JP2011084484A - Cleanser composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cleanser composition that causes low irritation of the skin or hair, forms rich, smooth bubbles at washing, exerts high rinsing property and smoothness at rinsing and, after use, gives moderate feeling of residue remaining and imparts smoothness and moistness to the skin or hair. <P>SOLUTION: The cleanser composition includes (A) an amphoteric surfactant represented by formula (1) (wherein: R<SP>1</SP>is 8C-20C alkyl group; R<SP>2</SP>is hydrogen atom or 1C-2C alkyl group; and n is an integer of 1-4) and (B) one or more cationized sugar derivative chosen from cationized locust bean gum, cationized tara gum and cationized starch. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a cleaning composition.

  Conventionally, various surfactants have been proposed as cleaning bases for the purpose of cleaning skin and hair. These cleaning bases are required to have various performances other than mere surface-active ability, for example, to improve moisture to skin and hair, to reduce irritation, or to reduce discoloration of dyed hair For the purpose, amino acid-derived anionic surfactants and amphoteric surfactants are used (Patent Documents 1 and 2). In addition, cationized polymers are used for the purpose of imparting flexibility and smoothness (for example, Patent Documents 3 to 5).

JP 2006-22085 A Japanese Patent Laid-Open No. 2000-204035 JP 2004-203799 A JP 2004-203803 A JP 2005-272359 A

However, these conventional cleaning agents have low irritation to the skin and hair, feel and foam quality at the time of washing, rinsing and sliding properties at the time of rinsing, and moisturizing and smoothness to the skin and hair after washing. Not all of them were satisfied at the same time.
Therefore, the object of the present invention is to suppress irritation to the skin and hair, to realize a rich and smooth foam at the time of washing, to give rinsing properties and slipperiness at the time of rinsing, and to have an appropriate after-feel and smoothness after use. An object of the present invention is to provide a cleaning composition that provides a moist feeling.

  Therefore, the present inventors have studied to develop a detergent that simultaneously satisfies the above four characteristics. As a result, the carbobetaine type amphoteric surfactant having an N-hydroxyethyl group and an N-hydroxyalkyl group, a cationized cellulose, Even though the combination with a cationic polymer does not provide a sufficient effect, it is quite surprising that a carbobetaine-type amphoteric surfactant having an N-hydroxyethyl group and an N-hydroxyalkyl group has a specific cationic property. When combined with a sugar derivative, a detergent composition that is hypoallergenic, achieves a rich and smooth foam with excellent foam quality and foam volume, and is excellent in use feeling after rinsing and after use. As a result, the present invention was completed.

That is, the present invention includes the following components (A) and (B):
(A) Amphoteric surfactant represented by the following general formula (1)

(In the formula, R ¹ represents an alkyl group having 8 to 20 carbon atoms, R ² represents a hydrogen atom or an alkyl group having 1 to 2 carbon atoms, and n represents an integer of 1 to 4)
(B) Provided is a detergent composition containing one or more cationic sugar derivatives selected from cationized locust bean gum, cationized tara gum and cationized starch.

  The cleaning composition of the present invention suppresses irritation to skin and hair, realizes a rich and smooth foam at the time of washing, provides rinsing properties and slipping properties at the time of rinsing, and has a moderate after-feel, smoothness after use. In addition, it has an excellent feeling of use that provides a moist feeling.

Hereinafter, the configuration of the present invention will be described in detail.
The amphoteric surfactant of the component (A) used in the present invention is represented by the following general formula (1), has both a cationic group and an anionic group in the molecule, and has a hydroxyalkyl group in its structure. It is a carbobetaine type amphoteric surfactant having a structure of hydroxyethyl group.

(In the formula, R ¹ represents an alkyl group having 8 to 20 carbon atoms, R ² represents a hydrogen atom or an alkyl group having 1 to 2 carbon atoms, and n represents an integer of 1 to 4)

In general formula (1), the alkyl group represented by R ¹ is preferably an alkyl group having 10 to 18 carbon atoms, and more preferably an alkyl group having 10 to 14 carbon atoms. These alkyl groups may be linear or branched. R ² is preferably a methyl group or an ethyl group. n is preferably an integer of 1 to 3, particularly preferably 1 or 2. More preferable combinations of R ² and n are R ² = CH ₃ , n = 1 (N-methylglycine (sarcosine)), R ² = H, n = 2 (β-alanine). Among these, the case where R ² = CH ₃ and n = 1 is particularly preferable. Commercially available products of these components (A) include Anholex MA-1 (manufactured by Sanyo Kasei Co., Ltd.), Softazoline LMEB (manufactured by Kawaken Fine Chemical Co., Ltd.) and the like.

  Moreover, although a component (A) may be used independently, you may use 2 or more types together. The content of the component (A) in the present invention is preferably 0.05 to 20% by mass (hereinafter simply referred to as%), more preferably 0.1 to 10% in the total amount of the cleaning composition. If it is in this range, smoothness during washing and rich foaming are obtained, which is preferable.

Component (B) used in the present invention is one or more selected from cationized locust bean gum, cationized cod gum and cationized starch, and is a cationic sugar derivative in which a cation group is added to a saccharide or polysaccharide. It is.
Among these components (B), it is preferable to use cationized locust bean gum or cationized tara gum.
These cationic saccharide derivatives have a structure in which a part of the hydroxyl group contained in the saccharide is substituted with a quaternary nitrogen-containing group, preferably a quaternary ammonium group. For example, by reacting a saccharide with a quaternary ammonium salt such as glycidyl trialkylammonium salt or 3-halogeno-2-hydroxypropyltrialkylammonium salt and introducing a quaternary ammonium group into a part of the hydroxyl group of the saccharide. Obtainable.
Commercially available products of these components (B) include cationized locust bean gum (Catinal CLB-100; manufactured by Toho Chemical Co., Ltd.), cationized starch (Sensomer CI-50; manufactured by Nalco Japan Co., Ltd.), and cationized tara gum (Catinal CTR). -100; manufactured by Toho Chemical Co., Ltd.).

  Moreover, a component (B) may be used independently, but 2 or more types may be used together. The content of the component (B) in the present invention is preferably 0.05 to 2%, more preferably 0.1 to 1% in the total amount of the cleaning composition. Within this range, rich foaming and excellent foam quality are obtained, which is preferable.

  In the cleaning composition of the present invention, the content ratio (A: B) of the component (A) and the component (B) is from the viewpoint of the performance after suppressing irritation, cleaning, rinsing and after cleaning. 100: 1 to 1: 1 is preferable, and 100: 1 to 2: 1 is more preferable.

The cleaning composition of the present invention is characterized in that the component (A) and the specific cationized sugar derivative (B) are combined, and (C) cationized cellulose, cationized guar gum, and cationization. By including one or more selected from honey and cationized fenugreek gum, effects such as smoothness at the time of washing, moisture after rinsing, and an appropriate feeling of after-remaining can be enhanced.
Here, fenugreek gum is a polysaccharide obtained from the endosperm of the seed of the leguminous plant Koroha (scientific name: Trigonella Foenum-Graecum).
In these cationized cellulose, cationized guar gum, cationized honey, and cationized fenugreek gum, a part of hydroxyl groups contained in cellulose, guar gum, honey, and fenugreek gum are quaternary nitrogen-containing groups, preferably quaternary ammonium groups. The structure is substituted with For example, a quaternary ammonium salt such as glycidyl trialkylammonium salt or 3-halogeno-2-hydroxypropyltrialkylammonium salt is reacted with cellulose or guar gum, and a quaternary ammonium group is added to a part of the hydroxyl groups of cellulose or guar gum. It can be obtained by introduction.
Commercially available products of these components (C) include cationized cellulose (poise C-60H; manufactured by Kao Corporation), cationized guar gum (Jaguar C-14S; manufactured by Rhodia Corporation), cationized honey (Honeyquat 50; manufactured by GSI Creos). Etc.), cationized fenugreek gum (Catinal CF-100; manufactured by Toho Chemical Co., Ltd.) and the like.

Moreover, although a component (C) may be used independently, you may use 2 or more types together. The content of the component (C) in the present invention is preferably 0.02 to 2%, more preferably 0.05 to 1%, most preferably 0.1 to 0.5% in the total amount of the cleaning composition. is there. If it is in this range, the smoothness at the time of washing | cleaning, the moisture after a rinse, and a suitable after-feeling feeling are obtained and it is preferable.
Moreover, it is preferable that these components (C) contain 0.1-10 mass parts with respect to 1 mass part of component (B) from the point of the smoothness at the time of washing | cleaning, the moisture after a rinse, and a moderate after-residence feeling. .

In addition to the above essential components, the cleaning composition of the present invention contains an anionic surfactant and one or more selected from amphoteric surfactants not corresponding to the component (A), and further cleaning. Strength, foaming power, and feeling of use are improved. Examples of the anionic surfactant include fatty acid soap, alkyl sulfate type surfactant, alkyl ether sulfate type surfactant, olefin sulfonate type surfactant, phosphate ester type surfactant, alkyl ether carboxylate Type surfactants, amino acid salt type surfactants (sarcosine salt type, β-alanine salt type, glutamate type, aspartate type, etc.), sulfosuccinate type surfactants, taurine type surfactants, etc. . Examples of amphoteric surfactants other than the component (A) include sulfobetaine type amphoteric surfactants, alkylbetaine type amphoteric surfactants, amidopropyl betaine type amphoteric surfactants, imidazolinium betaine type amphoteric surfactants, and the like. Is mentioned.
The lipophilic group of these surfactants may be linear or branched, or may be partially modified with other functional groups, and is usually an acyl group or an alkyl group. A straight chain or branched chain having an average carbon number of 8 to 22 is preferably used. Further, these surfactants may have an alkylene oxide structure, an amide structure, a hydroxyl group, or the like in the molecule. These surfactants can be used singly or in combination of two or more, and it is usually preferable to contain 0.1 to 50% in the total amount of the detergent composition.

  The cleaning composition of the present invention can be used as a body cleaning agent and a hair cleaning agent, but when used as a hair cleaning agent, the above-described effects after washing, rinsing and after washing are more prominent. This is preferable.

  In addition to the above components, the cleaning composition of the present invention can use any component that is normally used as long as it does not impair the effects of the present invention. Examples of these components include cationic surfactants, nonionic surfactants, fatty acids, silicones, oils, extracts, preservatives, moisturizers, polymers, amino acid derivatives, sugar derivatives, fragrances, water, Examples include alcohol, thickener, colorant, sequestering agent, antioxidant, and drug.

  Next, although the present invention is explained in detail based on an example, the present invention is not limited to this. All compounding amounts are mass%.

  The test methods described in the examples are as follows.

Test Example 1 (Evaluation of smoothness during hair washing)
Chinese hair (8 g / 20 cm) was immersed in 8% aqueous hydrogen peroxide for 30 minutes to perform a bleaching treatment. Each hair was immersed in a cleaning composition aqueous solution containing 5% of the following control hair shampoo, or a cleaning composition aqueous solution containing 5% of the hair shampoo shown in Table 1 below. Brushing with a brushing tester (manufactured by Techno Hashimoto) at the time of rinsing (12 times of brushing while rinsing), measuring the load according to the comb during shampooing, and evaluating "smoothness during shampooing" using the following evaluation criteria did.

Evaluation criteria ◎: Very good compared to control ○: Good compared to control △: Slightly good compared to control ×: Equivalent or bad compared to control

Test Example 2 (Evaluation of feeling of use, finishing, and irritation when washing hair: half head method)
“Smoothness” when the panel (30 persons) divided the hair into left and right halves, applied the control hair shampoo described in (Table 1) on one side, and the hair shampoo shown in Table 2 on the other side, and washed the hair at the same time. , “Foam amount / foam quality”, “Rinse”, “Slippery (smooth feeling)”, “Moisture feeling” after drying hair and “Remaining feeling after rest” using the following criteria evaluated. Moreover, the irritation | stimulation property at the time of hair washing was evaluated using the following reference | standard.

Evaluation criteria (feeling of using and finishing when washing hair)
◎: More than 25 people answered that it was better than control ○: 20-24 people answered that it was better than control △: 16-19 people answered that it was better than control ×: Number of people who said it was better than control 15 or less

Evaluation criteria (irritant)
◎: No more than 1 person replied that they felt irritation during hair washing ○: 2 to 3 persons replied that i felt irritation during hair washing △: 4-5 persons replied that i felt irritation during hair washing ×: Hair washing More than 6 people answered that they sometimes felt irritation

Examples 1-9, Comparative Examples 1-8 (hair shampoo)
A hair shampoo having the composition shown in Tables 2 and 3 was prepared according to a conventional method, and the above Test Examples 1 and 2 were evaluated. The results are shown in Tables 2 and 3 together.

As is clear from Tables 2 and 3, the hair shampoos of Examples 1 to 9 were used to dry the hair after washing the hair smoothness, foam amount / foam quality, rinsing property, slipperiness (smooth feeling) at the time of washing the hair. It was extremely excellent in feeling of use such as a moist feeling after a lingering feeling, a feeling of remaining after, and a lack of irritation.
On the other hand, a combination of an anionic surfactant derived from an amino acid and the component (B) (Comparative Example 1) or a combination of an amphoteric surfactant other than the component (A) and the component (B) (Comparative Examples 2 and 3). However, a sufficient effect was not obtained. Moreover, sufficient effect was not acquired even with the combination (Comparative Examples 4-8) of the component (A) and cationized cellulose, cationized guar gum, cationized fenugreek gum, a cationic polymer, or cationized hyaluronic acid.

Example 10 Hair Shampoo

Ingredient name Compounding amount (%)

POE (2) sodium lauryl ether sulfate 5.0
POE (3) sodium lauryl ether acetate 5.0
Hydroxyalkyl hydroxyethyl sarcosine (same as Table 2) 5.0
1,3-butylene glycol 2.0
Lauric acid monoisopropanolamide 1.0
Ethylene glycol distearate 2.0
POE cetyl ether 1.0
(Product name: N-BC-15TX [manufactured by Nippon Surfactant])
Cationized cellulose 0.2
(Product name: Leo Guard GP [Lion Corporation])
Cationized locust bean gum 0.2
(Product name: Kachinar CLB-100 [manufactured by Toho Chemical Co., Ltd.])
Edetate disodium 0.2
Phenoxyethanol 0.2
Sodium benzoate 0.4
Dimethyldiallylammonium chloride / acrylamide copolymer solution 0.5
(Product name: Marcote 550 [Calgon Co., Ltd.])
Dipotassium glycyrrhizate 0.1
Isopropylmethylphenol 0.1
Citric acid appropriate amount carrot extract 0.1
(Product name: carrot extract BG [Maruzen Pharmaceutical Co., Ltd.])
Oat extract 0.1
(Product name: Aoba Liquid B [Ichimaru Falcos])
Olive oil 0.1
Dimethiconol 1.0
Menthol 0.1
Perfume Appropriate amount Purified water Residual

  A hair shampoo having the above composition was adjusted by a conventional method (pH 6/25 ° C.), and according to Test Examples 1 and 2, the hair smoothness, the amount of foam / foam quality, the rinsing property, and the slipperiness (smooth feeling) during hair washing, When the feeling of moisture after drying the hair after shampooing, the feeling of aftertaste, and the feeling of use such as lack of irritation were evaluated, all of them showed good results.

Example 11 Hair Shampoo

Ingredient name Compounding amount (%)

Ammonium lauryl sulfate 5.0
Lauric acid amidopropyl betaine solution 3.0
Lauroylmethyl-β-alanine sodium solution 3.0
Hydroxyalkylhydroxyethylalanine (same as Table 2) 4.0
Dipropylene glycol 4.0
Palm oil fatty acid monoethanolamide 1.0
Ethylene glycol distearate 1.5
Cationized honey 0.1
(Product name: Honeyquat50 [GSI Creos Co., Ltd.])
Cationized guar gum 0.3
(Product name: Jaguar C-13S [manufactured by Rhodia])
Cationized tara gum 0.1
(Product name: Kachinar CTR-100 [Toho Chemical Co., Ltd.])
Edetate disodium 0.2
Phenoxyethanol 0.1
Sodium benzoate 0.4
Dimethyldiallylammonium chloride / acrylamide copolymer solution 2.0
(Product name: Marcote 550 [manufactured by Ondeo Nalco])
L-alanine 0.1
Glycine 0.1
Hydroxypropyltrimonium hydrolyzed silk 0.1
(Product name: Promois Silk-1000Q [manufactured by Seiwa Kasei Co., Ltd.])
Citric acid appropriate amount Honey 0.1
Hydrolyzed conchiolin 0.1
(Brand name: Pearl protein extract BG-J [Maruzen Pharmaceutical Co., Ltd.])
Murasakichi Extract 0.1
(Product name: Murasakichi extract (Maruzen Pharmaceutical Co., Ltd.))
Hydrolyzed wheat 0.1
(Product name: Gluadin AGP [manufactured by Ichimaru Falcos])
Dimethiconol 1.0
Dimethicone 0.5
Perfume Appropriate amount Purified water Residual

  A hair shampoo having the above composition was adjusted by a conventional method (pH 6/25 ° C.), and according to Test Examples 1 and 2, the hair smoothness, the amount of foam / foam quality, the rinsing property, and the slipperiness (smooth feeling) during hair washing, When the feeling of moisture after drying the hair after shampooing, the feeling of aftertaste, and the feeling of use such as lack of irritation were evaluated, all of them showed good results.

Example 12 Hair Shampoo

Ingredient name Compounding amount (%)

Palm kernel oil fatty acid amidopropyl betaine 10.0
Hydroxyalkyl hydroxyethyl sarcosine (same as Table 2) 6.0
Glycerin 3.0
Lauryl glycol hydroxypropyl ether 0.5
Palm oil fatty acid diethanolamide 3.0
Cationized locust bean gum 0.05
(Product name: Kachinar CLB-100 [manufactured by Toho Chemical Co., Ltd.])
Cationized cellulose 0.3
(Product name: CELQUAT SC-230M [made by NSC Japan])
Edetate disodium 0.2
Phenoxyethanol 0.3
Sodium benzoate 0.4
Hibiscus flower extract 0.1
(Product name: Phyto Fleur Hibiscus [made by Croda])
Evening primrose seed extract 0.1
(Product name: Luna White B [made by Ichimaru Falcos])
Pomegranate extract 0.1
(Brand name: Pomegranate fruit extract B [Ikeda Sakka Kogyo Co., Ltd.])
Citric acid appropriate amount Fragrance appropriate amount Purified water Residual

  A hair shampoo having the above composition was adjusted by a conventional method (pH 6/25 ° C.), and according to Test Examples 1 and 2, the hair smoothness, the amount of foam / foam quality, the rinsing property, and the slipperiness (smooth feeling) during hair washing, When the feeling of moisture after drying the hair after shampooing, the feeling of aftertaste, and the feeling of use such as lack of irritation were evaluated, all of them showed good results.

Example 13 Hair Shampoo

Ingredient name Compounding amount (%)

Cocoyl Methyl Taurine Taurine Sodium 2.0
Hydroxyalkyl hydroxyethyl sarcosine (same as Table 2) 18.0
Diglycerin 2.0
Lauric acid monoethanolamide 3.0
Cationized fenugreek gum 0.05
(Product name: Kachinar CF-100 [Toho Chemical Co., Ltd.])
Cationized cellulose 0.1
(Product name: Kachinar LC-200 [manufactured by Toho Chemical Co., Ltd.])
Cationized starch 0.2
(Product name: Sensomer CI-50 [manufactured by Nalco Japan])
Edetate disodium 0.2
Phenoxyethanol 0.3
Sodium benzoate 0.4
Chamomile flower extract 0.1
(Product name: Camisole Liquid MD [made by Ichimaru Falcos])
Cornflower extract 0.1
(Product name: Falco Rex cornflower B [made by Ichimaru Falcos])
Yukinoshita extract 0.1
(Product name: Yukinoshita Extract BG [Maruzen Pharmaceutical Co., Ltd.])
Citric acid appropriate amount Fragrance appropriate amount Purified water Residual

  A hair shampoo having the above composition was adjusted by a conventional method (pH 6/25 ° C.), and according to Test Examples 1 and 2, the hair smoothness, foam amount / foam quality, rinsing properties, and slipperiness (smooth feeling) during hair washing, When the feeling of moisture after drying the hair after shampooing, the feeling of aftertaste, and the feeling of use such as lack of irritation were evaluated, all of them showed good results.

Example 14 Hair Shampoo

Ingredient name Compounding amount (%)

Lauroyl sarcosine triethanolamine 10.0
Palm oil fatty acid amidopropyl betaine 6.0
Hydroxyalkyl hydroxyethyl sarcosine (same as Table 2) 0.5
Glycerin 3.0
Lauryl glycol hydroxypropyl ether 0.5
Palm oil fatty acid monoisopropanolamide 3.0
Cationized tara gum 0.2
(Product name: Kachinar CTR-100 [Toho Chemical Co., Ltd.])
Cationized guar gum 0.3
(Product name: Labor Gum CG-M [Dainippon Sumitomo Pharma Co., Ltd.])
Edetate disodium 0.2
Phenoxyethanol 0.3
Sodium benzoate 0.4
Rose water 0.1
(Product name: Rose extract [manufactured by Koei Kogyo Co., Ltd.])
Brown algae extract 0.1
(Product name: Arge Colloid [Yamakawa Trading Co., Ltd.])
Citric acid appropriate amount Fragrance appropriate amount Purified water Residual

  A hair shampoo having the above composition was adjusted by a conventional method (pH 6/25 ° C.), and according to Test Examples 1 and 2, the hair smoothness, foam amount / foam quality, rinsing properties, and slipperiness (smooth feeling) during hair washing, When the feeling of moisture after drying the hair after shampooing, the feeling of aftertaste, and the feeling of use such as lack of irritation were evaluated, all of them showed good results.

Example 15 Body Shampoo

Ingredient name Compounding amount (%)

Hydroxyalkyl hydroxyethyl sarcosine (same as Table 2) 10.0
Lauryl sulfate triethanolamine 5.0
Lauric acid amidopropyl betaine 3.0
N-coconut oil fatty acid acyl-DL-alanine triethanolamine 0.5
POE cetyl ether 1.0
(Product name: N-BC-10TX [made by Nippon Surfactant])
Lauric acid monoisopropanolamide 0.2
POE cetostearyl hydroxymyristyl ether 1.0
(Product name: Elfacos GT282S [manufactured by Akzo])
Ethylene glycol distearate 1.0
Cationized starch 0.3
(Product name: Sensomer CI-50 [manufactured by Narco])
Cationized tara gum 0.2
(Product name: Kachinar CTR-100 [Toho Chemical Co., Ltd.])
Dimethyldiallylammonium chloride / acrylamide copolymer solution 1.0
(Product name: Marcote 550 [Nalco])
Edetate disodium 0.2
Salicylic acid 0.1
Paraben 0.1
Phenoxyethanol 0.2
Lemon extract 0.1
(Product name: Lemon extract [manufactured by Koei Kogyo Co., Ltd.])
Kiwi extract 0.1
(Product name: Kiwi extract [manufactured by Koei Kogyo Co., Ltd.])
Acerola extract 0.1
(Product name: Nichirei Acerola Extract WB [manufactured by Nichirei Bioscience)]
Citric acid appropriate amount Fragrance appropriate amount Purified water Residual

  A hair shampoo having the above composition was adjusted by a conventional method (pH 6/25 ° C.), and according to Test Examples 1 and 2, the hair smoothness, the amount of foam / foam quality, the rinsing property, and the slipperiness (smooth feeling) during hair washing, When the feeling of moisture after drying the hair after shampooing, the feeling of aftertaste, and the feeling of use such as lack of irritation were evaluated, all of them showed good results.

Example 16 Body Soap

Ingredient name Compounding amount (%)

Lauric acid 6.0
Myristic acid 6.0
Palmitic acid 5.0
Hydroxyalkyl hydroxyethyl sarcosine (same as Table 2) 7.0
Palm oil fatty acid monoisopropanolamide 2.0
Cationized fenugreek gum 0.2
(Product name: Kachinar CF-100 [manufactured by Toho Chemical Industry Co., Ltd.])
Cationized guar gum 0.1
(Product name: Jaguar C-162 [manufactured by Rhodia)]
Cationized locust bean gum 0.2
(Product name: Kachinar CLB-100 [manufactured by Toho Chemical Co., Ltd.])
Acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer solution 1.0
(Product name: Marcote Plus 3330 [manufactured by Nalco])
Dimethyldiallylammonium chloride / acrylamide copolymer solution 1.0
(Product name: Marcote 550 [Nalco])
Ethylene glycol distearate 2.0
Hydroxypropyl methylcellulose 0.5
Propylene glycol 5.0
Concentrated glycerin 2.0
Edetate disodium 0.2
Phenoxyethanol 0.1
Apricot juice 0.1
(Product name: Hormo Fruit Apricot [manufactured by Koei Kogyo Co., Ltd.])
Hydrolyzed silk 0.1
(Product name: Promois Silk-1000P [manufactured by Seiwa Kasei Co., Ltd.])
Hydrolyzed collagen 0.1
(Product name: Promois W-52MD5 [manufactured by Seiwa Kasei Co., Ltd.])
Peach leaf extract 0.1
(Product name: Peach extract [Maruzen Pharmaceutical Co., Ltd.])
Camellia oil 0.1
(Product name: Refined cocoon oil [manufactured by Yokoseki Oil & Fat Co., Ltd.])
Potassium hydroxide appropriate amount Fragrance appropriate amount Purified water Residual

  A hair shampoo having the above composition was adjusted by a conventional method (pH 6/25 ° C.), and according to Test Examples 1 and 2, the hair smoothness, foam amount / foam quality, rinsing properties, and slipperiness (smooth feeling) during hair washing, When the feeling of moisture after drying the hair after shampooing, the feeling of aftertaste, and the feeling of use such as lack of irritation were evaluated, all of them showed good results.

Example 17 Face Wash

Ingredient name Compounding amount (%)

Lauric acid 5.0
Myristic acid 20.0
Stearic acid 2.0
Hydroxyalkylhydroxyethylalanine (same as Table 2) 5.0
Palm oil fatty acid monoethanolamide 2.0
POE cetyl ether 1.0
(Product name: N-BC-15TX [manufactured by Nippon Surfactant])
Glycerol isostearate 1.0
Cationized tara gum 0.5
(Product name: Kachinar CTR-100 [Toho Chemical Industry Co., Ltd.])
Coconut oil fatty acid methyl taurine sodium 1.0
Acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer solution 1.0
(Product name: Marcote Plus 3330 [manufactured by Nalco])
Ethylene glycol distearate 1.0
Concentrated glycerin 30.0
Phenoxyethanol 0.1
Hypericum extract 0.1
(Product name: Hypericum extract (manufactured by Koei Kogyo Co., Ltd.))
Royal Jelly Extract 0.1
(Product name: Royal Jelly Extract B [Ikeda Sakka Kogyo Co., Ltd.])
Brown sugar extract 0.1
(Product name: Coct Oligo Pure III [manufactured by Yamakawa Trading Co., Ltd.])
Grapefruit extract 0.1
(Product name: Falco Rex Grapefruit B [Ichimaru Falcos])
Giant extract 0.1
(Product name: Falco Rex Zio B [Ichimaru Falcos])
Potassium hydroxide appropriate amount Fragrance appropriate amount Purified water Residual

  A hair shampoo having the above composition was adjusted by a conventional method (pH 6/25 ° C.), and according to Test Examples 1 and 2, the hair smoothness, the amount of foam / foam quality, the rinsing property, and the slipperiness (smooth feeling) during hair washing, When the feeling of moisture after drying the hair after shampooing, the feeling of aftertaste, and the feeling of use such as lack of irritation were evaluated, all of them showed good results.

  The present invention suppresses irritation to the skin and hair, achieves a rich and smooth foam when washing, gives rinsing and slipping properties when rinsing, and has a moderate after-feel, smoothness and moisture after use. The resulting cleaning composition can be provided.

Claims (4)

The following components (A) and (B):
(A) General formula (1)

(In the formula, R ¹ represents an alkyl group having 8 to 20 carbon atoms, R ² represents a hydrogen atom or an alkyl group having 1 to 2 carbon atoms, and n represents an integer of 1 to 4)
(B) A detergent composition containing one or more cationic sugar derivatives selected from cationized locust bean gum, cationized tara gum, and cationized starch. The detergent composition according to claim 1, wherein the amphoteric surfactant of (A) contains an N-methylglycine (sarcosine) structure represented by R ² = CH ₃ and n = 1 in the general formula (1). .   The cleaning composition according to claim 1 or 2, wherein the cleaning composition is for hair.   The detergent composition according to any one of claims 1 to 3, further comprising (C) one or more selected from cationized cellulose, cationized guar gum, cationized honey, and cationized fenugreek gum. .