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JP2012233122A - Soil deodorizing material, and soil deodorizing execution method - Google Patents

Soil deodorizing material, and soil deodorizing execution method Download PDF

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Publication number
JP2012233122A
JP2012233122A JP2011103918A JP2011103918A JP2012233122A JP 2012233122 A JP2012233122 A JP 2012233122A JP 2011103918 A JP2011103918 A JP 2011103918A JP 2011103918 A JP2011103918 A JP 2011103918A JP 2012233122 A JP2012233122 A JP 2012233122A
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soil
deodorization
deodorizing
deodorizing material
odors
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Tsutomu Katsura
勤 桂
Michiko Yamakawa
通子 山川
Osamu Tada
修 多田
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SASANUMA TORU
Eco First Co Ltd
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SASANUMA TORU
Eco First Co Ltd
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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

PROBLEM TO BE SOLVED: To suppress explosive generation of septic and decomposed odors such as soil deodorization related to organic waste disposals of food residues and the like and livestock waste disposals, and odors from landfill disposal grounds after killing disposals for foot-and-mouth disease countermeasure.SOLUTION: A soil deodorizing material is configured such that one or a plurality of porous materials is made to carry a single or a plurality of components of antimicrobials and fungicides to sustain long-term antimicrobial and fungicidal effects; slag, coal ash, lime stone and the like are used to control putrescence and decomposition of organic wastes, livestock dungs and livestock killing-disposed-of bodies by killing disposals, in the soil; and by releasing alkali components in the soil, accessory components compensating the flowout of alkalis by rainfall assist the antimicrobial and fungicidal effects. The soil deodorizing material is plowed into surface soil to thereby secure long-term in-soil sterile environment, and to thereby suppress explosive putrescence and decomposition of organic substances, whereby the soil deodorizing execution to thoroughly suppress the generation of odors is carried out.

Description

本発明は、食品残さ等の有機性廃棄物処理、畜産廃棄物処理に関わる土壌消臭、口蹄疫対策の殺処分後の埋め立て処分場などの臭気対策に係り、特に土壌消臭材および土壌消臭施工方法に関する。   The present invention relates to organic waste treatment such as food residues, soil deodorization related to livestock waste treatment, and odor countermeasures such as landfill disposal sites after killing of foot-and-mouth disease countermeasures, especially soil deodorizers and soil deodorizers. It relates to the construction method.

耕地において肥料成分の効果(薬効)を長期間にわたり発揮させる目的と、急激な栄養塩の供給により作物に障害を起こさない目的で、遅効性肥料、緩効性肥料あるいは徐放性肥料と呼ばれる肥料が知られている。   Fertilizers called slow-acting fertilizers, slow-acting fertilizers, or slow-release fertilizers for the purpose of demonstrating the effects (medicinal effects) of fertilizer components over long periods in cultivated land and preventing the crops from being damaged by rapid nutrient supply It has been known.

これら肥料の製造方法を支える技術には特許文献1から4に見られるように3大栄養素のうち、特にカリウムに着目し、スラグなどをケイ酸の供給源として結合させ、ケイ酸カリウム化合物を得、ケイ酸カリウムの溶解度の低さを利用して遅効性を獲得しているものがある。 As seen in Patent Documents 1 to 4, the technology supporting these fertilizer production methods focuses on potassium among the three major nutrients, and slag and the like are combined as a silicic acid supply source to obtain a potassium silicate compound. Some have obtained delayed action by utilizing the low solubility of potassium silicate.

また、特許文献5のように高分子化合物皮膜を形成し、その皮膜自体に炭酸アルカリ土類金属塩を含有させたものもある。   In addition, as disclosed in Patent Document 5, a polymer compound film is formed, and the film itself contains an alkaline earth metal carbonate.

本発明に関連する抗菌効果を長期間発現させる技術的思想としては特許文献6および7のようにスラグ由来のアルカリによって抗菌効果を持続する着色砂、特許文献8および9のように抗菌塗料やセメントを基材として抗菌成分を添加したものがある。 As a technical idea to develop the antibacterial effect related to the present invention for a long period of time, colored sand that maintains the antibacterial effect by alkali derived from slag as in Patent Documents 6 and 7, and antibacterial paint and cement as in Patent Documents 8 and 9 There are those with antibacterial components added as a base material.

特開2005−170686号公報JP-A-2005-170686 特開2003−226589号公報JP 2003-226589 A 特開2003−155486号公報JP 2003-155486 A 特開2003−048793号公報JP 2003-048793 A 特開2002−321994号公報JP 2002-321994 A 特開2010−137210号公報JP 2010-137210 A 特開2008−201999号公報JP 2008-201999 A 特開2006−327866号公報JP 2006-327866 A 特開2006−315883号公報JP 2006-315883 A

食品残さ等の有機性廃棄物処理、畜産廃棄物処理に関わる土壌消臭、口蹄疫対策の殺処分後の埋め立て処分地の臭気など腐敗、腐乱臭の爆発的な発生を抑えることが課題である。 The challenge is to control the explosive generation of decay and decaying odors, such as soil deodorization related to organic waste treatment such as food residues, soil deodorization related to livestock waste treatment, and odors in landfills after killing of foot-and-mouth disease countermeasures.

本発明は、上記問題を解決することを課題としたものである。   An object of the present invention is to solve the above problems.

上記課題を解決するために、本発明では、多孔質材料の1種または複数材料に抗菌剤、防カビ剤の単体あるいは複数成分を担持させ長期的な抗菌、防カビ効果を持続させ、また、土壌中で有機性廃棄物、家畜糞、殺処分による家畜殺処分体の腐敗、腐乱を制御するためスラグ、石炭灰、石灰石などを使用し、土壌中でアルカリ分を放出することにより、降雨によるアルカリの流出を補う副成分により抗菌剤、防カビ剤の効果を助ける土壌消臭材を構成し、当該土壌消臭材を表土にすき込むことにより、長期的な土壌中の一定部位の無菌環境を確保し、爆発的な有機物の腐敗および腐乱を抑え、よって臭気の発生を根本的に抑える土壌消臭施工を行う。   In order to solve the above-mentioned problems, in the present invention, one or more porous materials are loaded with an antibacterial agent or a single component of an antifungal agent to maintain a long-term antibacterial and antifungal effect, Organic waste in the soil, livestock dung, slag, coal ash, limestone, etc. are used to control the decay and decay of livestock slaughtered bodies. By constructing a soil deodorant that helps the effect of antibacterial and antifungal agents with auxiliary components that compensate for the outflow of alkali, and inserting the soil deodorant into the topsoil, a long-term aseptic environment in the soil in the soil The soil deodorization work will be carried out to prevent explosive organic matter decay and decay, thus fundamentally suppressing the generation of odors.

本発明の土壌消臭材はゼオライト、シリカゲル、パーライト、珪藻土、軽石、活性炭、木炭などの多孔質材料に抗菌剤、防カビ剤を担持、またはコーティングして形成され、広い表面積によって抗菌効果を高めていることをひとつの特徴とするが、土壌消臭の目的としては完全な抗菌、滅菌環境を土壌中に構成することが有利な訳ではない。   The soil deodorizing material of the present invention is formed by loading or coating an antibacterial agent and fungicide on a porous material such as zeolite, silica gel, pearlite, diatomaceous earth, pumice, activated carbon, charcoal, etc. However, it is not advantageous to construct a complete antibacterial and sterilized environment in the soil for the purpose of soil deodorization.

本発明は優れた抗菌、防カビ効果を持った土壌消臭材を土壌の適切な部位に施工することで腐敗菌の爆発的な繁殖を抑えながら、一方で土壌表層近傍には無菌あるいは好気性菌の生息しやすい層を構成することによって一般の好気性土壌菌の働きを活かして消臭を効果を最大にするものである。   The present invention suppresses the explosive growth of spoilage bacteria by applying a soil deodorizing material having excellent antibacterial and antifungal effects to an appropriate part of the soil, while being sterile or aerobic near the soil surface layer. By constructing a layer in which fungi tend to live, the effect of general aerobic soil fungi is utilized to maximize the effect of deodorization.

本発明により土壌中に構成する土壌消臭環境は土壌層すべてを無菌状態にするものではないため、悪臭成分の種類の変化や発生量変動に対して必要な菌が比較的生息しやすい土壌環境を用意する結果となる。 Since the soil deodorizing environment constituted in the soil according to the present invention does not make all soil layers sterile, the soil environment in which bacteria necessary for changes in the types of malodorous components and fluctuations in the amount of generation are relatively inhabited The result is to prepare.

本発明の一実施形態に係る土壌消臭施工断面図である。It is a soil deodorization construction sectional view concerning one embodiment of the present invention.

以下、図面を参照して本発明について説明する。図1は、本発明の一実施形態に係る土壌消臭施工断面図である。同図では、有機性廃棄物あるいは殺処分体を投入した対策土壌表面から2mの部分に土壌消臭材を混入した土壌およびアルカリ材を厚さ1m分覆土し、さらにその上1mを未加工の土壌で覆土した状態を示す。   The present invention will be described below with reference to the drawings. FIG. 1 is a soil deodorization construction sectional view according to an embodiment of the present invention. In this figure, the soil and alkali material mixed with soil deodorant material are covered by 2m from the surface of the countermeasure soil to which organic waste or sacrificial material has been introduced. Shows the state covered with soil.

土壌消臭材としては、ゼオライト、シリカゲル、パーライト、珪藻土、軽石、活性炭、木炭を含む多孔質材料の少なくとも一つに抗菌剤、防カビ剤の単体あるいは複数成分を担持させ、長期間の抗菌、防カビ効果を持たせたものとするのがよい。   As a soil deodorant, at least one of porous materials including zeolite, silica gel, pearlite, diatomaceous earth, pumice, activated carbon, charcoal carries an antibacterial agent, a fungicide alone or a plurality of components, and a long-term antibacterial, It should have a fungicidal effect.

新規に土壌中に殺処分に付した動物死骸などを埋設する際には通常のブルーシートなどで死骸を覆い、消石灰などの散布を行い、通常の土壌でほとんどの埋設口を埋め戻す。さらに埋め戻さずに残した表層2m分の土壌のうち、その半分に本発明の土壌消臭材を土壌体積の(略)5%から(略)75%の容積部を土壌にすき込むように加え、十分に撹拌、均一な状態にして埋設口を埋める。最後に土壌消臭材を含んだ土壌の最表面に加工していない土壌を覆土し施工を完了する。   When burying dead animal corpses that have been killed in the soil, cover the corpse with a normal blue sheet, etc., spray slaked lime, etc., and fill most of the burial mouths with normal soil. Further, among the soil of 2 m of the surface layer left without being backfilled, half of the soil deodorizing material of the present invention is soaked into the soil from (approximately) 5% to (approximately) 75% of the soil volume. In addition, the embedding port is filled with sufficient agitation and uniform condition. Finally, the soil that has not been processed on the outermost surface of the soil containing the soil deodorizing material is covered and the construction is completed.

好適には、こうした土壌消臭施工方法による施工完了した土壌のさらに表層に一般土を盛り、好気性微生物の活動層を作る。 Preferably, general soil is further added to the surface layer of the soil that has been constructed by the soil deodorizing construction method to create an active layer of aerobic microorganisms.

すでに有機性廃棄物等の埋設が完了、覆土し、腐敗臭などの悪臭を発している土壌では表層土壌の掘削だけでもさらに悪臭を放散することになるので、この場合には土壌表面に本発明の土壌消臭材をmあたり10kg散布し2週間ほど放置し、表層土壌を抗菌状態に変えたのちに、あらためて表層から50cm程度を掘削し、土壌消臭剤をmあたり20kgから80kgの範囲で散布し、最後に表層土で覆い施工を完了する。 In soils that have already been buried, covered with organic waste, etc., and have generated odors such as spoiled odors, only the excavation of the surface soil will dissipate further odors. After spraying 10 kg of soil deodorant material per m 2 and leaving it for about two weeks, changing the surface soil to an antibacterial state, excavating about 50 cm from the surface layer again, soil deodorant of 20 kg to 80 kg per m 2 Sprinkle over the area and finally cover with surface soil.

上記の施工に際して土壌消臭材の散布に加えてさらにスラグ、石炭灰、消石灰、サンゴ化石、石灰石などのアルカリ材を適宜加えてもよい。 In addition to the application of the soil deodorizer, an alkali material such as slag, coal ash, slaked lime, coral fossil, or limestone may be appropriately added during the above construction.

また、上記において、土壌消臭材を造粒及び/もしくは固化してもよい。 In the above, the soil deodorizing material may be granulated and / or solidified.

上記説明したように、多孔質材料の1種または複数材料に抗菌剤、防カビ剤の単体あるいは複数成分を担持させ長期的な抗菌、防カビ効果を持続させ、また、土壌中で有機性廃棄物、家畜糞、殺処分による家畜殺処分体の腐敗、腐乱を制御するためスラグ、石炭灰、石灰石などを使用し、土壌中でアルカリ分を放出することにより、降雨によるアルカリの流出を補う副成分により抗菌剤、防カビ剤の効果を助ける土壌消臭材を構成し、当該土壌消臭材を表土にすき込むことにより、長期的な土壌中の無菌環境を確保し、爆発的な有機物の腐敗および腐乱を抑え、よって臭気の発生を根本的に抑える土壌消臭施工を行う。 As explained above, antibacterial and antifungal agents alone or multiple components are supported on one or more porous materials to maintain long-term antibacterial and antifungal effects, and organic waste in the soil Slag, coal ash, limestone, etc. are used to control the decay and decay of livestock excrement, livestock excrement, and slaughter. By constructing a soil deodorant that helps the effect of antibacterial and antifungal agents depending on the ingredients, and soaking the soil deodorant into the topsoil, ensuring a long-term aseptic environment in the soil, explosive organic matter Soil deodorization work is carried out to suppress rot and decay, thus fundamentally suppressing the generation of odor.

BET値50から70m/gを示す多孔質ケイ酸カルシウム系水和物であるトバモライト1tを温風乾燥し、株式会社ウイズユー社製抗菌・防カビ剤プロモール20Lを同社エアミスティノズルより噴霧、撹拌を繰り返し、全面に薬剤を担持、乾燥させ土壌消臭材を作る。 Tobermorite 1t, which is a porous calcium silicate hydrate showing a BET value of 50 to 70 m 2 / g, is dried with warm air and sprayed with Prom 20L, an antibacterial and antifungal agent made by With You Co., Ltd., from its air misty nozzle. Repeat the agitation to load the chemical on the entire surface and dry it to make a soil deodorant.

調製した土壌消臭材10gを精秤し精製水500mLを加えて6時間撹拌、溶出試験を行った。プロモール成分のひとつであるTBZを溶出液中濃度を測定した結果、3ppm以下であった。比較試験としてシリカゲルに同様の担持操作を行い、溶出試験を行ったが200ppm以上の溶出試験結果となり、プロモールとの組み合わせでは溶出が大きく長期間の消臭性能は得られないと判断した。 10 g of the prepared soil deodorant was precisely weighed, 500 mL of purified water was added, and the mixture was stirred for 6 hours and subjected to an elution test. The concentration of TBZ, one of the promol components, in the eluate was measured and found to be 3 ppm or less. As a comparative test, the same loading operation was performed on silica gel, and an elution test was performed. However, an elution test result of 200 ppm or more was obtained, and it was judged that long-term deodorization performance was not obtained in combination with promol.

乾燥シリカゲル1tに対して株式会社モルテック社製防カビコート剤モルシール10kgを担持させた結果、溶出試験においても成分の溶出は確認できなかった。   As a result of supporting 10 kg of mold anti-mold coating agent Molseal manufactured by Moltec Co., Ltd. on 1 t of dry silica gel, elution of components could not be confirmed even in the elution test.

水処理プラントに併設した土壌消臭プラントなど好気性菌類の働きに多くを期待した消臭システムでは通常と異なる性状の廃水混入や想定以上の大きな負荷によって、微生物群あるいは栄養のバランスが崩れ、十分な消臭効果が得られないことが多い。また、一度ダメージを受けた土壌消臭システムでは回復に長い時間を必要とした。そのような土壌消臭システムの能力拡大に本発明の土壌消臭材および土壌消臭施工方法は絶大な効果を発揮する。したがって、本発明は経済的価値を有するとともに産業上利用することができる発明である。   Deodorant systems such as a soil deodorization plant attached to a water treatment plant are expected to have a great deal of aerobic fungal activity. In many cases, a deodorizing effect cannot be obtained. In addition, the soil deodorization system once damaged required a long time for recovery. The soil deodorizing material and the soil deodorizing construction method of the present invention exert a tremendous effect in expanding the capacity of such a soil deodorizing system. Therefore, the present invention has economic value and can be used industrially.

1 対策土壌表面
2 土壌消臭材混合土層
3 有機性廃棄物、殺処分体
1 Countermeasure soil surface 2 Soil deodorant mixed soil layer 3 Organic waste, killed body

Claims (5)

ゼオライト、シリカゲル、パーライト、珪藻土、軽石、活性炭、木炭を含む多孔質材料の少なくとも一つに抗菌剤、防カビ剤の単体あるいは複数成分を担持させ、長期間の抗菌、防カビ効果を持たせたことを特徴とする土壌消臭材。 At least one of porous materials including zeolite, silica gel, pearlite, diatomaceous earth, pumice, activated carbon, charcoal is loaded with antibacterial and antifungal agents alone or with multiple components to provide long-term antibacterial and antifungal effects. Soil deodorant characterized by that. 請求項1記載の土壌消臭材において、さらに土壌をアルカリ性にする材料としてスラグ、石炭灰、サンゴ化石、石灰石のうちの少なくとも一種以上を混合してなることを特徴とする土壌消臭材。 The soil deodorizing material according to claim 1, further comprising at least one of slag, coal ash, coral fossil, and limestone as a material for making the soil alkaline. 請求項1あるいは2記載の土壌消臭材であって、造粒及び/もしくは固化してなることを特徴とする土壌消臭材。 The soil deodorizing material according to claim 1 or 2, wherein the soil deodorizing material is granulated and / or solidified. 請求項1乃至3のうちのいずれか1項記載の土壌消臭材を施工するにあたり、土壌消臭機能を付与する土壌の略5%から略75%の容積部を土壌にすき込むことを特徴とした土壌消臭施工方法。 In constructing the soil deodorizing material according to any one of claims 1 to 3, a volume part of about 5% to about 75% of the soil imparting a soil deodorizing function is scrubbed into the soil. Soil deodorization construction method. 請求項4記載の土壌消臭施工方法による施工完了した土壌のさらに表層に一般土を盛り、好気性微生物の活動層を作ることを特徴とした土壌消臭施工方法。 A soil deodorization construction method characterized in that general soil is further deposited on the surface layer of soil that has been completed by the soil deodorization construction method according to claim 4 to create an active layer of aerobic microorganisms.
JP2011103918A 2011-05-08 2011-05-08 Soil deodorizing material, and soil deodorizing execution method Withdrawn JP2012233122A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016163427A1 (en) * 2015-04-07 2016-10-13 アサヒグループホールディングス株式会社 Plant growth improving agent capable of improving growth inhibition due to excessive humidity, and method for improving growth inhibition due to excessive humidity

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016163427A1 (en) * 2015-04-07 2016-10-13 アサヒグループホールディングス株式会社 Plant growth improving agent capable of improving growth inhibition due to excessive humidity, and method for improving growth inhibition due to excessive humidity

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