JP2010159527A - Steel cord for reinforcing rubber product - Google Patents
Steel cord for reinforcing rubber product Download PDFInfo
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- JP2010159527A JP2010159527A JP2009004136A JP2009004136A JP2010159527A JP 2010159527 A JP2010159527 A JP 2010159527A JP 2009004136 A JP2009004136 A JP 2009004136A JP 2009004136 A JP2009004136 A JP 2009004136A JP 2010159527 A JP2010159527 A JP 2010159527A
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/062—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
- D07B1/0626—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration the reinforcing cords consisting of three core wires or filaments and at least one layer of outer wires or filaments, i.e. a 3+N configuration
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/062—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2023—Strands with core
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2024—Strands twisted
- D07B2201/2029—Open winding
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2047—Cores
- D07B2201/2052—Cores characterised by their structure
- D07B2201/2059—Cores characterised by their structure comprising wires
- D07B2201/206—Cores characterised by their structure comprising wires arranged parallel to the axis
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Abstract
Description
本発明は、車両用タイヤや工業用ベルト等のゴム製品の補強材として使用されるゴム製品補強用スチールコードに関する。 The present invention relates to a steel cord for reinforcing rubber products used as a reinforcing material for rubber products such as vehicle tires and industrial belts.
タイヤやベルト等のゴム製品の補強材とするゴム製品補強用スチールコード(以下、単にスチールコードあるいはコードということもある。)として、複数本の素線からなる芯(コア)の周りに側(シース)となる複数本の素線を撚り合わせたスチールコードがある。そして、例えば、芯となる素線が2本で側となる素線が2本の2+2構造のスチールコードにおいて、芯となる2本の素線は略平行で相互に撚りがないものとし、側となる2本の素線は芯と側との撚り合わせの方向およびピッチと同じ方向およびピッチで相互にねじり合ったものとすることが従来から知られている(例えば、特許文献1参照)。 As a steel cord for reinforcing rubber products (hereinafter, also simply referred to as steel cord or cord) used as a reinforcing material for rubber products such as tires and belts, the side around the core (core) consisting of a plurality of strands ( There is a steel cord in which multiple strands that form a sheath are twisted together. For example, in a steel cord having a 2 + 2 structure with two core wires and two side wires, the two core wires are substantially parallel and do not twist each other. It has been conventionally known that the two strands of wire are twisted with each other in the same direction and pitch as the twisting direction and pitch of the core and the side (see, for example, Patent Document 1).
2+2構造のスチールコードは、このように、芯となる2本の素線が略平行で相互に撚りがないものとし、側となる2本の素線は芯と側との撚り合わせの方向およびピッチと同じ方向およびピッチで相互にねじり合ったものとすることで、ゴム侵入性を確保することができ、また、芯となる略平行で相互に撚りが無い2本の素線がコード断面において一方向に並ぶ配置となり、それに、側となる2本の素線が撚り合わされることによって、コード断面が高さ方向に薄い偏平な形状となり、例えば複数本のコードを互いに平行に揃えてゴムシートに埋設しタイヤの補強材とする場合に、そのゴムシートの厚みを小さくすることができ、タイヤ成形の自由度が高まる。 In this way, the steel cord of the 2 + 2 structure is such that the two strands that become the core are substantially parallel and do not twist each other, and the two strands that are the sides are in the direction of twisting between the core and the side and By twisting each other in the same direction and pitch as the pitch, rubber penetration can be ensured, and two strands that are substantially parallel and have no twists in the core are crossed in the cord cross section. It is arranged in one direction, and the two strands on the side are twisted together, so that the cord cross-section is thin and flat in the height direction. For example, a rubber sheet with a plurality of cords aligned in parallel with each other When it is embedded in a tire as a reinforcing material for a tire, the thickness of the rubber sheet can be reduced, and the degree of freedom in forming the tire is increased.
芯となる複数本の素線が略並行で相互に撚りがなく、それら芯となる複数本の素線がコード断面において一方向に並ぶ配置となる場合に、それに側となる複数本の素線が撚り合わされることによって、コード断面が高さ方向に薄い偏平な形状となることは、2+2構造のスチールコードに限らない。芯となる素線が3本で側となる素線が2本の3+3構造や、芯となる素線が4本で側となる素線が5本の4+5構造のスチールコードの場合も、芯となる3本あるいは4本の素線が略平行で相互に撚りがなく、それら3本あるいは4本の芯となる素線がコード断面において略直線状に一方向に並ぶ配置となるよう構成すると、側となる3本(芯となる素線が3本の場合)あるいは5本(芯となる素線が4本の場合)の素線の撚り合わされることによって、コード断面形状が高さ方向に相対的に薄い超偏平な形状となる。つまり、N(N=3〜4)本の素線からなる芯の周りに側となるN本あるいは(N+1)本の素線を撚り合わせたN+N構造あるいはN+(N+1)構造のスチールコードは、芯となるN本の素線の全てが互いに略平行で、且つコード断面において略直線状に一方向に並ぶ構成とすることで、断面形状が超偏平なスチールコードとすることができる。 When a plurality of strands that are cores are substantially parallel and are not twisted with each other, and the plurality of strands that become the cores are arranged in one direction in the cross section of the cord, the plurality of strands on the side thereof It is not limited to a steel cord having a 2 + 2 structure that the cord cross-section becomes thin and flat in the height direction by being twisted together. Even in the case of a steel cord with a 3 + 3 structure with three core wires and two side wires, or a 4 + 5 structure steel cord with four core wires and five side wires When the three or four strands are substantially parallel and are not twisted with each other, the three or four core strands are arranged in a straight line in one direction in the cord cross section. The cross-sectional shape of the cord is increased by twisting three strands (when there are three core wires) or five strands (when there are four core wires). It becomes a relatively thin super flat shape. That is, a steel cord of N + N structure or N + (N + 1) structure in which N or (N + 1) strands on the side are wound around a core made of N (N = 3 to 4) strands is A steel cord having a super-flat cross-sectional shape can be obtained by adopting a configuration in which all of the N strands serving as the core are substantially parallel to each other and arranged in one direction in a substantially straight line in the cord cross-section.
また、それとは別に、例えば3+3構造のスチールコードで、コード断面において芯となる3本の素線の中心を結ぶ仮想線が直線状または鈍角三角形状となる横並び配列とし、芯となる3本の素線の少なくとも1本に波付けを施すことで、コア内部へのゴムの侵入を促進するようにしたものが知られている(例えば、特許文献2参照)。 Separately, for example, in a steel cord of 3 + 3 structure, a virtual line connecting the centers of three strands that become cores in the cross section of the cord is arranged side by side in a straight line or an obtuse triangular shape, and the three cores that become the core It is known that at least one strand is corrugated to promote the penetration of rubber into the core (for example, see Patent Document 2).
上述のように、N(N=3〜4)本の素線からなる芯の周りに側となるN本あるいは(N+1)本の素線を撚り合わせたN+N構造あるいはN+(N+1)構造のスチールコードは、例えば3+3構造のコードの場合でいえば、芯となる3本の素線の全てが互いに略平行で、且つコード断面において略直線状に一方向に並ぶ構成とすることで、断面形状が超偏平なスチールコードとすることができる。しかしながら、例えば3+3構造のコードで、芯となる3本の素線の全てが互いに略平行という場合、通常は、それら芯となる3本の素線は略ストレートな形状であって、これら3本の略ストレートな形状の素線からなる芯がコード長手方向に略真っ直ぐな状態で中心部に位置し、この略真っ直ぐな状態の芯の周りに側の素線が巻き付くように撚られた状態となる。この場合、コードは、芯の素線に比べて側の素線が伸びやすい状態となる。そのため、コードに引張荷重がかかり、コードが伸びると、芯の素線と側の素線に引張荷重が均等に分散されて作用するのではなく、芯の素線に偏って力(引張荷重)が作用することになり、耐疲労性が悪くなる。つまり、芯となる3本の素線がコード断面において略直線状に一方向に並び、その周りに側となる2本の素線が撚り合わされた構成の超偏平なコードとすることはできても、耐疲労性を十分に高めることができない。 As described above, steel of N + N structure or N + (N + 1) structure in which N or (N + 1) strands are twisted around a core consisting of N (N = 3 to 4) strands. For example, in the case of a cord having a 3 + 3 structure, the cord has a cross-sectional shape in which all three core wires serving as the core are substantially parallel to each other and arranged substantially in a straight line in the cord cross section. Can be a super flat steel cord. However, for example, in the case of a 3 + 3 structure cord, when all of the three core wires that are the cores are substantially parallel to each other, the three core wires that are the cores are generally substantially straight and these three wires A core made of a substantially straight wire is positioned at the center in a state that is substantially straight in the longitudinal direction of the cord, and is twisted so that the strand on the side is wrapped around this substantially straight core It becomes. In this case, the cord is in a state in which the strand on the side is easier to extend than the strand of the core. Therefore, when a tensile load is applied to the cord and the cord is stretched, the tensile load is not evenly distributed and acts on the core strand and the side strand, but is biased toward the core strand (tensile load) Will act, resulting in poor fatigue resistance. That is, it is possible to make a super flat cord with a configuration in which three strands as cores are arranged in one direction in a substantially straight line in the cord cross section, and two strands on the side are twisted around each other. However, the fatigue resistance cannot be sufficiently increased.
また、上述のように、例えば3+3構造のスチールコードで、コード断面において芯となる3本の素線の中心を結ぶ仮想線が直線状または鈍角三角形状となる横並び配列とし、芯となる3本の素線の少なくとも1本に波付けを施すことで、コア内部へのゴムの侵入を促進したりするようにしたものはあり、そうしたものでは、芯となる素線は少なくとも1本はストレート形状ではなくなって、その素線については引張荷重の偏りが緩和されると考えられるが、その場合でも、必ずしも、芯となる素線と側となる素線の全てに引張荷重が均等に分散されて作用するものとはならないし、また、ゴムの侵入を促進するために芯となる素線に施す波付けというのは、好ましくは波高の向きが、芯となる素線の横並び方向を横切る向きの波付けであって、その場合、コードの断面形状は偏平なものではなくなる。 Further, as described above, for example, a steel cord having a 3 + 3 structure, a virtual line connecting the centers of three strands that are cores in the cord cross section is arranged in a side-by-side arrangement in a straight line or an obtuse triangular shape, and the three cores There are some that have been made to promote the penetration of rubber into the core by corrugating at least one of the strands, in which at least one of the core strands is straight However, it is considered that the bias of the tensile load is alleviated for the strands, but even in that case, the tensile load is not necessarily distributed evenly to all of the core strands and the side strands. In addition, the corrugation applied to the core wire to promote the penetration of rubber is preferably such that the direction of the wave height is transverse to the side-by-side direction of the core wires. Wavy , In which case the code cross-sectional shape is not a flat.
また、コードに撚る前の素線の状態で芯の素線がストレートであっても、コードの撚りピッチを小さくすれば、コードの状態では芯の素線もねじられた形となり、そのため、引張荷重が掛かったときに芯の素線に偏ってかかる力が多少とも緩和されるが、それにも限度があり、また、撚りピッチを小さくすると、コードの生産性が悪化する。 Also, even if the core strand is straight in the state of the strand before twisting the cord, if the cord twist pitch is reduced, the core strand will also be twisted in the cord state, The force applied to the core wire when the tensile load is applied is somewhat relaxed, but there is a limit to this, and if the twist pitch is reduced, the productivity of the cord deteriorates.
本発明は、車両用タイヤや工業用ベルト等のゴム製品の補強材として使用されるゴム製品補強用スチールコードを、偏平で且つ耐疲労性に優れたものとすることを目的とする。 An object of the present invention is to make a steel cord for reinforcing a rubber product used as a reinforcing material for a rubber product such as a vehicle tire or an industrial belt flat and excellent in fatigue resistance.
本発明のゴム製品補強用スチールコードは、N(N=3〜4)本の素線からなる芯の周りに側となるN本又は(N+1)本の素線を撚り合わせたN+N構造またはN+(N+1)構造のスチールコードであって、前記芯となるN本の素線が全て互いに平行で、且つコード断面において略直線状に一方向に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、前記波形の振幅dと素線径Dとが、1.1≦d/D≦2.4を満たすことを特徴とする。 The steel cord for reinforcing rubber products of the present invention has an N + N structure or N + in which N or (N + 1) strands are twisted around a core made of N (N = 3 to 4) strands. A steel cord having a (N + 1) structure, in which all the N strands serving as the core are parallel to each other and arranged in one direction in a substantially straight line in the cord cross section, and in phase with each other in the longitudinal direction of the cord It exhibits a waveform, and the amplitude d and the wire diameter D of the waveform satisfy 1.1 ≦ d / D ≦ 2.4.
このスチールコードは、芯となるN(N=3〜4)本の全てが互いに平行で、且つコード断面において略直線状に一方向に並び、その周りに側となるN本又は(N+1)本の素線が撚り合わされていることにより、コード断面が偏平な形状となり、また、その略平行で、且つ芯となるN本の素線がコード長手方向に相互に位相が揃った波形を呈し、その波形の振幅dと素線径Dとが、1.1≦d/D≦2.4を満たすことにより、コードに引張荷重がかかったときに、芯となる素線と側となる素線が共に伸びて、芯となる素線と側となる素線に適度に引張荷重が分散されることとなり、破断強度が大きく耐疲労性に優れたコードとなる。 In this steel cord, all N (N = 3 to 4) cores are parallel to each other and arranged in one direction in a substantially straight line in the cord cross section, and N or (N + 1) strands on the side around it Are twisted together so that the cross section of the cord becomes flat, and the N strands that are substantially parallel and core have a waveform in which the phases are aligned with each other in the longitudinal direction of the cord, When the amplitude d and the wire diameter D of the waveform satisfy 1.1 ≦ d / D ≦ 2.4, the core wire and the wire on the side when a tensile load is applied to the cord Are stretched together, and the tensile load is appropriately dispersed between the core wire and the side wire, resulting in a cord having high breaking strength and excellent fatigue resistance.
d/D>2.4だと、芯の素線の波形の振幅dが大きすぎ、芯の素線が過剰に伸びやすくなって、引張荷重が側の素線に偏り、そのため、コードの破断強度が低下し、耐疲労性が悪くなる。 If d / D> 2.4, the amplitude d of the waveform of the core wire is too large, the core wire tends to be excessively stretched, and the tensile load is biased toward the side wire, so that the cord breaks. Strength decreases and fatigue resistance deteriorates.
また、d/D<1.1だと、芯の素線は波形の振幅dが小さ過ぎ、略ストレートな形状に近くて、伸びにくく、引張荷重が芯の素線に偏って掛かるのを十分に緩和できないため、コードの破断強度は十分に大きくならず、耐疲労性は十分に改善されない。 Further, when d / D <1.1, the core wire has a waveform amplitude d that is too small, is nearly straight, is not easily stretched, and the tensile load is sufficiently applied to the core wire. Therefore, the breaking strength of the cord is not sufficiently increased, and the fatigue resistance is not sufficiently improved.
本発明によれば、ゴム製品補強用スチールコードを偏平で且つ、撚りピッチを大きくして生産コストを低減しつつ、耐疲労性に優れたものとすることができる。そして、例えば複数本のコードを互いに平行に揃えてゴムシートに埋設したものをタイヤ等の補強材とする場合に、薄くて強力で耐疲労性に優れたゴムシートとすることができる。 According to the present invention, it is possible to make the steel cord for reinforcing rubber products flat and excellent in fatigue resistance while reducing the production cost by increasing the twist pitch. For example, when a reinforcing material such as a tire is formed by arranging a plurality of cords parallel to each other and embedded in a rubber sheet, the rubber sheet can be thin, strong, and excellent in fatigue resistance.
以下、本発明の実施形態を図面に基づいて説明する。
図1は本発明の実施形態の一例に係るもので、(a)はスチールコードの平面図、(b)はスチールコードの側面図、(c)はスチールコードの断面図であり、図2は図1に示すスチールコードの芯の素線のコード状態での波形を示す説明図である。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
FIG. 1 relates to an example of an embodiment of the present invention, (a) is a plan view of a steel cord, (b) is a side view of the steel cord, (c) is a sectional view of the steel cord, and FIG. It is explanatory drawing which shows the waveform in the cord state of the strand of the core of the steel cord shown in FIG.
この実施形態のスチールコードは、車両用タイヤや工業用ベルト等の補強材として使用されるゴム製品補強用スチールコードであって、6本の素線(スチールフィラメント)1〜6から成り、それら6本の素線1〜6は、線径(素線径)が同じで、3本の素線1〜3が芯(コア)となり、その3本の素線1〜3からなる芯の周りに側となる3本の素線4〜6が撚り合わされた3+3構造のスチールコードである。6本の素線1〜6の線径は例えば0.20〜0.38mmである。また、コードの撚りピッチは例えば10〜20mmである。 The steel cord of this embodiment is a steel cord for reinforcing rubber products that is used as a reinforcing material for vehicle tires, industrial belts, etc., and is composed of six strands (steel filaments) 1-6. The strands 1 to 6 have the same wire diameter (strand diameter), and the three strands 1 to 3 become cores, and around the core composed of the three strands 1 to 3 This is a steel cord having a 3 + 3 structure in which three strands 4 to 6 on the side are twisted together. The wire diameters of the six strands 1 to 6 are, for example, 0.20 to 0.38 mm. Further, the twist pitch of the cord is, for example, 10 to 20 mm.
そして、このスチールコードは、芯の素線(芯となる3本の素線)1〜3が全て、図1の(a)および(b)に示すようにコード状態において互いに略平行で、且つ、図1の(c)に示すようにコード断面において略直線状に一方向(横方向)に並ぶとともに、図1の(a)に示すようにコード長手方向に相互に位相が揃った波形を呈している。 In this steel cord, all of the core wires (three core wires) 1 to 3 are substantially parallel to each other in the cord state as shown in FIGS. 1 (a) and (b), and As shown in FIG. 1 (c), waveforms are arranged in one direction (lateral direction) in a substantially straight line in the cross section of the cord, and in which the phases are aligned in the longitudinal direction of the cord as shown in FIG. 1 (a). Presents.
芯の素線1〜3の波形は、図2に示すとおりで、波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dとが、1.1≦d/D≦2.4の関係を満たしている。 The waveforms of the core strands 1 to 3 are as shown in FIG. 2, and the amplitude of the waveform (the apparent wave height of the core in the cord state) d and the strand diameter D are 1.1 ≦ d / D ≦ The relationship of 2.4 is satisfied.
このスチールコードは、芯となる3本の素線1〜3の全てが互いに略平行で、且つコード断面において略直線状に一方向に並び、その周りに側となる3本の素線4〜6が撚り合わされていることにより、コード断面が偏平な形状となり、また、その略平行で、且つ芯となる3本の素線1〜3がコード長手方向に相互に位相が揃った波形を呈し、その波形の振幅dと素線径Dとが、1.1≦d/D≦2.4を満たすことにより、コードに引張荷重がかかったときに、芯となる素線1〜3と側となる素線4〜6がともに伸びて、芯となる素線1〜3と側となる素線4〜6に適度に引張荷重が分散されるとことなり、破断強度が大きく耐疲労性に優れたコードとなっている。 In this steel cord, all of the three strands 1 to 3 as cores are substantially parallel to each other and arranged in one direction in a substantially straight line in the cord cross section, and the three strands 4 to 6 is twisted together, the cross section of the cord becomes flat, and the three strands 1 to 3 that are substantially parallel and core form a waveform in which the phases are aligned in the longitudinal direction of the cord. When the amplitude d of the waveform and the wire diameter D satisfy 1.1 ≦ d / D ≦ 2.4, when the tensile load is applied to the cord, the wires 1 to 3 and the core that are the core The strands 4 to 6 to be stretched together, and the tensile load is appropriately dispersed in the strands 1 to 3 to be the core and the strands 4 to 6 to be the side, and the fracture strength is large and the fatigue resistance is increased. Excellent code.
d/D>2.4だと、芯の素線1〜3の波形の振幅dが大き過ぎ、芯の素線1〜3が過剰に伸びやすくなって、引張荷重が側の素線4〜6に偏り、そのため、コードの破断強度が低下し、耐疲労性が悪くなる。また、d/D<1.1だと、芯の素線1〜3は波形の振幅dが小さ過ぎ、略ストレートな形状に近くて、伸びにくく、引張荷重が芯の素線1〜3に偏って掛かるのを十分に緩和できないため、コードの破断強度は十分に大きくならず、耐疲労性は十分に改善されない。 If d / D> 2.4, the amplitude d of the waveform of the core strands 1 to 3 is too large, and the core strands 1 to 3 tend to be excessively stretched. Therefore, the breaking strength of the cord is lowered and the fatigue resistance is deteriorated. Moreover, when d / D <1.1, the core wires 1 to 3 have a waveform amplitude d that is too small, is nearly straight, hardly stretched, and the tensile load is reduced to the core wires 1 to 3. Since it is not possible to sufficiently relax the bias, the cord breaking strength is not sufficiently increased, and the fatigue resistance is not sufficiently improved.
また、図示の例は3+3構造のスチールコードに適用した実施形態であるが、本発明は他に、3+4構造にも適用できる。その場合、スチールコード(図示省略)は、7本の素線(スチールフィラメント)からなり、それら7本の素線は、線径(素線径)が同じで、3本の素線が芯(コア)となり、その3本の素線からなる芯の周りに側素線となる4本の素線が撚り合わされた3+4構造のスチールコードである。7本の素線の線径は例えば0.20〜0.38mmである。また、コードの撚りピッチは例えば10〜20mmである。 Moreover, although the example of illustration is embodiment applied to the steel cord of 3 + 3 structure, this invention can be applied also to 3 + 4 structure. In this case, the steel cord (not shown) is composed of seven strands (steel filaments), and these seven strands have the same wire diameter (strand diameter) and three strands are cores ( A steel cord having a 3 + 4 structure in which four strands serving as side strands are twisted around a core composed of the three strands. The wire diameter of the seven strands is, for example, 0.20 to 0.38 mm. Further, the twist pitch of the cord is, for example, 10 to 20 mm.
さらに、本発明は、4+4構造にも適用できる。その場合、スチールコード(図示省略)は、8本の素線(スチールフィラメント)からなり、それら8本の素線は、線径(素線径)が同じで、4本の素線が芯(コア)となり、その4本の素線からなる芯の周りに側素線となる4本の素線が撚り合わされた4+4構造のスチールコードである。8本の素線の線径は例えば0.20〜0.38mmである。また、コードの撚りピッチは例えば10〜20mmである。 Furthermore, the present invention can be applied to a 4 + 4 structure. In this case, the steel cord (not shown) is composed of eight strands (steel filaments), and these eight strands have the same wire diameter (strand diameter), and the four strands are cores ( This is a 4 + 4 steel cord in which four strands serving as side strands are twisted around a core composed of the four strands. The wire diameter of the eight strands is, for example, 0.20 to 0.38 mm. Further, the twist pitch of the cord is, for example, 10 to 20 mm.
また、本発明は、4+5構造にも適用できる。その場合、スチールコード(図示省略)は、9本の素線(スチールフィラメント)からなり、それら9本の素線は、線径(素線径)が同じで、4本の素線が芯(コア)となり、その4本の素線からなる芯の周りに側素線となる5本の素線が撚り合わされた4+5構造のスチールコードである。9本の素線の線径は例えば0.20〜0.38mmである。また、コードの撚りピッチは例えば10〜20mmである。 The present invention can also be applied to a 4 + 5 structure. In this case, the steel cord (not shown) is composed of nine strands (steel filaments), and these nine strands have the same wire diameter (strand diameter), and the four strands are cores ( This is a steel cord having a 4 + 5 structure in which five strands serving as side strands are twisted around a core composed of the four strands. The diameter of the nine strands is, for example, 0.20 to 0.38 mm. Further, the twist pitch of the cord is, for example, 10 to 20 mm.
そして、上記スチールコードは、芯の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈する。そして、芯の素線の波形はやはり図2に示すとおりであり、この場合、波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dとが、1.1≦d/D≦2.4の関係を満たす。 The steel cord has a waveform in which the core strands are all substantially parallel to each other in the cord state, and are arranged in one direction (lateral direction) in a substantially straight line in the cord cross section, and in phase with each other in the cord longitudinal direction. Presents. The waveform of the core wire is still as shown in FIG. 2, and in this case, the amplitude of the waveform (the apparent wave height of the core in the state of the cord) d and the wire diameter D are 1.1 ≦ d. The relationship of /D≦2.4 is satisfied.
上記スチールコードは、芯となるN本の素線(N=3または4)の全てが互いに略平行で、且つコード断面において略直線状に一方向に並び、その周りに側となる素線(N本またはN+1本)が撚り合わされていることにより、コード断面が偏平な形状となり、また、その略平行で、且つ芯となるN本素線がコード長手方向に相互に位相が揃った波形を呈し、その波形の振幅dと素線径Dとが、1.1≦d/D≦2.4を満たすことにより、コードに引張荷重がかかったときに、芯となる素線と側となる素線が共に伸びて、芯となる素線と側となる素線に適度に引張荷重が分散されることとなり、破断強度が大きく耐疲労性に優れたコードとなる。 In the steel cord, all of the N strands (N = 3 or 4) serving as cores are substantially parallel to each other and arranged in one direction in a substantially straight line in the cord cross section, and the strands on the sides around the strands ( N or N + 1) are twisted together so that the cross section of the cord has a flat shape, and the N strands that are substantially parallel to each other in the core have a waveform in which the phases are aligned in the longitudinal direction of the cord. When the cord has a tensile load, the amplitude d and the wire diameter D of the waveform satisfy 1.1 ≦ d / D ≦ 2.4. The strands are stretched together, and a tensile load is appropriately dispersed between the core strand and the side strand, resulting in a cord having high breaking strength and excellent fatigue resistance.
この場合、d/D>2.4だと、芯の素線の波形の振幅dが大き過ぎ、芯の素線が過剰に伸びやすくなって、引張荷重が側の素線に偏り、そのため、コードの破断強度が低下し、耐疲労性が悪くなる。また、d/D<1.1だと、芯の素線は波形の振幅dが小さ過ぎ、略ストレートな形状に近くて、伸びにくく、引張荷重が芯の素線に偏って掛かるのを十分に緩和できないため、コードの破断強度は十分に大きくならず、耐疲労性は十分に改善されない。 In this case, if d / D> 2.4, the amplitude d of the waveform of the core wire is too large, the core wire tends to extend excessively, and the tensile load is biased toward the side wire, The breaking strength of the cord is lowered and the fatigue resistance is deteriorated. Further, when d / D <1.1, the core wire has a waveform amplitude d that is too small, is nearly straight, is not easily stretched, and the tensile load is sufficiently applied to the core wire. Therefore, the breaking strength of the cord is not sufficiently increased, and the fatigue resistance is not sufficiently improved.
本発明を適用した試料(実施例1−1〜1−4および実施例2−1〜2−4)を作成し、耐疲労性および形状(均一性)の評価を行った。その結果を、従来例並びに比較例1−1〜1−4及び比較例2−1〜2−4についての評価を対比して表1、表2に示す。 Samples (Examples 1-1 to 1-4 and Examples 2-1 to 2-4) to which the present invention was applied were prepared, and fatigue resistance and shape (uniformity) were evaluated. The results are shown in Tables 1 and 2 in comparison with the evaluations of the conventional example and Comparative Examples 1-1 to 1-4 and Comparative Examples 2-1 to 2-4.
実施例1−1は、3+3構造のスチールコードで、芯の3本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.25mm、撚りピッチが16mm、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=1.82であり、1.1≦d/D≦2.4を満たしている。 Example 1-1 is a steel cord having a 3 + 3 structure, in which all three strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned with each other in the longitudinal direction, the wire diameter is 0.25 mm, the twist pitch is 16 mm, the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the strand The relationship of the diameter D is d / D = 1.82, which satisfies 1.1 ≦ d / D ≦ 2.4.
実施例1−2は、3+3構造のスチールコードで、芯の3本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.25mm、撚りピッチが16mm、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=2.20であり、1.1≦d/D≦2.4を満たしている。 Example 1-2 is a steel cord having a 3 + 3 structure, in which all three strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned with each other in the longitudinal direction, the wire diameter is 0.25 mm, the twist pitch is 16 mm, the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the strand The relationship of the diameter D is d / D = 2.20, which satisfies 1.1 ≦ d / D ≦ 2.4.
実施例1−3は、3+4構造のスチールコードで、芯の3本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.23mm、撚りピッチが14mm、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=1.75であり、1.1≦d/D≦2.4を満たしている。 Example 1-3 is a steel cord having a 3 + 4 structure, in which all three strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the wire diameter is 0.23 mm, the twist pitch is 14 mm, the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the strand The relationship of the diameter D is d / D = 1.75, which satisfies 1.1 ≦ d / D ≦ 2.4.
実施例1−4は、3+4構造のスチールコードで、芯の3本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.23mm、撚りピッチが14mm、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=2.35であり、1.1≦d/D≦2.4を満たしている。 Example 1-4 is a steel cord having a 3 + 4 structure, in which all three strands of the core are substantially parallel to each other in the cord state, and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the wire diameter is 0.23 mm, the twist pitch is 14 mm, the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the strand The relationship of the diameter D is d / D = 2.35, which satisfies 1.1 ≦ d / D ≦ 2.4.
実施例2−1は、4+4構造のスチールコードで、芯の4本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.28mm、撚りピッチが18mm、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=1.22であり、1.1≦d/D≦2.4を満たしている。 Example 2-1 is a steel cord having a 4 + 4 structure, in which all four strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the wire diameter is 0.28 mm, the twist pitch is 18 mm, the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the strand The relationship of the diameter D is d / D = 1.22, which satisfies 1.1 ≦ d / D ≦ 2.4.
実施例2−2は、4+4構造のスチールコードで、芯の4本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.28mm、撚りピッチが18mm、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=2.35であり、1.1≦d/D≦2.4を満たしている。 Example 2-2 is a steel cord having a 4 + 4 structure, in which all four strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the wire diameter is 0.28 mm, the twist pitch is 18 mm, the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the strand The relationship of the diameter D is d / D = 2.35, which satisfies 1.1 ≦ d / D ≦ 2.4.
実施例2−3は、4+5構造のスチールコードで、芯の4本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.25mm、撚りピッチが16mm、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=1.16であり、1.1≦d/D≦2.4を満たしている。 Example 2-3 is a steel cord having a 4 + 5 structure, in which all four strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned with each other in the longitudinal direction, the wire diameter is 0.25 mm, the twist pitch is 16 mm, the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the strand The relationship of the diameter D is d / D = 1.16, which satisfies 1.1 ≦ d / D ≦ 2.4.
実施例2−4は、4+5構造のスチールコードで、芯の4本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.25mm、撚りピッチが16mm、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=2.38であり、1.1≦d/D≦2.4を満たしている。 Example 2-4 is a steel cord having a 4 + 5 structure, in which all four strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned with each other in the longitudinal direction, the wire diameter is 0.25 mm, the twist pitch is 16 mm, the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the strand The relationship of the diameter D is d / D = 2.38, which satisfies 1.1 ≦ d / D ≦ 2.4.
また、従来例は、2+2構造のスチールコードで、芯となる2本の素線は略平行で相互に撚りが無く(コード断面において一方向に並ぶ)、素線径が0.25mm、撚りピッチが14mmで、芯の素線の波形はコードの撚りによる緩やかな波形で、その振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係はd/D=0.3である。 In addition, the conventional example is a steel cord with a 2 + 2 structure, and the two core wires that are cores are substantially parallel and do not twist each other (aligned in one direction in the cord cross section), the wire diameter is 0.25 mm, and the twist pitch 14 mm, and the core wire has a gentle waveform due to the twist of the cord, and the relationship between the amplitude (apparent wave height of the core in the cord state) d and the strand diameter D is d / D = 0.3. It is.
比較例1−1は、3+3構造のスチールコードで、芯の3本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.25mm、撚りピッチが16mmである。但し、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=1.04で、1.1≦d/D≦2.4を満たさない。 Comparative Example 1-1 is a steel cord having a 3 + 3 structure, in which all three strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the strand diameter is 0.25 mm, and the twist pitch is 16 mm. However, the relationship between the amplitude of the waveform of the core wire (the apparent wave height of the core in the cord state) d and the wire diameter D is d / D = 1.04, and 1.1 ≦ d / D ≦ 2. Does not satisfy 4.
比較例1−2は、3+3構造のスチールコードで、芯の3本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.25mm、撚りピッチが16mmである。但し、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=2.46で、1.1≦d/D≦2.4を満たさない。 Comparative Example 1-2 is a steel cord having a 3 + 3 structure, in which all three strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the strand diameter is 0.25 mm, and the twist pitch is 16 mm. However, the relationship between the amplitude of the core wire waveform (the apparent wave height of the core in the state of the cord) d and the wire diameter D is d / D = 2.46, and 1.1 ≦ d / D ≦ 2. Does not satisfy 4.
比較例1−3は、3+4構造のスチールコードで、芯の3本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.23mm、撚りピッチが14mmである。但し、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=1.06で、1.1≦d/D≦2.4を満たさない。 Comparative Example 1-3 is a steel cord having a 3 + 4 structure, in which all three strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the wire diameter is 0.23 mm, and the twist pitch is 14 mm. However, the relationship between the amplitude of the waveform of the core wire (the apparent wave height of the core in the state of the cord) d and the wire diameter D is d / D = 1.06, and 1.1 ≦ d / D ≦ 2. Does not satisfy 4.
比較例1−4は、3+4構造のスチールコードで、芯の3本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.23mm、撚りピッチが14mmである。但し、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=2.44で、1.1≦d/D≦2.4を満たさない。 Comparative Example 1-4 is a steel cord having a 3 + 4 structure, in which all three strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the wire diameter is 0.23 mm, and the twist pitch is 14 mm. However, the relationship between the amplitude of the core wire waveform (apparent wave height of the core in the cord state) d and the wire diameter D is d / D = 2.44, and 1.1 ≦ d / D ≦ 2. Does not satisfy 4.
比較例2−1は、4+4構造のスチールコードで、芯の4本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.28mm、撚りピッチが18mmである。但し、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=1.02で、1.1≦d/D≦2.4を満たさない。 Comparative Example 2-1 is a steel cord having a 4 + 4 structure, in which all four strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the wire diameter is 0.28 mm, and the twist pitch is 18 mm. However, the relationship between the amplitude of the waveform of the core wire (the apparent wave height of the core in the state of the cord) d and the wire diameter D is d / D = 1.02, and 1.1 ≦ d / D ≦ 2. Does not satisfy 4.
比較例2−2は、4+4構造のスチールコードで、芯の4本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.28mm、撚りピッチが18mmである。但し、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=2.45で、1.1≦d/D≦2.4を満たさない。 Comparative Example 2-2 is a steel cord having a 4 + 4 structure, in which all four strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the wire diameter is 0.28 mm, and the twist pitch is 18 mm. However, the relationship between the amplitude of the waveform of the core wire (the apparent wave height of the core in the cord state) d and the wire diameter D is d / D = 2.45, and 1.1 ≦ d / D ≦ 2. Does not satisfy 4.
比較例2−3は、4+5構造のスチールコードで、芯の4本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.25mm、撚りピッチが16mmである。但し、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=1.05で、1.1≦d/D≦2.4を満たさない。 Comparative Example 2-3 is a steel cord having a 4 + 5 structure, in which all four strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the strand diameter is 0.25 mm, and the twist pitch is 16 mm. However, the relationship between the amplitude of the waveform of the core wire (the apparent wave height of the core in the state of the cord) d and the wire diameter D is d / D = 1.05, and 1.1 ≦ d / D ≦ 2. Does not satisfy 4.
比較例2−4は、4+5構造のスチールコードで、芯の4本の素線が全てコード状態において互いに略平行で、且つコード断面において略直線状に一方向(横方向)に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、素線径が0.25mm、撚りピッチが16mmである。但し、芯の素線の波形の振幅(コードの状態での芯の見かけの波高)dと素線径Dの関係がd/D=2.45で、1.1≦d/D≦2.4を満たさない。 Comparative Example 2-4 is a steel cord having a 4 + 5 structure, in which all four strands of the core are substantially parallel to each other in the cord state and arranged in one direction (lateral direction) in a substantially straight line in the cord cross section. It has a waveform in which the phases are aligned in the longitudinal direction, the strand diameter is 0.25 mm, and the twist pitch is 16 mm. However, the relationship between the amplitude of the waveform of the core wire (the apparent wave height of the core in the cord state) d and the wire diameter D is d / D = 2.45, and 1.1 ≦ d / D ≦ 2. Does not satisfy 4.
耐疲労性は、複数本のコードをゴム材中に埋め込んで複合体シートを作成し、このシートを用いて2層ベルト疲労試験機により、フレッティング摩耗、座屈等を経てコードが破断するまでの繰り返し回数を求め、2+2構造の従来例を100として指数表示した。 For fatigue resistance, a composite sheet is created by embedding a plurality of cords in a rubber material, and this sheet is used to create a composite sheet until the cord breaks through fretting wear, buckling, etc. The number of repetitions was determined and the index was displayed with the conventional example of 2 + 2 structure as 100.
形状(均一性)は、2+2構造の従来例を基準(均一)として、それより良好な場合を「均一」、そうでない場合を「不均一」とした。 With respect to the shape (uniformity), the conventional example of the 2 + 2 structure was set as a reference (uniform), and the case of better shape was “uniform” and the case of not being “non-uniform”.
この評価結果から、本発明を適用した試料である実施例1−1〜1−4及び実施例2−1〜2−4のスチールコードは、従来例および比較例1−1〜1−4および比較例2−4に比べ耐疲労性においてはるかに優れ、また、形状の均一性にも優れていることがわかる。 From the evaluation results, the steel cords of Examples 1-1 to 1-4 and Examples 2-1 to 2-4, which are samples to which the present invention is applied, are the conventional examples and Comparative Examples 1-1 to 1-4 and It can be seen that the fatigue resistance is far superior to that of Comparative Example 2-4, and that the shape uniformity is also excellent.
1、2、3 素線(芯となる素線)
4、5、6 素線(側となる素線)
d 波形の振幅
D 素線径
1, 2, 3 strands (core strands)
4, 5, 6 strands (side strands)
d Waveform amplitude D Wire diameter
Claims (1)
前記芯となるN本の素線が全て互いに平行で、且つコード断面において略直線状に一方向に並ぶとともに、コード長手方向に相互に位相が揃った波形を呈し、
前記波形の振幅dと素線径Dとが、1.1≦d/D≦2.4を満たすことを特徴とするゴム製品補強用スチールコード。 A steel cord of N + N structure or N + (N + 1) structure in which N or (N + 1) strands on the side are wound around a core composed of N (N = 3 to 4) strands,
The N core wires that are the cores are all parallel to each other and arranged in one direction substantially linearly in the cord cross section, and exhibit a waveform in which the phases are aligned in the cord longitudinal direction,
A steel cord for reinforcing rubber products, wherein the amplitude d of the waveform and the wire diameter D satisfy 1.1 ≦ d / D ≦ 2.4.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004323981A (en) * | 2003-04-21 | 2004-11-18 | Bridgestone Corp | Steel cord for reinforcing rubber article and tire |
JP2006507414A (en) * | 2002-04-08 | 2006-03-02 | トクセン ユー.エス.エー.、インコーポレイテッド | Flat helically wound tire cord |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2006507414A (en) * | 2002-04-08 | 2006-03-02 | トクセン ユー.エス.エー.、インコーポレイテッド | Flat helically wound tire cord |
JP2004323981A (en) * | 2003-04-21 | 2004-11-18 | Bridgestone Corp | Steel cord for reinforcing rubber article and tire |
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