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JP2010037675A - Spinneret for modified cross-section fiber yarn - Google Patents

Spinneret for modified cross-section fiber yarn Download PDF

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JP2010037675A
JP2010037675A JP2008200688A JP2008200688A JP2010037675A JP 2010037675 A JP2010037675 A JP 2010037675A JP 2008200688 A JP2008200688 A JP 2008200688A JP 2008200688 A JP2008200688 A JP 2008200688A JP 2010037675 A JP2010037675 A JP 2010037675A
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section
spinneret
cross
line segment
center
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Masayoshi Kokabe
正義 小壁
Masami Ota
雅巳 太田
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Teijin Frontier Co Ltd
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Teijin Fibers Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a spinneret capable of making a melt spinning of a modified cross-section multifilament yarn with a nearly equilateral-triangular fiber cross section excellent in silk-like glossy feeling, and also enabling its own nozzle shape to be made easier and more inexpensively than ever. <P>SOLUTION: The spinneret for modified cross-section fiber yarn has the following design: Semicircles each with a radius of curvature (R) are processed respectively at three apexes (A, B and C) forming the respective tips of slit holes branched in three-way fashion at equal angles. The ratio (R/L) is (1:8) to (1:12) (wherein (L) is the length of a line segment connecting each of the apexes (A, B and C) and the center (O)). When the midpoints (M) of the respective sides of an equilateral triangle formed by connecting the apexes one another with a straight line each and points (N) where the respective line segments MO connecting the midpoints (M) and the center (O) and the profile line of the discharge hole intersect are imagined, the ratio (l<SB>1</SB>/l<SB>2</SB>) is (2.8:2) to (3.2:2) (wherein l<SP>1</SP>is the line segment OM's length, and l<SB>2</SB>is the line segment ON's length). <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は熱可塑性合成重合体の溶融物または溶液から異形断面繊維を得るための紡糸口金に関するものであり、特に、繊維横断面の形状が略正三角形状を呈する異形断面糸を得るための紡糸口金に関する。   The present invention relates to a spinneret for obtaining a modified cross-section fiber from a melt or solution of a thermoplastic synthetic polymer, and in particular, spinning for obtaining a modified cross-section yarn having a substantially equilateral triangular shape in the cross section of the fiber. Regarding the base.

一般的に、ポリエステル、ポリアミド、ポリオレフィンなどの熱可塑性合成重合体(以下、単に「ポリマー」と言う)から異型断面糸を得る紡糸口金として、Y字形のスリット孔が穿設されたものが知られている。このY字形のポリマー吐出孔が穿設された紡糸口金から得られる異型断面糸の中でも、繊維の横断面が正三角形状を呈するものは、衣料用繊維に付加する特性の中でもシルクに似た光沢感や風合いを出すことができる。更には、正三角形状の横断面を有する繊維は、これら繊維群を隙間なく稠密充填するのに適しているという特性も併せ持っている。   Generally, a Y-shaped slit hole is known as a spinneret for obtaining a modified cross-section yarn from a thermoplastic synthetic polymer (hereinafter simply referred to as “polymer”) such as polyester, polyamide, and polyolefin. ing. Among the modified cross-section yarns obtained from the spinneret with the Y-shaped polymer discharge holes, the cross-section of the fibers is an equilateral triangle. Can give a feeling and texture. Furthermore, fibers having a regular triangular cross section also have a characteristic that they are suitable for densely filling these fiber groups without gaps.

しかしながら、紡糸口金から吐出された直後のポリマーはベーラス効果によって一旦膨らむため、紡糸後の繊維横断面が略正三角形状のものを得るのは難しいが、図3に例示したように特許文献1には、このような繊維横断面を得るための紡糸口金が提案されている。ここで、前記特許文献1に提案された紡糸口金に穿設されているY字形のポリマー吐出孔について簡単に説明すると、この吐出孔は中心Oからスリット幅を漸減させながら各120°の等角度を置いて放射状に延びる3本のスリット孔部L,M,Nから構成される。   However, since the polymer immediately after being discharged from the spinneret swells once due to the Belas effect, it is difficult to obtain a fiber having a substantially equilateral triangular cross section after spinning. However, as illustrated in FIG. Has proposed a spinneret for obtaining such a fiber cross section. Here, the Y-shaped polymer discharge hole provided in the spinneret proposed in Patent Document 1 will be briefly described. The discharge hole is equiangular at 120 ° with the slit width gradually reduced from the center O. And three slit holes L, M, and N extending radially.

また、各スリット孔部は中心Oよりl離れた点L,M,Nから中心Oよりl離れた点L,M,Nに至るまでスリット幅が一定のrとなり、スリット孔部の各先端において、点L,M,Nをそれぞれ中心とし直径がrの半円が設けられている。そして、隣り合うスリット孔部に挟まれた凹状の円弧はO,O及びOを中心とし半径Rの円の円周の一部を構成し、直線O,直線O及び直線Oはそれぞれ長さが等しく正三角形Oを形成する。 Further, each slit holes is L l 1 away point from the center O 1, M 1, N 1 l 2 away point from the center O from L 2, M 2, N r next slit width is constant up to 2 At each end of the slit hole portion, a semicircle having a diameter r and a center at the points L 2 , M 2 , and N 2 is provided. A concave arc sandwiched between adjacent slit holes constitutes a part of the circumference of a circle with a radius R centered on O 1 , O 2, and O 3 , and includes a straight line O 1 M 1 O 2 , a straight line O 2 N 1 O 3 and straight line O 3 L 1 O 2 are equal in length and form an equilateral triangle O 1 O 2 O 3 .

このとき、略正三角形状の繊維横断面を得るために、特許文献1では、Rとr並びにrとl(ただし、l=l−l)の比率が極めて重要であって、R/rは1.5〜5.0の範囲でかつr/lが0.35〜7の範囲に入ることを要求するものである。しかしながら、前述の図3からも明らかな通り、このような複雑な形状を有する多数個の吐出孔群(通常、30個以上の吐出孔群)が一個の紡糸口金に穿設される場合には、その製作費用が高くなる。 In this case, in order to obtain a substantially equilateral triangular fiber cross section, in Patent Document 1, the ratios of R and r and r and l (where l = l 2 −l 1 ) are extremely important. r is required to be in the range of 1.5 to 5.0 and r / l to be in the range of 0.35 to 7. However, as is apparent from FIG. 3 described above, when a large number of discharge hole groups (usually, 30 or more discharge hole groups) having such a complicated shape are formed in one spinneret. , Its production cost increases.

また、長期間に渡って使用すると、吐出孔から流出するポリマーによってエッジ部が磨耗して、その形状が変化する。そうすると、当初は略正三角形状の横断面形状を有していた異形断面繊維の形状が丸みを帯びた円形横断面を呈するようになり、プリズム効果に起因するシルクライクな光沢という高機能な特性を持った異形断面糸が得られなくなる。
特開昭62−97917号公報
Further, when used for a long period of time, the edge portion is worn by the polymer flowing out from the discharge hole, and the shape thereof is changed. As a result, the shape of the modified cross-section fiber, which initially had a substantially equilateral triangular cross-sectional shape, has a rounded circular cross-section, and has a high-performance characteristic of silky luster due to the prism effect. It becomes impossible to obtain a modified cross-section yarn having
Japanese Patent Laid-Open No. 62-9717

以上に説明した従来技術が有する諸問題に鑑み、本発明の目的は、シルクライクな光沢感に優れた略正三角形状の繊維横断面を有する異形断面マルチフィラメント糸を溶融紡糸でき、しかも、その吐出孔形状を従来のものより安価かつ容易に製作異形断面糸用紡糸口金を提供することにある。   In view of the problems of the prior art described above, the object of the present invention is to melt-spin a modified multi-filament yarn having a substantially equilateral triangular fiber cross section excellent in silk-like glossiness, and its An object of the present invention is to provide a spinneret for deformed cross-section yarns that can be produced more easily and cheaply than conventional ones.

上記本発明の目的は、「溶融した熱可塑性重合体を複数個の吐出孔から吐出して繊維横断面が略正三角形状を呈する異形マルチフィラメント糸を紡出するための紡糸口金であって、
前記吐出孔は中心(O)から放射状にそのスリット幅を漸減させながら互いに120°の挟角を形成してY字形に3方向へそれぞれ分岐して延びた同形状の3つのスリット孔から形成され、
更に3方向へそれぞれ分岐した前記スリット孔の各先端を形成する3つの頂点(A,B及びC)部に曲率半径(R)を有する半円がそれぞれ加工され、
前記曲率半径(R)と前記中心(O)から前記各頂点(A,B及びC)を結んだ線分の長さ(L)との寸法比率(R/L)が1/8〜1/12の範囲にあり、
前記各頂点(A,B及びC)間をそれぞれ直線で結んで形成される正三角形の各辺の中点(M)とこの中点(M)と前記中心(O)を結ぶ線分MOと前記吐出孔の外形線とがそれぞれ交わる点(N)を仮想した場合に、線分OMの長さ(l)と線分ONの長さ(l)との寸法比率(l/l)が2.8/2〜3.2/2の範囲にあることを特徴とする異形断面繊維用紡糸口金」によって達成できる。
The object of the present invention is “a spinneret for spinning a deformed multifilament yarn having a substantially transverse triangular cross section by discharging a molten thermoplastic polymer from a plurality of discharge holes,
The discharge hole is formed of three slit holes having the same shape extending from the center (O) and diverging in three directions in a Y-shape by gradually reducing the slit width radially from the center (O). ,
Further, semi-circles each having a radius of curvature (R) at each of the three apexes (A, B, and C) forming the tips of the slit holes branched in three directions are respectively processed.
A dimensional ratio (R / L) between the radius of curvature (R) and the length (L) of the line segment connecting each vertex (A, B, and C) from the center (O) is 1/8 to 1 / In the range of 12,
A midpoint (M) of each side of an equilateral triangle formed by connecting the vertices (A, B and C) with straight lines, and a line segment MO connecting the midpoint (M) and the center (O). When a point (N) where the outer shape lines of the discharge holes intersect is assumed, a dimensional ratio (l 1 / l) between the length of the line segment OM (l 1 ) and the length of the line segment ON (l 2 ) 2 ) is in the range of 2.8 / 2 to 3.2 / 2 ”and can be achieved by a spinneret for irregularly shaped cross-section fibers”.

本発明により、その繊維横断面がこれまでにない良好な略正三角形状を有する異形断面マルチフィラメント糸を得ることができ、略正三角形の断面を有するが故にプリズム効果が強く発現し、優れた光沢感を示す。しかも、得られた異形断面を有するマルチフィラメント糸はその横断面が正三角形に近いので、これらを幾層にも並べ積層させた場合に隙間なく最密充填することができる。   According to the present invention, it is possible to obtain a deformed cross-section multifilament yarn having a substantially equilateral triangular shape whose fiber cross section has never been obtained, and since it has a substantially equilateral triangular cross section, the prism effect is strongly expressed and is excellent. Shows gloss. In addition, since the obtained multifilament yarn having an irregular cross section has a cross section close to an equilateral triangle, when these layers are arranged and laminated in layers, the multifilament yarn can be closely packed without a gap.

その上、本発明に係る紡糸口金に穿設する吐出孔は、同形状を有して3等配(挟角がそれぞれ120°)されて3方向に分岐する3つのスリット孔の先端に曲率半径がRの半円を形成し、前述の寸法比率(R/L)を1/8〜1/12の範囲に収め、更に、前述の寸法比率(l/l)を2.8/2〜3.2/2の範囲に収めるように穿孔すればよい。したがって、従来技術のような複雑かつ精巧な加工は不要であって、それ故に製作が容易であり、かつ製作コストも安価となる。 In addition, the discharge holes drilled in the spinneret according to the present invention have the same shape and are arranged in three equal positions (the included angles are 120 °) and the radii of curvature at the tips of the three slit holes branched in three directions. Forms a semicircle of R, and the dimensional ratio (R / L) is within a range of 1/8 to 1/12, and the dimensional ratio (l 1 / l 2 ) is 2.8 / 2. What is necessary is just to drill so that it may fit in the range of -3.2 / 2. Therefore, complicated and elaborate processing as in the prior art is not required, and therefore, the manufacturing is easy and the manufacturing cost is low.

以下に図面に基づいて、本発明に係る紡糸口金について詳述する。
図1は異形断面糸を紡糸する際に用いられる紡糸口金に穿設された吐出孔の形状を説明するための平面図(ポリマーの吐出面側から見た図)である。
The spinneret according to the present invention will be described in detail below with reference to the drawings.
FIG. 1 is a plan view (viewed from the polymer discharge surface side) for explaining the shape of a discharge hole formed in a spinneret used when spinning a modified cross-section yarn.

なお、図1は、Y字形を形成しながら放射状に3方向へそれぞれ分岐し、かつそれぞれの孔形が全く同じである3つのスリット孔から構成されたポリマーの吐出孔が紡糸口金のポリマー吐出面に開口した図である。このとき、Y字形に分岐した前記スリット孔は、分岐の中心から各スリット孔の中心線に対して3方向へ120°の挟角を形成した状態で、そのスリット幅を漸減させながら放射状にそれぞれ3方向に分岐して延びている。   FIG. 1 shows a polymer discharge surface of a spinneret that is composed of three slit holes that branch radially in three directions while forming a Y-shape and that have exactly the same hole shape. FIG. At this time, the slit holes branched in a Y-shape are radially formed while gradually reducing the slit width in a state in which an angle of 120 ° is formed in three directions with respect to the center line of each slit hole from the center of the branch. The branch extends in three directions.

また、この図1において、符号A,B及びCは、点線で記載した正三角形の各頂点(3つの各スリット孔の頂点でもある)をそれぞれ示し、符号Oは前記正三角形の中心(すなわち、3つのスリット孔が分岐する分岐の中心でもある)をそれぞれ示す。更に、符号Aの近傍に記載された符号Rはスリット孔の先端である頂部に曲率加工を施す場合の曲率半径を示している。なお、この曲率半径Rも特別な理由がない限り、通常は各頂点A,B及びCに対して同じ値に設定される。   Further, in FIG. 1, symbols A, B, and C respectively indicate the vertices of an equilateral triangle described by dotted lines (also vertices of three slit holes), and symbol O represents the center of the equilateral triangle (that is, 3 is also the center of the branch where the three slit holes branch). Furthermore, the symbol R described in the vicinity of the symbol A indicates the radius of curvature when the curvature processing is performed on the apex that is the tip of the slit hole. The radius of curvature R is usually set to the same value for each vertex A, B, and C unless there is a special reason.

次に、符号Mと符号Nについて説明する。先ず、符号Mは点線で記載した正三角形ABCの各辺AB,BC及びCA(図では、辺BCの場合が記載されている)の中点であり、符号Nは線分MOと吐出孔(3方向に分岐したスリット孔)の外形線と交わる点である。このとき、本発明の紡糸口金に穿設する吐出孔形状は、下記の(1)及び(2)に記載した特徴を備えていることが肝要である。   Next, the code | symbol M and the code | symbol N are demonstrated. First, the symbol M is the midpoint of each side AB, BC and CA (in the figure, the case of the side BC) of the equilateral triangle ABC indicated by the dotted line, and the symbol N is the line segment MO and the discharge hole ( It is a point that intersects with the outline of the slit hole branched in three directions. At this time, it is important that the shape of the discharge hole formed in the spinneret of the present invention has the characteristics described in the following (1) and (2).

(1)各頂点A,B及びCにおいて、曲率半径(R)と正三角形の中心Oから各頂点A,B及びCとをそれぞれ結んだ各線分の長さ(L)との寸法比率(R/L)を1/8〜1/12の範囲とする。何故ならば、R/Lが1/12より小さくなると、正三角形状断面を有する異形糸を得ようとしても紡出されるポリマーの表面張力の影響により、円形になろうとする力が大きく働くため、おにぎり形に近い形状となり、目的とする断面形状が得られないからである。また、R/Lが1/8より大きくなると、吐出孔から吐出されたポリマーがベーラス効果により膨らみ、特に各頂点A,B及びCにおいて膨らみが大きくなって、丸みを帯びた頂点を有する三角形となり、鋭い頂点を有する三角形とならない。そのため、上記比率が最適値であると考えられる。   (1) At each vertex A, B, and C, a dimensional ratio (R) between the radius of curvature (R) and the length (L) of each line segment connecting each vertex A, B, and C from the center O of the regular triangle. / L) is in the range of 1/8 to 1/12. This is because, when R / L is smaller than 1/12, a force to make a circular shape is exerted greatly due to the influence of the surface tension of the polymer to be spun even if an irregular yarn having an equilateral triangular cross section is obtained. This is because the shape is close to a rice ball shape and the desired cross-sectional shape cannot be obtained. Further, when R / L is larger than 1/8, the polymer discharged from the discharge hole swells due to the balus effect, and the bulge is increased particularly at each of the vertices A, B, and C, resulting in a triangle having a rounded vertex. It does not become a triangle with a sharp vertex. Therefore, it is considered that the above ratio is an optimum value.

(2)「中点Mと中点Oとを結んだ線分の長さ(l)」と「点Nと中点Oとを結んだ線分の長さ(l)」の寸法比率(l/l)を略3/2(2.8/2〜3.2/2)とする。何故ならば、上記比率範囲から外れる場合、異形断面糸がくびれを持ったY字形状糸や円形状に近い異形断面糸ができ上がるので好ましくないからである。したがって、上記比率が最適値である。 (2) Dimensional ratio of “length of line segment connecting middle point M and middle point O (l 1 )” and “length of line segment connecting point N and middle point O (l 2 )” Let (l 1 / l 2 ) be approximately 3/2 (2.8 / 2 to 3.2 / 2). This is because, if the ratio is out of the above-mentioned ratio range, the modified cross-sectional yarn is not preferable because a Y-shaped yarn having a constriction or a modified cross-sectional yarn close to a circular shape is formed. Therefore, the above ratio is an optimum value.

以下、本発明に係る紡糸口金を使用して、繊維横断面形状が略正三角形状を有する
Y字形状の吐出孔において、図1において点線で記載した正三角形の中心Oから各頂点A,B及びCを結んだ線分の長さ(L)を0.35mmとし、各頂点A,B、Cにおける半円状に施す曲率加工において、その曲率半径Rを0.030mmとした。更に、)「中点Mと中点Oとを結んだ線分の長さ(l)」と「点Nと中点Oとを結んだ線分の長さ(l)」の寸法比率(l/l)を3/2にすると共に、Y字形吐出孔の互いに隣接する頂点間に形成するくびれ加工部(凹状加工部)については、各点Nにおいて曲率半径が0.5mmとなるようにして滑らかな曲線で各頂点A,B及びCの曲率加工部(半円加工部)と接続した。
Hereinafter, using the spinneret according to the present invention, in a Y-shaped discharge hole having a substantially equilateral triangular fiber cross-sectional shape, each vertex A, B from the center O of the equilateral triangle indicated by the dotted line in FIG. In addition, the length (L) of the line segment connecting C and C is 0.35 mm, and the curvature radius R is 0.030 mm in the curvature processing applied to each of the vertices A, B, and C in a semicircular shape. Further, dimensional ratio of “the length of the line segment connecting the middle point M and the middle point O (l 1 )” and “the length of the line segment connecting the point N and the middle point O (l 2 )”. (L 1 / l 2 ) is set to 3/2, and the constricted portion (concave portion) formed between adjacent vertices of the Y-shaped discharge hole has a radius of curvature of 0.5 mm at each point N In this way, it was connected to the curvature machining part (semicircle machining part) of each vertex A, B and C with a smooth curve.

そして、以上のようにして形成した30個のポリマー吐出孔を1枚の紡糸口金に穿設した。この紡糸口金を用いて、ポリエチレンナフタレートを200g/min(一孔当り6.67g/min)、巻取り速度1000m/minで紡糸した。この場合、得られた各フィラメントの繊維横断面を光学顕微鏡で撮影して写真に撮ったところ、図2に示したような良好な略正三角形状の異形断面糸を得ることができた。   Then, 30 polymer discharge holes formed as described above were formed in one spinneret. Using this spinneret, polyethylene naphthalate was spun at 200 g / min (6.67 g / min per hole) at a winding speed of 1000 m / min. In this case, when the fiber cross section of each filament obtained was photographed with an optical microscope and photographed, a good substantially equilateral triangular shaped cross-section yarn as shown in FIG. 2 could be obtained.

三角形断面糸を紡糸するための本発明に係る紡糸口金に穿設された吐出孔形状の説明図である。It is explanatory drawing of the discharge hole shape drilled in the spinneret based on this invention for spinning a triangular cross-section yarn. 本発明に係る紡糸口金を使用して得られた三角形断面糸の繊維横断面を光学顕微鏡で撮影した写真である。It is the photograph which image | photographed the fiber cross section of the triangular cross-section yarn obtained using the spinneret which concerns on this invention with the optical microscope. 三角形断面糸を紡糸するための従来の紡糸口金に穿設された吐出孔形状の説明図(平面図)である。It is explanatory drawing (plan view) of the discharge hole shape pierced in the conventional spinneret for spinning a triangle section yarn.

符号の説明Explanation of symbols

A,B,C 正三角形の各頂点
L 正三角形の中心と各頂点とを結んだ各線分の長さ
M 正三角形の各辺の中点
N 線分AOを延長した直線が吐出孔の外形と交わる点
R 各頂点部に施した曲率加工の曲率半径
O 正三角形ABCの中心
A, B, C Each vertex of the equilateral triangle L Length of each segment connecting the center of the equilateral triangle and each vertex M Midpoint of each side of the equilateral triangle N A straight line extending the segment AO is the outline of the discharge hole Intersection point R Curvature radius of curvature applied to each vertex O Center of equilateral triangle ABC

Claims (2)

溶融した熱可塑性重合体を複数個の吐出孔から吐出して繊維横断面が略正三角形状を呈する異形マルチフィラメント糸を紡出するための紡糸口金であって、
前記吐出孔は中心(O)から放射状にそのスリット幅を漸減させながら互いに120°の挟角を形成してY字形に3方向へそれぞれ分岐して延びた同形状の3つのスリット孔から形成され、
更に3方向へそれぞれ分岐した前記スリット孔の各先端を形成する3つの頂点(A,B及びC)部に曲率半径(R)を有する半円がそれぞれ加工され、
前記曲率半径(R)と前記中心(O)から前記各頂点(A,B及びC)を結んだ線分の長さ(L)との寸法比率(R/L)が1/8〜1/12の範囲にあり、
前記各頂点(A,B及びC)間をそれぞれ直線で結んで形成される正三角形の各辺の中点(M)とこの中点(M)と前記中心(O)を結ぶ線分MOと前記吐出孔の外形線とがそれぞれ交わる点(N)を仮想した場合に、線分OMの長さ(l)と線分ONの長さ(l)との寸法比率(l/l)が2.8/2〜3.2/2の範囲にあることを特徴とする異形断面糸用紡糸口金。
A spinneret for spinning a deformed multifilament yarn in which a molten thermoplastic polymer is ejected from a plurality of ejection holes and the cross section of the fiber has a substantially equilateral triangle shape,
The discharge hole is formed of three slit holes having the same shape extending from the center (O) by diverging in three directions in a Y-shape by gradually reducing the slit width from the center (O) and forming a 120 ° included angle. ,
Further, semi-circles each having a radius of curvature (R) are processed at the three apexes (A, B, and C) forming the respective ends of the slit holes branched in three directions,
A dimensional ratio (R / L) between the radius of curvature (R) and the length (L) of the line segment connecting each vertex (A, B, and C) from the center (O) is 1/8 to 1 / In the range of 12,
A midpoint (M) of each side of an equilateral triangle formed by connecting the vertices (A, B and C) with straight lines, and a line segment MO connecting the midpoint (M) and the center (O). When a point (N) at which the outline of the discharge hole intersects is assumed, a dimensional ratio (l 1 / l) between the length of the line segment OM (l 1 ) and the length of the line segment ON (l 2 ) 2 ) is in the range of 2.8 / 2 to 3.2 / 2, a spinneret for deformed section yarns.
Y字形の吐出孔において、Y字形中央部から各先端部までの距離が等しく、正三角形状の異形断面繊維を紡糸する事ができる、請求項1の異形断面繊維用紡糸口金。   The spinneret for a modified cross-section fiber according to claim 1, wherein the Y-shaped discharge hole has an equal distance from the Y-shaped central portion to each tip, and can spin a regular cross-section shaped cross-section fiber.
JP2008200688A 2008-08-04 2008-08-04 Spinneret for modified cross-section fiber yarn Pending JP2010037675A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102808231A (en) * 2012-08-27 2012-12-05 嘉兴市普利莱新材料有限公司 Preparation method of polylactic acid fiber filament imitated silk material
CN107904675A (en) * 2017-12-11 2018-04-13 济南大自然新材料有限公司 A kind of fibre spinning spinneret cap
CN108893793A (en) * 2018-09-06 2018-11-27 福建锦江科技有限公司 A kind of spinneret, 6 drafting silk of special-shaped polyamide fibre and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102808231A (en) * 2012-08-27 2012-12-05 嘉兴市普利莱新材料有限公司 Preparation method of polylactic acid fiber filament imitated silk material
CN107904675A (en) * 2017-12-11 2018-04-13 济南大自然新材料有限公司 A kind of fibre spinning spinneret cap
CN107904675B (en) * 2017-12-11 2023-05-23 济南大自然新材料有限公司 Fiber spinning cap
CN108893793A (en) * 2018-09-06 2018-11-27 福建锦江科技有限公司 A kind of spinneret, 6 drafting silk of special-shaped polyamide fibre and preparation method thereof

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