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JP2012036940A - Roller and cage assembly, roller bearing and cage assembly, and cage - Google Patents

Roller and cage assembly, roller bearing and cage assembly, and cage Download PDF

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Publication number
JP2012036940A
JP2012036940A JP2010176012A JP2010176012A JP2012036940A JP 2012036940 A JP2012036940 A JP 2012036940A JP 2010176012 A JP2010176012 A JP 2010176012A JP 2010176012 A JP2010176012 A JP 2010176012A JP 2012036940 A JP2012036940 A JP 2012036940A
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Prior art keywords
plating layer
cage
ptfe
plating
roller
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JP2010176012A
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Inventor
Katsushi Abe
克史 阿部
Yoshinobu Kubota
好信 久保田
Hiromitsu Kawai
弘光 河合
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NTN Corp
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NTN Corp
NTN Toyo Bearing Co Ltd
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Priority to JP2010176012A priority Critical patent/JP2012036940A/en
Priority to PCT/JP2011/066937 priority patent/WO2012017860A1/en
Publication of JP2012036940A publication Critical patent/JP2012036940A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/04Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/38Lubricating compositions characterised by the base-material being a macromolecular compound containing halogen
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • C25D15/02Combined electrolytic and electrophoretic processes with charged materials
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10Electroplating with more than one layer of the same or of different metals
    • C25D5/12Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
    • C25D5/14Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60Electroplating characterised by the structure or texture of the layers
    • C25D5/605Surface topography of the layers, e.g. rough, dendritic or nodular layers
    • C25D5/611Smooth layers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/46Cages for rollers or needles
    • F16C33/54Cages for rollers or needles made from wire, strips, or sheet metal
    • F16C33/542Cages for rollers or needles made from wire, strips, or sheet metal made from sheet metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/46Cages for rollers or needles
    • F16C33/56Selection of substances
    • F16C33/565Coatings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/66Special parts or details in view of lubrication
    • F16C33/6696Special parts or details in view of lubrication with solids as lubricant, e.g. dry coatings, powder
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/05Metals; Alloys
    • C10M2201/053Metals; Alloys used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06Perfluoro polymers
    • C10M2213/062Polytetrafluoroethylene [PTFE]
    • C10M2213/0623Polytetrafluoroethylene [PTFE] used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/02Bearings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/14Composite materials or sliding materials in which lubricants are integrally molded
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2080/00Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C9/00Bearings for crankshafts or connecting-rods; Attachment of connecting-rods
    • F16C9/04Connecting-rod bearings; Attachments thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • Rolling Contact Bearings (AREA)
  • Lubricants (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a roller and cage assembly, and a bearing employing the roller and cage assembly exhibiting such properties that a film formed by surface treatment causes no increase in stress and is not peeled off from the cage even if the film is thick, surface treatment is not affected by an additive included in oil for use, the wear of the cage can be prevented when the cage is used in an engine with large displacement or the like, and adhesiveness between the surface treatment layer and a substrate is improved.SOLUTION: The cage 2 is plated to form a primary plated layer 4 on the surface, and further plated to form a plated multilayer 5 comprising a plurality of plated layers on the surface of the primary plated layer 4. The plated multilayer 5 has a Ni PTFE plated layer formed on the surface of the primary plated layer 4, another plated layer which is formed on the surface of the Ni PTFE plated layer and has the same plating as that of the primary plated layer 4, and a Ni PTFE plated layer formed on the surface of the another plated layer.

Description

この発明は、例えば四輪車や二輪車及び汎用エンジン等のクランク軸用支持構造及びコンロッド支持構造等に使用される保持器付きころ、保持器付きころ軸受および保持器に関し、保持器に発生する摩耗及び潤滑不良を解決する技術に関する。   The present invention relates to a roller with a cage, a roller bearing with a cage, and a cage used in, for example, a support structure for a crankshaft and a connecting rod support structure for a four-wheeled vehicle, a two-wheeled vehicle, and a general-purpose engine. And a technique for solving poor lubrication.

保持器付きころは、ころと保持器で構成され、ころの外周面と、内輪及び外輪の軌道面とが線接触する構造である。このため、軸受投影面積が小さい割に、高負荷容量と高剛性を得られる利点を有している。したがって、保持器付きころは、自動車用を初めあらゆる分野に広く利用されている。
一般に二輪車の大小端用には、滑り軸受または転がり軸受の保持器付きころが使用されている。2サイクルエンジンの場合、大小端部は、ガソリンとエンジンオイルとを混合させた噴霧状の混合液によって潤滑される。したがって、滑り軸受では、摩耗や潤滑不良が発生するため、保持器付きころ、シェルラジアル軸受等の転がり軸受が使用されている。ただし、使用される転がり軸受で保持器付きころは、保持器外径や幅面の摩耗や潤滑不良防止のために、銅メッキや銀メッキが使用されていた。
銅メッキや銀メッキで耐えられない高速回転では、母材はニッケルを主要素材としフッ素樹脂の微粒子を均一に分散共析させた複合メッキが提案されている(特許文献1)。この考案は、高速使用条件による摩耗や潤滑不良の防止を視点とした対策内容である。
A roller with a cage is composed of a roller and a cage, and has a structure in which the outer peripheral surface of the roller is in line contact with the raceway surfaces of the inner ring and the outer ring. For this reason, it has the advantage that high load capacity and high rigidity can be obtained for a small bearing projected area. Accordingly, the roller with cage is widely used in various fields including automobiles.
Generally, a roller with a cage of a sliding bearing or a rolling bearing is used for a large and small end of a two-wheeled vehicle. In the case of a two-cycle engine, the large and small ends are lubricated by a spray-like mixed liquid in which gasoline and engine oil are mixed. Accordingly, rolling bearings such as rollers with cages and shell radial bearings are used for sliding bearings because wear and lubrication failure occur. However, in the rolling bearings used, the rollers with cages used copper plating or silver plating in order to prevent the outer diameter and width of the cage from being worn and poor lubrication.
For high-speed rotation that cannot be tolerated by copper plating or silver plating, composite plating in which the base material is nickel as a main material and fine particles of fluororesin are uniformly dispersed and co-deposited has been proposed (Patent Document 1). This device is a countermeasure content from the viewpoint of preventing wear and poor lubrication under high-speed use conditions.

そこで、本件出願人は、前記特許文献1に対して、新たに出願(特願2009−120894)した。この出願に係る発明は、保持器の表面に下地メッキ層を施し、この下地メッキ層の表面に、Ni・PTFEメッキ層を施し、これら下地メッキ層およびNi・PTFEメッキ層の総膜厚を規定した技術である。なお、軽量コンパクトでかつ強度が大きく柔軟性、耐熱性、耐油性に優れた保持器として、保持器の表面に、隣接する層が互いに異なる金属または合金からなるように積層した多層膜を設けた技術等が提案されている(特許文献2)。   Therefore, the applicant of the present application newly applied for Japanese Patent Application No. 2009-120894. In the invention according to this application, a base plating layer is applied to the surface of the cage, a Ni / PTFE plating layer is applied to the surface of the base plating layer, and the total film thickness of the base plating layer and the Ni / PTFE plating layer is specified. Technology. In addition, as a cage that is lightweight, compact, large in strength, and excellent in flexibility, heat resistance, and oil resistance, a multilayer film is provided on the surface of the cage so that adjacent layers are made of different metals or alloys. Techniques have been proposed (Patent Document 2).

実用新案登録第2582402号公報Utility Model Registration No. 2582402 特開2007−120734号公報JP 2007-120734 A

特許文献1では、高速性に対する摩耗・潤滑不良を防止することを目的として、ニッケルを主要素材としフッ素樹脂を含む複合メッキを保持器に形成している。しかし、近年の銅及び銀メッキの摩耗は、使用条件の厳しさではなく、潤滑油の影響によりメッキが化学反応を起こすことで溶解(消失)し、保持器が潤滑不良を起こすことがある。特に、4サイクルエンジンに使用される軸受に発生することが多い。   In Patent Document 1, a composite plating containing nickel as a main material and containing a fluororesin is formed on a cage for the purpose of preventing wear and lubrication failure with respect to high speed. However, the wear of copper and silver plating in recent years is not severe in use conditions, but the plating dissolves (disappears) due to a chemical reaction due to the influence of lubricating oil, and the cage may cause poor lubrication. In particular, it often occurs in bearings used in 4-cycle engines.

4サイクルエンジンの場合、ガソリンとエンジンオイルとは混合されず、エンジンオイルを直接大小端部へ給油することができる。このため、安価で転がり軸受よりも負荷能力が高い滑り軸受が使用されており、転がり軸受は殆んど使用されていない。
しかしながら、近年ではエンジンの燃費向上のため、4サイクルエンジンの支持部(例えば、コンロッド大端部)の滑り軸受が転がり軸受(保持器付きころ)へ置き換わっている。この4サイクルエンジンへの転がり軸受の適用が、課題の発端である。
In the case of a four-cycle engine, gasoline and engine oil are not mixed, and the engine oil can be directly supplied to the large and small ends. For this reason, a low-priced plain bearing having a higher load capacity than a rolling bearing is used, and the rolling bearing is hardly used.
However, in recent years, a sliding bearing (a roller with a cage) has been replaced with a sliding bearing of a support portion (for example, a connecting rod large end) of a four-cycle engine in order to improve engine fuel efficiency. The application of rolling bearings to this four-cycle engine is the beginning of the problem.

ところで、2サイクルエンジンと4サイクルエンジンとでは、使用するオイルが異なっている。4サイクルエンジンでは、オイルパンのオイルが圧送されてエンジン各部を潤滑する。その後、オイルはオイルパンに再び戻る。これに対して2サイクルエンジンでは、オイルは燃料に混合され回転部等に付着することにより、またはオイルタンクからの圧送によりエンジン各部を潤滑した後、混合気と共に燃焼室に入り燃焼する。このような潤滑機構の差異および動弁機構の有無のような構造の差異により、2サイクルエンジンオイルと4サイクルエンジンオイルに要求される性能は大きく異なる。   By the way, the oil to be used is different between the 2-cycle engine and the 4-cycle engine. In a 4-cycle engine, oil in the oil pan is pumped to lubricate each part of the engine. After that, the oil returns to the oil pan again. On the other hand, in a two-cycle engine, oil is mixed with fuel and adhered to a rotating part or the like, or each part of the engine is lubricated by pumping from an oil tank, and then enters the combustion chamber and burns with the mixture. The performance required for the two-cycle engine oil and the four-cycle engine oil is greatly different due to the difference in the structure such as the difference in the lubrication mechanism and the valve mechanism.

これら2サイクルエンジンオイルと4サイクルエンジンオイルの組成上の大きな差異は、硫酸灰分と、ジアルキルジチオりん酸亜鉛(Zinc Dialkyldithiophosphate;略称ZnDTP)の有無にある。2サイクルエンジンオイルで硫酸灰分が低いのは、灰分の主要要因である過塩基性清浄剤の酸中和性能が要求されないことと、灰分が燃焼室堆積物を増加させ、プラグ失火を生じることがあるためである。2サイクルエンジンオイルにZnDTPが処方されないのは、2サイクルエンジンではオイルの酸化防止性が要求されないことと、動弁機構がないため、厳しい摩耗防止性能が要求されないためである。前記ZnDTPは通常150〜200℃で熱分解されると言われているが、高負荷運転時のピストン、リングまわりの温度は200℃を超えるという報告もあり、ZnDTPの添加剤がかえってピストンの汚れ、リング膠着を生じる。このピストン汚れおよびリング膠着を防止するため、多くの清浄剤を必要とすることもZnDTPを添加しない理由である。前記ZnDTPは、酸化防止能、腐食防止能、耐荷重性能、摩耗防止能等を有し、いわゆる多機能型添加剤として、エンジンオイルや工業用潤滑油に広く使用されている。   The major difference in the composition of these two-cycle engine oil and four-cycle engine oil is the presence or absence of sulfated ash and zinc dialkyldithiodiphosphate (ZnDTP). The low sulfated ash content in the two-cycle engine oil is that the acid neutralization performance of the overbased detergent, which is the main factor of the ash content, is not required, and the ash content increases the combustion chamber deposits and can cause plug misfire. Because there is. The reason why ZnDTP is not prescribed for the two-cycle engine oil is that the two-cycle engine does not require anti-oxidation property of the oil, and because there is no valve mechanism, severe wear prevention performance is not required. It is said that ZnDTP is usually pyrolyzed at 150 to 200 ° C, but there is a report that the temperature around the piston and ring during high load operation exceeds 200 ° C. , Causing ring sticking. In order to prevent this piston contamination and ring sticking, a large amount of detergent is required, which is why ZnDTP is not added. The ZnDTP has antioxidation ability, corrosion prevention ability, load bearing performance, wear prevention ability and the like, and is widely used in engine oil and industrial lubricating oil as a so-called multifunctional additive.

ZnDTPの摩耗防止機構としては、
(1)ZnDTP中の硫黄やりんが金属と反応して硫化鉄やりん酸塩の皮膜を作り摩耗を防ぐ。
(2)ZnDTPが分解して金属表面にポリフォスフェートの膜を生成し摩耗を防ぐ。
という説が有力である。
以上のように、4サイクルエンジンオイルには、添加剤であるZnDTPが入っており、このZnDTP中の成分に硫黄が入っている。摩耗防止機構として、この硫黄が金属と反応し皮膜を作り摩耗防止効果があるとのことだが、保持器に施す銅メッキや銀メッキでは逆効果であることが、種々の評価から判明した。
As a wear prevention mechanism of ZnDTP,
(1) Sulfur and phosphorus in ZnDTP react with metals to form iron sulfide and phosphate films to prevent wear.
(2) ZnDTP decomposes to form a polyphosphate film on the metal surface to prevent wear.
The theory is powerful.
As described above, the 4-cycle engine oil contains ZnDTP, which is an additive, and sulfur is contained in the components in this ZnDTP. As a wear prevention mechanism, this sulfur reacts with metals to form a film and has a wear prevention effect, but it has been found from various evaluations that copper plating and silver plating applied to the cage are counterproductive.

すなわち銅メッキや銀メッキを施した保持器を、高温の4サイクルエンジンオイルに浸漬させると、時間と共に油中に銅、銀の化学成分が増加していることが判明し、油中への溶け出しが認められた。また、銀メッキは黒色に変化し、メッキが脆くなり容易に剥れが認められた。さらに、前記保持器のうち他の部品と接することのない部分のメッキ剥れが認められることがある。これらメッキ剥がれ防止には莫大な費用がかかっていた。したがって、エンジンオイルに含まれる添加剤に影響されない表面処理が必要である。また、基材(保持器)との密着性を向上させることでメッキ剥れを防ぐ必要がある。   In other words, when a cage plated with copper or silver is immersed in high-temperature four-cycle engine oil, it turns out that the chemical components of copper and silver increase in the oil over time, and it dissolves in the oil. It was approved. Further, the silver plating changed to black, and the plating became brittle and was easily peeled off. Furthermore, plating peeling of a part of the cage that does not come into contact with other parts may be recognized. It was very expensive to prevent these platings from peeling off. Therefore, a surface treatment that is not affected by the additive contained in the engine oil is necessary. Moreover, it is necessary to prevent peeling of plating by improving the adhesion with the base material (retainer).

前述の本件出願人の出願に係る表面処理でも、大排気量のエンジンでは、表面処理した皮膜が摩耗してしまうことが判明した。そのため、表面処理の膜厚を厚くすることを試みたが、同一種類の表面処理では、膜厚を厚くすると内部の皮膜応力が増加し、皮膜が剥れ易くなることが判明した。この表面処理した皮膜を剥れにくくするには、莫大な費用がかかっていた。
特許文献2の技術では、保持器表面と多層膜との間に下地メッキ層が無く、また多層膜の総膜厚もnmオーダーと非常に薄いため、厳しい使用環境下で長期稼動すると、多層膜が摩耗して保持器表面が摩耗することが懸念される。
Even in the surface treatment according to the above-mentioned application of the present applicant, it has been found that the surface-treated film is worn by an engine having a large displacement. Therefore, an attempt was made to increase the film thickness of the surface treatment. However, it was found that with the same type of surface treatment, when the film thickness is increased, the internal film stress increases and the film easily peels off. Enormous costs have been incurred to make it difficult to remove the surface-treated film.
In the technology of Patent Document 2, there is no base plating layer between the cage surface and the multilayer film, and the total film thickness of the multilayer film is very thin, on the order of nm. There is a concern that the surface of the cage may wear due to wear.

この発明の目的は、皮膜厚さが厚くても表面処理の皮膜応力が増加せず、皮膜が保持器から剥がれないようにすること、使用オイルに含まれる添加剤に影響されない表面処理とすること、さらに、大排気量のエンジン等で保持器を使用する場合に、前記保持器の摩耗、潤滑不良を防止することができると共に、この表面処理層と基材との密着性を向上させた保持器付きころおよび保持器付きころを用いた軸受を提供することである。   The purpose of the present invention is to prevent the surface treatment from increasing the film stress even if the film thickness is large, and to prevent the film from being peeled off from the cage, and to make the surface treatment unaffected by the additive contained in the oil used. Furthermore, when the cage is used in a large displacement engine or the like, the cage can be prevented from wearing and lubrication failure, and the adhesion between the surface treatment layer and the substrate is improved. It is providing a bearing using a roller with a cage and a roller with a cage.

この発明の保持器付きころは、複数のころと、円周方向の複数箇所に、前記各ころをそれぞれ保持するポケットを有するリング状の保持器とを備えた保持器付きころにおいて、前記保持器の表面に下地メッキ層を施し、この下地メッキ層の表面に、ニッケルとPTFEとを含むNi・PTFEメッキ層と、このNi・PTFEメッキ層の表面に施され前記下地メッキ層と同一のメッキからなるメッキ層と、このメッキ層の表面に施された、ニッケルとPTFEとを含むNi・PTFEメッキ層とを有する複数層のメッキ層からなる積層状メッキ層を施したものである。   The roller with cage according to the present invention is the roller with cage having a plurality of rollers and a ring-shaped cage having pockets respectively holding the rollers at a plurality of locations in the circumferential direction. An undercoat plating layer is applied to the surface of the Ni, PTFE plating layer containing nickel and PTFE on the surface of the undercoat plating layer, and the same plating as the undercoat plating layer is applied to the surface of the Ni · PTFE plating layer. And a multilayer plating layer comprising a plurality of plating layers having a nickel / PTFE plating layer containing nickel and PTFE applied to the surface of the plating layer.

上記構成によると、下地メッキ層の表面に、複数層のメッキ層からなる積層状メッキ層を施したため、厳しい使用環境下で皮膜厚さつまりメッキ層の総膜厚を厚くしてもメッキ層が剥がれない。換言すれば、下地メッキ層の表面に、複数層のメッキ層からなる積層状メッキ層を施したため、メッキ層の総膜厚が厚くても表面処理の皮膜応力が増加せず、メッキ層の剥れを防止し得る。さらに積層状メッキ層の皮膜厚さを厚くすることができるので、長期に稼動しても表面処理が残存し、保持器の摩耗や潤滑不良を防止することができる。
なお、この発明のサンプル、および従来技術に係る2層構造からなるメッキ層を施したサンプルを複数種類製作し、これらサンプルのメッキの密着力つまり耐摩耗性について、いわゆるリングオンディスク型の試験機を用いて評価した。本発明のサンプルにおけるメッキ層の総膜厚は、従来技術に係るサンプルにおけるメッキ層の総膜厚よりも厚くしている。
試験結果によると、この発明のサンプルでは、積層状メッキ層の表層等が摩耗するものの、地金の発生は無かった。またメッキ層の剥れも認められなかった。これに対し、従来技術に係るサンプルでは、メッキ層が徐々に摩耗し地金が発生したものや、メッキ層の摩耗と共にメッキ層が一部剥れたもの等が認められた。
According to the above configuration, since the laminated plating layer composed of a plurality of plating layers is applied to the surface of the base plating layer, the plating layer can be formed even if the film thickness, that is, the total thickness of the plating layer is increased under severe use environment. It will not peel off. In other words, since a multilayer plating layer composed of a plurality of plating layers is applied to the surface of the underlying plating layer, even if the total thickness of the plating layer is large, the film stress of the surface treatment does not increase, and the plating layer is peeled off. This can be prevented. Furthermore, since the film thickness of the laminated plating layer can be increased, the surface treatment remains even after long-term operation, and the wear and lubrication failure of the cage can be prevented.
A plurality of types of samples according to the present invention and samples with a two-layered plating layer according to the prior art are manufactured, and the so-called ring-on-disk type tester is used for the adhesion of plating of these samples, that is, the wear resistance. Was used to evaluate. The total film thickness of the plating layer in the sample of the present invention is larger than the total film thickness of the plating layer in the sample according to the prior art.
According to the test results, in the sample of the present invention, although the surface layer of the laminated plating layer was worn, no metal was generated. Moreover, peeling of the plating layer was not recognized. On the other hand, in the samples according to the prior art, those in which the plating layer was gradually worn and metal was generated, and those in which the plating layer was partially peeled off with the wear of the plating layer were observed.

前記積層状メッキ層は、前記下地メッキ層の表面に施された、ニッケルとPTFEとを含むNi・PTFEメッキ層と、このNi・PTFEメッキ層の表面に施され前記下地メッキ層と同一のメッキからなるメッキ層と、このメッキ層の表面に施された、ニッケルとPTFEとを含むNi・PTFEメッキ層とを有する。
前記「PTFE」とは、ポリテトラフルオロエチレン(Polytetrafluoroethylene)の略称であり、テトラフルオロエチレンの重合体で、フッ素原子と炭素原子のみから成るフッ化炭素樹脂である。このフッ化炭素樹脂形状は多角形状となっている。
The laminated plating layer includes a nickel / PTFE plating layer containing nickel and PTFE applied to the surface of the base plating layer, and the same plating as the base plating layer applied to the surface of the Ni / PTFE plating layer. And a Ni / PTFE plating layer containing nickel and PTFE applied to the surface of the plating layer.
The “PTFE” is an abbreviation for polytetrafluoroethylene, which is a polymer of tetrafluoroethylene, which is a fluorocarbon resin composed of only fluorine atoms and carbon atoms. This fluorocarbon resin shape is a polygonal shape.

この構成によると、Ni・PTFEメッキ層におけるニッケルは、銅、銀に比べ添加剤と反応し難い性質を持つため、溶出を抑制することが可能となる。Ni・PTFEメッキ層の金属成分であるニッケル等が、4サイクルエンジンオイルの高温条件下で溶解しないことを浸漬試験で確認したところ、浸漬時間として200時間を経過しても、Ni・PTFEメッキ層および下地メッキ層に関係した元素は検出されなかった。さらにNi・PTFEメッキ層中のPTFEの自己潤滑作用により、メッキの摩擦係数が低減し、耐摩耗性が向上する。   According to this configuration, nickel in the Ni · PTFE plating layer has a property that it is difficult to react with the additive as compared with copper and silver, so that elution can be suppressed. It was confirmed by immersion test that nickel, which is a metal component of the Ni / PTFE plating layer, does not dissolve under the high temperature condition of the 4-cycle engine oil. Even if 200 hours passed as the immersion time, the Ni / PTFE plating layer And no element related to the underlying plating layer was detected. Furthermore, the self-lubricating action of PTFE in the Ni / PTFE plating layer reduces the friction coefficient of plating and improves the wear resistance.

前記各Ni・PTFEメッキ層におけるPTFEは、ニッケルメッキ中にPTFE粒子が分散しているものであっても良い。
前記積層状メッキ層における、下地メッキ層と同一のメッキからなる前記メッキ層、および前記下地メッキ層は、ニッケルメッキ層であっても良い。このニッケルメッキ層と各Ni・PTFEメッキ層とが共通の組成物すなわちニッケルを含むため、両層付近の組成が徐々に変化し、これらニッケルメッキ層とNi・PTFEメッキ層との界面を隙間無く密着させることができる。したがって、基材、ニッケルメッキ層、Ni・PTFEメッキ層、およびニッケルメッキ層にわたって密着性が優れたものとなる。
The PTFE in each of the Ni / PTFE plating layers may be one in which PTFE particles are dispersed during nickel plating.
In the laminated plating layer, the plating layer made of the same plating as the base plating layer and the base plating layer may be a nickel plating layer. Since this nickel plating layer and each Ni / PTFE plating layer contain a common composition, that is, nickel, the composition in the vicinity of both layers gradually changes, and there is no gap between the nickel plating layer and the Ni / PTFE plating layer. It can be adhered. Therefore, the adhesiveness is excellent over the base material, the nickel plating layer, the Ni / PTFE plating layer, and the nickel plating layer.

前記メッキ層の膜厚を3μm以上10μm以下とし、前記Ni・PTFEメッキ層の膜厚を5μm以上15μm以下としても良い。
下地メッキ層は、Ni・PTFEメッキ層と基材とのアンカー効果を成し、前記メッキ層は、Ni・PTFEメッキ層同士のアンカー効果を成すメッキ層であるため、前記のような3μm以上10μm以下の薄い膜厚で足りる。
The plating layer may have a thickness of 3 μm to 10 μm, and the Ni / PTFE plating layer may have a thickness of 5 μm to 15 μm.
The base plating layer forms an anchor effect between the Ni / PTFE plating layer and the base material, and the plating layer is a plating layer that forms an anchor effect between the Ni / PTFE plating layers. The following thin film thickness is sufficient.

前記Ni・PTFEメッキ層におけるPTFE量を、各Ni・PTFEメッキ層毎に異なるPTFE量としても良い。このようにPTFE量を変化させることで、より密着性に優れた積層状メッキ層にすることができる。
前記下地メッキ層は、PTFEを含まないメッキ層とし、前記積層状メッキ層のうち最外層は、PTFEを含むメッキ層としても良い。このように最外層をPTFEを含むメッキ層とすると、PTFEの自己潤滑性能に効果的に摺動抵抗の低減を図れる。
The PTFE amount in the Ni / PTFE plating layer may be a different PTFE amount for each Ni / PTFE plating layer. Thus, by changing the amount of PTFE, a laminated plating layer having better adhesion can be obtained.
The base plating layer may be a plating layer that does not include PTFE, and the outermost layer of the laminated plating layer may be a plating layer that includes PTFE. Thus, when the outermost layer is a plated layer containing PTFE, the sliding resistance can be effectively reduced for the self-lubricating performance of PTFE.

前記積層状メッキ層における各メッキ層を、各メッキ層毎に異なる膜厚としても良い。
前記積層状メッキ層は、3層以上のメッキ層からなるものとしても良い。
これらの場合、この場合、メッキ層の総膜厚を厚くでき、摩耗に対する延命効果がある。
Each plating layer in the laminated plating layer may have a different film thickness for each plating layer.
The laminated plating layer may be composed of three or more plating layers.
In these cases, in this case, the total thickness of the plating layer can be increased, and there is a life extension effect against wear.

この発明の保持器付きころ軸受は、この発明の前記いずれかの保持器付きころと、前記複数のころが転接する軌道輪とを備えたものである。
この発明の保持器は、複数のころと、円周方向の複数箇所に、前記各ころをそれぞれ保持するポケットを有するリング状の保持器とを備えた保持器付きころにおける保持器であって、この保持器の表面に下地メッキ層を施し、この下地メッキ層の表面に、複数層のメッキ層からなる積層状メッキ層を施したものである。
A roller bearing with a cage according to the present invention includes any one of the rollers with a cage according to the present invention and a bearing ring on which the plurality of rollers roll.
The cage of the present invention is a cage in a roller with a cage comprising a plurality of rollers and ring-shaped cages each having a pocket for holding each of the rollers at a plurality of locations in the circumferential direction, A base plating layer is applied to the surface of the cage, and a multilayer plating layer composed of a plurality of plating layers is applied to the surface of the base plating layer.

この発明の前記いずれかの保持器付きころを用いたエンジンのコンロッド大端用軸受を適用しても良い。   You may apply the connecting rod large end bearing of the engine using the said roller with a retainer of this invention.

この発明の保持器付きころは、複数のころと、円周方向の複数箇所に、前記各ころをそれぞれ保持するポケットを有するリング状の保持器とを備えた保持器付きころにおいて、前記保持器の表面に下地メッキ層を施し、この下地メッキ層の表面に、ニッケルとPTFEとを含むNi・PTFEメッキ層と、このNi・PTFEメッキ層の表面に施され前記下地メッキ層と同一のメッキからなるメッキ層と、このメッキ層の表面に施された、ニッケルとPTFEとを含むNi・PTFEメッキ層とを有する複数層のメッキ層からなる積層状メッキ層を施した。このため、皮膜厚さが厚くても表面処理の皮膜応力が増加せず、皮膜つまり下地メッキ層および積層状メッキ層が保持器から剥がれない。また、使用オイルに含まれる添加剤に影響されない表面処理とできる。さらに、大排気量のエンジン等で保持器を使用する場合に、前記保持器の摩耗、潤滑不良を防止することができると共に、この皮膜と基材との密着性を向上させることができる。   The roller with cage according to the present invention is the roller with cage having a plurality of rollers and a ring-shaped cage having pockets respectively holding the rollers at a plurality of locations in the circumferential direction. An undercoat plating layer is applied to the surface of the Ni, PTFE plating layer containing nickel and PTFE, and the same plating as the undercoat plating layer is applied to the surface of the Ni · PTFE plating layer. And a multilayer plating layer comprising a plurality of plating layers having a nickel / PTFE plating layer containing nickel and PTFE applied to the surface of the plating layer. For this reason, even if the film thickness is thick, the film stress of the surface treatment does not increase, and the film, that is, the base plating layer and the laminated plating layer do not peel from the cage. Further, the surface treatment can be performed without being affected by the additive contained in the oil used. Further, when the cage is used in a large displacement engine or the like, wear and lubrication failure of the cage can be prevented, and adhesion between the film and the substrate can be improved.

(A)はこの発明の第1の実施形態に係る保持器付きころの断面図、(B)は同保持器の要部平面図である。(A) is sectional drawing of the roller with a retainer which concerns on 1st Embodiment of this invention, (B) is a principal part top view of the retainer. 同保持器付きころの積層状メッキ層の要部断面図である。It is principal part sectional drawing of the laminated plating layer of the roller with the same holder | retainer. (A)は、同保持器付きころのメッキの耐摩耗性を評価する試験機の断面図、(B)は、同試験機の要部の拡大断面図である。(A) is sectional drawing of the testing machine which evaluates the abrasion resistance of plating of the roller with the cage, (B) is an expanded sectional view of the principal part of the testing machine. 浸漬時間と検出元素量との関係を表す図である。It is a figure showing the relationship between immersion time and the amount of detected elements. Ni・PTFEメッキ層の表面粗さと摩耗量との関係を示す図である。It is a figure which shows the relationship between the surface roughness and wear amount of a Ni * PTFE plating layer. Ni・PTFEメッキ層の焼入れ後のメッキ硬度と摩耗量との関係を表す図である。It is a figure showing the relationship between the plating hardness after quenching of a Ni * PTFE plating layer, and the amount of wear. この発明の実施形態に係る保持器付きころ軸受の断面図である。1 is a cross-sectional view of a roller bearing with a cage according to an embodiment of the present invention. (A)この発明のさらに他の実施形態に係る保持器付きころの断面図、(B)は図8(A)のA−A線断面図である。(A) Sectional drawing of the roller with a retainer which concerns on other embodiment of this invention, (B) is the sectional view on the AA line of FIG. 8 (A). 同保持器付きころを用いたエンジンのコンロッド大端用軸受の要部断面図である。It is principal part sectional drawing of the bearing for connecting rod big ends of the engine using the roller with the said holder | retainer.

この発明の一実施形態を図1ないし図6と共に説明する。この発明の実施形態に係る保持器付きころは、例えば四輪車や二輪車及び汎用エンジン等のクランク軸用支持構造及びコンロッド支持構造等に使用される。ただし、これらクランク軸用支持構造及びコンロッド支持構造に限定されるものではない。
図1(A)に示すように、保持器付きころ50は、複数のころ1と保持器2とを備えている。内輪は無く、この保持器付きころ50が支持する軸の外周面に、ころ1が転接するものとされている。ころ1は例えば針状ころが適用され、このころ1の端面1aを平坦面としている。図1(B)に示すように、保持器2は、円周方向の複数箇所に、前記各ころ1をそれぞれ保持するポケット3を有するリング状のものである。図1(A)および図2に示すように、この保持器2の表面に、下地メッキ層4を施し、この下地メッキ層4の表面に、積層状メッキ層5(後述する)を施している。図1(A)では、積層状メッキ層5を、実際のものよりメッキ層の厚みを強調して表している。
An embodiment of the present invention will be described with reference to FIGS. The roller with cage according to the embodiment of the present invention is used in, for example, a support structure for a crankshaft and a connecting rod support structure for a four-wheeled vehicle, a two-wheeled vehicle, and a general-purpose engine. However, the present invention is not limited to the crankshaft support structure and the connecting rod support structure.
As shown in FIG. 1A, the roller with cage 50 includes a plurality of rollers 1 and a cage 2. There is no inner ring, and the roller 1 is in rolling contact with the outer peripheral surface of the shaft supported by the roller 50 with cage. For example, a needle roller is used as the roller 1, and the end surface 1a of the roller 1 is a flat surface. As shown in FIG. 1B, the cage 2 has a ring shape having pockets 3 for holding the rollers 1 at a plurality of locations in the circumferential direction. As shown in FIGS. 1A and 2, a base plating layer 4 is applied to the surface of the cage 2, and a laminated plating layer 5 (described later) is applied to the surface of the base plating layer 4. . In FIG. 1 (A), the laminated plating layer 5 is shown with the thickness of the plating layer emphasized from the actual one.

図1(A)に示すように、この保持器2は例えば円筒材からの旋削加工品から成る。また、他の工法では薄肉鋼板材からのプレス成形品から成る。保持器2は、両端に内径側に突出した環状部である一対の鍔部6、6を有する略円筒状に形成され、かつ周壁の軸方向中央部分が、径方向内方へ小径部分7としている。図1(B)に示すように、保持器2は、一対の鍔部6、6を繋ぐ円周方向複数箇所の柱部8を有し、隣合う柱部8、8間がそれぞれ前記ポケット3となる。なお、保持器2は、鍔部6、6の代わりに平坦形状等の環状部を有するものとしても良い。   As shown in FIG. 1 (A), the cage 2 is formed of a turned product from a cylindrical material, for example. In another construction method, it consists of a press-formed product from a thin steel plate material. The cage 2 is formed in a substantially cylindrical shape having a pair of flange portions 6, 6 that are annular portions projecting to the inner diameter side at both ends, and the axial central portion of the peripheral wall is formed as a small diameter portion 7 radially inward. Yes. As shown in FIG. 1 (B), the retainer 2 has a plurality of circumferential column portions 8 that connect a pair of flange portions 6 and 6, and the space between adjacent column portions 8 and 8 is the pocket 3. It becomes. The cage 2 may have an annular portion such as a flat shape instead of the flange portions 6 and 6.

図1(B)に示すように、柱部8におけるポケット3の開口周縁において、軸方向中央の小径部分7に、ころ1の脱落防止用突縁9が形成され、且つ、軸方向両端の大径部分にころ1の脱落防止用突縁10、10が形成されている。柱部8におけるポケット3の開口周縁において、脱落防止用突縁9、10間に、ころ1を周方向に案内する傾斜縁11が形成されている。この傾斜縁11は、軸方向の中央部分に向かうに従って径方向外方から内方に傾斜する。ころ1は、これら脱落防止用突縁9、10で内外に抜け止めされ、且つ傾斜縁11で周方向に案内される。   As shown in FIG. 1 (B), on the peripheral edge of the opening of the pocket 3 in the column portion 8, a falling edge 9 for preventing the roller 1 from falling off is formed on the small diameter portion 7 in the center in the axial direction. Protrusions 10 and 10 for preventing the rollers 1 from falling off are formed in the diameter portion. An inclined edge 11 for guiding the roller 1 in the circumferential direction is formed between the protruding edges 9 and 10 for preventing the dropout at the peripheral edge of the opening of the pocket 3 in the column portion 8. The inclined edge 11 is inclined inward from the radially outer side toward the central portion in the axial direction. The rollers 1 are prevented from slipping in and out by the falling-off preventing protrusions 9 and 10 and guided in the circumferential direction by the inclined edges 11.

積層状メッキ層5について説明する。
図1(A)および図2に示すように、保持器2の表面に下地メッキ層4を施し、この下地メッキ層4の表面に、積層状メッキ層5を施している。積層状メッキ層5とは複数層のメッキ層からなるものである。前記下地メッキ層4はニッケルメッキ層である。メッキを処理する面は、保持器表面であり、同保持器の幅面、内径面、ポケットも含む。
積層状メッキ層5は、この例では、図2に示すように、下地メッキ層4の表面に施された、ニッケルとPTFEとを含むNi・PTFEメッキ層5aと、このNi・PTFEメッキ層5aの表面に施され下地メッキ層4と同一のメッキ(つまりニッケルメッキ)からなるメッキ層5bと、このメッキ層5bの表面に施された、ニッケルとPTFEとを含むNi・PTFEメッキ層5cとを有する。つまりこの例では、基材である保持器2の表面に対し、順次、第1層の下地メッキ層4、第2層のNi・PTFEメッキ層5a、第3層のメッキ層5b、第4層のNi・PTFEメッキ層5cが施されている。
The laminated plating layer 5 will be described.
As shown in FIGS. 1A and 2, a base plating layer 4 is applied to the surface of the cage 2, and a laminated plating layer 5 is applied to the surface of the base plating layer 4. The laminated plating layer 5 is composed of a plurality of plating layers. The base plating layer 4 is a nickel plating layer. The surface to be plated is the cage surface, and includes the width surface, inner diameter surface, and pocket of the cage.
In this example, as shown in FIG. 2, the laminated plating layer 5 includes a Ni / PTFE plating layer 5a containing nickel and PTFE, and the Ni / PTFE plating layer 5a. A plating layer 5b made of the same plating as that of the base plating layer 4 (ie, nickel plating) and a Ni / PTFE plating layer 5c containing nickel and PTFE applied to the surface of the plating layer 5b. Have. In other words, in this example, the first base plating layer 4, the second Ni / PTFE plating layer 5 a, the third plating layer 5 b, and the fourth layer are sequentially formed on the surface of the cage 2 that is the base material. Ni / PTFE plating layer 5c is applied.

各Ni・PTFEメッキ層5a,5cにおけるPTFEは、図2に示すように、ニッケルを主要素材とする母材中にPTFEの微粒子(同図中、黒点で示す)を分散共析させたものである。各Ni・PTFEメッキ層5a,5cにおけるPTFE量を1vol%以上35vol%以下と規定している。なお、PTFE量が少ないと摩耗係数が高く摺動特性が劣り、メッキ摩耗量が多い傾向にある。逆に、PTFE量が多すぎると熱処理後の硬度が低いため、摩耗量が多くなる傾向にあった。さらに、PTFEが多く含まれるとコスト高となる。
この実施形態では、各Ni・PTFEメッキ層5a,5cのPTFE量を1vol%以上35vol%以下と規定することで、摩擦係数が低く摺動特性に優れ、メッキ摩耗量を低くすることができる。さらに製造コストの低減を図ることが可能となる。
As shown in FIG. 2, PTFE in each of the Ni / PTFE plating layers 5a and 5c is obtained by dispersing and eutecting PTFE fine particles (indicated by black dots in the figure) in a base material mainly composed of nickel. is there. The amount of PTFE in each of the Ni / PTFE plating layers 5a and 5c is defined as 1 vol% or more and 35 vol% or less. When the amount of PTFE is small, the wear coefficient is high and the sliding characteristics are inferior, and the amount of plating wear tends to be large. On the contrary, when the amount of PTFE is too large, the hardness after heat treatment is low, so that the amount of wear tends to increase. Further, when a large amount of PTFE is contained, the cost increases.
In this embodiment, by defining the PTFE amount of each of the Ni / PTFE plating layers 5a and 5c as 1 vol% or more and 35 vol% or less, the friction coefficient is low, the sliding characteristics are excellent, and the plating wear amount can be reduced. Further, it becomes possible to reduce the manufacturing cost.

第1層の下地メッキ層4、第3層のメッキ層5bの膜厚δ1、δ3を、それぞれ3μm以上10μm以下、第2層,第4層のNi・PTFEメッキ層5a,5cの膜厚δ2,δ4を、それぞれ5μm以上15μm以下としている。
第1層の下地メッキ層4は、Ni・PTFEメッキ層5aと基材とのアンカー効果を成し、第3層のメッキ層5bは、Ni・PTFEメッキ層5a,5c同士のアンカー効果を成すメッキ層である。
また、メッキの密着力つまり耐摩耗性について、以下のリングオンディスク型の試験機を用いて評価したところ、第2層,第4層のNi・PTFEメッキ層5a,5cの膜厚δ2,δ4を、それぞれ5μm以上15μm以下とすると、メッキ層の総膜厚δtを厚くでき、摩耗に対する延命効果がある。
The film thicknesses δ1 and δ3 of the first base plating layer 4 and the third plating layer 5b are 3 μm or more and 10 μm or less, respectively, and the film thicknesses δ2 of the second and fourth Ni / PTFE plating layers 5a and 5c. , Δ4 are 5 μm or more and 15 μm or less, respectively.
The first base plating layer 4 forms an anchor effect between the Ni / PTFE plating layer 5a and the substrate, and the third plating layer 5b forms an anchor effect between the Ni / PTFE plating layers 5a and 5c. It is a plating layer.
Further, when the adhesion of the plating, that is, the wear resistance, was evaluated using the following ring-on-disk type tester, the film thicknesses δ2, δ4 of the second and fourth Ni / PTFE plating layers 5a, 5c were evaluated. When the thickness is 5 μm or more and 15 μm or less, the total film thickness δt of the plating layer can be increased, and there is an effect of extending the life against wear.

積層状メッキ層5の密着力(耐摩耗性)について、表1、図3と共に説明する。

Figure 2012036940
The adhesion (abrasion resistance) of the laminated plating layer 5 will be described with reference to Table 1 and FIG.
Figure 2012036940

表1に示すように、サンプルを5種類(No.A〜E)製作して、メッキの密着力について、リングオンディスク型の試験機を用いて評価した。表1において、サンプルAおよびBは、それぞれ第3層、第4層にメッキ層が設けられていない、従来技術に係る2層構造のサンプルである。サンプルC,D,Eは、それぞれ、この発明の実施形態に係る、積層状メッキ層が設けられたサンプルである。同表における数値の単位はμmである。   As shown in Table 1, five types of samples (No. A to E) were manufactured, and the adhesion of plating was evaluated using a ring-on-disk type tester. In Table 1, samples A and B are samples having a two-layer structure according to the prior art in which no plating layer is provided on the third layer and the fourth layer, respectively. Samples C, D, and E are samples each provided with a laminated plating layer according to the embodiment of the present invention. The unit of numerical values in the table is μm.

図3(A)に示すように、リングオンディスク型の試験機RMは、回転駆動される回転軸30と、この回転軸30の上端部にボルト等の固定具31を介して固定される円板状の相手材32と、この相手材32の表面部に対向して同心に配置される負荷軸33と、この負荷軸33の下端部に取り付けられる金属製のリング部材34とを有する。
この例では、図3(B)に示すように、リング部材34の下端面34aに設けられる各サンプルを、相手材32の表面部に押圧しつつ、回転軸30を回転する。これにより各サンプルにおけるメッキ層の摩耗、剥がれの有無を確認する。なお、相手材32は、例えばSUJ2から成り、この相手材32の表面部を研磨したものを用いている。
As shown in FIG. 3A, the ring-on-disk type testing machine RM includes a rotating shaft 30 that is rotationally driven, and a circle that is fixed to the upper end of the rotating shaft 30 via a fixture 31 such as a bolt. It has a plate-like mating member 32, a load shaft 33 arranged concentrically facing the surface portion of the mating member 32, and a metal ring member 34 attached to the lower end portion of the load shaft 33.
In this example, as shown in FIG. 3B, the rotating shaft 30 is rotated while pressing each sample provided on the lower end surface 34 a of the ring member 34 against the surface portion of the counterpart material 32. This confirms the presence or absence of wear and peeling of the plating layer in each sample. The counterpart material 32 is made of, for example, SUJ2, and a material obtained by polishing the surface portion of the counterpart material 32 is used.

試験結果によると、サンプルC,D,Eでは、積層状メッキ層5の表層等が摩耗するものの、地金の発生は無く、メッキ層の剥れも認められなかった。これに対し、従来技術に係るサンプルAでは、第1層および第2層が徐々に摩耗し地金が発生した。従来技術に係るサンプルBでは、第2層が摩耗すると共にこの第2層の剥がれが認められた。
このように、本発明のサンプルC,D,Eでは、厳しい使用環境下でメッキ層の総膜厚δtを厚くしてもメッキ層が剥がれない。換言すれば、メッキ層の総膜厚δtが厚くても表面処理の皮膜応力が増加せず、メッキ層の剥れを防止し得る。さらに積層状メッキ層5の皮膜厚さを厚くすることができるので、長期に稼動しても表面処理が残存し、保持器2の摩耗や潤滑不良を防止することができる。
According to the test results, in Samples C, D, and E, the surface layer of the laminated plating layer 5 was worn, but no metal was generated and the plating layer was not peeled off. On the other hand, in the sample A according to the prior art, the first layer and the second layer were gradually worn and bare metal was generated. In sample B according to the prior art, the second layer was worn and peeling of the second layer was observed.
As described above, in the samples C, D, and E of the present invention, the plating layer does not peel off even when the total thickness δt of the plating layer is increased in a severe use environment. In other words, even if the total thickness δt of the plating layer is large, the film stress of the surface treatment does not increase, and the plating layer can be prevented from peeling off. Furthermore, since the film thickness of the laminated plating layer 5 can be increased, the surface treatment remains even after long-term operation, and wear and lubrication failure of the cage 2 can be prevented.

下地メッキ層の有無によるメッキの密着力について
この実施形態に係る保持器2は、メッキの密着力の向上を図るために、下地メッキ層4としてニッケルメッキ層を施している。この下地メッキ層4の有無による密着力を、実際の保持器付きころ(内径28mm×外径34mm×幅17mm)を用い、実機と同じクランクモーション運動で比較した。その結果を表2に示す。
About the adhesion strength of the plating with and without the underlying plating layer The cage 2 according to this embodiment is provided with a nickel plating layer as the underlying plating layer 4 in order to improve the adhesion strength of the plating. The adhesion force due to the presence or absence of the underlying plating layer 4 was compared using the actual roller with cage (inner diameter 28 mm × outer diameter 34 mm × width 17 mm) in the same crank motion motion as the actual machine. The results are shown in Table 2.

Figure 2012036940
Figure 2012036940

表2に示すように、下地メッキ層4を施さない製品は、試験後にメッキ層の摩耗と剥れが認められた。一方、下地メッキ層4を施した製品は、試験後に軽微な摩耗は認められたが、メッキ層の剥れは認められなかった。このように、メッキの密着力の向上を図るには、下地処理が必要であることが判明した。   As shown in Table 2, the product without the base plating layer 4 was found to wear and peel off the plating layer after the test. On the other hand, although the product which gave the base plating layer 4 showed slight abrasion after the test, peeling of the plating layer was not recognized. Thus, it has been found that the base treatment is necessary to improve the adhesion of the plating.

表面処理の溶解について説明する。
この発明の実施形態に係るNi・PTFEメッキ層5a,5cの金属成分等が、4サイクルエンジンオイルの高温条件下で溶解しないことを浸漬試験で確認した。図4に示すように、従来の銅メッキ、銀メッキは、浸漬時間の経過と共に油中から多くの元素量が検出されている。同図中、銅メッキは四角印で表記し、銀メッキは三角印で表記している。
これに対し、同図中、菱形で表記する実施形態に係るNi・PTFEメッキ層を有するものは、浸漬時間200時間を経過しても、下地メッキ層、Ni・PTFEメッキ層、ニッケルメッキ層、およびNi・PTFEメッキ層に関係した元素は検出されなかった。
The dissolution of the surface treatment will be described.
It was confirmed by an immersion test that the metal components and the like of the Ni / PTFE plating layers 5a and 5c according to the embodiment of the present invention do not dissolve under the high temperature conditions of the 4-cycle engine oil. As shown in FIG. 4, in the conventional copper plating and silver plating, a large amount of element is detected from the oil as the immersion time elapses. In the figure, copper plating is indicated by square marks, and silver plating is indicated by triangle marks.
On the other hand, in the same figure, the one having the Ni / PTFE plating layer according to the embodiment represented by rhombus, even if the immersion time is 200 hours, the base plating layer, the Ni / PTFE plating layer, the nickel plating layer, And the elements related to the Ni · PTFE plating layer were not detected.

Ni・PTFEメッキ層5cの表面粗さの規格値について説明する。
この発明の実施形態では、最外層であるNi・PTFEメッキ層5cの表面粗さはRa0.7μm以下としている。
「Ra」は、日本工業規格で規定される中心線平均粗さRaであり、JIS 0601
−1976表面粗さの規格に準拠して測定する。
Ni・PTFEメッキ層5cの表面粗さにより、メッキ自体の摩耗量が変化するかどうかを確認するため、膜厚評価を行った上記保持器付きころ及び上記試験条件で、摩耗比較評価を実施した。その結果、図5に示すように、表面粗さがRa0.7μmを超えると、摩耗量が増加する傾向にある。これは、粗さ自身の凹凸の凸部が高く表面粗さが粗い方が摩耗しやすい結果であった。
The standard value of the surface roughness of the Ni / PTFE plating layer 5c will be described.
In the embodiment of the present invention, the surface roughness of the Ni · PTFE plating layer 5c which is the outermost layer is set to Ra 0.7 μm or less.
“Ra” is a center line average roughness Ra defined by Japanese Industrial Standards, and is JIS 0601.
-Measured according to 1976 surface roughness standard.
In order to confirm whether or not the wear amount of the plating itself changes depending on the surface roughness of the Ni / PTFE plating layer 5c, the wear comparison evaluation was performed using the roller with cage and the test conditions for which the film thickness was evaluated. . As a result, as shown in FIG. 5, when the surface roughness exceeds Ra 0.7 μm, the amount of wear tends to increase. This is a result that the roughness of the roughness itself is higher and the surface roughness is easier to wear.

Ni・PTFEメッキ層5a,5cの硬度について説明する。
この発明の実施形態では、Ni・PTFEメッキ層5a,5cを熱処理により硬化させ、このNi・PTFEメッキ層5a,5cの熱処理後のメッキ硬度をHv300以上Hv700以下としている。
Ni・PTFEメッキ層5a,5cのメッキ硬度の最適値を決定するために、総膜厚δtを決定した際と同じ保持器付きころで同じ試験条件で摩耗比較を実施した。メッキ硬度は、Ni・PTFEメッキ層5a,5cにおけるPTFEの含有量と焼入れ温度で決定する値である。したがって、試験サンプルは、PTFEの含有量を一定にして、焼入れ温度を変更して製作した。
The hardness of the Ni · PTFE plating layers 5a and 5c will be described.
In the embodiment of the present invention, the Ni / PTFE plating layers 5a and 5c are cured by heat treatment, and the plating hardness after the heat treatment of the Ni / PTFE plating layers 5a and 5c is set to Hv300 or more and Hv700 or less.
In order to determine the optimum value of the plating hardness of the Ni / PTFE plating layers 5a and 5c, wear comparison was performed under the same test conditions using the same roller with cage as when the total film thickness δt was determined. The plating hardness is a value determined by the PTFE content and the quenching temperature in the Ni / PTFE plating layers 5a and 5c. Therefore, the test sample was manufactured by changing the quenching temperature while keeping the PTFE content constant.

図6に示すように、この結果からNi・PTFEメッキ層5a,5cの焼入れ後のメッキ硬度がHv300以上Hv700以下であれば、摩耗量の差は0.001mm以内であり、差が認められない結果であった。Ni・PTFEメッキ層5a,5cの焼入れ後のメッキ硬度がHv300未満では、摩耗量が大きくなる。Hv700を超えると、硬度が高すぎてメッキ層がヒビ割れる可能性がある。   As shown in FIG. 6, if the plating hardness after quenching of the Ni / PTFE plating layers 5a and 5c is Hv300 or more and Hv700 or less, the difference in wear amount is within 0.001 mm, and no difference is recognized. It was a result. When the plating hardness after quenching of the Ni · PTFE plating layers 5a and 5c is less than Hv300, the amount of wear increases. If it exceeds Hv700, the hardness is too high and the plating layer may crack.

以上説明した保持器付きころ50によると、保持器2の表面に下地メッキ層4を施し、この下地メッキ層4の表面に、複数層のメッキ層からなる積層状メッキ層5を施したため、メッキ層の総膜厚δtが厚くても表面処理の皮膜応力が増加せず、メッキ層の剥れを防止し得る。さらに積層状メッキ層5の皮膜厚さを厚くすることができるので、長期に稼動しても表面処理が残存し、保持器2の摩耗や潤滑不良を防止することができる。
積層状メッキ層5のうち、Ni・PTFEメッキ層5a,5cにおけるニッケルは、銅、銀に比べ添加剤と反応し難い性質を持つため、図4に示したように溶出を抑制することが可能となる。したがって、この保持器付きころ50を4サイクルエンジンに用いた場合において、このエンジンオイルに保持器付きころ50を浸漬させても、同エンジンオイル中にニッケルが溶出することを抑制し得る。よって、積層状メッキ層5が脆くなることを防止し、これによりメッキ剥れを防止することができる。前記エンジンオイルに添加剤が含まれていても、この添加剤に影響されることなく、エンジンオイル中にニッケルが溶出することを抑制し、これにより、積層状メッキ層5が脆くなることを防止し、メッキ剥れを防止することができる。
According to the roller 50 with a cage described above, the base plating layer 4 is applied to the surface of the cage 2, and the surface of the base plating layer 4 is provided with the laminated plating layer 5 composed of a plurality of plating layers. Even if the total film thickness δt of the layer is large, the film stress of the surface treatment does not increase, and peeling of the plating layer can be prevented. Furthermore, since the film thickness of the laminated plating layer 5 can be increased, the surface treatment remains even after long-term operation, and wear and lubrication failure of the cage 2 can be prevented.
Of the multi-layer plating layer 5, nickel in the Ni / PTFE plating layers 5a and 5c is less likely to react with additives than copper and silver, so that elution can be suppressed as shown in FIG. It becomes. Therefore, when this roller 50 with a retainer is used in a four-cycle engine, even if the roller 50 with a retainer is immersed in this engine oil, it can be suppressed that nickel is eluted in the engine oil. Therefore, it is possible to prevent the laminated plating layer 5 from becoming brittle, thereby preventing plating peeling. Even if an additive is contained in the engine oil, nickel is not eluted into the engine oil without being affected by the additive, thereby preventing the laminated plating layer 5 from becoming brittle. And plating peeling can be prevented.

また、第1層の下地メッキ層4をニッケルメッキ層とし、このニッケルメッキ層を第2層のNi・PTFEメッキ層5aと基材(保持器)の間に設けることにより、基材とNi・PTFEメッキ層5aとの密着強度が向上し、メッキ剥れを防止する。つまり第1層と第2層とが共通の組成物すなわちニッケルを含むため、両層付近の組成が徐々に変化し、これらニッケルメッキ層とNi・PTFEメッキ層5aとの界面を隙間無く密着させることができる。よって、基材、ニッケルメッキ層、およびNi・PTFEメッキ5a層にわたって密着性が優れたものになる。上記のように、密着力が向上するのは、組成の近いメッキを間に設けることにより金属同士の結合を強くしているためである。
第3層のメッキ層5bをニッケルメッキ層とし、このニッケルメッキ層を、第2層,第4層のNi・PTFEメッキ層5a,5c間に介在させることにより、前記第1層,第2層間と同様に第2層と第3層との密着強度が向上すると共に第3層と第4層との密着強度が向上し、メッキ剥れを防止する。
さらにNi・PTFEメッキ層5c中のPTFEの自己潤滑作用により、メッキの摩擦係数が低減し、耐摩耗性が向上する。
Also, the base plating layer 4 of the first layer is a nickel plating layer, and this nickel plating layer is provided between the Ni / PTFE plating layer 5a of the second layer and the base material (cage), so that the base material and the Ni. The adhesion strength with the PTFE plating layer 5a is improved, and plating peeling is prevented. In other words, since the first layer and the second layer contain a common composition, that is, nickel, the composition in the vicinity of both layers gradually changes, and the interface between the nickel plating layer and the Ni / PTFE plating layer 5a is brought into close contact with no gap. be able to. Therefore, the adhesiveness is excellent over the base material, the nickel plating layer, and the Ni / PTFE plating 5a layer. As described above, the adhesion is improved because the bonding between the metals is strengthened by providing a plating having a similar composition between them.
The third plating layer 5b is a nickel plating layer, and the nickel plating layer is interposed between the second and fourth Ni / PTFE plating layers 5a and 5c, thereby allowing the first and second layers to be interposed. Similarly, the adhesion strength between the second layer and the third layer is improved, and the adhesion strength between the third layer and the fourth layer is improved, thereby preventing plating peeling.
Further, the self-lubricating action of PTFE in the Ni / PTFE plating layer 5c reduces the friction coefficient of plating and improves the wear resistance.

下地メッキ層4および積層状メッキ層5を保持器に施した場合、保持器ポケット3のころ案内面にメッキ層が付くため、ころ1の摩耗低減を図れる。また、保持器2の一部をマスキングしたり、付着したメッキ層を除去する手間がなくなるため、メッキ作業全体の工数低減を図ることができる。
積層状メッキ層5は、前記第4層のNi・PTFEメッキ層5cの表面に施され、下地メッキ層4と同一のメッキ(つまりニッケルメッキ)からなるメッキ層(第5層)を含むものとしても良い。
下地メッキ層4および積層状メッキ層5を、保持器の全表面に施しても良いし、保持器の外径面や幅面等必要な箇所のみに施しても良い。
When the base plating layer 4 and the laminated plating layer 5 are applied to the cage, a plating layer is attached to the roller guide surface of the cage pocket 3, so that the wear of the roller 1 can be reduced. Further, since there is no need to mask a part of the cage 2 or to remove the adhered plating layer, it is possible to reduce the man-hour of the entire plating operation.
The laminated plating layer 5 is applied to the surface of the fourth Ni / PTFE plating layer 5c and includes a plating layer (fifth layer) made of the same plating as the base plating layer 4 (that is, nickel plating). Also good.
The base plating layer 4 and the laminated plating layer 5 may be applied to the entire surface of the cage, or may be applied only to necessary portions such as the outer diameter surface and the width surface of the cage.

図7は、この発明の一実施形態に係る保持器付きころ軸受を示す。この保持器付きころ軸受は、前記いずれかの構成の保持器付きころ50(50A)と、前記複数のころ1が転接する軌道輪14とでなる。軌道輪14はこの例では外輪が適用される。保持器付きころ軸受は、前記外輪および内輪(または軸Sh)のいずれか一方、または両方を含む構成としても良い。   FIG. 7 shows a roller bearing with a cage according to an embodiment of the present invention. This roller bearing with cage is composed of the roller with cage 50 (50A) having any one of the above-described configurations and the race ring 14 with which the plurality of rollers 1 are in rolling contact. In this example, the outer ring is used as the race ring 14. The roller bearing with a cage may be configured to include one or both of the outer ring and the inner ring (or shaft Sh).

図8の保持器付きころ50Bは、複数のころ1と、第1および第2の保持器2C、15とを有する。図8(A)は軸線L1を含む平面で保持器付きころを切断して見た断面図である。図8(B)は図8(A)のA−A線断面図である。第1の保持器2Cは、図1,図2と共に前述した第1の実施形態の保持器2と同様の構成とされている。第1の保持器2Cの表面に下地メッキ層4および積層状メッキ層5が施されている。第2の保持器15は、平坦面からなるリング状のものであり、ころ1を保持するポケット15aが形成されている。この第2の保持器15の表面にも下地メッキ層4および積層状メッキ層5が施されている。この第2の保持器15は、第1の保持器2Cの鍔部6の内周面に径方向隙間を介して配置される。   A roller 50B with a retainer in FIG. 8 includes a plurality of rollers 1 and first and second retainers 2C and 15. FIG. 8A is a cross-sectional view of a roller with a cage cut along a plane including the axis L1. FIG. 8B is a cross-sectional view taken along line AA in FIG. The first cage 2C has the same configuration as the cage 2 of the first embodiment described above with reference to FIGS. A base plating layer 4 and a laminated plating layer 5 are provided on the surface of the first cage 2C. The second retainer 15 is a ring-shaped member having a flat surface, and a pocket 15a for retaining the roller 1 is formed. The surface of the second cage 15 is also provided with a base plating layer 4 and a laminated plating layer 5. The second cage 15 is disposed on the inner peripheral surface of the flange portion 6 of the first cage 2C via a radial gap.

図9は、保持器付きころを用いたエンジンのコンロッド大端用軸受の要部断面図である。この発明のいずれかの保持器付きころ50等が、クランクシャフト用支持軸受BR1,BR1や、コンロッドCRとクランクシャフトCSとの連結部35の軸受BR2、つまりコンロッド大端用軸受に適用される。   FIG. 9 is a cross-sectional view of the main part of a connecting rod large end bearing for an engine using rollers with cages. Any one of the rollers with cage 50 according to the present invention is applied to the crankshaft support bearings BR1 and BR1, the bearing BR2 of the connecting portion 35 between the connecting rod CR and the crankshaft CS, that is, the connecting rod large end bearing.

1…ころ
2,2A…保持器
3…ポケット
4…下地メッキ層
5…積層状メッキ層
5a,5c…Ni・PTFEメッキ層
5b…メッキ層
50,50A,50B…保持器付きころ
DESCRIPTION OF SYMBOLS 1 ... Roller 2, 2A ... Cage 3 ... Pocket 4 ... Base plating layer 5 ... Laminated plating layer 5a, 5c ... Ni / PTFE plating layer 5b ... Plating layer 50, 50A, 50B ... Roller with cage

Claims (11)

複数のころと、円周方向の複数箇所に、前記各ころをそれぞれ保持するポケットを有するリング状の保持器とを備えた保持器付きころにおいて、
前記保持器の表面に下地メッキ層を施し、この下地メッキ層の表面に、ニッケルとPTFEとを含むNi・PTFEメッキ層と、このNi・PTFEメッキ層の表面に施され前記下地メッキ層と同一のメッキからなるメッキ層と、このメッキ層の表面に施された、ニッケルとPTFEとを含むNi・PTFEメッキ層とを有する複数層のメッキ層からなる積層状メッキ層を施した保持器付きころ。
In a roller with a cage provided with a plurality of rollers and a ring-shaped cage having a pocket for holding each of the rollers at a plurality of locations in the circumferential direction,
A base plating layer is applied to the surface of the cage, a Ni / PTFE plating layer containing nickel and PTFE is provided on the surface of the base plating layer, and the same as the base plating layer is applied to the surface of the Ni / PTFE plating layer. Roller with a cage having a laminated plating layer composed of a plurality of plating layers each having a plating layer made of the above-described plating and a nickel / PTFE plating layer containing nickel and PTFE applied to the surface of the plating layer .
請求項1において、前記各Ni・PTFEメッキ層におけるPTFEは、ニッケルメッキ中にPTFE粒子が分散しているものである保持器付きころ。   2. The roller with a retainer according to claim 1, wherein PTFE in each of the Ni · PTFE plating layers is one in which PTFE particles are dispersed during nickel plating. 請求項1または請求項2において、前記積層状メッキ層における、下地メッキ層と同一のメッキからなる前記メッキ層、および前記下地メッキ層は、ニッケルメッキ層である保持器付きころ。   3. The roller with a cage according to claim 1, wherein the plating layer made of the same plating as the base plating layer in the laminated plating layer, and the base plating layer is a nickel plating layer. 4. 請求項1ないし請求項3のいずれか1項において、前記メッキ層の膜厚を3μm以上10μm以下とし、前記Ni・PTFEメッキ層の膜厚を5μm以上15μm以下とした保持器付きころ。   4. The roller with a retainer according to claim 1, wherein a thickness of the plating layer is 3 μm or more and 10 μm or less, and a thickness of the Ni / PTFE plating layer is 5 μm or more and 15 μm or less. 請求項1ないし請求項4のいずれか1項において、前記Ni・PTFEメッキ層におけるPTFE量を、各Ni・PTFEメッキ層毎に異なるPTFE量とした保持器付きころ。   The roller with a retainer according to any one of claims 1 to 4, wherein the PTFE amount in the Ni / PTFE plating layer is different for each Ni / PTFE plating layer. 請求項1ないし請求項5のいずれか1項において、前記下地メッキ層は、PTFEを含まないメッキ層とし、前記積層状メッキ層のうち最外層は、PTFEを含むメッキ層とした保持器付きころ。   The roller with a retainer according to any one of claims 1 to 5, wherein the base plating layer is a plating layer that does not include PTFE, and the outermost layer of the laminated plating layer is a plating layer that includes PTFE. . 請求項1ないし請求項6のいずれか1項において、前記積層状メッキ層における各メッキ層を、各メッキ層毎に異なる膜厚とした保持器付きころ。   The roller with a retainer according to any one of claims 1 to 6, wherein each plating layer in the laminated plating layer has a different thickness for each plating layer. 請求項1ないし請求項7のいずれか1項において、前記積層状メッキ層は、3層以上のメッキ層からなる保持器付きころ。   The roller with a retainer according to any one of claims 1 to 7, wherein the laminated plating layer includes three or more plating layers. 請求項1ないし請求項8のいずれか1項に記載の保持器付きころと、前記複数のころが転接する軌道輪とを備えた保持器付きころ軸受。   A roller bearing with a cage, comprising: the roller with a cage according to any one of claims 1 to 8; and a bearing ring on which the plurality of rollers roll. 複数のころと、円周方向の複数箇所に、前記各ころをそれぞれ保持するポケットを有するリング状の保持器とを備えた保持器付きころにおける保持器であって、この保持器の表面に下地メッキ層を施し、この下地メッキ層の表面に、複数層のメッキ層からなる積層状メッキ層を施した保持器。   A retainer in a roller with a retainer comprising a plurality of rollers and a ring-shaped retainer having a pocket for retaining each of the rollers at a plurality of locations in the circumferential direction, and a base on the surface of the retainer A cage in which a plating layer is applied and a laminated plating layer composed of a plurality of plating layers is applied to the surface of the underlying plating layer. 請求項1ないし請求項8のいずれか1項に記載の保持器付きころを用いたエンジンのコンロッド大端用軸受。   A bearing for a connecting rod large end of an engine using the roller with a cage according to any one of claims 1 to 8.
JP2010176012A 2010-08-05 2010-08-05 Roller and cage assembly, roller bearing and cage assembly, and cage Pending JP2012036940A (en)

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US10465750B2 (en) 2014-02-03 2019-11-05 Ntn Corporation Sliding member, rolling bearing, and cage

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DE102012210689A1 (en) * 2012-06-25 2014-04-17 Schaeffler Technologies Gmbh & Co. Kg Device with mutually movable elements, preferably planetary gear
DE102015210924A1 (en) * 2015-06-15 2016-07-07 Schaeffler Technologies AG & Co. KG Wälzkörperkäfig a planetary gear bearing with lubrication pockets on the outer diameter
WO2019089058A1 (en) 2017-11-06 2019-05-09 Koyo Bearings North America Llc Two-piece roller retainer cage for a roller thrust bearing
CN109774181B (en) * 2018-12-26 2021-10-01 洛阳轴承研究所有限公司 Forming method of bar for manufacturing miniature bearing retainer

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JPH07332371A (en) * 1994-06-09 1995-12-22 Koyo Seiko Co Ltd Cage for rolling bearing used for connecting rod of two--cycle engine
JP4514151B2 (en) * 2005-09-27 2010-07-28 株式会社ジェイテクト Roller bearing cage and roller bearing

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US10465750B2 (en) 2014-02-03 2019-11-05 Ntn Corporation Sliding member, rolling bearing, and cage
JP2015194250A (en) * 2014-03-24 2015-11-05 Ntn株式会社 Cage for rolling bearing and rolling bearing

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