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JP2012071296A5
JP2012071296A5 JP2011173205A JP2011173205A JP2012071296A5 JP 2012071296 A5 JP2012071296 A5 JP 2012071296A5 JP 2011173205 A JP2011173205 A JP 2011173205A JP 2011173205 A JP2011173205 A JP 2011173205A JP 2012071296 A5 JP2012071296 A5 JP 2012071296A5
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sludge
dewatering
aid
fiber
dehydration
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本発明の汚泥脱水装置の一例を示すフロー構成図。The flow block diagram which shows an example of the sludge dehydration apparatus of this invention. 本発明の汚泥脱水装置の他の例を示すフロー構成図。The flow block diagram which shows the other example of the sludge dehydration apparatus of this invention. 本発明の汚泥脱水装置の他の例を示すフロー構成図。The flow block diagram which shows the other example of the sludge dehydration apparatus of this invention. 脱水助剤A,B,E,G(実施例)を構成する繊維の断面斜視図。The cross-sectional perspective view of the fiber which comprises dehydration adjuvant A, B, E, G (Example). 脱水助剤C,D(実施例)を構成する繊維の断面斜視図。The cross-sectional perspective view of the fiber which comprises dehydration auxiliary | assistance C and D (Example). 脱水助剤F(実施例)を構成する繊維の断面斜視図。The cross-sectional perspective view of the fiber which comprises the dehydration adjuvant F (Example). 脱水助剤H(実施例)を構成する繊維の断面斜視図。The cross-sectional perspective view of the fiber which comprises the dehydration adjuvant H (Example). 脱水助剤I(比較例)を構成する繊維の断面斜視図。The cross-sectional perspective view of the fiber which comprises the dehydration adjuvant I (comparative example). 従来における脱水助剤J(市販品),Kを構成する繊維の断面斜視図。The cross-sectional perspective view of the fiber which comprises the dehydration adjuvant J (commercial item) and K in the past . 繊維径を示す脱水助剤を構成する繊維の断面図。Sectional drawing of the fiber which comprises the dehydration adjuvant which shows a fiber diameter. 筋を形成する凹部の最深部の頂点までの深さを示す脱水助剤を構成する繊維の断面図。Sectional drawing of the fiber which comprises the dehydration adjuvant which shows the depth to the vertex of the deepest part of the recessed part which forms a line | wire.

図9は、従来の技術を示す脱水助剤J、Kの斜視図である。繊維断面に凹部は無く、繊維長手方向に沿って延在する筋が存在しない。
[実施例1] (本発明の脱水助剤有無による比較)
表2に示す性状を有するオキシデーションディッチ方式下水処理場から発生する余剰汚泥スラリーに、SSを100として絶乾重量で3wt%となるように脱水助剤Aを添加して、汚泥スラリーを調整した。次に、高分子凝集剤(ジメチルアミノエチルアクリレートの塩化メチル四級化物/アクリルアミド共重合体、分子量400万、水道水で0.2%に調整)を使用して脱水試験を行った。汚泥200mlを300mlのビーカーに入れ、高分子凝集剤を所定量添加した後、ビーカー間の移し変えを10回行って汚泥を凝集させた。凝集した汚泥の大きさを測定した後、凝集した汚泥を60メッシュのナイロンろ布に載せて、重力をかけて脱水し、30秒後のろ過水量を測定した。重力ろ過後の汚泥を、2枚のろ布に挟み、ピストン型脱水機を用いて、2kg/cmの圧力で1分間圧搾した。得られた脱水ケーキの剥離性の評価と含水率の測定を行った。剥離性の評価は、脱水後、2枚のろ布を開いたときに、ろ布から剥がれるケーキ量を目視測定し、ほぼ完全に剥離している場合を◎、半分程度が剥離している場合を△、半分程度より多いが完全には剥離していない場合を○、ろ布全面に付着して剥離していない場合を×と判定した。結果を表3に示す。
FIG. 9 is a perspective view of dehydration aids J and K showing the prior art . There are no recesses in the fiber cross section, and there are no streaks extending along the longitudinal direction of the fiber.
[Example 1] (Comparison with and without dehydration aid of the present invention)
To the excess sludge slurry generated from the oxidation ditch system sewage treatment plant having the properties shown in Table 2, the dewatering aid A was added so that the dry weight would be 3 wt% with SS as 100 to prepare the sludge slurry. . Next, a dehydration test was carried out using a polymer flocculant (dimethylaminoethyl acrylate methyl chloride quaternized / acrylamide copolymer, molecular weight of 4 million, adjusted to 0.2% with tap water). 200 ml of sludge was put in a 300 ml beaker, a predetermined amount of a polymer flocculant was added, and the sludge was agglomerated by changing between beakers 10 times. After measuring the size of the agglomerated sludge, the agglomerated sludge was placed on a 60 mesh nylon filter cloth, dehydrated by gravity, and the amount of filtered water after 30 seconds was measured. The sludge after gravity filtration was sandwiched between two filter cloths and squeezed for 1 minute at a pressure of 2 kg / cm 2 using a piston-type dehydrator. The obtained dehydrated cake was evaluated for peelability and the water content was measured. The peelability is evaluated by visually measuring the amount of cake peeled off from the filter cloth when two filter cloths are opened after dehydration. △, more than about half, but not completely peeled, ○, and the case where it adhered to the entire filter cloth and did not peel was judged as x. The results are shown in Table 3.

本発明の汚泥の脱水方法に使用する装置のフロー構成図を、図1〜図3に示す。
図1は、機械脱水機としてベルトプレス脱水機4を用いた1例である。汚泥濃縮槽1で濃縮された汚泥は、汚泥濃縮槽1の底部から汚泥貯留槽2に送出され、所定時間、貯留される。その後、汚泥は、汚泥貯留槽2から凝集槽3に送出される。凝集槽3には、高分子凝集剤溶解装置6から高分子凝集剤が添加され、汚泥を凝集させて凝集フロックを形成する。次いで、凝集フロック(汚泥)は、脱水機4に送出され、脱水処理されて脱水ケーキを形成する。脱水助剤供給機5から、汚泥濃縮槽1、汚泥貯留槽2、凝集槽3及び高分子凝集剤溶解装置6の1以上に、脱水助剤を添加できるように配管が接続されている。脱水助剤を汚泥に添加する場所は、処理状況に応じて、別々に又は同時に複数の槽及び配管を選択してよい。凝集フロック(汚泥)に脱水助剤を添加すると、個々の汚泥と脱水助剤との接触が低下するので、高分子凝集剤の添加前あるいは高分子凝集剤の添加と同時に脱水助剤を汚泥に添加することが好ましい。このため、脱水助剤を汚泥濃縮槽1又は高分子凝集剤溶解装置6に添加することが特に好ましい。
The flow block diagram of the apparatus used for the dewatering method of the sludge of this invention is shown in FIGS. 1-3.
FIG. 1 shows an example in which a belt press dehydrator 4 is used as a mechanical dehydrator. The sludge concentrated in the sludge concentration tank 1 is sent from the bottom of the sludge concentration tank 1 to the sludge storage tank 2 and stored for a predetermined time. Thereafter, the sludge is sent from the sludge storage tank 2 to the coagulation tank 3. The flocculation tank 3, the polymeric flocculant is added from polymer coagulant dissolving device 6, to form a floc by aggregating the sludge. Next, the aggregated floc (sludge) is sent to the dehydrator 4 and dehydrated to form a dehydrated cake. A pipe is connected from the dehydration aid supply machine 5 to one or more of the sludge concentration tank 1, the sludge storage tank 2, the coagulation tank 3, and the polymer coagulant dissolving apparatus 6 so that the dehydration aid can be added. The place where the dehydrating aid is added to the sludge may be selected separately or simultaneously from a plurality of tanks and pipes depending on the treatment status. When dehydration aid is added to the coagulation floc (sludge), the contact between the individual sludge and the dehydration aid decreases, so the dehydration aid is added to sludge before or simultaneously with the addition of the polymer flocculant. It is preferable to add. For this reason, it is particularly preferable to add the dehydrating aid to the sludge concentration tank 1 or the polymer flocculant dissolving device 6.

Claims (14)

繊維状物の横断面外周面に形成された凸部と凹部が、長手方向に沿って延在し、
当該凹部は、汚泥が接触する際に毛細管作用により水分を移送する水分移送路として形成され、
当該繊維状物が、複数集合して成ることを特徴とする汚泥用脱水助剤。
Projection and recess formed on the cross-section outer peripheral surface of the fibrous material is, extend in the longitudinal direction,
The concave portion is formed as a moisture transfer path for transferring moisture by capillary action when the sludge contacts .
A dewatering aid for sludge , characterized in that a plurality of the fibrous materials are assembled .
複数の繊維が集合してなり、各繊維の外周面に繊維の長手方向に沿って延在する複数の凹部を有し、
当該凹部は、汚泥が接触する際に毛細管作用により汚泥水分を移送する水分移送路として作用する筋が繊維の長手方向に沿って延在して形成されたことを特徴とする汚泥用脱水助剤。
A plurality of fibers are aggregated, and have a plurality of recesses extending along the longitudinal direction of the fibers on the outer peripheral surface of each fiber,
The recess sludge for dewatering aid muscle which acts as a moisture transport path for transporting the sludge water is characterized by being formed extend along the longitudinal direction of the fiber by capillary action when the sludge is in contact .
前記繊維状物又は繊維は、再生セルロース繊維であることを特徴とする、請求項1又は2に記載の汚泥用脱水助剤。 The fibrous material or fibers, characterized in that it is a regenerated cellulose fiber, the sludge for dewatering aid according to claim 1 or 2. 前記繊維状物又は繊維は、含水率が30〜80質量%の範囲にあることを特徴とする請求項1〜3の何れか1項に記載の汚泥用脱水助剤。 The sludge dewatering aid according to any one of claims 1 to 3, wherein the fibrous material or fiber has a moisture content in a range of 30 to 80 mass%. 前記繊維状物又は繊維は、1mm〜50mmの繊維長と、1μm〜100μmの繊維径とを有することを特徴とする、請求項1〜4の何れか1項に記載の汚泥用脱水助剤。 The fibrous material or fibers, and a fiber length of 1 mm to 50 mm, and having a fiber diameter of 1 m to 100 m, the sludge for dewatering aid according to any one of claims 1-4. 前記繊維状物又は繊維は、その断面形状がY型、X型、T型のいずれかに形成されていることを特徴とする、請求項1〜5のいずれか1項に記載の汚泥用脱水助剤。The sludge dehydration according to any one of claims 1 to 5, wherein the fibrous material or fiber has a cross-sectional shape formed in any of Y-type, X-type, and T-type. Auxiliary. 前記繊維状物又は繊維は、隣接する凸部の頂点を結ぶ接線と凹部の最深部の頂点までの距離が0.1〜5μmの範囲に形成されていることを特徴とする、請求項1〜6のいずれか1項に記載の汚泥用脱水助剤。The said fibrous material or fiber is formed in the range of 0.1-5 micrometers in the distance to the tangent which connects the vertex of an adjacent convex part, and the vertex of the deepest part of a recessed part, It is characterized by the above-mentioned. The dewatering aid for sludge according to any one of 6 above. 前記繊維は、乾燥状態での比重が1.4以上であることを特徴とする、請求項1〜7のいずれか1項に記載の汚泥用脱水助剤。   The dewatering aid for sludge according to any one of claims 1 to 7, wherein the fiber has a specific gravity in a dry state of 1.4 or more. 高分子凝集剤を有機性汚泥に添加して、有機性汚泥を凝集させた後、加圧脱水又は機械脱水する汚泥の脱水方法において、
繊維状物の横断面外周面に形成された凸部と凹部が、長手方向に沿って延在し、当該凹部は、汚泥が接触する際に毛細管作用により水分を移送する水分移送路として形成され、当該繊維状物が複数集合して成る汚泥用脱水助剤と、高分子凝集剤と、を含有する脱水助剤含有高分子凝集剤液を、有機性汚泥に添加して、
当該有機性汚泥を凝集させた後、加圧脱水又は機械脱水することを特徴とする汚泥の脱水方法。
In the dewatering method of sludge, which adds a polymer flocculant to organic sludge and coagulates the organic sludge, followed by pressure dewatering or mechanical dewatering,
Protrusions and recesses formed on the outer peripheral surface of the cross-section of the fibrous material extend along the longitudinal direction, and the recesses are formed as a moisture transfer path that transfers moisture by capillary action when the sludge contacts. In addition, a dehydration aid-containing polymer flocculant liquid containing a sludge dehydration aid comprising a plurality of the fibrous materials and a polymer flocculant is added to the organic sludge,
A method for dewatering sludge characterized by coagulating the organic sludge and then dehydrating under pressure or mechanically .
高分子凝集剤を有機性汚泥に添加して、有機性汚泥を凝集させた後、加圧脱水又は機械脱水する汚泥の脱水方法において、
複数の繊維が集合してなり、各繊維の外周面に繊維の長手方向に沿って延在する複数の凹部を有し、当該凹部は、汚泥が接触する際に毛細管作用により汚泥水分を移送する水分移送路として作用する筋が繊維の長手方向に沿って延在して形成されている汚泥用脱水助剤と、高分子凝集剤と、を含有する脱水助剤含有高分子凝集剤液を、有機性汚泥に添加して、
当該有機性汚泥を凝集させた後、加圧脱水又は機械脱水することを特徴とする汚泥の脱水方法。
In the dewatering method of sludge, which adds a polymer flocculant to organic sludge and coagulates the organic sludge, followed by pressure dewatering or mechanical dewatering,
A plurality of fibers are aggregated, and each fiber has a plurality of recesses extending along the longitudinal direction of the fibers, and the recesses transfer sludge moisture by capillary action when the sludge contacts. sludge for dewatering aid muscle which acts as a moisture transport passage is formed by extending in the longitudinal direction of the fibers, and polymer coagulant, the dehydrating aid containing polymer flocculant solution containing, Add to organic sludge,
A method for dewatering sludge characterized by coagulating the organic sludge and then dehydrating under pressure or mechanically .
前記凝集工程と前記加圧脱水又は機械脱水工程との間に、凝集した有機性汚泥を濾過濃縮する濾過濃縮工程とをさらに具備することを特徴とする請求項9又は10に記載の汚泥脱水方法。The sludge dewatering method according to claim 9 or 10, further comprising a filtration concentration step for filtering and condensing the aggregated organic sludge between the aggregation step and the pressure dehydration or mechanical dehydration step. . 有機性汚泥に高分子凝集剤を添加して凝集フロックを形成し、当該凝集フロックを加圧脱水又は機械脱水する汚泥の脱水装置であって、
当該有機性汚泥を貯留する汚泥貯留槽と、
当該有機性汚泥に高分子凝集剤を添加して凝集フロックを形成させる凝集槽と、
当該凝集フロックを脱水する加圧脱水機又は機械脱水機と、
当該高分子凝集剤を調製する高分子凝集剤溶解装置と、
繊維状物の横断面外周面に形成された凸部と凹部が、長手方向に沿って延在し、当該凹部は、汚泥が接触する際に毛細管作用により水分を移送する水分移送路として形成され、当該繊維状物が複数集合して成る汚泥用脱水助剤を、有機性汚泥に添加する脱水助剤供給機と、を具備し、
当該脱水助剤供給機は、当該汚泥貯留槽、当該凝集槽、又は当該高分子凝集剤溶解装置の少なくとも1に、当該脱水助剤を供給し、
当該凝集槽にて、当該高分子凝集剤溶解装置から高分子凝集剤が添加され、当該汚泥用脱水助剤と混合され、
当該脱水助剤を含む凝集フロックを加圧脱水機又は機械脱水機で脱水することで、安定した脱水処理を可能とすることを特徴とする、汚泥脱水装置。
A sludge dewatering device that forms a coagulation floc by adding a polymer flocculant to organic sludge, pressurizing or mechanically dehydrating the coagulation floc,
A sludge storage tank for storing the organic sludge;
A coagulation tank in which a polymer flocculant is added to the organic sludge to form an aggregate floc;
A pressure dehydrator or a mechanical dehydrator for dewatering the aggregated floc;
And a polymeric flocculant dissolution apparatus for preparing the polymeric flocculant,
Protrusions and recesses formed on the outer peripheral surface of the cross-section of the fibrous material extend along the longitudinal direction, and the recesses are formed as a moisture transfer path that transfers moisture by capillary action when the sludge contacts. A dewatering aid supply machine for adding a sludge dewatering aid composed of a plurality of the fibrous materials to organic sludge ,
The dehydration aid feeder supplies the dehydration aid to at least one of the sludge storage tank, the coagulation tank, or the polymer coagulant dissolving apparatus,
In the coagulation tank, the polymer coagulant is added from the polymer coagulant dissolving device, mixed with the sludge dewatering aid,
A sludge dewatering apparatus characterized in that a stable dewatering treatment can be performed by dewatering the agglomerated floc containing the dewatering aid with a pressure dewatering machine or a mechanical dewatering machine .
有機性汚泥に高分子凝集剤を添加して凝集フロックを形成し、当該凝集フロックを脱水する汚泥の脱水装置であって、
当該有機性汚泥を貯留する汚泥貯留槽と、
当該有機性汚泥に高分子凝集剤を添加して凝集フロックを形成させる凝集槽と、
当該凝集フロックを脱水する加圧脱水機又は機械脱水機と、
当該高分子凝集剤を調製する高分子凝集剤溶解装置と、
複数の繊維が集合してなり、各繊維の外周面に繊維の長手方向に沿って延在する複数の凹部を有し、当該凹部は、汚泥が接触する際に毛細管作用により汚泥水分を移送する水分移送路として作用する筋が繊維の長手方向に沿って延在して形成されている汚泥用脱水助剤を、有機性汚泥に添加する脱水助剤供給機と、を具備し、
当該脱水助剤供給機は、少なくとも当該高分子凝集剤溶解装置に、当該脱水助剤を供給し、
当該凝集槽には、脱水助剤と高分子凝集剤とを混合した脱水助剤含有高分子凝集剤液が添加され、
当該脱水助剤を含む凝集フロックを加圧脱水機又は機械脱水機で脱水することで、汚泥含水率を低減させることを特徴とする、汚泥脱水装置。
A sludge dewatering device that forms a floc floc by adding a polymer flocculant to organic sludge, and dewaters the flocs.
A sludge storage tank for storing the organic sludge;
A coagulation tank in which a polymer flocculant is added to the organic sludge to form an aggregate floc;
A pressure dehydrator or a mechanical dehydrator for dewatering the aggregated floc;
And a polymeric flocculant dissolution apparatus for preparing the polymeric flocculant,
A plurality of fibers are aggregated, and each fiber has a plurality of recesses extending along the longitudinal direction of the fibers, and the recesses transfer sludge moisture by capillary action when the sludge contacts. sludge for dewatering aid muscle which acts as a moisture transport passage is formed by extending in the longitudinal direction of the fibers, comprising the dehydrating aid supplier to be added to the organic sludge, a,
The dehydration aid supply machine supplies the dehydration aid to at least the polymer flocculant dissolving apparatus ,
A dehydration aid-containing polymer flocculant liquid in which a dehydration aid and a polymer flocculant are mixed is added to the coagulation tank,
A sludge dewatering device characterized in that the moisture content of sludge is reduced by dewatering the coagulated floc containing the dewatering aid with a pressure dehydrator or a mechanical dehydrator .
前記凝集槽と前記加圧脱水機又は機械脱水機との間に、凝集した有機性汚泥を濾過濃縮する濾過濃縮部が設けられていることを特徴とする請求項12又は13に記載の汚泥脱水装置。 The sludge dewatering according to claim 12 or 13, wherein a filtration and concentration unit for filtering and condensing the condensed organic sludge is provided between the coagulation tank and the pressure dehydrator or the mechanical dehydrator. apparatus.
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