JP2011162372A - Hydrogen production system - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a compact hydrogen production system having high responsiveness to load fluctuation and promptly producing hydrogen. <P>SOLUTION: The hydrogen production system 1 is loaded in a vehicle and includes an internal combustion engine 10 for driving which generates a reformed gas containing hydrogen, carbon monoxide and steam by rich combustion of fuel for the vehicle, and a shift reactor 51 with a built-in water gas shift catalyst 51c which causes carbon monoxide and steam contained in the reformed gas from the internal combustion engine 10 to be subjected to a water gas shift reaction to thereby generate hydrogen and carbon dioxide. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a hydrogen production system that easily reforms a fuel for a vehicle and produces hydrogen in a high yield.

  Hydrogen is clean energy and is expected to be used in the future as an energy source for internal combustion engines and fuel cells. With respect to the internal combustion engine, research on a hydrogen engine, a hydrogenation engine, a NOx purification catalyst that purifies NOx using hydrogen as a reducing agent, and the like is underway (see Patent Document 1). In addition, with regard to the supply of hydrogen to internal combustion engines and fuel cells, research on hydrogen production by fuel reforming is underway.

JP 2006-105088 A

  By the way, when fuel reforming is performed on a vehicle, it is important that the hydrogen production system is small in size so that it can be easily mounted on the vehicle, that the response to load fluctuations is high, and that hydrogen can be produced quickly. .

  Therefore, an object of the present invention is to provide a hydrogen production system that is small in size, has high responsiveness to load fluctuations, and can quickly produce hydrogen.

  Here, the inventor of the present application diligently studied the production of hydrogen from fuel for vehicles. (1) First, the fuel was richly burned in the internal combustion engine, and a part of the fuel was replaced with hydrogen, carbon monoxide and Converting to reformed gas containing water vapor, (2) Stabilizing hydrogen by continuously reforming fuel by converting water monoxide and water vapor to water and carbon dioxide to convert to hydrogen and carbon dioxide As a result, the inventors have obtained the knowledge that they can be produced in a high yield.

  Based on such knowledge, as a means for solving the above-mentioned problems, the present invention is a hydrogen production system mounted on a vehicle, in which fuel for the vehicle is richly burned to generate hydrogen, carbon monoxide and water vapor. An internal combustion engine for generating a reformed gas containing water, and an aqueous solution that generates hydrogen and carbon dioxide by causing a water gas shift reaction between carbon monoxide and water vapor contained in the reformed gas from the internal combustion engine A hydrogen production system comprising: a shift reactor including a gas shift catalyst.

  According to such a hydrogen production system, (1) the internal combustion engine richly burns the fuel for the vehicle and generates a reformed gas containing hydrogen, carbon monoxide, and water vapor. Then, (2) the water gas shift catalyst incorporated in the shift reactor generates hydrogen and carbon dioxide by causing a water gas shift reaction between carbon monoxide and water vapor. Thus, according to the hydrogen production system, hydrogen can be easily produced on the vehicle.

  That is, the internal combustion engine for driving mounted on the vehicle is used to reform the fuel for the vehicle to constitute a hydrogen production system, that is, a reformer or hydrogen tank only for reforming the fuel is installed. Since it is not provided, the number of parts of the hydrogen production system is small and inexpensive, the hydrogen production system is downsized, and can be easily mounted on a vehicle. Also, control of the reformer (temperature control or the like) becomes unnecessary.

  Further, since the operating state of the driving internal combustion engine follows the load fluctuation, the generation of the reformed gas by the internal combustion engine can easily cope with the load fluctuation and the response to the load fluctuation is enhanced.

  Further, in order to cause the water gas shift reaction, it is necessary to raise the water gas shift catalyst to a predetermined temperature. However, since the high temperature reformed gas generated in the internal combustion engine is supplied to the water gas shift catalyst, the water gas shift catalyst is promptly used. The water gas shift reaction becomes possible by raising the temperature. That is, it becomes possible to produce hydrogen quickly in a short time.

  In the hydrogen production system, the internal combustion engine includes a rich combustion cylinder and a normal combustion cylinder.

  According to such a hydrogen production system, since the internal combustion engine includes the rich combustion cylinder and the normal combustion cylinder, the rich combustion in the rich combustion cylinder and the normal combustion cylinder in the internal combustion engine. The normal combustion in can also be performed simultaneously.

  In the hydrogen production system, the reformed gas from the internal combustion engine is supplied, and a catalytic reactor containing a three-way catalyst, and the reformed gas from the internal combustion engine to the shift reactor or the catalytic reactor And a flow rate control means for controlling the flow rate.

  According to such a hydrogen production system, the flow rate of the reformed gas from the internal combustion engine to the shift reactor or the catalytic reactor can be controlled by the flow rate control means. Therefore, for example, if the flow rate of the reformed gas toward the shift reactor is increased, the temperature of the water gas shift catalyst can be increased.

  The hydrogen production system further includes first temperature control means for controlling the temperature of the water gas shift catalyst.

  According to such a hydrogen production system, the first temperature control means controls the temperature of the water gas shift catalyst, thereby controlling the water gas shift reaction and controlling the amount of hydrogen produced.

  The hydrogen production system further comprises an A / F control means for controlling an A / F (air / fuel ratio) of rich combustion in the internal combustion engine.

  According to such a hydrogen production system, the A / F control means controls the amount of carbon monoxide and water vapor in the reformed gas by controlling the rich combustion A / F, thereby producing hydrogen. You can control the amount.

  The hydrogen production system further includes second temperature control means for controlling the temperature of the reformed gas from the internal combustion engine toward the shift reactor.

  According to such a hydrogen production system, since the second temperature control means controls the temperature of the reformed gas from the internal combustion engine to the shift reactor, the temperature of the water gas shift catalyst can be controlled. As a result, the amount of hydrogen produced can be controlled.

  In the hydrogen production system, the internal combustion engine is supplied with at least one of air, oxygen-enriched air, nitrogen-enriched air, oxygen, carbon dioxide, and EGR gas as a modifier. Features.

  According to such a hydrogen production system, the internal combustion engine is supplied with air, oxygen-enriched air, nitrogen-enriched air, oxygen, carbon dioxide, and EGR (Exhaust Gas Recirculation) gas supplied as a modifier. The reformed gas can be produced by richly burning the fuel in at least one kind of atmosphere.

  The hydrogen production system further includes a mixer that mixes hydrogen generated in the shift reactor and fresh intake air and supplies the mixture to the internal combustion engine.

  According to such a hydrogen production system, the hydrogen produced in the shift reactor and the new intake air are mixed by a mixer to obtain a uniform mixed state, which can then be supplied to the internal combustion engine. Therefore, combustion in the internal combustion engine is stabilized.

  In the hydrogen production system, the rich combustion in the internal combustion engine and the water gas shift reaction in the shift reactor are continuously performed.

  According to such a hydrogen production system, the rich combustion in the internal combustion engine and the water gas shift reaction in the shift reactor are performed not continuously, but continuously, so that hydrogen can be generated continuously.

  According to the present invention, it is possible to provide a hydrogen production system that is small in size, has high responsiveness to load fluctuations, and can quickly produce hydrogen.

It is a figure showing the composition of the hydrogen production system concerning this embodiment. It is a sectional side view of the mixer concerning this embodiment. When the internal combustion engine is richly burned at 72 Nm / 1500 rpm, (a) is a graph showing the relationship between the crank angle and the in-cylinder pressure, and (b) is a graph showing the relationship between the crank angle and the heat generation rate. is there. When the internal combustion engine is richly burned at 140 Nm / 1500 rpm, (a) is a graph showing the relationship between the crank angle and the in-cylinder pressure, and (b) is a graph showing the relationship between the crank angle and the heat generation rate. is there. 7 is a graph showing the relationship between A / F and the hydrogen concentration and carbon monoxide concentration in the reformed gas when the internal combustion engine is richly burned at 72 Nm / 1500 rpm. 6 is a graph showing the relationship between A / F and the hydrogen concentration and carbon monoxide concentration in the reformed gas when the internal combustion engine is richly burned at 140 Nm / 1500 rpm.

  Hereinafter, an embodiment of the present invention will be described with reference to FIGS.

≪Configuration of hydrogen production system≫
A hydrogen production system 1 according to this embodiment shown in FIG. 1 is mounted on a vehicle (not shown).
The hydrogen production system 1 includes an internal combustion engine 10, first to second injectors 21 to 24 that inject fuel into the internal combustion engine 10, an intake system that guides air outside the vehicle to the internal combustion engine 10, and exhaust gas generated by the internal combustion engine 10. An exhaust system that guides gas to the outside of the vehicle, a shift reaction system that generates hydrogen by a water gas shift reaction of the reformed gas generated in the internal combustion engine 10, and an ECU 60 (Electronic Control Unit, electronic control device) that is a control means for electronically controlling these. ) And.

  Then, the hydrogen production system 1 (1) reforms the fuel in the first cylinder 11 described later of the internal combustion engine 10 to generate a reformed gas containing hydrogen, carbon monoxide, and water vapor, and (2) shift reaction. A shift reactor 51 (water gas shift catalyst) described later in the system is characterized in that carbon monoxide and water vapor in the reformed gas undergo a water gas shift reaction to generate (manufacture) hydrogen and carbon dioxide.

Here, the fuel is a fuel for vehicles, and specifically, hydrocarbons such as gasoline, diesel fuel, alcohol, natural gas, propane gas, and biodiesel. The hydrocarbons include alkanes, alkenes, alkynes, aromatic compounds and the like.
The first cylinder 11 for rich combustion of the internal combustion engine 10 has at least one selected from air, oxygen-enriched air, nitrogen-enriched air, oxygen, water vapor, carbon dioxide, and EGR gas as a modifier. Is supplied.

<Internal combustion engine>
The internal combustion engine 10 is a power source that generates the driving force of the vehicle, and its operating condition (rotational speed) follows the load fluctuation well. Therefore, the generation of the reformed gas by the first cylinder 11 described later also follows the load fluctuation well. Here, the internal combustion engine 10 according to the present embodiment is a diesel internal combustion engine with inline 4-cylinder and displacement of 2 L, and self-ignites when fuel is injected into the cylinder and compressed.
However, the number of cylinders, the arrangement, and the displacement are not limited to this and can be changed freely. The type of the internal combustion engine 10 is not limited to a diesel internal combustion engine, and can be appropriately selected from known internal combustion engines. Furthermore, the ignition system in the internal combustion engine 10 is not limited to the self-ignition system by compression, but may be, for example, a spark ignition system using a spark plug.

The internal combustion engine 10 includes a first cylinder 11 to a fourth cylinder 14. The first cylinder 11 is assigned for rich combustion or normal combustion, and the second cylinder 12, the third cylinder 13 and the fourth cylinder 14 are assigned for normal combustion. Thereby, the internal combustion engine 10 can simultaneously perform the rich combustion in the first cylinder 11 and the normal combustion in the second cylinder 12 to the fourth cylinder 14 in parallel.
However, the number of cylinders for rich combustion or normal combustion and the number of cylinders for normal combustion are not limited to this and can be changed freely.

<Injector>
The first injector 21 to the fourth injector 24 inject a desired amount of fuel into the first cylinder 11 to the fourth cylinder 14. In addition, the fuel of a fuel tank (not shown) is pressure-fed and supplied to the first injector 21 to the fourth injector 24 via a common rail (not shown) by a fuel pump (not shown). .

The first injector 21 is provided in the first cylinder 11, the second injector 22 is provided in the second cylinder 12, the third injector 23 is provided in the third cylinder 13, and the fourth injector 24 is provided in the fourth cylinder 14. In addition, the fuel injection amount (injection time) of the first injector 21 to the fourth injector 24 is independently controlled by the ECU 60. That is, the first injector 21 to the fourth injector 24 are appropriately controlled in accordance with the flow rate of new intake air or the like corresponding to the opening of the throttle valve 32 described later, so that the first cylinder 11 to the first cylinder The A / F (air / fuel) ratio in the four cylinders 14 is individually controlled.
In the present embodiment, the first injector 21 is controlled so that rich combustion or normal combustion is performed in the first cylinder 11, and the second injector 22 to the fourth injector 24 are the second cylinder 12 to the fourth cylinder. 14 is controlled to perform normal combustion.

  Therefore, in this embodiment, the A / F control means for controlling the rich combustion A / F in the first cylinder 11 includes the first injector 21, the throttle valve 32, and the ECU 60. Then, the rich combustion A / F in the first cylinder 11 is controlled, so that the amount of reformed gas (hydrogen, carbon monoxide, water vapor) produced is controlled. As a result, the production of hydrogen in the shift reactor 51 is controlled. The amount is also controlled.

<Intake system>
The intake system includes an air cleaner 31 that removes dust and the like, a throttle valve 32, a mixer 33, and an intake manifold 34 that is branched into four branches on the downstream side. From the air cleaner 31, the pipe 31 a, the throttle valve 32, the pipe 32 a, the mixer 33, the pipe 33 a, and the intake manifold 34 are connected in this order. Each is connected to the fourth cylinder 14.

When the internal combustion engine 10 is operated, the air outside the vehicle is naturally sucked and goes to the mixer 33 through the pipe 31a and the like.
The pipe 32a is joined by a pipe 51a from the shift reactor 51, which will be described later, and hydrogen and carbon dioxide generated by the water gas shift reaction join with the newly sucked air and go to the mixer 33. The internal combustion engine 10 is hydrogenated.

  The throttle valve 32 is constituted by a butterfly valve or the like, and the opening degree of the throttle valve 32 is controlled by the ECU 60 to control the flow rate of new intake air from the outside of the vehicle.

<Mixer>
The mixer 33 (gas mixer) mixes air newly sucked from the outside of the vehicle with hydrogen and carbon dioxide from the shift reactor 51 to obtain a uniform mixed state, and then introduces the intake manifold 34 (first cylinders 11 to 11). The fourth cylinder 14) is supplied. In this way, a uniform mixed state is supplied to the first cylinder 11 and the like, so that combustion in the first cylinder 11 and the like is stabilized and knocking or the like is difficult.

As shown in FIG. 2, the mixer 33 according to the present embodiment splits, converts, and inverts new intake air flowing through the interior, hydrogen and carbon dioxide from the shift reactor 51, It mixes efficiently.
Specifically, the mixer 33 includes a cylindrical casing 33b, a plurality of (three in FIG. 2) right elements 33c (right swirl vanes), and a plurality (three in FIG. 2) left elements 33d. (Left swirl blade).

  And in the housing | casing 33b, it arrange | positions alternately like the right element 33c, the left element 33d, the right element 33c, ... downstream. The right element 33c is a blade that turns new intake air or the like in the downstream direction, and the left element 33d is a blade that turns left. Such right element 33c and left element 33d are formed by twisting a rectangular plate material to the right or left at 180 °. The length L1 in the flow direction of the right element 33c and the left element 33d is designed to be 1.5 times the diameter D1 (L1 = 1.5 × D1), for example.

<Exhaust system>
Returning to FIG. 1, the description will be continued.
The exhaust system includes an exhaust manifold 41 whose upstream side branches into three branches and a catalytic reactor 42. The second cylinder 12, the third cylinder 13, and the fourth cylinder 14 are connected to the catalytic reactor 42 via an exhaust manifold 41 and a pipe 42a, and the exhaust generated in the second cylinder 12 to the fourth cylinder 14 is connected. The gas is collected in the exhaust manifold 41 and then supplied to the catalytic reactor 42 through the pipe 42a.

<Catalytic reactor>
The catalytic reactor 42 has a built-in three-way catalyst 42c that purifies NOx in the exhaust gas. The three-way catalyst 42c is supported on the inner wall surface of a cordierite honeycomb body by a wash coat method or the like. As shown in Table 1, the three-way catalyst 42c is formed of, for example, a (Pt-Pd-Rh + rare earth) system, its reaction temperature is 250 to 700 (° C.), and the space velocity is 5000 to 100,000 ( h- ¹ ). The reaction temperature of the three-way catalyst 42c is a temperature at which the three-way catalyst 42c exhibits its catalytic function well, and the space velocity (GHSV) is the gas velocity per hour. is there.

The three-way catalyst 42c oxidizes carbon monoxide (CO) in the exhaust gas to generate carbon dioxide (CO ₂ ) (see formula (1) in Table 1). Further, the three-way catalyst 42c decomposes HC (hydrocarbon) in the exhaust gas to generate water vapor (H ₂ O) and carbon dioxide (CO ₂ ) (see formula (2) in Table 1). Further, the three-way catalyst 42c reduces nitrogen oxide (NOx) in the exhaust gas to generate nitrogen (N ₂ ) (see formula (3) in Table 1).

  The exhaust gas from which nitrogen oxide (NOx) has been purified in this way is exhausted outside the vehicle through the pipe 42b.

<Shift reaction system>
The shift reaction system includes a shift reactor 51, flow rate control valves 52 to 53, a temperature sensor 54, and a heater 55 (first temperature control means). The first cylinder 11 is connected to the shift reactor 51 via a pipe 52a, a flow control valve 52, and a pipe 52b, and the reformed gas (hydrogen, monoxide) generated by rich combustion in the first cylinder 11 is connected. Carbon, water vapor) is supplied to the shift reactor 51 through the pipe 52a and the like.

<Shift reactor>
The shift reactor 51 incorporates a water gas shift catalyst 51c that generates hydrogen and carbon dioxide by causing a water gas shift reaction of carbon monoxide and water vapor in the reformed gas (see equation (4) in Table 1). As with the three-way catalyst 42c, the water gas shift catalyst 51c is supported on the inner wall surface of a cordierite honeycomb body by a wash coat method or the like. As shown in Table 1, such a water gas shift catalyst 51c is formed of, for example, (Fe—Cr system + Cu—Zn system), the reaction temperature is 150 to 500 (° C.), and the space velocity is 5000 to 100,000. It is designed to (h ⁻¹ ). That is, the reaction temperature of the water gas shift catalyst 51c is designed to be lower than the reaction temperature of the three-way catalyst 42c.

The pipe 52a is connected to the pipe 42a through the pipe 53a, the flow control valve 53, and the pipe 53b.
The flow rate control valves 52 and 53 are valves that can control the flow rate including 0 in accordance with a command from the ECU 60, and are constituted by needle valves, for example. Thus, the flow rate of the reformed gas from the first cylinder 11 toward the catalytic reactor 42 or the shift reactor 51 can be appropriately controlled by appropriately controlling the opening degree of the flow rate control valves 52 and 53. Specifically, for example, if the flow control valve 53 is fully closed and the flow control valve 52 is fully opened, all of the high-temperature reformed gas can be directed to the shift reactor 51, and the shift reactor 51 can be quickly turned on. Can warm up.

  The temperature sensor 54 is a sensor that detects the temperature of the water gas shift catalyst 51 c and is provided in the vicinity of the shift reactor 51. The temperature sensor 54 outputs the detected temperature to the ECU 60.

  The heater 55 is an electric heater that controls the temperature of the water gas shift catalyst 51c, is provided in the vicinity of the shift reactor 51, and is connected to a power source 57 via an inverter 56 controlled by the ECU 60. The ECU 60 controls the inverter 56, whereby the output (heat amount) of the heater 55 is controlled. As a result, the temperature of the water gas shift catalyst 51c is controlled.

<ECU>
The ECU 60 is a control device that electronically controls the hydrogen production system 1, and includes a CPU, a ROM, a RAM, various interfaces, an electronic circuit, and the like, and exhibits various functions in accordance with programs stored therein. And control various devices.

≪Operation and effect of hydrogen production system≫
Next, the operation and effect of the hydrogen production system 1 will be described.
According to the hydrogen production system 1, (1) the fuel is richly burned by the first cylinder 11, and a reformed gas containing hydrogen, carbon monoxide and water vapor is continuously generated, and (2) the water gas shift catalyst 51c is used. Carbon monoxide and water vapor can be subjected to a water gas shift reaction to continuously generate hydrogen and carbon dioxide.

In addition, the hydrogen production system 1 reforms the fuel using the driving internal combustion engine 10 and does not include a reformer or a hydrogen tank. Therefore, the hydrogen production system 1 is reduced in size and can be easily mounted on a vehicle.
Furthermore, since the high temperature reformed gas generated by rich combustion is supplied to the shift reactor 51, the temperature of the water gas shift catalyst 51c can be quickly increased.

  As mentioned above, although one Embodiment of this invention was described, this invention is not limited to this, It can change as follows.

In the above-described embodiment, the configuration in which the fuel is directly injected into the first cylinder 11 to the fourth cylinder 14 of the internal combustion engine 10 is exemplified. However, for example, an intake chamber is provided between the mixer 33 and the intake manifold 34. It is good also as a structure which injects and vaporizes fuel in the gas (background gas) containing the new intake air which flows through in this intake chamber. That is, the fuel injection method may be either in-cylinder injection or intake port injection.
In addition, when injecting a fuel into background gas in this way, it is preferable to set A / F in the range of 5-14. This is because when the oxygen concentration in the background gas increases, hydrogen generated by the water gas shift reaction is oxidized with oxygen to become water, and there is a possibility that the hydrogen recovery rate may be lowered.

  In the above-described embodiment, the configuration in which the temperature of the water gas shift catalyst 51c is directly controlled by the heater 55 (first temperature control means) disposed in the vicinity of the shift reactor 51 is exemplified. A heater (second temperature control means) is provided in the vicinity of 52b, and the temperature of the reformed gas flowing through the pipe 52b is controlled by this heater, so that the temperature of the water gas shift catalyst 51c is indirectly controlled. Good.

  In the above-described embodiment, the reformed gas is continuously generated by the rich combustion in the first cylinder 11, and the hydrogen is continuously generated by the water gas shift reaction in the shift reactor 51 (water gas shift catalyst 51c). Although illustrated, for example, a configuration in which reformed gas and hydrogen are generated in a batch manner may be used.

  Hereinafter, based on an Example, this invention is demonstrated further more concretely.

(1) Range of A / F that burns normally Diesel internal combustion engine was tested for whether or not it burned normally by injecting light oil directly into the cylinder of the internal combustion engine while changing A / F. A / F was in the range of 10-18. The test results are shown in FIGS.
FIG. 3A shows the pressure in the cylinder with respect to the crank angle in the case of rich combustion at 72 Nm / 1500 rpm, and FIG. 3B shows the heat generation rate with respect to the crank angle. 4A shows the pressure in the cylinder with respect to the crank angle when rich combustion is performed at 140 Nm / 1500 rpm, and FIG. 4B shows the heat generation rate with respect to the crank angle.

  As shown in FIGS. 3 (a) to 4 (b), even when the A / F is changed within the range of 10 to 18, the waveform of the pressure in the cylinder and the waveform of the heat generation rate are almost changed. I did not. Thereby, even if rich combustion was performed, it turned out that it burns normally until AF = 10 grade.

(2) A / F and hydrogen concentration and carbon monoxide concentration in reformed gas Next, the relationship between A / F and the hydrogen concentration and carbon monoxide concentration in the reformed gas was tested. A / F was in the range of 10-18. The test results are shown in FIGS.
5 shows the hydrogen concentration and carbon monoxide concentration in the reformed gas with respect to A / F in the case of rich combustion at 72 Nm / 1500 rpm, and FIG. 6 shows the case of rich combustion at 140 Nm / 1500 rpm. Fig. 2 shows the hydrogen concentration and carbon monoxide concentration in the reformed gas with respect to A / F.

  As shown in FIG. 5 to FIG. 6, under any condition, when A / F decreases, the hydrogen concentration and carbon monoxide concentration in the reformed gas tend to increase. Under any of the conditions, when the A / F was about 10, the hydrogen concentration was 2 mol% and the carbon monoxide concentration was about 10 mol%.

(3) Water gas shift reaction Next, the water gas shift reaction of carbon monoxide and water vapor | steam (steam) was carried out using the water gas shift catalyst 51c.
The space velocity (GHSV) is 10,000 (h ⁻¹ ), the volume ratio of carbon monoxide to water vapor is 1: 2, and the temperature of the mixed gas of carbon monoxide and water vapor at the inlet of the water gas shift catalyst 51c is 300 ° C. , And.

  And when the composition of the gas discharged | emitted from the water gas shift catalyst 51c was analyzed, it turned out that 71% of carbon monoxide is converted into hydrogen.

(4) Summary In summary, when the internal combustion engine 10 is richly burned at A / F = 10, (1) a reformed gas containing 2 mol% hydrogen, 10 mol% carbon monoxide is generated, (2) When this reformed gas is subjected to a water gas shift reaction, 70% of carbon monoxide is converted to hydrogen, and 7.1 mol% (= 10 × 0.71) of hydrogen is generated. (3) Overall hydrogen production system 1 As a result, it was confirmed that 9.1 mol% (= 2 + 7.1) of hydrogen was obtained, and it was confirmed that hydrogen could be produced easily and in a high yield.

DESCRIPTION OF SYMBOLS 1 Hydrogen production system 10 Internal combustion engine 21 1st injector (A / F control means)
32 Throttle valve (A / F control means)
33 Mixer 42 Catalytic reactor 42c Three-way catalyst 51 Shift reactor 51c Water gas shift catalyst 52, 53 Flow control valve 55 Heater (first temperature control means)
70 ECU (control means)

Claims (9)

A hydrogen production system mounted on a vehicle,
An internal combustion engine for driving that burns rich fuel for vehicles and generates reformed gas containing hydrogen, carbon monoxide, and water vapor;
A shift reactor containing a water gas shift catalyst that generates hydrogen and carbon dioxide by causing a water gas shift reaction of carbon monoxide and water vapor contained in the reformed gas from the internal combustion engine;
A hydrogen production system comprising: The hydrogen production system according to claim 1, wherein the internal combustion engine includes a rich combustion cylinder and a normal combustion cylinder. A catalytic reactor which is supplied with reformed gas from the internal combustion engine and contains a three-way catalyst;
A flow rate control means for controlling the flow rate of the reformed gas from the internal combustion engine toward the shift reactor or the catalytic reactor;
The hydrogen production system according to claim 1 or 2, characterized by comprising: The hydrogen production system according to any one of claims 1 to 3, further comprising first temperature control means for controlling a temperature of the water gas shift catalyst. 5. The hydrogen production system according to claim 1, further comprising an A / F control unit that controls an A / F of rich combustion in the internal combustion engine. The hydrogen production system according to any one of claims 1 to 5, further comprising second temperature control means for controlling the temperature of the reformed gas from the internal combustion engine toward the shift reactor. The internal combustion engine is supplied with at least one of air, oxygen-enriched air, nitrogen-enriched air, oxygen, carbon dioxide, and EGR gas as a modifier. Item 7. The hydrogen production system according to any one of Items 6. The hydrogen production according to any one of claims 1 to 7, further comprising a mixer that mixes hydrogen generated in the shift reactor and fresh intake air and supplies the mixture to the internal combustion engine. system. The hydrogen production system according to any one of claims 1 to 8, wherein the rich combustion in the internal combustion engine and the water gas shift reaction in the shift reactor are continuously performed.

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