JP2016124863A - Oily solid cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oily solid cosmetic that has enough hardness to become solid, has an excellent aesthetic appearance including transparency, has smooth spreadability during application and has an excellent use feeling.SOLUTION: This invention relates to an oily solid cosmetic comprising components (a)-(c): (a) N-acyl amino acid amide derivative, (b) polyglyceryl fatty acid ester, and (c) volatile hydrocarbon oil.SELECTED DRAWING: None

Description

  The present invention relates to an oily solid cosmetic, and more particularly to an oily solid cosmetic excellent in transparency.

Oil-based solid cosmetics are applied to lipsticks, makeup cosmetics such as foundation, teak, and eye shadow, and various cosmetics for skin care and hair care such as eye sticks, antiperspirants, hair styling, and kneading perfumes. The dosage form. Such oil-based solid cosmetics are not only good in function and feel, but also have a novel shape and excellent aesthetic appearance, and those with a transparent appearance are also preferred.
For oily solid cosmetics, a technique in which liquid oil is solidified using a solidifying agent is generally used. These incorporate liquid oil into the structure formed by the solidifying agent, form a solid oil gel, and apply shear stress due to application during use, so that part of the structure collapses and is applied to the desired site Is something that can be done. Oily solid cosmetics containing a film-forming agent dissolved in volatile oil are useful in make-up cosmetics because the volatile oil volatilizes after application and a strong film is formed, resulting in excellent cosmetic effects. Although used, it is not easy to solidify volatile oils, and various solidifying agents have been studied. Among them, the oil gel formed by wax has been widely used because it can form a harder gel than the oil gel formed by other solidifying agents, but it has excellent gel strength, but it has the shear stress required to break down the structure. Therefore, when applying cosmetics, the feel became hard, leading to a loss of smooth use feeling. Moreover, the obtained gel was cloudy.

  In the past, oil-based solid cosmetics that have both sufficient hardness while achieving both a transparent appearance and a smooth feeling of use have been studied. For example, an oily cosmetic for hair with good elongation has been proposed by solidifying volatile hydrocarbon oil with solid high-viscosity hydrocarbons or waxes and an oil gelling agent at room temperature (Patent Document 1). In addition, a volatile oil agent is hardened using dextrin fatty acid ester, and a transparent solid cosmetic material having a refreshing feeling and good stability by blending a specific refractive index oil and a spherical powder. Patent Document 2), a solid cosmetic that combines an N-acylamino acid amide derivative, a volatile hydrocarbon oil, and a specific spherical powder, has a good feeling when applied, and has excellent appearance transparency (Patent Document) 3) has been proposed.

JP 2008-303178 A JP 2005-213145 A JP 2012-240994 A

  However, the technique of Patent Document 1 is not satisfactory in terms of transparency, and the technique of Patent Document 2 is not high in solidification ability of dextrin fatty acid esters with respect to volatile oils. In some cases, it was insufficient. Moreover, the technique of patent document 3 which solidified volatile hydrocarbon oil with the N-acylamino acid amide derivative and improved the expansion spread at the time of application | coating by adding a specific spherical powder to this is volatile hydrocarbon oil. In addition to the poor solubility of the N-acylamino acid amide derivative with respect to the above, it contained a powder, so that sufficient transparency could not be obtained.

  In this way, it is very difficult to solidify volatile oils transparently while maintaining the basic quality of oily solid cosmetics with sufficient hardness and excellent stability, and to realize a better feeling of use. Therefore, development of an oily solid cosmetic material having these characteristics has been desired.

  Under such circumstances, the present inventor has conducted intensive research in view of the above problems, and as a result, the combination of the N-acylamino acid amide derivative and the volatile hydrocarbon oil is inferior in transparency, and the oil gel is fragile. Can not be obtained, but combined with a polyglycerin fatty acid ester excellent in solubility of N-acylamino acid amide derivatives, it is highly transparent and has a sufficient hardness but is used in a smooth manner The present inventors have found that an oily solid cosmetic with a good feeling can be obtained, and have completed the present invention.

That is, the present invention
The following components (a) to (c);
(A) N-acylamino acid amide derivative (b) Polyglycerin fatty acid ester (c) An oily solid cosmetic containing a volatile hydrocarbon oil is provided.

(In the formula, R ¹ and R ² each independently represent a hydrocarbon group having 1 to 26 carbon atoms, R ³ represents a hydrocarbon group having 7 to 17 carbon atoms, and n represents 1 or 2)

  The present invention relates to an oily solid cosmetic having sufficient hardness, excellent aesthetics of a transparent appearance, and good elongation spread at the time of application.

Details of the present invention will be described below.
The term “transparent” in the present invention means that a paper on which a black character (font: Times New Roman, font size: 24 points) of a predetermined size is placed on a white background on the bottom of a container, and the composition melted by heating is placed on the paper. After pouring so that it may become 10-mm thickness, and cooling and solidifying completely, when it sees from right above at 25 degreeC, it points out what can recognize the character of a bottom face visually. In addition, as long as a character can recognize visually, the transparency of this invention includes what was colored.

  Component (a) used in the present invention is an N-acylamino acid amide derivative represented by the following formula (1).

(In the formula, R ¹ and R ² each independently represent a hydrocarbon group having 1 to 26 carbon atoms, R ³ represents a hydrocarbon group having 7 to 17 carbon atoms, and n represents 1 or 2)

The hydrocarbon group for R ¹ and R ² is preferably independently a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably a linear or branched alkyl group having 3 to 5 carbon atoms. preferable. The hydrocarbon group for R ³ is preferably a linear or branched alkyl group having 7 to 17 carbon atoms. n represents 1 or 2, but is preferably 2. Among these, N-2-ethylhexanoyl-L-glutamic acid dibutylamide and N-lauroyl-L-glutamic acid dibutylamide are preferably used, and N-lauroyl-L-glutamic acid dibutylamide is more preferably used. Examples of commercially available products include EB-21 and GP-1 (both manufactured by Ajinomoto Co., Inc.).

  Although content in particular of the component (a) in this invention is not restrict | limited, 0.1-10 mass% (henceforth only%) is preferable in oil-based solid cosmetics, More preferably, it is 0.5-6. %. Within this range, sufficient hardness and excellent transparency as an oily solid cosmetic can be obtained.

  The polyglycerin fatty acid ester of component (b) used in the present invention is an ester oil of polyglycerin having a polymerization degree of 2 or more and a fatty acid. Examples of polyglycerin include polyglycerin having a degree of polymerization of 2 to 10, and diglycerin, triglycerin, tetraglycerin, pentaglycerin, hexaglycerin, decaglycerin, and the like. Moreover, it does not specifically limit as a fatty acid which comprises polyglyceryl fatty acid ester, However, C8-C22 linear or branched fatty acid is used preferably. Specifically, linear fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, eicosenoic acid, behenic acid, 2-ethylhexanoic acid, isononanoic acid, isodecanoic acid, isotridecanoic acid, isomyristic acid, Examples include branched fatty acids such as isopalmitic acid, isostearic acid, isoarachidic acid, and isobehenic acid. These may be one type or two or more types of mixed fatty acids.

  The polyglycerin fatty acid ester of component (b) includes diglycerin mono, di, tri, or tetra fatty acid esters, hexaglycerin mono, di, tri, tetra, penta, hexa, hepta, or octa fatty acid esters, decaglycerin. Mono, di, tri, tetra, penta, hexa, hepta, octa, nona, deca, undeca, or dodeca fatty acid ester, and the like, and one or more of these may be used in combination. As commercial products, Cosmol 42V (polyglyceryl-2 diisostearate, manufactured by Nisshin Oillio Group), Cosmol 43V (polyglyceryl triisostearate-2, manufactured by Nisshin Oilio Group), Cosmol 44V (polyglyceryl-2 tetraisostearate, Nisshin Oilio Group), KIS-1009 (Nonisoisostearate polyglyceryl-10, Sakamoto Yakuhin Kogyo), KEH-1010 (decaethylhexanoic acid polyglyceryl-10, Sakamoto Yakuhin Kogyo), KIS-1010 (Deca Polyglyceryl-10 isostearate, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.), NIKKOL Decaglyn 10-ISV (polyglyceryl-10 decaisostearate, manufactured by Nikko Chemicals), NIKKOL Decaglyn 10-O (Dekaorein polyglyceryl -10, Nikko Chemicals Co., Ltd.) and the like.

  The component (b) in this invention can use the 1 type (s) or 2 or more types, Content is not restrict | limited in particular, However, 1 to 49% is preferable on the basis of the total amount of solid cosmetics, More preferably, 5 ~ 45%. By containing within the said range, the outstanding transparency and smooth usability | use_condition can be obtained.

  In the present invention, when the mass ratio of the component (a) to the component (b) is (a) :( b) is 1: 1 to 1: 100, and further 1: 1 to 1:50, the oily solid cosmetic It is preferable in terms of hardness.

  The volatile hydrocarbon oil of component (c) in the present invention is intended to impart a light and light feel and a good feeling of makeup by volatilization after application. The volatile hydrocarbon oil has a boiling point in the range of 60 to 260 ° C. under normal pressure, and may be linear or branched as long as it is generally used in cosmetics. . For example, light isoparaffin, light liquid isoparaffin, isododecane, isohexadecane, and the like can be mentioned. Examples of commercially available products include IP solvent 1620, IP solvent 2028 (above, manufactured by Idemitsu Petrochemical Co., Ltd.), PERMETHYL 99A (manufactured by PRESPERS), and the like. Can be mentioned. These volatile hydrocarbon oils may be used alone or in combination of two or more.

  (C) component in this invention is used suitably for what is 50% or more in oil-based solid cosmetics, The content is preferably 50 to 98%, More preferably, it is 50 to 95%. Within this range, it is possible to obtain a light touch at the time of use and a moisturizing effect.

  When the oil-based solid cosmetic of the present invention is further blended with the component (d) oil-soluble film-forming agent in addition to the above essential components, water resistance and oil resistance are imparted, and cosmetic durability is improved. The oil-soluble film-forming agent can be used without particular limitation as long as it is usually blended in cosmetics. For example, trimethylsiloxysilicic acid, polymethylsilsesquioxane, silicone resins such as acrylic modified silicone, rosin modified phenolic resin, rosin acid resin such as rosin ester, candelilla resin, vinyl acetate resin, polyvinyl isobutyl ether, polybutene And oil-soluble resins such as polyisobutylene can be used, and one or more of these can be used. Among these, silicone resins, rosin acid resins, and polyisobutylene are preferably used in terms of forming a film that has excellent adhesion and is resistant to sweat and sebum. These oil-soluble film forming agents may be used alone or in combination of two or more.

  In the present invention, the content of the component (d) is preferably 1 to 20%, more preferably 1 to 10% in the oily solid cosmetic. Within this range, a non-sticky coating film and an excellent makeup-enhancing effect can be obtained.

  In the oily solid cosmetic composition of the present invention, in addition to the components (a) to (d), components (usually contained in the cosmetic composition) as necessary, as long as the effects of the present invention are not impaired. Oil components other than a) to (c), powders such as inorganic pigments, organic pigments and extender pigments, surfactants, water, polyhydric alcohols, lower alcohols, aqueous components such as humectants, water-soluble polymers, saccharides UV absorbers, antioxidants, anti-fading agents, preservatives, medicinal ingredients, stabilizers, pigments, fragrances and the like can be appropriately contained for imparting various effects.

As the oily component, other than components (a) to (d), carbonization is possible regardless of the properties of solid oil, semi-solid oil, liquid oil, etc. of origin such as animal oil, vegetable oil, synthetic oil and the like generally used in cosmetics. Examples include hydrogens, fats and oils, hydrogenated oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, and oily gelling agents.
Specifically, hydrocarbons such as liquid paraffin and squalane, oils and fats such as owl, olive oil, castor oil, mink oil and macadamian nut oil, waxes such as beeswax, gay wax and carnauba wax, isononyl isononanoate, Isotridecyl isononanoate, cetyl 2-ethylhexanoate, neopentyl glycol diethylhexanoate, propylene glycol dicaprate, isostearyl lactate, octyldodecyl lactate, oleyl lactate, stearyl lactate, isopropyl myristate, isopropyl palmitate, octyl palmitate, rosin Acid pentaerythritol ester, hydrogenated jojoba oil, glyceryl tribehenate, cholesterol fatty acid ester, phytosterol fatty acid ester, stearic acid, lauric acid, myristic Fatty acids such as behenic acid, isostearic acid and oleic acid, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol and behenyl alcohol, dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopenta Siloxane, octamethylcyclotetrasiloxane, high degree of polymerization methylphenyl polysiloxane, cross-linked methyl polysiloxane, polyoxy-modified organopolysiloxane, cross-linked polyether-modified methyl polysiloxane, methacryl-modified polysiloxane, stearyl-modified methyl polysiloxane, oleyl-modified Methylpolysiloxane, behenyl-modified methylpolysiloxane, polyvinylpyrrolidone-modified methylpolysiloxane, high degree of polymerization Silicone such as chilled polysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, cross-linked organopolysiloxane, fluorinated oils such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin Lanolin derivatives such as lanolin acetate, lanolin fatty acid isopropyl, lanolin alcohol, dextrin octoate, dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, fatty acid dextrin palmitate (palmitic acid / octanoic acid Dextrin, sucrose fatty acid ester, starch fatty acid ester, aluminum isostearate, potassium stearate, 12-hydroxystearic acid These include oily gelling agents, and the like, and one or more of them can be used.

  As a powder component, as long as it is a powder generally used in cosmetics, spherical, plate-like, needle-like shapes, fumes, fine particles, pigment grades, etc., porous, non-porous, etc. It is not particularly limited by the particle structure and the like, and examples thereof include inorganic powders, glitter powders, organic powders, pigment powders, metal powders, composite powders and the like. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, etc. Colored inorganic pigments, talc, muscovite, phlogopite, saucite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, aluminum oxide, magnesium oxide , Zirconium oxide, Silica, Aluminum silicate, Aluminum magnesium silicate, Calcium silicate, Barium silicate, Magnesium silicate, Calcium carbonate, Magnesium carbonate, Hydroxyapatite, Boron nitride etc. White body powder, Titanium dioxide coating Mica, titanium dioxide coated bismuth oxychloride, iron oxide mica Bright powder such as Tungsten, Bituminous treated mica titanium, Carmine treated Mica titanium, Bismuth oxychloride, Fish scale foil, Polyethylene terephthalate / aluminum / epoxy laminated powder, Polyethylene terephthalate / Polyolefin laminated film powder, Polyethylene terephthalate / Polymethyl methacrylate laminated film powder Body, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, silicone resin, fluorine resin, cellulose resin, polystyrene resin, styrene-acrylic copolymer resin, polypropylene resin, Organic polymer resin powder such as urethane resin, organic low molecular weight powder such as zinc stearate and N-acyl lysine, natural organic powder such as silk powder and cellulose powder, red 201, red 202 and red 205 Organic pigment powders such as Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Organic pigment powders such as yellow No. 5, green No. 3, blue No. 1 such as zirconium, barium or aluminum lake, or metal powders such as aluminum powder, gold powder, silver powder, fine titanium oxide coated mica titanium, fine zinc oxide coated Examples include composite powders such as mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, and zinc oxide-containing silicon dioxide. These powders can be used singly or in combination of two or more as required. Fluorine compounds, silicone compounds, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esthetics It is also possible to use a surface treatment by a known method using a rubber, wax, wax, surfactant, etc.

  As the surfactant, any surfactant that is generally used in cosmetics can be used. Nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Is mentioned. Examples include glycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, polyether-modified organopolysiloxane, lecithin and the like. It is done.

Examples of the aqueous component include, in addition to water, alcohols such as ethyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, 1,2-pentanediol, dipropylene glycol, and polyethylene glycol, glycerin, and diglycol. Examples include glycerols such as glycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose.
Examples of the ultraviolet absorber include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, such as 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone, 2-methoxyhexyl paramethoxycinnamate 2, 4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, hexyl diethylaminohydroxybenzoylbenzoate, bisethylhexyloxyphenol methoxyphenyl triazine and the like can be mentioned. Examples of the humectant include proteins, mucopolysaccharides, collagen, elastin, keratin and the like. Examples of the antioxidant include α-tocopherol and ascorbic acid. Examples of the beauty ingredients include vitamins and anti-inflammatory agents. Herbal medicines and the like, and examples of the preservative include paraoxybenzoic acid ester, phenoxyethanol, and 1,2 pentadiol.

  The oily solid cosmetics of the present invention are made up of lipsticks, lip glosses, lipstick base coats, lipstick overcoats, lip balms, lip treatments, eye liners, eye colors, eyebrow mascaras, blushers, hair sticks, hair waxes. It can be applied to hair cosmetics such as hair colors, basic cosmetics such as sunscreens, eye sticks, cleansings, and perfumes. Among them, since it has excellent appearance sustainability as well as transparency in appearance, it can be usefully used in makeup cosmetics. Above all, appearance transparency, excellent temporal stability, and feeling of use, which are remarkable features in the present invention product, are eye cosmetics such as eye colors and eye liners, lipsticks, lip glosses, lipstick base coats, lipstick overcoats. Lip cosmetics such as lip balms and lip treatments are preferred because they have particularly important qualities. Examples of the shape include a casting type into a dish or a jar pot, and a stick shape (stick shape).

  The oily solid cosmetic of the present invention does not have fluidity at 25 ° C., and can be applied to an oil-based oil whose main component is an oil agent and a water-in-oil type having an outer layer as a continuous phase of the oil agent, It is preferable that the amount is 1% or less, and it is oily substantially free of water.

  Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

Examples 1 to 8 and Comparative Examples 1 to 3: Oily solid eye color An oily solid eye color having the composition shown in Table 1 was produced by the following production method. The obtained oily solid eye color was evaluated for (a) hardness, (b) transparency of appearance, and (c) smoothness of elongation by the following methods. The results are also shown in Table 1.

* 1: GP-1 (Ajinomoto Co., Inc.)
* 2: Leopard KL2 (Chiba Flour Mills)
* 3: KIS-1010 (Sakamoto Pharmaceutical Co., Ltd.)
* 4: KEH-1010 (Sakamoto Pharmaceutical Co., Ltd.)
* 5: PERMETHYL 99A (made by PRESPERS)
* 6: SR1000 (made by Momentive Performance Materials Japan)
* 7: Metashine 1080RC-R (manufactured by Nippon Sheet Glass Co., Ltd.)

(Production method)
A: Components (1) to (11) are dissolved by heating at 130 ° C.
B: Components (12) to (14) are added to A and mixed uniformly.
C: After defoaming B, it was heated to 100 ° C. and directly poured into a jar, and after cooling, an oily solid eye color was obtained.

(Evaluation item)
(A) Hardness (b) Transparency of appearance (c) Smoothness of expansion

(Evaluation method)
(A) Using a rheometer manufactured by Fudo Kogyo Co., Ltd. for each sample after filling the hardness, a circular probe having a diameter of 10 mm is penetrated from the surface to a depth of 1.0 mm from the surface at a penetration speed of 6 cm / min. The maximum load value (g) was measured, and the value was evaluated according to the following absolute evaluation criteria.
<Absolute evaluation criteria>
(Judgment): (Maximum load value)
◎: 100 or more ○: 50 or more and less than 100 ×: less than 50

(B) Transparency of appearance A sheet of black characters (fonts: Times New Roman, font sizes 16 and 24) of a predetermined size is placed on the bottom of the jar container on a white background, and the composition obtained by heating and melting is placed on the paper. After pouring to a thickness, cooling and solidifying completely, it was evaluated according to the following absolute evaluation criteria whether the characters on the bottom surface could be visually recognized when viewed from directly above at 25 ° C.
<Absolute evaluation criteria>
(Judgment): (Evaluation)
◎: Characters with font size 16 can be recognized ○: Characters with font size 16 cannot be recognized, but characters with font size 24 can be recognized ×: Characters with font size 24 cannot be recognized

(C) Smoothness at the time of application Each of the samples was subjected to a use test by 20 professional panels. Each panel member applied each sample to the eyelid, and immediately after that, a score was assigned according to the following absolute evaluation criteria, an average value was calculated from the total score of all the panels, and a comprehensive judgment was made based on the following criteria.

<Absolute evaluation criteria>
(Score): (Evaluation)
4 points: Very smooth 3 points: Smooth 2 points: Normal 1 point: Slightly smooth 0 point: Slightly smooth <Criteria>
(Judgment): (Average score)
：: 3.5 points or more ○: 2.5 points or more and less than 3.5 points ×: less than 2.5 points In the present invention, it is judged that determination of ◯ or more is suitable.

As is apparent from Table 1, Examples 1 to 8 of the present invention have high hardness, which is the basic quality of oily solid cosmetics, and are highly transparent and excellent in aesthetic appearance, and further spread and expand. It was excellent in smoothness and had a feeling of use.
On the other hand, in Comparative Example 1 in which dextrin palmitate was used as a solidifying agent instead of the N-acylamino acid amide derivative of component (a), the hardness was low and the basic quality of the oily solid cosmetic was not satisfied, and component (b) In Comparative Example 2 containing other ester oil instead of polyglycerin fatty acid ester, the hardness was similarly low and it could not be used.
Moreover, the comparative example 3 which did not mix | blend a component (b) polyglyceryl fatty acid ester and used only (c) volatile hydrocarbon oil as liquid oil was inferior to smoothness of transparency and elongation spread.

Example 9: Lip gloss (stick shape)
(Ingredient) (%)
1. N-lauroyl-L-glutamic acid dibutylamide * 1 3
2. N-2-ethylhexanoyl-L-glutamic acid dibutylamide * 8 3
3. Polyglyceryl-2 triisostearate-15
4). Decaisostearate polyglyceryl-10 * 3 15
5). Lauroyl glutamate di (octyldodecyl / phytosteryl / behenyl) * 9 5
6). Light liquid isoparaffin * 10 Residual amount 7. Polymethylsilsesquioxane * 11 3
8. 2,6-Di-tert-butyl-para-cresol 0.1
9. Silicic anhydride 1
10. Red No. 202 0.1
11. Yellow No.4 0.1
12 Titanium oxide coated borosilicate (Ca / Al) 0.5
13. polyethylene terephthalate·
Polymethylmethacrylate laminated film powder * 12 0.5
14 Tocopherol acetate 0.1
15. Phenoxyethanol 0.3
16. Fragrance 0.1
* 8: EB-21 (Ajinomoto Co., Inc.)
* 9: El Dew PS-306 (Ajinomoto Co., Inc.)
* 10: IP solvent 1620 (made by Idemitsu Kosan Co., Ltd.)
* 11: SILFORM FLEXIBLE RESIN (made by Momentive Performance Materials Japan)
* 12: Aurora flakes red 0.1mm (manufactured by Kakuhachi Fish Foil Company)
(Production method)
A: Components (1) to (7) are uniformly dissolved at 120 to 130 ° C.
B: Components (8) to (16) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured directly into a lipstick container, and after cooling, a stick-like lip gloss was obtained.
The lip gloss of Example 9 was satisfactory in all points of hardness, transparency, and smoothness during application.

Example 10: Lip Gloss (Plate Casting)
(Ingredient) (%)
1. N-2-ethylhexanoyl-L-glutamic acid dibutylamide * 8 3
2. Polyglyceryl-2 diisostearate 15
3. Decaethylhexanoic acid polyglyceryl-10 * 4 15
4). Heavy liquid isoparaffin (kinematic viscosity at 30 ° C. 600,000 mm ² / s) * 135
5). Hexa (hydroxystearic acid / stearic acid / rosinic acid)
Dipentaerythrityl * 14 3
6). Dimethylpolysiloxane (25 ° C .: 10 mm ² / s) 2
7). Liquid paraffin 3
8). Isododecane * 5 remaining amount 9.2,6-di-tert-butyl-para-cresol 0.1
Methyl paraoxybenzoate 0.1
10. Silicic anhydride 1
11. Red No. 202 0.1
12 Water repellent and oil repellent Bengala coated mica titanium * 15 1
13. Rosemary extract 0.1
* 13: Pearl Ream 46 (Nippon Yushi Co., Ltd.)
* 14: Cosmall 168ARV (Nisshin Oillio Group)
* 15: FLAMENCO SPARKLE RED (BASF) 2% perfluoroalkyl phosphate diethanolamine salt treatment (production method)
A: Components (1) to (8) are uniformly dissolved at 120 to 130 ° C.
B: Components (9) to (13) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured into a metal pan. After cooling, lip gloss was obtained.
The lip gloss of Example 10 was satisfactory in terms of hardness, transparency, and smoothness during application.

Example 11: Lip balm (solid)
(Ingredient) (%)
1. N-lauroyl-L-glutamic acid dibutylamide * 15
2. Polypropylene * 16 0.5
3. Polyglyceryl tetraisostearate-2 * 17 20
4). Nonaisostearate polyglyceryl-10 * 18 10
5). Dimer dilinoleic acid Dimer dilinoleyl bisisostearyl * 19 3
6). Dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) * 20 2
7). Bisdiglyceryl polyacyl adipate-2 * 21 2
8). Isostearyl alcohol 1
9. Isododecane * 5 Remaining amount 10. Ethyl hexyl methoxycinnamate 3
11.2,6-di-tert-butyl-para-cresol 0.1
12 Methyl paraoxybenzoate 0.1
13. Silicic anhydride 1
14 Methyl methacrylate cross polymer powder * 22 1
15. Bengala 0.1
16. Natural vitamin E 0.1
17. Arnica extract 0.1
* 16: L-MODU S400 (made by Idemitsu Kosan Co., Ltd.)
* 17: Cosmall 44V (Nisshin Oilio Group)
* 18: IS-1009 (Sakamoto Pharmaceutical Co., Ltd.)
* 19: LUSPLAN DA-DD-IS (manufactured by Nippon Seika Co., Ltd.)
* 20: PLANDOOL-S (manufactured by Nippon Seika Co., Ltd.)
* 21: SOFTISAN649 (manufactured by SASOL)
* 22: Matsumoto Microsphere M-305 (average particle size 8 μm, manufactured by Matsumoto Yushi Seiyaku Co., Ltd.)
(Production method)
A: Components (1) to (10) are uniformly dissolved at 120 to 130 ° C.
B: Components (11) to (17) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured into a metal pan, and after cooling, an oily solid lip balm was obtained.
The lip balm of Example 11 was satisfactory in all points of hardness, transparency and smoothness when applied.

Example 12: cheek red (solid)
(Ingredient) (%)
1. N-lauroyl-L-glutamic acid dibutylamide * 1 2
2. N-2-ethylhexanoyl-L-glutamic acid dibutylamide * 8 2
3. Polyglyceryl-2 triisostearate-15
4). Decaisostearate polyglyceryl-10 * 23 15
5). Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl) * 24 5
6). (Vinyl dimethicone / lauryl dimethicone) cross polymer (isododecane dissolved product) * 25 3
7). Light liquid isoparaffin * 10 Remaining amount 8. Rosin acid pentaerythlit * 26 1
9. Organically modified clay mineral 0.5
10. Red 226 0.1
11. Yellow No. 4 aluminum lake 0.2
12 Black iron oxide 0.2
13. Fragrance 0.1
14.1,2-Pentanediol 0.5
* 23: NIKKOL Decaglyn 10-ISV (Nikko Chemicals)
* 24: PLANDOOL-G (Nippon Seika Co., Ltd.)
* 25: KSG-42 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 26: Esther gum HP (Arakawa Chemical Industries)
(Production method)
A: Components (1) to (8) are uniformly dissolved at 120 to 130 ° C.
B: Components (9) to (14) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured into a metal pan, and after cooling, a solid blusher was obtained.
The cheek red of Example 12 was satisfactory in all points of hardness, transparency, and smoothness during application.

Example 13: Eye color (component) (%)
1. N-lauroyl-L-glutamic acid dibutylamide * 14
2. Polyglyceryl-2 diisostearate 15
3. Polyglyceryl dekaleate-10 * 27 15
4). Diisostearic acid dimer linoleil * 28 5
5). Polybutene (30 ° C .: 400,000 mm ² / s) 3
6). Isododecane * 5 Remaining 7 (Acrylates / Dimethicone) Copolymer * 29 2
8. 2,6-Di-tert-butyl-para-cresol 0.1
9. Methyl paraoxybenzoate 0.1
10. Silylated Anhydrous Silicic Acid 0.5
11. (Vinyl dimethicone / methicone silsesquioxane)
Cross polymer * 30 1
12 Red 226 0.5
13. Ultramarine 0.5
14 Silicone treatment (3%) Titanium oxide treatment Synthetic phlogopite * 31 3
* 27: NIKKOL Decaglyn 10-OV (manufactured by Nikko Chemicals)
* 28: LUSPLAN DD-IS (manufactured by Nippon Seika Co., Ltd.)
* 29: KP-540 (Shin-Etsu Chemical Co., Ltd.)
* 30: KSP-100 (Shin-Etsu Chemical Co., Ltd.)
* 31: Prominence SF (Nippon Koken Co., Ltd.)
(Production method)
A: Components (1) to (7) are uniformly dissolved at 120 to 130 ° C.
B: Components (8) to (14) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured into a jar, and after cooling, a solid eye color was obtained.
The eye color of Example 13 was satisfactory in terms of hardness, transparency, and smoothness during application.

Example 14: Eyeliner (solid)
(Ingredient) (%)
1. N-lauroyl-L-glutamic acid dibutylamide * 1 3
2. Decaisostearate polyglyceryl-10 * 3 10
3. Decaethylhexanoic acid polyglyceryl-10 * 4 10
4). Acetic acid liquid lanolin 5
5). Polybutene (30 ° C .: 400,000 mm ² / s) 5
6). Isododecane * 5 Remaining 7 Polymethylsilsesquioxane * 11 5
8). Trimethylsiloxysilicic acid * 6 5
9. 2,6-di-tert-butyl-para-cresol 0.1
10. Methyl paraoxybenzoate 0.1
11. Silicic anhydride 1
12 Polymethylsilsesquioxane * 32 1
13. Red 226 0.01
14 Polyethylene terephthalate, aluminum,
Epoxy laminated powder * 33 3
15. Titanium oxide coated borosilicate (Ca / Al) * 7 1
16. polyethylene terephthalate·
Polymethylmethacrylate laminated film powder * 12 1
* 32: Tospearl 150KA (made by Momentive Performance Materials Japan)
* 33: Aluminum flake silver 0.15 mm (manufactured by Kakuhachi Phosphor Leaf Company)
(Production method)
A: Components (1) to (8) are uniformly dissolved at 120 to 130 ° C.
B: Components (9) to (16) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured into a metal pan. After cooling, a solid eyeliner was obtained.
The eyeliner of Example 14 was satisfactory in terms of hardness, transparency, and smoothness during application.

Example 15: Eye cream (solid stick shape)
(Ingredient) (%)
1. N-lauroyl-L-glutamic acid dibutylamide * 1 3
2. N-2-ethylhexanoyl-L-glutamic acid dibutylamide * 8 3
3. Polyglyceryl-2 triisostearate-10
4). Polyglyceryl-2 diisostearate-10
5). Heavy fluid isoparaffin (30 ° C kinematic viscosity 600,000 mm ² / s) 5
6). α-Olefin oligomer * 34 3
7). N-lauroyl-L-glutamate di (phytostale 2-octyldodecyl) * 35 5
8). (PEG-15 / lauryl dimethicone) cross polymer (isododecane dissolved product) * 362
9. Vaseline 5
10. Light liquid isoparaffin * 10 Remaining amount 11. Smoke-like silica 0.5
12 Mica titanium 1
13. Dipropylene glycol 0.5
14.1,3-Butylene glycol 1
15. Fragrance 0.1
* 34: SILKFLO364NF (LIPO CHEMICALS INC)
* 35: El Dew PS-203 (Ajinomoto Co., Inc.)
* 36: KSG-320 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A: Components (1) to (10) are uniformly dissolved at 120 to 130 ° C.
B: Components (11) to (15) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured into a jar, and after cooling, a stick-shaped eye cream was obtained.
The eye cream of Example 15 was satisfactory in all points of hardness, transparency, and smoothness during application.

Example 16: Kneaded perfume (solid type)
(Ingredient) (%)
1. N-lauroyl-L-glutamic acid dibutylamide * 15
2. Polyglyceryl-2 triisostearate-10
3. Decaisostearate polyglyceryl-10 * 3 10
4). Dialkyl carbonate (C14,15) * 37 5
5). Vaseline 5
6). Isododecane * 5 Remaining 7 Dextrin isostearate * 38 2
8. 2,6-Di-tert-butyl-para-cresol 0.1
9. Methyl paraoxybenzoate 0.1
10. Silicic anhydride 1
11. Bengala 0.01
12 Red 226 0.01
13. Mica titanium * 39 1
14 Natural vitamin E 0.1
15. Fragrance 10
* 37: LIALCARB SR-1000 / R (Mitsui Chemicals Fine)
* 38: Unifilma HV-Y (Chiba Flour Mills)
* 39: Flamenco sparkle red (BASF) 5% methylpolysiloxane treatment (manufacturing method)
A: Components (1) to (7) are uniformly dissolved at 120 to 130 ° C.
B: Components (8) to (15) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured into a metal pan, and after cooling, a solid kneaded perfume was obtained.
The kneaded perfume of Example 16 was satisfactory in all points of hardness, transparency, and smoothness during application.

Example 17: Hair wax (component) (%)
1. N-lauroyl-L-glutamic acid dibutylamide * 1 3
2. N-2-ethylhexanoyl-L-glutamic acid dibutylamide * 8 3
3. Polyglyceryl-2 triisostearate-10
4). Polyglyceryl-2 diisostearate-10
5). Heavy fluid isoparaffin (30 ° C kinematic viscosity 600,000 mm ² / s) 5
6). Dipentaerythrityl pentaisostearate * 40 5
7). N-lauroyl-L-glutamate di (octyldodecyl / phytosteil / behenyl) * 41 5
8). Vaseline 5
9. Isododecane * 5 Remaining amount 10. (Cyclohexyl methacrylate / ethyl hexyl methacrylate) copolymer (light liquid isoparaffin solution) * 42 3
11. Disteadimonium hectorite 1
12 Blue No. 1 0.01
13.1,3-Butylene glycol 2
14 Preservative (1,2 pentanediol) 0.1
15. Fragrance 0.3
* 40: Saracos DP-518N (Nisshin Oillio Group)
* 41: El Dew PS-304 (Ajinomoto Co., Inc.)
* 42: Plus size L-250 (manufactured by Kanayo Chemical Co., Ltd.)
(Production method)
A: Components (1) to (10) are uniformly dissolved at 120 to 130 ° C.
B: Components (11) to (15) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated to 100 ° C. and poured into a jar, and after cooling, a hair wax was obtained.
The hair wax of Example 17 was satisfactory in all points of hardness, transparency, and smoothness during application.

Claims (5)

The following components (a) to (c);
(A) an N-acylamino acid amide derivative represented by the following formula (1);
(B) polyglycerol fatty acid ester;
(C) volatile hydrocarbon oils;
Oily solid cosmetic containing
(In the formula, R ¹ and R ² each independently represent a hydrocarbon group having 1 to 26 carbon atoms, R ³ represents a hydrocarbon group having 7 to 17 carbon atoms, and n represents 1 or 2)   The oily solid cosmetic according to claim 1, comprising 0.5 to 6% by mass of the component (a).   The oily solid cosmetic according to claim 1 or 2, wherein a mass ratio (a) :( b) of the component (a) to the component (b) is from 1: 1 to 1: 100.   The oily solid cosmetic according to any one of claims 1 to 3, comprising 50 to 98% by mass of the component (c). The oily solid cosmetic according to any one of claims 1 to 4, further comprising a component (d) an oil-soluble film-forming agent.