JP2013052329A - Coater and method of producing film provided with multi-layer film - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a coater enabling good film formation even when a coating liquid of a low viscosity is used and a method of producing a film provided with a multi-layer film.SOLUTION: The coater includes a suction device for reducing the pressure of the space of the tip part of a die and a pocket for storing a coating liquid, and the pocket is located at a position lower than the coating point. With the shortest distance between the downstream lip and a web taken as d1, the shortest distance between the adjacent lip and the web taken as d2, the width of the adjacent lip in the running direction taken as L2, the film thickness of the uppermost layer taken as h1 and the total film thickness of all films other than the uppermost layer taken as h2, the die is configured by arranging blocks in such a way as to meet equations (1)-(4): equation (1) 10 μm≤(d1-d2)≤200 μm; equation (2) d2≤3×h2; equation (3) 50 μm≤L2≤200 μm; and equation (4) dP/dX>0.

Description

  The present invention relates to a coating apparatus that coats a coating liquid onto the surface of a web that is continuously conveyed using an extrusion die, and a method for producing a film with a multilayer film, and more particularly, a coating that forms a plurality of films simultaneously. The present invention relates to an apparatus and a method for producing a film with a multilayer film.

  Conventionally, as a coating apparatus for coating and forming a coating film (coating layer) having a desired thickness on the surface of a flexible support (hereinafter also referred to as a web), a bar coater system, a reverse roll coater system, and a gravure roll coater. A slot die coater method such as a method and an extrusion coater is known.

  Among them, the slot die coater type coating apparatus is widely used because it can apply a thin film (thin layer) at a higher speed than other systems. In recent years, with the spread of personal computers and the thinning of home televisions, the demand for liquid crystal monitors has increased, and the demand for optical films such as polarizing films and optical compensation films that require thin film formation has also increased. Along with this, a slot die coater type coating apparatus capable of forming a thin film and capable of forming a multilayer film has attracted attention.

  As such a slot die coater type coating apparatus, for example, there is an extrusion coating apparatus described in Patent Document 1. The extrusion coating method described in Patent Document 1 is characterized in that, in the extrusion coating method in which two or more coating layers are simultaneously coated on a belt-like support, the lowermost layer viscosity is lower than that of the adjacent layer. Yes. As a result, a coating solution having a high viscosity of 0.01 Pa · s or more can be formed into a thin film and applied at high speed.

JP 2002-59062 A

  However, in the coating method described in Patent Document 1, it is necessary to make the viscosity of the lowermost layer lower than the viscosity of the adjacent layer. This is a great limitation when a multilayer film is formed.

  Also, the lip distance, which is the distance between the lip, which is the tip surface of the block constituting the die that discharges the coating liquid, and the web (band-like support) must be made larger as the lip on the upstream side with respect to the traveling direction of the web. Don't be. As the number of layers increases, the lip distance on the most upstream side becomes larger, which becomes a restriction on the device configuration.

  Furthermore, through extensive research by the present researchers and the like, it has been found that the coating method of Patent Document 1 causes step unevenness and streak defects.

  In view of such circumstances, the present invention is capable of simultaneous multilayer film formation even using a low viscosity coating liquid of 40 mPa · s or less, and can reduce the occurrence of unevenness and streaks, and a film with a multilayer film It is intended to provide a manufacturing method.

  The problems of the present invention can be solved by the following inventions.

That is, the method for producing a film with a multilayer film according to the present invention produces a film with a multilayer film by simultaneously applying a coating liquid having a viscosity of 40 mPa · s or less onto the surface of a web that is continuously supported by a backup roller. A method for producing a film with a multilayer film, comprising: a preparation step of preparing a die composed of a plurality of blocks and a suction device for sucking air; and an upstream side of the die in the running direction of the web From the tip end of the die to the web while reducing the pressure in the pressure reducing step, by reducing the space between the die tip and the web by sucking air from the suction device. And forming a multilayer film on the web, and the die stores the coating liquid formed by combining the plurality of blocks And a pocket below the application point where the application liquid supplied from the pocket is discharged to the web and is in contact with the web or a coating film formed on the web. The shortest distance between the downstream lip, which is the tip surface of the most downstream block with respect to the traveling direction of the blocks, and the web is d1, and is one upstream of the most downstream block. The shortest distance between the adjacent lip located next to the downstream lip and the web, which is the tip surface of the block, is d2, the width of the adjacent lip in the running direction is L2, and the film thickness of the uppermost layer is h1. And when the total film thickness of all films except the uppermost layer is h2, the main feature is that the block is installed and the die is configured so as to satisfy all of Formulas 1 to 4. .
10 μm ≦ (d1−d2) ≦ 200 μm Formula 1
d2 ≦ 3 × h2 Formula 2
50 μm ≦ L2 ≦ 200 μm Formula 3
dP / dX> 0 Equation 4
Thereby, step irregularities and streak defects can be reduced.

Further, the coating apparatus of the present invention applies a coating liquid having a viscosity of 40 mPa · s or less from the tip of a die constituted by a plurality of blocks, and is applied to the surface of the web continuously supported by a backup roller by the coating liquid. A coating apparatus for forming two or more layers simultaneously, wherein air is sucked from the upstream side of the die in the running direction of the web between the die tip and the surface of the web. A suction device for decompressing the space; and a pocket for storing the coating liquid formed by combining the plurality of blocks. The pocket discharges the coating liquid supplied from the pocket to the web. Is disposed at a position below the application point, which is a position in contact with the web or the coating film formed on the web, and is the most downstream in the traveling direction of the block. The shortest distance between the downstream lip, which is the front end surface of the block, and the web is d1, and is the front end surface of the block on the upstream side of one of the most downstream blocks, adjacent to the downstream lip. The shortest distance between the lip and the web is d2, the width of the adjacent lip in the running direction is L2, the film thickness of the uppermost layer is h1, and the total film thickness of all films except the uppermost layer is h2. Then, the main feature is that the block is installed and the die is configured so as to satisfy all of Formulas 1 to 4.
10 μm ≦ (d1−d2) ≦ 200 μm Formula 1
d2 ≦ 3 × h2 Formula 2
50 μm ≦ L2 ≦ 200 μm Formula 3
dP / dX> 0 Equation 4

  Even when a coating solution having a viscosity of 40 mPa · s or less is used, a good film can be formed by simultaneous multilayer coating.

It is sectional drawing which shows an example of the coating device of this invention. It is the schematic which shows the positional relationship and dimension of the die | dye 160 and the web 120. FIG. It is a table | surface which shows evaluation conditions and a result. (A) It is the schematic which shows equal pitch-shaped step unevenness. (B) It is the schematic which shows the step unevenness which generate | occur | produces at random. (A) It is the schematic which shows the grain-shaped stripe. (B) It is the schematic which shows an equipitch-like thin stripe. (C) It is the schematic which shows an equal pitch-shaped thick stripe. (D) It is the schematic which shows a thick stripe.

  Hereinafter, embodiments for carrying out the present invention will be described in detail with reference to the accompanying drawings. Here, in the drawing, portions indicated by the same symbols are similar elements having similar functions. In addition, in the present specification, when a numerical range is expressed using “˜”, upper and lower numerical values indicated by “˜” are also included in the numerical range.

<Configuration of coating apparatus>
The coating apparatus of the present invention uses an extrusion die, applies a coating liquid which is a Newtonian fluid to the surface of a web (also referred to as a support or a film) that is continuously supported by a backup roller, A film with a multilayer film (also referred to as a laminated film) is produced by simultaneously forming two or more layers of the coating liquid on the surface of the web.

  An embodiment of a coating apparatus of the present invention will be described with reference to the drawings. FIG. 1 is a cross-sectional view showing an example of a coating apparatus of the present invention. The coating apparatus 100 of the present invention mainly includes a backup roller 140 that rotates while supporting the web 120, and a die 160 that applies a coating liquid to the web 120.

  The die 160 includes a plurality of blocks 162a, 162b, and 162c. Inside the die 160, a plurality of blocks are combined to form pockets 164a and 164b for storing the coating liquid, and slots 166a and 166b extending from the pockets 164a and 164b to the tip of the die 160. Is done.

  As shown in FIG. 1, the pockets 164a and 164b may be configured to have a substantially circular shape or a semicircular cross-sectional shape. The pockets 164a and 164b are liquid storage spaces for the coating liquid whose cross-sectional shape is extended in the width direction (perpendicular to the drawing) of the die 160.

  Here, FIG. 1 shows three blocks 162a, 162b, and 162c, two pockets 164a and 164b, and two slots 166a and 166b, but the number of blocks is limited to three. The number of pockets and slots is not limited to two. It is possible to form the required number of pockets and slots with the required number of blocks according to the type and number of coating films required.

  The lip, which is the tip surface of the die, is installed at a predetermined distance from the web 120. The most downstream with respect to the conveyance direction of the web 120 (hereinafter, “upstream, downstream, upstream, and downstream” all mean upstream (side) and downstream (side) with respect to the conveyance direction of the web 120. ), The front end surface of the block 162a, which is a block located at the center, is referred to as a downstream lip, and is a middle block (a block adjacent to the downstream lip and one upstream from the block located most downstream). If the front end surface of the block 162b is referred to as an adjacent lip, and the front end portion of the block 162c, which is the most upstream block, is referred to as an upstream lip, the die is formed so that the following expressions 1 to 5 and conditions 1 to 3 are satisfied. Composed.

Here, further description will be given with reference to FIG. FIG. 2 is a schematic diagram showing the positional relationship and dimensions between the die 160 and the web 120. The film thickness of the film applied by the most downstream slot 166a is h1, the film thickness of the film applied by the slot 166b one upstream of the most downstream slot is h2, and the shortest distance between the tip of the adjacent lip and the web is d2, the shortest distance between the tip of the most downstream lip and the web is d1, the length of the adjacent lip in the web conveying direction is L2, and dP / dX is the pressure gradient in the web conveying direction between the most downstream lip and the web. , The coating apparatus 100 is configured to satisfy all of the following conditions.
・ 10μm ≦ (d1-d2) ≦ 200μm Formula 1
D2 ≦ 3 × h2 Formula 2
・ 50μm ≦ L2 ≦ 200μm Formula 3
DP / dX> 0 Formula 4
-A pressure reducing device is provided on the upstream side, and pressure is reduced from the upstream side. Condition 1
・ Coating solution viscosity 40mPa ・ s or less Condition 2
The pocket is positioned so that it is below the application point (where the coating liquid discharged from the die 160 contacts the web 120). Condition 3
Here, as shown in FIG. 1, the pocket position of the condition 3 is located below the application point by X1 and X2. As long as X1 and X2 are positive values, arbitrary values can be adopted as long as they do not adversely affect the configuration of other devices.

  In the above description, an example in which a two-layer coating film is formed on the web has been described. However, when three or more coating films are coated on the web, the total film thickness of the films other than the uppermost layer is h2, and the uppermost layer is formed. The die is configured to satisfy the relationship of the above formula, where the film thickness is h1, the shortest distance between the tip of the most downstream lip and the web is d2, and the shortest distance between the tip of the lip adjacent to the most downstream lip and the web is d2. can do.

  Even if a coating liquid having a viscosity of 40 mPa · s or less is used by configuring the coating apparatus 100 so as to satisfy the above-mentioned conditions of d1, d2, h1, h2, and dP / dX by the inventors' diligent research. It has been found that a laminated film can be produced by forming a good coating film free of unevenness, streaks, bubble streaks, streaks of foreign matter on the lip tip, and the like on the web.

  Next, Formulas 1 to 4 and Conditions 1 to 3 will be described in detail below.

(1) Formula 1 [10 μm ≦ (d1−d2) ≦ 200 μm] The present invention satisfies the relationship of 10 μm ≦ (d1−d2) ≦ 200 μm. If d1-d2 is less than 10 μm, the upper layer bead is disturbed by the lower layer bead, and the entire bead is not uniformly formed. On the other hand, if it is 200 μm or more, d1 may be too large and the bead may be cut off from the end portion or random unevenness may occur.

  Further, when d1-d2 is set to 200 μm or less, simultaneous multi-layer coating can be performed with a wet film thickness of 5 μm or less and a top film adjacent layer with a wet film thickness of 40 μm or less. If the film thickness cannot be reduced, the solid content concentration and viscosity of each layer must be reduced, and layer mixing tends to occur. If d1-d2 exceeds 200 μm, streaks occur and the uppermost film cannot be applied with a wet film thickness of 5 μm or less.

(2) Formula 2 [d2 ≦ 3 × h2] The present invention satisfies the relationship of d2 ≦ 3 × h2. This is because no vortex is formed in the bead formed between the lip adjacent to the most downstream lip and the web, so that the laminated bead can be stably formed.

(3) Formula 3 [50 μm ≦ L2 ≦ 200 μm] The present invention satisfies the relationship of 50 μm ≦ L2 ≦ 200 μm. This is because when L2 is smaller than 200 μm, the degree of decompression can be reduced, and when it is larger than 50 μm, the static contact line at the liquid-liquid interface is prevented from coming off from the lip end surface due to minute disturbance.

(4) Formula 4 [dP / dX] The present invention satisfies the pressure gradient dP / dX> 0 in the web conveyance direction between the most downstream lip and the web. This is because if the shortest distance between the lip and the web is too short with respect to the film thickness, resistance to minute disturbances such as vibration is lowered, and step unevenness occurs.

(5) Condition 1 [Depressurization Application] Here, by widening the gap between the lip and the web, a phenomenon may occur in which the bead on the web surface formed by the coating liquid applied from the tip of the lip is broken. is there. In order to suppress this phenomenon, the bead can be decompressed from the upstream side in the web conveyance direction. In order to reduce disturbance to the bead, it is preferable that the reduced pressure value is as small as possible within the range where the bead is established.

  In order to reduce the pressure from the upstream side in the web conveyance direction, a cover can be provided on the upstream side of the die, and the pressure can be reduced by sucking air out of the cover by a pump as a suction device.

(6) Condition 2 [Viscosity of coating solution of 40 mPa · s or less] For example, when the coating film after drying is very thin like an optical film, in order to increase the wet film thickness and make it easier to apply, Apply the solid content as low as possible. Therefore, the viscosity of the coating solution is also considerably reduced. However, it has been found that when a liquid having a viscosity of 40 mPa · s or less is applied, it is very difficult to form a laminated bead uniformly due to the high fluidity of the liquid. The present invention is a technique that exerts a great effect when a liquid of 40 mPa · s or less is used.

(7) Condition 3 [Pocket Position] Next, the positional relationship between the pocket and the application point will be described with reference to FIG. Here, the application point refers to a position where the coating liquid discharged from the lip contacts the web (the uppermost film on the web when a film is formed on the web). In the present invention, the pocket is arranged so that its position is below the application point. This is because by setting the pocket position below the application point, bubbles and the like are removed without accumulating in the pocket, and bubble streaks are not generated. Therefore, “below the application point” here means not only just below the application point but also the entire position below the horizontal plane passing through the application point and parallel to the ground.

<Evaluation>
Next, evaluation contents and evaluation results of the coating apparatus of the present invention will be described. The evaluation was performed by forming a coating film on the web under predetermined conditions using the coating apparatus described in FIG. 1, and visually observing the formed coating film to evaluate the quality of the film.

  The coating liquid B200 was applied by discharging from the slot 166b, and the coating liquid A210 was applied by discharging from the slot 166a. Application was performed while sucking air from the upstream side in the web traveling direction and reducing the pressure. As shown in FIG. 1, the coating liquid A210 was applied with a wet film thickness of h2 μm, and the coating liquid B200 was applied with a wet film thickness of h1 μm, as shown in FIG.

  As shown in FIG. 2, the shortest distance between the adjacent lip and the web 120 is d2, and the shortest distance between the most downstream lip and the web 120 is d1. The application speed was 30 m / min.

  In this evaluation, the evaluation was performed using an under bite, that is, a coating apparatus satisfying d1> d2.

  FIG. 3 shows the conditions and evaluation results of the examples and comparative examples of the evaluation. FIG. 3 is a table showing evaluation conditions and results. In FIG. 3, the column of the positional relationship between the pocket and the application point indicates the one with the high position (the one on the top). Therefore, when it is described as an application point, it indicates that the application device is set and applied such that the position of the application point is higher than the position of the pocket. In addition, when it is described as a pocket, it indicates that the coating device is set and applied so that the position of the pocket is higher than the position of the application point.

  dP / dX indicates the pressure gradient (inclination) in the web conveying direction between the most downstream lip and the web, positive means that the inclination is positive, negative means that the inclination is negative, Indicates that the slope is zero.

  In the column of step unevenness, streak, and comprehensive evaluation, “o”, “x”, and “not determined” indicate the following.

-Step unevenness column (circle): Under 3 wavelength white light, step unevenness is not visually recognized or slightly visible, but it does not affect performance.

  X: Unevenness is visually recognized under three-wavelength white light, and the performance cannot be satisfied.

Cannot be determined: Application cannot be established, or the application state is too bad to determine which defective mode.
-Lines of stripes ○: Under 3 wavelength white light, streaks are not visually recognized or slightly visible, but the performance is not affected.

  X: Streaks are visually recognized under three-wavelength white light, and the performance cannot be satisfied.

Cannot be determined: Application cannot be established, or the application state is too bad to determine which defective mode.
・ Comprehensive evaluation column ○: Both step unevenness and streaks are judged as ○.

  X: When at least one of step unevenness and streak is x or cannot be judged.

  Here, step unevenness and streaks will be described with reference to FIGS. 4A to 5D. In FIG. 4A to FIG. 5D, the arrows indicate the traveling direction of the web.

  FIG. 4A is a schematic diagram showing stepwise irregularities with an equal pitch. As shown in FIG. 4A, uniform pitch unevenness means that a certain film thickness unevenness parallel to the web width direction (direction perpendicular to the traveling direction) occurs at regular intervals in the web traveling direction. It is what you did.

  FIG. 4B is a schematic diagram showing random unevenness. As shown in FIG. 4B, the step unevenness that occurs randomly means that the film thickness unevenness parallel to the width direction of the web occurs randomly in the direction of travel of the web.

  FIG. 5A is a schematic diagram showing a grain-shaped streak. As shown in FIG. 5 (A), the grain-shaped streaks are those that occur in the form of a grain in the traveling direction of the web.

  FIG. 5B is a schematic diagram showing thin lines having an equal pitch. As shown in FIG. 5 (B), a thin line having an equal pitch is that unevenness of thickness of 1 mm or less parallel to the traveling direction of the web occurs at equal intervals in the width direction of the web. .

  FIG. 5C is a schematic diagram showing thick lines having an equal pitch. As shown in FIG. 5 (C), a thick streak having an equal pitch is one in which film thickness unevenness with a thickness of 1 mm or more parallel to the traveling direction of the web occurs at equal intervals in the width direction of the web. .

  FIG. 5D is a schematic diagram showing thick stripes. As shown in FIG. 5 (D), a thick streak is a film thickness unevenness with a thickness of 1 mm or more parallel to the traveling direction of the web that occurs in the width direction of the web. It seems that.

<< Evaluation results >>
Next, the evaluation results will be described with reference to FIG.

(1) Formula 1 [10 μm ≦ (d1−d2) ≦ 200 μm] Example 1-3 is compared with Comparative Examples 3 and 4. While Example 1-3 satisfies 10 μm ≦ (d1-d2) ≦ 200 μm, Comparative Examples 3 and 4 do not satisfy 10 μm ≦ (d1-d2) ≦ 200 μm. In particular, when Example 3 and Comparative Examples 3 and 4 are compared, Example 3 [(d1−d2) = 200 μm] is a comprehensive evaluation ○ even though the conditions other than d1 and d2 are the same, and Comparative Example 3 [ (d1-d2) = 5] is such a bad application state that the failure mode cannot be judged, and the overall evaluation is x, and Comparative Example 4 [(d1-d2) = 210] is, for example, randomly generated step unevenness Pitch-like thick streaks were generated and the overall evaluation was x. The overall evaluation of Example 1 [(d1-d2) = 10] and Example 2 [(d1-d2) = 100] was also good. Therefore, it was found that by satisfying the condition of 10 μm ≦ (d1−d2) ≦ 200 μm, step unevenness and streak defects can be prevented.

(2) Formula 2 [d2 ≦ 3 × h2] Examples 5 and 8 are compared with Comparative Example 8. Example 5 satisfies d2 <3 × h2, and Example 8 satisfies d2 = 3 × h2, while Comparative Example 8 does not satisfy d2 ≦ 3 × h2. The evaluation conditions other than d2 are the same in Examples 5 and 8 and Comparative Example 8. At this time, in Examples 5 and 8, the overall evaluation was ○, but in Comparative Example 8, an equal pitch step unevenness occurred and the overall evaluation was x. In addition, Examples 1-4 and 6-7 both satisfy d2 ≦ 3 × h2, and are comprehensive evaluations ◯. Therefore, it has been found that satisfying d2 ≦ 3 × h2 can prevent step irregularities and streaks.

(3) Formula 3 [50 μm ≦ L2 ≦ 200 μm] Next, Example 4-6 and Comparative Examples 5 and 6 are compared. Example 4 (L2 = 50), Example 5 (L2 = 100), and Example 6 (L2 = 200) all satisfy 50 μm ≦ L2 ≦ 200 μm, but Comparative Example 5 (L2 = 40) and Comparative Example 6 (L2 = 210) does not satisfy 50 μm ≦ L2 ≦ 200 μm. Example 4-6 and Comparative Examples 5 and 6 have the same evaluation conditions other than L2. In Examples 4-6, the overall evaluation is ○, but in Comparative Example 5, a uniform streak-like fine streak is generated and the overall evaluation is x, and in Comparative Example 6, stepwise unevenness is generated. The overall evaluation is x. Therefore, it was found that by satisfying the condition of 50 μm ≦ L2 ≦ 200 μm, step unevenness and streak defects can be prevented.

(4) About Formula 4 [dP / dX] In all of Examples 1 to 8, dP / dX is positive and the overall evaluation is “good”. On the other hand, in Comparative Example 1 in which dP / dX is negative and Comparative Example 2 in which dP / dX is 0 (zero), uniform pitch unevenness occurs and the overall evaluation is x. Therefore, it was found that step unevenness can be prevented by satisfying the condition of dP / dX> 0.

(5) Condition 2 [Coating liquid viscosity of 40 mPa · s or less] In Comparative Example 9, the coating liquid viscosity is 60 mPa · s, which is larger than 40 mPa · s. In this case, the overall evaluation is ○ even if dP / dX is negative. This shows a conventional coating method using a highly viscous coating solution. However, in recent years, there has been a high demand for forming a thin film, and it has been necessary to use a low-viscosity coating solution in order to form a thin film.

  Here, referring to Comparative Example 1, when forming a film under the same conditions as Comparative Example 9 (conventional conditions using a high-viscosity coating liquid) except that the viscosity is 40 mPa · s, uneven steps with an equal pitch are observed. It has occurred. As a result, when using a low-viscosity coating solution having a coating solution viscosity of 40 mPa · s or less, a step unevenness that does not occur when using a coating solution having a viscosity higher than 40 mPa · s occurs. discovered.

(6) Condition 3 [Pocket Position] Example 5 and Comparative Example 7 are compared. Example 5 was applied with an apparatus having a higher application point than the pocket position, and Comparative Example 7 was applied with an apparatus having a higher pocket position than the application point. The evaluation conditions other than the height positions of the pockets and the application points are the same in Example 5 and Comparative Example 7. At this time, in Example 5, the overall evaluation was ○, but in Comparative Example 7, a thick streak apparently caused by bubbles was generated, and the overall evaluation was x. In addition, Examples 1-4 and 6-8 were applied with an apparatus having a higher application point than the pocket position, and were evaluated as a comprehensive evaluation. Therefore, it was found that defects due to bubbles can be prevented by applying at a position where the application point is higher than the pocket position.

  DESCRIPTION OF SYMBOLS 100 ... Application | coating apparatus, 120 ... Web, 140 ... Backup roller, 160 ... Die, 162a ... Block, 162b ... Block, 162c ... Block, 164a ... Pocket, 164b ... Pocket, 166a ... Slot, 166b ... Slot, 200 ... Application liquid B, 210 ... coating solution A

Claims (2)

A method for producing a film with a multilayer film, in which a film with a multilayer film is produced by simultaneously applying a coating liquid having a viscosity of 40 mPa · s or less onto the surface of a web continuously supported by a backup roller,
A preparation step of preparing a die composed of a plurality of blocks and a suction device for sucking air;
A depressurization step of depressurizing a space between the tip of the die and the web by sucking air from the upstream side of the die with respect to the traveling direction of the web by the suction device;
A film forming step of forming a multilayer film on the web by discharging the coating liquid from the tip of the die to the web while reducing the pressure in the pressure reducing step;
With
The die has a pocket for storing the coating liquid formed by combining the plurality of blocks,
The pocket is disposed at a position below the application point where the coating liquid supplied from the pocket is discharged to the web and is in contact with the web or a coating film formed on the web,
D1 is the shortest distance between the downstream lip, which is the tip surface of the most downstream block with respect to the traveling direction, and the web among the blocks,
D2 represents the shortest distance between the web and the adjacent lip located next to the downstream lip, which is the front end surface of the block on the upstream side of the most downstream block,
The width of the adjacent lip in the running direction is L2,
The film thickness of the top layer is h1,
The manufacturing method of the film with a multilayer film by which the said block was installed and the said die | dye was comprised so that all of Formula 1-Formula 4 might be satisfy | filled when the total film thickness of all the films | membranes except the uppermost layer was set to h2.
10 μm ≦ (d1−d2) ≦ 200 μm Formula 1
d2 ≦ 3 × h2 Formula 2
50 μm ≦ L2 ≦ 200 μm Formula 3
dP / dX> 0 Equation 4 A coating solution having a viscosity of 40 mPa · s or less is applied from the tip of a die composed of a plurality of blocks, and two or more layers of the coating solution are simultaneously formed on the surface of the web that is continuously supported by a backup roller. An application device for
A suction device for decompressing the space between the die tip and the surface of the web by sucking air from the upstream side of the die in the traveling direction of the web;
A pocket for storing the coating liquid formed by combining the plurality of blocks;
With
The pocket is disposed at a position below the application point where the coating liquid supplied from the pocket is discharged to the web and is in contact with the web or a coating film formed on the web,
D1 is the shortest distance between the downstream lip, which is the tip surface of the most downstream block with respect to the traveling direction, and the web among the blocks,
D2 represents the shortest distance between the web and the adjacent lip located next to the downstream lip, which is the front end surface of the block on the upstream side of the most downstream block,
The width of the adjacent lip in the running direction is L2,
The film thickness of the top layer is h1,
A coating apparatus in which the die is configured by installing the block so as to satisfy all of Formulas 1 to 4, where h2 is the total thickness of all films except the uppermost layer.
10 μm ≦ (d1−d2) ≦ 200 μm Formula 1
d2 ≦ 3 × h2 Formula 2
50 μm ≦ L2 ≦ 200 μm Formula 3
dP / dX> 0 Equation 4

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