressure-resistant bottle 1 is connected to a substantially conical shoulder portion 3 having a curved peripheral surface from a lower edge of the mouthpiece portion 2 to which the cap is attached. A cylindrical body 4 is connected to each other, and a bottom part 5 which is narrowed while curving inwardly from the body 4 is provided at a lower part of the body 4.

詳しくは、図3及び図4に示されるように、底部5は、その中央部に、ボトル1を机上や床面に置いたときに水平な接地面と略平行となる平坦面である平面部51が設けられ、この平面部51の周囲に、下方へ突出した球状の脚部52を、ボトル1の軸心Oを中心とした同一円周上に、隣接した脚部52との間隔が等間隔となるように設定して、五つ配置した形状に設けてある。各脚部52の下方への突出幅は同じとしてある。   Specifically, as shown in FIG. 3 and FIG. 4, the bottom portion 5 is a flat portion that is a flat surface that is substantially parallel to the horizontal ground contact surface when the bottle 1 is placed on a desk or floor surface at the center. 51. A spherical leg portion 52 projecting downward is provided around the flat portion 51 on the same circumference centered on the axis O of the bottle 1, and the spacing between the adjacent leg portions 52 is equal. It is set to have an interval and is provided in a shape in which five are arranged. The downward projecting width of each leg 52 is the same.

各脚部52は、底部5内で平面部51よりも下方へ突出しつつ球状に膨出した輪郭を呈する部分であり、各々その外周面が胴部4と底部5の境界である底部起点部5aから、ボトル1の内方へ曲率半径R1で湾曲した湾曲面を介して当該湾曲面に連なってボトル1の内方へ曲率半径R2で湾曲した湾曲面に連なり、また、その内周面がボトル1の内方へ曲率半径R3で湾曲した湾曲面を介して平面部51に連なるように設けて形成してある。
図2において、各球状の脚部52を湾曲する部分の輪郭を二本の細線で囲って示してあるが、各脚部52は隣接する脚部52同士で湾曲面が交差することなく、所定の間隔を開けて底部5の表面から下方へ独立して突出した形状に設けてある。
また、各脚部52の外周面には、整形時に各脚部52の外側面が面する位置の金型に形成された点状エアースリットの跡である点状の凸部52aが脚部52の球状の頂点と、これを中心とした周囲とに五つ配置して形成してある。
Each leg portion 52 is a portion having a spherically bulging outline projecting downward from the plane portion 51 in the bottom portion 5, and a bottom starting point portion 5 a whose outer peripheral surface is a boundary between the trunk portion 4 and the bottom portion 5. To the inside of the bottle 1 through the curved surface curved with the radius of curvature R1 and the curved surface curved with the radius of curvature R2 inward of the bottle 1 through the curved surface. 1 is formed so as to be continuous with the flat portion 51 through a curved surface curved inwardly with a radius of curvature R3.
In FIG. 2, the outline of the curved portion of each spherical leg 52 is surrounded by two thin lines, but each leg 52 has a predetermined shape without a curved surface intersecting between adjacent leg portions 52. Are provided so as to project independently downward from the surface of the bottom portion 5.
Further, on the outer peripheral surface of each leg portion 52, a dot-like convex portion 52a which is a trace of a dot-like air slit formed on a mold at a position where the outer surface of each leg portion 52 faces during shaping is the leg portion 52. Are arranged at five vertices of a spherical shape and around the center.

具体的には、各脚部52は、各々球状の輪郭の半径を規定する中心点cの位置が、ボトル1の軸心Oから一定の距離bだけ離れ、且つボトル1の軸心Oから胴部4の内面に至る胴部4の半径aと前記距離bの比(a/b)が、1.5〜2.2の範囲(a/b=1.5〜2.2)となるように設けてある。
また、各脚部52は、胴部4の半径aと、脚部5の接地面(最下点)から平面部51までの高さdの比(a/d)が、5〜18の範囲(a/d=5〜18)となるように設けてある。
Specifically, each leg 52 has a center point c that defines the radius of the spherical contour, separated from the axis O of the bottle 1 by a certain distance b, and the barrel 52 from the axis O of the bottle 1. The ratio (a / b) between the radius a of the body 4 reaching the inner surface of the part 4 and the distance b (a / b) is in the range of 1.5 to 2.2 (a / b = 1.5 to 2.2). Is provided.
Each leg 52 has a ratio (a / d) of the radius a of the body 4 and the height d from the ground contact surface (the lowest point) of the leg 5 to the flat surface 51 in the range of 5 to 18. (A / d = 5 to 18).

また、底部5の底部起点部5aから脚部52と平面部51に連なる湾曲した各曲面の曲率半径は、曲率半径R1が35mm〜45mm、R2が20mm〜45mm、R3が5mm〜15mmの範囲内に設定してある。
さらに、図4に示されるように、胴部4の肉厚t1は0.2mm〜0.5mm、底部5の平面部51の肉厚t2は1.3mm〜3.2mm、脚部52の接地面の肉厚t3は0.3mm〜1.0mmの範囲内に設定してある。また、底部5の平面部51には、その中央にボトル1の軸心Oを中心とする円形の肉厚部51aを設けて、その周囲の平面部51の肉厚t2よりも厚くしてある。
Further, the curvature radii of the curved surfaces that continue from the bottom starting point 5a of the bottom 5 to the leg 52 and the flat part 51 are in a range where the curvature radius R1 is 35 mm to 45 mm, R2 is 20 mm to 45 mm, and R3 is 5 mm to 15 mm. It is set to.
Further, as shown in FIG. 4, the thickness t1 of the body portion 4 is 0.2 mm to 0.5 mm, the thickness t2 of the flat portion 51 of the bottom portion 5 is 1.3 mm to 3.2 mm, and the contact of the leg portion 52 is achieved. The thickness t3 of the ground is set in the range of 0.3 mm to 1.0 mm. Further, the flat portion 51 of the bottom portion 5 is provided with a circular thick portion 51a centering on the axis O of the bottle 1 at the center thereof, and is thicker than the thickness t2 of the surrounding flat portion 51. .

以下、本発明の好適な実施の形態を実施例に基づいて詳細に説明する。なお、下記実施例は本発明を限定するものではない。   DESCRIPTION OF EMBODIMENTS Hereinafter, preferred embodiments of the present invention will be described in detail based on examples. The following examples do not limit the present invention.

(実施例1)
図1に示された形状のボトルを成形し、その内面にDLC被膜をコーティングして、1L用の自立性耐圧ボトル1を作製した。
ボトル1の成形寸法は、全長が182mm、胴部4の内径を106mm、脚部52の高さdを5.6mm、底部起点部5aから脚部52と平面部51に連なる湾曲面の曲率半径が曲率半径R1を40mm、R2を30mm、R3を8mmとし、また、胴部4の肉厚t1を0.2mm〜0.5mm、平面部51の肉厚t2を2.2mm、脚部52の接地面の肉厚t3を0.8mmに設定した。
このボトル1の底部5は、その中央部に平坦な平面部51が配置されており、ボトルの外方へ突出する突起はない。
Example 1
A bottle having the shape shown in FIG. 1 was molded, and a DLC film was coated on the inner surface thereof to produce a 1 L self-supporting pressure-resistant bottle 1.
The molding dimensions of the bottle 1 are 182 mm in total length, 106 mm in the inner diameter of the body 4, 5.6 mm in the height d of the leg 52, and the radius of curvature of the curved surface extending from the bottom starting point 5 a to the leg 52 and the flat part 51. The radius of curvature R1 is 40 mm, R2 is 30 mm, R3 is 8 mm, the thickness t1 of the body portion 4 is 0.2 mm to 0.5 mm, the thickness t2 of the flat portion 51 is 2.2 mm, and the leg portion 52 is The thickness t3 of the ground contact surface was set to 0.8 mm.
The bottom portion 5 of the bottle 1 is provided with a flat plane portion 51 at the center thereof, and there is no protrusion protruding outward from the bottle.

(実施例2)
図6に示された形状のボトルを成形し、その内面にDLC被膜をコーティングして、2L用の自立性耐圧ボトル1を作製した。
ボトル1の成形寸法は、全長が300mm、胴部4の肉厚t1を0.3mm〜0.4mm、平面部51の肉厚t2を1.9mm、脚部52の接地面の肉厚t3を0.5mmに設定する以外、実施例1の各部の寸法と同じに設定した。
このボトル1の底部5も、その中央部に平坦な平面部51が配置されており、ボトルの外方へ突出する突起はない。
(Example 2)
A bottle having the shape shown in FIG. 6 was formed, and a DLC film was coated on the inner surface thereof to produce a self-supporting pressure-resistant bottle 1 for 2L.
The molding dimensions of the bottle 1 are as follows: the overall length is 300 mm, the thickness t1 of the body portion 4 is 0.3 mm to 0.4 mm, the thickness t2 of the flat portion 51 is 1.9 mm, and the thickness t3 of the ground contact surface of the leg portion 52 is Except for setting to 0.5 mm, the dimensions were set to be the same as the dimensions of each part in Example 1.
The bottom portion 5 of the bottle 1 is also provided with a flat flat portion 51 at the center thereof, and there is no protrusion protruding outward from the bottle.

(実施例3)
実施例1と同じ成形寸法のボトルであって、内面にDLC被膜はコーティングされていない自立性耐圧ボトルを作製した。
Example 3
A self-supporting pressure-resistant bottle having the same molding dimensions as in Example 1 and having an inner surface not coated with a DLC film was produced.

(実施例4)
実施例2と同じ成形寸法のボトルであって、内面にDLC被膜はコーティングされていない自立性耐圧ボトルを作製した。
Example 4
A self-supporting pressure-resistant bottle having the same molding dimensions as in Example 2 and having an inner surface not coated with a DLC film was produced.

(比較例1)
図7に示された、略半球状基礎ベースを輪郭に独立した複数の脚形状を有する、1L用の自立性耐圧ボトルを作製した。
ボトルの成形寸法は、全長が182mm、胴部の内径が106mmと実施例1と同じであるが、ボトルの底部の中央部分は、実施例1と異なり、下方へ突出した湾曲形状に形成した。このボトルの内面には、DLC被膜はコーティングされていない。
(Comparative Example 1)
A self-supporting pressure-resistant bottle for 1 L having a plurality of leg shapes independent of the outline of the substantially hemispherical base base shown in FIG. 7 was produced.
The bottle has the same molding dimensions as in Example 1 with a total length of 182 mm and an inner diameter of the barrel of 106 mm, but unlike the first example, the central part of the bottom of the bottle was formed in a curved shape protruding downward. The inner surface of the bottle is not coated with a DLC film.

(比較例2)
図8に示された、底部をペタロイド形状に設けるとともに、底部中央に下方へ突出した突起部を配置した、400ml用の自立性耐圧ボトルを作製した。
ボトルの成形寸法は、全長を205mm、胴部の内径を66mmに設定した。このボトルの内面には、DLC被膜はコーティングされていない。
(Comparative Example 2)
A self-supporting pressure-resistant bottle for 400 ml was prepared in which a bottom portion shown in FIG. 8 was provided in a petaloid shape and a protruding portion that protruded downward was arranged in the center of the bottom portion.
The molding dimensions of the bottle were set to 205 mm for the overall length and 66 mm for the inner diameter of the barrel. The inner surface of the bottle is not coated with a DLC film.

前記各実施例と比較例で作製した自立性耐圧ボトルについて、以下の項目について評価を行なった。   The following items were evaluated for the self-supporting pressure-resistant bottles produced in each of the examples and comparative examples.

(項目1:飲料充填後の外観確認)
自立性耐圧ボトルに、3ガスボリュームの炭酸水をボトル天面の下方40mmの高さに達するまで充填するとともにキャップをして密封し、その状態で、底部に凹んだり突出したりする形状の変化があるか否かを、底部の外観を目視により確認した。
(Item 1: Appearance check after beverage filling)
Fill the self-supporting pressure-resistant bottle with 3 gas volumes of carbonated water until it reaches a height of 40 mm below the top of the bottle and seal it with a cap. In that state, there is a change in shape that dents or protrudes at the bottom. Whether or not there was was visually confirmed the appearance of the bottom.

(項目2:保管後の外観観察)
自立性耐圧ボトルに、3ガスボリュームの炭酸水をボトル天面の下方40mmの高さに達するまで充填するとともにキャップをして密封し、これを38℃60%RHの苛酷環境下で一週間保管した後、底部に凹んだり突出したりする形状の変化があるか否かを、底部の外観を目視により確認した。
(Item 2: Observation of appearance after storage)
Fill a self-supporting pressure-resistant bottle with 3 gas volumes of carbonated water until it reaches a height of 40 mm below the top of the bottle, seal it with a cap, and store it in a harsh environment of 38 ° C and 60% RH for one week. Then, the appearance of the bottom portion was visually confirmed to determine whether or not there was a change in shape that was recessed or protruded at the bottom portion.

(項目3:転倒試験)
前記項目1と同様に自立性耐圧ボトルに炭酸水を充填するとともにキャップをして密封し、これを、自立方向から徐々に傾けることが可能な治具に設置し、自立性耐圧ボトルが倒れるときの傾き角度を測定した。
(Item 3: Fall test)
When the self-supporting pressure-resistant bottle falls down, the self-supporting pressure-resistant bottle is filled with carbonated water, sealed with a cap, and installed in a jig that can be gradually tilted from the self-standing direction. The inclination angle of was measured.

(項目4:落下試験)
前記項目1と同様に自立性耐圧ボトルに炭酸水を充填するとともにキャップをして密封し、これを、0.9mの高さから、ボトルの底部側を下向けて垂直に落下させ、底部の割れ発生の有無を目視で確認した。
(Item 4: Drop test)
As in the above item 1, the self-supporting pressure-resistant bottle is filled with carbonated water and sealed with a cap, and this is dropped vertically from the height of 0.9 m with the bottom side of the bottle facing downward. The presence or absence of cracking was confirmed visually.

(項目5:耐アルカリ試験)
前記項目1と同様に自立性耐圧ボトルに炭酸水を充填するとともにキャップをして密封し、これを、0.2%の水酸化ナトリウム水溶液(深さ20mm)中に立たせて15分間浸水した後、底部の変形及び割れの有無を目視で確認した。
(Item 5: Alkali resistance test)
As in the above item 1, after filling a self-supporting pressure-resistant bottle with carbonated water and sealing it with a cap, this was placed in a 0.2% aqueous sodium hydroxide solution (depth 20 mm) and immersed for 15 minutes. The presence or absence of deformation and cracks at the bottom was visually confirmed.

(項目6:DLC膜厚)
ボトルの内面に黒色インキでマスキングを行い、DLC成膜後にジエチルエーテルでマスキングを除去し、高精度微細形状測定器(ET4000A:小坂研究所社製)を用いて成膜段差形状測定から膜厚を求めた。
(Item 6: DLC film thickness)
Mask the inner surface of the bottle with black ink, remove the masking with diethyl ether after DLC film formation, and measure the film thickness from the film thickness difference measurement using a high-precision fine shape measuring instrument (ET4000A: manufactured by Kosaka Laboratory). Asked.

(項目7:酸素透過度(BIF))
製作した自立性耐圧ボトルの酸素透過率を測定した。測定は、酸素透過率測定装置(Oxtran:Modern Contorl社製、単位cc/pkg/day/air)を用い、23℃、相対湿度50%の条件下で行なった。
また、未コーティングボトルに対する改善率をBIF(Barrier Improvemennt Factor)として算出した。
(Item 7: Oxygen permeability (BIF))
The oxygen permeability of the manufactured self-supporting pressure-resistant bottle was measured. The measurement was carried out using an oxygen permeability measuring device (Oxtran: Modern Control, unit cc / pg / day / air) under conditions of 23 ° C. and 50% relative humidity.
Moreover, the improvement rate with respect to an uncoated bottle was computed as BIF (Barrier Improvent Factor).

(項目8:炭酸ガス保持率)
前記項目1と同様に自立性耐圧ボトルに炭酸水を充填するとともにキャップをして密封し、この状態の炭酸ガスボリュームを測定した。
測定は、ガスボリュームテスター(DGV−1;ビクスル社製)を用いて行い、炭酸水充填直後に測定したガスボリュームをA、38℃60%RHに一週間保管後に測定したガスボリュームをBとし、算出式(B/A×100)にて保持率を導出することで行なった。
(Item 8: Carbon dioxide retention)
As in item 1, the self-supporting pressure-resistant bottle was filled with carbonated water and sealed with a cap, and the carbon dioxide volume in this state was measured.
The measurement is performed using a gas volume tester (DGV-1; manufactured by Bixle). The gas volume measured immediately after filling with carbonated water is A, and the gas volume measured after storage at 38 ° C. and 60% RH for one week is B. This was done by deriving the retention rate by the calculation formula (B / A × 100).

各項目の評価結果を図9中の表に示す。
実施例1,2における自立性耐圧ボトル1は、炭酸水の充填後及び保管後において、底部が接地面の向きへ飛び出るような変形は発生せず、良好な耐圧性を備えていることが確認できた。また、自立性が良好で、底部の剛性も高いとともにアルカリ水溶液に対する耐性も高いことが確認できた。さらに、内面にDLCコーティングを施していない実施例3,4と比較して、酸素透過率(BIF)が10倍以上あり、また、炭酸ガス保持率が95%以上あることにより、実施例1,2のボトルは耐圧性能を有するボトル形状であるとともに、高い酸素バリア性及び炭酸ガス保持性能を具備していることが確認できた。
実施例3,4のボトルは、炭酸水の充填後及び保管後において、底部が接地面の向きへ飛び出るような変形は発生せず、またアルカリ水溶液に対する耐性も高かった。
比較例1のボトルは、炭酸水の充填後の保管により底部が接地面の向きへ飛び出す変形が発生し、自立性が損なわれる結果となった。
また、比較例2のボトルでは、底部が接地面の向きに飛び出す変形は生じなかったが、アルカリ溶液浸水時に底部の割れが発生した。
The evaluation results for each item are shown in the table in FIG.
It is confirmed that the self-supporting pressure-resistant bottle 1 in Examples 1 and 2 has a good pressure resistance without deformation such that the bottom portion protrudes toward the grounding surface after filling with carbonated water and after storage. did it. Moreover, it was confirmed that the self-supporting property was good, the bottom portion had high rigidity, and the resistance to the alkaline aqueous solution was high. Further, compared with Examples 3 and 4 in which DLC coating is not applied to the inner surface, the oxygen permeability (BIF) is 10 times or more and the carbon dioxide gas retention is 95% or more. It was confirmed that the bottle of No. 2 has a bottle shape having pressure resistance, and has high oxygen barrier properties and carbon dioxide retention performance.
The bottles of Examples 3 and 4 were not deformed such that the bottom part jumped out toward the ground surface after filling with carbonated water and after storage, and also had high resistance to the alkaline aqueous solution.
The bottle of Comparative Example 1 was deformed such that the bottom part jumped out in the direction of the ground contact surface during storage after filling with carbonated water, resulting in a loss of self-supporting property.
Moreover, in the bottle of the comparative example 2, although the deformation | transformation which a bottom part jumps out in the direction of a ground surface did not arise, the crack of the bottom part generate | occur | produced at the time of alkaline solution immersion.

1 自立性耐圧ボトル(ボトル)、2 口栓部、3 肩部、4 胴部、5 底部、51 平面部、52 脚部
1 self-supporting pressure-resistant bottle (bottle), 2 mouth plug part, 3 shoulder part, 4 body part, 5 bottom part, 51 flat part, 52 leg part

Claims (5)

口栓部と肩部と胴部と底部とを備えた自立性耐圧ボトルにおいて、
前記底部の中央部に平面部が設けられ、この平面部の周囲に、下方へ突出した球状の脚部が複数設けられた構成を有することを特徴とする自立性耐圧ボトル。
In a self-supporting pressure-resistant bottle provided with a spout part, a shoulder part, a trunk part, and a bottom part,
A self-supporting pressure-resistant bottle having a configuration in which a flat portion is provided at the center of the bottom portion, and a plurality of spherical legs protruding downward are provided around the flat portion.
ボトルの軸心Oから胴部の内面までの胴部の半径aと、球状の脚部の輪郭の半径を規定する中心点cとボトルの軸心Oの間の距離bが、以下の関係式を満たすように設けられた構成を有することを特徴とする請求項1に記載の自立性耐圧ボトル。
(関係式) a/b=1.5〜2.2
The radius a of the barrel from the bottle axis O to the inner surface of the barrel, and the distance b between the center point c defining the radius of the spherical leg contour and the bottle axis O are expressed by the following relational expression: The self-supporting pressure-resistant bottle according to claim 1, having a configuration provided to satisfy
(Relational expression) a / b = 1.5 to 2.2
胴部の半径aと、脚部の接地面から底部中央に設けられた平面部までの高さdが、以下の関係式を満たすように設けられた構成を有することを特徴とする請求項1又は2に記載の自立性耐圧ボトル。
(関係式) a/d=5〜18
2. A configuration in which the radius a of the trunk portion and the height d from the ground contact surface of the leg portion to the flat portion provided at the center of the bottom portion are provided so as to satisfy the following relational expression. Or the self-supporting pressure-resistant bottle according to 2.
(Relational expression) a / d = 5-18
底部の起点部の輪郭の曲率半径R1と、脚部の輪郭の外側部分の曲率半径R2及び内側部分の曲率半径R3が、以下の関係式を満たすように設けられた構成を有することを特徴とする請求項1〜3の何れかに記載の自立性耐圧ボトル。
(関係式) R3<R2<R1
The curvature radius R1 of the contour of the starting portion of the bottom, the curvature radius R2 of the outer portion of the contour of the leg portion, and the curvature radius R3 of the inner portion are provided so as to satisfy the following relational expression: The self-supporting pressure-resistant bottle according to any one of claims 1 to 3.
(Relational expression) R3 <R2 <R1
底部の中央の平面部内にボトルの軸心Oを中心とする円形の肉厚部が形成された構成を有することを特徴とする請求項1〜4の何れかに記載の自立性耐圧ボトル。   The self-supporting pressure-resistant bottle according to any one of claims 1 to 4, wherein the self-supporting pressure-resistant bottle has a configuration in which a circular thick portion centered on the axis O of the bottle is formed in a flat portion at the center of the bottom portion.
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Publication number Priority date Publication date Assignee Title
JP2019172350A (en) * 2018-03-29 2019-10-10 三菱ケミカル株式会社 Pressure-resistant container

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