JP2010132619A - Water-in-oil type solid makeup cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a water-in-oil type solid makeup cosmetic that has a high internal water phase ratio to allow good serviceability and exhibits good emulsion stability though it is a water-in-oil type solid emulsified cosmetic exhibiting good makeup sustainability and having an emollient effect on the skin. <P>SOLUTION: The water-in-oil type solid makeup cosmetic includes the following components (A), (B), (C) and (D), and satisfies the requirements (1) and (2) below. Components: (A) glycerine monoisostearate; (B) an aqueous component; (C) an oily component containing a solid oily component; and (D) a powder. Requirements: (1) The internal water phase ratio which is obtained by dividing the sum of the mass of the component (A) and the component (B), the aqueous component, by the sum of the mass of the component (A), the component (B), the aqueous component, and the component (C), the oily component, is at least 50%. (2) The purity of (A) glycerine monoisostearate is at least 90 mass% based on the total amount of glycerine monoisostearate, glycerine diisostearate and glycerine triisostearate. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a water-in-oil solid makeup cosmetic, and more particularly to the realization of improved stability in water-in-oil emulsions and the accompanying improvement in usability.

Conventionally, as a type of solid makeup cosmetics, it is generally used as a solidified oil type in which oil is solidified with wax, a specific oily solidifying agent, a hydrophobized powder, water, and a lipophilic surfactant. There is a solid water-in-oil type emulsified type (for example, see Patent Document 1), a specific wax ester and an amphoteric surfactant, and an oil-in-water solid cosmetic obtained by combining higher fatty acids. It is used properly according to usage. Of these, the oil-based type and the water-in-oil emulsified type are inferior in terms of “freshness” and “freshness”, but are excellent in long-lasting makeup. On the other hand, the oil-in-water emulsification type has a fresh feeling of use, but has disadvantages such as the limit of makeup.
Therefore, the actual condition is that a solid emulsified makeup composition having a feeling of use such as “freshness” and “smoothness” and also having good cosmetic durability has not been obtained.

  In general, water-in-oil emulsions with an oil phase as the outer phase and an aqueous phase as the inner phase can efficiently spread oil-soluble active ingredients such as emollient oil, oil-soluble drugs, and UV absorbers on the skin. Therefore, it is a dosage form suitable as an external preparation for skin, and is superior to the oil-in-water type in this respect. In addition, one of the characteristics is that a dosage form with a long makeup can be obtained by blending the hydrophobic powder.

  Further, the ratio of the inner aqueous phase obtained by dividing the amount of the inner aqueous phase component by the total amount of the emulsion has a great influence on the properties of the emulsion, particularly in the cosmetics containing the emulsion. Specifically, when the internal water phase ratio is increased, a refreshing and good feeling of use can be given, and when the internal water phase ratio is low, an oily feel is obtained. Therefore, in the water-in-oil type emulsion composition, it is considered that the one having an increased internal water phase ratio is an ideal base.

However, in a normal water-in-oil solid makeup composition, when the internal water phase ratio is increased, it becomes difficult to maintain stability at around 50%. This is because the water molecules that make up the emulsified particles in the inner aqueous phase migrate and are absorbed by other emulsified particles (Ostwal Dryening), and the emulsified particles are more This is because coalescence of the emulsified particles occurs due to a significant increase in the collision frequency. In addition, since the emulsifying system is thermodynamically non-equilibrium, in order to stabilize it so that it can be utilized industrially, the amount of emulsifier, the ratio of the internal water phase, the type and amount of the aqueous component, the oil content There was a limit to the use of the type and amount thereof, and the type and amount of other stabilizers.
In other words, the water-in-oil type solid emulsified cosmetics that have good makeup and emollient effects on the skin have a high internal water phase ratio in order to give them a freshness and refreshment. It was difficult to keep.
JP-A-1-143812

As a result of devising the surfactant used to increase the internal water phase ratio, the conventional method has a sticky feeling and has a problem in usability, and is stable while maintaining a high internal water phase ratio. In order to maintain the quality, there are restrictions on the types of oils to be blended, and the quality of the cosmetics is not always satisfactory.
The present invention has been made in view of the above-mentioned problems of the prior art, and is a water-in-oil type solid emulsified cosmetic having a good makeup and having an emollient effect on the skin. It is an object of the present invention to provide a water-in-oil solid makeup cosmetic that has a good ratio and good emulsion stability.

  As a result of intensive studies to solve the above-mentioned problems, the present inventors have identified (A) glycerin monoisostearate having a small amount of impurities, (C) an oil component containing a solid oil, and (D) a powder. It was found that the water-in-oil solid makeup cosmetics contained in the above ratio have good makeup and good emulsification stability, and the present invention has been completed.

  That is, the water-in-oil solid makeup cosmetic according to the present invention includes the following components (A), (B), (C), and (D), and further satisfies the following conditions (1) and (2): And Ingredient: (A) glyceryl monoisostearate, (B) aqueous component, (C) oily component containing solid oil, (D) powder, condition: (1) the mass of the aqueous component of component (B), component (B) The internal water phase ratio obtained by dividing by the sum of the mass of the aqueous component and the oil component of component (C) is 50% or more. (2) The purity of glyceryl monoisostearate is 90% by mass or more.

  In addition, it is preferable that the water-in-oil solid makeup cosmetic further contains (E) tetramethyltrihydroxyhexadecane.

In the water-in-oil solid makeup cosmetic, the mass of the component (A) is preferably 0.8 to 4.0% by mass with respect to the total mass.
In the water-in-oil solid makeup cosmetic, the component (C) oily component preferably contains isostearic acid or sorbitan sesquiisostearate.
In the water-in-oil solid makeup cosmetic, the mass of the component (D) powder is preferably 10 to 20% by mass relative to the total amount of the cosmetic.

  In the method for producing a water-in-oil solid makeup cosmetic, it is preferable that (E) tetramethyltrihydroxyhexadecane is further mixed during the oil phase adjustment step.

The water-in-oil solid makeup cosmetic according to the present invention is a mixture of (A) glycerin monoisostearate with a small amount of impurities, (C) an oil component containing a solid oil, and (D) a powder in a specific ratio. Make-up cosmetics with a high internal water phase ratio, good emulsification stability, good makeup, excellent emollient effect on the skin, and high internal water phase ratio. Is also excellent.
Furthermore, by adding (E) tetramethyltrihydroxyhexadecane, the emulsion stability is further improved.

  The water-in-oil solid makeup cosmetic according to the present invention comprises (A) glyceryl monoisostearate, (B) an aqueous component, (C) an oily component containing a solid oil, (D) a powder, and (1 ) The internal water phase ratio obtained by dividing the mass of the aqueous component of component (B) by the sum of the mass of the aqueous component of component (B) and the oily component of component (C) is 50% or more, (2 ) The condition that the glycerin monoisostearate purity is 90% by mass or more is satisfied. Hereinafter, each component will be described in detail.

  The component (A) glyceryl monoisostearate can be provided by various known synthetic methods. According to the usual synthesis method, it is produced as a mixture of glyceryl monoisostearate, glyceryl diisostearate, and glyceryl triisostearate. The component (A) glyceryl monoisostearate constituting the water-in-oil solid makeup cosmetic according to the present invention preferably has a high purity. As a purification method of glyceryl monoisostearate, a molecular distillation method is usually used, but is not limited thereto.

  The glycerin fatty acid diester and glycerin fatty acid triester contained as impurities of the component (A) are less than 10% by mass relative to the total amount of the component (A). While glyceryl monooleate has a function as a surfactant (emulsifier), glycerin dioleate and glycerin trioleate behave as oils. Therefore, when the purity of glyceryl monoisostearate is low, the emulsion behaves as if glycerin diisostearate and glyceryl triisostearate were blended as oil components in addition to the oil component of component (C). That is, the purity of glyceryl monoisostearate is low, and glycerin fatty acid diester and / or glycerin fatty acid triester contained as an impurity of component (A) as a kind of oil blended as an oil component of component (C) When it exceeds 10 mass% with respect to the whole quantity of (A), stability of an emulsion will be impaired. In addition, the purity of glyceryl monoisostearate can be measured by general methods such as gas chromatography (GC), gel permeation chromatography (GPC), and high performance liquid chromatography (HPLC).

  In addition, as a suitable compounding quantity of component (A) glyceryl monoisostearate, it is 0.8-4.0 mass% with respect to cosmetics whole quantity, Preferably it is 1.5-2.5 mass%. If it is 0.8% by mass or less, the stability of the emulsion may be remarkably impaired, and if it exceeds 4.0% by mass, the usability may be inferior.

As the aqueous component of component (B), those that can be usually used for cosmetics, pharmaceuticals, and the like can be blended within a range that does not impair the stability of the emulsion. Examples of the humectant include 1,3-butylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, hexylene glycol, glycerin, diglycerin, xylitol, maltitol, maltose, D-mannitol, and the like. Examples of water-soluble polymers include plant polymers such as gum arabic, carrageenan, pectin, agar, quince seed (malmello), starch, and alge colloid (brown algae extract), microbial polymers such as dextran and pullulan, collagen, and casein. Animal polymers such as gelatin, starch polymers such as carboxymethyl starch and methylhydroxypropyl starch, alginic acid polymers such as sodium alginate, vinyl polymers such as carboxyvinyl polymer (such as CARBOPOL), polyoxyethylene Polymers, polyoxyethylene polyoxypropylene copolymer polymers, acrylic polymers such as sodium polyacrylate and polyacrylamide, inorganic water-soluble polymers such as bentonite, aluminum magnesium silicate, and laponite That.
Examples of UV absorbers include benzoic acid UV absorbers such as paraaminobenzoic acid, anthranilic acid UV absorbers such as methyl anthramylate, salicylic acid UV absorbers such as octyl salicylate and phenyl salicylate, isopropyl paramethoxycinnamate, Cinnamic acid UV absorbers such as octyl paramethoxycinnamate and glyceryl di-2-methoxycinnamate mono-2-ethylhexanoate, 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2- Benzophenone ultraviolet absorbers such as hydroxy-4-methoxybenzophenone-5-sulfonic acid, urocanic acid, 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 4-tert-butyl-4′-methoxybenzoyl There is methane.

Examples of the sequestering agent include sodium edetate, sodium metaphosphate, phosphoric acid and the like.
Examples of the antioxidant include ascorbic acid, α-tocopherol, dibutylhydroxytoluene, butylhydroxyanisole and the like.
Drugs include vitamin A oil, retinol, retinol palmitate, inosit, pyridoxine hydrochloride, benzyl nicotinate, nicotinamide, nicotinic acid DL-α-tocopherol, ascorbic acid magnesium phosphate, ascorbic acid 2-glucoside, vitamin D2 ( Ergocassipherol), dl-α-tocopherol 2-L potassium ascorbate diester potassium salt, dl-α-tocopherol, acetic acid dl-α-tocopherol, pantothenic acid, vitamins such as biotin, anti-inflammation such as allantoin and azulene Agents, whitening agents such as arbutin, astringents such as zinc oxide and tannic acid, sulfur, lysozyme chloride, pyridoxine hydrochloride, γ-oryzanol and the like.
In addition to the above drugs being used in a free state, those capable of salt formation can be used in the form of an acid or base salt, and those having a carboxylic acid group can be used in the form of its ester.

As the oily component of the component (C), a solid oil component can be used as long as it does not impair the stability of the emulsion. The liquid oil is preferably silicone oil, more preferably cyclic silicone oil. Examples of silicone oils include chain silicone oils such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane, and octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane. There are typical cyclic silicone oils.
In addition, about polar oil, it is desirable to mix | blend a small quantity in the range which does not impair the stability of an emulsion. Typical polar oils include cetyl octanoate, hexyl laurate, isopropyl myristate, octyl palmitate, isocetyl stearate, isopropyl isostearate, octyl isopalmitate, isodecyl oleate, 2-ethylhexyl succinate, diethyl sebacate, etc. There are ester oils.
Nonpolar oils include hydrocarbon oils typified by liquid paraffin, squalane, squalene, paraffin, isoparaffin, isododecane, isohexadecane and the like.

  In addition, solid oils contained in the oil component of component (C) include cocoa butter, coconut oil, horse oil, hardened coconut oil, palm oil, beef tallow, sheep fat, hardened castor oil, and the like, paraffin wax ( Straight chain hydrocarbons), microcrystalline wax (branched saturated hydrocarbons), ceresin wax, owl, montan wax, Fischer-Trops wax and other hydrocarbons, beeswax, lanolin, carnauba wax, candelilla wax, rice bran wax (rice wax) ), Gallow, jojoba oil, nukarou, montan wax, kapok wax, bayberry wax, shellac wax, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, hard lanolin, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE core Waxes such as terol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, higher fatty acids such as myristic acid, palmitic acid, stearic acid, behenic acid, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, cetostearyl Higher alcohol such as alcohol can be raised. In addition, 3-10 mass% is preferable with respect to cosmetics whole quantity, and, as for the compounding quantity of solid oil, More preferably, it is 5-8 mass%. If the solid oil content is less than 3% by mass, it will not solidify and the effect of the solid makeup cosmetic will not be exhibited, and if it exceeds 10% by mass, the cosmetic will become heavy.

  The internal water phase ratio of the water-in-oil solid makeup cosmetic in the present invention is 50% or more. When the internal water phase ratio is less than 50%, a refreshing feeling may not be obtained. Furthermore, in the present invention, it is possible to prepare a water-in-oil solid makeup cosmetic having a high internal water phase ratio of 60% or more, and a refreshing feeling can be given. The internal water phase ratio is calculated by dividing the mass of (B) the aqueous component by the total mass of (A) component, (B) aqueous component, and (C) oil component.

  As the powder of component (D), inorganic powders (for example, talc, kaolin, sericite, muscovite, synthetic mica, phlogopite, red mica, biotite, lithia mica, vermiculite, magnesium carbonate, calcium carbonate, diatomaceous earth, silica Magnesium silicate, calcium silicate, aluminum silicate, barium silicate, strontium silicate, metal tungstate, silica, hydroxyapatite, zeolite, boron nitride, ceramic powder, etc .; organic powder (eg polyamide resin powder (nylon powder) ), Polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigment (for example, zinc oxide, etc.) ); Inorganic red pigments (for example, Inorganic purple pigments (eg, mango violet, cobalt violet, etc.); inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (eg, ultramarine blue) Pearl pigments (eg, titanium oxide coated mica, titanium oxide coated bismuth oxychloride chloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc.); metal powder pigments (eg, aluminum powder) , Copper powder, etc.); organic pigments such as zirconium, barium or aluminum lake (for example, red 201, red 202, red 204, red 205, red 220, red 226, red 228, red 405) Orange 203, orange 204, yellow 205, Organic pigments such as yellow 401 and blue 404, red 3, red 104, red 106, red 227, red 230, red 401, red 505, orange 205, yellow 4 and yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3 and Blue No. 1); natural pigments (for example, chlorophyll, β-carotene and the like) and the like.

  In addition, as a suitable compounding quantity of a component (D) powder component, it is 10-30 mass% with respect to cosmetics whole quantity, Preferably it is 15-25 mass%. If it is less than 10% by mass, the covering power of the water-in-oil solid makeup cosmetic may be insufficient, and if it exceeds 30% by mass, the spread may become heavy.

  Component (E), tetramethyltrihydroxyhexadecane (trade name: phytantriol) has four branched chains. The property that these structures bring about during emulsion purification includes prevention of crystallization at low temperatures.

  Further, the water-in-oil solid makeup cosmetic of the present invention can be widely applied to makeup cosmetics conventionally applied to skin, eyebrows, eyelashes, lips, etc. For example, foundation, eye shadow, eye Examples include liners and mascaras.

式中、Ｇ：測定応力（ｇｒ）×９８０ｄｙｎ
Ｌ：サンプルの厚み（ｍｍ）
ｌ：圧縮距離（ｍｍ）
ａ：針の断面積（ｃｍ²） The term “solid” or “solid” used in the present invention indicates that the composition or components do not exhibit fluidity at a temperature of 50 ° C. or lower, and do not exhibit significant deformation even under normal storage conditions. Indicates that it is in a state. More specifically, the term “solid” refers to the following formula when the hardness is measured at 37 ° C. using a hardness meter (rheometer) commonly used in the technical field. The required hardness (γ) is 2 or more.

In the formula, G: measured stress (gr) × 980 dyn
L: Sample thickness (mm)
l: Compression distance (mm)
a: Cross-sectional area of the needle (cm ² )

  The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto. Unless otherwise specified, the blending amount is expressed in mass% with respect to the system in which the component is blended.

Method for preparing water-in-oil solid makeup cosmetic (foundation) Glycerol monoisostearate, an oil component and other oil-soluble components are mixed and heated to about 80 ° C. to dissolve. Disperse the powder in the oil component. The aqueous component and other water-soluble components are mixed, dissolved, and heated to 80 ° C. The water-soluble component parts are gradually added while stirring the oil-soluble component parts relatively strongly.

Evaluation Method for Water-in-oil Solid Makeup Cosmetics The compositions shown in Tables 1 to 5 below were evaluated for emulsion stability, hardness feeling, and phase equilibrium based on the following evaluation criteria.
1. Emulsion stability after production at room temperature Stability was visually evaluated after storage for 1 week at room temperature.
A: Separation of water and / or oil is not observed at all.
○: Slight separation of water and / or oil is observed.
X: Separation of water and / or oil is clearly observed.

2. Hardness Using a hardness meter (RHEO METER: manufactured by FUDOH Kogyo Co., Ltd.), hardness (γ) was measured under the following measurement conditions and evaluated based on the following evaluation criteria.
(Measurement condition)
Load weight: 200g
Needle diameter: 5.6φ
Needle penetration speed: 2 cm / min
Needle penetration distance: 1mm
Measurement temperature: 37 ° C
(Evaluation criteria)
◎: Hardness is 90 or more ○: Hardness is 70 or more and less than 90 Δ: Hardness is 50 or more and less than 70 ×: Hardness is 50 or less

3. Usability (fresh feeling)
Usability was evaluated by 10 professional panels.
A: Evaluated that 9 or more of 10 people are fresh and refreshing.
○: Evaluated as 7 to 8 out of 10 people being fresh and refreshing.
Δ: Evaluated that 4 to 6 out of 10 people were fresh and refreshing.
X: It is evaluated that 3 or less of 10 people are fresh and refreshing.

（＊）：テトラメチルトリヒドロキシヘキサデカン

(*): Tetramethyltrihydroxyhexadecane

As is clear from the results shown in Table 1, in Test Example 1-2 using a conventionally used surfactant, a somewhat stable W / O solid emulsion can be prepared. , You can not get a satisfactory in terms of usability.
On the other hand, in Test Example 1-2 in which the constituent requirement (A) glyceryl monoisostearate of the present invention is used as the surfactant, it has an excellent feeling of use and is a stable W / O solid emulsion. Can be prepared. Further, in Test Example 1-1 in which glyceryl monoisostearate and phytantriol were used in combination, a W / O emulsion having a further excellent stability could be prepared, and the feeling in use was also very good. .
From the above results, as the surfactant used in the water-in-oil solid makeup cosmetic of the present invention, it is W that has high internal water phase ratio and good stability, using glyceryl monoisostearate. It is understood that this is preferred for the preparation of / O type emulsions.
Subsequently, the present inventors examined the relationship between the purity of glyceryl monoisostearate used for the preparation of a high internal water phase specific water-in-oil solid makeup cosmetic and the emulsion stability.

（＊）：テトラメチルトリヒドロキシヘキサデカン

(*): Tetramethyltrihydroxyhexadecane

As shown in Table 2, the amount of glyceryl monoisostearate is 2% by mass and the purity of glyceryl monoisostearate is adjusted to 90% by mass and 30% by mass, respectively, and the purity is a water-in-oil solid makeup. The effects of cosmetics on the phase state and emulsion stability were investigated. Regarding the purity of glycerol monoisostearate of 30% by mass, a commercially available product EMALEX GWIS-100EX (manufactured by Nippon Emulsion Co., Ltd.) was used.
As a result, when the purity of glyceryl monoisostearate is 90% by mass (Test Example 2-1), the composition has excellent emulsion stability, but the purity is 30% by mass (Test Example 2-2). When the purity of glyceryl monoisostearate was lowered, the emulsification stability tended to further decrease.
Then, the present inventors examined the suitable compounding quantity of (A) component used for preparation of the water-in-oil type emulsion cosmetics of this invention.

（＊）：テトラメチルトリヒドロキシヘキサデカン

(*): Tetramethyltrihydroxyhexadecane

As shown in Table 3, in Test Examples 3-1 to 3-3, the blending amount of glycerin monoisostearate as the component (A) was appropriately changed, and each emulsion stability was examined.
As a result, it was found that when glyceryl monoisostearate was blended in the range of 0.8 to 4.0% by mass, excellent usability and emulsion stability were obtained.
Next, the present inventors have further studied the oil component used for maintaining good emulsification stability while being a water-in-oil solid makeup cosmetic with a high internal water phase ratio.

（＊）：テトラメチルトリヒドロキシヘキサデカン

(*): Tetramethyltrihydroxyhexadecane

As shown in Table 4, (C) oily components were fixed to decamethylcyclopentasiloxane, diphenylsiloxyphenyl trimethicone, rice bran wax, and other oily components were changed to adjust the composition, and each emulsion stability was examined. did.
As a result, it was found that when isostearic acid and sorbitan sesquiisostearate were used (Test Examples 4-1 and 4-2), the composition was particularly excellent in emulsion stability.
From the above results, for the preparation of a W / O type emulsion having a high internal water phase ratio and maintaining good stability, it is possible to use isostearic acid and sorbitan sesquiisostearate as the oil component (C). Is more preferable.

  Furthermore, the present inventors have proceeded with investigations on the types of powders to be blended in preparing a water-in-oil solid makeup cosmetic with a high internal water phase ratio and excellent emulsion stability.

（＊）：テトラメチルトリヒドロキシヘキサデカン

(*): Tetramethyltrihydroxyhexadecane

  As shown in Table 5, in the water-in-oil solid makeup cosmetic of the present invention, the types of powders that can be blended are very wide. In addition to the foundation, an eyeliner base (Test Example 5-3), It was found that application to various fields such as eye shadow (Test Example 5-4) is also possible.

Claims (5)

A water-in-oil solid makeup cosmetic comprising the following components (A), (B), (C), and (D), and further satisfying the following conditions (1) and (2):
Component: (A) Glycerol monoisostearate (B) Aqueous component (C) Oily component containing solid oil (D) Powder condition: (1) The mass of the aqueous component of component (B) is expressed as component (A) and component (B ) And the internal water phase ratio obtained by dividing by the sum of the mass of the oil component of component (C) is 50% or more.
(2) The purity of component (A) glycerol monoisostearate is 90% by mass or more based on the total amount of glycerol monoisostearate, glycerol diisostearate, and glycerol triisostearate.   The water-in-oil solid makeup cosmetic according to claim 1, further comprising (E) tetramethyltrihydroxyhexadecane.   The water-in-oil solid makeup cosmetic according to claim 1 or 2, wherein the mass of the component (A) is 0.8 to 4.0 mass% with respect to the total mass. Mold-type makeup cosmetics.   The makeup cosmetic according to any one of claims 1 to 3, wherein the oil component (C) contains isostearic acid or sorbitan sesquiisostearate, a water-in-oil solid makeup cosmetic.   5. The water-in-oil solid makeup cosmetic according to claim 1, wherein the mass of the powder of the component (D) is 10 to 30% by mass with respect to the total amount of the cosmetic. A water-in-oil solid makeup cosmetic.