JP2010006750A - Hair cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hair cosmetic while improving the moisture-holding power of hair, without giving stickiness and a weight to the hair, giving a flexible and moist finishing feeling and also excellent in the prevention of stiff and dry state at low humidity, and in a wet feeling. <P>SOLUTION: This hair cosmetic contains the following components (A) to (C). (A) A hydroxyether type cation expressed by general formula (I): R<SP>1</SP>-(OCH<SB>2</SB>CH(OH)CH<SB>2</SB>)<SB>m</SB>-N<SP>+</SP>(R<SP>2</SP>)<SB>3</SB>X<SP>-</SP>[wherein, R<SP>1</SP>is a linear or branched 12-24C saturated or unsaturated alkyl; R<SP>2</SP>is a 1-3C alkyl; (m) is an integer of 1 to 3; and X is a halogen atom or a 1-3C alkyl sulfate group], (B) An ether type amine expressed by general formula (II): R<SP>3</SP>-O-(CH<SB>2</SB>)<SB>n</SB>-N(R<SP>4</SP>)<SB>2</SB>[wherein, R<SP>3</SP>is a linear or branched 12-22C saturated or unsaturated fatty acid residue; R<SP>4</SP>is a 1-3C alkyl; and (n) is an integer of 1 to 5] and (C) A higher alcohol having a 14-24C long chain alkyl group. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

The present invention relates to a hair cosmetic, and in particular, increases the moisture retention of the hair, and as a result, can give the hair a supple and moist finish without feeling sticky or heavy, and low The present invention relates to a hair cosmetic that is excellent in preventing rustiness and moisture in humidity.

With the trend of women's hairstyles, the required finish and feel of hair are changing in parallel. Recently, hair styles with reduced hair volume such as shaggy and layer cut are common, and on the other hand, treatment such as coloring and perm, as well as a supple and moist finish, as well as a sticky feeling and hair There is a need for a texture that produces volume without increasing weight. In addition, it is desired that these functions continue even in a low humidity environment in winter. In hair cosmetics such as hair rinses and hair treatments, conventionally, for the purpose of softening the hair and improving the combing, it is possible to add a cationic surfactant, silicone, etc., or to give a moist feel. Attempts have been made to blend solid oils, but with these conventional technologies, it is difficult to satisfy the needs required in recent hairstyles, with a moist finish and no stickiness or weight. It was a challenge to achieve both.

As a method for solving these problems, for example, a hair cosmetic that imparts smoothness and flexibility to hair by using a fatty acid amidoamine compound or a hydroxyetheramine compound has been proposed (see, for example, Patent Documents 1 to 4). .) All of these technologies have been improved to some extent, but the moisture retention of the hair has been reduced the next day after washing the hair, causing the hair to feel dry and uncomfortable, making it difficult to set. In particular, in a low humidity environment in winter, it was not sufficiently satisfactory, for example, the rustling was intense and the effect of smoothness and moistness was not sustained.

In addition, attempts have been made to impart smoothness and flexibility to hair by blending new oils and silicones with high water-holding properties. For example, a method of blending various silicone compounds to impart softness and moist feeling ( For example, refer to Patent Document 5), dimerinolinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) blended cosmetics with excellent fit and elongation (see Patent Document 6, for example), branched fatty acid cholesteryl. A hair cosmetic (for example, see Patent Document 7) that imparts a moist feeling, a smooth feeling, and flexibility by blending an ester is disclosed. However, even in these inventions, although a supple, moist feeling can be realized, the hair becomes sticky and heavy, and under low-humidity environment, it is soft and not sufficiently satisfactory in the sustainability of moisture.

JP-A-9-71515 JP 2000-053537 A Special Table 2000-501430 JP 2004-323495 A JP 2008-056665 A JP 2007-269746 A Japanese Patent Laid-Open No. 7-48232

The object of the present invention is to provide a supple and moist finish without giving the hair stickiness and weight while increasing the moisture retention of the hair, and to prevent rustiness under low humidity. An object of the present invention is to provide a hair cosmetic with an excellent moisture feeling.

As a result of diligent research in view of such a situation, the present inventor has found that a hair cosmetic containing a hydroxy ether cation, an ether amine, and a higher alcohol solves the above-mentioned problems. The invention has been completed.

That is, the hair cosmetic composition of the present invention is characterized by containing the following components (A) to (C).
(A) Hydroxy ether type cation represented by the following general formula (I) R ¹ — (OCH ₂ CH (OH) CH ₂ ) _m —N ⁺ (R ² ) ₃ · X ⁻ (I) (wherein R ¹ is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R ² is an alkyl group having 1 to 3 carbon atoms, m is an integer of 1 to 5, X is a halogen atom or carbon number 1 ˜3 alkyl sulfate groups.)
(B) Ether type amine represented by the following general formula (II) R ³ —O— (CH ₂ ) _n —N (R ⁴ ) ₂ (II)
(In the formula, R ³ represents a linear or branched saturated or unsaturated fatty acid residue having 12 to 22 carbon atoms, R ⁴ represents an alkyl group having 1 to 3 carbon atoms, and n represents an integer of 1 to 5).
(C) A higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms.

The hair cosmetic composition of the present invention preferably further contains (D) a silicone derivative, and (E) contains at least one selected from the group consisting of sphingolipids, ceramides, cholesterol derivatives, and phytosterol derivatives. Is more desirable.

The hair cosmetic composition of the present invention increases the moisture retention of the hair, and as a result, it can give the hair a supple and moist finish without feeling sticky or heavy, and at low humidity. The effect which was excellent in the prevention of rustiness and a feeling of moisture can be provided.

Hereinafter, the present invention will be described in detail.

The hydroxy ether type cation of the component (A) in the present invention is, for example, the following general formula (I):
R ¹ — (OCH ₂ CH (OH) CH ₂ ) _m —N ⁺ (R ² ) ₃ · X ⁻ (I) (wherein R ¹ is a straight-chain or branched C 12-24 saturated or An unsaturated alkyl group, R ² is an alkyl group having 1 to 3 carbon atoms, m is an integer of 1 to 5 and X is a halogen atom or an alkyl sulfate group having 1 to 3 carbon atoms. As shown, lauryl PG trimonium chloride, myristyl PG trimonium chloride, palmityl PG trimonium chloride, cetyl PG trimonium chloride, cetostearyl PG trimonium chloride, stearyl PG trimonium chloride, aralkyl PG trimonium chloride, behenyl PG trimonium Chloride, Carnerville PG Trimonium Chloride, Oleyl PG Trimonium Chloride, Elidyl PG Tri Nium chloride, linoleyl PG trimonium chloride, linoleyl PG trimonium chloride, lauryl PG trimonium bromide, myristyl PG trimonium bromide, palmityl PG trimonium bromide, cetyl PG trimonium bromide, cetostearyl PG trimonium bromide, stearyl PG trimonium Bromide, aralkyl PG trimonium bromide, behenyl PG trimonium bromide, carnervir PG trimonium bromide, oleyl PG trimonium bromide, elaidyl PG trimonium bromide, linoleyl PG trimonium bromide, linoleyl PG trimonium bromide, lauryl PG trimonium ethosulphate , Myristyl PG trimonium sulfate, palmityl PG trimonium Sulfate, cetyl PG trimonium ethosulphate, cetostearyl PG trimonium ethosulphate, stearyl PG trimonium ethosulphate, aralkyl PG trimonium ethosulphate, behenyl PG trimonium ethosulphate, carnervir PG trimonium ethosulphate, oleyl PG trimonium eth Sulfate, Elidyl PG Trimonium Ethosulfate, Linoleyl PG Trimonium Ethosulfate, Linolenyl PG Trimonium Ethosulfate, Lauryl PG Trimonium Metosulfate, Myristyl PG Trimonium Metosulfate, Palmityl PG Trimonium Metosulfate, Cetyl PG Trimonium Metosulfate , Cetostearyl PG trimonium methosulphate Stearyl PG trimonium methosulphate, aralkyl PG trimonium methosulphate, behenyl PG trimonium methosulphate, carnervir PG trimonium methosulphate, oleyl PG trimonium methosulphate, elaidyl PG trimonium methosulphate, linoleyl PG trimonium methosulphate, Examples include hydroxy ether type cations such as linolenyl PG trimonium methosulphate. Among these, behenyl PG trimonium chloride in which R ¹ is a behenyl group having 22 carbon atoms, R ² is a methyl group, and X is chlorine is particularly preferable. In this invention, 1 type (s) or 2 or more types can be arbitrarily used from these hydroxy ether type | mold cations, The compounding quantity becomes like this. Preferably it is 0.1-10 mass% (hereinafter, especially except what is described) Represents mass% simply by “%”), more preferably in the range of 0.5 to 5%. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.

The ether type amine of the component (B) in the present invention is, for example, the following general formula (II)
^{_{R 3 -O- (CH 2) n}} -N (R 4) 2 ... (II)
(In the formula, R ³ represents a linear or branched saturated or unsaturated fatty acid residue having 12 to 22 carbon atoms, R ⁴ represents an alkyl group having 1 to 3 carbon atoms, and n represents an integer of 1 to 5). Specific examples are represented by: Lauroxypropyldimethylamine, Myroxypropyldimethylamine, Palmitopropylpropyldimethylamine, Stearoxypropyldimethylamine, Behenoxypropyldimethylamine, Lauroxypropyldiethylamine, Myroxypropyldiethylamine , Palmitopropylpropylamine, stearoxypropyldiethylamine, behenoxypropyldiethylamine and the like. Among these, palmitopropylpropyldimethylamine and stearoxypropyldimethylamine, in which R ³ is an integer having 16 to 18 carbon atoms, R ⁴ is a methyl group, and n is 3, are particularly preferable. In this invention, 1 type (s) or 2 or more types can be arbitrarily used from these ether type amines, The compounding quantity becomes like this. Preferably it is 0.1-10%, More preferably, it is 0.5-5% Range. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.

The ether type amine is usually preferably added and neutralized by adding an acid, and the function as an emulsifier is more exhibited by neutralization. It is preferable to use an organic acid as the neutralizing agent. Examples of the organic acid include hydroxy monocarboxylic acids such as glycolic acid, lactic acid, glyceric acid, gluconic acid and pantothenic acid; hydroxydicarboxylic acids such as malic acid and tartaric acid; hydroxytricarboxylic acids such as citric acid, oxalic acid and malonic acid Dicarboxylic acids such as maleic acid, succinic acid and glutaric acid; acidic amino acids such as L-glutamic acid and L-aspartic acid; pyroglutamic acid; aromatic acids such as benzoic acid and p-toluenesulfonic acid. Among these, from the viewpoint of emulsification, hydroxymonocarboxylic acid, hydroxydicarboxylic acid, and hydroxytricarboxylic acid are preferable, and lactic acid is more preferable among them. The neutralization of the ether type amine and the organic acid may be carried out in the emulsification step, or may be blended after a salt of the ether type amine and the organic acid is formed in advance. Moreover, the organic acid can be used alone or in combination of two or more thereof, and the blending amount thereof is preferably 0.5 to 2.0 moles, more preferably 0.7 times the ether type amine. It is the range of -1.2 mol times.

The higher alcohol having a long chain alkyl group having 14 to 22 carbon atoms as the component (C) in the present invention is preferably a long chain higher alcohol having 16 to 22 carbon atoms, such as cetyl alcohol, stearyl alcohol, or behenyl alcohol. is there. These higher alcohols can be used singly or in combination of two or more, and the blending amount is preferably 1 to 20%, more preferably 3 to 10%. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.

Furthermore, in the present invention, a silicone derivative as the component (D) can be blended for the purpose of enhancing the feel during use. Specific examples of the silicone derivative include dimethylpolysiloxane, methylphenylpolysiloxane, alcohol-modified silicone, alkyl-modified silicone, amino-modified silicone, polyether silicone and the like, for example, the following (a) to (g). .

(A) Dimethylpolysiloxane: A polymer having a methylsiloxane structure and a viscosity of 6 to 100,000 mPa · s at 25 ° C.
(B) Cyclic silicone: A silicone oil having a cyclic methylpolysiloxane structure, such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and cyclic silicone resin.
(C) Highly polymerized dimethylpolysiloxane: one having a methylsiloxane structure and a viscosity at 25 ° C. of 50,000 to 20,000,000 mPa · s. When blended in, it may be blended by dissolving in liquid oil, or an aqueous emulsion prepared in an aqueous solution of a nonionic surfactant such as a cationic surfactant or polyoxyethylene alkyl ether may be blended. preferable. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.
(D) Amino-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or N- (2-aminoethyl) aminoisobutyl group, and the amino-modified silicone is blended in the hair cosmetic composition of the present invention. In this case, it is preferable to mix in a liquid oil or mix an aqueous emulsion prepared in an aqueous solution of a nonionic surfactant such as a cationic surfactant or polyoxyethylene alkyl ether. When used as an aqueous emulsion, the amount of amino-modified silicone contained in the aqueous emulsion is preferably 20 to 60% by mass, and more preferably 30 to 50% by mass. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.
(E) Polyether-modified silicone: dimethylsiloxane / methyl (polyoxyethylene) siloxane / methyl (polyoxypropylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane / methyl (polyol) Xypropylene) siloxane copolymer and the like.
(F) Alcohol-modified silicone: has a structure in which part of the methyl group of dimethylpolysiloxane is replaced with an alkoxy group, and examples thereof include stearoxymethyl polysiloxane and cetoxymethyl polysiloxane.
(G) Alkyl-modified silicone: having a structure in which a part of methyl group of dimethylpolysiloxane is replaced with a long-chain alkyl group, and having liquid to wax-like properties depending on the substitution rate and size of the alkyl group. It is done.
(H) Aminophenyl-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or N- (2-aminoethyl) aminoisobutyl group and a phenyl group. When blended in cosmetics, dissolve in liquid oil or blend an aqueous emulsion prepared in a nonionic surfactant solution such as a cationic surfactant or polyoxyethylene alkyl ether. It is preferable. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.

Among these silicone derivatives, (a) dimethylpolysiloxane, (c) highly polymerized dimethylpolysiloxane, (d) amino-modified silicone and (h) aminophenyl-modified silicone are particularly preferable. These silicone derivatives can be used alone or in combination of two or more, and the blending amount thereof is 0.1 to 20% by mass, more preferably 0.5 to 5.0% by mass with respect to the whole composition. is there. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.

Furthermore, in this invention, 1 or more types chosen from the group which consists of a sphingolipid, a ceramide, a cholesterol derivative, and a phytosterol derivative of (E) component can be mix | blended. Examples of sphingolipids include sphingophospholipids such as sphingomyelin, glycosphingolipids such as cerebroside and ganglioside, and various plants extracted from plants such as corn, wheat germ, rice bran, spinach, Shirohirotake and evening primrose. Sex sphingolipids. Ceramide is a sphingosine in which a fatty acid is amide-bonded. Ceramide 1, ceramide 2, ceramide 3, ceramide 4, ceramide 5, ceramide 6 are listed as natural ceramides, and pseudo-ceramides produced by chemical synthesis, etc. Can be mentioned. Examples of cholesterol derivatives include hydrogenated dihydrocholesterol, esters with lower or higher fatty acids, such as cholesteryl hydroxystearate, cholesteryl oleate, cholesteryl isostearate, lanolin fatty acid cholesteryl, macadamia nut oil fatty acid cholesteryl, nonoleate cholesteryl. In addition, cholesteryl stearate, cholesteryl butyrate, and the like are commercially available. Examples of phytosterol derivatives include β-sitosterol, stigmasterol, campesterol, and esters of these hydrogenated compounds and lower or higher fatty acids, such as rice bran oil fatty acid phytosteryl, oleic acid phytosterol, nonanoic acid phytosterol. In addition, phytosterol stearate, phytosterol butyrate and the like are commercially available.

Moreover, in order to dissolve the sphingolipids, ceramides, cholesterols and phytosterols, a liquid oil can be blended in the hair cosmetic composition of the present invention. Specific examples of liquid oils include liquid hydrocarbons such as liquid paraffin and squalane, olive oil, macadamia nut oil, jojoba oil, liquid lanolin and other liquid animal and plant extract oils, silicone oil, perfluorinated oils, fatty acids and higher alcohols. And liquid ester oils obtained.

Among these (E) components, ceramide and phytosterol derivatives are particularly preferable in terms of economy and effect. Moreover, these (E) components can be used 1 type or in combination of 2 or more types, The compounding quantity becomes like this. Preferably it is 0.01-10%, More preferably, it is 0.1-5%. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.

The hair cosmetic composition of the present invention is prepared by using the above-mentioned hydroxy ether cation, ether amine, and higher alcohol as essential components, and adding them to water or a solution obtained by adding an appropriate solvent to water. In addition to these essential components, other components generally blended in hair cosmetics can be blended depending on the purpose within a range not impairing the effects of the present invention.

Examples of such components include anionic surfactants such as lauryl sulfate, polyoxyethylene lauryl sulfate, lauryl benzene sulfonate, sodium lauroylmethy-β-alanine; 2-alkyl-N-carboxymethyl -Amphoteric surfactants such as N-hydroxyethyl imidazolium betaine, coconut oil fatty acid amidopropyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethyl imidazolinium betaine sodium: polyoxyethylene alkyl ether, polyoxyethylene sorbitan Nonionic surfactants such as fatty acid esters and glycerin fatty acid esters; polymers such as cationized cellulose, hydroxyethyl cellulose, poly (diallyldimethylammonium chloride), and highly polymerized polyethylene glycol Compound: Wetting agent such as glycerin, propylene glycol, butylene glycol, dipropylene glycol; higher fatty acid such as stearic acid, behenic acid, oleic acid; ester oil such as isopropyl myristate; hydrocarbon such as liquid isoparaffin, petrolatum, squalane Silicones such as dimethylpolysiloxane, highly polymerized silicone and polyether-modified silicone; antidandruff components such as zinc pyrithione and benzalkonium chloride; lower alcohols such as ethanol, methanol, propyl alcohol and isopropyl alcohol; L-aspartic acid, L -Amino acids such as sodium aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, L-threonine; other UV absorbers, preservatives, sugars, fragrances, colorants, metals Examples include ion sequestering agents, antioxidants, and various drugs.

The hair cosmetic composition of the present invention can be used for hair rinses, hair conditioners, hair treatments, hair packs, hair lotions, hair liquids, hair creams, hair foams, leave-on treatments, permanent agents, hair colors, and the like. The hair cosmetic composition of the present invention can be produced by a conventional method.

EXAMPLES Next, although this invention is demonstrated in detail using an Example, this invention is not limited by this. Prior to the examples, test methods and evaluation methods employed in each example will be described.

(1) Hair moisture retention test method The hair bundle treated with each sample is allowed to stand for 24 hours under conditions of a temperature of 25 ° C. and a humidity of 90%, and then its mass is measured. Thereafter, after being left for 24 hours under conditions of a temperature of 25 ° C. and a humidity of 30%, the mass is measured, and the relative value when the mass under the condition of a humidity of 90% is set to 1 is obtained as moisture retention. A larger value indicates higher moisture retention.

(2) Feeling test method during use 20 panels use samples, and the hair familiarity and fingering during use are judged in three stages: “good”, “normal”, and “bad”. Judgment was based on the number of respondents who answered “good”.
Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less

(3) Hair finish feeling test method after use 20 panels use samples to judge the moist feeling and suppleness of the hair after use in three stages: “good”, “normal”, and “bad”. The judgment result was judged by the number of people who answered “good”.
Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less

(4) No rustling in low humidity environment, moist feeling Commercially available black hair (10 g, 15 cm, manufactured by Beaulux) was shampooed with 2 g of 10% polyoxyethylene (2E.O.) sodium lauryl ether sulfate. After thoroughly rinsing with hot water, 2 g of the hair rinse composition of the present invention was applied, rinsed thoroughly with hot water, towel-dried, and dried in an environment of 25 ° C. and 60% humidity for 6 hours. Next, let it stand in a low humidity environment (25 ° C, 30% humidity) for 12 hours, and there are three stages of "good", "normal", and "bad" with 20 panelists on the items of non-pumpiness and moisture feeling. Judgment was made based on the number of people who answered “good”.
Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less

Examples 1 to 13 and Comparative Examples 1 to 5 (hair rinse)
Prepare hair rinses with the composition shown in Tables 1 to 3, moisture retention of hair, familiarity with hair during use, feeling of use such as fingering, finished feeling after use, lack of roughness under low humidity, moisture The feeling was examined, and the results are shown in Tables 1-3.

As is apparent from Tables 1 to 3, the hair cosmetic composition according to the present invention exhibited superior performance as compared with the composition of the comparative example.

Hereinafter, other formulation examples of the hair cosmetic composition of the present invention will be given as examples. In addition, for the hair cosmetics of these examples, the moisture retention of the hair, the familiarity with the hair during use, the feeling of use as a finger, the feeling of finish after use, the lack of roughness under low humidity, moisture When each item of feeling was examined, all the examples had excellent characteristics and were good.

Example 14 (hair conditioner)
Compounding amount (%)
(1) Behenyl PG trimonium chloride 1.0
(2) Stearyl PG trimonium chloride 1.0
(3) Stearoxypropyldimethylamine 0.5
(4) Cetostearyl alcohol 6.5
(5) Behenyl alcohol 0.5
(6) Methyl polysiloxane (300 cs) 0.5
(7) Highly polymerized methylpolysiloxane (100,000 cs) 1.0
(8) Rice bran oil fatty acid phytosteryl 2.0
(9) Lactic acid 0.3
(10) Paraffin 1.0
(11) Propylene glycol 0.5
(12) Sorbitol 3.0
(13) Glycerin 0.5
(14) Ceramide 2 0.1
(15) Corn-derived sphingolipid 0.1
(16) Hydroxyethyl cellulose 0.4
(17) Phenoxyethanol 0.2
(18) Fragrance 0.5
(19) Make the total amount of purified water 100

(Production method) (1) to (14) were uniformly mixed and dissolved at 80 ° C., and (15) to (17) dispersed in (19) heated to 80 ° C. was added with stirring with a propeller. , Emulsification. The hair conditioner was prepared by gradually cooling, adding (18) at 60 ° C., and cooling to room temperature.

Example 15 Hair Treatment
Compounding amount (%)
(1) Behenyl PG trimonium chloride 2.0
(2) Stearoxypropyldimethylamine 1.0
(3) Myroxypropyldimethylamine 0.5
(4) Cetostearyl alcohol 6.0
(5) Behenyl alcohol 3.0
(6) Methyl polysiloxane (100 cs) 2.0
(7) Highly polymerized methylpolysiloxane (100,000 cs) 5.0
(8) Rice bran oil fatty acid phytosteryl 3.0
(9) Sericin 0.5
(10) Lactic acid 0.4
(11) Paraffin 2.0
(12) White petrolatum 1.0
(13) 1,3-butylene glycol 3.0
(14) Cholesteryl hydroxystearate 0.5
(15) Cerebroside 0.1
(16) Cypress extract 0.5
(17) Hydrolyzed wheat powder 1.0
(18) LIPIDURE-C (manufactured by NOF Corporation) 1.0
(19) Preservative (Caisson CG) 0.1
(20) Fragrance 0.5
(21) 100% purified water

(Production Method) (1) to (4), (6) and (8) to (13) are uniformly mixed and dissolved at 80 ° C. to obtain an oil phase. (7) and (21) are uniformly mixed and stirred at 60 ° C. to obtain an aqueous phase. After the oil phase is added to the aqueous phase and emulsified, (5) and (14) to (19) are added and mixed uniformly using a homomixer. While mixing, the mixture was gradually cooled, (20) was added at 40 ° C., and the mixture was cooled to room temperature to prepare a hair treatment.

Example 16 Out bath treatment
Compounding amount (%)
(1) Behenyl PG trimonium chloride 1.0
(2) Stearoxypropyldimethylamine 0.5
(3) Myroxypropyldimethylamine 0.2
(4) Cetyl alcohol 4.0
(5) Silicone aqueous emulsion 2.0
(XS65-B7116, manufactured by GE Toshiba Silicon Corporation)
(6) Rice bran oil fatty acid phytosteryl 3.0
(7) Cholesteryl oleate 1.0
(8) 1,3-butylene glycol 2.0
(9) Diethyl sebacate 3.0
(10) Nori protein hydrolyzate 2.0
(Pure Porphyra PE, manufactured by Shiroko Co., Ltd.)
(11) Glycolic acid 0.2
(12) Phenoxyethanol 0.2
(13) Fragrance fine amount (14) Purified water Total amount is 100

(Production method) (1) to (4) and (6) to (8) are uniformly mixed and dissolved at 80 ° C, and (9) to (12) and (14) are mixed at 70 ° C. While emulsifying and mixing and dispersing with a homomixer, (5) and (13) were added at 60 ° C. and cooled to room temperature to prepare an out bath treatment.

Example 17 Hair Pack
Compounding amount (%)
(1) Behenyl PG trimonium chloride 0.5
(2) Stearoxypropyldimethylamine 2.0
(3) Behenyl alcohol 5.0
(4) Cetostearyl alcohol 5.0
(5) Rice bran oil fatty acid phytosteryl 1.0
(6) Silicone aqueous emulsion 6.0
(XS65-B7116, manufactured by GE Toshiba Silicon Corporation)
(7) Hydroxyurea 1.0
(8) PG 3.0
(9) Diethyl sebacate 1.0
(10) Lactic acid 0.5
(11) Phenoxyethanol 0.2
(12) Fragrance 0.6
(13) Total amount of purified water is 100

(Production method) (1) to (5) are uniformly mixed and dissolved at 80 ° C, and (8) to (13) mixed at 50 ° C are added and emulsified, and mixed and dispersed with a homomixer. (6) to (7) were added at 50 ° C. and cooled to room temperature to prepare a hair pack.

Example 18 Treatment Form
Compounding amount (%)
(1) Behenyl PG trimonium chloride 0.5
(2) Stearoxypropyldimethylamine 0.2
(3) cetostearyl alcohol 1.0
(4) Methyl polysiloxane (300 cs) 0.5
(5) Polyether-modified silicone 0.5
(Silicon FZ-4173, Toray Dow Corning)
(6) Rice bran oil fatty acid phytosteryl 1.0
(7) Macadamia nut oil fatty acid cholesteryl 0.2
(8) Ceramide 1 / ceramide 5 mixture (1: 1) 0.1
(9) Lactic acid 0.2
(10) Polyoxyethylene (20) cetyl ether 1.0
(11) Polyoxyethylene (60) hydrogenated castor oil 0.5
(12) 1,3-butylene glycol 0.5
(13) Phenoxyethanol 0.5
(14) Total amount of purified water is 100

(Manufacturing method) (1) to (11) are uniformly mixed and dissolved at 80 ° C and added to (14) heated to 80 ° C while stirring with a propeller to emulsify. The mixture was gradually cooled, (12) and (13) were added at 60 ° C., and cooled to room temperature to obtain a stock solution. Next, the aerosol pressure vessel was filled with stock solution: LPG gas at a ratio of 92: 8 to prepare a treatment foam.

As described above, the present invention provides a hair cosmetic that can give a supple and moist finish without feeling sticky or heavy, and that is excellent in prevention of moisture and moisture in low humidity. can do.

Claims (4)

A hair cosmetic containing the following components (A) to (C).
(A) Hydroxy ether type cation represented by the following general formula (I) R ¹ — (OCH ₂ CH (OH) CH ₂ ) _m —N ⁺ (R ² ) ₃ · X ⁻ (I) (wherein R ¹ is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R ² is an alkyl group having 1 to 3 carbon atoms, m is an integer of 1 to 3, X is a halogen atom or 1 carbon atom ˜3 alkyl sulfate groups.)
(B) Ether type amine represented by the following general formula (II) R ³ —O— (CH ₂ ) _n —N (R ⁴ ) ₂ (II)
(In the formula, R ³ represents a linear or branched saturated or unsaturated fatty acid residue having 12 to 22 carbon atoms, R ⁴ represents an alkyl group having 1 to 3 carbon atoms, and n represents an integer of 1 to 5)
(C) A higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms The hair cosmetic composition according to claim 1, wherein the hydroxy ether type cation of component (A) is behenyl PG trimonium chloride. Furthermore, (D) Hair cosmetics in any one of Claims 1-2 containing a silicone derivative. Furthermore, (E) 1 or more types chosen from the group which consists of a sphingolipid, a ceramide, a cholesterol derivative, and a phytosterol derivative are contained, The hair cosmetics in any one of Claims 1-3 characterized by the above-mentioned.