JP2013125732A - Positive electrode active material for nonaqueous electrolyte secondary battery, method for manufacturing the same, and nonaqueous electrolyte secondary battery including the positive electrode active material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a positive electrode active material for a nonaqueous electrolyte secondary battery offering a high capacity and high output when used as a positive electrode material.SOLUTION: A method for manufacturing a positive electrode active material for a nonaqueous electrolyte secondary battery includes a first step in which an alkaline solution is added to and mixed with a Li metal complex oxide powder composed of primary particles and secondary particles to disperse W on the surfaces of the primary particles, the alkaline solution containing a W compound dissolved therein, the primary particles being represented by the formula: LiNiCoMO, where 0.10≤x≤0.35, 0≤y≤0.35, 0.97≤z≤1.20, and M represents at least one kind of element selected from Mn, V, Mg, Mo, Nb, Ti, and Al, the secondary particles being composed of aggregates of the primary particles; and a second step in which a heat treatment at 100-800°C is applied to the alkaline solution containing the W compound dissolved therein, and the Li metal complex oxide powder mixed with each other, in an oxygen atmosphere or a vacuum atmosphere to form fine particles containing lithium tungstate represented by LiWO, LiWO, or LiWOon the surfaces of the primary particles.

Description

  The present invention relates to a positive electrode active material for a non-aqueous electrolyte secondary battery, a method for producing the same, and a non-aqueous electrolyte secondary battery using the positive electrode active material.

In recent years, with the widespread use of portable electronic devices such as mobile phones and laptop computers, development of small and lightweight non-aqueous electrolyte secondary batteries having high energy density is strongly desired. In addition, development of a high output secondary battery is strongly desired as a battery for electric vehicles including hybrid vehicles.
As a secondary battery satisfying such requirements, there is a lithium ion secondary battery. This lithium ion secondary battery is composed of a negative electrode, a positive electrode, an electrolyte, and the like, and a material capable of desorbing and inserting lithium is used as the active material of the negative electrode and the positive electrode.

Such a lithium ion secondary battery is currently being actively researched and developed. Among them, a lithium ion secondary battery using a layered or spinel type lithium metal composite oxide as a positive electrode material, Since a high voltage of 4V class can be obtained, practical use is progressing as a battery having a high energy density.
The materials mainly proposed so far include lithium cobalt composite oxide (LiCoO ₂ ), which is relatively easy to synthesize, lithium nickel composite oxide (LiNiO ₂ ) using nickel, which is cheaper than cobalt, and lithium nickel. Examples thereof include cobalt manganese composite oxide (LiNi _1/3 Co _1/3 Mn _1/3 O ₂ ) and lithium manganese composite oxide (LiMn ₂ O ₄ ) using manganese.
Among these, lithium nickel composite oxide and lithium nickel cobalt manganese composite oxide are attracting attention as materials that have good cycle characteristics and can provide high output with low resistance. In recent years, it is important to reduce resistance required for high output. Is being viewed.

Addition of foreign elements is used as a method for realizing the low resistance, and transition metals capable of taking high numbers such as W, Mo, Nb, Ta, Re, etc. are particularly useful.
For example, Patent Document 1 contains one or more elements selected from Mo, W, Nb, Ta, and Re in an amount of 0.1 to 5 mol% with respect to the total molar amount of Mn, Ni, and Co. Lithium transition metal compound powder for a lithium secondary battery positive electrode material has been proposed, and Mo, W, Nb, Ta, and Li in the surface portion of primary particles and the total of metal elements other than Mo, W, Nb, Ta, and Re The total atomic ratio of Re is preferably 5 times or more of the atomic ratio of the entire primary particle.
According to this proposal, it is possible to achieve both low cost and high safety of the lithium transition metal compound powder for the lithium secondary battery positive electrode material, high load characteristics, and improved powder handling properties.

  However, the lithium transition metal compound powder is obtained by pulverizing raw materials in a liquid medium, spray-drying a slurry in which these are uniformly dispersed, and firing the resulting spray-dried body. Therefore, a part of different elements such as Mo, W, Nb, Ta, and Re is replaced with Ni arranged in a layer, and there is a problem that battery characteristics such as battery capacity and cycle characteristics are deteriorated. It was.

Patent Document 2 discloses a positive electrode active material for a non-aqueous electrolyte secondary battery having at least a layered lithium transition metal composite oxide, the lithium transition metal composite oxide being composed of primary particles and aggregates thereof. A non-aqueous electrolyte having a compound which is present in the form of a particle composed of one or both of secondary particles and has at least one selected from the group consisting of molybdenum, vanadium, tungsten, boron and fluorine on at least the surface of the particle A positive electrode active material for a secondary battery has been proposed.
As a result, it is said that a positive electrode active material for a non-aqueous electrolyte secondary battery having excellent battery characteristics even under a more severe use environment can be obtained, and in particular, the surface of the particle is composed of molybdenum, vanadium, tungsten, boron and fluorine. By having a compound having at least one selected from the group, the initial characteristics are improved without impairing the improvement of thermal stability, load characteristics and output characteristics.

  However, the effect of at least one additive element selected from the group consisting of molybdenum, vanadium, tungsten, boron and fluorine is considered to be an improvement in initial characteristics, that is, initial discharge capacity and initial efficiency. is not. Further, according to the disclosed manufacturing method, since the additive element is mixed with the hydroxide that has been heat-treated at the same time as the lithium compound and fired, a part of the additive element is replaced with nickel arranged in layers. There was a problem that caused the battery characteristics to deteriorate.

Further, Patent Document 3 discloses a metal including at least one selected from Ti, Al, Sn, Bi, Cu, Si, Ga, W, Zr, B, and Mo around the positive electrode active material and / or a plurality of these. A positive electrode active material coated with an intermetallic compound and / or oxide obtained by a combination has been proposed.
Such a coating can absorb oxygen gas and ensure safety, but no output characteristics are disclosed. Further, the disclosed manufacturing method is a method of coating using a planetary ball mill, and such a coating method causes physical damage to the positive electrode active material, resulting in deterioration of battery characteristics.

In Patent Document 4, a composite oxide particle mainly composed of lithium nickelate is subjected to heat treatment by adhering a tungstic acid compound, and the content of carbonate ions is 0.15% by weight or less. A positive electrode active material has been proposed.
According to this proposal, there is a tungstic acid compound or a decomposition product of the tungstic acid compound on the surface of the positive electrode active material, and the oxidation activity on the surface of the composite oxide particles in a charged state is suppressed. Although gas generation can be suppressed, the output characteristics are not disclosed at all.

  Furthermore, the disclosed production method preferably comprises a composite oxide particle heated to a boiling point or higher of a solution in which an adherent component is dissolved, and a sulfuric acid compound, a nitric acid compound, a boric acid compound, or a phosphoric acid compound as well as a tungstate compound. A solution dissolved in a solvent is applied as an adsorbing component. Since the solvent is removed in a short time, the tungsten compound is not sufficiently dispersed on the surface of the composite oxide particles and is uniformly applied. It is difficult.

JP 2009-289726 A JP 2005-251716 A Japanese Patent Laid-Open No. 11-16566 JP 2010-40383 A

  In view of such problems, the present invention has an object to provide a positive electrode active material for a non-aqueous electrolyte secondary battery that, when used as a positive electrode material, provides high capacity and high output.

  In order to solve the above-mentioned problems, the present inventor conducted intensive research on the powder characteristics of a lithium metal composite oxide used as a positive electrode active material for a non-aqueous electrolyte secondary battery and the influence on the positive electrode resistance of the battery. It has been found that by forming fine particles containing W and Li on the surface of the primary particles constituting the lithium metal composite oxide powder, the positive electrode resistance of the battery can be reduced and the output characteristics can be improved. Furthermore, as a manufacturing method thereof, it is possible to form fine particles containing W and Li on the entire primary particle surface by mixing and heat-treating an alkaline solution containing tungsten and a lithium metal composite oxide solution. The headline and the present invention have been completed.

That is, the first invention of the present invention is a method for producing a positive electrode active material for a non-aqueous electrolyte secondary battery, the general formula _{Li z Ni 1-x-y} Co x M y O 2 ( where 0.10 ≦ x ≦ 0.35, 0 ≦ y ≦ 0.35, 0.97 ≦ z ≦ 1.20, M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti and Al) An alkaline solution in which a tungsten compound is dissolved in a lithium metal composite oxide powder composed of primary particles and secondary particles formed by agglomeration of primary particles is represented by 0 with respect to 100 g of the lithium metal composite oxide powder. Addition and mixing of 5 to 150 ml to mix the first step of dispersing W on the surface of the primary particle of the lithium metal composite oxide powder or the surface of the primary particle of the powder, and the alkali solution in which the mixed tungsten compound is dissolved The lithium metal composite oxide powder and, in an oxygen atmosphere or in a vacuum atmosphere, by heat treatment at 100 to 800 ° _C., represented by any one of _{Li 2 WO 4, Li 4 WO} 5, Li 6 W 2 O 9 It has the 2nd process of forming the microparticles | fine-particles containing lithium tungstate on the surface of the lithium metal complex oxide powder, or the surface of the primary particle of this powder.

  Moreover, the manufacturing method which concerns on 2nd invention of this invention has the process of washing lithium metal complex oxide powder with water before the 1st process in 1st invention.

  According to a third aspect of the present invention, the amount of tungsten contained in the alkaline solution in which tungsten is dissolved in the first and second aspects of the present invention is such that Ni, Co, and Li contained in the lithium metal composite oxide powder mixed with the alkaline solution. It is characterized by being 0.1 to 3.0 atomic% with respect to the total number of M atoms, and further having a tungsten concentration in the alkaline solution of 0.05 to 2 mol / l.

  According to a fourth aspect of the present invention, the alkaline solution in which tungsten is dissolved in the first to third aspects is obtained by dissolving a tungsten compound in an aqueous lithium hydroxide solution.

  The fifth invention of the present invention is a mixture of an alkaline solution in which the tungsten compound in the first to fourth inventions is dissolved and a lithium metal composite oxide powder, wherein the alkaline solution is liquid and is 50 ° C. or less. It is characterized by being performed at temperature.

Sixth aspect of the present invention, the positive electrode active material for a non-aqueous electrolyte secondary battery, the general formula _{Li z Ni 1-x-y} Co x M y O 2 ( however, 0.10 ≦ x ≦ 0.35, 0 ≦ y ≦ 0.35, 0.97 ≦ z ≦ 1.20, and M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti and Al) Lithium tungstate in which the surface of the lithium metal composite oxide powder composed of secondary particles formed by aggregation of primary particles is represented by any one of Li ₂ WO ₄ , Li ₄ WO ₅ , and Li ₆ W ₂ O ₉ It has the fine particle containing this.

Seventh aspect of the present invention, the positive electrode active material for a non-aqueous electrolyte secondary battery, the general formula _{Li z Ni 1-x-y} Co x M y O 2 ( however, 0.10 ≦ x ≦ 0.35, 0 ≦ y ≦ 0.35, 0.97 ≦ z ≦ 1.20, and M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti and Al) Tungsten in which the primary particle surface of the lithium metal composite oxide powder composed of secondary particles formed by aggregation of primary particles is represented by any one of Li ₂ WO ₄ , Li ₄ WO ₅ , and Li ₆ W ₂ O _9. It has the microparticles | fine-particles containing lithium acid.
The eighth invention of the present invention is characterized in that the lithium tungstate contained in the fine particles in the sixth and seventh inventions is Li ₄ WO ₅ .

  According to a ninth aspect of the present invention, the amount of tungsten contained in the fine particles according to the sixth to eighth aspects of the invention is W with respect to the total number of Ni, Co and M atoms contained in the lithium metal composite oxide. The number of atoms is 0.1 to 3.0 atomic%.

  According to a tenth aspect of the present invention, a non-aqueous electrolyte secondary battery has a positive electrode containing the positive electrode active material according to any one of the sixth to ninth aspects.

ADVANTAGE OF THE INVENTION According to this invention, when used for the positive electrode material of a battery, the positive electrode active material for nonaqueous electrolyte secondary batteries which can implement | achieve high output with a high capacity | capacitance is obtained.
Furthermore, the manufacturing method is easy and suitable for production on an industrial scale, and its industrial value is extremely large.

It is a schematic explanatory drawing of the measurement example of impedance evaluation, and the equivalent circuit used for analysis. It is a cross-sectional SEM photograph (observation magnification 10,000 times) of the lithium metal complex oxide of this invention. It is a schematic sectional drawing of the coin-type battery 1 used for battery evaluation.

  Hereinafter, after describing the positive electrode active material of the present invention, the non-aqueous electrolyte secondary battery using the production method and the positive electrode active material according to the present invention will be described.

(1) the positive electrode active material the positive electrode active material for a non-aqueous electrolyte secondary battery of the present invention have the general formula _{Li z Ni 1-x-y} Co x M y O 2 ( however, 0.10 ≦ x ≦ 0.35, 0 ≦ y ≦ 0.35, 0.97 ≦ z ≦ 1.20, and M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti and Al) The surface of the lithium metal composite oxide powder comprising secondary particles formed by agglomeration of the primary particles has fine particles containing W and Li. As a further aspect, the primary particles of the lithium metal composite oxide powder it is characterized in that it has a fine particle containing lithium tungstate represented by any one of _{Li 2 WO 4, Li 4 WO} 5, Li 6 W 2 O 9 to the surface.

In the present invention, the general formula _{Li z Ni 1-x-y} Co x M y O 2 as the base material ((where, 0.10 ≦ x ≦ 0.35,0 ≦ y ≦ 0.35,0.97 ≦ z ≦ 1.20, where M is a lithium metal composite oxide represented by (at least one element selected from Mn, V, Mg, Mo, Nb, Ti, and Al). Furthermore, by the fine particles containing lithium tungstate formed on the surface of the powder made of lithium metal composite oxide and represented by any one of Li ₂ WO ₄ , Li ₄ WO ₅ and Li ₆ W ₂ O ₉ The output characteristics are improved while maintaining the charge / discharge capacity.

In general, when the surface of the positive electrode active material is completely covered with a different compound, the movement (intercalation) of lithium ions is greatly limited, resulting in a high capacity of the lithium nickel composite oxide. The advantages are erased.
On the other hand, in the present invention, fine particles containing lithium tungstate represented by any one of Li ₂ WO ₄ , Li ₄ WO ₅ and Li ₆ W ₂ O ₉ are formed on the surface of the lithium metal composite oxide powder. However, by forming the lithium tungstate, the fine particles have a higher lithium ion conductivity than the fine particles containing W and Li without forming a compound, and have an effect of promoting the movement of lithium ions. . For this reason, by forming the fine particles on the surface of the lithium metal composite oxide powder, a Li conduction path is formed at the interface with the electrolytic solution, thereby reducing the reaction resistance of the active material and improving the output characteristics. Is.

  Here, when the surface of the positive electrode active material is coated with a layered material, the specific surface area decreases regardless of the coating thickness, so even if the coating has high lithium ion conductivity, The contact area with the liquid becomes small, which tends to cause a decrease in charge / discharge capacity and an increase in reaction resistance. However, by forming fine particles according to the present invention, it is possible to effectively improve lithium ion conduction with a sufficient contact area with the electrolytic solution, thereby suppressing a decrease in charge / discharge capacity and reducing reaction resistance. Can do.

Such fine particles preferably have a particle diameter of 1 to 100 nm.
If the particle diameter is less than 1 nm, fine particles may not have sufficient lithium ion conductivity. Further, if the particle diameter exceeds 100 nm, the formation of the coating with the fine particles becomes non-uniform and the effect of reducing the reaction resistance may not be sufficiently obtained.

  Furthermore, since the contact with the electrolytic solution occurs on the surface of the primary particles, it is important that fine particles are formed on the surface of the primary particles. Here, the primary particle surface in the present invention refers to the primary particle surface exposed on the outer surface of the secondary particle and the void in the vicinity of the inner surface of the secondary particle through which the electrolyte solution can penetrate through the outer surface of the secondary particle. It includes exposed primary particle surfaces. Furthermore, even a grain boundary between primary particles is included as long as the primary particles are not completely bonded and the electrolyte solution can penetrate.

This contact with the electrolytic solution occurs not only on the outer surface of the secondary particles constituted by aggregation of primary particles, but also in the vicinity of the surface of the secondary particles and in the internal voids, and also on the incomplete grain boundaries. It is necessary to form fine particles on the surface of the primary particles to promote the movement of lithium ions. Therefore, the reaction resistance of the lithium metal composite oxide particles can be further reduced by forming fine particles on the entire primary particle surface.
Here, the fine particles do not need to be completely formed on the entire surface of the primary particles, and may be scattered. Even in the scattered state, if fine particles are formed on the primary particle surfaces exposed on the outer surface and the inner voids of the lithium metal composite oxide particles, an effect of reducing the reaction resistance can be obtained.

  The property of the surface of such a lithium metal composite oxide powder can be judged by observing with a field emission scanning electron microscope, for example. For the positive electrode active material for a non-aqueous electrolyte secondary battery of the present invention, the lithium metal composite oxide It has been confirmed that fine particles containing the lithium tungstate are formed on the surface of the oxide powder.

  On the other hand, when fine particles are formed non-uniformly between lithium metal composite oxide powders, the movement of lithium ions between lithium metal composite oxide powders becomes non-uniform. Load is applied, which tends to deteriorate cycle characteristics and increase reaction resistance. Therefore, it is preferable that the fine particles are uniformly formed between the lithium metal composite oxide powders.

The fine particles of the present invention contain W and Li in the form of lithium tungstate and are any of Li ₂ WO ₄ , Li ₄ WO ₅ , Li ₆ W ₂ O ₉ , preferably Li one in which has become a ₄ WO _5. By forming these lithium tungstates, the lithium ion conductivity is further increased, and the effect of reducing the reaction resistance is further increased.

The amount of tungsten contained in the fine particles is preferably 0.1 to 3.0 atomic% with respect to the total number of Ni, Co and M atoms contained in the lithium metal composite oxide. Thereby, it is possible to achieve both high charge / discharge capacity and output characteristics.
If the amount of tungsten is less than 0.1 atomic%, the effect of improving the output characteristics may not be sufficiently obtained. If the amount of tungsten exceeds 3.0 atomic%, the amount of fine particles to be formed increases so that lithium metal is formed. Lithium conduction between the composite oxide and the electrolytic solution may be inhibited, and the charge / discharge capacity may be reduced.

  The amount of lithium contained in the fine particles is not particularly limited, and if contained in the fine particles, an effect of improving lithium ion conductivity can be obtained. Usually, there is surplus lithium on the surface of the lithium metal composite oxide, and the amount of lithium supplied to the fine particles by the surplus lithium when mixed with an alkaline solution may be sufficient, but an amount sufficient to form lithium tungstate It is preferable that

  Further, the total amount of lithium in the positive electrode active material is such that the ratio “Li / M” of the number of atoms of Ni, Co and Mo in the positive electrode active material (M) to the number of Li atoms is 0.95 to 1. 30 is preferable. When the Li / M is less than 0.95, the reaction resistance of the positive electrode in the non-aqueous electrolyte secondary battery using the obtained positive electrode active material increases, and the output of the battery decreases. On the other hand, if Li / M exceeds 1.30, the initial discharge capacity of the positive electrode active material is reduced and the reaction resistance of the positive electrode is also increased.

In the positive electrode active material of the present invention, fine particles containing lithium tungstate represented by any one of Li ₂ WO ₄ , Li ₄ WO ₅ , and Li ₆ W ₂ O ₉ are formed on the primary particle surface of the lithium metal composite oxide. Thus, the output characteristics are improved, and the powder characteristics such as particle size and tap density as the positive electrode active material may be within the range of the positive electrode active material that is usually used.

The effect of attaching fine particles containing lithium tungstate represented by any of Li ₂ WO ₄ , Li ₄ WO ₅ , and Li ₆ W ₂ O _{9 to} the primary particle surface of the lithium metal composite oxide powder is, for example, , Lithium cobalt complex oxide, lithium manganese complex oxide, lithium nickel cobalt manganese complex oxide and other powders, and not only the positive electrode active materials listed in the present invention but also commonly used lithium secondary batteries It can also be applied to a positive electrode active material.

(2) Method for Producing Positive Electrode Active Material Hereinafter, the method for producing a positive electrode active material for a non-aqueous electrolyte secondary battery of the present invention will be described in detail for each step.
[First step]
The first step is an alkaline solution in which a tungsten compound is dissolved in a lithium metal composite oxide powder composed of primary particles and secondary particles formed by aggregation of primary particles (hereinafter, an alkaline solution in which a tungsten compound is dissolved is alkalinized). This is a step of adding and mixing the solution (W). Thereby, W can be disperse | distributed to the primary particle surface of the lithium metal complex oxide powder which can contact electrolyte solution. In the case of mixing a solid tungsten compound, not only dispersion is not sufficient, but Li from the lithium metal composite oxide powder does not elute, and the resulting fine particles may not contain Li and become tungsten oxide.

In the first step, first, a tungsten compound is dissolved in an alkaline solution.
The dissolution method may be a normal powder dissolution method. For example, the tungsten compound may be added and dissolved while stirring the solution using a reaction vessel equipped with a stirring device. It is preferable from the uniformity of dispersion that the tungsten compound is completely dissolved in an alkaline solution.

The tungsten compound is not particularly limited as long as it can be dissolved in an alkaline solution, and it is preferable to use a tungsten compound that is easily soluble in alkali, such as tungsten oxide, lithium tungstate, and ammonium tungstate.
The amount of tungsten dissolved in the alkaline solution is preferably 0.1 to 3.0 atomic% with respect to the total number of nickel, cobalt and M atoms contained in the lithium metal composite oxide to be mixed. Furthermore, in the production method of the present invention, since solid-liquid separation is not performed after mixing with the alkaline solution, the total amount of tungsten in the alkaline solution (W) is dispersed and adhered to the primary particle surface of the lithium metal composite oxide. The amount necessary for forming fine particles on the primary particle surface may be used. However, when the lithium metal composite oxide powder is crushed after the heat treatment, fine particles containing W and Li formed on the surface of the powder may be peeled off, and the tungsten content of the obtained positive electrode active material may be reduced. is there. In such a case, the amount of tungsten to be dissolved in the alkaline solution may be determined in anticipation of the decrease, that is, 5 to 20 atomic% with respect to the added tungsten amount.

The alkaline solution (W) to be mixed with the lithium metal composite oxide is 0.5 to 150 ml, preferably 2 to 150 ml, more preferably 3 to 100 ml, and still more preferably 5 to 150 ml with respect to 100 g of the lithium metal composite oxide powder. What is necessary is just to make it 60 ml and the liquid quantity which can melt | dissolve a tungsten compound. When the alkaline solution (W) is less than 0.5 ml with respect to 100 g of the lithium metal composite oxide powder, the alkaline solution is small and W cannot be uniformly dispersed on the surface of the primary particles. On the other hand, when the alkaline solution (W) exceeds 150 ml, the alkaline solution becomes too much and becomes a slurry when mixed with the lithium metal composite oxide. When the slurry is formed, Li contained in the layered lattice of the lithium metal composite oxide is eluted, which causes a decrease in battery characteristics. By making the alkaline solution (W) 0.5 to 150 ml with respect to 100 g of the lithium metal composite oxide powder, elution of Li contained in the layered lattice is suppressed and W is uniformly dispersed on the surface of the primary particles. be able to.
Moreover, it is preferable that the tungsten concentration of an alkaline solution (W) is 0.05-2 mol / l. If it is less than 0.05 mol / l, a large amount of alkaline solution to be mixed with a low tungsten concentration is required. On the other hand, when the tungsten concentration exceeds 2 mol / l, the alkaline solution is small and W may not be uniformly dispersed on the surface of the primary particles.

  As the alkali used in the alkaline solution, a general alkaline solution that does not contain impurities harmful to the positive electrode active material is used in order to obtain a high charge / discharge capacity. Ammonia and lithium hydroxide, which are free of impurities, can be used, but lithium hydroxide is preferably used from the viewpoint of not inhibiting Li intercalation. When lithium hydroxide is used, the amount of lithium contained in the positive electrode active material after mixing needs to be within the range of Li / M in the above general formula. The atomic ratio is preferably 4.5 to 15.0. Li is eluted and supplied from the lithium metal composite oxide. By using lithium hydroxide in this range, an amount of Li sufficient to form lithium tungstate can be supplied.

The alkaline solution is preferably an aqueous solution. In order to disperse W over the entire surface of the primary particles, it is necessary to permeate into the voids and imperfect grain boundaries inside the secondary particles. When a solvent such as alcohol with high volatility is used, the alkaline solution becomes secondary. The solvent may evaporate and not fully penetrate before it penetrates into the voids inside the particles.
The pH of the alkaline solution may be a pH at which the tungsten compound dissolves, but is preferably 9-12. When the pH is less than 9, the amount of lithium eluted from the lithium metal composite oxide becomes too large, and the battery characteristics may be deteriorated. Moreover, when pH exceeds 12, there exists a possibility that the excessive alkali which remains in lithium metal complex oxide may increase too much, and a battery characteristic may deteriorate.

In the production method of the present invention, the composition of the positive electrode active material obtained is only the lithium content that increases as the alkaline solution is added from the lithium metal composite oxide as the base material. , from the viewpoint of high capacity and low reaction resistance, generally known type _{Li z Ni 1-x-y} Co x M y O 2 ( however, 0.10 ≦ x ≦ 0.35,0 ≦ y ≦ 0. 35, 0.97 ≦ z ≦ 1.20, and M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti, and Al).
In addition, increasing the contact area with the electrolytic solution is advantageous for improving the output characteristics. Therefore, the primary particles and the secondary particles are formed by agglomeration of the primary particles. It is preferable to use a lithium metal composite oxide powder having voids and grain boundaries that can penetrate.

Next, the lithium metal composite oxide powder is added to and mixed with the alkaline solution (W) prepared while stirring.
The mixing is preferably carried out at a temperature of 50 ° C. or lower when the alkaline solution (W) is liquid. The alkaline solution (W) needs to penetrate into the voids and grain boundaries of the secondary particles, and needs to be liquid. On the other hand, when the temperature exceeds 50 ° C., the alkaline solution is dried quickly, and thus there is a possibility that it does not sufficiently penetrate the voids and grain boundaries of the secondary particles. Further, if the drying is fast, elution of Li from the lithium metal composite oxide powder cannot be expected, and in particular, when Li is not contained in the alkaline solution (W), the fine particles formed on the surface may not contain Li.

  The lithium metal composite oxide powder and the alkaline solution (W) are sufficiently mixed in order to make the dispersion of W uniform, and a general mixer can be used for the mixing. For example, the mixture may be sufficiently mixed with the alkaline solution (W) using a shaker mixer, a Laedige mixer, a Julia mixer, a V blender, or the like so that the shape of the lithium metal composite oxide powder is not destroyed. Thereby, W in the alkaline solution (W) can be uniformly distributed on the primary particle surface of the lithium metal composite oxide.

In the production method of the present invention, in order to improve the battery capacity and safety of the positive electrode active material, the lithium metal composite oxide powder as a base material can be further washed with water before the first step.
This washing with water may be performed by a known method and conditions as long as lithium is not excessively eluted from the lithium metal composite oxide powder and the battery characteristics are not deteriorated. In the case of washing with water, either a method of drying and mixing with the alkali solution (W) or a method of mixing with the alkali solution (W) without drying only by solid-liquid separation may be used. In the case of only solid-liquid separation, the water content after mixing with the alkali solution (W) is the maximum water content of the mixture of the dried lithium metal composite oxide powder and the alkali solution (W), that is, the lowest tungsten concentration. It is preferable not to exceed the moisture content when mixed with the alkaline solution (W). When the moisture content increases, lithium eluted from the lithium metal composite oxide becomes excessive, and battery characteristics may be deteriorated.

[Second step]
The second step is a step of heat-treating the lithium metal composite oxide powder mixed with the alkaline solution (W). Accordingly, any one of Li ₂ WO ₄ , Li ₄ WO ₅ , and Li ₆ W ₂ O ₉ from W supplied from the alkaline solution (W) and the alkaline solution (W) or Li supplied by elution of lithium. And a positive electrode active material for a non-aqueous electrolyte secondary battery having fine particles containing W and Li on the primary particle surface of the lithium metal composite oxide.

The heat treatment method is not particularly limited, but is 100 to 800 ° C., preferably 100 to 700 in an oxygen atmosphere or a vacuum atmosphere in order to prevent deterioration of electrical characteristics when used as a positive electrode active material for a non-aqueous electrolyte secondary battery. It heat-processes at the temperature of 100 degreeC, More preferably, 100-650 degreeC.
When the heat treatment temperature is less than 100 ° C., the evaporation of moisture is not sufficient and fine particles may not be formed sufficiently. On the other hand, when the heat treatment temperature exceeds 800 ° C., primary particles of the lithium metal composite oxide are sintered and a part of W is dissolved in the layered structure of the lithium metal composite oxide. The discharge capacity may decrease.

The atmosphere during the heat treatment is preferably an oxidizing atmosphere such as an oxygen atmosphere or a vacuum atmosphere in order to avoid a reaction with moisture or carbonic acid in the atmosphere.
The heat treatment time is not particularly limited, but is preferably 5 to 15 hours in order to sufficiently evaporate the water in the alkaline solution to form fine particles.

(3) Non-aqueous electrolyte secondary battery The non-aqueous electrolyte secondary battery of the present invention includes a positive electrode, a negative electrode, a non-aqueous electrolyte solution, and the like, and includes the same components as those of a general non-aqueous electrolyte secondary battery. The embodiment described below is merely an example, and the nonaqueous electrolyte secondary battery of the present invention can be variously modified based on the knowledge of those skilled in the art based on the embodiment described in the present specification. It can be implemented in an improved form. Moreover, the use of the nonaqueous electrolyte secondary battery of the present invention is not particularly limited.

(A) Positive electrode Using the positive electrode active material for a non-aqueous electrolyte secondary battery described above, for example, a positive electrode of a non-aqueous electrolyte secondary battery is produced as follows.
First, a powdered positive electrode active material, a conductive material, and a binder are mixed, and, if necessary, a target solvent such as activated carbon and viscosity adjustment is added and kneaded to prepare a positive electrode mixture paste.
Each mixing ratio in the positive electrode mixture paste is also an important factor for determining the performance of the non-aqueous electrolyte secondary battery. When the total mass of the solid content of the positive electrode mixture excluding the solvent is 100 parts by mass, the content of the positive electrode active material is 60 to 95 parts by mass in the same manner as the positive electrode of a general non-aqueous electrolyte secondary battery, and the conductive material It is desirable to set the content of 1 to 20 parts by mass and the content of the binder to 1 to 20 parts by mass.

  The obtained positive electrode mixture paste is applied to the surface of a current collector made of, for example, an aluminum foil and dried to disperse the solvent. If necessary, pressurization may be performed by a roll press or the like to increase the electrode density. In this way, a sheet-like positive electrode can be produced. The sheet-like positive electrode can be cut into an appropriate size or the like according to the target battery and used for battery production. However, the method for manufacturing the positive electrode is not limited to the illustrated one, and other methods may be used.

  In producing the positive electrode, as the conductive agent, for example, graphite (natural graphite, artificial graphite, expanded graphite, etc.), carbon black materials such as acetylene black, ketjen black, and the like can be used.

  The binder plays a role of anchoring the active material particles. For example, polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), fluorine rubber, ethylene propylene diene rubber, styrene butadiene, cellulosic resin, polyacrylic. An acid or the like can be used.

  If necessary, a positive electrode active material, a conductive material, and activated carbon are dispersed, and a solvent that dissolves the binder is added to the positive electrode mixture. Specifically, an organic solvent such as N-methyl-2-pyrrolidone can be used as the solvent. Activated carbon can be added to the positive electrode mixture in order to increase the electric double layer capacity.

(B) Negative electrode A negative electrode mixture in which a negative electrode active material capable of occluding and desorbing lithium ions is mixed with a binder and an appropriate solvent is added to the negative electrode. Is applied to the surface of a metal foil current collector such as copper, dried, and compressed to increase the electrode density as necessary.

  As the negative electrode active material, for example, natural graphite, artificial graphite, a fired organic compound such as phenol resin, or a powdery carbon material such as coke can be used. In this case, as the negative electrode binder, a fluorine-containing resin such as PVDF can be used as in the case of the positive electrode, and as a solvent for dispersing these active materials and the binder, N-methyl-2-pyrrolidone or the like can be used. Organic solvents can be used.

(C) Separator A separator is interposed between the positive electrode and the negative electrode. The separator separates the positive electrode and the negative electrode and retains the electrolyte, and a thin film such as polyethylene or polypropylene and a film having many minute holes can be used.

(D) Non-aqueous electrolyte The non-aqueous electrolyte is obtained by dissolving a lithium salt as a supporting salt in an organic solvent.
Examples of the organic solvent include cyclic carbonates such as ethylene carbonate, propylene carbonate, butylene carbonate, and trifluoropropylene carbonate; chain carbonates such as diethyl carbonate, dimethyl carbonate, ethyl methyl carbonate, and dipropyl carbonate; and tetrahydrofuran, 2- One kind selected from ether compounds such as methyltetrahydrofuran and dimethoxyethane, sulfur compounds such as ethylmethylsulfone and butanesultone, phosphorus compounds such as triethyl phosphate and trioctyl phosphate, etc. are used alone or in admixture of two or more. be able to.

As the supporting salt, LiPF ₆ , LiBF ₄ , LiClO ₄ , LiAsF ₆ , LiN (CF ₃ SO ₂ ) ₂ , or a composite salt thereof can be used.
Furthermore, the non-aqueous electrolyte solution may contain a radical scavenger, a surfactant, a flame retardant, and the like.

(E) Battery shape and configuration The shape of the non-aqueous electrolyte secondary battery of the present invention composed of the positive electrode, negative electrode, separator and non-aqueous electrolyte described above can be various, such as a cylindrical type and a laminated type. Can be.
In any case, the positive electrode and the negative electrode are laminated via a separator to form an electrode body, and the obtained electrode body is impregnated with a non-aqueous electrolyte and communicated with the positive electrode current collector and the outside. The positive electrode terminal and the negative electrode current collector and the negative electrode terminal communicating with the outside are connected using a current collecting lead or the like and sealed in a battery case to complete a non-aqueous electrolyte secondary battery. .

(F) Characteristics The nonaqueous electrolyte secondary battery using the positive electrode active material of the present invention has a high capacity and a high output.
The non-aqueous electrolyte secondary battery using the positive electrode active material according to the present invention obtained in a particularly preferred form is, for example, 150 mAh / g or more when used for the positive electrode of a 2032 type coin battery, and 165 mAh / A high initial discharge capacity of not less than g and a low positive electrode resistance are obtained, and the capacity is high and the output is high. Moreover, it can be said that it has high thermal stability and is excellent in safety.

In addition, if the measuring method of the positive electrode resistance in this invention is illustrated, it will become as follows. When the frequency dependence of the battery reaction is measured by a general AC impedance method as an electrochemical evaluation method, the Nyquist diagram based on the solution resistance, the negative electrode resistance and the negative electrode capacity, and the positive electrode resistance and the positive electrode capacity is shown in FIG. Is obtained as follows.
The battery reaction at the electrode consists of a resistance component accompanying the charge transfer and a capacity component due to the electric double layer. When these are expressed as an electric circuit, it becomes a parallel circuit of resistance and capacity. It is represented by an equivalent circuit in which circuits are connected in series. Fitting calculation is performed on the Nyquist diagram measured using this equivalent circuit, and each resistance component and capacitance component can be estimated. The positive electrode resistance is equal to the diameter of the semicircle on the low frequency side of the obtained Nyquist diagram.
From the above, the positive electrode resistance can be estimated by performing AC impedance measurement on the manufactured positive electrode and performing fitting calculation on the obtained Nyquist diagram with an equivalent circuit.

About the secondary battery which has a positive electrode using the positive electrode active material obtained by this invention, the performance (initial stage discharge capacity, positive electrode resistance) was measured.
Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited to these examples.

(Battery manufacture and evaluation)
For the evaluation of the positive electrode active material, a 2032 type coin battery 1 (hereinafter referred to as a coin type battery) shown in FIG. 3 was used.
As shown in FIG. 3, the coin battery 1 includes a case 2 and an electrode 3 accommodated in the case 2.
The case 2 has a positive electrode can 2a that is hollow and open at one end, and a negative electrode can 2b that is disposed in the opening of the positive electrode can 2a. When the negative electrode can 2b is disposed in the opening of the positive electrode can 2a, A space for accommodating the electrode 3 is formed between the negative electrode can 2b and the positive electrode can 2a.

The electrode 3 includes a positive electrode 3a, a separator 3c, and a negative electrode 3b, which are stacked in this order. The positive electrode 3a contacts the inner surface of the positive electrode can 2a, and the negative electrode 3b contacts the inner surface of the negative electrode can 2b. As shown in FIG.
The case 2 includes a gasket 2c, and relative movement is fixed by the gasket 2c so as to maintain a non-contact state between the positive electrode can 2a and the negative electrode can 2b. Further, the gasket 2c also has a function of sealing a gap between the positive electrode can 2a and the negative electrode can 2b to block the inside and outside of the case 2 in an airtight and liquid tight manner.

The coin-type battery 1 shown in FIG. 3 was manufactured as follows.
First, 52.5 mg of a positive electrode active material for a non-aqueous electrolyte secondary battery, 15 mg of acetylene black, and 7.5 mg of polytetrafluoroethylene resin (PTFE) are mixed, and press-molded to a diameter of 11 mm and a thickness of 100 μm at a pressure of 100 MPa. A positive electrode 3a was produced. The produced positive electrode 3a was dried at 120 ° C. for 12 hours in a vacuum dryer.
Using the positive electrode 3a, the negative electrode 3b, the separator 3c, and the electrolytic solution, the coin-type battery 1 described above was produced in a glove box in an Ar atmosphere in which the dew point was controlled at −80 ° C.

As the negative electrode 3b, a negative electrode sheet in which graphite powder having an average particle diameter of about 20 μm punched into a disk shape with a diameter of 14 mm and polyvinylidene fluoride were applied to a copper foil was used.
As the separator 3c, a polyethylene porous film having a film thickness of 25 μm was used. As the electrolytic solution, an equivalent mixed solution (manufactured by Toyama Pharmaceutical Co., Ltd.) of ethylene carbonate (EC) and diethyl carbonate (DEC) using 1M LiClO ₄ as a supporting electrolyte was used.

The initial discharge capacity and positive electrode resistance showing the performance of the manufactured coin battery 1 were evaluated as follows.
The initial discharge capacity is left for about 24 hours after the coin-type battery 1 is manufactured, and after the open circuit voltage OCV (Open Circuit Voltage) is stabilized, the current density with respect to the positive electrode is set to 0.1 mA / cm ² and the cut-off voltage 4 The capacity when the battery was charged to 3 V, discharged after a pause of 1 hour to a cutoff voltage of 3.0 V was defined as the initial discharge capacity.

In addition, the positive electrode resistance is determined by charging the coin-type battery 1 at a charging potential of 4.1 V and measuring it by the AC impedance method using a frequency response analyzer and a potentiogalvanostat (manufactured by Solartron, 1255B). A plot is obtained. Since this Nyquist plot is represented as the sum of the solution resistance, the negative electrode resistance and its capacity, and the characteristic curve indicating the positive electrode resistance and its capacity, the fitting calculation was performed using an equivalent circuit based on this Nyquist plot, and the positive resistance The value of was calculated.
Note that, in this example, Wako Pure Chemical Industries, Ltd. reagent grade samples were used for the production of composite hydroxide, the production of the positive electrode active material, and the secondary battery.

A lithium metal composite represented by Li _1.060 Ni _0.76 Co _0.14 Al _0.10 O ₂ obtained by a known technique of mixing and baking oxide powder containing Ni as a main component and lithium hydroxide Oxide powder was used as a base material. This lithium metal composite oxide powder had an average particle size of 5.0 μm and a specific surface area of 0.9 m ² / g. In addition, the average particle diameter was evaluated using the volume integrated average value in the laser diffraction scattering method, and the specific surface area was evaluated using the BET method based on nitrogen gas adsorption.

Alkaline solution containing tungsten (W) by adding 0.183 g of tungsten oxide (WO ₃ ) and stirring in an aqueous solution in which 0.2 g of lithium hydroxide (LiOH) is dissolved in 3 ml of pure water. Got. Next, an alkaline solution (W) is added to 15 g of the lithium metal composite oxide powder used as a base material, and further sufficiently mixed using a shaker mixer device (TURBULA Type T2C manufactured by Willy et Bacofen (WAB)). Thus, a mixture of the alkaline solution (W) and the lithium metal composite oxide powder was obtained.

The obtained mixture was put in a magnesia baking vessel, heated to 500 ° C. at a temperature rising rate of 2.8 ° C./min in a 100% oxygen stream, heat-treated for 10 hours, and then cooled to room temperature.
When the tungsten content and Li / M of the lithium metal composite oxide powder after the heat treatment were analyzed by ICP method, the tungsten content was a composition of 0.5 atomic% with respect to the total number of Ni, Co and M atoms. It was confirmed that the Li / M was 1.097. From this, it was confirmed that the mixture of the alkaline solution (W) and the lithium metal composite oxide powder was equivalent to the composition after the heat treatment.

Finally, the mixture was pulverized through a sieve having an aperture of 38 μm to obtain a positive electrode active material having fine particles containing W and Li on the primary particle surface.
When the tungsten content and Li / M of the obtained positive electrode active material were analyzed in the same manner as described above, it was confirmed that the tungsten content was 0.45 atomic% and Li / M was 1.082. These values indicate that excess lithium separated during crushing was removed with a sieve together with tungsten.

[Battery evaluation]
The battery characteristics of the coin-type battery 1 shown in FIG. 3 having a positive electrode produced using the obtained positive electrode active material were evaluated. In addition, the positive electrode resistance used the relative value which set Example 1 as 100 as the evaluation value. The initial discharge capacity was 178.8 mAh / g, and the discharge capacity after 500 cycles was 160.9 mAh / g.
Hereinafter, for Examples 2 to 12 and Comparative Example 1, only the substances and conditions changed from those of Example 1 are shown. Table 1 shows the initial discharge capacity and positive electrode resistance evaluation values of Examples 1 to 12 and Comparative Example 1.

A positive electrode active material for a nonaqueous electrolyte secondary battery was obtained and the battery characteristics were evaluated in the same manner as in Example 1 except that the WO ₃ used was 0.549 g. Table 1 shows the results.

  A positive electrode active material for a non-aqueous electrolyte secondary battery was obtained and the battery characteristics were evaluated in the same manner as in Example 1 except that 9 ml of pure water used for preparing the alkaline solution was used. The results are shown in Table 1. .

  Except that the heat treatment after mixing was performed in a vacuum atmosphere at 140 ° C. for 14 hours, in the same manner as in Example 1, a positive electrode active material for a non-aqueous electrolyte secondary battery was obtained and the battery characteristics were evaluated. Table 1 shows.

Lithium metal having a composition represented by Li _1.060 Ni _0.82 Co _0.15 Al _0.03 O ₂ as a base material, an average particle size of 13.2 μm, and a specific surface area of 0.7 m ² / g A positive electrode active material for a non-aqueous electrolyte secondary battery was obtained in the same manner as in Example 1 except that the composite oxide powder was used, and the battery characteristics were evaluated. The results are shown in Table 1.

  A positive electrode active material for a non-aqueous electrolyte secondary battery was obtained and the battery characteristics were evaluated in the same manner as in Example 5 except that the pure water used for the preparation of the alkaline solution was changed to 0.75 ml. Shown in

Lithium metal having a composition represented by Li _1.060 Ni _0.34 Co _0.33 Mn _0.33 O ₂ as a base material, an average particle diameter of 4.1 μm, and a specific surface area of 1.0 m ² / g A positive electrode active material for a non-aqueous electrolyte secondary battery was obtained in the same manner as in Example 1 except that the composite oxide powder was used, and the battery characteristics were evaluated. The results are shown in Table 1.

A positive electrode active material for a non-aqueous electrolyte secondary battery is obtained in the same manner as in Example 1 except that lithium tungstate (Li ₂ WO ₄ ) is used as the tungsten compound and the amount dissolved in the alkaline solution is 0.190 g. In addition, the battery characteristics were evaluated, and the results are shown in Table 1.

  The lithium metal composite oxide as a base material is stirred for 1 minute as a slurry having a concentration of 1.5 g / cc with pure water before mixing with the alkali solution, separated into solid and liquid, then vacuum dried at 200 ° C. and washed with water. Is the same as in Example 1 to obtain a positive electrode active material for a non-aqueous electrolyte secondary battery and evaluate battery characteristics. Table 1 shows the results.

A positive electrode active material for a non-aqueous electrolyte secondary battery was obtained and the battery characteristics were evaluated in the same manner as in Example 1 except that the WO ₃ used was 1.464 g. Table 1 shows the results.

  A positive electrode active material for a non-aqueous electrolyte secondary battery was obtained and the battery characteristics were evaluated in the same manner as in Example 1 except that 18 ml of pure water used for preparing the alkaline solution was changed, and the results are shown in Table 1. .

  Except that the heat treatment after mixing was performed at 700 ° C. for 10 hours, in the same manner as in Example 1, a positive electrode active material for a non-aqueous electrolyte secondary battery was obtained and the battery characteristics were evaluated. Show.

(Comparative Example 1)
The lithium metal composite oxide used as the base material in Example 1 was used as Comparative Example 1 without forming fine particles, and the battery characteristics were evaluated. The results are shown in Table 1.

(Conventional example)
Using a method similar to the example disclosed in Patent Document 4, nickel sulfate, cobalt sulfate, and sodium aluminate are dissolved in water, and a sodium hydroxide solution is added to the mixture while stirring sufficiently. The nickel-cobalt-aluminum composite coprecipitated hydroxide coprecipitate produced so that the molar ratio of Al to Al was Ni: Co: Al = 77: 20: 3 was washed with water and dried, and then lithium hydroxide was added. A precursor was prepared by adding a monohydrate salt and adjusting the molar ratio to be Li: (Ni + Co + Al) = 105: 100. Next, these precursors were calcined at 700 ° C. for 10 hours in an oxygen stream, cooled to room temperature, and then pulverized to be represented by the composition formula Li _1.03 Ni _0.77 Co _0.20 Al _0.03 O ₂ . Composite oxide particles mainly composed of lithium nickelate were prepared.

This composite oxide particles 100 parts by weight of ammonium paratungstate _{((NH 4) 10 W 12} O 41 · 5H 2 O) and 1.632 parts by weight was added and the mixture was thoroughly mixed in a mortar, a stream of oxygen, After baking at 700 degreeC for 4 hours and cooling to room temperature, it took out and grind | pulverized and the positive electrode active material of the prior art example was produced.
The battery characteristics of the coin-type battery 1 shown in FIG. 3 having a positive electrode produced using the obtained positive electrode active material were evaluated. The results are shown in Table 1.

[Evaluation]
As is apparent from Table 1, since the composite hydroxide particles and positive electrode active materials of Examples 1 to 12 were produced according to the present invention, the initial discharge capacity was higher and the positive electrode resistance was lower than that of the conventional example. Thus, the battery has excellent characteristics. In particular, Examples 1 to 9, which were carried out under the preferable conditions of the added tungsten amount, the tungsten concentration of the alkaline solution, and the heat treatment temperature, had even better initial discharge capacity and positive electrode resistance, and were positive electrode active materials for non-aqueous electrolyte secondary batteries. It becomes more suitable as.

FIG. 2 shows an example of a cross-sectional SEM observation result of the positive electrode active material obtained in the example of the present invention. The obtained positive electrode active material is composed of secondary particles composed of primary particles and primary particles agglomerated. It was confirmed from the results of X-ray diffraction analysis that fine particles containing lithium tungstate (Li ₄ WO ₅ ) were formed on the primary particle surface.

In Example 10 in which the added amount of tungsten is large, the formed fine particles are excessive. For this reason, the initial discharge capacity and the positive electrode resistance are lower than those in Examples 1-9.
In Example 11, the amount of pure water used in the preparation of the alkaline solution was large, and it was considered that lithium in the lithium metal composite oxide was eluted, and the initial discharge capacity and the positive electrode resistance were lower than those in Examples 1-9.
Moreover, in Example 12, since the heat treatment temperature after mixing the alkaline solution (W) and the lithium metal composite oxide is as high as 700 ° C., it is considered that tungsten was dissolved in the nickel site of the layered structure of the positive electrode active material, The initial discharge capacity and the positive electrode resistance are lower than those in Examples 1-9.

In Comparative Example 1, since the fine particles containing W and Li according to the present invention are not formed on the surface of the primary particles, the positive electrode resistance is significantly high, and it is difficult to meet the demand for higher output.
Since the conventional example was mixed with a solid tungsten compound, the dispersion of W was not sufficient and the supply of Li into the fine particles was not achieved, resulting in a significantly high positive electrode resistance.
From the above results, it can be confirmed that the nonaqueous electrolyte secondary battery using the positive electrode active material of the present invention has a high initial discharge capacity and a low positive electrode resistance, and is a battery having excellent characteristics.

  The non-aqueous electrolyte secondary battery of the present invention is suitable for a power source of a small portable electronic device (such as a notebook personal computer or a mobile phone terminal) that always requires a high capacity, and an electric vehicle battery that requires a high output. Also suitable.

  In addition, the nonaqueous electrolyte secondary battery of the present invention has excellent safety, and can be downsized and increased in output, and thus is suitable as a power source for an electric vehicle subject to restrictions on mounting space. The present invention can be used not only as a power source for an electric vehicle driven purely by electric energy but also as a power source for a so-called hybrid vehicle used in combination with a combustion engine such as a gasoline engine or a diesel engine.

DESCRIPTION OF SYMBOLS 1 Coin type battery 2 Case 2a Positive electrode can 2b Negative electrode can 2c Gasket 3 Electrode 3a Positive electrode 3b Negative electrode 3c Separator

Claims (11)

Formula _{Li z Ni 1-x-y} Co x M y O 2 ( however, 0.10 ≦ x ≦ 0.35,0 ≦ y ≦ 0.35,0.97 ≦ z ≦ 1.20, M is Lithium metal composite oxide powder comprising primary particles represented by (Mn, V, Mg, Mo, Nb, Ti and Al) and secondary particles formed by aggregation of the primary particles In addition, 0.5 to 150 ml of an alkaline solution in which a tungsten compound is dissolved is added to and mixed with 100 g of the lithium metal composite oxide powder, thereby the surface of the lithium metal composite oxide powder or the primary particles of the powder. A first step of dispersing W on the surface;
Li ₂ WO ₄ , Li ₄ WO _5, Li ₆ W by heat-treating the mixed alkali solution in which the tungsten compound is dissolved and the lithium metal composite oxide powder at 100 to 800 ° C. in an oxygen atmosphere or a vacuum atmosphere. A non-aqueous system comprising a second step of forming fine particles containing lithium tungstate represented by any of ₂ O _{9 on} the surface of the lithium metal composite oxide powder or the primary particles of the powder. A method for producing a positive electrode active material for an electrolyte secondary battery.   The method for producing a positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1, further comprising a step of washing the lithium metal composite oxide powder with water before the first step.   The amount of tungsten contained in the alkaline solution in which the tungsten compound is dissolved is 0.1 to 3.0 atomic% with respect to the total number of Ni, Co and M atoms contained in the lithium metal composite oxide powder to be mixed. The manufacturing method of the positive electrode active material for non-aqueous electrolyte secondary batteries of Claim 1 or 2 characterized by these.   4. The positive electrode for a non-aqueous electrolyte secondary battery according to claim 1, wherein the tungsten concentration in the alkaline solution in which the tungsten compound is dissolved is 0.05 to 2 mol / l. A method for producing an active material.   The method for producing a positive electrode active material for a non-aqueous electrolyte secondary battery according to any one of claims 1 to 4, wherein the alkaline solution is obtained by dissolving a tungsten compound in an aqueous lithium hydroxide solution. .   2. The mixing of the alkaline solution in which the tungsten compound is dissolved and the lithium metal composite oxide powder is performed at a temperature of 50 ° C. or less, wherein the alkaline solution in which the tungsten compound is dissolved is liquid. The manufacturing method of the positive electrode active material for nonaqueous electrolyte secondary batteries of any one of -5. Formula _{Li z Ni 1-x-y} Co x M y O 2 ( however, 0.10 ≦ x ≦ 0.35,0 ≦ y ≦ 0.35,0.97 ≦ z ≦ 1.20, M is A lithium metal composite oxide comprising primary particles represented by at least one element selected from Mn, V, Mg, Mo, Nb, Ti and Al) and secondary particles formed by aggregation of the primary particles. There,
A non-aqueous electrolyte 2 having fine particles containing lithium tungstate represented by any one of Li ₂ WO ₄ , Li ₄ WO ₅ , and Li ₆ W ₂ O _{9 on} the surface of the lithium metal composite oxide. Positive electrode active material for secondary battery. Formula _{Li z Ni 1-x-y} Co x M y O 2 ( however, 0.10 ≦ x ≦ 0.35,0 ≦ y ≦ 0.35,0.97 ≦ z ≦ 1.20, M is A lithium metal composite oxide comprising primary particles represented by at least one element selected from Mn, V, Mg, Mo, Nb, Ti and Al) and secondary particles formed by aggregation of the primary particles. There,
The non-aqueous electrolyte characterized in that primary particles of the lithium metal composite oxide have lithium tungstate fine particles represented by any of Li ₂ WO ₄ , Li ₄ WO ₅ and Li ₆ W ₂ O ₉ on the surface. Positive electrode active material for secondary battery. The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 7 or 8, wherein the lithium tungstate is Li ₄ WO _5.   The amount of tungsten contained in the fine particles is such that the number of W atoms is 0.1 to 3.0 atomic% with respect to the total number of Ni, Co and M atoms contained in the lithium metal composite oxide. The positive electrode active material for a nonaqueous electrolyte secondary battery according to any one of claims 7 to 9.   It has a positive electrode containing the positive electrode active material for nonaqueous electrolyte secondary batteries of any one of Claims 7-10, The nonaqueous electrolyte secondary battery characterized by the above-mentioned.