JP2016004760A - Organic light-emitting device and organic display device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an organic light-emitting device and an organic display device that can suppress deterioration of a layer composed of an oxide semiconductor, and an organic film that are included in a configuration, and that has excellent light emitting characteristics over a long time period.SOLUTION: In a display panel, an encapsulation layer 111 is formed so as to cover an upper part in a Z-axis direction of an organic film, such as an organic light-emitting layer, in a display region. The encapsulation layer 111 has a configuration that an AlOx film 1111, an SiN film 1112, and an AlOx film 1113 are sequentially laminated from a lower side in the Z-axis direction. The encapsulation layer 111 is extended to a part between a substrate 101 and an encapsulation wall 116, in a surrounding region 10b. The AlOx film 1111 is interposed between the substrate 101 and the SiN film 1112. An edge end of the SiN film 1112 is sandwiched between the AlOx film 1111 and the AlOx film 1113. The SiN film 1112 is formed by using the CVD method, and the AlOx films 1111 and 1113 are formed by using the ALD method.

Description

  The present invention relates to an organic light emitting device and an organic display device, and more particularly to a technique for suppressing deterioration of an organic film such as an organic light emitting layer.

In recent years, development for practical application of organic light-emitting devices such as organic EL (electroluminescence) panels has been actively conducted. The configuration of the organic EL panel according to the prior art will be described with reference to FIG.
An organic EL panel as an example shown in FIG. 16 is an active matrix display panel, and a TFT layer 902 is formed on the main surface of a substrate 901. The TFT layer 902 includes gate electrodes 9021 and 9022, a gate insulating film 9023, channel layers 9024 and 9025, a protective film 9026, source electrodes 9027 and 9028, drain electrodes 9028 and 9029, and a passivation film 9030. Electrode 9023. In the TFT layer 902, an oxide semiconductor containing at least one of In, Zn, and Sn is used as a constituent material of the channel layers 9024 and 9025 (see Patent Document 1).

An anode 904 and a hole injection layer 905 are sequentially stacked on the TFT layer 902 with an insulating layer 903 interposed therebetween. The anode 904 is electrically connected to the connection electrode 9032 in the TFT layer 902 through a contact hole opened in the insulating layer 904. Banks 906 are stacked on the hole injection layer 905 and on the exposed upper surface of the insulating layer 903.
A hole transport layer 907, an organic light emitting layer 908, and an electron transport layer 909 are sequentially stacked in the opening formed by the bank 906. A cathode 910 and a sealing layer 911 are sequentially stacked on the electron transport layer 909 and the exposed top surface of the bank 906. Here, SiN or SiON is used as a constituent material of the sealing layer 911 (see Patent Document 2).

A color filter layer 913 and a black matrix layer 914 are formed on the sealing layer 911 with a resin layer 912 interposed therebetween. The color filter layer 913 and the black matrix layer 914 are formed on the lower surface of the substrate 915 in the Z-axis direction.
Although not shown, a sealing wall (seal layer) is formed on the outer edge of the organic EL panel so as to surround the display area in plan view. The sealing wall is provided in a state of sealing between the substrate 901 and the substrate 902 (see Patent Document 3).

JP 2008-166716 A JP 2000-223264 A JP 2007-103317 A

In the organic light emitting device according to the prior art including the organic EL panel, there are two problems, that is, deterioration of the oxide semiconductor in the TFT layer and intrusion of moisture, oxygen, and the like from between the substrate and the sealing wall.
Degradation of the oxide semiconductor layer in the TFT layer, which is the first problem, occurs when hydrogen is desorbed from the sealing layer formed by CVD or the like and reaches the channel layer made of the oxide semiconductor. it is conceivable that.

It is considered that the intrusion of moisture, oxygen, etc. from between the substrate and the sealing wall, which is the second problem, occurs when the adhesion between the substrate and the sealing wall is insufficient. Thereby, the organic film contained in a structure deteriorates.
The present invention has been made in view of the above-described problems, and an organic light-emitting device having excellent light-emitting characteristics over a long period of time, in which deterioration of a layer made of an oxide semiconductor and an organic film contained in the structure are suppressed, and An object is to provide an organic display device.

An organic light emitting device according to an aspect of the present invention includes a first substrate, a second substrate, a first functional unit, a second functional unit, a sealing wall, a first coating film, and a second coating unit. And an intermediate film.
The first and second substrates are opposed to each other with a space therebetween.
The first functional unit is disposed in a gap between the first substrate and the second substrate, and is interposed between the first and second electrodes and the first electrode and the second electrode. And an organic light emitting layer.

The second functional portion is disposed between the first substrate and the first functional portion, and has a layer including at least an oxide semiconductor (hereinafter referred to as an “oxide semiconductor layer”) in the configuration.
The sealing wall is a gap between the first substrate and the second substrate, and surrounds a region where the first functional unit and the second functional unit are arranged in a plan view, and the first function The region where the part and the second functional part are arranged is sealed.

The first coating film is a gap between the first substrate and the second substrate, and is disposed in a state of covering the second substrate side with respect to the first functional unit and the second functional unit, and is nitrided Including silicon or silicon oxynitride.
The second coating film is disposed between the first coating film and the oxide semiconductor layer in the second functional part and covers the oxide semiconductor layer in the second functional part, and is made of aluminum oxide.

  The intermediate film is interposed between the first substrate and the sealing wall and is made of aluminum oxide.

  In the organic light-emitting device according to the above aspect, the first light-emitting device has a gap between the first substrate and the second substrate, and covers the second substrate side with respect to the first functional unit and the second functional unit. A coating film is formed. Since the first coating film is made of silicon nitride or silicon oxynitride, it is possible to effectively suppress the intrusion of moisture and oxygen into the first functional part and the second functional part. For this reason, it is excellent from a viewpoint of protection of the organic film in each part of the 1st functional part and the 2nd functional part.

  In the organic light emitting device according to the above aspect, the second coating film is formed between the first coating film and the oxide semiconductor layer so as to cover the oxide semiconductor layer. Since the second coating film is made of aluminum oxide, it is possible to effectively suppress hydrogen from entering the oxide semiconductor layer included in the second functional part. For this reason, it is excellent from the viewpoint of protecting the oxide semiconductor layer in the second functional part.

  Moreover, in the organic light emitting device according to the above aspect, an intermediate film is disposed between the first substrate and the sealing wall. Since the intermediate film is made of aluminum oxide, the adhesion between the first substrate and the sealing wall can be improved. For this reason, the penetration | invasion of the water | moisture content and oxygen from between a 1st board | substrate and a sealing wall can be suppressed effectively, and it is from a viewpoint of protection of the organic film in each part of a 1st function part or a 2nd function part. Are better.

  As described above, the organic light-emitting device according to the above aspect has excellent emission characteristics over a long period of time, with the deterioration of the layer made of an oxide semiconductor and the organic film included in the configuration being suppressed.

1 is a schematic block diagram showing a schematic configuration of an organic EL display device 1 according to an embodiment of the present invention. 2 is a schematic plan view of the display panel 10 viewed from above. 4 is a schematic cross-sectional view showing a partial configuration of a display region 10a in the display panel 10. FIG. 4 is a schematic cross-sectional view showing a partial configuration of an surrounding area 10b in the display panel 10. FIG. 4 is a schematic cross-sectional view showing a partial configuration of an surrounding area 10b in the display panel 10. FIG. (A) is a figure which shows typically the structure in the display area 10a of the display panel 10 which concerns on embodiment, (b) is a figure which shows typically the structure in the display area of the display panel which concerns on a comparative example. It is. (A) is a figure which shows typically the structure of the sealing layer 111 which concerns on the sample 1, (b) is a figure which shows typically the structure of the sealing layer 121 which concerns on the sample 2, (c (A) is a figure which shows typically the structure of the sealing layer 131 which concerns on the sample 3, (d) is a figure which shows typically the structure of the sealing layer 911 which concerns on the sample 4. FIG. It is a characteristic view which shows the relationship between the temperature and the amount of desorption hydrogen in each of samples 1-4 measured using the TDS method. (A) is a characteristic figure which shows the TFT characteristic at the time of employ | adopting the sealing layer 911 which concerns on the sample 4, (b) is a TFT characteristic at the time of employ | adopting the sealing layer 111 which concerns on the sample 1. FIG. (A) is a figure which shows typically the structure of the surrounding area in the display panel which concerns on the sample 11, (b) is a figure which shows typically the structure of the surrounding area in the display panel which concerns on the sample 14 is there. And the epoxy resin layer is a table showing the measurement results of the respective peel strength of the glass substrate, SiN film, Al ₂ O ₃ film. (A) is a figure which shows typically the structure of the go area | region in the display panel which concerns on the modification 1, (b) shows typically the structure of the go area in the display panel which concerns on the modification 2. FIG. (A) is a figure which shows typically the structure of the go area | region in the display panel which concerns on the modification 3, (b) shows typically the structure of the go area in the display panel which concerns on the modification 4. FIG. (A) is a figure which shows typically the structure of the go area | region in the display panel which concerns on the modification 5, (b) shows typically the structure of the go area in the display panel which concerns on the modification 6. FIG. (A) is a figure which shows typically the structure of the go area | region in the display panel which concerns on the modification 7, (b) shows typically the structure of the go area | region in the display panel which concerns on the modification 8. FIG. It is a schematic cross section which shows the structure of the display panel which concerns on a prior art. It is a schematic cross section which shows the structure of the surrounding area | region in a display panel.

[Adhesion between substrate and sealing wall]
The inventors of the present invention examined the adhesion between the substrate and the sealing wall when creating each aspect of the present invention. This will be described with reference to FIG.
As shown in FIG. 17, at the edge of the display panel, the space between the substrate 901 and the substrate 915 is sealed with a sealing wall 916. In FIG. 17, the end edge portion 9033 a of the lead wiring 9033 and the end edge portion 9031 a of the passivation film 9031 are extended from the sealing wall 916 to the end portion of the substrate 901. As the display panel is narrowed, the end edge portion 911a of the sealing layer 911 may be positioned between the substrate 901 and the sealing wall 916.

  Thus, when the edge 911a of the sealing layer 911 made of SiN or SiON is interposed between the substrate 901 and the sealing wall 916, the adhesion between the substrate 901 and the sealing wall 916 is improved. Will fall. In particular, as indicated by the arrow D, when the edge 911b of the sealing layer 911 is positioned between the substrate 901 and the sealing wall 916, the sealing wall 916 is separated from the surface 901a of the substrate 901. It becomes easy to peel off.

Note that FIG. 17 illustrates a state in which the end edge portion 911a of the sealing layer 911 is interposed between the substrate 901 and the sealing wall 916, but the sealing layer 911 is not necessarily interposed. However, it is the same that it is required to improve the adhesion between the substrate 901 and the sealing wall 916.
In addition, it is desirable that the adhesiveness between the surface 915a of the substrate 915 and the sealing wall 916 disposed above the Z-axis direction is higher, but for this, the organic layer and the oxide semiconductor layer are formed by forming the sealing layer 911. This is not always necessary.

[Embodiments of the present invention]
An organic light emitting device according to an aspect of the present invention includes a first substrate, a second substrate, a first functional unit, a second functional unit, a sealing wall, a first coating film, and a second coating unit. And an intermediate film.
The first and second substrates are opposed to each other with a space therebetween.
The first functional unit is disposed in a gap between the first substrate and the second substrate, and is interposed between the first and second electrodes and the first electrode and the second electrode. And an organic light emitting layer.

The second functional unit is disposed between the first substrate and the first functional unit, and has at least an oxide semiconductor layer in the configuration.
The sealing wall is a gap between the first substrate and the second substrate, and surrounds a region where the first functional unit and the second functional unit are arranged in a plan view, and the first function The region where the part and the second functional part are arranged is sealed.

The first coating film is a gap between the first substrate and the second substrate, and is disposed in a state of covering the second substrate side with respect to the first functional unit and the second functional unit, and is nitrided Including silicon or silicon oxynitride.
The second coating film is disposed between the first coating film and the oxide semiconductor layer in the second functional part and covers the oxide semiconductor layer in the second functional part, and is made of aluminum oxide.

The intermediate film is interposed between the first substrate and the sealing wall and is made of aluminum oxide.
In the organic light-emitting device according to the above aspect, the first light-emitting device has a gap between the first substrate and the second substrate, and covers the second substrate side with respect to the first functional unit and the second functional unit. A coating film is formed. Since the first coating film is made of silicon nitride or silicon oxynitride, it is possible to effectively suppress the intrusion of moisture and oxygen into the first functional part and the second functional part. For this reason, it is excellent from a viewpoint of protection of the organic film in each part of the 1st functional part and the 2nd functional part.

  In the organic light emitting device according to the above aspect, the second coating film is formed between the first coating film and the oxide semiconductor layer so as to cover the oxide semiconductor layer. Since the second coating film is made of aluminum oxide, it is possible to effectively suppress hydrogen from entering the oxide semiconductor layer included in the second functional part. For this reason, it is excellent from the viewpoint of protecting the oxide semiconductor layer in the second functional part.

  Moreover, in the organic light emitting device according to the above aspect, an intermediate film is disposed between the first substrate and the sealing wall. Since the intermediate film is made of aluminum oxide, the adhesion between the first substrate and the sealing wall can be improved. For this reason, the penetration | invasion of the water | moisture content and oxygen from between a 1st board | substrate and a sealing wall can be suppressed effectively, and it is from a viewpoint of protection of the organic film in each part of a 1st function part or a 2nd function part. Are better.

As described above, the organic light-emitting device according to the above aspect has excellent emission characteristics over a long period of time, with the deterioration of the layer made of an oxide semiconductor and the organic film included in the configuration being suppressed.
In the organic light emitting device according to another aspect of the present invention, in the above aspect, the second coating film is in contact with the first coating film. Thus, by disposing the second coating film in contact with the first coating film, hydrogen degassing from the first coating film can be suppressed by the second coating film immediately below, Degradation of the oxide semiconductor layer in the second functional unit can be more effectively suppressed.

  Moreover, in the organic light-emitting device which concerns on another aspect of this invention, the 2nd coating film and the intermediate film are continuing in the said aspect. Thus, if the structure with which the 2nd coating film and the intermediate film are continuing is employ | adopted, it is not necessary to form an intermediate film separately from a 2nd coating film, and the man-hour concerning manufacture can be reduced. However, it is not always necessary to adopt a configuration in which the second coating film and the intermediate film are continuous, and another configuration may be used.

  In the organic light-emitting device according to another aspect of the present invention, in the above configuration, at least a part of the edge portion of the first coating film extends below the sealing wall, and extends below the sealing wall. The edge part of the provided 1st coating film is arrange | positioned between the intermediate film and the sealing wall. As described above, even if the first coating film made of SiN or SiON extends to the bottom of the sealing wall, the intermediate film is interposed between the first coating film and the substrate. High adhesion between the substrate 1 and the sealing wall can be ensured. Therefore, it is desirable to promote narrowing of the device frame.

  In the organic light emitting device according to another aspect of the present invention, in the above aspect, the organic light emitting device is disposed between the second substrate and the first coating film so as to cover at least a part of the first coating film. And a third coating film made of aluminum oxide. As described above, if the third coating film is arranged so as to cover at least a part of the upper surface of the first coating film, even if the surface of the first coating film has irregularities, the planarization is performed. Is planned. Therefore, undesired refraction of emitted light can be suppressed, and the light extraction efficiency can be improved.

Further, by disposing the third coating film on the first coating film, it is possible to more effectively suppress the entry of hydrogen from the outside. Therefore, deterioration of the oxide semiconductor layer in the second functional unit can be suppressed.
Moreover, in the organic light emitting device according to another aspect of the present invention, in the above aspect, at least a part of the edge portion of the third coating film extends to the bottom of the sealing wall, and to the bottom of the sealing wall. The edge part in the extended 3rd coating film is arrange | positioned between the intermediate film and the sealing wall. Thus, the edge part of the 3rd coating film extended under the sealing wall is arrange | positioned between an intermediate film and a sealing wall, and a 1st board | substrate, a sealing wall, It is easy to ensure the total film thickness of the intermediate film and the third coating film between the two. Therefore, the adhesion between the first substrate and the sealing wall can be more reliably maintained, and moisture and oxygen can be more reliably suppressed from entering the boundary.

  Moreover, in the organic light-emitting device which concerns on another aspect of this invention, in the said aspect, the edge of a 1st coating film is arrange | positioned in the state pinched | interposed between the intermediate film and the 3rd coating film. When the edge of the first coating film made of SiN or SiON is located between the first substrate and the sealing wall, the adhesion between the first substrate and the sealing wall is likely to be lowered and easily peeled off. . On the other hand, the peeling of the first substrate and the sealing wall can be suppressed by sandwiching the edge of the first coating film between the intermediate film and the third coating film. Therefore, the adhesion between the first substrate and the sealing wall can be improved, and moisture and oxygen can be reliably prevented from entering from the boundary.

  In the organic light emitting device according to another aspect of the present invention, in the above aspect, the second coating film is a film formed by using an atomic layer deposition (ALD) method. Thus, hydrogen permeation can be effectively suppressed by using the second coating film as a film formed using the ALD method. Therefore, even when hydrogen is desorbed from the first coating film, entry into the oxide semiconductor layer in the second functional unit can be suppressed, and deterioration of the oxide semiconductor layer can be reliably suppressed.

An organic display device according to one embodiment of the present invention includes a display panel, a control drive circuit connected to the display panel,
Is provided. And as a display panel, the device structure which concerns on the aspect in any one of the above is employ | adopted. Accordingly, the organic display device according to one embodiment of the present invention can also achieve the same effect as described above.

[Embodiment]
Hereinafter, the configuration of the organic EL display device 1 according to the embodiment will be described with reference to the drawings.
1. Schematic Configuration A schematic configuration of the organic EL display device 1 according to the present embodiment will be described with reference to FIGS.

As shown in FIG. 1, the organic EL display device 1 according to the present embodiment as an organic display device includes a display panel 10 and a drive control circuit unit 20 connected thereto. The display panel 10 is a kind of organic display device, and is an organic EL panel using an electroluminescence phenomenon of an organic material.
As shown in FIG. 2, the display panel 10 includes a display area 10a and an surrounding area 10b surrounding the area in plan view. Although not shown, in the display region 10a, a plurality of subpixels are two-dimensionally arranged in a plane direction configured by the X-axis direction and the Y-axis direction. In this embodiment, as an example, one pixel (pixel unit) is formed by combining three subpixels of an adjacent red (R) subpixel, a green (G) subpixel, and a blue (B) subpixel. ).

Returning to FIG. 1, the drive / control circuit unit 20 in the organic EL display device 1 includes four drive circuits 21 to 24 and one control circuit 25. The arrangement relationship between the display panel 10 and the drive / control circuit unit 20 in the organic EL display device 1 is not limited to the form shown in FIG.
In addition, the configuration of the pixel (pixel portion) is not limited to the above-described form of the combination of three subpixels, and one pixel is configured by a combination of four or more subpixels. It is good.

2. Configuration in Display Area 10a A configuration in the display area 10a of the display panel 10 will be described with reference to FIG.
As shown in FIG. 3, the display panel 10 has a configuration in which a plurality of layers are stacked on a TFT substrate 100 as a base. FIG. 3 schematically shows only one subpixel 100 portion extracted from the configuration of the display region 10 a in the display panel 10.

As shown in FIG. 3, in each subpixel 100 in the display panel 10, a TFT layer 102 is formed on the main surface of the substrate 101. In the present embodiment, as an example of the TFT layer 102, each subpixel 100 includes a two-transistor element portion.
The TFT layer 102 includes gate electrodes 1021 and 1022, a gate insulating film 1023, channel layers 1024 and 1025, a protective film 1026, source electrodes 1027 and 1030 and drain electrodes 1028 and 1029, a passivation film 1031, and a connection electrode 1032. The gate electrodes 1021 and 1022 are disposed on the main surface of the substrate 101 and are spaced from each other in the X-axis direction. The gate insulating film 1023 is formed so as to cover the gate electrodes 1021 and 1022, and the channel layers 1024 and 1025 are disposed on the gate insulating film 1023 so as to correspond to the gate electrodes 1021 and 1022. The protective film 1026 is formed so as to cover the channel layers 1024 and 1025 and the gate insulating film 1023, and the source electrodes 1027 and 1030 and the drain electrodes 1028 and 1029 are formed on the channel layers 1024 and 1025 on the protective film 1026. Correspondingly arranged.

  Source electrodes 1027 and 1030 and drain electrodes 1028 and 1029 are partially in contact with corresponding channel layers 1024 and 1025, and drain electrode 1028 is connected to gate electrode 1022. The source electrodes 1027 and 1030 and the drain electrodes 1028 and 1029 are covered with a passivation film 1031, and the source electrode 1030 is connected to the connection electrode 1032 exposed on the passivation film 1031.

  An insulating layer 103 is formed on the TFT layer 102, and an anode 104 and a hole injection layer 105 are formed thereon. A contact hole is formed in the insulating layer 103 at a position corresponding to the upper side of the connection electrode 1032 in the TFT layer 102, and the anode 104 and the connection electrode 1032 in the TFT layer 102 are connected through the contact hole. ing.

In this embodiment, as an example, the hole injection layer 105 is also divided into units of subpixels 100. However, the present invention is not limited to this. For example, a form in which adjacent subpixels 100 are continuous may be employed.
Next, a bank 106 is formed so as to cover the exposed surface of the insulating layer 103 and a part of the hole injection layer 105. Each bank 106 extends in a direction perpendicular to the paper surface, and defines a groove (concave portion) between adjacent banks 106.

In the present embodiment, a line bank structure is adopted as an example, but the present invention is not limited to this. For example, a pixel bank structure can be adopted.
As shown in FIG. 3, a hole transport layer 107, an organic light emitting layer 108, and an electron transport layer 109 are stacked in this order from the lower side in the Z-axis direction in the groove defined by the two adjacent banks 106. Yes. A cathode 110 and a sealing layer 111 are stacked in order from the lower side in the Z-axis direction so as to cover the electron transport layer 109 and the top surface of the bank 106.

  The sealing layer 111 in this embodiment is described as a film made of aluminum oxide (hereinafter referred to as an “AlOx film”) above and below a film made of silicon nitride (hereinafter referred to as “SiN film”) 1112. ) 1111 and 1113. Here, the SiN film 1112 is formed using a chemical vapor deposition (CVD) method, and the AlOx films 1111 and 1113 are formed using an atomic layer deposition (ALD) method. Yes.

In the present embodiment, the film thicknesses of the constituent films 1111 to 1113 of the sealing layer 111 in the display region 10a are set as follows as an example.
The thickness of the AlOx film ₁₁₁₁ t 1111; 10nm~100nm
Thickness t ₁₁₁₂ of the SiN film 1112; 100 nm to 2000 nm
The film thickness t ₁₁₁₃ of the AlOx film 1113; 10nm~100nm
As an example of “AlOx”, for example, Al ₂ O ₃ can be used, but the composition ratio of Al and O is not limited to this. Further, the composition ratio may be different depending on the region in the film. The same applies to the case where “AlOx” is described in this specification.

  A color filter panel is disposed on the sealing layer 111 with a resin layer 112 interposed therebetween. The color filter panel is a panel in which a color filter layer 113 and a black matrix layer 114 are formed on the lower main surface in the Z-axis direction of the substrate 115. The sealing layer 111 and the resin layer 112 and the resin layer 112, the color filter layer 113, and the black matrix layer 114 are in close contact with each other without a gap.

The display panel 10 according to the present embodiment is a top emission type display panel, and light is extracted upward in the Z-axis direction.
In the display panel 10, the other subpixels 100 in the display area 10a have the same configuration.
3. Configuration of Surrounding Area 10b The configuration of the surrounding area 10b in the display panel 10 will be described with reference to FIGS. The difference between FIG. 4 and FIG. 5 is whether or not lead-out wiring is arranged.

  As shown in FIG. 4, in the surrounding region 10b, an edge portion 1033a of the lead-out wiring 1033 connected to each of the gate electrode 1021, the source electrodes 1027 and 1030, and the drain electrodes 1028 and 1029 in the TFT layer 102 in a part thereof. Is extended to the edge of the substrate 101. A passivation film 1031 is covered on the lead-out wiring 1033, and the edge portion 1031 a of the passivation film 1031 is also extended to the edge portion of the substrate 101.

Note that the lead-out wiring 1033 and the passivation film 1031 are in a state along the main surface 101 a of the substrate 101 at the edge portion of the substrate 101.
In the surrounding region 10b, a sealing wall 116 is provided between the substrate 101 and the substrate 115, and the sealing wall 116 is in close contact with the main surface 115a on the lower side in the Z-axis direction with respect to the substrate 115. Yes. A resin layer 112 is formed in a region between the sealing layer 111 and the substrate 115 between the substrates 101 and 105 surrounded by the sealing wall 116 and forming a sealed region.

In the surrounding area 10 b, another member containing a getter agent can be disposed in the area between the substrates 101 and 115 surrounded by the sealing wall 116.
As indicated by an arrow A in FIG. 4, in the surrounding area 10 b, end edges 1111 a to 1113 a of the films 1111 to 1113 of the sealing layer 111 are interposed between the sealing wall 116 and the substrate 101. It is in a state. Among these, the edge 1112b of the edge 1111a of the SiN film 1112 is located in the middle of the sealing wall 116 in the X-axis width direction, and the upper and lower sides in the Z-axis direction are sandwiched between the AlOx film 1111 and the AlOx film 1113. It is in the state.

  Similarly, as indicated by an arrow B in FIG. 6, a part of each of the edge portions 1111 a to 1113 a of the three films 1111 to 1113 constituting the sealing layer 111 in a portion where the lead-out wiring 1033 does not exist in the surrounding region 10 b. Is sandwiched between the sealing wall 116 and the substrate 101. Also in this portion, the edge 1112b of the edge 1111a of the SiN film 1112 is located in the middle of the sealing wall 116 in the X-axis width direction, and the top and bottom in the Z-axis direction are the AlOx film 1111 and the AlOx film 1113. It is in a state of being sandwiched between.

In the present embodiment, the film thicknesses of the constituent films 1111 to 1113 (edge portions 1111a to 1113a) of the sealing layer 111 in the surrounding region 10b are set as follows as an example.
Film thickness t _1111a of the AlOx film 1111; 10 nm to 100 nm
Film thickness t _1112a of SiN film 1112; 100 nm to ₂₀₀₀ nm
Film thickness t _{1113a of AlOx} film 1113; 10 nm to 100 nm
4). Each constituent material of display panel 10 (1) Substrate 101
The substrate 101 is, for example, a glass substrate, a quartz substrate, a silicon substrate, molybdenum sulfide, copper, zinc, aluminum, stainless steel, magnesium, iron, nickel, gold, silver or other metal substrate, a gallium arsenide based semiconductor substrate, a plastic substrate, or the like. Etc. are used.

  As the plastic substrate, either a thermoplastic resin or a thermosetting resin may be used. For example, polyolefin such as polyethylene, polypropylene, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer (EVA), cyclic polyolefin, modified polyolefin, polyvinyl chloride, polyvinylidene chloride, polystyrene, polyamide, polyimide (PI), Polyamideimide, polycarbonate, poly- (4-methylbenten-1), ionomer, acrylic resin, polymethyl methacrylate, acrylic-styrene copolymer (AS resin), butadiene-styrene copolymer, polio copolymer (EVOH) ), Polyesters such as polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate (PEN), precyclohexane terephthalate (PCT), polyethers, polyether ketones Polyethersulfone (PES), polyetherimide, polyacetal, polyphenylene oxide, modified polyphenylene oxide, polyarylate, aromatic polyester (liquid crystal polymer), polytetrafluoroethylene, polyvinylidene fluoride, other fluororesins, styrene, polyolefin Various types of thermoplastic elastomers such as polyvinyl chloride, polyurethane, fluororubber, chlorinated polyethylene, epoxy resin, phenol resin, urea resin, melamine resin, unsaturated polyester, silicone resin, polyurethane, etc. Copolymers, blends, polymer alloys and the like are mentioned, and a laminate obtained by laminating one or more of these can be used.

(2) TFT layer 102
(2-1) Gate electrodes 1021, 1022
As the gate electrodes 1021 and 1022, for example, a stacked body of copper (Cu) and molybdenum (Mo) can be employed. Moreover, it can also be set as Cu single layer, and the laminated body of Cu and tungsten (W) is also employable. In addition to these, chromium (Cr), aluminum (Al), tantalum (Ta), niobium (Nb), silver (Ag), gold (Au), platinum (Pt), palladium (Pd), indium (In ), Nickel (Ni), neodymium (Nd), or other metals, or alloys thereof, or conductive metal oxides such as zinc oxide, tin oxide, indium oxide, gallium oxide, or indium tin oxide (ITO), indium oxide. Conductive metal decoding oxides such as zinc (IZO), aluminum zinc oxide (AZO), and gallium zinc oxide (GZO), or conductive polymers such as polyaniline, polypyrrole, polythiophene, polyacetylene or the like, hydrochloric acid, sulfuric acid, Acids such as sulfonic acid, Lewis acids such as phosphorus hexafluoride, arsenic pentafluoride, iron chloride, etc. Halogen atom etc., sodium, obtained by adding a dopant such as a metal atom such as potassium, or the like can be used composite material of the conductive dispersed carbon black or metal particles.

Further, a polymer mixture containing fine metal particles and conductive particles such as graphite may be used. These may be used alone or in combination of two or more.
(2-2) Gate insulating film 1023
As the gate insulating film 1023, for example, a stacked body of silicon oxide (SiO) and silicon nitride (SiN) can be employed. Note that the structure of the gate insulating film 1023 is not limited to this, and any other known organic material or inorganic material can be used as long as the material has electrical insulating properties.

As an organic material that can be used for forming the gate insulating film 1023, for example, an acrylic resin, a phenol resin, a fluorine resin, an epoxy resin, an imide resin, a novolac resin, or the like is used. You can also.
Examples of inorganic materials that can be used to form the gate insulating film 1023 include metal oxides such as silicon oxide, aluminum oxide, tantalum oxide, zirconium oxide, cerium oxide, zinc oxide, and cobalt oxide. Metal nitrides such as silicon nitride, aluminum nitride, zirconium nitride, cerium nitride, zinc nitride, cobalt nitride, titanium nitride and tantalum nitride, and metal decoding oxides such as barium strontium titanate and zirconium titanate. . These may be used alone or in combination of two or more.

Furthermore, what processed the surface by the surface treating agent (ODTS OTS HMDS (beta) PTS) etc. using the above materials is also contained.
(2-3) Channel layers 1024 and 1025
As the channel layers 1024 and 1025, for example, a layer made of amorphous indium gallium zinc oxide (IGZO) can be employed. As a constituent material of the channel layers 1024 and 1025, an oxide semiconductor containing at least one selected from indium (In), gallium (Ga), and zinc (Zn) can be used.

Note that the channel layer 1024 and the channel layer 1025 can have different constituent materials or can have different layer thicknesses.
(2-4) Protective film 1026
As the protective film 1026, for example, a film made of silicon oxide (SiO) can be employed. As a constituent material of the protective film 1026, silicon oxynitride (SiON), silicon nitride (SiN), aluminum oxide (AlOx), or the like can be used.

Further, the protective film 1026 can be formed by stacking a plurality of layers using the above materials.
(2-5) Source electrodes 1027 and 1030 and drain electrodes 1028 and 1029
As the source electrodes 1027 and 1030 and the drain electrodes 1028 and 1029, for example, a laminated body of copper manganese (CuMn), copper (Cu), and molybdenum (Mo) can be employed.

(2-6) Passivation film 1031
As the passivation film 1031, for example, a film made of silicon oxide (SiO) can be used.
In addition, as a constituent material of the passivation film 1031, silicon nitride (SiN), silicon oxynitride (SiON), or the like can be used. As the passivation film 1031, not only a single-layer structure made of the above materials but also a stacked body of silicon oxide (SiO), aluminum oxide (AlOx), and silicon nitride (SiN) can be used.

(2-7) Connection electrode 1032
As the connection electrode 1032, for example, a stacked body of copper (Cu) and indium tin oxide (ITO) can be used.
Note that the structure of the connection electrode 1032 is not limited to this, and can be appropriately selected from conductive materials.

(3) Insulating layer 103
The insulating layer 103 is formed using, for example, an organic compound such as polyimide, polyamide, or acrylic resin material. Here, the insulating layer 103 preferably has organic solvent resistance.
In addition, since the insulating layer 103 may be subjected to an etching process, a baking process, or the like during the manufacturing process, the insulating layer 103 is formed using a material having high resistance that does not excessively deform or deteriorate the process. It is desirable that

(4) Anode 104
As the anode 104, for example, a layer made of a metal material containing silver (Ag) or aluminum (Al) can be used. In the case of the top emission type display panel 10 according to the present embodiment, the surface portion thereof preferably has high reflectivity.
For the anode 104, not only a single layer structure made of a metal material as described above but also a laminate of a metal layer and a transparent conductive layer can be adopted. As a constituent material of the transparent conductive layer, for example, indium tin oxide (ITO), indium zinc oxide (IZO), or the like can be used.

(5) Hole injection layer 105
The hole injection layer 105 may be formed of, for example, an oxide such as silver (Ag), molybdenum (Mo), chromium (Cr), vanadium (V), tungsten (W), nickel (Ni), iridium (Ir), or PEDOT. It is a layer made of a conductive polymer material such as (mixture of polythiophene and polystyrene sulfonic acid).

Note that when a metal oxide is used as a constituent material of the hole injection layer 105, organic light emission is achieved by stabilizing holes or assisting the generation of holes as compared with the case of using a conductive polymer material such as PEDOT. It has a function of injecting holes into the layer 107 and has a large work function.
Here, when the hole injection layer 105 is made of a transition metal oxide, a plurality of levels can be obtained by taking a plurality of oxidation numbers. As a result, the hole injection becomes easy and the drive voltage is reduced. Can be reduced. In particular, it is desirable to use tungsten oxide (WO _X ) from the viewpoint of stably injecting holes and assisting the generation of holes.

(6) Bank 106
The bank 106 is formed using, for example, an organic material such as a resin and has an insulating property. Examples of the organic material used for forming the bank 106 include acrylic resin, polyimide resin, and novolac type phenol resin. The bank 106 can be subjected to fluorine treatment on the surface in order to give the surface water repellency.

Further, as the structure of the bank 106, not only a single layer structure as shown in FIG. 3 but also a multilayer structure of two or more layers can be adopted. In this case, the above materials can be combined for each layer, and an inorganic material and an organic material can be used for each layer.
(7) Hole transport layer 107
As the hole transport layer 107, for example, a layer formed using a high molecular compound having no hydrophilic group can be used. For example, polyfluorene or a derivative thereof, or a polymer compound such as polyarylamine or a derivative thereof that does not have a hydrophilic group can be used.

(8) Organic light emitting layer 108
The organic light emitting layer 108 has a function of emitting light by generating an excited state when holes and electrons are injected and recombined. As a material used for forming the organic light emitting layer 107, it is necessary to use a light emitting organic material that can be formed by a wet printing method.
Specifically, for example, an oxinoid compound, a perylene compound, a coumarin compound, an azacoumarin compound, an oxazole compound, an oxadiazole compound, a perinone compound, and pyrrolopyrrole described in Japanese Patent Publication (JP-A-5-163488). Compound, naphthalene compound, anthracene compound, fluorene compound, fluoranthene compound, tetracene compound, pyrene compound, coronene compound, quinolone compound and azaquinolone compound, pyrazoline derivative and pyrazolone derivative, rhodamine compound, chrysene compound, phenanthrene compound, cyclopentadiene compound, stilbene compound , Diphenylquinone compound, styryl compound, butadiene compound, dicyanomethylenepyran compound, dicyanomethylenethiopyran compound, fluorene In compounds, pyrylium compounds, thiapyrylium compounds, serenapyrylium compounds, telluropyrylium compounds, aromatic aldadiene compounds, oligophenylene compounds, thioxanthene compounds, anthracene compounds, cyanine compounds, acridine compounds, 8-hydroxyquinoline compound metal complexes, 2- It is preferably formed of a fluorescent substance such as a metal complex of a bipyridine compound, a Schiff salt and a group III metal complex, an oxine metal complex, or a rare earth complex.

(9) Electron transport layer 109
The electron transport layer 109 has a function of transporting electrons injected from the cathode 110 to the organic light emitting layer 108, and includes, for example, an oxadiazole derivative (OXD), a triazole derivative (TAZ), and a phenanthroline derivative (BCP, Bphen). ) Or the like.
(10) Cathode 110
The cathode 110 is formed using, for example, indium tin oxide (ITO) or indium zinc oxide (IZO). As in this embodiment, in the case of the display panel 10 according to this embodiment of the top emission type, it is necessary to be formed of a light transmissive material. About light transmittance, it is preferable that the transmittance | permeability shall be 80 [%] or more.

(11) Sealing layer 111
The sealing layer 111 has a function of suppressing exposure of an organic layer such as the organic light emitting layer 106 to moisture or exposure to air. And each film | membrane 1111 to 1113 which comprises the sealing layer 111 is comprised from the following materials.
(11-1) AlOx films 1111 and 1113
The AlOx films 1111 and 1113 are both made of aluminum oxide (AlOx). Although a detailed description of the formation method is omitted, in the present embodiment, at least the AlOx film 1111 disposed below the SiN film 1112 in the Z-axis direction is formed using an atomic layer deposition (ALD) method. ing.

(11-2) SiN film 1112
In this embodiment, the SiN film 1112 is formed using silicon nitride (SiN). As a film formed at the position in the structure of the sealing layer 111, silicon oxynitride (SiON) can be formed in addition to SiN.
In the top emission type display panel 10, the sealing layer 111 needs to have light transmittance as a whole.

(12) Resin layer 112
As the resin layer 112, for example, a layer formed using an epoxy resin can be used.
In addition to the above, for example, a silicone resin can be used as the constituent material of the resin layer 112. In addition, a getter agent for adsorbing moisture and oxygen can be mixed in the resin layer 112.

(13) Color filter layer 113
The color filter layer 113 is made of a known material that selectively transmits visible light in the wavelength range of each color of red (R), green (G), and blue (B). Each color filter layer 113 is formed based on, for example, an acrylic resin.
(14) Black matrix layer 114
The black matrix layer 114 is formed of, for example, an ultraviolet curable resin containing a black pigment that is excellent in light absorption and light shielding properties. Specific examples of the ultraviolet curable resin include acrylic resins.

(15) Substrate 115
The substrate 115 serving as the base of the color filter panel is formed using, for example, a glass substrate, a quartz substrate, a silicon substrate, a semiconductor substrate such as a gallium arsenide group, a plastic substrate, or the like, similar to the substrate 101.
(16) Sealing wall 116
The sealing wall 116 maintains adhesion between the substrates 101 and 115 (including adhesion between the TFT layer 102 and the passivation film 1031), a gap between the substrate 101 and the substrate 115, and an external pressure. In this case, it can be formed using a material selected in consideration of rigidity capable of maintaining the sealing structure. As a constituent material of the sealing wall 116, for example, a weldable glass frit, an epoxy resin, a urethane resin, an acrylic resin, or the like can be used.

5. Suppression of deterioration of organic film and oxide semiconductor layer in display region 10a A mechanism for suppressing deterioration of the organic film and oxide semiconductor layer in the display region 10a in the present embodiment will be described with reference to FIG. FIG. 6A is a diagram schematically showing the configuration of the display area 10a of the display panel 10 according to the present embodiment, and FIG. 6B is a display panel according to the above-described prior art as a comparative example. It is the figure which represented typically the structure of this display area.

(1) Suppression of deterioration of organic films such as organic light emitting layers 108 and 908 As shown in FIG. 6B, the structure of the display panel according to the comparative example employs a sealing layer 911 made of SiN. For this reason, it has a function of blocking moisture and oxygen to enter from above the panel to some extent, but it is not sufficient. For this reason, in the display panel according to the comparative example, the organic film such as the organic light emitting layer 908 provided below the display panel may be deteriorated.

  On the other hand, as shown in FIG. 6A, the display panel 10 according to the present embodiment has a three-layer structure in which the sealing layer 111 is sandwiched between the AlOx films 1111 and 1113 in the upper and lower directions of the SiN film 1112 in the Z-axis direction. It has been adopted. For this reason, it can suppress effectively that a water | moisture content or oxygen penetrate | invades into the side in which organic films, such as the organic light emitting layer 108, were formed rather than the display panel which concerns on the comparative example shown in FIG.6 (b). In addition, the suppression of moisture and oxygen penetration can also have the effect of suppressing cathode deterioration.

(2) Suppression of deterioration of oxide semiconductor (IGZO) layer in TFT layers 102 and 902 As described above, hydrogen is released from the sealing layer 911 made of SiN and formed using the CVD method. For this reason, as shown in FIG. 6B, hydrogen released from the sealing layer (SiN film) 911 also enters the TFT layer 902 side, and the channel layer (oxide semiconductor layer) in the TFT layer 902 Will deteriorate.

  On the other hand, as shown in FIG. 6A, in the display panel 10 according to the present embodiment, in the sealing layer 111, the lower side of the SiN film 1112 in the Z-axis direction, in other words, between the SiN film 1112 and the TFT layer 102. An AlOx film 1111 is provided therebetween. Therefore, even when hydrogen is released from the SiN film 1112, the released hydrogen is blocked by the AlOx film 1111, and intrusion into the channel layer (oxide semiconductor layer) in the TFT layer 102 can be suppressed. Therefore, in the display panel 10 according to this embodiment, deterioration of the oxide semiconductor layers (channel layers 1024 and 1025) of the TFT layer 102 due to hydrogen degassing from the SiN film 1112 can be effectively suppressed.

In this embodiment, since the AlOx film 1111 is formed by using the ALD method, hydrogen degassing from the AlOx film 1111 is difficult to occur, which is more excellent from this point.
(3) Light Extraction As shown in FIG. 6A, in the display panel 10 according to the present embodiment, in the sealing layer 111, an AlOx film 1113 is also provided above the SiN film 1112 in the Z-axis direction. . By forming the AlOx film 1113, the unevenness on the upper surface in the Z-axis direction of the SiN film 1112 is buried, which is excellent from the viewpoint of increasing the light extraction efficiency.

6). Suppression of deterioration of oxide semiconductor layer The effect of suppressing deterioration of the oxide semiconductor layer (channel layers 1024 and 1025) in the display panel 10 according to this embodiment was confirmed. The results will be described with reference to FIGS.
(1) Samples used for confirmation For confirmation, four types (samples 1 to 4) of display panel samples having the same structure other than that of the sealing layer were prepared and used.

(1-1) Sample 1
As shown in FIG. 7A, in the panel according to Sample 1, the sealing layer 111 is arranged in order from the lower side in the Z-axis direction (EL element part and TFT layer side), the AlOx film 1111, the SiN film 1112, and the AlOx film 1113. A structure in which is stacked is adopted. The structure of the sealing layer 111 is the same as that of the display panel 10 according to the above embodiment.

(1-2) Sample 2
As shown in FIG. 7B, in the panel according to Sample 2, the AlOx film 1211 and the SiN film 1212 were laminated in order from the lower side (EL element part and TFT layer side) of the sealing layer 121 in the Z-axis direction. The structure is adopted. That is, the AlOx film 1113 on the upper side in the Z-axis direction is omitted from the sealing layer 111 of the sample 1.

The film thickness of the AlOx film 1211 is the same as the film thickness of the AlOx film 1111 of sample 1, and the film thickness of the SiN film 1212 is the same as the film thickness of the SiN film 1112 of sample 1.
(1-3) Sample 3
As shown in FIG. 7C, the panel according to Sample 3 employs a sealing layer 131 having a single layer of AlOx film. The film thickness of the sealing layer 131 is the same as the film thickness of the AlOx film 1111 of Sample 1.

(1-4) Sample 4
As shown in FIG. 7D, the panel according to Sample 4 employs a single SiN film sealing layer 911. The structure of the sealing layer 911 is the same as the sealing layer structure in the display panel according to the conventional technique (see FIG. 16).
Note that the film thickness of the sealing layer 911 is the same as the film thickness of the SiN film 1112 of Sample 1.

(2) Desorption hydrogen amount evaluation result About the said samples 1-4, the amount of desorption hydrogen which penetrate | invaded the TFT layer was measured, and the result is shown in FIG. For the measurement of the amount of desorbed hydrogen, a temperature-programmed desorption gas spectroscopy (TDS) was used.
As shown in FIG. 8, the amount of desorbed hydrogen of sample 4 increases rapidly from when the temperature exceeds 90 ° C.

On the other hand, the amount of desorbed hydrogen in Samples 1 to 3 does not increase rapidly even when the temperature is raised to 90 ° C. or higher.
Looking at the amount of desorbed hydrogen of Samples 1 to 3 in more detail, Sample 3 that does not contain a SiN film is the lowest in the configuration of the sealing layer, and almost no change occurs when the temperature is raised. I couldn't see it. This indicates that the amount of desorbed hydrogen in samples 1, 2, and 4 is affected by the desorbed hydrogen from the SiN film.

(3) Shift of threshold voltage in TFT For Sample 1 and Sample 4, the threshold voltage of the initial TFT and the threshold voltage of the TFT after storage for 16 hours in an environment of 80 ° C. were measured. The result is shown in FIG.
As shown in FIG. 9A, in the panel of Sample 4, the threshold voltage of the TFT after storage under the above conditions is shifted by about 2 to 3 (V) with respect to the initial threshold voltage of the TFT. Yes.

On the other hand, as shown in FIG. 9B, in the panel of Sample 1, there was hardly any shift in the threshold voltage of the TFT after storage under the above conditions from the threshold voltage of the initial TFT.
(4) Consideration From the data of FIG. 8 and FIG. 9, in the sample 4 in which the AlOx film is not arranged between the SiN film and the TFT layer, the amount of desorbed hydrogen when the temperature is set to 90 ° C. or more is abrupt. Since the increase in the threshold voltage of the TFT is large, it can be considered that the desorbed hydrogen from the SiN film (sealing layer 911) has reached the oxide semiconductor layer (channel layer) in the TFT layer. .

On the other hand, in the samples 1 and 2 in which the AlOx films 1111 and 1211 are arranged between the SiN films 1112 and 1212 and the TFT layer, and in the sample 3 that does not include the SiN film in the configuration of the sealing layer 131, the temperature is 90 ° C. or more. Even in the region, there was almost no increase in the amount of desorbed hydrogen, and in Sample 1, the shift of the threshold voltage of the TFT was also suppressed.
In Sample 3, the SiN film is not included in the structure of the sealing layer 131. However, it is necessary to provide a sealing layer having a certain thickness in the sealing layer of an actual light emitting device. Conceivable. This is because it is necessary to form a sealing layer having a certain thickness from the viewpoint of suppressing entry of moisture, oxygen, and the like from the outside.

In addition, for a sealing layer provided in a light emission path such as a top emission type panel, it is also necessary that light is refracted to some extent. For this reason, it is practically difficult to make the AlOx film formed using the ALD method too thick because the tact time at the time of manufacture becomes too long, leading to an increase in cost.
As described above, the AlOx film is provided with the SiN film for suppressing moisture and oxygen from entering from the outside, and the hydrogen desorbed from the SiN film is prevented from entering the oxide semiconductor layer in the TFT layer. It is desirable to provide a sealing layer with which an excellent light emitting device is provided.

7). Adhesiveness between the sealing wall and the substrate Regarding the adhesiveness between the sealing wall 116 and the substrate 101 in the surrounding region 10b, two types of samples 11 and 14 were prepared and confirmed.
(1) Sample used for confirmation The schematic configuration of the two types of samples 11 and 14 used for confirmation will be described with reference to FIG.

(1-1) Sample 11
As shown in FIG. 10A, the sample 11 has an AlOx film in the sealing layer 111 between the sealing wall 116 and the substrate 101, like the surrounding region 10b of the display panel 10 according to the above embodiment. 1111 and 1113 and the respective edge portions 1111a, 1112a and 1113a of the SiN film 1112 are inserted. The main surface 101a of the substrate 101 and the edge portion 1111a of the AlOx film 1111 are in close contact with each other, and the upper surface of the sealing wall 116 is in close contact with the main surface 115a of the substrate 115.

Note that the edge 1112b of the sealing layer 111 is located below the sealing wall 116, and the upper and lower sides in the Z-axis direction are sandwiched and covered by the AlOx films 1111 and 1113.
For sample 11, sealing wall 116 was formed using an epoxy resin material.
(1-2) Sample 14
As shown in FIG. 10B, in the sample 14, the edge 911b of the edge portion 911a in the sealing layer 911 (SiN film single layer) is between the sealing wall 916 and the substrate 901 in the surrounding area. The AlOx film is not interposed between the main surface 901a of the substrate 901 and the sealing layer 911 (SiN film).

As for the constituent material of the sealing wall 916 in the sample 14, as in the sample 11, an epoxy resin material was employed.
Also in the sample 14, the sealing wall 916 and the main surface 915a of the upper substrate 915 are in close contact.
(2) Results of confirming adhesion The measurement results of the peel strengths of the epoxy resin layer, glass substrate, SiN film, and Al ₂ O ₃ film are shown in FIG.

As shown in FIG. 11, the peel strength between the epoxy resin layer and the glass substrate was 4.2 MPa, and the peel strength between the epoxy resin layer and the Al ₂ O ₃ film was 4.3 MPa.
On the other hand, the peel strength between the epoxy resin layer and the SiN film is 2.3 MPa, compared with the peel strength between the epoxy resin layer and the glass substrate and the peel strength between the epoxy resin layer and the Al ₂ O ₃ film. Thus, the value was 1.9 to 2.0 MPa lower.

From the above results, in the sample 14 having the structure shown in FIG. 10B, there is a region where the sealing wall 916 and the SiN film 911 are in direct contact with each other, resulting in a decrease in peeling strength at the portion. it is conceivable that.
On the other hand, in the sample 11 having the structure shown in FIG. 10A, a high peel strength is secured by inserting the AlOx film 1113 between the sealing wall 116 made of an epoxy resin material and the SiN film 1112. be able to. For this reason, the adhesiveness between the substrate 101 and the sealing wall 116 can be improved, and moisture and oxygen can be effectively prevented from entering between the substrate 101 and the channel layer in the TFT layer and the EL element portion. It is excellent from the viewpoint of protecting each organic film.

[Modification 1]
The structure of the light emitting device according to Modification 1 will be described with reference to FIG. In FIG. 12A, only the go region is extracted and schematically shown in the configuration of the light emitting device according to the first modification.
As shown in FIG. 12A, the light emitting device according to this modification includes a sealing layer 141 in which two layers of an AlOx film 1411 and a SiN film 1412 are stacked from the lower side in the Z-axis direction. The edge portions 1411 a and 1412 a of the films 1411 and 1412 in the sealing layer 141 are interposed between the sealing wall 146 and the substrate 101. The AlOx film 1411 is formed using the ALD method as described above.

The edge 1412b of the edge 1414a of the SiN film 1412 is located below the sealing wall 146.
Also in the light emitting device according to the first modification example having the configuration as shown in FIG. 12A, the AlOx film 1411 is disposed below the SiN film 1412 in the sealing layer 141 in the Z-axis direction. In addition, the effect of suppressing deterioration of the TFT layer can be obtained in the same manner as described above.

In addition, since the SiN film 1412 is included in the configuration of the sealing layer 141, a certain degree of film thickness is ensured while suppressing an increase in tact time associated with the formation of the sealing layer 141 during manufacturing. And has high optical performance while suppressing entry of moisture and oxygen from the outside.
Further, since the AlOx film 1411 is interposed between the SiN film 1412 included in the configuration of the sealing layer 141 and the substrate 101 in the surrounding region, the adhesiveness is high. Therefore, intrusion of moisture and oxygen from between the sealing wall 146 and the substrate 101 can be effectively suppressed. This is the same as the display panel 10 of the above embodiment.

[Modification 2]
The structure of the light emitting device according to Modification 2 will be described with reference to FIG. In FIG. 12B, as in FIG. 12A, only the go region is extracted and schematically shown in the configuration of the light emitting device according to the second modification.
As shown in FIG. 12B, the light emitting device according to this modification includes a sealing layer 151 in which two layers of an AlOx film 1511 and a SiN film 1512 are stacked from the lower side in the Z-axis direction. Among these, the end edge portion 1511 a of the AlOx film 1511 is interposed between the sealing wall 156 and the substrate 101.

On the other hand, the SiN film 1512 included as a constituent element of the sealing layer 151 does not go below the sealing wall 156 and has an edge at a position on the display region side.
Also in this modification, the AlOx film 1511 is formed using the ALD method in the same manner as described above.
Also in the light emitting device according to the second modification having the configuration as shown in FIG. 12B, since the AlOx film 1511 is disposed below the SiN film 1512 in the Z-axis direction in the sealing layer 151, the EL element portion In addition, the effect of suppressing deterioration of the TFT layer can be obtained in the same manner as described above.

Further, since the SiN film 1512 is included in the configuration of the sealing layer 151, a certain degree of film thickness is ensured while suppressing an increase in the takt time associated with the formation of the sealing layer 151 during manufacturing. And has high optical performance while suppressing entry of moisture and oxygen from the outside.
In addition, since the AlOx film 1511 included in the configuration of the sealing layer 151 is interposed between the sealing wall 156 and the substrate 101 in the surrounding region, the adhesiveness is high. Therefore, intrusion of moisture and oxygen from between the sealing wall 156 and the substrate 101 can be effectively suppressed. This is the same as the display panel 10 of the above embodiment.

[Modification 3]
The structure of the light emitting device according to Modification 3 will be described with reference to FIG. In FIG. 13A, as in FIGS. 12A and 12B, only the go region is extracted and schematically shown in the configuration of the light emitting device according to the modified example 3.
As shown in FIG. 13A, the light emitting device according to this modification includes a sealing layer 161 in which two layers of an AlOx film 1611 and a SiN film 1612 are stacked from the lower side in the Z-axis direction. The edge portions 1611 a and 1612 a of the films 1611 and 1612 in the sealing layer 161 are interposed between the sealing wall 166 and the substrate 101. The AlOx film 1611 is formed using the ALD method as described above.

In this modification, both the edge 1612 b of the SiN film 1612 and the edge 1611 b of the AlOx film 1611 are located below the sealing wall 166.
Also in the light emitting device according to Modification 3 having the configuration as shown in FIG. 13A, the AlOx film 1611 is disposed below the SiN film 1612 in the Z-axis direction in the sealing layer 161. In addition, the effect of suppressing deterioration of the TFT layer can be obtained in the same manner as described above.

In addition, since the SiN film 1612 is included in the configuration of the sealing layer 161, a certain degree of film thickness is ensured while suppressing an increase in tact time associated with the formation of the sealing layer 161 during manufacturing. And has high optical performance while suppressing entry of moisture and oxygen from the outside.
In addition, since the AlOx film 1611 is interposed between the SiN film 1612 included in the configuration of the sealing layer 161 and the substrate 101 in the surrounding region, it has high adhesion. Therefore, intrusion of moisture and oxygen from between the sealing wall 166 and the substrate 101 can be effectively suppressed. This is the same as the display panel 10 of the above embodiment.

[Modification 4]
The structure of the light emitting device according to Modification 4 will be described with reference to FIG. In FIG. 13B, as in FIGS. 12A, 12B, and 13A, only the go region is extracted from the configuration of the light-emitting device according to the modified example 4 and schematically illustrated. It is shown.
As shown in FIG. 13B, the light emitting device according to this modification includes a sealing layer 171 in which two layers of an AlOx film 1711 and a SiN film 1712 are stacked from the lower side in the Z-axis direction. Of these, the edge 1711a of the AlOx film 1711 is interposed between the sealing wall 176 and the substrate 101, and the edge 1711b is located below the sealing wall 176.

On the other hand, the SiN film 1712 included as a component of the sealing layer 171 does not wrap around the sealing wall 176 and has an edge at the position on the display area side, as in the second modification. ing.
Also in this modification, the AlOx film 1711 is formed using the ALD method as described above.

Also in the light emitting device according to the modified example 4 having the configuration as shown in FIG. 13B, the AlOx film 1711 is disposed in the sealing layer 171 below the SiN film 1712 in the Z-axis direction. In addition, the effect of suppressing deterioration of the TFT layer can be obtained in the same manner as described above.
In addition, since the SiN film 1712 is included in the configuration of the sealing layer 171, it is possible to secure a certain film thickness while suppressing an increase in tact time associated with the formation of the sealing layer 171 during manufacturing. And has high optical performance while suppressing entry of moisture and oxygen from the outside.

Further, since the AlOx film 1711 included in the configuration of the sealing layer 171 is interposed between the sealing wall 176 and the substrate 101 in the surrounding region, it has high adhesion. Therefore, intrusion of moisture and oxygen from between the sealing wall 176 and the substrate 101 can be effectively suppressed. This is the same as the display panel 10 of the above embodiment.
[Modification 5]
A configuration of a light emitting device according to Modification 5 will be described with reference to FIG. In FIG. 14 (a), only the go region is extracted from the configuration of the light emitting device according to the modified example 5, similarly to FIGS. 12 (a), 12 (b) and 13 (a), 13 (b). This is schematically illustrated.

As shown in FIG. 14A, the light emitting device according to this modification includes a sealing layer 181 in which three layers of an AlOx film 1811, a SiN film 1812, and an AlOx film 1813 are stacked from the lower side in the Z-axis direction. . Among these, the end edge portion 1811 a of the AlOx film 1811 and the end edge portion 1813 a of the AlOx film 1813 are interposed between the sealing wall 186 and the substrate 101.
On the other hand, the SiN film 1812 included as a constituent element of the sealing layer 181 does not go below the sealing wall 186 and has an edge at a position on the display region side.

Also in this modification, the AlOx films 1811 and 1813 are formed using the ALD method in the same manner as described above.
Also in the light emitting device according to the modified example 5 having the configuration shown in FIG. 14A, the AlOx film 1811 is disposed below the SiN film 1812 in the Z-axis direction in the sealing layer 181. In addition, the effect of suppressing deterioration of the TFT layer can be obtained in the same manner as described above. Further, since the AlOx film 1813 is disposed above the SiN film 1812 in the Z-axis direction, the surface irregularities of the SiN film 1812 can be buried to some extent.

In addition, since the SiN film 1812 is included in the configuration of the sealing layer 181, it is possible to secure a certain film thickness while suppressing an increase in tact time associated with the formation of the sealing layer 181 during manufacturing. And has high optical performance while suppressing entry of moisture and oxygen from the outside.
In addition, since the AlOx films 1811 and 1813 included in the configuration of the sealing layer 181 are interposed between the sealing wall 186 and the substrate 101 in the surrounding region, the adhesiveness is high. Therefore, intrusion of moisture and oxygen from between the sealing wall 186 and the substrate 101 can be effectively suppressed. This is the same as the display panel 10 of the above embodiment.

In this modification, two layers of AlOx films 1811 and 1813 are interposed between the sealing wall 186 and the substrate 101. Therefore, even when the AlOx films 1811 and 1813 are thin films, there are variations in manufacturing. Even if this is taken into consideration, the sealing wall 186 and the substrate 101 are surely inserted, and a manufacturing margin can be secured.
[Modification 6]
The structure of the light emitting device according to Modification 6 will be described with reference to FIG. 14B, in the configuration of the light emitting device according to the modified example 6, as in FIGS. 12A, 12B, 13A, 13B, and 14A, Only the Go region is extracted and schematically shown.

As shown in FIG. 14B, the light emitting device according to this modification includes a sealing layer 191 in which three layers of an AlOx film 1911, an SiN film 1912, and an AlOx film 1913 are stacked from the lower side in the Z-axis direction. . Among these, the end edge portion 1911 a of the AlOx film 1911 and the end edge portion 1913 a of the AlOx film 1913 are interposed between the sealing wall 196 and the substrate 101.
On the other hand, the SiN film 1912 included as a component of the sealing layer 191 does not wrap around the sealing wall 196 and has an edge at a position on the display region side.

Here, in the present modification, unlike the modification 5, the edge edges 1911b and 1913b of the AlOx films 1911 and 1913 are positioned below the sealing wall 196.
Also in this modification, the AlOx films 1911 and 1913 are formed using the ALD method as described above.
Also in the light emitting device according to the modified example 6 having the configuration as shown in FIG. 14B, since the AlOx film 1911 is disposed below the SiN film 1912 in the Z-axis direction in the sealing layer 191, the EL element portion In addition, the effect of suppressing deterioration of the TFT layer can be obtained in the same manner as described above. Further, since the AlOx film 1913 is disposed above the SiN film 1912 in the Z-axis direction, the surface irregularities of the SiN film 1912 can be buried to some extent.

In addition, since the SiN film 1912 is included in the configuration of the sealing layer 191, it is possible to ensure a certain film thickness while suppressing an increase in tact time associated with the formation of the sealing layer 191 during manufacturing. And has high optical performance while suppressing entry of moisture and oxygen from the outside.
In addition, since the AlOx films 1911 and 1913 included in the configuration of the sealing layer 191 are inserted in a partial region between the sealing wall 196 and the substrate 101 in the surrounding region, the adhesiveness is high. Therefore, intrusion of moisture and oxygen from between the sealing wall 196 and the substrate 101 can be effectively suppressed. This is the same as the display panel 10 of the above embodiment.

Even in this modification, since the two layers of AlOx films 1911 and 1913 are interposed in a partial region between the sealing wall 196 and the substrate 101, even when the AlOx films 1911 and 1913 are thin films, Even when variations in manufacturing are taken into consideration, the sealing wall 196 and the substrate 101 are surely inserted, and a manufacturing margin can be taken.
[Modification 7]
The structure of the light emitting device according to Modification 7 will be described with reference to FIG. 15A, the light emitting device according to the modified example 7 is similar to FIGS. 12A, 12B, 13A, 13B, 14A, and 14B. Of the configuration, only the Go region is extracted and schematically shown.

As shown in FIG. 15A, the light emitting device according to this modification includes a sealing layer 201 in which three layers of an AlOx film 2011, an SiN film 2012, and an AlOx film 2013 are stacked from the lower side in the Z-axis direction. . Among these, the edge portion 2011a of the AlOx film 2011 and the edge portion 2013a of the AlOx film 2013 are interposed between the sealing wall 206 and the substrate 101.
On the other hand, the SiN film 2012 included as a component of the sealing layer 201 does not wrap around the sealing wall 206 and has an edge at a position on the display region side.

Here, in this modification, unlike the modification 5, the edge 2013b of the AlOx film 2013 is positioned below the sealing wall 206. The edge of the AlOx film 2011 is in a state extending to the left side in the X-axis direction from the sealing wall 206 as in the fifth modification.
Also in this modification, the AlOx films 2011 and 2013 are formed using the ALD method as described above.

  Also in the light emitting device according to the modified example 7 having the configuration as illustrated in FIG. 15A, the AlOx film 2011 is disposed below the SiN film 2012 in the sealing layer 201 in the EL element portion. In addition, the effect of suppressing deterioration of the TFT layer can be obtained in the same manner as described above. Further, since the AlOx film 2013 is arranged above the SiN film 2012 in the Z-axis direction, the surface irregularities of the SiN film 2012 can be buried to some extent.

In addition, since the SiN film 2012 is included in the configuration of the sealing layer 201, a certain degree of film thickness is ensured while suppressing a long tact time associated with the formation of the sealing layer 201 during manufacturing. And has high optical performance while suppressing entry of moisture and oxygen from the outside.
In the surrounding region, the AlOx film 2011 included in the configuration of the sealing layer 201 is interposed between the sealing wall 206 and the substrate 101, and the AlOx film 2013 is disposed between the sealing wall 206 and the substrate 101. Since it is inserted in the partial area, it has high adhesion. Therefore, intrusion of moisture and oxygen from between the sealing wall 206 and the substrate 101 can be effectively suppressed. This is the same as the display panel 10 of the above embodiment.

Even in this modification, since the two layers of AlOx films 2011 and 2013 are interposed in a partial region between the sealing wall 206 and the substrate 101, even when the AlOx films 2011 and 2013 are thin films, Even when variations in manufacturing are taken into account, the sealing wall 206 and the substrate 101 are surely inserted, and a manufacturing margin can be taken.
[Modification 8]
The structure of the light emitting device according to Modification 8 will be described with reference to FIG. In FIG. 15B, as in FIGS. 12A, 12B, 13A, 13B, 14A, 14B, and 15A, a modified example is shown. FIG. 8 schematically shows only the surrounding area extracted from the configuration of the light emitting device according to FIG.

As shown in FIG. 15B, the light emitting device according to this modification includes a sealing layer 211 in which three layers of an AlOx film 2111, an SiN film 2112, and an AlOx film 2113 are stacked from the lower side in the Z-axis direction. . Among these, the edge 2111 a of the AlOx film 2111 is interposed between the sealing wall 216 and the substrate 101.
On the other hand, the SiN film 2112 and the AlOx film 2113 included as constituent elements of the sealing layer 211 do not wrap around the sealing wall 216, and the edge is located at the position on the display region side.

Also in this modification, the AlOx films 2111, 2113 are formed using the ALD method in the same manner as described above.
Also in the light emitting device according to the modified example 8 having the configuration as shown in FIG. 15B, since the AlOx film 2111 is disposed below the SiN film 2112 in the Z-axis direction in the sealing layer 211, the EL element portion In addition, the effect of suppressing deterioration of the TFT layer can be obtained in the same manner as described above. Further, since the AlOx film 2113 is disposed above the SiN film 2112 in the Z-axis direction, the surface irregularities of the SiN film 2112 can be buried to some extent.

In addition, since the SiN film 2112 is included in the configuration of the sealing layer 211, a certain degree of film thickness can be secured while suppressing an increase in tact time associated with the formation of the sealing layer 211 during manufacturing. And has high optical performance while suppressing entry of moisture and oxygen from the outside.
Further, in the surrounding region, the AlOx film 2111 included in the configuration of the sealing layer 211 is interposed in a partial region between the sealing wall 216 and the substrate 101, and thus has high adhesion. Therefore, intrusion of moisture and oxygen from between the sealing wall 216 and the substrate 101 can be effectively suppressed. This is the same as the display panel 10 of the above embodiment.

[Other matters]
In the above-described embodiment and Modifications 1 to 8, the SiN films 1112, 1412, 1512, 1612, 1712, 1812 are included in the configuration of the sealing layers 111, 141, 151, 161, 171, 181, 191, 201, 211. , 1912, 2012, 2112 are included, but the present invention is not limited to this. For example, a film made of silicon oxynitride (SiON) can be included instead of the SiN film. Even in this case, the same effect as described above can be obtained.

Moreover, although the number of AlOx films included in the sealing layer is one layer or two layers in the above-described embodiment and modifications 1 to 8, the number of AlOx films may be three or more. It is sufficient that the AlOx film is disposed at least on the EL element part and TFT layer sides than the SiN film.
Moreover, in the said embodiment and the modifications 1-8, in the sealing layers 111, 141, 151, 161, 171, 181, 191, 201, 211, the SiN films 1112, 1412, 1512, 1612, 1712, 1812, Although the AlOx films 1111, 1411, 1511, 1611, 1711, 1811, 1911, 2011, and 2111 are provided in contact with 1912, 2012, and 2112, the present invention is not limited to this. For example, a configuration in which an AlOx film is disposed below another SiN film below the SiN film can be adopted. In this case, the same effect as described above can be obtained.

  Moreover, in the said embodiment and the modifications 1-8, the AlOx film | membrane 1111,1113,1411,1511,1611,1711,1811 in the sealing layers 111,141,151,161,171,181,191,201,211 , 1813, 1911, 1913, 2011, 2013, 2111, 2113 are extended to the surrounding area 10b, but the AlOx film in the display area 10a and the AlOx film in the surrounding area 10b need to be continuous. There is no. The AlOx film in the surrounding region 10b may be separately formed as an intermediate film, and the intermediate film may be interposed between the sealing wall and the substrate.

  Moreover, in the said embodiment and the modifications 1-8, the AlOx film | membrane 1111,1113,1411,1511,1611,1711,1811 in the sealing layers 111,141,151,161,171,181,191,201,211 , 1813, 1911, 1913, 2011, 2013, 2111, 2113 are formed using the ALD method, but the present invention is not limited to this. It is good also as forming using another method. However, from the viewpoint of suppressing the deterioration of the oxide semiconductor layer in the TFT layer due to hydrogen degassing, it is desirable to form using the ALD method.

In the above-described embodiment and Modifications 1 to 8, the constituent films of the sealing layers 111, 141, 151, 161, 171, 181, 191, 201, 211 are “SiN films” and “AlOx films”. Each constituent film may contain other molecules at the impurity level.
In the display panel 10 according to the above embodiment, the planar structure of the pixel has not been described in detail, but the present invention can adopt various forms. For example, one pixel can be composed of a combination of three subpixels each having a rectangular shape in plan view, and one pixel can be composed of a combination of four or more subpixels. You can also Also, the planar shape of each subpixel is not limited to a rectangular shape, and for example, a planar shape such as a triangle, a hexagon, or an octagon can be employed. Moreover, it can also be set as a honeycomb-shaped arrangement form as a whole.

  In the above embodiment, the hole injection layer 105 and the hole transport layer 107 are interposed between the anode 104 and the organic light emitting layer 108. However, these layers are not necessarily inserted. In some cases, a further intermediate functional layer can be inserted. Similarly, the configuration in which the electron transport layer 109 is interposed between the organic light emitting layer 108 and the cathode 110 is employed. However, in some cases, the insertion of the electron transport layer can be omitted. Another intermediate functional layer may be interposed between the layer 108 and the cathode 110.

  In the above embodiment, the configuration in which the anode 104 is disposed on the lower side in the Z-axis direction and the cathode 110 is disposed on the upper side with respect to the organic light emitting layer 108 is employed as an example. The arrangement relationship may be reversed. That is, the cathode may be disposed on the lower side in the Z-axis direction with respect to the organic light emitting layer 108, and the anode may be disposed on the upper side. Also in this case, top emission can be realized by adopting a light transmissive electrode on the light extraction side and arranging a light reflective electrode on the opposite side.

  INDUSTRIAL APPLICABILITY The present invention is useful for realizing an organic light emitting device and an organic display device that can maintain excellent light emission characteristics even when driven for a long time.

1. Organic EL display device 10. Display panel 10a. Display area 10b. Go area 20. Drive control circuit unit 21-24. Drive circuit 25. Control circuit 100. Subpixel 101. Substrate 102. TFT layer 103. Insulating layer 104. Anode 105. Hole injection layer 106. Bank 107. Hole transport layer 108. Organic light emitting layer 109. Electron transport layer 110. Cathode 111, 121, 131, 141, 151, 161, 171, 181, 191, 201, 211. Sealing layer 112. Resin layer 113. Color filter layer 114. Black matrix layer 115. Substrate 116,146,156,166,176,186,196,206,216. Sealing walls 1021, 1022. Gate electrode 1023. Gate insulating film 1024, 1025. Channel layer 1026. Protective films 1027, 1030. Source electrodes 1028, 1029. Drain electrode 1031. Passivation film 1032. Connection electrode 1033. Lead wires 1111, 1113, 1211, 1411, 1511, 1611, 1711, 1811, 1813, 1911, 1913, 2011, 2013, 2111, 1131, 113. AlOx films 1112, 1212, 1412, 1512, 1612, 1712, 1812, 1912, 2012, 2112. SiN film

Claims (9)

First and second substrates disposed opposite each other at a distance;
An organic light emitting layer disposed in a gap between the first substrate and the second substrate, and interposed between the first and second electrodes and the first electrode and the second electrode A first functional unit having:
A second functional unit disposed between the first substrate and the first functional unit and having a layer including at least an oxide semiconductor in its configuration;
A gap between the first substrate and the second substrate, which surrounds a region in which the first functional unit and the second functional unit are disposed in a plan view, and the first function A sealing wall that seals a region where the portion and the second functional portion are disposed;
It is a gap between the first substrate and the second substrate, and is disposed in a state of covering the second substrate side with respect to the first function portion and the second function portion, and silicon nitride or A first coating film containing silicon oxynitride;
Between the first covering film and the layer including the oxide semiconductor in the second function part, and in a state of covering the layer including the oxide semiconductor in the second function part; A second coating film,
An intermediate film interposed between the first substrate and the sealing wall and made of aluminum oxide;
An organic light-emitting device comprising: The organic light-emitting device according to claim 1, wherein the second coating film is in contact with the first coating film. The organic light-emitting device according to claim 1, wherein the second coating film and the intermediate film are continuous. In the first coating film, at least a part of an edge portion extends to the bottom of the sealing wall,
The edge part of the said 1st coating film extended to the bottom of the said sealing wall is arrange | positioned between the said intermediate film and the said sealing wall. Organic light emitting device. A third coating film made of aluminum oxide is further provided between the second substrate and the first coating film so as to cover at least a part of the first coating film. The organic light emitting device according to any one of claims 1 to 4. In the third coating film, at least a part of the edge portion extends to the bottom of the sealing wall,
The organic light-emitting device according to claim 5, wherein the edge portion of the third coating film extending to below the sealing wall is disposed between the intermediate film and the sealing wall. The organic light emitting device according to claim 5, wherein an edge of the first coating film is disposed in a state of being sandwiched between the intermediate film and the third coating film. The organic light-emitting device according to claim 1, wherein the second coating film is a film formed using an atomic layer deposition method. A display panel;
A control drive circuit connected to the display panel;
With
An organic display device, wherein the device structure according to any one of claims 1 to 8 is employed as the display panel.

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