JP2014086352A - Nonaqueous electrolyte secondary battery - Google Patents

Abstract

PROBLEM TO BE SOLVED: To supply an increasing need for improvement of characteristics of a lithium nonaqueous electrolyte secondary battery in recent years, especially to overcome the problem that a large drop in capacity is caused by the reiteration of charge and discharge under a severe environment such as a high-temperature environment.SOLUTION: A nonaqueous electrolyte secondary battery comprises: a positive electrode and a negative electrode which are capable of occluding and releasing metal ions; a separator; and a nonaqueous electrolyte including a nonaqueous solvent and an electrolytic substance dissolved in the nonaqueous solvent. At least one of the positive electrode and the negative electrode is an electrode having an electrode mixture layer including an electrode active material and vinylidene fluoride-based polymer as a binding agent. As to the vinylidene fluoride-based polymer, the ratio (A/A) of an absorbance (A) in the vicinity of 1750 cmto an absorbance (A) in the vicinity of 3025 cmis 0.06-2 in IR spectrum measurement. The nonaqueous electrolyte contains a compound having an isocyanato group.

Description

  The present invention relates to a non-aqueous electrolyte secondary battery.

  Non-aqueous electrolyte secondary batteries that use alkali-containing transition metal oxides for the positive electrode and non-aqueous solvent for the electrolyte can achieve high energy density, so from small power sources such as mobile phones and laptop computers to automobiles It is applied to a wide range of applications, from large power supplies for railways and road leveling. However, the demand for higher performance of non-aqueous electrolyte batteries in recent years is increasing, and there is a strong demand for improvement of various characteristics.

Non-aqueous electrolyte secondary batteries include cyclic carbonates such as ethylene carbonate and propylene carbonate; chain carbonates such as dimethyl carbonate, diethyl carbonate and ethyl methyl carbonate; cyclic carboxylic acids such as γ-butyrolactone and γ-valerolactone Esters: linear carboxylic acid esters such as methyl acetate, ethyl acetate, and methyl propionate, and solutes such as LiPF ₆ , LiBF ₄ , LiAsF ₆ , LiClO ₄ , LiCF ₃ SO ₃ , LiN (CF ₃ SO ₂ ) ₂ A nonaqueous electrolytic solution containing is used.

  In the non-aqueous electrolyte secondary battery using such a non-aqueous electrolyte, the reactivity varies depending on the composition of the non-aqueous electrolyte, and thus the battery characteristics are greatly changed by the non-aqueous electrolyte. In order to improve battery characteristics such as load characteristics, cycle characteristics and storage characteristics of non-aqueous electrolyte secondary batteries, and to improve battery safety during overcharge, various studies have been conducted on non-aqueous solvents and electrolytes. Has been made.

For example, Patent Document 1 reports that by dissolving a low molecular weight isocyanate compound in an organic electrolyte, a reaction layer is formed at the electrode interface, and excellent cycle stability can be obtained.
For non-aqueous electrolyte secondary batteries, an electrode mixture obtained by dissolving or dispersing an electrode active material, a conductive material, etc. in a suitable solvent together with a binder is applied to the current collector and dried. The electrode obtained by doing so is generally used.

In Patent Document 2, a negative electrode is manufactured so as to be a mixture layer containing 5% by weight or more and 20% by weight or less of a vinylidene fluoride polymer as a binder in the negative electrode mixture. A method for obtaining an electrode without peeling or cracking is disclosed.
In Patent Document 3, a polymer solid electrolyte excellent in adhesiveness with a current collector substrate is obtained by using a vinylidene fluoride copolymer in which a polar group is introduced by copolymerization, and stable characteristics are obtained. A technology for obtaining a battery having the same is disclosed.

JP 2005-259641 A JP-A-4-249860 Japanese Patent Laid-Open No. 11-130821

However, demands for improving the characteristics of non-aqueous electrolyte secondary batteries in recent years are increasing, and it is required to combine various performances such as energy density, output performance, life, high temperature resistance, and low temperature characteristics at a high level. However, it has not been achieved yet. In particular, when charge and discharge are repeated in a severe environment such as a high temperature environment, there is a problem that the capacity is greatly reduced. In use in automobiles and the like, batteries are often used at high temperatures, and since long-term reliability exceeding 10 years is required for applications, it has been particularly problematic in recent years.

The present invention has been made in view of the above-described problems. That is, an object of the present invention is to provide a non-aqueous electrolyte secondary battery that has a reduced capacity even when charging and discharging are repeated at high temperatures.
As a result of intensive studies, the inventor of the present invention has found that the above problem can be solved by including a specific binder in the electrode and simultaneously including a specific compound in the electrolyte. Completed.

The gist of the present invention is as follows.
In a non-aqueous electrolyte secondary battery comprising a positive electrode and a negative electrode capable of occluding and releasing metal ions, a separator, and a non-aqueous electrolyte solution containing a non-aqueous solvent and an electrolyte dissolved in the non-aqueous solvent,
At least one of the positive electrode or the negative electrode is an electrode having an electrode mixture layer containing an electrode active material and a vinylidene fluoride polymer as a binder,
The vinylidene fluoride based polymer, absorbance around 3025cm ^-1 when measuring IR spectra _{(A 3025)} and 1750 cm ^-1 near the absorbance ratio of _{(A 1750) (A 1750 /} A 3025) is 0. 06 or more and 2 or less,
The non-aqueous electrolyte solution is
A non-aqueous electrolyte secondary battery comprising a compound represented by the following general formula (1):

(In the above formula (1), N represents a nitrogen atom, C represents a carbon atom, O represents an oxygen atom, R ¹ is an organic group which may have a hetero element having 30 or less carbon atoms, and n is 1. Represents an integer of ~ 4.)
The negative electrode, the absorbance around 3025cm ^-1 when measuring IR spectra _{(A 3025)} and 1750 cm ^-1 near the absorbance ratio of _{(A 1750) (A 1750 /} A 3025) is 0.06 to 2 It is preferable to contain a vinylidene fluoride polymer characterized by being present in the electrode mixture layer as a binder.

Moreover, it is preferable that the said vinylidene fluoride polymer is 1 mass% or more and 10 mass% or less as content in the said electrode mixture layer.
In the general formula (1), n is preferably 2 or 3.
Moreover, it is preferable to contain 0.001 mass% or more and 10 mass% or less of the compound shown by the said General formula (1) in nonaqueous electrolyte solution.

  According to the present invention, it is possible to suppress a decrease in battery capacity even when charging and discharging are repeated at high temperatures.

Hereinafter, embodiments of the present invention will be described in detail. However, the description of the constituent elements described below is an example (representative example) of an embodiment of the present invention, and the present invention is limited to these specific contents. However, various modifications can be made within the scope of the invention.
[1. Action]
By using an electrode having an electrode mixture layer containing the specific binder of the present invention, and simultaneously using a non-aqueous electrolyte solution containing a compound represented by the general formula (1), it is charged in a high temperature environment. Even if the discharge is repeated, the battery capacity can be maintained. Although this action and principle are not clear, the present inventors consider as follows. However, the present invention is not limited to the operations and principles described below.

Patent Document 3 discloses a technique for obtaining a battery having stable characteristics by obtaining a polymer solid electrolyte excellent in adhesiveness with a current collector base by using a vinylidene fluoride copolymer into which a polar group is introduced by copolymerization. Is disclosed. A characteristic of the vinylidene fluoride copolymer is the presence of an absorption peak in the vicinity of 1750 cm ⁻¹ when an IR spectrum is measured. This absorption peak is an absorption peak corresponding to the C═O stretching motion in the carboxyl group as the introduced polar group, and it is almost a polar group based on comparison with the absorption peak corresponding to the CH stretching motion of 3025 cm ^−1. It is described that the introduction amount of is calculated.

Of the present invention, absorbance around 3025cm ^-1 when performing the infrared spectroscopic analysis _{(A 3025)} and 1750 cm ^-1 vicinity of absorbance _{(A 1750)} the ratio of _(A 1750 _/ A ₃₀₂₅₎ is 0.06 or more 2 A vinylidene fluoride polymer characterized by the following is also considered to be a vinylidene fluoride polymer containing a polar group.
Patent Document 1 reports that by dissolving a low molecular weight isocyanate compound in an organic electrolyte, a reaction layer is formed at the electrode interface, and excellent cycle stability can be obtained. Similarly, the compound represented by the general formula (1) of the present invention is expected to form a reaction layer at the electrode interface.

  As will be apparent from the examples described later, the battery capacity after repeated charging and discharging in a high-temperature environment is reduced only by using an electrode having an electrode mixture layer containing a specific binder of the present invention. End up. This is because the polar group of the binder in the electrode mixture layer described above is electrochemically unstable, causing decomposition during charging and discharging, and inducing side reactions such as decomposition of the electrolyte. It is thought that it is because it ends.

  On the other hand, as disclosed in the present invention, the simultaneous use of an electrode having an electrode mixture layer containing a specific binder and a non-aqueous electrolyte containing a compound represented by the general formula (1) As a reaction starting from the polar group of the binder in the electrode mixture layer decomposed at the time of charge / discharge, the compound represented by the general formula (1) reacts with priority over the other components of the electrolyte. In addition to suppressing side reactions such as the decomposition of the electrolyte, rather than actively forming a composite reaction layer at the electrode interface, the composite reaction layer is suitable for electrode reactions, so it can be used in high temperature environments. Even if charging / discharging is repeated below, the battery capacity can be maintained.

[2. Non-aqueous electrolyte secondary battery]
The non-aqueous electrolyte secondary battery of the present invention is a non-aqueous electrolyte secondary battery comprising a positive electrode and a negative electrode capable of occluding and releasing metal ions, a separator, and a specific non-aqueous electrolyte described later. At least one of the positive electrode and the negative electrode is an electrode having an electrode mixture layer containing an electrode active material and a specific vinylidene fluoride polymer described later as a binder.

<2-1. Battery configuration>
The non-aqueous electrolyte secondary battery of the present invention is the same as the conventionally known non-aqueous electrolyte secondary battery except for the non-aqueous electrolyte and the binder, and is usually a specific non-aqueous electrolyte described later. A positive electrode and a negative electrode are laminated through a separator impregnated with an electrolytic solution, and these are cases (exterior bodies).
It has the form stored in. Therefore, the shape of the non-aqueous electrolyte secondary battery of the present invention is not particularly limited, and may be any of a cylindrical shape, a square shape, a laminate shape, a coin shape, a large size, and the like.

<2-2. Non-aqueous electrolyte>
The non-aqueous electrolyte in the present invention is a non-aqueous electrolyte containing a non-aqueous solvent and an electrolyte dissolved in the non-aqueous solvent, and contains a compound represented by the following general formula (1). Electrolytic solution.

(In the above formula (1), N represents a nitrogen atom, C represents a carbon atom, O represents an oxygen atom, R ¹ is an organic group which may have a hetero element having 30 or less carbon atoms, and n is 1. Represents an integer of ~ 4.)
<2-2-1. Compound represented by general formula (1)>
The non-aqueous electrolyte solution in the present invention contains a compound represented by the following general formula (1) (hereinafter sometimes referred to as “specific OCN compound”) as an essential component. In the non-aqueous electrolyte solution in the present invention, one type of the specific OCN compound may be used, or two or more types may be used in combination.

(In the above formula (1), N represents a nitrogen atom, C represents a carbon atom, O represents an oxygen atom, R ¹ is an organic group which may have a hetero element having 30 or less carbon atoms, and n is 1. Represents an integer of ~ 4.)
There is no particular limitation on the molecular weight of the specific OCN compound in the present invention, and it is arbitrary as long as the effects of the present invention are not significantly impaired. Moreover, 500 or less, preferably 400 or less, more preferably 300 or less, and particularly preferably 270 or less is practical. When the molecular weight is within the above range, the solubility in the non-aqueous electrolyte solution is excellent, and a more excellent effect is easily achieved.

In general formula (1), n is preferably 2 or 3, particularly preferably 2.
R ¹ is an organic group which may have a hetero element having 30 or less carbon atoms, but is preferably an organic group which may have a hetero element having 25 or less carbon atoms, and has 10 or less carbon atoms. Particularly preferred is an aliphatic hydrocarbon group.

As a specific example of the specific OCN compound,
Isocyanatomethane, isocyanatoethane, 1-isocyanatopropane, 1-isocyanatobutane, 1-isocyanatopentane, 1-isocyanatohexane, 1-isocyanatoheptane, 1-isocyanatooctane, 1-isocyanatotonane, 1-isocyanatodecane, isocyanatocyclohexane, methoxycarbonyl isocyanate, ethoxycarbonyl isocyanate, propoxycarbonyl isocyanate, butoxycarbonyl isocyanate, methoxysulfonyl isocyanate, ethoxysulfonyl isocyanate, propoxysulfonyl isocyanate, butoxysulfonyl isocyanate, fluorosulfonyl isocyanate, 1,4- Diisocyanatobutane, 1,5-diisocyanatopentane, 1,6-diisocyanatohe Sun, 1,7-diisocyanatoheptane, 1,8-diisocyanatooctane, 1,9-diisocyanatononane, 1,10-diisocyanatodecane, 1,3-diisocyanatopropene, 1,4 -Diisocyanato-2-butene, 1,4-diisocyanato-2-fluorobutane, 1,4-diisocyanato-2,3-difluorobutane, 1,5-diisocyanato-2-pentene, 1,5-diisocyanato-2-methyl Pentane, 1,6-diisocyanato-2-hexene, 1,6-diisocyanato-3-hexene, 1,6-diisocyanato-3-fluorohexane, 1,6-diisocyanato-3,4-difluorohexane, toluene diisocyanate, xylene Diisocyanate, tolylene diisocyanate, 1,2-bis (isocyanatomethyl) Rhohexane, 1,3-bis (isocyanatomethyl) cyclohexane, 1,4-bis (isocyanatomethyl) cyclohexane, 1,2-diisocyanatocyclohexane, 1,3-diisocyanatocyclohexane, 1,4-diisocyanate Natocyclohexane, dicyclohexylmethane-1,1′-diisocyanate, dicyclohexylmethane-2,2′-diisocyanate, dicyclohexylmethane-3,3′-diisocyanate, dicyclohexylmethane-4,4′-diisocyanate, isophorone diisocyanate, 1,6,6 11-triisocyanatoundecane, 4-isocyanatomethyl-1,8-octamethylene diisocyanate, 1,3,5-triisocyanate methylbenzene, bicyclo [2.2.1] heptane-2,5-diylbis (methyl = B Cyanate), bicyclo [2.2.1] heptane-2,6-diylbis (methyl = isocyanate), 1,3,5-tris (6-isocyanatohex-1-yl) -1,3,5-triazine -2,4,6 (1H, 3H, 5H) -trione, 2,4,4-trimethylhexamethylene diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, 4- (isocyanatomethyl) octa Isocyanate compounds such as methylene diisocyanate are listed.

Among them, methoxycarbonyl isocyanate, ethoxycarbonyl isocyanate, propoxycarbonyl isocyanate, butoxycarbonyl isocyanate, methoxysulfonyl isocyanate, ethoxysulfonyl isocyanate, propoxysulfonyl isocyanate, butoxysulfonyl isocyanate, fluorosulfonyl isocyanate, 1,4-diisocyanatobutane, 1,5 -Diisocyanatopentane, 1,6-diisocyanatohexane, 1,7-diisocyanatoheptane, 1,8-diisocyanatooctane, 1,9-diisocyanatononane, 1,10-diisocyanatodecane , Toluene diisocyanate, xylene diisocyanate, tolylene diisocyanate, 1,3-bis (isocyanatomethyl) cyclohexane, Cyclohexyl methane-1,1'-diisocyanate,
Dicyclohexylmethane-2,2′-diisocyanate, dicyclohexylmethane-3,3′-diisocyanate, dicyclohexylmethane-4,4′-diisocyanate, isophorone diisocyanate, 1,6,11-triisocyanatoundecane, 4-isocyanatomethyl- 1,8-octamethylene diisocyanate, 1,3,5-triisocyanate methylbenzene, bicyclo [2.2.1] heptane-2,5-diylbis (methyl = isocyanate), bicyclo [2.2.1] heptane- 2,6-diylbis (methyl = isocyanate), 1,3,5-tris (6-isocyanatohex-1-yl) -1,3,5-triazine-2,4,6 (1H, 3H, 5H) -Trione, 2,4,4-trimethylhexamethylene diisocyanate, 2,2 4- trimethylhexamethylene diisocyanate, 4- (isocyanatomethyl) octamethylene = diisocyanates are preferred.

Of these, 1,6-diisocyanatohexane, 1,3-bis (isocyanatomethyl) cyclohexane, 2,4,4-trimethylhexamethylene diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate Is particularly preferred.
The reason why the above compound is preferable is that the raw materials are industrially easily available, the production cost of the electrolytic solution can be kept low, the point that the specific OCN compound is easily dissolved in the nonaqueous electrolytic solution, and the electrode surface. It is mentioned that the reactivity of is optimal.

In addition, the specific OCN compound may use a commercially available thing, and when manufacturing, the manufacturing method is not limited, What was manufactured by the well-known method can be used.
The ratio of the specific OCN compound in the non-aqueous electrolyte solution is arbitrary as long as the effects of the present invention are not significantly impaired, but is generally 0.001% by mass or more in total with respect to the whole non-aqueous electrolyte solution, preferably It is 0.01 mass% or more, More preferably, it is 0.05 mass% or more, Most preferably, it is 0.1 mass% or more. Further, the upper limit is generally 10% by mass or less, preferably 8% by mass or less, more preferably 6% by mass or less, still more preferably 5% by mass or less, particularly preferably 4% by mass or less, and most preferably 3% by mass. It is as follows. When the concentration of the specific OCN compound is within the above range, the action at the electrode interface proceeds more suitably, and thus it is possible to effectively prevent a decrease in battery capacity.

  When the specific OCN compound is contained in a non-aqueous electrolyte solution and actually used for the production of a non-aqueous electrolyte secondary battery, even if the battery is disassembled and the non-aqueous electrolyte solution is extracted again, the content in the non-aqueous electrolyte solution is significantly In many cases, it is decreasing. Therefore, what can detect even a small amount of specific OCN compound from the non-aqueous electrolyte extracted from the battery is considered to be included in the present invention. In addition, when the specific OCN compound is actually used as a non-aqueous electrolyte for the production of a non-aqueous electrolyte secondary battery, the specific OCN compound is not contained in the non-aqueous electrolyte that is disassembled and extracted again. Even in such a case, it is often detected on the positive electrode, the negative electrode, or the separator, which is another component of the non-aqueous electrolyte secondary battery. Therefore, a case where a specific OCN compound is detected from at least one constituent member of the positive electrode, the negative electrode, and the separator is also considered to be included in the present invention.

  Furthermore, the specific OCN compound may be contained in advance in the separator of the non-aqueous electrolyte secondary battery to be produced or on the surface of the separator. In this case, a part or all of the specific OCN compound contained in advance is expected to be dissolved in the non-aqueous electrolytic solution and exhibit its function, and is considered to be included in the present invention. The means for containing in the separator or on the surface of the separator in advance is not particularly limited, but as a specific example, a specific OCN compound is mixed at the time of separator preparation or before a non-aqueous electrolyte secondary battery is prepared. In this separator, after applying or impregnating a solution prepared by dissolving a specific OCN compound in an arbitrary non-aqueous solvent in advance, the solvent used is dried and removed, and then included.

<2-2-2. Electrolyte>
The electrolyte used for the non-aqueous electrolyte in the present invention is not particularly limited, and can be arbitrarily adopted depending on the intended non-aqueous electrolyte secondary battery. Among these, it is preferable to use a lithium salt.
Specific examples of the electrolyte include inorganic lithium salts such as LiClO ₄ , LiAsF ₆ , LiPF ₆ , Li ₂ CO ₃ , LiBF ₄ , and LiAlF ₄ ;
LiCF ₃ SO ₃ , LiN (FSO ₂ ) ₂ , LiN (CF ₃ SO ₂ ) ₂ , LiN (C ₂ F ₅ SO ₂ ) ₂ , LiN (CF ₃ SO ₂ ) (C ₂ F ₅ SO ₂ ), LiN ( _{CF 3 SO 2) (C 3} F 7 SO 2), LiN (CF 3 SO 2) (C 4 F 9 SO 2), lithium cyclic 1,2-ethane sulfonyl imide, lithium cyclic 1,3-propane-di-sulfonyl Imide, lithium cyclic 1,2-perfluoroethanedisulfonylimide, lithium cyclic 1,3-perfluoropropane disulfonylimide, lithium cyclic 1,4-perfluorobutanedisulfonylimide, LiC (CF ₃ SO ₂ ) ₃ , _{LiPF 4 (CF 3) 2,} LiPF 4 (C 2 F 5) 2, LiPF 4 (CF 3 SO 2) 2, LiPF 4 (C _{F 5 SO 2) 2, LiBF} 3 (CF 3), LiBF 3 (C 2 F 5), LiBF 2 (CF 3) 2, LiBF 2 (C 2 F 5) 2, LiBF 2 (CF 3 SO 2) 2 Fluorine-containing organic lithium salts such as LiBF ₂ (C ₂ F ₅ SO ₂ ) ₂ ;
Lithium bis (oxalato) borate, lithium difluoro (oxalato) borate, lithium tris (oxalato) phosphate, lithium difluorobis (oxalato) phosphate, lithium tetrafluoro (oxalato) phosphate, lithium bis (malonato) borate, lithium difluoro (malonato) borate , Lithium tris (malonate) phosphate, lithium difluorobis (malonate) phosphate, lithium tetrafluoro (malonate) phosphate, lithium bis (methylmalonate) borate, lithium difluoro (methylmalonate) borate, lithium tris (methylmalonate) phosphate, lithium difluorobis (methylmalonate) ) Phosphate, lithium tetrafluoro (methylmalonato) phosphate , Lithium bis (dimethylmalonate) borate, lithium difluoro (dimethylmalonate) borate, lithium tris (dimethylmalonate) phosphate, lithium difluorobis (dimethylmalonate) phosphate, lithium tetrafluoro (dimethylmalonate) phosphate, etc. Dicarboxylic acid complex lithium salt;
Sodium salts or potassium salts such as KPF ₆ , NaPF ₆ , NaBF ₄ , CF ₃ SO ₃ Na;
Etc.

Among these, LiPF ₆ , LiBF ₄ , LiCF ₃ SO ₃ , LiN (FSO ₂ ) ₂ , LiN (CF ₃ SO ₂ ) ₂ , LiN (C ₂ F ₅ SO ₂ ) ₂ , lithium cyclic 1,2-perfluoro Ethanedisulfonylimide is preferred, and LiPF ₆ , LiBF ₄ or LiN (CF ₃ SO ₂ ) ₂ is particularly preferred.
These electrolytes may be used individually by 1 type, and may use 2 or more types together by arbitrary combinations and a ratio. Among them, two types of combined use of inorganic lithium salt, combined use of inorganic lithium salt and fluorine-containing organic lithium salt, or combined use of inorganic lithium salt and lithium-containing dicarboxylic acid complex lithium salt are produced after gas generation during continuous charging or after high temperature storage. Deterioration is effectively suppressed, which is preferable.

In particular, the combination and the LiPF ₆ and LiBF _4, and an inorganic lithium salt such as _{LiPF 6, LiBF 4, LiCF 3} SO 3, LiN (CF 3 SO 2) 2, LiN (C 2 F 5 SO 2) _2, etc. The combined use with a fluorine-containing organic lithium salt is preferred.
When LiPF ₆ and LiBF ₄ are used in combination, the proportion of LiBF _{4 in} the entire electrolyte is preferably 0.001% by mass or more and 20% by mass or less. Within this range, the resistance of the non-aqueous electrolyte can be suppressed from increasing due to the low degree of dissociation of LiBF ₄ .

On the other hand, when an inorganic lithium salt such as LiPF ₆ or LiBF ₄ and a fluorine-containing organic lithium salt such as LiCF ₃ SO ₃ , LiN (CF ₃ SO ₂ ) ₂ , or LiN (C ₂ F ₅ SO ₂ ) ₂ are used in combination The proportion of the inorganic lithium salt in the entire electrolyte is preferably 70% by mass or more and 99.9% by mass or less. Within this range, the ratio of the fluorine-containing organic lithium salt having a large molecular weight is generally too high compared to the inorganic lithium salt, and the ratio of the non-aqueous solvent in the entire non-aqueous electrolyte decreases, resulting in non-aqueous electrolysis. An increase in the resistance of the liquid can be suppressed.

  The concentration of the electrolyte such as a lithium salt in the final composition of the nonaqueous electrolytic solution in the present invention is arbitrary as long as the effects of the present invention are not significantly impaired, but preferably 0.5 mol / L or more, 3 mol / L or less. If the electrolyte concentration is above this lower limit, sufficient electric conductivity of the non-aqueous electrolyte solution can be easily obtained, and if it is lower than the upper limit, it is avoided that the viscosity is excessively increased. It is easy to ensure the performance of the non-aqueous electrolyte secondary battery using the electrolyte. The concentration of the electrolyte such as a lithium salt is more preferably 0.6 mol / L or more, further preferably 0.8 mol / L or more, more preferably 2 mol / L or less, more preferably 1.5 mol / L. L or less.

<2-2-3. Nonaqueous solvent>
In the present invention, the non-aqueous solvent contained in the non-aqueous electrolyte solution is not particularly limited as long as it is a solvent that does not adversely affect the battery characteristics when it is used as a battery. Preferably there is.
Examples of non-aqueous solvents include chain carbonates and cyclic carbonates, chain carboxylic acid esters and cyclic carboxylic acid esters, chain ethers and cyclic ethers, phosphorus-containing organic solvents, sulfur-containing organic solvents, and boron-containing organic solvents. It is done.

The kind of chain carbonate is not particularly limited, and examples thereof include dialkyl carbonates. Among them, the number of carbon atoms of the alkyl group is preferably 1 to 5, and more preferably 1 to 4, more preferably 1 Those of ˜3 are particularly preferred. Specific examples include dimethyl carbonate, ethyl methyl carbonate, diethyl carbonate, methyl-n-propyl carbonate, ethyl-n-propyl carbonate, di-n-propyl carbonate, and the like.
Among these, dimethyl carbonate, ethyl methyl carbonate, and diethyl carbonate are preferable in terms of industrial availability and various characteristics in the non-aqueous electrolyte secondary battery.

  Further, chain carbonates having a fluorine atom (hereinafter sometimes abbreviated as “fluorinated chain carbonate”) can also be suitably used. Although the number of fluorine atoms contained in the fluorinated chain carbonate is not particularly limited as long as it is 1 or more, it is usually 6 or less, preferably 4 or less, more preferably 3 or less. When the fluorinated chain carbonate has a plurality of fluorine atoms, they may be bonded to the same carbon or may be bonded to different carbons. Examples of the fluorinated chain carbonate include fluorinated dimethyl carbonate, fluorinated ethyl methyl carbonate, and fluorinated diethyl carbonate.

Examples of the fluorinated dimethyl carbonate include fluoromethyl methyl carbonate, difluoromethyl methyl carbonate, trifluoromethyl methyl carbonate, bis (fluoromethyl) carbonate, bis (difluoro) methyl carbonate, and bis (trifluoromethyl) carbonate.
As fluorinated ethyl methyl carbonate, 2-fluoroethyl methyl carbonate, ethyl fluoromethyl carbonate, 2,2-difluoroethyl methyl carbonate, 2-fluoroethyl fluoromethyl carbonate, ethyl difluoromethyl carbonate, 2,2,2-trifluoro Examples include ethyl methyl carbonate, 2,2-difluoroethyl fluoromethyl carbonate, 2-fluoroethyl difluoromethyl carbonate, and ethyl trifluoromethyl carbonate.

  As fluorinated diethyl carbonate, ethyl- (2-fluoroethyl) carbonate, ethyl- (2,2-difluoroethyl) carbonate, bis (2-fluoroethyl) carbonate, ethyl- (2,2,2-trifluoroethyl) ) Carbonate, 2,2-difluoroethyl-2′-fluoroethyl carbonate, bis (2,2-difluoroethyl) carbonate, 2,2,2-trifluoroethyl-2′-fluoroethyl carbonate, 2,2,2 -Trifluoroethyl-2 ', 2'-difluoroethyl carbonate, bis (2,2,2-trifluoroethyl) carbonate and the like.

In addition, a fluorinated chain carbonate expresses an effective function not only as a solvent but also as an additive described in 1-4 below. When the fluorinated chain carbonate is used as a solvent and additive, there is no clear boundary in the blending amount, and the described blending amount can be followed as it is.
The kind of cyclic carbonate is not particularly limited, and examples thereof include alkylene carbonate. Among them, the number of carbon atoms of the alkylene group constituting is preferably 2 to 6, particularly preferably 2 to 4. Specific examples include ethylene carbonate, propylene carbonate, butylene carbonate (2-ethylethylene carbonate, cis and trans 2,3-dimethylethylene carbonate) and the like.
Among these, ethylene carbonate or propylene carbonate is preferable in that various characteristics of the non-aqueous electrolyte non-aqueous electrolyte secondary battery are good.

Further, cyclic carbonates having a fluorine atom (hereinafter sometimes abbreviated as “fluorinated cyclic carbonate”) can also be suitably used.
Examples of the fluorinated cyclic carbonate include cyclic carbonates having a fluorinated alkylene group having 2 to 6 carbon atoms, such as fluorinated ethylene carbonate and derivatives thereof. Examples of the fluorinated ethylene carbonate and its derivatives include ethylene carbonate or a fluorinated product of ethylene carbonate substituted with an alkyl group (for example, an alkyl group having 1 to 4 carbon atoms). Eight ethylene carbonate fluorides are preferred.

  Specifically, monofluoroethylene carbonate, 4,4-difluoroethylene carbonate, 4,5-difluoroethylene carbonate, 4-fluoro-4-methylethylene carbonate, 4,5-difluoro-4-methylethylene carbonate, 4- Fluoro-5-methylethylene carbonate, 4,4-difluoro-5-methylethylene carbonate, 4- (fluoromethyl) -ethylene carbonate, 4- (difluoromethyl) -ethylene carbonate, 4- (trifluoromethyl) -ethylene carbonate 4- (fluoromethyl) -4-fluoroethylene carbonate, 4- (fluoromethyl) -5-fluoroethylene carbonate, 4-fluoro-4,5-dimethylethylene carbonate, 4,5-difluoro-4,5-dimethyl Le ethylene carbonate, 4,4-difluoro-5,5-dimethylethylene carbonate.

Among these, at least one selected from the group consisting of monofluoroethylene carbonate, 4,4-difluoroethylene carbonate, 4,5-difluoroethylene carbonate, and 4,5-difluoro-4,5-dimethylethylene carbonate is more preferable. As 4,5-difluoroethylene carbonate, a trans isomer is preferable to a cis isomer. This is to provide high ion conductivity and to suitably form an interface protective film.

In addition, a fluorinated cyclic carbonate expresses an effective function not only as a solvent but also as an additive described in 1-4 below. When the fluorinated cyclic carbonate is used as a solvent and additive, there is no clear boundary, and the described amount can be followed as it is.
The type of the chain carboxylic acid ester is not particularly limited. For example, methyl acetate, ethyl acetate, acetic acid-n-propyl, acetic acid-i-propyl, acetic acid-n-butyl, acetic acid-i-butyl, acetic acid-t-butyl , Methyl propionate, ethyl propionate, propionate-n-propyl, propionate-i-propyl, propionate-n-butyl, propionate-i-butyl, propionate-t-butyl, methyl butyrate, ethyl butyrate, etc. Is mentioned.

Among these, methyl acetate, ethyl acetate, methyl propionate, ethyl propionate, methyl butyrate, and ethyl butyrate are preferable in terms of industrial availability and various characteristics in non-aqueous electrolyte secondary batteries.
Furthermore, it does not specifically limit about cyclic carboxylic acid ester, For example, (gamma) -butyrolactone, (gamma) -valerolactone, (delta) -valerolactone etc. are mentioned.

Among these, γ-butyrolactone is preferable in terms of industrial availability and various characteristics in the non-aqueous electrolyte secondary battery.
The type of chain ether is not particularly limited, and examples thereof include dimethoxymethane, dimethoxyethane, diethoxymethane, diethoxyethane, ethoxymethoxymethane, and ethoxymethoxyethane.

Of these, dimethoxyethane and diethoxyethane are preferable in terms of industrial availability and various characteristics in the non-aqueous electrolyte secondary battery.
The cyclic ether is not particularly limited, and examples thereof include tetrahydrofuran, 2-methyltetrahydrofuran, tetrahydropyran and the like.
Further, the phosphorus-containing organic solvent is not particularly limited, and examples thereof include trimethyl phosphate, triethyl phosphate, triphenyl phosphate, tris phosphate (2,2,2-trifluoroethyl), trimethyl phosphite, triethyl phosphite, and triphosphite. Examples include phenyl, trimethylphosphine oxide, triethylphosphine oxide, and triphenylphosphine oxide.

The type of sulfur-containing organic solvent is not particularly limited, and examples thereof include ethylene sulfite, 1,3-propane sultone, 1,4-butane sultone, methyl methanesulfonate, ethyl methanesulfonate, busulfan, sulfolane, sulfolene, and dimethyl. Examples include sulfone, ethyl methyl sulfone, diphenyl sulfone, methyl phenyl sulfone, dibutyl disulfide, dicyclohexyl disulfide, tetramethyl thiuram monosulfide, N, N-dimethylmethanesulfonamide, N, N-diethylmethanesulfonamide, and the like.
The boron-containing organic solvent is not particularly limited, and examples thereof include boroxines such as 2,4,6-trimethylboroxine and 2,4,6-triethylboroxine.

  Among these, chain carbonates, cyclic carbonates, chain carboxylic acid esters, and cyclic carboxylic acid esters are preferable because they have various characteristics in the non-aqueous electrolyte non-aqueous electrolyte secondary battery. Among these, ethylene carbonate , Propylene carbonate, dimethyl carbonate, ethyl methyl carbonate, diethyl carbonate, 2,2,2-trifluoroethyl methyl carbonate, bis (2,2,2-trifluoroethyl) carbonate, methyl acetate, ethyl acetate, methyl propionate, More preferred are ethyl propionate, methyl butyrate, ethyl butyrate, and γ-butyrolactone, ethylene carbonate, propylene carbonate, dimethyl carbonate, ethyl methyl carbonate, diethyl carbonate, 2,2,2-trifluoro Chill methyl carbonate, methyl acetate, ethyl acetate, methyl propionate, and ethyl butyrate more preferred.

These nonaqueous solvents may be used alone or in combination of two or more, but two or more of them are preferably used. For example, it is preferable to use a high dielectric constant solvent of cyclic carbonates in combination with a low viscosity solvent such as chain carbonates or chain esters.
One preferred combination of non-aqueous solvents is a combination mainly composed of cyclic carbonates and chain carbonates. Among them, the total of the cyclic carbonates and the chain carbonates in the entire non-aqueous solvent is preferably 80% by volume or more, more preferably 85% by volume or more, and particularly preferably 90% by volume or more. The volume of the cyclic carbonates with respect to the sum of the chain and the chain carbonates is preferably 5% by volume or more, more preferably 10% by volume or more, particularly preferably 15% by volume or more, preferably 70% by volume or less, more It is preferably 50% by volume or less, particularly preferably 35% by volume or less. A battery produced using a combination of these non-aqueous solvents is preferable because the balance between cycle characteristics and high-temperature storage characteristics (particularly, remaining capacity and high-load discharge capacity after high-temperature storage) is improved.

Examples of preferred combinations of cyclic carbonates and chain carbonates include combinations of ethylene carbonate and chain carbonates, such as ethylene carbonate and dimethyl carbonate, ethylene carbonate and diethyl carbonate, ethylene carbonate and ethyl methyl carbonate, Examples thereof include ethylene carbonate, dimethyl carbonate and diethyl carbonate, ethylene carbonate, dimethyl carbonate and ethyl methyl carbonate, ethylene carbonate, diethyl carbonate and ethyl methyl carbonate, ethylene carbonate, dimethyl carbonate, diethyl carbonate and ethyl methyl carbonate.

  A combination in which propylene carbonate is further added to the combination of these ethylene carbonate and chain carbonate is also preferable. When propylene carbonate is contained, the volume ratio of ethylene carbonate to propylene carbonate is preferably 99: 1 to 40:60, particularly preferably 95: 5 to 50:50. Furthermore, when the amount of propylene carbonate in the entire non-aqueous solvent is 0.1% by volume or more and 10% by volume or less, further excellent discharge is maintained while maintaining the characteristics of the combination of ethylene carbonate and chain carbonates. This is preferable because load characteristics can be obtained. The amount of propylene carbonate in the entire non-aqueous solvent is more preferably 1% by volume, particularly preferably 2% by volume or more, more preferably 8% by volume or less, and particularly preferably 5% by volume or less.

  Among these, those containing asymmetrical chain carbonates as chain carbonates are more preferable, and in particular, ethylene carbonate and dimethyl carbonate and ethyl methyl carbonate, ethylene carbonate and diethyl carbonate and ethyl methyl carbonate, ethylene carbonate and dimethyl carbonate. Among them, those containing diethyl carbonate and ethyl methyl carbonate, or further containing propylene carbonate are preferable because the balance between cycle characteristics and discharge load characteristics is good. In particular, it is preferable that the asymmetric chain carbonate is ethyl methyl carbonate, and it is preferable that the alkyl group constituting the dialkyl carbonate has 1 to 2 carbon atoms.

  Other examples of preferred non-aqueous solvents are those containing chain carboxylic esters. In particular, those containing a chain carboxylic acid ester in the mixed solvent of cyclic carbonates and chain carbonates are preferable from the viewpoint of improving the discharge load characteristics of the battery. In this case, as the chain carboxylic acid esters, Are particularly preferably methyl acetate, ethyl acetate, methyl propionate, methyl butyrate and ethyl butyrate. The volume of the chain carboxylic acid esters in the non-aqueous solvent is preferably 5% by volume or more, more preferably 8% by volume or more, particularly preferably 10% by volume or more, preferably 50% by volume or less, more preferably It is 35% by volume or less, particularly preferably 30% by volume or less, and particularly preferably 25% by volume or less.

<2-2-4. Additives>
The non-aqueous electrolyte solution in the present invention may contain various additives as long as the effects of the present invention are not significantly impaired. A conventionally well-known thing can be arbitrarily used for an additive. An additive may be used individually by 1 type and may use 2 or more types together by arbitrary combinations and a ratio.

  Examples of the additive include an overcharge inhibitor and an auxiliary agent for improving capacity maintenance characteristics and cycle characteristics after high-temperature storage. Among these, carbonates having at least one of an unsaturated bond or a halogen atom as an auxiliary for improving capacity retention characteristics and cycle characteristics after high-temperature storage (hereinafter, may be abbreviated as “specific carbonate” in some cases). Is preferably added. Hereinafter, the specific carbonate and other additives will be described separately.

<2-2-4-1. Specific carbonate>
The molecular weight of the specific carbonate is not particularly limited and is arbitrary as long as the effects of the present invention are not significantly impaired, but those having a molecular weight of 50 to 250 are preferred. Within this range, the solubility of the unsaturated carbonate in the non-aqueous electrolyte is good, and the effect of addition can be fully expressed. The molecular weight of the unsaturated carbonate is preferably 80 or more and 150 or less.

Moreover, there is no restriction | limiting in particular also in the manufacturing method of specific carbonate, It is possible to select and manufacture a well-known method arbitrarily. A commercially available product may also be used.
In addition, the specific carbonate may be included alone in the nonaqueous electrolytic solution in the present invention, or two or more may be combined in any combination and ratio.
Moreover, when using a specific carbonate, the blending amount of the specific carbonate of the non-aqueous electrolyte solution in the present invention is not particularly limited, and is arbitrary as long as the effect of the present invention is not significantly impaired. Preferably they are 0.001 mass% or more and 20 mass% or less.

  When the blending amount of the specific carbonate is not less than this lower limit, a sufficient cycle characteristic improving effect can be brought about in the non-aqueous electrolyte secondary battery. In addition, if it is below this upper limit, it is possible to avoid deterioration of the high-temperature storage characteristics and continuous charge characteristics of the non-aqueous electrolyte non-aqueous electrolyte secondary battery, the amount of gas generation increases, and the capacity maintenance rate decreases. Can also be avoided. The blending amount of the specific carbonate is more preferably 0.1% by mass or more, particularly preferably 0.3% by mass or more, more preferably 15% by mass or less, and particularly preferably 10% by mass or less.

<2-2-4-1-1. Unsaturated carbonate>
Among specific carbonates, carbonates having an unsaturated bond (hereinafter sometimes abbreviated as “unsaturated carbonate”) include carbon-carbon unsaturated bonds such as carbon-carbon double bonds and carbon-carbon triple bonds. If it is the carbonate which has, it will not specifically limit, Arbitrary unsaturated carbonates can be used. In addition, the carbonate which has an aromatic ring shall also be contained in unsaturated carbonate.

Examples of unsaturated carbonates include vinylene carbonates, ethylene carbonates substituted with a substituent having an aromatic ring or a carbon-carbon unsaturated bond, phenyl carbonates, vinyl carbonates, allyl carbonates, propargyl carbonates, etc. Can be mentioned.
Specific examples of vinylene carbonates include vinylene carbonate, methyl vinylene carbonate, 4,5-dimethyl vinylene carbonate, phenyl vinylene carbonate, 4,5-diphenyl vinylene carbonate, catechol carbonate and the like.

Specific examples of ethylene carbonates substituted with an aromatic ring or a substituent having a carbon-carbon unsaturated bond include vinyl ethylene carbonate, 4,5-divinyl ethylene carbonate, ethynyl ethylene carbonate, propargyl ethylene carbonate, phenyl ethylene carbonate, Examples include 4,5-diphenylethylene carbonate.
Specific examples of phenyl carbonates include diphenyl carbonate, ethyl phenyl carbonate, methyl phenyl carbonate, t-butyl phenyl carbonate, and the like.

Specific examples of vinyl carbonates include divinyl carbonate and methyl vinyl carbonate.
Specific examples of allyl carbonates include diallyl carbonate and allyl methyl carbonate.
Specific examples of propargyl carbonates include dipropargyl carbonate and propargyl methyl carbonate.

  Among these, vinylene carbonates, ethylene carbonates substituted with a substituent having an aromatic ring or a carbon-carbon unsaturated bond are preferable, and in particular, vinylene carbonate, vinyl ethylene carbonate, ethynyl ethylene carbonate, and dipropargyl carbonate are stable. An interface protective film can be formed and is more preferably used.

<2-2-4-1-2. Halogenated carbonate>
Among the specific carbonates, a carbonate having a halogen atom (hereinafter sometimes abbreviated as “halogenated carbonate”) is not particularly limited as long as it has a halogen atom, and any halogenated carbonate is used. Can do.
Examples of the halogen atom contained in the halogenated carbonate include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. Among them, a fluorine atom or a chlorine atom is preferable, and a fluorine atom is particularly preferable. Further, the number of halogen atoms contained in the halogenated carbonate is not particularly limited as long as it is 1 or more, preferably 6 or less, more preferably 4 or less, and particularly preferably 2 or less. When the halogenated carbonate has a plurality of halogen atoms, they may be the same as or different from each other.

  Examples of the halogenated carbonate include halogenated ethylene carbonate and derivatives thereof, halogenated dimethyl carbonate and derivatives thereof, halogenated ethyl methyl carbonate and derivatives thereof, halogenated diethyl carbonate and derivatives thereof, and the like.

  Specific examples of halogenated ethylene carbonate and derivatives thereof include fluoroethylene carbonate, chloroethylene carbonate, 4,4-difluoroethylene carbonate, 4,5-difluoroethylene carbonate, 4,4-dichloroethylene carbonate, 4,5-dichloroethylene carbonate. 4-fluoro-4-methylethylene carbonate, 4-chloro-4-methylethylene carbonate, 4,5-difluoro-4-methylethylene carbonate, 4,5-dichloro-4-methylethylene carbonate, 4-fluoro-5 -Methyl ethylene carbonate, 4-chloro-5-methyl ethylene carbonate, 4,4-difluoro-5-methyl ethylene carbonate, 4,4-dichloro-5-methyl ethylene carbonate, 4- ( Fluoromethyl) -ethylene carbonate, 4- (chloromethyl) -ethylene carbonate, 4- (difluoromethyl) -ethylene carbonate, 4- (dichloromethyl) -ethylene carbonate, 4- (trifluoromethyl) -ethylene carbonate, 4- ( Trichloromethyl) -ethylene carbonate, 4- (fluoromethyl) -4-fluoroethylene carbonate, 4- (chloromethyl) -4-chloroethylene carbonate, 4- (fluoromethyl) -5-fluoroethylene carbonate, 4- (chloro Methyl) -5-chloroethylene carbonate, 4-fluoro-4,5-dimethylethylene carbonate, 4-chloro-4,5-dimethylethylene carbonate, 4,5-difluoro-4,5-dimethylethylene carbonate, 4,5 Dichloro-4,5-dimethylethylene carbonate, 4,4-difluoro-5,5-dimethylethylene carbonate, 4,4-dichloro-5,5-dimethylethylene carbonate.

  Specific examples of halogenated dimethyl carbonate and derivatives thereof include fluoromethyl methyl carbonate, difluoromethyl methyl carbonate, trifluoromethyl methyl carbonate, bis (fluoromethyl) carbonate, bis (difluoro) methyl carbonate, bis (trifluoro) methyl carbonate , Chloromethyl methyl carbonate, dichloromethyl methyl carbonate, trichloromethyl methyl carbonate, bis (chloromethyl) carbonate, bis (dichloro) methyl carbonate, bis (trichloro) methyl carbonate.

Specific examples of halogenated ethyl methyl carbonate and derivatives thereof include 2-fluoroethyl methyl carbonate, ethyl fluoromethyl carbonate, 2,2-difluoroethyl methyl carbonate, 2-fluoroethyl fluoromethyl carbonate, ethyl difluoromethyl carbonate, 2, 2,2-trifluoroethyl methyl carbonate, 2,2-difluoroethyl fluoromethyl carbonate, 2-fluoroethyl difluoromethyl carbonate, ethyl trifluoromethyl carbonate, 2-chloroethyl methyl carbonate, ethyl chloromethyl carbonate, 2,2- Dichloroethyl methyl carbonate, 2-chloroethyl chloromethyl carbonate, ethyl dichloromethyl carbonate, 2,2,2-trichloroethyl Chill carbonate, 2,2-dichloroethyl chloromethyl carbonate, 2-chloroethyl dichloromethyl carbonate, ethyl trichloromethyl carbonate.

  Specific examples of the halogenated diethyl carbonate and its derivatives include ethyl- (2-fluoroethyl) carbonate, ethyl- (2,2-difluoroethyl) carbonate, bis (2-fluoroethyl) carbonate, ethyl- (2,2 , 2-trifluoroethyl) carbonate, 2,2-difluoroethyl-2′-fluoroethyl carbonate, bis (2,2-difluoroethyl) carbonate, 2,2,2-trifluoroethyl-2′-fluoroethyl carbonate 2,2,2-trifluoroethyl-2 ′, 2′-difluoroethyl carbonate, bis (2,2,2-trifluoroethyl) carbonate, ethyl- (2-chloroethyl) carbonate, ethyl- (2,2 -Dichloroethyl) carbonate, bis (2-chloroethyl) carbonate Bonate, ethyl- (2,2,2-trichloroethyl) carbonate, 2,2-dichloroethyl-2′-chloroethyl carbonate, bis (2,2-dichloroethyl) carbonate, 2,2,2-trichloroethyl- Examples include 2'-chloroethyl carbonate, 2,2,2-trichloroethyl-2 ', 2'-dichloroethyl carbonate, bis (2,2,2-trichloroethyl) carbonate, and the like.

  Among these halogenated carbonates, carbonates having fluorine atoms are preferable, ethylene carbonate derivatives having fluorine atoms are more preferable, and in particular, fluoroethylene carbonate, 4- (fluoromethyl) -ethylene carbonate, 4,4-difluoroethylene carbonate. 4,5-difluoroethylene carbonate can form a stable interface protective film and is more preferably used.

<2-2-4-1-3. Halogenated unsaturated carbonate>
Furthermore, as the specific carbonate, a carbonate having both an unsaturated bond and a halogen atom (this may be abbreviated as “halogenated unsaturated carbonate” as appropriate) may be used. There is no restriction | limiting in particular as a halogenated unsaturated carbonate, As long as the effect of this invention is not impaired remarkably, arbitrary halogenated unsaturated carbonates can be used.

  Examples of halogenated unsaturated carbonates include halogenated vinylene carbonate and derivatives thereof, halogenated ethylene carbonate and derivatives thereof substituted with a substituent having an aromatic ring or a carbon-carbon unsaturated bond, halogenated phenyl carbonate and derivatives thereof , Halogenated vinyl carbonate and derivatives thereof, halogenated allyl carbonate and derivatives thereof, and the like.

  Specific examples of the halogenated vinylene carbonate and derivatives thereof include fluorovinylene carbonate, 4-fluoro-5-methyl vinylene carbonate, 4-fluoro-5-phenyl vinylene carbonate, 4- (trifluoromethyl) vinylene carbonate chlorovinylene carbonate, Examples include 4-chloro-5-methyl vinylene carbonate, 4-chloro-5-phenyl vinylene carbonate, 4- (trichloromethyl) vinylene carbonate, and the like.

Specific examples of the halogenated ethylene carbonate substituted with a substituent having an aromatic ring or a carbon-carbon unsaturated bond and derivatives thereof include 4-fluoro-4-vinylethylene carbonate, 4-fluoro-5-vinylethylene carbonate, 4,4-difluoro-4-vinylethylene carbonate, 4,5-difluoro-4-vinylethylene carbonate, 4-chloro-5-vinylethylene carbonate, 4,4-dichloro-4-vinylethylene carbonate, 4,5- Dichloro-4-vinylethylene carbonate, 4-fluoro-4,5
-Divinylethylene carbonate, 4,5-difluoro-4,5-divinylethylene carbonate, 4-chloro-4,5-divinylethylene carbonate, 4,5-dichloro-4,5-divinylethylene carbonate, 4-fluoro-4 -Phenylethylene carbonate, 4-fluoro-5-phenylethylene carbonate, 4,4-difluoro-5-phenylethylene carbonate, 4,5-difluoro-4-phenylethylene carbonate, 4-chloro-4-phenylethylene carbonate, 4 -Chloro-5-phenylethylene carbonate, 4,4-dichloro-5-phenylethylene carbonate, 4,5-dichloro-4-phenylethylene carbonate, 4,5-difluoro-4,5-diphenylethylene carbonate, 4,5 - Rollo 4,5-diphenylethylene carbonate.

  Specific examples of the halogenated phenyl carbonate and its derivatives include fluoromethyl phenyl carbonate, 2-fluoroethyl phenyl carbonate, 2,2-difluoroethyl phenyl carbonate, 2,2,2-trifluoroethyl phenyl carbonate, chloromethyl phenyl carbonate. 2-chloroethyl phenyl carbonate, 2,2-dichloroethyl phenyl carbonate, 2,2,2-trichloroethyl phenyl carbonate, and the like.

  Specific examples of halogenated vinyl carbonate and its derivatives include fluoromethyl vinyl carbonate, 2-fluoroethyl vinyl carbonate, 2,2-difluoroethyl vinyl carbonate, 2,2,2-trifluoroethyl vinyl carbonate, chloromethyl vinyl carbonate. 2-chloroethyl vinyl carbonate, 2,2-dichloroethyl vinyl carbonate, 2,2,2-trichloroethyl vinyl carbonate, and the like.

  Specific examples of halogenated allyl carbonate and derivatives thereof include fluoromethyl allyl carbonate, 2-fluoroethyl allyl carbonate, 2,2-difluoroethyl allyl carbonate, 2,2,2-trifluoroethyl allyl carbonate, chloromethyl allyl carbonate 2-chloroethyl allyl carbonate, 2,2-dichloroethyl allyl carbonate, 2,2,2-trichloroethyl allyl carbonate, and the like.

Among the above specific carbonates, vinylene carbonate, vinyl ethylene carbonate, ethynyl ethylene carbonate, dipropargyl carbonate, fluoroethylene carbonate and 4,5-difluoroethylene carbonate, or two or more of these are highly effective when used alone Is particularly preferable.
<2-2-4-2. Other additives>
Examples of additives other than the specific carbonate include overcharge inhibitors, auxiliary agents for improving capacity maintenance characteristics and cycle characteristics after high-temperature storage, and the like.

<2-2-4-2-1. Overcharge prevention agent>
Specific examples of the overcharge inhibitor include toluene derivatives such as toluene and xylene; biphenyl derivatives substituted with an unsubstituted or alkyl group such as biphenyl, 2-methylbiphenyl, 3-methylbiphenyl, and 4-methylbiphenyl; o- Terphenyl derivatives that are unsubstituted or substituted with alkyl groups such as terphenyl, m-terphenyl, p-terphenyl; partial hydrides of terphenyl derivatives that are unsubstituted or substituted with alkyl groups; cyclopentylbenzene, cyclohexylbenzene, etc. Cycloalkylbenzene derivatives of the following: alkylbenzene derivatives having a tertiary carbon directly bonded to a benzene ring such as cumene, 1,3-diisopropylbenzene, 1,4-diisopropylbenzene; t-butylbenzene, t-amylbenzene, t-hexyl Benzene rings such as benzene Alkylbenzene derivative having a quaternary carbon direct bond; diphenyl ether, aromatic compounds having an oxygen atom of dibenzofuran and the like; aromatic compounds, and the like.

  Furthermore, specific examples of other overcharge preventing agents include partially fluorinated products of the aromatic compounds such as fluorobenzene, fluorotoluene, benzotrifluoride, 2-fluorobiphenyl, o-cyclohexylfluorobenzene, p-cyclohexylfluorobenzene and the like. And fluorinated anisole compounds such as 2,4-difluoroanisole, 2,5-difluoroanisole and 1,6-difluoroanisole;

In addition, these overcharge inhibitors may be used individually by 1 type, and may use 2 or more types together by arbitrary combinations. Moreover, when using together by arbitrary combinations, it may use together by the compound of the same classification illustrated above and may be used together by a compound of a different classification | category.
When blending the overcharge inhibitor, the blending amount of the overcharge inhibitor is arbitrary as long as the effect of the present invention is not significantly impaired, but is preferably 0.001% by mass or more based on the whole non-aqueous electrolyte. It is the range of 10 mass% or less.

  Including an overcharge inhibitor in the non-aqueous electrolyte solution in the present invention within a range that does not significantly impair the effects of the present invention, the overcharge protection circuit such as an incorrect usage or an abnormality of the charging device should operate normally. Even if the battery is overcharged due to the situation, it is preferable because the safety of the non-aqueous electrolyte secondary battery is improved.

<2-2-4-2-2. Auxiliary>
On the other hand, specific examples of the auxiliary for improving capacity maintenance characteristics and cycle characteristics after high-temperature storage include the following.
Dicarboxylic acid anhydrides such as succinic acid, maleic acid and phthalic acid; carbonate compounds other than those corresponding to carbonates having an unsaturated bond such as erythritan carbonate and spiro-bis-dimethylene carbonate; cyclic compounds such as ethylene sulfite Sulfite; cyclic sulfonate ester such as 1,3-propane sultone, 1,4-butane sultone, 1,3-propene sultone, 1,4-butene sultone; chain sulfonate ester such as methyl methanesulfonate and busulfan; sulfolane Cyclic sulfones such as sulfolene; chain sulfones such as dimethyl sulfone, diphenyl sulfone and methylphenyl sulfone; sulfides such as dibutyl disulfide, dicyclohexyl disulfide and tetramethylthiuram monosulfide; N, N-dimethylmeta Sulfur-containing compounds such as sulfonamides such as sulfonamides and N, N-diethylmethanesulfonamide; 1-methyl-2-pyrrolidinone, 1-methyl-2-piperidone, 3-methyl-2-oxazolidinone, 1,3- Nitrogen-containing compounds such as dimethyl-2-imidazolidinone; hydrocarbon compounds such as heptane, octane and cycloheptane; fluorine-containing aromatic compounds such as fluorobenzene, difluorobenzene and benzotrifluoride.

In addition, these adjuvants may be used individually by 1 type, and may use 2 or more types together by arbitrary combinations and a ratio.
Further, when the non-aqueous electrolyte in the present invention contains these auxiliaries, it is optional as long as the effects of the present invention are not significantly impaired, but preferably 0.001% by mass or more with respect to the entire non-aqueous electrolyte. It is the range of 10 mass% or less.

<2-2-5. Method for producing non-aqueous electrolyte>
The non-aqueous electrolyte solution in the present invention can be prepared by dissolving the electrolyte, the specific OCN compound, and, if necessary, the above-mentioned “additives” and “auxiliaries” in the above-mentioned non-aqueous solvent.
When preparing the non-aqueous electrolyte, each raw material of the non-aqueous electrolyte, that is, an electrolyte such as a lithium salt, a specific OCN compound, a non-aqueous solvent, an additive, an auxiliary agent, and the like are preferably dehydrated in advance. . The degree of dehydration is usually 50 ppm or less, preferably 30 ppm or less.

  By removing moisture in the non-aqueous electrolyte, water electrolysis, water-lithium metal reaction, lithium salt hydrolysis, and the like are less likely to occur. The dehydration means is not particularly limited. For example, when the object to be dehydrated is a liquid such as a non-aqueous solvent, a desiccant such as molecular sieve may be used. In addition, when the object to be dehydrated is a solid such as an electrolyte, it may be dried by heating at a temperature lower than the temperature at which decomposition occurs.

<2-3. Vinylidene fluoride polymer>
The non-aqueous electrolyte secondary battery of the present invention is a non-aqueous electrolyte secondary battery comprising a positive electrode and a negative electrode capable of occluding and releasing metal ions, a separator, and the specific non-aqueous electrolyte described above. ratio of at least one of the positive electrode or the negative electrode, and the electrode active material, absorbance around 3025cm ^-1 when measuring IR spectrum as a binder _{(a 3025)} and 1750 cm ^-1 vicinity of absorbance between _{(a 1750)} ( A ₁₇₅₀ / A ₃₀₂₅ ) is an electrode having an electrode mixture layer containing a vinylidene fluoride polymer characterized by 0.06 or more and 2 or less.

In the present invention, the positive electrode or the negative electrode of at least one to 3025cm ^-1 vicinity of absorbance when measuring IR spectra of certain vinylidene fluoride polymer contained _{(A 3025)} and 1750 cm ^-1 vicinity of absorbance _{(A 1750)} The ratio (A ₁₇₅₀ / A ₃₀₂₅ ) is 0.06 or more and 2 or less, preferably 0.10 or more, more preferably 1.5 or less, and 1.2 or less. More preferably, it is particularly preferably 1.0 or less. As described above, A ₁₇₅₀ / A ₃₀₂₅ is a numerical value that correlates with the amount of polar groups introduced into the vinylidene fluoride polymer. However, if it is too large, gelation tends to occur when an electrode described later is formed, and workability is impaired. On the other hand, if it is too small, the above-mentioned action cannot be recognized.

The specific vinylidene fluoride-based polymer in the present invention may be included in at least one of the positive electrode and the negative electrode, and may be included in both the positive electrode and the negative electrode at the same time.
In the present invention, the specific vinylidene fluoride polymer contained in at least one of the positive electrode and the negative electrode may be used alone or in combination of two or more in any combination and ratio. Good.
In the present invention, the above-mentioned specific vinylidene fluoride polymer contained in at least one of the positive electrode and the negative electrode may be a commercially available one, and in the case of production, the production method is not limited and is publicly known. What was manufactured by the method can be used.

<2-4. Negative electrode>
The negative electrode active material used for the negative electrode is not particularly limited as long as it can electrochemically occlude and release lithium ions. Specific examples thereof include carbonaceous materials, metal compound materials, lithium-containing metal composite oxide materials, and the like. One of these may be used alone, or two or more may be used in any combination.

<2-4-1. Carbonaceous material>
The carbonaceous material used as the negative electrode active material is not particularly limited, but a material selected from the following (A) to (D) is preferable because it has a good balance between initial irreversible capacity and high current density charge / discharge characteristics.
(A) Natural graphite (I) Artificial carbonaceous material and carbonaceous material obtained by heat treating artificial graphite material at least once in the range of 400 to 3200 ° C. (C) The negative electrode active material layer has at least two different crystallinities. (D) a negative electrode active material layer comprising carbonaceous materials having at least two different orientations, and / or a carbonaceous material having an interface with which the different crystalline carbonaceous materials are in contact. And / or the carbonaceous materials (a) to (d) having an interface with which the carbonaceous materials having different orientations are in contact may be used alone or in any combination of two or more. And may be used in combination in a ratio.

Specific examples of the artificial carbonaceous material or artificial graphite material of (i) above include natural graphite, coal-based coke, petroleum-based coke, coal-based pitch, petroleum-based pitch and those pitch-oxidized, needle coke, Pitch coke and carbon materials partially graphitized thereof, furnace black, acetylene black, pyrolysis products of organic substances such as pitch-based carbon fibers, carbonizable organic substances and their carbides, and carbonizable organic substances as benzene, toluene, Examples include solution-like carbides dissolved in low-molecular organic solvents such as xylene, quinoline, and n-hexane.
As for the properties of the carbonaceous material, it is desirable that any one or a plurality of items (1) to (8) shown below are satisfied at the same time.

(1) X-ray parameters The d-value (interlayer distance) of the lattice plane (002 plane) obtained by X-ray diffraction by the Gakushin method of carbonaceous materials is preferably 0.335 nm or more, and is usually 0.8. It is 360 nm or less, preferably 0.350 nm or less, and more preferably 0.345 nm or less. The crystallite size (Lc) determined by X-ray diffraction by the Gakushin method is preferably 1.0 nm or more, more preferably 1.5 nm or more, and still more preferably 2 nm or more.

(2) Volume-based average particle diameter The volume-based average particle diameter of the carbonaceous material is usually 1 μm or more, and more preferably 3 μm or more, based on the volume-based average particle diameter (median diameter) determined by the laser diffraction / scattering method. It is more preferably 5 μm or more, particularly preferably 7 μm or more, preferably 100 μm or less, more preferably 50 μm or less, further preferably 40 μm or less, particularly preferably 30 μm or less, and particularly preferably 25 μm or less. When the volume reference average particle diameter is within the above range, the irreversible capacity does not increase excessively, and it is easy to avoid incurring loss of the initial battery capacity. In addition, when an electrode is produced by coating, it is easy to uniformly coat the surface, which is desirable in the battery manufacturing process.

  In order to measure the volume-based average particle size, a carbonaceous material powder is dispersed in a 0.2% by mass aqueous solution (about 10 mL) of polyoxyethylene (20) sorbitan monolaurate as a surfactant, and laser diffraction / A scattering type particle size distribution meter (LA-700 manufactured by Horiba, Ltd.) is used. The median diameter determined by the measurement is defined as the volume-based average particle diameter of the carbonaceous material.

(3) Raman R value, Raman half value width The Raman R value of the carbonaceous material is preferably 0.01 or more, more preferably 0.03 or more, as measured using an argon ion laser Raman spectrum method. 0.1 or more is more preferable, and preferably 1.5 or less, more preferably 1.2 or less, still more preferably 1 or less, and particularly preferably 0.5 or less.

When the Raman R value is in the above range, the crystallinity of the particle surface is in an appropriate range, and it is possible to suppress a decrease in sites where Li enters between layers with charge / discharge, and charge acceptability is hardly lowered. Further, even when the negative electrode is densified by applying it to the current collector and then pressing it, it is difficult to cause a decrease in load characteristics. Furthermore, it is difficult to cause a decrease in efficiency and an increase in gas generation.
Moreover, the Raman half-width in the vicinity of 1580 cm ^{−1 of the} carbonaceous material is not particularly limited, but is 10 cm ⁻¹ or more, preferably 15 cm ⁻¹ or more, and is usually 100 cm ⁻¹ or less, and 80 cm ⁻¹ or less. Preferably, 60 cm ⁻¹ or less is more preferable, and 40 cm ⁻¹ or less is particularly preferable.

When the Raman half width is in the above range, the crystallinity of the particle surface is in an appropriate range, and the decrease in the sites where Li enters between the layers can be suppressed with charge / discharge, and the charge acceptability is hardly lowered. Further, even when the negative electrode is densified by applying it to the current collector and then pressing it, it is difficult to cause a decrease in load characteristics. Furthermore, it is difficult to cause a decrease in efficiency and an increase in gas generation.
The measurement of the Raman spectrum, using a Raman spectrometer (manufactured by JASCO Corporation Raman spectrometer), the sample is naturally dropped into the measurement cell and filled, and while irradiating the sample surface in the cell with argon ion laser light, This is done by rotating the cell in a plane perpendicular to the laser beam. The resulting Raman spectrum, the intensity _{I A} of the peak _{P A} in the vicinity of 1580 cm ^-1, and measuring the intensity _{I B} of a peak _{P B} in the vicinity of 1360 cm ^-1, the intensity ratio _{R (R = I B / I} A) Is calculated. The Raman R value calculated by the measurement is defined as the Raman R value of the carbonaceous material in the present invention. Further, the half width of the peak P _A in the vicinity of 1580 cm ^-1 of the resulting Raman spectrum was measured, which is defined as the Raman half-value width of the carbonaceous material in the present invention.

Moreover, said Raman measurement conditions are as follows.
Argon ion laser wavelength: 514.5nm
・ Laser power on the sample: 15-25mW
・ Resolution: 10-20cm ^-1
Measurement range: 1100 cm ^{−1 to} 1730 cm ⁻¹
・ Raman R value, Raman half width analysis: Background processing ・ Smoothing processing: Simple average, 5 points of convolution

(4) BET specific surface area As for the BET specific surface area of the carbonaceous material, the value of the specific surface area measured using the BET method is preferably 0.1 m ² · g ⁻¹ or more, and 0.7 m ² · g ^−1. The above is more preferable, 1.0 m ² · g ⁻¹ or more is further preferable, 1.5 m ² · g ⁻¹ or more is particularly preferable, and preferably 100 m ² · g ⁻¹ or less, and 25 m ² · g ^{−. 1} or less is more preferable, 15 m ² · g ⁻¹ or less is more preferable, and 10 m ² · g ⁻¹ or less is particularly preferable.

When the value of the BET specific surface area is within the above range, the acceptability of cations such as lithium is good at the time of charging when used as a negative electrode material, lithium and the like are difficult to deposit on the electrode surface, and the stability is avoided. Cheap. further. The reactivity with the non-aqueous electrolyte can be suppressed, gas generation is small, and a preferable battery is easily obtained.
The specific surface area was measured by the BET method using a surface area meter (a fully automated surface area measuring device manufactured by Okura Riken), preliminarily drying the sample at 350 ° C. for 15 minutes under nitrogen flow, A nitrogen adsorption BET one-point method using a gas flow method is performed using a nitrogen-helium mixed gas that is accurately adjusted so that the relative pressure value is 0.3. The specific surface area determined by the measurement is defined as the BET specific surface area of the carbonaceous material in the present invention.

(5) Circularity When the circularity is measured as a spherical degree of the carbonaceous material, it is preferably within the following range. The circularity is defined as “circularity = (peripheral length of an equivalent circle having the same area as the particle projection shape) / (actual perimeter of the particle projection shape)”, and is theoretical when the circularity is 1. Become a true sphere.
It is desirable that the circularity of particles having a carbonaceous material particle size in the range of 3 to 40 μm is closer to 1. Preferably it is 0.1 or more, 0.5 or more is more preferable, 0.8 or more is further more preferable, 0.85 or more is especially preferable, and 0.9 or more is especially preferable.

High current density charge / discharge characteristics generally improve as the circularity increases. Therefore, when the circularity is less than the above range, the filling property of the negative electrode active material is lowered, the resistance between particles is increased, and the high current density charge / discharge characteristics may be lowered for a short time.
The circularity of the carbonaceous material is measured using a flow particle image analyzer (FPIA manufactured by Sysmex Corporation). Specifically, about 0.2 g of a sample is dispersed in a 0.2% by mass aqueous solution (about 50 mL) of polyoxyethylene (20) sorbitan monolaurate, which is a surfactant, and an ultrasonic wave of 28 kHz is output at 1 with 60 W output. After irradiating for minutes, the detection range is specified as 0.6 to 400 μm, and the particle size is measured for particles in the range of 3 to 40 μm. The circularity obtained by the measurement is defined as the circularity of the carbonaceous material in the present invention.

  The method for improving the degree of circularity is not particularly limited, but a spheroidized sphere is preferable because the shape of the interparticle void when the electrode body is formed is preferable. Examples of spheroidizing treatment include a method of mechanically approximating a sphere by applying a shearing force and a compressive force, and a mechanical / physical treatment in which a plurality of fine particles are granulated by the binder or the adhesive force of the particles themselves. Methods and the like.

(6) The tap density of the tap density carbonaceous material, preferably at 0.1 g · ^{cm -3} or more, 0.5 g · ^{cm -3} or more, and more preferably 0.7 g · ^{cm -3} or more, 1 g · cm ⁻³ or more is particularly preferable. Moreover, 2 g * cm <^-3> or less is preferable, 1.8 g * cm < ^-3 > or less is more preferable, and 1.6 g * cm <^-3> or less is especially preferable.

When the tap density is within the above range, a sufficient packing density can be secured when used as a negative electrode, and a high-capacity battery can be obtained. Furthermore, voids between the particles in the electrode are not reduced too much, conductivity between the particles is ensured, and preferable battery characteristics are easily obtained.
The tap density is measured by passing through a sieve having an opening of 300 μm, dropping the sample onto a 20 cm ³ tapping cell and filling the sample to the upper end surface of the cell, and then measuring a powder density measuring device (for example, manufactured by Seishin Enterprise Co., Ltd.). Using a tap denser, tapping with a stroke length of 10 mm is performed 1000 times, and the tap density is calculated from the volume at that time and the mass of the sample. The tap density calculated by the measurement is defined as the tap density of the carbonaceous material in the present invention.

(7) Orientation ratio The orientation ratio of the carbonaceous material is preferably 0.005 or more, more preferably 0.01 or more, still more preferably 0.015 or more, and preferably 0.67 or less. When the orientation ratio is below the above range, the high-density charge / discharge characteristics may deteriorate. The upper limit of the above range is the theoretical upper limit value of the orientation ratio of the carbonaceous material.

The orientation ratio of the carbonaceous material is obtained by measuring by X-ray diffraction after pressure-molding the sample. Specifically, a molded body obtained by filling 0.47 g of a sample into a molding machine having a diameter of 17 mm and compressing with a 58.8 MN · m ⁻² is flush with the surface of the measurement sample holder using clay. Then, the X-ray diffraction is measured. From the (110) diffraction and (004) diffraction peak intensities of the obtained carbonaceous material, a ratio represented by (110) diffraction peak intensity / (004) diffraction peak intensity is calculated. The orientation ratio calculated by the measurement is defined as the orientation ratio of the carbonaceous material in the present invention.

The X-ray diffraction measurement conditions at this time are as follows. “2θ” indicates a diffraction angle.
・ Target: Cu (Kα ray) graphite monochromator ・ Slit:
Divergence slit = 0.5 degree Light receiving slit = 0.15 mm
Scattering slit = 0.5 degrees Measurement range and step angle / measurement time:
(110) plane: 75 degrees ≦ 2θ ≦ 80 degrees 1 degree / 60 seconds (004) plane: 52 degrees ≦ 2θ ≦ 57 degrees 1 degree / 60 seconds

(8) Aspect ratio (powder)
The aspect ratio of the carbonaceous material is usually 1 or more and usually 10 or less, preferably 8 or less, more preferably 5 or less. If the aspect ratio is out of the above range, streaking may occur when forming an electrode plate, a uniform coated surface may not be obtained, and high current density charge / discharge characteristics may be deteriorated. The lower limit of the above range is the theoretical lower limit value of the aspect ratio of the carbonaceous material.

  The aspect ratio of the carbonaceous material is measured by magnifying and observing the carbonaceous material particles with a scanning electron microscope. Specifically, arbitrary 50 carbonaceous material particles fixed to the end face of a metal having a thickness of 50 microns or less are selected, and the stage on which the sample is fixed is rotated and tilted, and observed three-dimensionally. Then, the longest diameter A of the carbonaceous material particles and the shortest diameter B orthogonal thereto are measured, and the average value of A / B is obtained. The aspect ratio (A / B) obtained by the measurement is defined as the aspect ratio of the carbonaceous material in the present invention.

<2-4-2. Metal compound materials>
The metal compound-based material used as the negative electrode active material is not particularly limited as long as it can occlude and release lithium, and is a single metal or alloy that forms a lithium alloy, or oxides, carbides, nitrides, silicides thereof. Compounds such as oxides, sulfides and phosphides. Examples of such metal compounds include compounds containing metals such as Ag, Al, Ba, Bi, Cu, Ga, Ge, In, Ni, P, Pb, Sb, Si, Sn, Sr, and Zn. Especially, it is preferable that it is a single metal or alloy which forms a lithium alloy, and it is more preferable that there is a material containing a metal / metalloid element (that is, excluding carbon) of Group 13 or Group 14 of the periodic table. (Si), tin (Sn), or lead (Pb) (hereinafter, these three elements may be referred to as “SSP metal elements”), simple metals, alloys containing these atoms, or their metals (SSP metals) Element). These may be used individually by 1 type, and may use 2 or more types together by arbitrary combinations and a ratio.

  Examples of the negative electrode active material having at least one kind of atom selected from SSP metal elements include a single metal of any one SSP metal element, an alloy composed of two or more SSP metal elements, one kind or two or more kinds. Alloys composed of SSP metal elements and other one or more metal elements, and compounds containing one or more SSP metal elements, or oxides, carbides, and nitrides of the compounds And composite compounds such as silicides, sulfides and phosphides. By using these simple metals, alloys or metal compounds as the negative electrode active material, the capacity of the battery can be increased.

  Moreover, the compound which these complex compounds combined with several elements, such as a metal simple substance, an alloy, or a nonmetallic element, can also be mentioned as an example. More specifically, for example, in silicon and tin, an alloy of these elements and a metal that does not operate as a negative electrode can be used. In addition, for example, in the case of tin, a complex compound containing 5 to 6 kinds of elements in combination with a metal that acts as a negative electrode other than tin and silicon, a metal that does not operate as a negative electrode, and a nonmetallic element can also be used. .

  Among these negative electrode active materials, since the capacity per unit mass is large when a battery is formed, any one element of an SSP metal element, an alloy of two or more SSP metal elements, oxidation of an SSP metal element In particular, silicon and / or tin metal, alloy, oxide, carbide, nitride and the like are preferable from the viewpoint of capacity per unit mass and environmental load.

In addition, although the capacity per unit mass is inferior to that of using a single metal or an alloy, the following compounds containing silicon and / or tin are also preferred because of excellent cycle characteristics.
The element ratio of silicon and / or tin to oxygen is usually 0.5 or more, preferably 0.7 or more, more preferably 0.9 or more, and usually 1.5 or less, preferably 1. “Silicon and / or tin oxide” of 3 or less, more preferably 1.1 or less.

-Element ratio of silicon and / or tin and nitrogen is usually 0.5 or more, preferably 0.7 or more, more preferably 0.9 or more, and usually 1.5 or less, preferably 1. “Silicon and / or tin nitride” of 3 or less, more preferably 1.1 or less.
The elemental ratio of silicon and / or tin to carbon is usually 0.5 or more, preferably 0.7 or more, more preferably 0.9 or more, and usually 1.5 or less, preferably 1. “Carbide of silicon and / or tin” of 3 or less, more preferably 1.1 or less.
In addition, any one of the above-described negative electrode active materials may be used alone, or two or more thereof may be used in any combination and ratio.

<2-4-3. Lithium-containing metal composite oxide material>
The lithium-containing metal composite oxide material used as the negative electrode active material is not particularly limited as long as it can occlude and release lithium, but lithium-containing composite metal oxide materials containing titanium are preferable, and lithium and titanium composite oxidation (Hereinafter sometimes abbreviated as “lithium titanium composite oxide”) is particularly preferable. That is, it is particularly preferable to use a lithium titanium composite oxide having a spinel structure in a negative electrode active material for a lithium ion non-aqueous electrolyte secondary battery because the output resistance is greatly reduced.

In addition, lithium or titanium of the lithium titanium composite oxide is at least selected from the group consisting of other metal elements such as Na, K, Co, Al, Fe, Ti, Mg, Cr, Ga, Cu, Zn, and Nb. Those substituted with one element are also preferred.
The metal oxide as the negative electrode active material is a lithium-titanium composite oxide represented by the following general formula (5). In the general formula (5), 0.7 ≦ x ≦ 1.5, 1.5 It is preferable that ≦ y ≦ 2.3 and 0 ≦ z ≦ 1.6 because the structure upon doping and dedoping of lithium ions is stable.

_{Li x Ti y M z O 4} (5)
(In General Formula (5), M represents at least one element selected from the group consisting of Na, K, Co, Al, Fe, Ti, Mg, Cr, Ga, Cu, Zn, and Nb.)
Among the compositions represented by the general formula (5),
(A) 1.2 ≦ x ≦ 1.4, 1.5 ≦ y ≦ 1.7, z = 0
(B) 0.9 ≦ x ≦ 1.1, 1.9 ≦ y ≦ 2.1, z = 0
(C) 0.7 ≦ x ≦ 0.9, 2.1 ≦ y ≦ 2.3, z = 0
This structure is particularly preferable because of a good balance of battery performance.

Particularly preferred representative compositions of the above compounds are Li _4/3 Ti _5/3 O ₄ in (a), Li ₁ Ti ₂ O ₄ in (b), and Li _4/5 Ti _11/5 O in (c). ₄ . As for the structure of z ≠ 0, for example, Li _4/3 Ti _4/3 Al _1/3 O ₄ is preferable.
In addition to the above requirements, the lithium titanium composite oxide as the negative electrode active material in the present invention further satisfies at least one of the characteristics such as physical properties and shapes shown in the following [1] to [8]. It is preferable to satisfy a plurality of items at the same time.

[1] BET specific surface area The BET specific surface area of the lithium-titanium composite oxide used as the negative electrode active material is preferably 0.5 m ² · g ⁻¹ or more as measured by the BET method. 7m ²・ g
More preferably at least ^-1, more preferably 1.0 m ² · ^{g -1} or more, particularly preferably 1.5 m ² · ^{g -1} or more,, 200 meters ² · ^{g -1} or less is preferable, 100 m ² · g ^{- 1} or less is more preferable, 50 m ² · g ⁻¹ or less is further preferable, and 25 m ² · g ⁻¹ or less is particularly preferable.

When the BET specific surface area is within the above range, the reaction area in contact with the non-aqueous electrolyte when used as the negative electrode material is unlikely to decrease, and the output resistance can be prevented from increasing. Furthermore, since the increase in the surface and end face portions of the metal oxide crystal containing titanium is suppressed and the resulting crystal distortion is less likely to occur, a preferable battery is easily obtained.
The specific surface area of the lithium-titanium composite oxide was preliminarily dried at 350 ° C. for 15 minutes under a nitrogen flow using a surface area meter (a fully automatic surface area measuring device manufactured by Rikura Okura) using a surface area meter. Thereafter, a nitrogen adsorption BET one-point method using a gas flow method is performed using a nitrogen helium mixed gas that is accurately adjusted so that the value of the relative pressure of nitrogen with respect to atmospheric pressure is 0.3. The specific surface area determined by the measurement is defined as the BET specific surface area of the lithium titanium composite oxide in the present invention.

[2] Volume-based average particle size The volume-based average particle size of the lithium-titanium composite oxide (secondary particle size when primary particles are aggregated to form secondary particles) is determined by the laser diffraction / scattering method. It is defined by the obtained volume-based average particle diameter (median diameter).
The volume-based average particle diameter of the lithium titanium composite oxide is preferably 0.1 μm or more, more preferably 0.5 μm or more, further preferably 0.7 μm or more, more preferably 50 μm or less, more preferably 40 μm or less, and 30 μm. The following is more preferable, and 25 μm or less is particularly preferable.

Specifically, the volume-based average particle diameter of the lithium-titanium composite oxide was measured by adding a lithium-titanium composite oxide to a 0.2% by mass aqueous solution (10 mL) of polyoxyethylene (20) sorbitan monolaurate as a surfactant. The powder is dispersed and the measurement is performed using a laser diffraction / scattering particle size distribution analyzer (LA-700, manufactured by Horiba, Ltd.). The median diameter determined by the measurement is defined as the volume-based average particle diameter of the lithium titanium composite oxide.
When the volume average particle size of the lithium titanium composite oxide is within the above range, the amount of the binder can be suppressed during the production of the negative electrode, and as a result, the battery capacity can be easily prevented from decreasing. Furthermore, when forming a negative electrode plate, a uniform coating surface is likely to be obtained, which is desirable in the battery manufacturing process.

[3] Average primary particle diameter When primary particles are aggregated to form secondary particles, the average primary particle diameter of the lithium titanium composite oxide is preferably 0.01 μm or more, more preferably 0.05 μm or more. Preferably, 0.1 μm or more is more preferable, 0.2 μm or more is particularly preferable, 2 μm or less is preferable, 1.6 μm or less is more preferable, 1.3 μm or less is further preferable, and 1 μm or less is particularly preferable. When the volume-based average primary particle diameter is within the above range, spherical secondary particles are easily formed and the specific surface area is easily secured, so that it is easy to prevent a decrease in battery performance such as output characteristics.

  In addition, the primary particle diameter of lithium titanium complex oxide is measured by observation using a scanning electron microscope (SEM). Specifically, in a photograph at a magnification at which particles can be confirmed, for example, a magnification of 10,000 to 100,000 times, the longest value of the intercept by the left and right boundary lines of the primary particles with respect to the horizontal straight line is determined for any 50 primary particles. Obtained and obtained by taking an average value.

[4] Shape The shape of the lithium-titanium composite oxide particles is a lump, polyhedron,
Spherical, elliptical spherical, plate-like, needle-like, columnar, etc. may be used. Among them, primary particles are aggregated to form secondary particles, and the secondary particles have a spherical or elliptical shape. Is preferred.

In general, an electrochemical element expands and contracts as the active material in the electrode expands and contracts as it is charged and discharged. Therefore, the active material is easily damaged due to the stress or the conductive path is broken. Therefore, it is possible to relieve the stress of expansion and contraction and prevent deterioration when the primary particles are aggregated to form secondary particles, rather than being a single particle active material consisting of only primary particles.
In addition, spherical or oval spherical particles are less oriented during molding of the electrode than plate-like equiaxed particles, so there is less expansion and contraction of the electrode during charge and discharge, and an electrode is produced. The mixing with the conductive material is also preferable because it can be easily mixed uniformly.

[5] The tap density of the tap density lithium-titanium composite oxide is preferably from 0.05 g · ^{cm -3} or more, 0.1 g · ^{cm -3} or more, and more preferably 0.2 g · ^{cm -3} or more, 0.4 g · cm ⁻³ or more is particularly preferable, 2.8 g · cm ⁻³ or less is preferable, 2.4 g · cm ⁻³ or less is further preferable, and 2 g · cm ⁻³ or less is particularly preferable. When the tap density of the lithium-titanium composite oxide is within the above range, a sufficient packing density can be secured when used as a negative electrode, and a contact area between the particles can be secured, so that the resistance between the particles hardly increases. It is easy to prevent the output resistance from increasing. Furthermore, since the space between the particles in the electrode is also appropriate, the flow path of the non-aqueous electrolyte solution can be secured, so that it is easy to prevent an increase in output resistance.

To measure the tap density of the lithium-titanium composite oxide, the sample is passed through a sieve having a mesh size of 300 μm, dropped into a 20 cm ³ tapping cell and filled up to the upper end surface of the cell, and then a powder density measuring device. Using, for example, a tap denser manufactured by Seishin Enterprise Co., Ltd., tapping with a stroke length of 10 mm is performed 1000 times, and the density is calculated from the volume at that time and the mass of the sample. The tap density calculated by the measurement is defined as the tap density of the lithium titanium composite oxide in the present invention.

[6] Circularity When the circularity is measured as the spherical degree of the lithium titanium composite oxide, it is preferably within the following range. The circularity is defined as “circularity = (peripheral length of an equivalent circle having the same area as the particle projection shape) / (actual perimeter of the particle projection shape)”, and is theoretical when the circularity is 1. Become a true sphere.

  The circularity of the lithium-titanium composite oxide is preferably closer to 1. Preferably, it is 0.10 or more, more preferably 0.80 or more, still more preferably 0.85 or more, and particularly preferably 0.90 or more. High current density charge / discharge characteristics generally improve as the circularity increases. Therefore, when the circularity is within the above range, the filling property of the negative electrode active material is not lowered, the increase in resistance between particles can be prevented, and the short time high current density charge / discharge characteristics can be prevented.

  The circularity of the lithium titanium composite oxide is measured using a flow type particle image analyzer (FPIA manufactured by Sysmex Corporation). Specifically, about 0.2 g of a sample is dispersed in a 0.2 mass% aqueous solution (about 50 mL) of polyoxyethylene (20) sorbitan monolaurate, which is a surfactant, and an ultrasonic wave of 28 kHz is output at 60 W for 1 After irradiating for minutes, the detection range is specified as 0.6 to 400 μm, and the particle size is measured for particles in the range of 3 to 40 μm. The circularity obtained by the measurement is defined as the circularity of the lithium titanium composite oxide in the present invention.

[7] Aspect ratio The aspect ratio of the lithium titanium composite oxide is preferably 1 or more, preferably 5 or less, more preferably 4 or less, still more preferably 3 or less, and particularly preferably 2 or less. When the aspect ratio is within the above range, streaking is less likely to occur when forming an electrode plate, and a uniform coated surface can be easily obtained, so that it is possible to prevent deterioration of high current density charge / discharge characteristics for a short time. The lower limit of the above range is the theoretical lower limit value of the aspect ratio of the lithium titanium composite oxide.

  The aspect ratio of the lithium titanium composite oxide is measured by magnifying and observing the particles of the lithium titanium composite oxide with a scanning electron microscope. When 50 arbitrary lithium-titanium composite oxide particles fixed to the end face of a metal having a thickness of 50 μm or less are selected, and the stage on which the sample is fixed is rotated and tilted, and three-dimensional observation is performed. The longest diameter A of the particles and the shortest diameter B orthogonal to the same are measured, and the average value of A / B is obtained. The aspect ratio (A / B) determined by the measurement is defined as the aspect ratio of the lithium titanium composite oxide in the present invention.

[8] Method for producing lithium-titanium composite oxide The method for producing lithium-titanium composite oxide is not particularly limited as long as it does not exceed the gist of the present invention. A general method is used.
For example, a method of obtaining an active material by uniformly mixing a titanium source material such as titanium oxide and a source material of another element and a Li source such as LiOH, Li ₂ CO ₃ , or LiNO ₃ as necessary, and firing at a high temperature. Is mentioned.

In particular, various methods are conceivable for producing a spherical or elliptical active material. As an example, a titanium precursor material such as titanium oxide and, if necessary, a raw material material of another element are dissolved or pulverized and dispersed in a solvent such as water, and the pH is adjusted while stirring to create a spherical precursor. There is a method in which the active material is obtained by recovering and drying it as necessary, and then adding a Li source such as LiOH, Li ₂ CO ₃ , or LiNO ₃ and baking at a high temperature.

As another example, a titanium raw material such as titanium oxide and, if necessary, a raw material of another element are dissolved or pulverized and dispersed in a solvent such as water. A method of obtaining an active material by adding a Li source such as LiOH, Li ₂ CO ₃ , LiNO _{3 and the} like to an elliptical spherical precursor and baking at a high temperature can be mentioned.
As yet another method, a titanium raw material such as titanium oxide, a Li source such as LiOH, Li ₂ CO ₃ and LiNO ₃ and a raw material of another element as necessary are dissolved or pulverized in a solvent such as water. There is a method in which it is dispersed and dried by a spray dryer or the like to obtain a spherical or elliptical precursor, which is then fired at a high temperature to obtain an active material.

  Also, during these steps, elements other than Ti, such as Al, Mn, Ti, V, Cr, Mn, Fe, Co, Li, Ni, Cu, Zn, Mg, Ga, Zr, C, Si, Sn , Ag may be present in the metal oxide structure containing titanium and / or in contact with the oxide containing titanium. By containing these elements, the operating voltage and capacity of the battery can be controlled.

<2-4-4. Structure, physical properties and preparation method of negative electrode>
For the negative electrode containing the above active material, electrode forming method, current collector, and non-aqueous electrolyte secondary battery, one or more items of (i) to (vi) shown below are simultaneously satisfied It is desirable that
(I) Production of negative electrode Any known method can be used for production of the negative electrode as long as the effects of the present invention are not significantly limited. For example, a negative electrode active material is formed by adding a binder, a solvent, and, if necessary, a thickener, a conductive material, a filler, etc. to form a slurry, which is applied to a current collector, dried and then pressed. can do.

(Ii) Current collector As the current collector for holding the negative electrode active material, a known material can be arbitrarily used. Examples of the current collector for the negative electrode include metal materials such as aluminum, copper, nickel, stainless steel, and nickel-plated steel. Copper is particularly preferable from the viewpoint of ease of processing and cost.
In addition, the shape of the current collector may be, for example, a metal foil, a metal cylinder, a metal coil, a metal plate, a metal thin film, an expanded metal, a punch metal, a foam metal, or the like when the current collector is a metal material. Among them, a metal thin film is preferable, and a copper foil is more preferable. A rolled copper foil by a rolling method and an electrolytic copper foil by an electrolytic method are more preferable, and both can be used as a current collector.

(Iii) Ratio of thickness of current collector and negative electrode active material layer The ratio of thickness of current collector and negative electrode active material layer is not particularly limited, but “(one side just before the non-aqueous electrolyte injection step) Negative electrode active material layer thickness) / (current collector thickness) "is preferably 150 or less, more preferably 20 or less, particularly preferably 10 or less, and more preferably 0.1 or more. 4 or more is more preferable, and 1 or more is particularly preferable.
When the ratio of the thickness of the current collector to the negative electrode active material layer exceeds the above range, the current collector may generate heat due to Joule heat during high current density charge / discharge. On the other hand, below the above range, the volume ratio of the current collector to the negative electrode active material increases, and the battery capacity may decrease.

(Iv) Electrode density The electrode structure when the negative electrode active material is made into an electrode is not particularly limited, and the density of the negative electrode active material present on the current collector is preferably 1 g · cm ⁻³ or more. .2g · ^{cm -3} or more preferably, 1.3 g · ^{cm -3} or more, and also preferably 4g · ^{cm -3} or less, more preferably 3 g · ^{cm -3} or less, 2.5 g · cm ^{- 3} or less is more preferable, and 1.7 g · cm ⁻³ or less is particularly preferable. When the density of the negative electrode active material existing on the current collector is within the above range, the negative electrode active material particles are less likely to be destroyed, and the increase in initial irreversible capacity and the vicinity of the current collector / negative electrode active material interface It becomes easy to prevent deterioration of high current density charge / discharge characteristics due to a decrease in permeability of the non-aqueous electrolyte. Further, the conductivity between the negative electrode active materials can be secured, and the capacity per unit volume can be earned without increasing the battery resistance.

(V) Binder, solvent, etc. The slurry for forming the negative electrode active material layer is usually prepared by adding a binder, a thickener, etc. to the solvent with respect to the negative electrode active material.
In the non-aqueous electrolyte secondary battery of the present invention, it is sufficient that the specific vinylidene fluoride polymer described above is contained in at least one of the positive electrode and the negative electrode. The dressing is not particularly limited.

When the negative electrode contains the above-mentioned specific vinylidene fluoride polymer, the solvent for forming the slurry includes a negative electrode active material, a binder, and a thickener and a conductive material used as necessary. If it is a solvent which can melt | dissolve or disperse | distribute a material, there will be no restriction | limiting in particular, Either an aqueous solvent or an organic solvent may be used.
Examples of the aqueous solvent include water, alcohol and the like, and examples of the organic solvent include N-methylpyrrolidone (NMP), dimethylformamide, dimethylacetamide, methyl ethyl ketone, cyclohexanone, methyl acetate, methyl acrylate, diethyltriamine, N , N-dimethylaminopropylamine, tetrahydrofuran (THF), toluene, acetone, diethyl ether, dimethylacetamide, hexamethylphosphalamide, dimethyl sulfoxide, benzene, xylene, quinoline, pyridine, methylnaphthalene, hexane, etc. . Of these, N-methylpyrrolidone is preferred.

When the positive electrode contains the above-mentioned specific vinylidene fluoride polymer, the binder used to bind the negative electrode active material may be a material that is stable with respect to the non-aqueous electrolyte and the solvent used during electrode production. There is no particular limitation.
Specific examples include resin-based polymers such as polyethylene, polypropylene, polyethylene terephthalate, polymethyl methacrylate, aromatic polyamide, cellulose, and nitrocellulose; SBR (styrene-butadiene rubber), isoprene rubber, butadiene rubber, fluorine rubber, NBR ( Acrylonitrile / butadiene rubber), rubbery polymers such as ethylene / propylene rubber; styrene / butadiene / styrene block copolymers or hydrogenated products thereof; EPDM (ethylene / propylene / diene terpolymer), styrene / ethylene / Thermoplastic elastomeric polymer such as butadiene / styrene copolymer, styrene / isoprene / styrene block copolymer or hydrogenated product thereof; syndiotactic-1,2-polybutadiene, polyvinyl acetate, ethylene Soft resinous polymers such as vinyl acetate copolymer and propylene / α-olefin copolymer; Fluorine-based polymers such as polyvinylidene fluoride, polytetrafluoroethylene, fluorinated polyvinylidene fluoride, and polytetrafluoroethylene / ethylene copolymer Polymers: Polymer compositions having ionic conductivity of alkali metal ions (particularly lithium ions), and the like. These may be used individually by 1 type, or may use 2 or more types together by arbitrary combinations and ratios.

As the solvent for forming the slurry, the negative electrode active material, the binder, and the thickener and conductive material used as necessary can be dissolved or dispersed as long as it is a solvent. There is no restriction, and either an aqueous solvent or an organic solvent may be used.
Examples of the aqueous solvent include water, alcohol and the like, and examples of the organic solvent include N-methylpyrrolidone (NMP), dimethylformamide, dimethylacetamide, methyl ethyl ketone, cyclohexanone, methyl acetate, methyl acrylate, diethyltriamine, N , N-dimethylaminopropylamine, tetrahydrofuran (THF), toluene, acetone, diethyl ether, dimethylacetamide, hexamethylphosphalamide, dimethyl sulfoxide, benzene, xylene, quinoline, pyridine, methylnaphthalene, hexane, etc. .

In particular, when an aqueous solvent is used, it is preferable to add a dispersant or the like in addition to the thickener and make a slurry using a latex such as SBR.
In addition, these solvents may be used individually by 1 type, or may use 2 or more types together by arbitrary combinations and a ratio.
The ratio of the binder to the negative electrode active material is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 0.6% by mass or more, and particularly preferably 1% by mass or more. 20 mass% or less is preferable, 15 mass% or less is more preferable, and 10 mass% or less is especially preferable. When the ratio of the binder to the negative electrode active material is within the above range, the ratio of the binder that does not contribute to the battery capacity does not increase, so that the battery capacity is hardly lowered. Furthermore, the strength of the negative electrode is hardly lowered.

In particular, when a rubbery polymer typified by SBR is contained as a main component, the ratio of the binder to the negative electrode active material is preferably 0.1% by mass or more, and more preferably 0.5% by mass or more. 0.6 mass% or more is more preferable, 5 mass% or less is preferable, 3 mass% or less is more preferable, and 2 mass% or less is still more preferable.
A thickener is usually used to adjust the viscosity of the slurry. The thickener is not particularly limited, and specific examples include carboxymethyl cellulose, methyl cellulose, hydroxymethyl cellulose, ethyl cellulose, polyvinyl alcohol, oxidized starch, phosphorylated starch, casein, and salts thereof. These may be used individually by 1 type, or may use 2 or more types together by arbitrary combinations and ratios.

  When using a thickener, the ratio of the thickener to the negative electrode active material is usually 0.1% by mass or more, preferably 0.5% by mass or more, and more preferably 0.6% by mass or more. Moreover, it is 5 mass% or less normally, 3 mass% or less is preferable and 2 mass% or less is more preferable. When the ratio of the thickener to the negative electrode active material is within the above range, the coating property is good. Furthermore, the ratio of the negative electrode active material in the negative electrode active material layer is also moderate, and the problem of a decrease in battery capacity and a problem of an increase in resistance between the negative electrode active materials are less likely to occur.

(Vi) Area of Negative Electrode Plate The area of the negative electrode plate is not particularly limited, but it is preferably designed to be slightly larger than the opposing positive electrode plate so that the positive electrode plate does not protrude from the negative electrode plate. Further, from the viewpoint of suppressing the life of a cycle in which charge and discharge are repeated and deterioration due to high temperature storage, it is preferable that the area be as close to the positive electrode as possible, because the ratio of electrodes that work more uniformly and effectively is increased and the characteristics are improved. In particular, when used with a large current, the design of the area of the negative electrode plate is important.

<2-5. Positive electrode>
The positive electrode used for the non-aqueous electrolyte secondary battery of the present invention will be described below.
<2-5-1. Cathode active material>
The positive electrode active material used for the positive electrode will be described below.
(1) Composition The positive electrode active material is not particularly limited as long as it can electrochemically occlude and release lithium ions. For example, a material containing lithium and at least one transition metal is preferable. Specific examples include lithium transition metal composite oxides, lithium-containing transition metal phosphate compounds, lithium-containing transition metal silicate compounds, and lithium-containing transition metal borate compounds.

V, Ti, Cr, Mn, Fe, Co, Ni, Cu, etc. are preferable as the transition metal of the lithium transition metal composite oxide. Specific examples include lithium-cobalt composite oxides such as LiCoO ₂ and LiNiO ₂ . Lithium / nickel composite oxides, LiMnO ₂ , LiMn ₂ O ₄ , Li ₂ MnO _{4 and} other lithium / manganese composite oxides, Al, Ti , V, Cr, Mn, Fe, Co, Li, Ni, Cu, Zn, Mg, Ga, Zr, Si, Nb, Mo, Sn, W and the like substituted with other metals.

As specific examples of the substituted ones, for example, LiNi _0.5 Mn _0.5 O ₂ , LiNi _0.85 Co _0.10 Al _0.05 O ₂ , LiNi _0.33 Co _0.33 Mn _0.33 O ₂ , LiMn _1.8 Al _0.2 O ₄ , LiMn _1.5 Ni _0.5 O _{4 and the} like.
Among these, a composite oxide containing lithium and manganese is more preferable. Cobalt or nickel is an expensive metal with a small amount of resources, and it is not preferable in terms of cost because it uses a large amount of active material in large batteries that require high capacity, such as for automobiles. It is desirable to use manganese as the main transition metal. That is, among the above specific examples, LiNi _0.5 Mn _0.5 O ₂ , LiNi _0.33 Co _0.33 Mn _0.33 O ₂ , LiMn _1.8 Al _0.2 O ₄ , LiMn _1.5 Ni _0.5 O ₄ or the like can be given as a more preferred specific example.

As the transition metal of the lithium-containing transition metal phosphate compound, V, Ti, Cr, Mn, Fe, Co, Ni, Cu and the like are preferable, and specific examples include, for example, LiFePO ₄ , Li ₃ Fe ₂ (PO ₄ ) _3. , Iron phosphates such as LiFeP ₂ O ₇ , cobalt phosphates such as LiCoPO ₄ , manganese phosphates such as LiMnPO ₄ , and some of the transition metal atoms that are the main components of these lithium transition metal phosphate compounds are Al, Ti, V , Cr, Mn, Fe, Co, Li, Ni, Cu, Z
Examples include those substituted with other metals such as n, Mg, Ga, Zr, Si, Nb, Mo, Sn, and W.

The transition metal of the lithium-containing transition metal borate compound, V, Ti, Cr, Mn , Fe, Co, Ni, Cu and the like are preferable, and specific examples, LiFeBO ₃ like boric Santetsurui, LiCoBO ₃ Cobalt borates such as these, some of the transition metal atoms that are the main components of these lithium transition metal borate compounds are Al, Ti, V, Cr, Mn, Fe, Co, Li, Ni, Cu, Zn, Mg, Examples include those substituted with other metals such as Ga, Zr, Si, Nb, Mo, Sn, and W.

(2) Surface coating A material having a composition different from that of the main constituent of the positive electrode active material (hereinafter referred to as “surface adhering substance” as appropriate) may be used on the surface of the positive electrode active material. . Examples of surface adhering substances include aluminum oxide, silicon oxide, titanium oxide, zirconium oxide, magnesium oxide, calcium oxide, boron oxide, antimony oxide, bismuth oxide, lithium sulfate, sodium sulfate, potassium sulfate, magnesium sulfate, Examples thereof include sulfates such as calcium sulfate and aluminum sulfate, carbonates such as lithium carbonate, calcium carbonate and magnesium carbonate, and carbon.

  These surface adhering substances are, for example, a method in which they are dissolved or suspended in a solvent and impregnated and added to the positive electrode active material and then dried, or a surface adhering substance precursor is dissolved or suspended in a solvent and impregnated and added to the positive electrode active material. Then, it can be made to adhere to the surface of the positive electrode active material by a method of reacting by heating or the like, a method of adding to the positive electrode active material precursor and firing simultaneously. In addition, when attaching carbon, the method of attaching carbonaceous material mechanically later, for example in the form of activated carbon etc. can also be used.

The mass of the surface adhering substance adhering to the surface of the positive electrode active material is preferably 0.1 ppm or more, more preferably 1 ppm or more, still more preferably 10 ppm or more with respect to the mass of the positive electrode active material. Further, it is preferably 20% or less, more preferably 10% or less, still more preferably 5% or less.
The surface adhering substance can suppress the oxidation reaction of the non-aqueous electrolyte on the surface of the positive electrode active material, and can improve the battery life. Moreover, when the adhesion amount is within the above range, the effect can be sufficiently exhibited, and resistance is hardly increased without inhibiting the entry and exit of lithium ions.

(3) Shape As the shape of the positive electrode active material particles, a lump shape, a polyhedron shape, a spherical shape, an elliptical spherical shape, a plate shape, a needle shape, a columnar shape, and the like, which are conventionally used, are used. The primary particles may be aggregated to form secondary particles, and the shape of the secondary particles may be spherical or elliptical.
(4) Tap Density Tap density positive electrode active material, preferably at 0.5 g · ^{cm -3} or more, more preferably 1.0 g · ^{cm -3} or more, 1.5 g · ^{cm -3} or more is more preferable. Further, it is preferably 4.0 g · cm ⁻³ or less, and more preferably 3.7 g · cm ⁻³ or less.

  By using a metal composite oxide powder having a high tap density, a high-density positive electrode active material layer can be formed. When the tap density of the positive electrode active material is within the above range, the amount of the dispersion medium required at the time of forming the positive electrode active material layer becomes appropriate, and the amount of the conductive material and binder is also appropriate. The filling rate of the positive electrode active material into the material layer is not limited, and the influence on the battery capacity is reduced.

The tap density of the positive electrode active material is measured by passing a sieve having a mesh size of 300 μm, dropping the sample onto a 20 cm ³ tapping cell to fill the cell volume, and then measuring a powder density measuring device (for example, manufactured by Seishin Enterprise Co., Ltd.). Using a tap denser, tapping with a stroke length of 10 mm is performed 1000 times, and the density is calculated from the volume at that time and the mass of the sample. The tap density calculated by the measurement is defined as the tap density of the positive electrode active material in the present invention.

(5) Median diameter d50
The median diameter d50 (secondary particle diameter when primary particles are aggregated to form secondary particles) of the positive electrode active material particles can be measured using a laser diffraction / scattering particle size distribution analyzer. it can.
The median diameter d50 is preferably 0.1 μm or more, more preferably 0.5 μm or more, further preferably 1 μm or more, particularly preferably 3 μm or more, preferably 30 μm or less, more preferably 20 μm or less, and more preferably 16 μm. The following is more preferable, and 15 μm or less is particularly preferable. When the median diameter d50 is within the above range, it becomes difficult to obtain a high bulk density product, and further, it does not take time for the diffusion of lithium in the particles, so that the battery characteristics are difficult to deteriorate. In addition, when forming a positive electrode of a battery, that is, when an active material, a conductive material, a binder, and the like are slurried with a solvent and applied in a thin film shape, streaking is less likely to occur.

In addition, the filling property at the time of positive electrode preparation can be further improved by mixing two or more types of positive electrode active materials having different median diameters d50 at an arbitrary ratio.
The median diameter d50 of the positive electrode active material is measured using a 0.1 mass% sodium hexametaphosphate aqueous solution as a dispersion medium, and using a particle size distribution meter (for example, LA-920 manufactured by Horiba, Ltd.) In contrast, after the ultrasonic dispersion for 5 minutes, the measurement refractive index is set to 1.24 and measured.

(6) Average primary particle diameter When primary particles are aggregated to form secondary particles, the average primary particle diameter of the positive electrode active material is preferably 0.01 μm or more, more preferably 0.05 μm or more, It is more preferably 0.08 μm or more, particularly preferably 0.1 μm or more, and preferably 3 μm or less, more preferably 2 μm or less, still more preferably 1 μm or less, and particularly preferably 0.6 μm or less. Within the above range, it becomes easy to form spherical secondary particles, the powder filling property becomes appropriate, and a sufficient specific surface area can be secured, so that deterioration of battery performance such as output characteristics can be suppressed. .

  The average primary particle size of the positive electrode active material is measured by observation using a scanning electron microscope (SEM). Specifically, in a photograph at a magnification of 10000 times, the longest value of the intercept by the left and right boundary lines of the primary particles with respect to the horizontal straight line is obtained for any 50 primary particles and obtained by taking the average value. It is done.

(7) BET specific surface area As for the BET specific surface area of the positive electrode active material, the value of the specific surface area measured using the BET method is preferably 0.2 m ² · g ⁻¹ or more, and 0.3 m ² · g ^−1. or more, and further preferably 0.4 m ² · ^{g -1} or higher, and preferably not more than 4.0m ² · ^{g -1,} 2.5m more preferably ² · ^{g -1} or less, 1.5 m ² · g ⁻¹ or less is more preferable. When the value of the BET specific surface area is within the above range, it is easy to prevent a decrease in battery performance. Furthermore, a sufficient tap density can be ensured, and the applicability at the time of forming the positive electrode active material becomes good.

The BET specific surface area of the positive electrode active material is measured using a surface area meter (for example, a fully automatic surface area measuring device manufactured by Okura Riken). Specifically, the sample was pre-dried for 30 minutes at 150 ° C. under a nitrogen flow, and then the nitrogen-helium mixed gas accurately adjusted so that the relative pressure of nitrogen to the atmospheric pressure was 0.3. Is measured by a nitrogen adsorption BET one-point method using a gas flow method. The specific surface area determined by the measurement is defined as the BET specific surface area of the positive electrode active material in the present invention.

(8) Method for Producing Positive Electrode Active Material The method for producing the positive electrode active material is not particularly limited as long as it does not exceed the gist of the present invention, but there are several methods, which are common as methods for producing inorganic compounds. The method is used.
In particular, various methods are conceivable for producing a spherical or elliptical active material. For example, transition metal source materials such as transition metal nitrates and sulfates, and source materials of other elements as necessary. Is dissolved or pulverized and dispersed in a solvent such as water, and the pH is adjusted while stirring to produce and recover a spherical precursor, which is dried as necessary, and then LiOH, Li ₂ CO ₃ , LiNO There is a method in which an active material is obtained by adding a Li source such as ₃ and baking at a high temperature.

In addition, as an example of another method, transition metal raw materials such as transition metal nitrates, sulfates, hydroxides, oxides and the like, and if necessary, raw materials of other elements are dissolved or ground and dispersed in a solvent such as water. Then, it is dry-molded with a spray dryer or the like to obtain a spherical or oval spherical precursor, and a Li source such as LiOH, Li ₂ CO ₃ , LiNO ₃ is added to the precursor and calcined at a high temperature to obtain an active material Is mentioned.

Examples of other methods include transition metal source materials such as transition metal nitrates, sulfates, hydroxides, oxides, Li sources such as LiOH, Li ₂ CO ₃ , LiNO ₃ , and other elements as necessary. The raw material is dissolved or pulverized and dispersed in a solvent such as water, and is then dried by a spray dryer or the like to form a spherical or elliptical precursor, which is fired at a high temperature to obtain an active material. Can be mentioned.

<2-5-2. Positive electrode structure and fabrication method>
Below, the structure of the positive electrode used for this invention and its preparation method are demonstrated.
(Production method of positive electrode)
The positive electrode is produced by forming a positive electrode active material layer containing positive electrode active material particles and a binder on a current collector. The production of the positive electrode using the positive electrode active material can be produced by any known method. For example, a positive electrode active material and a binder, and if necessary, a conductive material and a thickener mixed in a dry form into a sheet form are pressure-bonded to the positive electrode current collector, or these materials are liquid media A positive electrode can be obtained by forming a positive electrode active material layer on the current collector by applying it to a positive electrode current collector and drying it as a slurry by dissolving or dispersing in a slurry.

  The content of the positive electrode active material in the positive electrode active material layer is preferably 60% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, and preferably 99.9% by mass or less. Yes, 99 mass% or less is more preferable. When the content of the positive electrode active material is within the above range, a sufficient electric capacity can be secured. Furthermore, the strength of the positive electrode is sufficient. In addition, the positive electrode active material powder in this invention may be used individually by 1 type, and may use together 2 or more types of a different composition or different powder physical properties by arbitrary combinations and ratios. When two or more active materials are used in combination, the composite oxide containing lithium and manganese is preferably used as a powder component. As described above, cobalt or nickel is an expensive metal with a small amount of resources, and is not preferable in terms of cost because the amount of active material used is large in large batteries that require a high capacity such as automotive applications. Therefore, it is desirable to use manganese as a main component as a cheaper transition metal.

(Conductive material)
A known conductive material can be arbitrarily used as the conductive material. Specific examples include metal materials such as copper and nickel; graphite such as natural graphite and artificial graphite (graphite); carbon black such as acetylene black; and carbonaceous materials such as amorphous carbon such as needle coke. In addition, these may be used individually by 1 type and may use 2 or more types together by arbitrary combinations and a ratio.

  The content of the conductive material in the positive electrode active material layer is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 1% by mass or more, and preferably 50% by mass or less. 30 mass% or less is more preferable, and 15 mass% or less is still more preferable. When the content is within the above range, sufficient conductivity can be secured. Furthermore, it is easy to prevent a decrease in battery capacity.

(Binder)
In the non-aqueous electrolyte secondary battery of the present invention, the above-mentioned specific vinylidene fluoride-based polymer may be contained in at least one of the positive electrode and the negative electrode. The dressing is not particularly limited.
When the positive electrode contains the aforementioned specific vinylidene fluoride polymer, the positive electrode active material, the binder, and the thickener and conductive material used as necessary are used as the solvent for forming the slurry. If it is a solvent which can melt | dissolve or disperse | distribute a material, there will be no restriction | limiting in particular, Either an aqueous solvent or an organic solvent may be used.

  Examples of the aqueous solvent include water, alcohol and the like, and examples of the organic solvent include N-methylpyrrolidone (NMP), dimethylformamide, dimethylacetamide, methyl ethyl ketone, cyclohexanone, methyl acetate, methyl acrylate, diethyltriamine, N , N-dimethylaminopropylamine, tetrahydrofuran (THF), toluene, acetone, diethyl ether, dimethylacetamide, hexamethylphosphalamide, dimethyl sulfoxide, benzene, xylene, quinoline, pyridine, methylnaphthalene, hexane, etc. . Of these, N-methylpyrrolidone is preferred.

  When the negative electrode contains the above-mentioned specific vinylidene fluoride polymer, it is not particularly limited as long as it is a material that can be dissolved or dispersed in a liquid medium used at the time of electrode production. Specific examples include polyethylene and polypropylene. , Resin polymers such as polyethylene terephthalate, polymethyl methacrylate, aromatic polyamide, cellulose, nitrocellulose; SBR (styrene butadiene rubber), NBR (acrylonitrile butadiene rubber), fluorine rubber, isoprene rubber, butadiene rubber, ethylene Rubbery polymers such as propylene rubber; styrene / butadiene / styrene block copolymers or hydrogenated products thereof, EPDM (ethylene / propylene / diene terpolymers), styrene / ethylene / butadiene / ethylene copolymers, styrene・ Isoprene Thermoplastic elastomeric polymers such as styrene block copolymers or hydrogenated products thereof; syndiotactic-1,2-polybutadiene, polyvinyl acetate, ethylene / vinyl acetate copolymers, propylene / α-olefin copolymers, etc. Soft polymer such as polyvinylidene fluoride (PVdF), polytetrafluoroethylene, fluorinated polyvinylidene fluoride, polytetrafluoroethylene / ethylene copolymer, etc .; alkali metal ions (especially lithium ions) Examples thereof include a polymer composition having ion conductivity. In addition, these substances may be used individually by 1 type, and may use 2 or more types together by arbitrary combinations and a ratio.

  The content of the binder in the positive electrode active material layer is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 0.6% by mass or more, and particularly preferably 1% by mass or more. Moreover, 20 mass% or less is preferable, 15 mass% or less is more preferable, and 10 mass% or less is especially preferable. When the ratio of the binder is within the above range, the positive electrode active material can be sufficiently retained and the mechanical strength of the positive electrode can be secured, so that battery performance such as cycle characteristics is improved. Furthermore, it also leads to avoiding a decrease in battery capacity and conductivity.

(Liquid medium)
As a liquid medium used for preparing a slurry for forming a positive electrode active material layer, a positive electrode active material, a conductive material, a binder, and a thickener used as necessary can be dissolved or dispersed. If it is a solvent, there is no restriction | limiting in particular in the kind, You may use either an aqueous solvent or an organic solvent.

  Examples of the aqueous medium include water, a mixed medium of alcohol and water, and the like. Examples of organic media include aliphatic hydrocarbons such as hexane; aromatic hydrocarbons such as benzene, toluene, xylene, and methylnaphthalene; heterocyclic compounds such as quinoline and pyridine; ketones such as acetone, methyl ethyl ketone, and cyclohexanone. Esters such as methyl acetate and methyl acrylate; amines such as diethylenetriamine and N, N-dimethylaminopropylamine; ethers such as diethyl ether and tetrahydrofuran (THF); N-methylpyrrolidone (NMP) and dimethylformamide And amides such as dimethylacetamide; aprotic polar solvents such as hexamethylphosphalamide and dimethyl sulfoxide. In addition, these may be used individually by 1 type and may use 2 or more types together by arbitrary combinations and a ratio.

(Thickener)
When an aqueous medium is used as the liquid medium for forming the slurry, it is preferable to make a slurry using a thickener and a latex such as styrene butadiene rubber (SBR). A thickener is usually used to adjust the viscosity of the slurry.
The thickener is not limited as long as the effect of the present invention is not significantly limited. Specifically, carboxymethylcellulose, methylcellulose, hydroxymethylcellulose, ethylcellulose, polyvinyl alcohol, oxidized starch, phosphorylated starch, casein and salts thereof Etc. These may be used individually by 1 type, or may use 2 or more types together by arbitrary combinations and ratios.

  When a thickener is used, the ratio of the thickener to the positive electrode active material is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and further 0.6% by mass or more. It is preferably 5% by mass or less, more preferably 3% by mass or less, still more preferably 2% by mass or less. When the content is within the above range, the coating property is improved, and further, the ratio of the active material in the positive electrode active material layer becomes sufficient, so that the problem that the battery capacity decreases and the resistance between the positive electrode active materials increases. It is easier to avoid problems.

(Consolidation)
In order to increase the packing density of the positive electrode active material, the positive electrode active material layer obtained by applying the slurry to the current collector and drying is preferably consolidated by a hand press, a roller press or the like. The density of the positive electrode active material layer is preferably 1 g · cm ⁻³ or more, more preferably 1.5 g · cm ⁻³ or more, particularly preferably 2 g · cm ⁻³ or more, and preferably 4 g · cm ⁻³ or less. 3.5 g · cm ⁻³ or less is more preferable, and 3 g · cm ⁻³ or less is particularly preferable.
When the density of the positive electrode active material layer is within the above range, the non-aqueous electrolyte solution permeation into the vicinity of the current collector / active material interface does not decrease, and the charge / discharge characteristics particularly at a high current density are good. Become. Furthermore, the electrical conductivity between the active materials is difficult to decrease, and the battery resistance is difficult to increase.

(Current collector)
There is no restriction | limiting in particular as a material of a positive electrode electrical power collector, A well-known thing can be used arbitrarily. Specific examples include metal materials such as aluminum, stainless steel, nickel plating, titanium, and tantalum; and carbonaceous materials such as carbon cloth and carbon paper. Of these, metal materials, particularly aluminum, are preferred.
Examples of the shape of the current collector include metal foil, metal cylinder, metal coil, metal plate, metal thin film, expanded metal, punch metal, foam metal, etc. A carbon thin film, a carbon cylinder, etc. are mentioned. Of these, metal thin films are preferred. In addition, you may form a thin film suitably in mesh shape.

  The thickness of the current collector is arbitrary, but is preferably 1 μm or more, more preferably 3 μm or more, further preferably 5 μm or more, and preferably 1 mm or less, more preferably 100 μm or less, and further preferably 50 μm or less. preferable. When the thickness of the current collector is within the above range, sufficient strength required for the current collector can be ensured. Furthermore, the handleability is also improved.

The thickness ratio between the current collector and the positive electrode active material layer is not particularly limited, but (active material layer thickness on one side immediately before non-aqueous electrolyte injection) / (current collector thickness) is preferably 150 or less, more preferably 20 or less, particularly preferably 10 or less, preferably 0.1 or more, more preferably 0.4 or more, and particularly preferably 1 or more.
When the ratio of the thickness of the current collector to the positive electrode active material layer is within the above range, the current collector hardly generates heat due to Joule heat during high current density charge / discharge. Furthermore, the volume ratio of the current collector to the positive electrode active material is difficult to increase, and the battery capacity can be prevented from decreasing.

(Electrode area)
From the viewpoint of increasing the stability at high output and high temperature, the area of the positive electrode active material layer is preferably larger than the outer surface area of the battery outer case. Specifically, the total electrode area of the positive electrode with respect to the surface area of the exterior of the non-aqueous electrolyte secondary battery is preferably 20 times or more, and more preferably 40 times or more. The outer surface area of the outer case is the total area obtained by calculation from the vertical, horizontal, and thickness dimensions of the case part filled with the power generation element excluding the protruding part of the terminal in the case of a bottomed square shape. . In the case of a bottomed cylindrical shape, the geometric surface area approximates the case portion filled with the power generation element excluding the protruding portion of the terminal as a cylinder. The total electrode area of the positive electrode is the geometric surface area of the positive electrode mixture layer facing the mixture layer containing the negative electrode active material, and in the structure in which the positive electrode mixture layer is formed on both sides via the current collector foil. , The sum of the areas where each surface is calculated separately.

(Discharge capacity)
When the non-aqueous electrolyte of the present invention is used, the electric capacity of the battery element housed in one battery exterior of the non-aqueous electrolyte secondary battery (electric capacity when the battery is discharged from a fully charged state to a discharged state) ) Is 1 ampere hour (Ah) or more, since the effect of improving the low temperature discharge characteristics is increased. Therefore, the positive electrode plate is designed so that the discharge capacity is fully charged, preferably 3 Ah (ampere hour), more preferably 4 Ah or more, preferably 20 Ah or less, more preferably 10 Ah or less.

  Within the above range, the voltage drop due to the electrode reaction resistance does not become excessive when a large current is taken out, and the deterioration of the power efficiency can be prevented. Furthermore, the temperature distribution due to the internal heat generation of the battery during pulse charge / discharge does not become too large, the durability of repeated charge / discharge is inferior, and the heat dissipation efficiency is poor against sudden heat generation during abnormalities such as overcharge and internal short circuit. The phenomenon of becoming can be avoided.

(Thickness of positive plate)
The thickness of the positive electrode plate is not particularly limited, but from the viewpoint of high capacity, high output, and high rate characteristics, the thickness of the positive electrode active material layer minus the thickness of the current collector is relative to one side of the current collector. 10 μm or more is preferable, 20 μm or more is more preferable, 200 μm or less is preferable, and 100 μm or less is more preferable.

<2-6. Separator>
Usually, a separator is interposed between the positive electrode and the negative electrode in order to prevent a short circuit. In this case, the specific non-aqueous electrolyte in the present invention is usually used by impregnating the separator.
There is no restriction | limiting in particular about the material and shape of a separator, As long as the effect of this invention is not impaired remarkably, a well-known thing can be employ | adopted arbitrarily. Among them, a resin, glass fiber, inorganic material, etc. formed of a material that is stable with respect to the non-aqueous electrolyte solution of the present invention is used, and a porous sheet or a nonwoven fabric-like material having excellent liquid retention properties is used. Is preferred.

  As materials for the resin and glass fiber separator, for example, polyolefins such as polyethylene and polypropylene, aramid resins, polytetrafluoroethylene, polyethersulfone, glass filters and the like can be used. Of these, glass filters and polyolefins are preferred, and polyolefins are more preferred. These materials may be used individually by 1 type, and may use 2 or more types together by arbitrary combinations and a ratio.

  The thickness of the separator is arbitrary, but is preferably 1 μm or more, more preferably 5 μm or more, further preferably 10 μm or more, and preferably 50 μm or less, more preferably 40 μm or less, and even more preferably 30 μm or less. . When the thickness of the separator is within the above range, the insulation and mechanical strength are good. Furthermore, the battery performance such as rate characteristics can be prevented from being lowered, and the energy density of the non-aqueous electrolyte secondary battery as a whole can be prevented from being lowered.

  Furthermore, when a porous material such as a porous sheet or nonwoven fabric is used as the separator, the porosity of the separator is arbitrary, but is preferably 20% or more, more preferably 35% or more, and further 45% or more. Preferably, it is 90% or less, more preferably 85% or less, and further preferably 75% or less. When the porosity is within the above range, the membrane resistance does not increase excessively, and deterioration of rate characteristics can be suppressed. Furthermore, the mechanical strength of the separator becomes appropriate, and the deterioration of the insulation can be suppressed.

Moreover, although the average pore diameter of a separator is also arbitrary, Preferably it is 0.5 micrometer or less, 0.2 micrometer or less is more preferable, Preferably it is 0.05 micrometer or more. When the average pore diameter is within the above range, short circuit is difficult to occur. Furthermore, the film resistance is not increased too much, and the rate characteristics can be prevented from deteriorating.
On the other hand, as the inorganic material, for example, oxides such as alumina and silicon dioxide, nitrides such as aluminum nitride and silicon nitride, and sulfates such as barium sulfate and calcium sulfate are used. Things are used.

  As a form of the separator, a thin film shape such as a nonwoven fabric, a woven fabric, or a microporous film is used. In the thin film shape, those having a pore diameter of 0.01 to 1 μm and a thickness of 5 to 50 μm are preferably used. In addition to the independent thin film shape, a separator formed by forming a composite porous layer containing the inorganic particles on the surface layer of the positive electrode and / or the negative electrode using a resin binder can be used. For example, a porous layer may be formed by using alumina particles having a 90% particle size of less than 1 μm on both surfaces of the positive electrode and using a fluororesin as a binder.

<2-7. Battery design>
(Electrode group)
The electrode group has a laminated structure in which the positive electrode plate and the negative electrode plate are interposed via the separator, and a structure in which the positive electrode plate and the negative electrode plate are wound in a spiral shape via the separator. Either may be used. The ratio of the volume of the electrode group to the internal volume of the battery (hereinafter referred to as electrode group occupancy) is preferably 40% or more, more preferably 50% or more, and preferably 95% or less, 90% The following is more preferable. When the electrode group occupancy is within the above range, the battery capacity is difficult to decrease. In addition, since an appropriate gap space can be secured, the member expands due to the high temperature of the battery or the vapor pressure of the liquid component of the electrolyte increases, and the internal pressure rises. Various characteristics such as high-temperature storage can be deteriorated, and further, a case where a gas release valve that releases the internal pressure to the outside can be avoided.

(Current collection structure)
The current collecting structure is not particularly limited, but in order to more effectively realize the improvement of the discharge characteristics by the non-aqueous electrolyte solution of the present invention, it is necessary to make the structure to reduce the resistance of the wiring part and the joint part. preferable. Thus, when internal resistance is reduced, the effect of using the non-aqueous electrolyte solution of this invention is exhibited especially favorable.

  In the case where the electrode group has the laminated structure described above, a structure formed by bundling the metal core portions of the electrode layers and welding them to the terminals is preferably used. When the area of one electrode increases, the internal resistance increases. Therefore, it is also preferable to reduce the resistance by providing a plurality of terminals in the electrode. When the electrode group has the winding structure described above, the internal resistance can be lowered by providing a plurality of lead structures for the positive electrode and the negative electrode, respectively, and bundling the terminals.

(Protective element)
Protection elements such as PTC (Positive Temperature Coefficient), thermal fuse, thermistor, which increases resistance when abnormal heat is generated or excessive current flows, shuts off current flowing through the circuit due to sudden increase in battery internal pressure or internal temperature during abnormal heat generation And the like (current cutoff valve). It is preferable to select a protective element that does not operate under normal use at a high current, and it is more preferable that the protective element has a design that does not cause abnormal heat generation or thermal runaway even without the protective element.

(Exterior body)
The non-aqueous electrolyte secondary battery of the present invention is usually configured by housing the non-aqueous electrolyte, the negative electrode, the positive electrode, the separator, and the like in an exterior body (exterior case). There is no restriction | limiting in this exterior body, As long as the effect of this invention is not impaired remarkably, a well-known thing can be employ | adopted arbitrarily.
The material of the outer case is not particularly limited as long as it is a substance that is stable with respect to the non-aqueous electrolyte used. Specifically, a nickel-plated steel plate, stainless steel, aluminum or an aluminum alloy, a magnesium alloy, nickel, titanium, or a metal, or a laminated film (laminate film) of a resin and an aluminum foil is used. From the viewpoint of weight reduction, an aluminum or aluminum alloy metal or a laminate film is preferably used.

In the outer case using the above metals, the metal is welded to each other by laser welding, resistance welding, ultrasonic welding, or a sealed sealing structure, or a caulking structure using the above metals through a resin gasket To do. Examples of the outer case using the laminate film include a case where a resin-sealed structure is formed by heat-sealing resin layers. In order to improve sealing performance, a resin different from the resin used for the laminate film may be interposed between the resin layers. In particular, when a resin layer is heat-sealed through a current collecting terminal to form a sealed structure, a metal and a resin are joined, so that a resin having a polar group or a modified group having a polar group introduced as an intervening resin is used. Resins are preferably used.
The shape of the outer case is also arbitrary, and may be any of a cylindrical shape, a square shape, a laminate shape, a coin shape, a large size, and the like.

EXAMPLES Hereinafter, although an Example and a comparative example are given and this invention is demonstrated further more concretely, this invention is not limited to these Examples, unless the summary is exceeded.
<< Example 1-1, Comparative Example 1-1 >>
[Infrared spectroscopic analysis of vinylidene fluoride polymers]
As the vinylidene fluoride polymer, KF polymer L # 9305 (manufactured by Kureha) and KF polymer L # 7208 (manufactured by Kureha), which are N-methyl-2-pyrrolidone solutions, were used.

[Example 1-1]
KF polymer L # 9305 was taken on an aluminum foil, evaporated to dryness on a hot plate, and dried under reduced pressure at 110 ° C. to obtain a film. The IR spectrum of this film was measured. The obtained IR spectrum, the height of the absorption peak near 3025cm ^-1 in which the line connecting the vicinity 3300-2900Cm ^-1 baseline is defined as _{A 3025,} the baseline a line connecting the vicinity 1800-1660Cm ^-1 The height of the absorption peak near ₁₇₅₀ cm ⁻¹ was defined as A ₁₇₅₀ . Since A ₃₀₂₅ = 0.6316 and A ₁₇₅₀ = 0.0739, the ratio A ₁₇₅₀ / A ₃₀₂₅ = 0.1170 was obtained.

[Comparative Example 1-1]
A film was prepared in the same manner as in Example 1-1 except that KF polymer L # 7208 was used instead of KF polymer L # 9305, and the IR spectrum was measured. As a result, A ₃₀₂₅ = 0.1028, A ₁₇₅₀ = 0. As a result, the ratio was A ₁₇₅₀ / A ₃₀₂₅ = 0.0584.

<< Examples 2-1 to 2-2 and Comparative Examples 2-1 to 2-4 >>
[Preparation of non-aqueous electrolyte secondary battery]
<Preparation of positive electrode>
72 parts by mass of lithium manganate (Li _1.1 Mn _1.9 Al _0.1 O ₄ ) as the first positive electrode active material, lithium nickel manganese cobalt composite oxide (Li _{1. 15} Ni _0.45 Mn _0.45 Co _0.10 O ₂ ) 18 parts by mass, 5 parts by mass of carbon black as a conductive agent, KF polymer L # 7208 as a binder (concentration of vinylidene fluoride polymer) 82.5 mass parts) was mixed and slurried with 62.5 parts by mass in N-methyl-2-pyrrolidone, and the resulting slurry was uniformly applied to an aluminum foil having a thickness of 15 μm and dried. A positive electrode was obtained.

<Manufacture of non-aqueous electrolyte secondary battery>
The positive electrode, a negative electrode described later, and a polyolefin separator were laminated in the order of the negative electrode, the separator, and the positive electrode. The battery element thus obtained was wrapped in an aluminum laminate film, injected with an electrolyte solution described later, and then vacuum sealed to produce a sheet-like non-aqueous electrolyte secondary battery.

[Evaluation of non-aqueous electrolyte secondary battery]
Initial charge / discharge In a constant temperature bath of 25 ° C., sheet-like non-aqueous electrolyte secondary battery is 0.1 C (the rated capacity with a discharge capacity of 1 hour rate is 1 C. The current value is 1 C. The same applies hereinafter. )) To a constant current-constant voltage up to 4.2V, and then discharged to 3.0V at 0.1C. Subsequently, the battery was charged at a constant current-constant voltage to 4.2 V at 0.3 C, and then discharged to 3.0 V at 0.3 C. This was carried out for 2 cycles for a total of 3 cycles to stabilize the non-aqueous electrolyte secondary battery. Thereafter, the battery was kept at 60 ° C. for 24 hours to perform aging. Thereafter, charge and discharge were performed at 0.3 C, and the discharge capacity was measured to obtain an initial capacity. Furthermore, the battery was charged to exactly half the initial capacity, and a 50% charged battery was obtained.

-High-temperature cycle test The high-temperature cycle test was conducted in a high-temperature environment of 55 ° C, which is regarded as the actual use upper limit temperature of the non-aqueous electrolyte secondary battery. In a constant temperature bath at 55 ° C., a constant current-constant voltage charge at 1 C to 4.2 V was performed, and a process of discharging to 2.7 V at a constant current of 1 C was regarded as 99 cycles. The ratio of the capacity at the 99th cycle to the capacity at the first cycle was defined as a “capacity maintenance rate after cycle”.

[Example 2-1]
93 parts by mass of graphite powder as an active material, 1 part by mass of carbon black as a conductive agent, and 120 parts by mass of KF polymer L # 9305 (concentration of vinylidene fluoride polymer 5% by mass) as a binder , Mixed and slurried in N-methyl-2-pyrrolidone, the obtained slurry was uniformly applied to a copper foil having a thickness of 12 μm, dried, and roll-pressed to obtain a negative electrode.

Subsequently, in a dry argon atmosphere, 1 mol / L (as a concentration in the non-aqueous electrolyte) of LiPF ₆ sufficiently dried was dissolved in a mixture of ethylene carbonate and diethyl carbonate (volume ratio 3: 7), Further, 1,6-diisocyanatohexane (DIH) was dissolved in an amount of 0.3% by mass (as a concentration in the non-aqueous electrolyte solution) to prepare a non-aqueous electrolyte solution.
Using this negative electrode and a non-aqueous electrolyte, a battery was prepared by the method described above, and the above evaluation was performed.

[Example 2-2]
Dissolve 1,6-diisocyanatohexane in the non-aqueous electrolyte solution and dissolve 0.3% by mass (as a concentration in the non-aqueous electrolyte solution) of Duranate ^TM TPA-100 (manufactured by Asahi Kasei Chemicals) in the non-aqueous electrolyte solution. A battery was prepared in the same manner as in Example 2-1 except that the above evaluation was performed.
[Comparative Example 2-1]
93 parts by mass of graphite powder as an active material, 1 part by mass of carbon black as a conductive agent, and 75 parts by mass of KF polymer L # 7208 (concentration of vinylidene fluoride polymer as a binder) as a binder , Mixed and slurried in N-methyl-2-pyrrolidone, the obtained slurry was uniformly applied to a copper foil having a thickness of 12 μm, dried, and roll-pressed to obtain a negative electrode. A battery was prepared in the same manner as in Example 2-1, except that this negative electrode was used and 1,6-diisocyanatohexane was not dissolved in the nonaqueous electrolytic solution, and the above evaluation was performed.

[Comparative Example 2-2]
A battery was prepared in the same manner as in Comparative Example 2-1, except that 1,6-diisocyanatohexane was dissolved in 0.3% by mass (as a concentration in the non-aqueous electrolyte) in the non-aqueous electrolyte. Carried out.
[Comparative Example 2-3]
A battery was prepared in the same manner as in Comparative Example 2-1, except that 0.3% by mass (as a concentration in the non-aqueous electrolyte solution) of Duranate ^TM TPA-100 was dissolved in the non-aqueous electrolyte solution, and the above evaluation was performed.

[Comparative Example 2-4]
A battery was prepared in the same manner as in Example 2-1, except that 1,6-diisocyanatohexane was not dissolved in the nonaqueous electrolytic solution, and the above evaluation was performed.
Table 1 below shows the capacity retention ratio after cycle normalized by the value of Comparative Example 1-1.

As is apparent from the comparison between Comparative Example 2-1 and Comparative Example 2-4, the capacity maintenance rate after the cycle is reduced simply by using a binder having A ₁₇₅₀ / A ₃₀₂₅ of 0.06 or more and 2 or less. Further, as is clear from the comparison between Comparative Example 2-1 and Comparative Examples 2-2 to 2-3, the capacity retention rate after the cycle is increased simply by using a non-aqueous electrolyte solution containing the specific OCN compound. On the other hand, as shown in Examples 2-1 to 2-2, a nonaqueous electrolytic solution containing a specific OCN compound is used simultaneously with a binder having A ₁₇₅₀ / A ₃₀₂₅ of 0.06 or more and 2 or less. Thus, surprisingly, the capacity retention ratio after the cycle is increased as compared with the case where the non-aqueous electrolyte containing the specific OCN compound is simply used. The specific effects of the present invention are shown.

According to the non-aqueous electrolyte solution of the present invention, a battery with little reduction in capacity can be provided even when charging and discharging are repeated at high temperatures, so that all fields such as electronic devices in which the non-aqueous electrolyte secondary battery is used. Can be suitably used.
The application of the non-aqueous electrolyte solution and the non-aqueous electrolyte secondary battery of the present invention is not particularly limited, and can be used for various known applications. Specific examples of applications include laptop computers, electronic book players, mobile phones, mobile faxes, mobile copy, mobile printers, mobile audio players, small video cameras, LCD TVs, handy cleaners, transceivers, electronic notebooks, calculators, and memories. Cards, portable tape recorders, radios, backup power supplies, automobiles, motorcycles, motorbikes, bicycles, lighting equipment, toys, game machines, watches, electric tools, strobes, cameras, etc.

Claims (5)

In a non-aqueous electrolyte secondary battery comprising a positive electrode and a negative electrode capable of occluding and releasing metal ions, a separator, and a non-aqueous electrolyte solution containing a non-aqueous solvent and an electrolyte dissolved in the non-aqueous solvent,
At least one of the positive electrode or the negative electrode is an electrode having an electrode mixture layer containing an electrode active material and a vinylidene fluoride polymer as a binder,
The vinylidene fluoride based polymer, absorbance around 3025cm ^-1 when measuring IR spectra _{(A 3025)} and 1750 cm ^-1 near the absorbance ratio of _{(A 1750) (A 1750 /} A 3025) is 0. 06 or more and 2 or less,
The non-aqueous electrolyte solution is
A non-aqueous electrolyte secondary battery comprising a compound represented by the following general formula (1):

(In the above formula (1), N represents a nitrogen atom, C represents a carbon atom, O represents an oxygen atom, R ¹ is an organic group which may have a hetero element having 30 or less carbon atoms, and n is 1. Represents an integer of ~ 4.) The negative electrode, the absorbance around 3025cm ^-1 when measuring IR spectra _{(A 3025)} and 1750 cm ^-1 near the absorbance ratio of _{(A 1750) (A 1750 /} A 3025) is 0.06 to 2 2. The non-aqueous electrolyte secondary battery according to claim 1, wherein the electrode mixture layer contains a vinylidene fluoride-based polymer characterized in that the binder is a binder.   The non-aqueous electrolyte secondary solution according to claim 1 or 2, wherein the vinylidene fluoride-based polymer is 0.1 mass% or more and 20 mass% or less as a content in the electrode mixture layer. battery.   4. The non-aqueous electrolyte secondary battery according to claim 1, wherein in the general formula (1), n is 2 or 3. 5.   5. The non-aqueous system according to claim 1, wherein the compound represented by the general formula (1) is contained in a non-aqueous electrolytic solution in an amount of 0.001% by mass to 10% by mass. Electrolyte secondary battery.