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JP2015135195A - Pole plate drying device for secondary battery and pole plate drying method - Google Patents

Pole plate drying device for secondary battery and pole plate drying method Download PDF

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Publication number
JP2015135195A
JP2015135195A JP2014005908A JP2014005908A JP2015135195A JP 2015135195 A JP2015135195 A JP 2015135195A JP 2014005908 A JP2014005908 A JP 2014005908A JP 2014005908 A JP2014005908 A JP 2014005908A JP 2015135195 A JP2015135195 A JP 2015135195A
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pole plate
electrode plate
decompression chamber
pressure reducing
reducing chamber
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▲呉▼懷仁
Huai-Jen Wu
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CSB Energy Technology Co Ltd
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CSB Battery Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

PROBLEM TO BE SOLVED: To provide a pole plate drying device for a secondary battery and a pole plate drying method in which a quite high drying effect for the pole plate by a few consumption power and short drying time can be attained and a discharging amount of carbon dioxide is less.SOLUTION: A pole plate drying device for a secondary battery includes a pressure reducing chamber 1. The pressure reducing chamber 1 has a pole plate and a heating unit 2 in it and a ventilation valve 11 is installed outside of it. A vacuum pump 3 is connected to the pressure reducing chamber 1. The pole plate to be dried is installed in the pressure reducing chamber 1, the heating unit 2 installed in the pressure reducing chamber 1 is turned on to perform a heating operation and at the same time the vacuum pump 3 connected to the pressure reducing chamber 1 is turned on to perform vacuum discharging at the pressure reducing chamber 1, the pressure is adjusted by the ventilation valve 11 on the pressure reducing chamber 1, a boiling temperature of water is also decreased as the pressure is reduced, so that an inner pressure in the pressure reducing chamber 1 is decreased due to vacuum discharging of the vacuum pump 3 and along with this state, a boiling point of water on the pole plate is lowered and the pole plate is dried.

Description

本発明は、蓄電池の極板乾燥装置及びその方法に関し、特に、構造設計が簡素なため製造コストが安くてメンテナンスが容易であり、少ない消費電力及び乾燥時間で高い極板の乾燥効果を得て、二酸化炭素の排出量が少ない蓄電池の極板乾燥装置及びその方法に関する。   The present invention relates to an electrode plate drying apparatus for a storage battery and a method thereof, and in particular, since the structure design is simple, the manufacturing cost is low and maintenance is easy, and a high electrode plate drying effect is obtained with low power consumption and drying time. The present invention relates to an electrode plate drying apparatus and method for a storage battery that emits less carbon dioxide.

一般によく見かける各種鉛蓄電池は、正極板、負極板、セパレータ、バッテリースタック、電解液、接続端子などの部品により構成された蓄電池であり、化学エネルギ及び直流電気エネルギを変換して放電後に充電を行うと元の状態に戻るため、繰り返して使用することができる。   The various lead storage batteries that are commonly seen are storage batteries composed of components such as a positive electrode plate, a negative electrode plate, a separator, a battery stack, an electrolytic solution, and a connection terminal, and are charged after being discharged by converting chemical energy and DC electric energy. Because it returns to the original state, it can be used repeatedly.

これら蓄電池の極板を製造する際は、正負極板上に正負極材をそれぞれ塗布した後、乾燥工程により正負極板上に塗布した正負極材を乾燥・硬化させる。正負極板に対して乾燥作業を行う従来の乾燥装置4は、図2に示すように、主に乾燥室41を有する。
乾燥室41内には、極板が設置され、乾燥室41に対応して燃焼室42が設けられる。燃焼室42には、ガス燃焼装置43が接続され、ガス燃焼装置43の燃焼により燃焼室42内に熱気が発生し、燃焼室42と乾燥室41との間には、風循環ブロア44が接続され、燃焼室42内に発生した熱気を風循環ブロア44により乾燥室41内へ導入し、乾燥させる極板を乾燥室41内へ設置した後、ガス燃焼装置43を利用して燃焼を行い、燃焼室42内に熱気を発生させた後、風循環ブロア44により燃焼室42内の熱気を乾燥室41内へ導入し、導入した熱気により乾燥室41中で極板を乾燥させる。
When manufacturing the electrode plates of these storage batteries, the positive and negative electrode materials are respectively applied on the positive and negative electrode plates, and then the positive and negative electrode materials applied on the positive and negative electrode plates are dried and cured by a drying process. As shown in FIG. 2, the conventional drying apparatus 4 that performs a drying operation on the positive and negative electrode plates mainly includes a drying chamber 41.
An electrode plate is installed in the drying chamber 41, and a combustion chamber 42 is provided corresponding to the drying chamber 41. A gas combustion device 43 is connected to the combustion chamber 42, hot air is generated in the combustion chamber 42 by combustion of the gas combustion device 43, and a wind circulation blower 44 is connected between the combustion chamber 42 and the drying chamber 41. The hot air generated in the combustion chamber 42 is introduced into the drying chamber 41 by the wind circulation blower 44, and after the electrode plate to be dried is installed in the drying chamber 41, combustion is performed using the gas combustion device 43, After generating hot air in the combustion chamber 42, the hot air in the combustion chamber 42 is introduced into the drying chamber 41 by the wind circulation blower 44, and the electrode plate is dried in the drying chamber 41 by the introduced hot air.

しかし上述の乾燥装置は、極板の乾燥作業の際、熱気を利用して直接、乾燥室内の極板に対して乾燥作業を行っていたため、極板を完全に乾燥させるのに多くのエネルギが必要であり、燃焼により熱気が発生する過程で二酸化炭素が多く排出され、乾燥装置は高価な上にメンテナンスが容易でないため、全体の構造設計上、改良の必要性があった。   However, since the above-described drying apparatus performs the drying operation directly on the electrode plate in the drying chamber using hot air during the electrode plate drying operation, a large amount of energy is required to completely dry the electrode plate. It is necessary, and a large amount of carbon dioxide is discharged in the process of generating hot air by combustion, and the drying apparatus is expensive and not easy to maintain, so there is a need for improvement in the overall structural design.

そのため、従来技術の構造及び欠点を改良できる実用的な蓄電池の極板乾燥装置及びその方法が求められていた。
本発明の目的は、構造設計が簡素であるため製造コストが安くてメンテナンスが容易であり、少ない消費電力及び乾燥時間で非常に高い極板の乾燥効果を得て、二酸化炭素の排出量が少ない蓄電池の極板乾燥装置及びその方法を提供することにある。
Therefore, there is a need for a practical storage battery electrode drying apparatus and method that can improve the structure and drawbacks of the prior art.
The object of the present invention is that the structural design is simple, the manufacturing cost is low, the maintenance is easy, the very high electrode plate drying effect is obtained with low power consumption and drying time, and the carbon dioxide emission is small. An object of the present invention is to provide an electrode plate drying apparatus and method for a storage battery.

上記課題を解決するために、本発明の第1の形態によれば、減圧チャンバを備えた蓄電池の極板乾燥装置であって、前記減圧チャンバは、内部に極板及び加熱ユニットが配設され、外側に通気バルブが取り付けられ、前記減圧チャンバには、真空ポンプが接続されていることを特徴とする蓄電池の極板乾燥装置が提供される。   In order to solve the above problems, according to a first aspect of the present invention, there is provided an electrode plate drying apparatus for a storage battery including a decompression chamber, wherein the decompression chamber includes an electrode plate and a heating unit. A storage battery electrode plate drying apparatus is provided, wherein a ventilation valve is attached to the outside, and a vacuum pump is connected to the decompression chamber.

乾燥させる極板を減圧チャンバ内へ設置し、前記減圧チャンバ内に設置した加熱ユニットをオンして加熱を行うとともに、前記減圧チャンバに接続した真空ポンプをオンすると、前記真空ポンプにより前記減圧チャンバの真空排気を行い、前記減圧チャンバ上の通気バルブにより圧力を調節し、圧力の低下に伴って水の沸点も下がるため、前記真空ポンプの真空排気により前記減圧チャンバの内部圧力が下がり、それに伴って前記極板上の水分の沸点が下がって前記極板が乾燥することが好ましい。   The electrode plate to be dried is installed in the decompression chamber, the heating unit installed in the decompression chamber is turned on to perform heating, and the vacuum pump connected to the decompression chamber is turned on. Evacuation is performed, the pressure is adjusted by a vent valve on the decompression chamber, and the boiling point of water decreases as the pressure decreases. Therefore, the vacuum pump exhausts the internal pressure of the decompression chamber, and accordingly It is preferable that the boiling point of moisture on the electrode plate is lowered and the electrode plate is dried.

前記加熱ユニットの温度を65〜100℃に制御し、前記減圧チャンバの真空度を−300mmHg〜600mmHgに維持することが好ましい。   Preferably, the temperature of the heating unit is controlled to 65 to 100 ° C., and the vacuum degree of the decompression chamber is maintained at −300 mmHg to 600 mmHg.

本発明の一実施形態に係る蓄電池の極板乾燥装置を示す模式図である。It is a schematic diagram which shows the electrode plate drying apparatus of the storage battery which concerns on one Embodiment of this invention. 従来の蓄電池の極板乾燥装置を示す模式図である。It is a schematic diagram which shows the electrode plate drying apparatus of the conventional storage battery.

以下、本発明の実施形態について図に基づいて説明する。なお、これによって本発明が限定されるものではない。   Hereinafter, embodiments of the present invention will be described with reference to the drawings. Note that the present invention is not limited thereby.

図1を参照する。図1は、本発明の一実施形態に係る蓄電池の極板乾燥装置を示す模式図である。図1に示すように、本実施形態の蓄電池の極板乾燥装置は、減圧チャンバ1を含む。減圧チャンバ1内には、加熱ユニット2が配設されている。加熱ユニット2は、加熱器、スチームプレートなどでもよい。減圧チャンバ1には、外側に通気バルブ11が取り付けられている。減圧チャンバ1には、真空ポンプ3が接続され、回収した工業廃熱源が減圧チャンバ1内に導入されると、減圧チャンバ1内の温度が高まる。   Please refer to FIG. FIG. 1 is a schematic diagram showing an electrode plate drying apparatus for a storage battery according to an embodiment of the present invention. As shown in FIG. 1, the storage battery electrode plate drying apparatus of this embodiment includes a decompression chamber 1. A heating unit 2 is disposed in the decompression chamber 1. The heating unit 2 may be a heater, a steam plate, or the like. A vent valve 11 is attached to the decompression chamber 1 on the outside. When the vacuum pump 3 is connected to the decompression chamber 1 and the recovered industrial waste heat source is introduced into the decompression chamber 1, the temperature in the decompression chamber 1 increases.

本実施形態の蓄電池の極板乾燥装置を実際に使用する際、極板に対して酸洗を行った後に洗浄し、高パワー扇風機により極板表面の水分を吹き飛ばし、乾燥させる極板を減圧チャンバ1内へ設置し、減圧チャンバ1内に設置した加熱ユニット2をオンして加熱を行う。
加熱ユニット2の温度を65〜100℃に制御し、減圧チャンバ1に接続した真空ポンプ3をオンすると、真空ポンプ3により減圧チャンバ1の真空排気を行い、減圧チャンバ1上の通気バルブ11により圧力を調節し、減圧チャンバ1内の真空度を−300mmHg〜600mmHgに維持することができる。
水の沸点は、圧力の低下に伴って下がる特性を有するため、減圧チャンバ1の内部圧力は、真空ポンプ3の真空排気により下がり、それに伴って極板上の水分の沸点も下がり、最小の消費電力かつ最短時間内で極板を効率良く乾燥させることができる。
When actually using the electrode plate drying apparatus of the storage battery of this embodiment, the electrode plate is washed after pickling, the moisture on the surface of the electrode plate is blown off by a high-power electric fan, and the electrode plate to be dried is a decompression chamber. 1 is installed, and the heating unit 2 installed in the decompression chamber 1 is turned on to perform heating.
When the temperature of the heating unit 2 is controlled to 65 to 100 ° C. and the vacuum pump 3 connected to the decompression chamber 1 is turned on, the decompression chamber 1 is evacuated by the vacuum pump 3, and the pressure is obtained by the vent valve 11 on the decompression chamber 1. The vacuum degree in the decompression chamber 1 can be maintained at -300 mmHg to 600 mmHg.
Since the boiling point of water has a characteristic of decreasing with a decrease in pressure, the internal pressure of the decompression chamber 1 is lowered by the vacuum exhaust of the vacuum pump 3, and the boiling point of moisture on the electrode plate is lowered accordingly, and the minimum consumption The electrode plate can be efficiently dried within electric power and in the shortest time.

本発明の実験結果を以下(A)〜(D)に示す。
(A)減圧チャンバ1内の温度70℃、負圧50kpa、乾燥時間3時間の条件下で、密に並べた極板上にある水4kgのうち1.7kgを脱水し、その脱水率は42.5%である。
(B)減圧チャンバ1内の温度70℃、負圧50kpa、乾燥時間3時間の条件下で、大きな間隔で並べた極板上にある水1.7kgのうち1.5kgを脱水し、その脱水率は88.2%である。
(C)減圧チャンバ1内の温度70℃、負圧50kpa、乾燥時間6時間の条件下で、密に並べた極板上にある水2.5kgのうち1.7kgを脱水し、その脱水率は68%である。
(D)減圧チャンバ1内の温度70℃、負圧50kpa、乾燥時間6時間の条件下で、大きな間隔で並べた極板上にある含水量1.7kgのうち1.6kgを脱水し、その脱水率は94.1%である。
The experimental results of the present invention are shown in (A) to (D) below.
(A) 1.7 kg of 4 kg of water on the closely arranged electrode plates was dehydrated under the conditions of a temperature of 70 ° C. in the decompression chamber 1, a negative pressure of 50 kpa, and a drying time of 3 hours. .5%.
(B) Under the conditions of a temperature of 70 ° C. in the decompression chamber 1, a negative pressure of 50 kpa, and a drying time of 3 hours, 1.5 kg of 1.7 kg of water on the electrode plates arranged at large intervals is dehydrated, and the dehydration The rate is 88.2%.
(C) 1.7 kg of 2.5 kg of water on the closely arranged electrode plates is dehydrated under the conditions of a temperature in the decompression chamber 1 of 70 ° C., a negative pressure of 50 kpa, and a drying time of 6 hours, and the dehydration rate Is 68%.
(D) Under the conditions of 70 ° C. in the decompression chamber 1, 50 kpa negative pressure and 6 hours drying time, 1.6 kg out of 1.7 kg of water content on the electrode plates arranged at large intervals, The dehydration rate is 94.1%.

上述の実験データから分かるように、本発明は優れた乾燥効果を有する。   As can be seen from the above experimental data, the present invention has an excellent drying effect.

上述したことから分かるように、本発明の蓄電池の極板乾燥装置は、従来の構造と比べて以下(1)及び(2)の長所を有する。
(1)減圧チャンバ内の圧力を下げることにより極板上の水の沸点を下げ、少ない消費電力及び乾燥時間で高い極板の乾燥効果を得て、二酸化炭素の排出量を減らすことができる。
(2)減圧チャンバ内で加熱ユニットを利用して加熱を行うことにより、真空ポンプを利用して減圧チャンバで真空排気を行い、構造を簡素化することにより製造コストを大幅に減らして容易にメンテナンスを行うことができる。
As can be seen from the above description, the storage battery electrode plate drying apparatus of the present invention has the following advantages (1) and (2) as compared with the conventional structure.
(1) By lowering the pressure in the decompression chamber, the boiling point of water on the electrode plate can be lowered, a high electrode plate drying effect can be obtained with less power consumption and drying time, and carbon dioxide emissions can be reduced.
(2) Heating is performed in the decompression chamber using a heating unit, and vacuum pumping is performed in the decompression chamber using a vacuum pump. Simplification of the structure greatly reduces manufacturing costs and facilitates maintenance. It can be performed.

当該分野の技術を熟知するものが理解できるように、本発明の好適な実施形態を前述の通り開示したが、これらは決して本発明を限定するものではない。本発明の主旨と領域を逸脱しない範囲内で各種の変更や修正を加えることができる。従って、本発明の特許請求の範囲は、このような変更や修正を含めて広く解釈されるべきである。   While the preferred embodiments of the present invention have been disclosed above, as may be appreciated by those skilled in the art, they are not intended to limit the invention in any way. Various changes and modifications can be made without departing from the spirit and scope of the present invention. Accordingly, the scope of the claims of the present invention should be construed broadly including such changes and modifications.

1 減圧チャンバ
2 加熱ユニット
3 真空ポンプ
4 乾燥装置
11 通気バルブ
41 乾燥室
42 燃焼室
43 ガス燃焼装置
44 風循環ブロア
DESCRIPTION OF SYMBOLS 1 Decompression chamber 2 Heating unit 3 Vacuum pump 4 Drying device 11 Ventilation valve 41 Drying chamber 42 Combustion chamber 43 Gas combustion device 44 Wind circulation blower

Claims (3)

減圧チャンバを備えた蓄電池の極板乾燥装置であって、
前記減圧チャンバは、内部に極板及び加熱ユニットが配設され、外側に通気バルブが取り付けられ、
前記減圧チャンバには、真空ポンプが接続されていることを特徴とする蓄電池の極板乾燥装置。
An electrode plate drying apparatus for a storage battery having a decompression chamber,
The vacuum chamber has an electrode plate and a heating unit disposed therein, and a vent valve attached to the outside.
An electrode plate drying apparatus for a storage battery, wherein a vacuum pump is connected to the decompression chamber.
乾燥させる極板を減圧チャンバ内へ設置し、前記減圧チャンバ内に設置した加熱ユニットをオンして加熱を行うとともに、前記減圧チャンバに接続した真空ポンプをオンすると、前記真空ポンプにより前記減圧チャンバの真空排気を行い、前記減圧チャンバ上の通気バルブにより圧力を調節し、圧力の低下に伴って水の沸点も下がるため、前記真空ポンプの真空排気により前記減圧チャンバの内部圧力が下がり、それに伴って前記極板上の水分の沸点が下がって前記極板が乾燥することを特徴とする蓄電池の極板乾燥方法。   The electrode plate to be dried is installed in the decompression chamber, the heating unit installed in the decompression chamber is turned on to perform heating, and the vacuum pump connected to the decompression chamber is turned on. Evacuation is performed, the pressure is adjusted by a vent valve on the decompression chamber, and the boiling point of water decreases as the pressure decreases. Therefore, the vacuum pump exhausts the internal pressure of the decompression chamber, and accordingly A method for drying an electrode plate of a storage battery, wherein the electrode plate is dried by lowering the boiling point of moisture on the electrode plate. 前記加熱ユニットの温度を65〜100℃に制御し、
前記減圧チャンバの真空度を−300mmHg〜600mmHgに維持することを特徴とする請求項2に記載の蓄電池の極板乾燥方法。
Controlling the temperature of the heating unit to 65-100 ° C,
The electrode plate drying method for a storage battery according to claim 2, wherein the vacuum degree of the decompression chamber is maintained at -300 mmHg to 600 mmHg.
JP2014005908A 2014-01-16 2014-01-16 Pole plate drying device for secondary battery and pole plate drying method Pending JP2015135195A (en)

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CN106352669A (en) * 2016-08-19 2017-01-25 甘培嘉 Drying machine
CN106546072A (en) * 2015-09-18 2017-03-29 深圳市鹏翔运达机械科技有限公司 Contact heating vacuum drying oven
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CN112864463A (en) * 2020-12-31 2021-05-28 合肥国轩高科动力能源有限公司 Rapid baking method of square lithium ion battery
CN112880314A (en) * 2021-02-03 2021-06-01 深圳市鹏翔运达机械科技有限公司 Oil heating single cabinet type battery vacuum intelligent drying equipment and drying method

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CN105526784A (en) * 2016-01-19 2016-04-27 珠海格力电器股份有限公司 Drying machine
CN106288665A (en) * 2016-08-19 2017-01-04 东莞市超业精密设备有限公司 A kind of vacuum drying process
CN106352669A (en) * 2016-08-19 2017-01-25 甘培嘉 Drying machine
CN111637689A (en) * 2020-05-11 2020-09-08 常州奥凯干燥设备有限公司 Novel vacuum drying oven
CN112864463A (en) * 2020-12-31 2021-05-28 合肥国轩高科动力能源有限公司 Rapid baking method of square lithium ion battery
CN112880314A (en) * 2021-02-03 2021-06-01 深圳市鹏翔运达机械科技有限公司 Oil heating single cabinet type battery vacuum intelligent drying equipment and drying method

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