JP2008156516A - Perfume particle and detergent composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide perfume particles imparting excellent perfume to washed articles and excellent in persistency of perfume without involving deterioration of the perfume of a detergent even in long-term storage when the particles are used in a state mixed with powdery detergent, and a detergent composition using the perfume particles. <P>SOLUTION: The present invention relates to perfume particles characterized in that a perfume material is carried on a powdery nonionic cellulose ether used as a carrier. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a fragrance particle, particularly a fragrance particle that can be suitably used for a detergent, and a detergent composition using the fragrance particle.

Conventionally, perfumes have been added to detergents in order to impart a favorable scent to the product itself and the item to be washed. As a method for adding a fragrance to a powder detergent, a method in which a liquid fragrance is sprayed and adsorbed on a detergent particle with a trommel or the like is a general method.
However, this method has an unfavorable effect on the quality of the fragrance and the physical properties of the detergent particles because the fragrance is in direct contact with other detergent components typified by alkaline agents such as sodium carbonate, and during the storage period of the detergent composition. This caused a problem that the quality of the fragrance deteriorated. Therefore, in recent years, in order to avoid direct contact between the components in the detergent composition and the fragrance that adversely affects the storage stability of the fragrance (Patent Document 1), and to suppress loss due to the volatilization of the fragrance during storage (Patent Document) In order to mask the smell of the enzyme added to the detergent composition 2 or 3) or the detergent composition (Patent Document 4), a method in which a fragrance is supported on another carrier and mixed with detergent particles has been studied.

JP-A-5-506258 JP-A-5-209188 Japanese Patent Laid-Open No. 5-209189 Japanese Patent Laid-Open No. 10-279992

  The present invention further promotes such a technique, and by supporting a fragrance on a cellulose derivative having a specific structure and mixing it with a powder detergent, it is excellent in storage stability of the fragrance in the detergent composition, and excellent in washed objects. It is an object to develop a technology that imparts a fragrance and improves its sustainability.

As a result of intensive studies to solve the above-mentioned problems, the inventors have not only improved the storage stability by simply avoiding direct contact between the fragrance and the detergent component, but also an excellent fragrance carrier, and The present inventors have found that the above-mentioned problems can be solved by supporting a fragrance on a specific cellulose ether that is considered to have a high affinity with the article to be washed, and have reached the present invention.
That is, the present invention relates to a fragrance particle characterized in that a fragrance is supported using powdered nonionic cellulose ether as a carrier.

  When used in a powder detergent, the fragrance particles of the present invention do not cause deterioration of the scent of the detergent even during long-term storage, impart an excellent scent to the washed object, and maintain the scent. It has excellent properties. This is because the perfume particles of the present invention not only improve the storage stability of the perfume, but also the cellulose ether having excellent perfume adsorptivity has a high affinity for the wash, so It is considered that the adsorptivity is increased, the release of the fragrance from the object to be washed is delayed, and the scent of the object to be washed is maintained.

Perfume particles of the present invention The perfume particles of the present invention refer to particles in which a perfume is supported on a powdered nonionic cellulose ether as a carrier. In the particles, the powdered nonionic cellulose ether is contained in an amount of, for example, 1 to 49 parts by mass, preferably 2 to 30 parts by mass, and more preferably 3 to 20 parts by mass with respect to 1 part by mass of the fragrance. . When the ratio of the powdered nonionic cellulose ether to 1 part by mass of the fragrance is 1 part by mass or more, the stability during storage of the fragrance particles is improved and the detergent composition containing the fragrance particles is washed. The scent of the washing object and the persistence of the scent are improved. On the other hand, by setting it to 49 parts by mass or less, the blending amount of the fragrance in the particles is not relatively reduced, and when blending the fragrance particles in the detergent composition, avoiding an excessive increase in the blending amount. it can.

Although the particle diameter of the fragrance particles of the present invention is not particularly limited, it is 37 to 710 μm, preferably 37 to 500 μm, more preferably 37 to 350 μm as a 50% weight median diameter. When the particle diameter is 37 μm or more, fluidity is improved. On the other hand, solubility becomes favorable because it is 710 micrometers or less.
The value of the particle diameter is a value measured by the following method. Classification operation was performed using a 9-stage sieve and a tray with openings of 1000 μm, 710 μm, 500 μm, 350 μm, 250 μm, 149 μm, 105 μm, 74 μm, and 37 μm. In the classification operation, a sieve with a small opening is stacked on a tray in the order of a large opening, and a base sample of 100 g / time is placed on the top of the top 355 μm sieve, and a lid is covered and a low-tap type sieve shaker (( Attached to Iida Seisakusho Co., Ltd., Tapping: 156 times / minute, Rolling: 290 times / minute), and after vibrating for 10 minutes, the sample remaining on each sieve and the saucer was collected for each sieve, The mass of was measured. When the mass frequency of the tray and each sieve is integrated, the opening of the first sieve where the integrated mass frequency is 50% or more is set to a μm, and the opening of the sieve that is one step larger than a μm is set to b μm. The average particle size (weight: 50%) was calculated by the following equation, where c% was the cumulative mass frequency from the sieve to the aμm sieve and d% was the mass frequency on the aμm sieve.
[Formula 1]

Materials used in the present invention
Powdered nonionic cellulose ether In the present invention, a specific cellulose ether is used as a perfume carrier. Since the cellulose ether used in the present invention has a cellulose structure, it has a high affinity for the article to be washed and is thought to increase the perfume delivery to the article to be washed. Therefore, when the fragrance particles are prepared using cellulose ether as a fragrance carrier, not only the direct contact between the fragrance and the detergent component is avoided, but the storage stability is improved, and the fragrance adsorbability to the washing object is increased, and the sustained release is performed. Shows effect and contributes to fragrance sustainability.
The nonionic cellulose ether of the present invention is preferably in a powder form. Thus, by using powdery nonionic cellulose ether, it becomes possible to produce perfume particles having high storage stability and easy handling. In the present specification, the term “powder” is not limited to what is generally referred to as powder, but also includes a granular form such as a granule and a fibrous form. In particular, the specific water-soluble cellulose ether in the present invention is a fine powder having a fibrous or granular surface with large irregularities, and is an adsorption carrier excellent for a fragrance and preferably exhibits a swelling property by adsorbing a large amount of the fragrance.

The particle size is preferably 1000 μm or less, and the average particle size is preferably 30 to 200 μm, preferably 30 to 150 μm, more preferably 40 to 100 μm as a 50% weight median diameter. Dust generation is suppressed when the average particle size is 30 μm or more. On the other hand, when it is 200 μm or less, the carrying capacity of the fragrance is improved.
The value of the particle size is a value measured by the following method. Classification operation was performed using a 9-stage sieve having a mesh opening of 350 μm, 250 μm, 177 μm, 149 μm, 105 μm, 74 μm, 63 μm, 44 μm, and 37 μm and a tray. In the classification operation, a sieve with a small opening is stacked on a tray in the order of a large opening, and a base sample of 100 g / time is placed on the top of the top 355 μm sieve, and a lid is covered and a low-tap type sieve shaker (( Attached to Iida Seisakusho Co., Ltd., Tapping: 156 times / minute, Rolling: 290 times / minute), and after vibrating for 10 minutes, the sample remaining on each sieve and the saucer was collected for each sieve, The mass of was measured. When the mass frequency of the tray and each sieve is integrated, the opening of the first sieve where the integrated mass frequency is 50% or more is set to a μm, and the opening of the sieve that is one step larger than a μm is set to b μm. The average particle size (weight: 50%) was calculated by the following equation, where c% was the cumulative mass frequency from the sieve to the aμm sieve and d% was the mass frequency on the aμm sieve.
[Formula 2]

  Specific examples of nonionic cellulose ethers that can be used are, for example, hydroxyethylcellulose (HEC), methylcellulose (MC) hydroxypropylcellulose (HPC), hydroxypropylmethylcellulose (HPMC), and hydroxyethylmethylcellulose (HEMC). These can be used alone or in combination. The combination and the ratio of the combination are arbitrarily changed according to the performance required for the finally obtained perfume particles. It is possible. These nonionic cellulose ethers are, for example, HEC from Daicel Chemical Industries, Ltd. as HEC SE series (SE400, 600, 850, 900), MC from Shin-Etsu Chemical Co., Ltd. as Metros SM series, Matsumoto Yushi Seiyaku From Maruberose series to HPC, from Nihon Soda Co., Ltd. to NISSO HPC series, from HPMC from Shin-Etsu Chemical Co., Ltd. as Metroze 60SH, Metroze 65SH, Metroze 90SH series, and from HEMC as Shin-Etsu Chemical Co., Ltd. ) Is available as Metroise SEB and Metroise SNB series.

As the nonionic cellulose ether of the present invention, a water-soluble cellulose ether is used. By using a water-soluble material, the risk of undissolved residue when washing clothes is reduced.
In the present invention, HPMC can be particularly preferably used. The HPMC preferably has a mass average molecular weight of 10,000 or more, preferably 100,000 or more, more preferably 200,000 or more. When the molecular weight is 10,000 or more, the adsorptivity to an object to be washed is improved. The HPMC preferably has 19 to 38% by mass, preferably 22 to 36% by mass, and more preferably 25 to 32% by mass, based on the mass of HPMC. Further, the HPMC preferably has 2 to 16% by mass, preferably 3 to 14% by mass, more preferably 4 to 12% by mass of hydroxypropoxyl group based on the mass of HPMC. The HPMC preferably has a methoxyl group substitution degree of 1.0 to 2.5, preferably 1.4 to 2.3, and more preferably 1.6 to 2.0. Since such HPMC also has a high affinity for the fragrance and the object to be washed, the adsorptivity of the fragrance is increased, and the fragrance of the object to be washed can be maintained in order to delay the release of the fragrance from the object to be washed. Such HPMC is, for example, from Metropolitan 60SH10000 from Shin-Etsu Chemical Co., Ltd. (mass average molecular weight 380,000, methoxyl group substitution degree 1.9, methoxyl group 28-30% by mass, hydroxypropoxyl group 7-12% by mass, average (Particle size 62 μm), Metrolose 65SH40000 (mass average molecular weight 300,000, methoxyl group substitution degree 1.8, methoxyl group 27-30% by mass, hydroxypropoxyl group 4-7.5% by mass, average particle size 66 μm) are commercially available .

The mass average molecular weight can be measured by gel filtration chromatography (GPC) -multi-angle laser light scattering detector (MALLS) system. The apparatus is a liquid feed pump: Shodex DS-4 (manufactured by Showa Denko), degasser: ERC3115 (manufactured by ERC), column: Shodex SB-806MHQ (manufactured by Showa Denko), light scattering detector: DOWN (manufactured by Wyatt Technology) Concentration detector: Shodex RI-71 (manufactured by Showa Denko), operating conditions are eluent: 0.1 M NaNO ₃ 1.0 ml / min, sample: 0.02 to 0.3 mass% solvent is 0.1 M NaNO ₃ Injection amount: 200 μm.

Perfume As the perfume that can be used in the present invention, any perfume that is usually used in laundry products can be used.
Such fragrances include various documents such as “Perfume and Flavor Chemicals”, Vol. Iand II, Steffen Arctander, Allured Pub. Co. (1994) and "Synthetic fragrance chemistry and commercial knowledge", Motoichi Into, Chemical Industry Daily (1996) and "Perfume and Flavor Materials of Natural Origin", Stephen Arctander, Allred Pub. Co. (1994) and "Encyclopedia of Scents", edited by Japan Fragrance Association, Asakura Shoten (1989) and "Performer Material Performance V.3.3", Boelens Aroma Chemical Information Service (1996) and "Flower Oils". , Danute Lajaujis Anonis, Allured Pub. Co. (1993), etc., each of which is incorporated herein by reference. Although the typical example of a fragrance | flavor is given to the following, it is not limited to these.

  <Hydrocarbon-based compounds> Osimene, dihydromyrcene, farnesene, cedrene, α-pinene, β-pinene, limonene, dipentene, camphene, ferrandrene, terpinene, 3-carene, terpinolene, bisabolene, β-caryophyllene, kadinene, valencene , Tyuopsen, Guayen, Allocymene, Myrcene, Longifolene, Verdracine (1,3,5-undecatriene), p-cymene, 4-isopropyl-1-methyl-2-propenylbenzene, diphenyl, diphenylmethane, orange terpene, lemon terpene , Bergamot terpene, peppermint terpene, spearmint terpene, lime terpene, vetiver terpene, rose wax, jasmine wax, limonene dimer, pentane, hexane, heptane, oct , Nonane, decane, undecane, dodecane, tridecane, tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane, icosane, henicosan, docosan, tricosane, tetracosane, pentacosan, hexacosane, heptacosan, octacosane, nonacosan, triacontane, etc. .

<Alcohol-based compound> 3-methyl-1-pentanol, geraniol, cedrol, citronellol, rosinol, nerol, dihydrolinalol, linalool, tetrahydrolinalool, dimethyloctanol, tetrahydromumol, mugol, myrsenol, dihydromyrsenol, osimenol, Tetrahydromyrcenol, lavandulol, isodihydrolavandulol, hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), ethyl linalool, isopulegol, terpineol, dihydroterpineol, terpineol-4, perilla alcohol, 4- Tweenol, 3-Tyanol, farnesol, nerolidol, α-bisabolol, β-caryophyllene alcohol, santalol, vetivero , Cedrenol, patchoulialcohol, dihydrocarbeole, phytol, isophytol, sclareol, carveol, menthol, 1-heptanol, 2-heptanol, 3-heptanol, 1-octanol, 2-octanol, 3-octanol, 2-ethyl Hexanol, 1-nonanol, 2-nonanol, isononyl alcohol (3,5,5-trimethyl-1-hexanol), 1-decanol, 1-undecanol, 2-undecanol, 1-dodecanol, prenol (3-methyl-2 -Buten-1-ol), 2-methyl-3-buten-2-ol, β-pentenol (1-penten-3-ol), leaf alcohol (cis-3-hexenol), trans-2-hexenol, trans-3-hexe Cis-4-hexenol, 2,4-hexadien-1-ol, Matsutakeol (1-octen-3-ol), cis-6-nonenol, cucumbar alcohol (2,6-nonadienol), androll (1-nonen-3-ol), Rosalba (9-decenol), 1-undecenol, undecavertol (4-methyl-3-decen-5-ol), osylol (3,7-dimethyl-7-methoxy) -2-octanol), santalinol (2-methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), p, α-dimethylbenzyl alcohol, 2,2,6-trimethylcyclohexyl-3-hexanol, 1,2-pentanediol, benzyl alcohol, anise alcohol, -Phenylethyl alcohol, styryl alcohol (1-phenyl-1-hydroxyethane), hydratropa alcohol, methyl β-phenylethyl alcohol, α-propylphenylethyl alcohol, vanillyl alcohol, decahydro β-naphthol, furfuryl alcohol 3-methyl-1-phenyl-3-pentanol, amyl cinnamic alcohol, cinnamic alcohol, phenoxanol (3-methyl-5-phenyl pentanol), 1,2-pentanediol, 2-ethylhexanol, Dimethol (2,6-dimethylheptanol), 3,6-dimethyl-3-octanol, kohinol (3,4,5,6,6-pentamethyl-2-heptanol), brahamanol (methyltrimethylcyclopentenylbutanol), Vacdanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), sandalol (3-methyl-5- (2,2,3 -Trimethylcyclopent-3-en-yl) -pentan-2-ol), cyclohexyl ethyl alcohol, apopathion (p-isopropylcyclohexanol), floralol (2,4-dimethyl-3-cyclohexene-1-methanol), patch (P-tert-butylcyclohexanol), verdol (o-tert-butylcyclohexanol), mayol (p-isopropylcyclohexylmethanol), cyclomethylenecitronellol, ambrinol (2,5,5-trimethyl-octahydro-2-naphthol) ), Methyl sand deflor (5 ' or6′-methylnorborn-5′-en-2-yl) -2-methylpent-1-en-3-ol), timberol (2,2,6-trimethylcyclohexyl-3-hexanol), polysanthol (3 , 3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), Isopulegol, isocyclogeraniol, myrtenol, nopol (6,6-dimethylbicyclo [3.1.1] hept-2-en-2-ethanol), pinocarbeveol, α-fenkyl alcohol, borneol, isoborneol, Pachomint (2- (3,3-dimethylbicyclo [2.2.1] hept-2-ylidene) ethanol) , Camechol (trimethylnorbornanemethanol), dimethylcyclomol, Santarex T (isocamphylcyclohexanol), geranyl linalool, cumin alcohol, 2-methoxyphenylethyl alcohol, phenoxyethyl alcohol (1-hydroxy-2-phenoxyethane), α, α-dimethylphenyl ethyl alcohol, isobutyl benzyl carbinol, p-methyl benzyl carbinol, hydrocinnamic alcohol, centifol (1,1-dimethyl-3-phenylpropanol-1), muget alcohol (2,2 -Dimethyl-3-phenylpropanol), phenylhexanol, decahydro β-naphthol, AR-1 (3,6-dimethyloctane-3-ol), abitol (hydroabiethyla Coal), α-propylphenylethyl alcohol, p-methyldimethylbenzylcarbinol, mugetanol (1- (4-isopropylcyclohexyl) ethanol), Florol (2-isobutyl-4-hydroxy-4-methyltetrahydropyran), propylene glycol , Dipropylene glycol, hexylene glycol and the like.

<Phenolic and phenolic ether compounds> Anisole, estragole, chabicol, anethole, cresol, carvacrol, p-cresol, p-cresyl methyl ether, β-naphthol methyl ether, β-naphthol ethyl ether, β-naphthol isobutyl Ether, veratrol (1,2-dimethoxybenzene), 1,3-dimethoxybenzene, 1,4-dimethoxybenzene, catechol, resorcinol, guaiacol, valspice (4-methylguaiacol), 4-ethylguaiacol, orcinyl 3 (3 -Methoxy-5-methylphenol), thymol, methylthymol, propenyl guaetol (trans-2-ethoxy-5- (1-propenyl) -phenol), o-ethylphenol, m-ethyl Ruphenol, p-ethylphenol, 2-tert-butylphenol, syringol (2,6-dimethoxyphenol), hydroquinone dimethyl ether, resorcin dimethyl ether, eugenol, isoeugenol, dihydroeugenol, methyl eugenol, methylisoeugenol, ethylisoeugenol, Benzyl eugenol, benzyl isoeugenol, diosphenol, hinokitiol, banitrop (1-ethoxy-2-hydroxy-4-propenylbenzene), shogaol, gingerol, acetyl eugenol, acetyl isoeugenol safrole, isosafrole, diphenyl oxide, vetiver ether ( tert-butyl hydroquinone dimethyl ether) and the like.

<Aldehyde compound> Citronellal, citral, 3,7-dimethyl-1-octanal, hydroxycitronellal, methoxycitronellal, perilaaldehyde, myrtenal, caryophyllenaldehyde, n-hexal, 2-methylbutanal, isovaleraldehyde N-valeraldehyde, acetaldehyde, n-heptanal, n-octanal, n-nonanal, 2-methyloctanal, 3,5,5-trimethylhexanal, 1-decanal, undecanal, dodecanal, 2-methyldecanal, 2-methylundecanal, tridecanal, tetradecanal, 2-pentenal, cis-3-hexenal, trans-2-hexenal, trans-2-heptenal, 4-heptenal, trans 2-octenal, trans-2-nonenal, cis-6-nonenal, meronal (2,6-dimethyl-5-heptenal), trans-4-decenal, cis-4-decenal, trans-2-decenal, grinal (2 , 5,6-trimethyl-4-heptenal), 10-undecenal, trans-2-undecenal, trans-2-dodecenal, mandarinaldehyde (3-dodecenal), trans-2-tridecenal, adxal (2,6,10- Trimethyl-9-undecen-1-al), 2,4-hexadienal, 2,4-heptadienal, 2,4-octadienal, 2,4-nonadienal, 2,6-nonadienal, 2,4-decadienal , 2,4-Undecadienal, 2 4-dodecadienal, geraldaldehyde (5,9-dimethyl-4,8-decadienal), trimenal (3,7,9-trimethyl-2,6-decadien-1-al), oncidar (2,6,10-trimethyl-) 5,9-undecadienal), bergamar (α-methylenecitronellal), camphorene aldehyde, cyclocitral, isocyclocitral, safranal (2,6,6-trimethyl-1,3-cyclohexadiene-1 -Carboxaldehyde), mugealdehyde (6,10-dimethyl-3-oxa-9-undecenal), geranyloxyacetaldehyde, tripral (dimethyltetrahydrobenzaldehyde), chrysantal (3-propylbicyclo [2,2,1] -5 Heptene-2-carboxyal Hydr), centenal (methoxydicyclopentadiene carboxaldehyde), dupical (4-tricyclodecylidenebutanal), 4- (4-methyl-3-cyclohexenylidene-1) pentanal, mylacaldehyde (4 (3) -(4-Methyl-3-penten-1-yl) -3-cyclohexene-1-carboxaldehyde), Setneral (trimethylcyclohexenemethylbutanal), Inonal (2-methyl-4- (2,6,6-trimethyl) -1 (2) -cyclohexenyl) -butenal), telestral (4-cyclooctene-1-carboxaldehyde), benzaldehyde, p-tolylaldehyde, phenylacetaldehyde, trifernal (3-phenylbutanal), cuminaldehyde, p-methyl Phenylacetaldehyde, p-isopropylphenylacetaldehyde, hydratropaldehyde, p-methylhydratropaldehyde, p-isopropylhydratropaldehyde, phenylpropionaldehyde, β-methylhydrocinnamic aldehyde, jasmolandi (2-methyl-3- (4-methylphenyl) -propanal), burgeonal (p-tert-butylhydrocinnamic aldehyde), cyclamenaldehyde (2-methyl-3- (p-isopropylphenyl) -propionaldehyde), florarozone (p-ethyl) -Α, α-dimethylhydrocinnamic aldehyde), suzaral (p-isobutyl-α-methylhydrocinnamic aldehyde), synamic aldehyde, salicylaldehyde, anis alde , O-methoxybenzaldehyde, o-methoxycinnamic aldehyde, cantoxal (2-methyl-3- (p-methoxyphenyl) -propanal), vanillin, ethyl vanillin, methyl vanillin (3,4-dimethoxybenzaldehyde), helio Tropine, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde), phenoxyacetaldehyde, p-methylphenoxyacetaldehyde, furfural, 5-methylfurfural, 5-hydroxymethyl-2-furfural, furylacrolein, rilal (4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), Bernaldehyde (1-methyl-4- (4-methylpentyl) -3-cyclohex Sencarboxaldehyde), homomylacaldehyde (1-methyl-4 (4-methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde), junipal (4 (5) -formyl-7,7,9-trimethylbicyclo) [4.3.0] -nonene), vertoral (octahydro-4,7-methanoindenecarboxaldehyde), lyial (p-tert-butyl-α-methylhydrocinnamic aldehyde), mefranal (3-methyl-5) -Phenylvaleraldehyde), eglantal (4-methyl-2-phenyl-2-pentenal), cocarl (5-methyl-2-phenyl-2-hexenal), α-methyl cinnamic aldehyde, α-butyl cinnamic aldehyde, α-amylcinnamic aldehyde, α-hexy Rucinnamic aldehyde, formylethyltetramethyltetralin (6-ethyl-7-formyl-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene) and the like.

<Acetal and ketal compounds> Magnolan (2,4-dimethyl-4,4a, 5,9b-tetrahydroindeno [1.2d] -1,3-dioxane), anthoxane (4-isopropyl-5,5 -Dimethyl-1,3-dioxane), indofur (dihydroindenyl-2,4-dioxane), boa sambrene forte (formaldehyde cyclododecylethyl acetal), acetaldehyde diethyl acetal, leaf acetal (acetaldehyde ethyl hexenyl acetal), acetaldehyde Ethylhexyl acetal, citronellyl methyl acetal, erintal (acetaldehyde ethyl linalyl acetal), bonarox (2,4-dioxane-3-methyl-7,10-methanospiro [5.5] undecane) Ephetal (acetaldehyde ethyl phenylacetal), acetaldehyde ethyl isoeugenyl acetal, acetal R (acetaldehyde phenylethyl n-propyl acetal), fluoropearl (acetaldehyde 2-phenyl-2,4-pentanediol acetal), spirofurol (3-ethyl -2,4-dioxaspiro [5.5] undecene-8-ene), ethyldimethyldioxaspiroundecene, herboxan (2-butyl-4,4,6-trimethyl-1,3-dioxane), caranal (2 -(2,4-dimethylcyclo-3-sen-1-yl) -5-methyl-5 (1-methylpropyl) 1,3-dioxane), hexanal dimethyl acetal, hexanal diethyl acetal, hexanal propylene Glycol acetal, carotene (4,7-dihydro-2- (3-pentanyl) -1,3-dioxepin), 2-hexenal diethyl acetal, cis-3-hexenal diethyl acetal, heptanal dimethyl acetal, heptanal diethyl acetal, Heptanal ethylene glycol acetal, 2-hexyl-5-methyl-1,3-dioxolane, 5-methyl-5-propyl-2- (1-methylbutyl) -1,3-dioxane, octanal dimethyl acetal, octanal diethyl Acetal, nonanal dimethyl acetal, nonanal diethyl acetal, decanal dimethyl acetal, decanal diethyl acetal, 2-methylundecanal dimethyl acetal, dodecanal dimethyl acetal, Citral dimethyl acetal, citral diethyl acetal, citral propylene glycol acetal, citronellal cyclomonoglycol acetal, hydroxy citronellal dimethyl acetal, hydroxy citronellal diethyl acetal, cis-3-hexenal diethyl acetal, benzaldehyde dimethyl acetal, benzaldehyde diethyl acetal , Benzaldehyde propylene glycol acetal, benzaldehyde glycerin acetal, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde ethylene glycol acetal, phenylacetaldehyde diisobutyl acetal, phenylacetaldehyde propylene glycol acetal, phenylacetaldehyde 2 3-butylene glycol acetal, phenylacetaldehyde glyceryl acetal, resedabody (phenylacetaldehyde-2,4-dihydroxy-2-methylpentane acetal), 3-phenylpropionaldehyde dimethyl acetal, hydratropaldehyde dimethyl acetal, hydratropaldehyde ethylene glycol Acetal, osminal DMA (amylcinnamic aldehyde dimethyl acetal), osminal DEA (amylcinnamic aldehyde diethyl acetal), heliotropin dimethyl acetal, heliotropin diethyl acetal, vanillin propylene glycol acetal, verdoxane (2,2,5,5-tetra Methyl-4-isopropyl-1,3-dioxane), amberse (4,7-dihydro-2-isopentyl-2-methyl-1,3-dioxepin), acetoketal (2,5,5-trimethyl-2-phenyl-1,3-dioxane), jasmonan (2-butyl-4 -Dioxaspiro [4.4] nonanone), Freyston (ethyl-2,4-dimethyl-1,3-dioxolane-2-acetate), fructon (ethyl-2-methyl-1,3-dioxolane-2-acetate), etc. Is mentioned.

<Ketone-based compound> Acetyl caryophyllene, carvone, pregon, piperithenone, piperiton, menthone, show brain, oxocedrane, isolongifolanone, nootkatone, 2-heptanone, 2-pentanone, 3-hexanone, 3-heptanone, 4-heptanone, 2-octanone, 3-octanone, 2-nonanone, 3-nonanone, 2-undecanone, 2-tridecanone, methyl isopropyl ketone, ethyl isoamyl ketone, mesityl oxide, butylideneacetone, methylheptadienone, methylheptenone, dimethyloctenone , Coavone (4-methylene-3,5,6,6-tetramethyl-2-heptanone), geranyl acetone, farnesyl acetone, acetoin, butyroin (5-hydroxy-4-octanone), methyl labe Darketone (3-hydroxymethyl-2-nonane), diacetyl, 2,3-pentadione, 2,3-hexadione, 3,4-hexadione, 2,3-heptadione, acetylisovaleryl, amylcyclopentanone, amylcyclo Pentenone, 2-cyclopentylcyclopentanone, hexylcyclopentanone, fluuramon (2-n-heptylcyclopentanone), cis-jasmon, dihydrojasmon, isojasmon, trimethylpentylcyclopentanone, sedamon (2-butylidene-3 , 5,5 (3,3,5) -trimethylcyclopentanone), Sandex (3-methyl-5- (2,2,3-trimethyl-3-cyclopentenyl) -3-penten-2-one) , Cycloten, coronol (3,5-dimethyl-1,2-cycl Pentadione), methylcholylone (3,4-dimethyl1,2-cyclopentadione), verdon (2-tert-butylcyclohexanone), p-tert-butylcyclohexanone, Hellbach (3,3-dimethylcyclohexylmethylketone), frescomente (2-sec-butylcyclohexanone), artemon (1-acetyl-3,3-dimethyl-1-cyclohexene), celly ketone (3-methyl-5-propyl-2-cyclohexenone), krypton (4-isopropyl-2) -Cyclohexanone), olibon (p-tert-pentylcyclohexanone), methylcyclocitron (2,3,5-trimethyl-4-cyclohexenyl-1-methylketone), neron (1- (p-menten-6-yl)- 1-propane), vetiver (4-cyclohexyl-4-methyl-2-pentanone), habanol (2- (1-cyclohexen-1-yl) -cyclohexanone), maltol, ethyl maltol, oxide ketone (cis-2-acetonyl-4-methyl) -Tetrahydropyran), emoxifuron (5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone), homofurol (2-ethyl-4-hydroxy-5-methyl-3 [2H] -furanone and 5-ethyl -4-hydroxy-2-methyl-3 [2H] -furanone), sotron (3-hydroxy-4,5-dimethyl-2 [5H] -furanone), furaneol (2,5-dimethyl-4-hydroxy-3) [2H] -furanone), acetyldimethylfuran, furfural acetone, 2-acetyl-5-methyl Furan, 2-acetylfuran, methyltetrahydrofuranone, dibenzylketone, benzophenone, methylnaphthylketone, 4-damascol (5-phenyl-5-methyl-3-hexanone), ethicon (4-methyl-4-phenyl-2-phenyl) Pentanone), α-methylanisalacetone, heliotropylacetone, anisylideneacetone, anisylacetone, p-methoxyphenylacetone, raspberry ketone (4- (p-hydroxyphenyl) -2-butanone), labandone (3-methyl) -4-phenyl-3-buten-2-one), benzylideneacetone, p-methoxyacetophenone, p-methylacetophenone, propiophenone, acetophenone, damasenone, damascon, isodamascon, α-dynascon (1- (5,5- Zimechi Lucyclohexen-1-yl) -4-penten-1-one), iriton (4- (2,4,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one and 4-3 , 5,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one), ionone, pseudoionone, methylionone, methyliriton (3-methyl-4- (2,4,6-trimethyl-3- Cyclohexenyl) -3-buten-2-one), cyclowood (2,4-di-tert-butylcyclohexanone), iron, allyl ionone, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, Kamek DH (2-acetyl-3,3-dimethylnorbornane), Florex (6-ethylideneoctahydro-5,8-methano-2H-1-benzopyran 2-one), plicatone (4-methyltricyclo [6.2.1.02,7] undecan-5-one), oxocedrane, belt fix (9-acetyl-2,6,6,8-tetramethyltri) Cyclo [5.3.11,7.01,5] -8-undecene), berbenone (4,6,6-trimethyl- (1R) -bicyclohept-3-en-2-one), fenkon, caron (7 -Methyl-3,5-dihydro-2H-benzodioxepin-3-one), trimofix O (2,6,10-trimethyl-1-acetyl-2,5,9-cyclododecatriene), bitalide ( Acetyldimethyltetrahydrobenzindane), epiton (7 (8) -acetyl-5-isopropyl-2-methylbicyclo [2.2.2] oct-2-ene), atrinone (4 (5) -a) Cetyl-7,7,9 (7,7,9) -trimethylbicyclo [4.3.0] -1-nonene), cachemelan (6,7-dihydro-1,1,2,3,3-pentamethyl- 4 (5H) -Indanone), Muscon (3-methylcyclopentadecanone-1), Cybeton (cycloheptadec-9-en-1-one), Exalton (cyclopentadecanone), Musk TM-II (Cyclohexane) Sadesenone), fantolide (5-acetyl-1,1,2,3,3,6-hexamethylindane), celestoride (4-acetyl-6-tert-butyl-1,1-dimethylindane), traceolide (5 -Acetyl-3-isopropyl-1,1,2,6-tetramethylindane), tonalide (6-acetyl-1,1,2,4,4,7-hexamethyltetrahydro) Phthalene), bitalide (acetyldimethyltetrahydrobenzindane), iso-e-super (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl) Naphthalene), dihydrocarbon, diosphenol, gingerone and the like.

<Ether compound> Methyl hexyl ether, decyl methyl ether, decyl vinyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, citronellyl ethyl ether, geranyl ethyl ether, α-terpinyl methyl ether, Herbabert (3, 3, 5 -Trimethylcyclohexyl ethyl ether), isobornyl methyl ether, tricyclodecenyl methyl ether, isoproxen (2-ethylidene-6-isopropoxybicyclo [2.2.1] heptane), juniparome (methoxydimethyltricyclo [ 5.2.1.02,6] decane), cyclododecyl methyl ether, Madrox (1-methylcyclododecyl methyl ether), fizeol (2-ethoxy-2,6,6-tri) Til-9-methylenebicyclo [3.3.1] -nonane), cedlum bar (cedrol methyl ether), methyl benzyl ether, methyl phenyl ethyl ether, ethyl 2-methoxybenzyl ether, allyl phenyl ethyl ether, isoamyl benzyl ether, answer (Isoamylphenyl ethyl ether), jacene (2-methyl-2-butenylphenyl ethyl ether), dibenzyl ether, cyclohexyl phenyl ether, myroxide (oxime epoxide), limonene oxide (p-mentha-8-ene-1, 2-epoxide), rubofix (spiro [1,4-methanonaphthalene-2 (1H), 2'-oxirane],-3,4,4a, 5,8,8a-hexahydro-3 ', 7-dimethyl and spiro [1,4-Me Nonaphthalene-2 (1H), 2′-oxirane], − 3,4,4a, 5,8,8a-hexahydro-3 ′, 6-dimethyl), trimethylcyclododecatriene epoxide, caryophyllene oxide, cedrene epoxide, Isolongifolene epoxide, linalool oxide, citrooxide (2,2-dimethyl-5 (1-methyl-1-propenyl) -tetrahydrofuran), herboxoxide (5-isopropenyl-2-methyl-2-vinyltetrahydrofuran), Rose furan (3-methyl-2- (3-methyl-2-butenyl) -furan), heptabel (2-heptyltetrahydrofuran), mentfuran, theaspiran, oxybet (2-oxaspiro [4,7] dodecane), muskogen (3-oxabicyclo [10.3.0 ] -6-pentadecene), cyclamber (13-oxabicyclo [10.3.0] pentadecane), ambroxan (decahydro-3a, 6,6,9a-tetramethylnaphtho [2.1-b] furan), glycalva (3a-ethyldodecahydro-6,6,9a-trimethylnaphtho [2.1-b] furan), 1,8-cineol, 1,4-cineole, galaxolide (1,3,4,6,7,8 -Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-γ-2-benzopyran), rose oxide, nerol oxide, limetole (2,2,6-trimethyl-6-vinyltetrahydropyran) , Dirane (2-butyl-4,6-dimethyldihydropyran), dremox (tetrahydro-4-methyl-2-phenyl-2H-pyran) Rubofuroa (9 ethylidene-3-oxatricyclo [6.2.1.0 @ 2,7] undecane), hexahydroisochromeno indeno-pyran, and the like.

<Acid compound> Geranic acid, acetic acid, propionic acid, pyruvic acid, butyric acid, isobutyric acid, 2-methylbutyric acid, 2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric acid, 3-methylvaleric acid, Hexanoic acid, isohexanoic acid, 2-hexanoic acid, 4-pentenoic acid, 2-methyl-2-pentenoic acid, heptanoic acid, 2-methylheptanoic acid, octanoic acid, nonanoic acid, decanoic acid, 2-decenoic acid, undecylenic acid , Dodecanoic acid, myristic acid, palmitic acid, stearic acid, anthranilic acid, oleic acid, levulinic acid, lactic acid, benzoic acid, phenylacetic acid, cinnamic acid, 3-phenylpropionic acid, vanillic acid, valine, abietic acid, sorbic acid Etc.

<Lactone compound> Pentalide (cyclopentadecanolide), habanolide (oxacyclohexadecen-2-one), ambletide, cyclohexadecanolide, 10-oxahexadecanolide, 11-oxahexadecanolide , 12-oxahexadecanolide, ethylenedodecandioate, γ-butyrolactone, γ-valerolactone, angelica lactone, γ-hexalactone, γ-heptalactone, γ-octalactone, γ-nonalactone, whiskey lactone (3- Methyl-4-octanolide), [gamma] -decalactone, [gamma] -undecalactone, [gamma] -dodecalactone, [gamma] -jasmolactone, jasmine lactone, cisjasmon lactone, lacto jasmon (4-methyl-4-decanolide), jasmolactone (Tetrahydro-6- (3 Pentenyl) -2H-pyran-2-one), mentalactone (3,6-dimethyl-5,6,7,7a-tetrahydro-2 (4H) -benzofuranone), n-butylphthalide, propylidenephthalide, butylidenephthalate Lido, δ-hexalactone, δ-octalactone, trivalon (4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one), δ-nonalactone, δ-decalactone, δ-2-decenolactone, δ-undecalactone, δ-dodecalactone, δ-tridecalactone, δ-tetradecalactone, lactoskatone (decahydro-4, α-hydroxy-2,8,8-trimethylnaphthalene-2-carboxyacid-δ-lactone ), Coumarin, dihydrocoumarin, cyclohexyl lactone, 6-methylcoumarin, ε-decalacto And ε-dodecalactone.

<Ester compound> Ethyl formate, propyl formate, butyl formate, amyl formate, isoamyl formate, hexyl formate, cis-3-hexenyl formate, octyl formate, linalyl formate, citronellyl formate, geranyl formate, neryl formate, rosinyl formate, terpinyl formate , Cedryl formate, caryopherene formate, afermate (α, 3,3-trimethylcyclohexanemethyl formate), oxyoctaline formate, benzyl formate, cinnamyl formate, phenylethyl formate, anisyl formate, eugenyl formate, decahydro-β-naphthyl formate , Methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, 2-methylbutyl acetate, isoamyl acetate, amyl acetate, prenyl acetate, hexyl acetate, cis-3-hexenyl acetate, t rans-2-hexenyl, 2-ethylhexyl acetate, heptyl acetate, octyl acetate, 3-octyl acetate, octenyl acetate, nonyl acetate, decyl acetate, trimethylhexyl acetate, decenyl acetate, nonanediol acetate, dodecyl acetate, dimethylundecadienyl acetate , Diacetyl, diacetin, triacetin, ethylene glycol diacetate, ethylene glycol monobutyl ether acetate, allyl amyl glycolate, osmenyl acetate, mircenyl acetate, dihydromyrcenyl acetate, dimethyloctanyl acetate, linalyl acetate, citronellyl acetate, rosinyl acetate, acetic acid Geranyl, neryl acetate, tetrahydromugol acetate, ethyl linalyl acetate, lavandulyl acetate, isohydrolavandulyl acetate, nerolidol acetate, carbyl acetate, acetic acid Hydrocarbyl, dihydrocuminyl acetate, terpinyl acetate, isopulegol acetate, menthyl acetate, citryl acetate, myrtenyl acetate, nopyr acetate, fenkyl acetate, bornyl acetate, isobornyl acetate, cedolyl acetate, caryophyllene acetate, santalylacetate, vetiberyl acetate, guaiac acetate Methyl pentylidene acetate, cyclohexyl acetate, p-isopropylcyclohexanyl acetate, tert-amyl cyclohexyl acetate, dihydroterpinyl acetate, cyclohexyl ethyl acetate, fluorolate (2,4-dimethyl-3-cyclohexenylmethyl acetate), rosamsk ( Α, 3,3-trimethylcyclohexanemethyl acetate), Vertenex (p-tert-butylcyclohexyl acetate), Verdox (o-tert-butyl acetate) Chlorhexyl), 1-ethynylcyclohexyl acetate, dihydroambrate (1-acetoxy-2-sec-butyl-1-vinylcyclohexane), miraldyl acetate (4 (3)-(4-methyl-3-pentenyl) -3-cyclo Hexenylmethyl acetate), tricyclodecenyl acetate, tricyclodecyl acetate, benzyl acetate, p-cresyl acetate, phenylethyl acetate, styryl acetate, p-methylbenzyl acetate, anisyl acetate, piperonyl acetate, acetyl vanillin, rosephenone, Hydratropyl acetate, 2,4-dimethylbenzyl acetate, cinnamyl acetate, phenylpropyl acetate, cuminyl acetate, dimethylbenzyl carvinyl acetate, phenyl glycol diacetate, dimethylphenylethyl carvinyl acetate, phenylethyl methyl acetate Lucal vinyl, Beticol acetate (4-methyl-4-phenyl-2-pentyl acetate), α-amylcinnamimil acetate, Jasmalol (trans-decahydro-β-naphthyl acetate), Furfuryl acetate, Tetrahydrofurfuryl acetate, Jasmar ( 3-pentyltetrahydropyranyl acetate), jasmeria (5-methyl-3-butyltetrahydropyranyl acetate), ethyl acetoacetate, jessate (ethyl 2-hexylacetoacetate), ethyl benzylacetoacetate, allyl cyclohexylacetate, cyclohexenylacetic acid Isopropyl, ethyl propionate, propyl propionate, allyl propionate, butyl propionate, isobutyl propionate, isoamyl propionate, hexyl propionate, cis-propionate -Hexenyl, trans-2-hexenyl propionate, decenyl propionate, linalyl propionate, citronellyl propionate, rosinyl propionate, geranyl propionate, neryl propionate, carbyl propionate, terpinyl propionate, menthol propionate, bornyl propionate , Isobornyl propionate, tricyclodecenyl propionate, benzyl propionate, styryl propionate, anisyl propionate, phenylethyl propionate, cinnamil propionate, phenylpropyl propionate, dimethylbenzyl carvinyl propionate, phenoxyethyl propionate Propylene glycol dipropionate propionate, labdanax (3-hydroxy-3-phenylpropionic acid ethyl ), Isobutyl furanpropionate, methyl butyrate, ethyl butyrate, propyl butyrate, isopropyl butyrate, allyl butyrate, butyl butyrate, isobutyl butyrate, amyl butyrate, isoamyl butyrate, hexyl butyrate, heptyl butyrate, cis-3-hexenyl butyrate, trans-butyrate 2-hexenyl, octyl butyrate, propylene glycol dibutyrate, linalyl butyrate, citronellyl butyrate, rosinyl butyrate, geranyl butyrate, neryl butyrate, terpinyl butyrate, cyclohexyl butyrate, benzyl butyrate, cinnamyl butyrate, phenylethyl butyrate, dimethylbenzylcarbyl butyrate, butyric acid Tetrahydrofurfuryl, Santaryl butyrate, methyl isobutyrate, ethyl isobutyrate, propyl isobutyrate, isopropyl isobutyrate, butyl isobutyrate, isobutyl isobutyrate, isoamyl isobutyrate, isobutyrate Xyl, cis-3-hexenyl isobutyrate, 2,4-hexadienyl isobutyrate, isopentylate (1,3-dimethyl-3-butenyl isobutyrate), octyl isobutyrate, linalyl isobutyrate, citronellyl isobutyrate, rosinyl isobutyrate , Geranyl isobutyrate, neryl isobutyrate, terpinyl isobutyrate, tricyclodecenyl isobutyrate, benzyl isobutyrate, p-cresyl isobutyrate, cinnamyl isobutyrate, phenylethyl isobutyrate, phenylpropyl isobutyrate, styryl isobutyrate, iso Dimethylcarbyl butyrate, dimethylphenylethylcarbyl isobutyrate, floranol (phenoxyethyl isobutyrate), decahydro-β-naphthyl isobutyrate, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, 2-methylbutyl 2-methylbutyrate, sidolane (2-methylbutyric acid Xyl), cis-3-hexenyl 2-methylbutyrate, benzyl 2-methylbutyrate, phenylethyl 2-methylbutyrate, allyl 2-ethylbutyrate, ethyl 3-hydroxybutyrate, methyl valerate, ethyl valerate, butyl valerate, Isobutyl valerate, amyl valerate, cis-3-hexenyl valerate, benzyl valerate, phenylethyl valerate, furfuryl valerate, methyl isovalerate, ethyl isovalerate, propyl isovalerate, isopropyl isovalerate, iso Allyl valerate, isobutyl valerate, isobutyl isovalerate, isoamyl isovalerate, amyl isovalerate, 2-methylbutyl isovalerate, cis-3-hexenyl isovalerate, hexyl isovalerate, octyl isovalerate, Linalyl isovalerate, citronellyl isovalerate, geranyl isovalerate, isovaleric acid Ntil, terpinyl isovalerate, cyclohexyl isovalerate, benzyl isovalerate, phenylethyl isovalerate, phenylpropyl isovalerate, cinnamyl isovalerate, manzanate (ethyl 2-methylvalerate), phenyl salicylate, peranato (2 -Methyl valeric acid 2-methylpentyl ester), methyl hexanoate, ethyl hexanoate, propyl hexanoate, isopropyl hexanoate, allyl hexanoate, butyl hexanoate, isobutyl hexanoate, amyl hexanoate, isoamyl hexanoate, hexyl hexanoate , Cis-3-hexenyl hexanoate, trans-2-hexenyl hexanoate, heptyl hexanoate, linalyl hexanoate, citronellyl hexanoate, geranyl hexanoate, citronellyl hexanoate, benzyl hexanoate Methyl isohexanoate, methyl 2-hexenoate, ethyl trans-2-hexenoate, methyl 3-hexenoate, ethyl 3-hexenoate, methyl 3-hydroxyhexanoate, ethyl 3-hydroxyhexanoate, ethyl 2-ethylhexanoate , Mersat (ethyl 3,5,5-trimethylhexanoate), beliflo (ethyl 6-acetoxyhexanoate), methyl heptanoate, ethyl heptanoate, propyl heptanoate, allyl heptanoate, octyl heptanoate, methyl octanoate, Ethyl octanoate, amyl octanoate, butyl octanoate, propyl octanoate, allyl octanoate, isoamyl octanoate, hexyl octanoate, heptyl octanoate, octyl octanoate, linalyl octanoate, benzyl octanoate, phenyl ethyl octanoate , P-cresyl octanoate, ethyl 2-octenoate, methyl nonanoate, ethyl nonanoate, phenylethyl nonanoate, buvartate (methyl 2-nonenoate), methyl 3-nonenoate, methyl decanoate, ethyl decanoate, decane Isopropyl acid, butyl decanoate, isoamyl decanoate, ethyl 2-decenoate, ethyl 2,4-decadienoate, propyl 2,4-decadienoate, methyl undecylenate, butyl undecylate, isoamyl undecylate, methyl dodecanoate, dodecane Ethyl acetate, butyl dodecanoate, isoamyl dodecanoate, ethyl myristate, methyl myristate, isopropyl myristate, ethyl palmitate, ethyl stearate, butyl stearate, methyl oleate, ethyl oleate, methyl benzoate, ethyl benzoate , Propyl benzoate, isopropyl benzoate, allyl benzoate, isobutyl benzoate, isoamyl benzoate, prenyl benzoate, hexyl benzoate, cis-3-hexenyl benzoate, linalyl benzoate, geranyl benzoate, benzyl benzoate, Phenylethyl benzoate, cinnamyl benzoate, methyl anisate, ethyl anisate, methyl o-methoxybenzoate, ethyl o-methoxybenzoate, ethyl tiglate, hexyl tiglate, cis-3-hexenyl tiglate, citronellyl tiglate Geranyl tiglate, benzyl tiglate, phenylethyl tiglate, cinnamyl tiglate, methyl angelate, butyl angelate, isobutyl angelate, isoamyl angelate, prenyl angelate, cis angelic acid 3-hexenyl, angelic acid 3-methylpentyl, angelic acid phenylethyl, ethyl acrylate, phenylethyl methacrylate, ethyl crotonate, isobutyl crotonate, cyclohexyl crotonate, flutinato (4-methyl-pentan-2-ol-crotonate ), Pyropurnato (2-cyclopentyl-cyclopentylcrotonate), datilat (1-cyclohexylethylcrotonate), ethyl levulinate, butyl levulinate, isoamyl levulinate, methyl lactate, ethyl lactate, amyl lactate, isobutyl lactate, cis lactate 3-hexenyl, butyrylbutyl lactate, ethyl pyruvate, methyl gellanate, ethyl gellanate, methyl cyclogellanate, ethyl cyclogellanate, flutate (ethyltricyclo [5.2.1.02,6] Can-2-yl carboxylate), divescon (ethyl-2-ethyl-6,6-dimethyl-2-cyclohexene-1-carboxylate & ethyl-2,3,6,6-tetramethyl-2-cyclohexene carboxylate) ), Ethyl safranate (ethyl dehydrocyclogeranate), allyl cyclohexylpropionate, cyclogalvanate (allylcyclohexyloxyacetate), calixol (ethyl-2-methyl-6-pentyl-4-oxocyclohexyl-2-enecarboxyl) Rate), tacrisate (methyl-1-methyl-3-cyclohexenecarboxylate), floramate (ethyl-2-tert-butylcyclohexyl carbonate), jasma cyclate (methyl cyclooctyl carbonate), mahagonate ( 1-methyl-4-isopropyl-2-carbomethoxybicyclo [2,2,2] -oct-5-ene), phenylethyl pivalate, methyl jasmonate, hedion (methyl dihydrojasmonate), velamos (methyl-3 , 6-dimethyl-β-resorcylate),
Methyl furancarboxylate, ethyl furancarboxylate, propyl furan acrylate, methyl heptine carboxylate, ethyl heptine carboxylate, isoamyl heptine carboxylate, methyl octynecarboxylate, ethyl octynecarboxylate, methyl decynecarboxylate, glycomel ( 3- (Methyl ester of bicyclo [2.2.1] hept-5-en-2-yl) -3methyloxirane carboxyacid), methyl phenylglycidate, ethyl phenylglycidate, aldehyde C-16 (3 -Ethyl-3-phenylglycidate), aldehyde C-20 (ethyl p-methyl-β-phenylglycidate), ethyl p-tolylglycidate, ethyl citronellyl oxalate, diethyl succinate, dimethyl succinate , Diethyl malonate, diethyl tartrate , Diethyl adipate, diethyl sebacate, triethyl citrate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, methyl phenylacetate, ethyl phenylacetate, isopropyl phenylacetate, butylphenylacetate, propylphenylacetate, isobutylphenylacetate, phenyl Isoamyl acetate, hexyl phenyl acetate, cis-3-hexenyl phenyl acetate, citronellyl phenyl acetate, rosinyl phenyl acetate, geranyl phenyl acetate, menthyl phenyl acetate, phenyl benzyl acetate, phenyl ethyl phenyl acetate, p-cresyl phenyl acetate, eugenyl phenyl acetate, Isoeugenyl phenylacetate, methyl cinnamate, ethyl cinnamate, propyl cinnamate, isopropyl cinnamate, allyl cinnamate, isobutyl cinnamate, cinnamic acid Isoamyl, linalyl cinnamate, benzyl cinnamate, cinnamyl cinnamate, phenylethyl cinnamate, methyl salicylate, ethyl salicylate, butyl salicylate, isobutyl salicylate, amyl salicylate, isoamyl salicylate, hexyl salicylate, cis-3-hexenyl salicylate , Cyclohexyl salicylate, phenyl salicylate, benzyl salicylate, phenylethyl salicylate, cyclopyden (methylcyclopentylidene acetate), avalin (methyl abieticate), hercoline (methyldihydroabietate), p-cresyl salicylate, allyl phenoxyacetate, phenylpropionic acid Examples include ethyl, ethylene brush rate, and triacetin.

<Nitrogen-containing compounds> Methyl anthranilate, ethyl anthranilate, butyl anthranilate, cis-3-hexenyl anthranilate, phenylethyl anthranilate, cinnamyl anthranilate, methyl N-methylanthranylate, auranthiol (hydroxycitronellal) -Methylanthranilate Schiff Base), Mevantral (Methylpropylacetaldehyde-Methylanthranilate Schiff Base), Jasmentin (α-amylcinnamic aldehyde-Methylanthranilate Schiff Base), Ligantoral (Methyl- (3,5- Dimethyl-3-cyclohexen-1-yl) methyleneanthranilate), indole, skatole, clonal (dodecanenitrile), tangenyl (2-tridecenonitrile) ), Citralba (geranyl nitrile), citronellyl nitrile, lemonyl (3,7-dimethyl-2,6-nonadinitrile), cuminyl nitrile, cinnamarva (cinnamyl nitrile), trimethylamine, pyridine, 3-ethylpyridine, 2-acetyl Pyridine, 3-acetylpyridine, 2-isobutylpyridine, 3-isobutylpyridine, 2-n-pentylpyridine, 5-ethyl-2-methylpyridine, methyl nicotinate, 4- (1,4,8-trimethyl-3, 7-nonadienyl) pyridine, quinoline, isoquinoline, p-methylquinoline, tetrahydro-p-methylquinoline, 6-isopropylquinoline, isobutylquinoline, 2-isobutylquinoline, 6-sec-butylquinoline, 8-sec-butylquinoline, 6 (P) -te rt-butylquinoline, 2-tert-butylquinoline, pyrazine, 2-methylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3,5-trimethylpyrazine, 2-ethylpyrazine, 2-ethyl -3-methylpyrazine, 2-ethyl-5-methylpyrazine, 2-ethyl-3,5 (3,6) -dimethylpyrazine, 2,3-diethylpyrazine, 2,3-diethyl-5-methylpyrazine, tetra Methylpyrazine, 2-methyl-5-vinylpyrazine, methoxypyrazine, 2-methoxy-3-methylpyrazine, 2-methoxy-3-ethylpyrazine, 2-methoxy-3-isopropylpyrazine, 2-isobutyl-3-methoxypyrazine 2-acetylpyrazine, 2-acetyl-3-ethylpyrazine, methylthiomethylpyrazine, coli N-pyrazine (5-methyl-6,7-dihydrocyclopentapyrazine), 5-methylquinoxaline, cyclohexapyrazine (5,6,7,8-tetrahydroquinoxaline), 1-methylpyrrole, 2-acetylpyrrole, pyrrolidine, indolene (Schiff base of indole-hydroxycitronellal), 2-methylbenzoxazole, decahydrocyclododecoxazole, 5-methyl-3-heptanone oxime, bucoxime (bicyclo [3.2.1] octane-8-one, 1 , 5-dimethyl-, oxime), gardamide (N-methyl-N-phenyl-2-methylbutyramide), musk xylol, musk ketone, musk ambullet, musk tibutene, mosken, 2,6-lutidine, piperidine, 2- ( 1,4,8-trimethyl 3,7-nonadienyl) pyridine, 2- (2-pinen-10-ylmethyl) pyridine, 4- (2-pinene-10-isomethyl) pyridine, piperine, capsaicin, nonanoic acid vanillylamide, quinine, perillartine (L-perilaldehyde) α-anti-aldoxime), 2-isopropyl-4-methylthiazole, 2-isobutylthiazole and the like.

<Sulfur-containing compound> thiazole, 4-methylthiazole, 4,5-dimethylthiazole, trimethylthiazole, 2-methyl-5-methoxythiazole, 2-isopropyl-4-methylthiazole, 4-methyl-5-vinylthiazole, 2-isobutylthiazole, sulfuryl (4-methyl-5-thiazoleethanol), sulfuryl acetate (4-methyl-5-thiazoleethanolacetate), 2-acetylthiazole, 5-acetyl-2,4-dimethylthiazole, benzo Thiazole, propyl mercaptan, hydrogen sulfide, isopropyl mercaptan, 2-methyl-3-butanethiol, allyl mercaptan, isoamyl mercaptan, thiogeraniol, limonene thiol, sulfox (8-mercaptomentone) pheni Mercaptan, o-thiocresol, 2-ethylthiophenol, 2-naphthyl mercaptan, furfuryl mercaptan, 2-methyl-3-furanthiol, dimethyl sulfide, dimethyl disulfide, dimethyl trisulfide, methylpropyl disulfide, methylpropyl trisulfide, Propyl disulfide, dipropyl trisulfide, diallyl sulfide, diallyl disulfide, dibutyl sulfide, methionol (3- (methylthio) -1-propanol), 3-methylthio-1-hexanol, methional (3- (methylthio) propionaldehyde), mint Sulfide, dithiospirofurofuran, furfuryl methyl sulfide, 2-methyl-5-methylthiofuran, methyl furfuryl disulfide, furfuryl dis Fido, thiophene, tetrahydrothiophene, 3-thiophenecarboxaldehyde, 5-methyl-2-thiophenecarboxaldehyde, tetrahydrothiophene-3-one, trithioacetone, thioglycolic acid, methyl methylthioacetate, ethyl methylthioacetate, 2-mercaptopropion Acid, pineapple mercaptan (methyl mercaptomethylpropionate), ethyl 3-methylthiopropionate, ethyl thioacetate, furfuryl thioacetate, furfuryl thiopropionate, methyl thiobutyrate, methylmethanethiosulfonate, allyl isothiocyanate, isothiocyanic acid Benzyl, thiaridine (2,4,6-trimethyl-4,5-dihydro-1,3,5-dithiazone), oxane (2-methyl-4-propyl-1,3-oxathia) Etc.).

<Natural fragrance> Asafetida Resinoid, Ajowan Oil, Star Anise Oil, Abies Oil, Amiris Oil, Ambret Seed Oil, Ambergris Tincture, Ylang Ylang Oil, Ylang Ylang Absolute, Iris Resinoid, Iris Absolute, Iris Oil, Winter Green oil, Elemioleoresin, Elemiresinoid absolute, Elemi tincture, Oak moss concrete, Oak moss absolute, Oak moth resin, Oak moss resinoid, Ocotia oil, Osmanthus absolute, Ottomanthus concrete, Opopanax resinoid, Opopanax absolute, Opopanax Oil, Olivenum Resinoid, Olivenham Absolute, Olivenum Oil, All Spa Soil, Oregano oil, Oregano oleoresin, Orange oil, Orange flower absolute, Orange flower concrete, Cananga oil, Garjun balsam, Garjun balsam oil, Cascari bark oil, Castrium absolute, Cassie absolute, Cassie flower oil, Cassia oil , Gardenia Absolute, Carnation Absolute, Cabruba Oil, Camomil Oil, Cardamom Oil, Galvanam Oil, Galvanam Resin, Galvanam Resinoid, Caraway Seed Oil, Carrot Seed Oil, Guayac Wood Oil, Guayac Resin, Guayac Concrete, camphor oil , Kubeba Oil, Cumin Oil, Cumin Absolute, Cumin Oreo Gin, Clarisage oil, Grapefruit oil, Clove oil, Copasba balsam, Copaiba balsam oil, Copaiba balsam resin, Coriander oil, Sassafras oil, Sandalwood oil, Geneva absolute, Perilla oil, Citronella oil, Jasmine absolute, Jasmine concrete, Juniper berry oil, civet absolute, civet tincture, john kill absolute, agarwood oil, ginger oil, cinnamon oil, cinnamon bark oil, cinnamon leaf oil, cedar oil, stilax oil, stilax resinoid, spearmint oil, savory oil, sage oil, Cedar oil, Cedar leaf oil, geranium oil, celery -Seed oil, thyme oil, tagget oil, tarragon oil, tuberose absolute, dill oil, tea tree oil, Torimos absolute, trubal sum, nutmeg oil, Narcissus absolute, neroli oil, violet leaf absolute, pine oil, basil oil, parsley leaf oil , Parsley seed oil, parsley herb oil, patchouli oil, peppermint oil, vanilla absolute, honeysuckle absolute, palmarosa oil, valerian oil, bitter orange oil, hyssop oil, hiba oil, hyacinth absolute, fennel oil, fig absolute, petit gren oil, butchu oil , Vetiver oil, penny royal oil, pepper oil Peppermint oil, bergamot oil, peru balsam, benzoin tincture, benzoin resinoid, bore oil oil, pepper oil, hop oil, hop concrete, hop absolute, marjoram oil, mandarin oil, mandarin oil, mimosa concrete, mimosa absolute, mimosa oil, Milresinoid, Mill Absolute, Mill Oil, Musk Absolute, Mustinki, Eucalyptus Oil, Yuzu Oil, Artemisia Oil, Lime Oil, Labdanum Oil, Labdanum Resinoid, Lavender Oil, Lavender Absolute, Lavandin Oil, Lavandin Absolute, Linaroe Oil, Lemon Oil, Lemon Glass oil, rose oil, rose absolute, rose conch Over door, rosemary oil, Robejioiru, Laurel oil, laurel leaf oil, wormwood oil, musk, Reinekoko, dragon Zen incense, Castoreum, musk-Chibata, and the like.

<Combination fragrance> Moreover, there exist the following incense-like bases which are the combination fragrance | flavor which combined the fragrance | flavor component. Lemon-like, lime-like, orange-like, sweet orange-like, mandarin-like, bergamot-like citrus-type base, petit-glen-like, neroli-like, lemongrass-like, aggluten-like, etc. Fresh-type base, apple-like, peach-like, strawberry Tone, coconut tone, pineapple tone, raspberry tone, watermelon tone, etc., rose tone, jasmine tone, mugue tone, lilac tone, carnation tone, hyacinth tone, tuberose tone, gardenia tone, mimosa tone, narciss tone, Floral type bases such as violet, Iran, and floral bouquets, spicy types such as cinnamon bark, cinnamon leaf, clove, pimentoberry, nutmeg, pepper, cardamom, coriander, cumin Leather, cedarwood-like, vetiver-like, sandalwood-like, guaiac wood-like, woody-bar-like, woody-like-like woody base, smoky-like, quinoline-like leather type, vanilla-like, tonka-like, honey-like, pure Sweet type base such as balsam-like, other Aldehydic type base, amber type base, animal type base, anise type base, aromatic herbal type base, agar type base, aqua type base, camphor cineall type base, green type base, Seed type base, herb type base, pine type base, patchouli type base, balsamic type base, mint type base, musk type base, moss type base, lavender tie Base, linalool type base include resin type base, or the like.

In the present invention, the fragrance is preferably used together with a fragrance solvent and / or a fragrance stabilizer. Examples of the perfume solvent include ethanol, acetin (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, and deltile extra (isopropyl myristate). , Methyl carbitol (diethylene glycol monomethyl ether), carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate, propylene glycol, diethyl phthalate, tripropylene glycol, aboline (dimethyl phthalate), deltyl prime (Isopropyl palmitate), dipropylene glycol DPG-FC (dipropylene glycol), farnesene, dioctyl adipate, Butyrin (glyceryl tributanoate), hydrolite-5 (1,2-pentanediol), propylene glycol diacetate, cetyl acetate (hexadecyl acetate), ethyl abiate, avaline (methyl abietate), citroflex A-2 (Acetyl triethyl citrate), citroflex A-4 (tributyl acetyl citrate), citroflex no. 2 (triethyl citrate), Citroflex No. 4 (tributyl citrate), Durafix (methyl dihydroabietate), MITD (isotridecyl myristate), polylimonene (limonene polymer), propylene glycol, 1,3-butylene glycol and the like.
The amount of these solvents used is 0.1 to 99% by mass in the fragrance, but preferably 1 to 50% by mass.

  Examples of the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E and its derivatives, catechin compounds, flavonoid compounds, polyphenol compounds, etc., and 0.0001 to 10% by mass in the fragrance. However, Preferably, 0.001 to 5 mass% is mix | blended. Among these, a preferable stabilizer is dibutylhydroxytoluene.

Other raw materials In addition to the above fragrances and nonionic cellulose ethers, the fragrance particles of the present invention may optionally have an interface for the purpose of improving solubility in water and particle physical properties and for the purpose of improving productivity. Activators, inorganic and organic compounds can optionally be included.
Although the arbitrary component which can be used with respect to a fragrance | flavor particle | grain is illustrated below, in this invention, these arbitrary components are not limited at all.
The solubility with respect to water improves by mix | blending 1-5 mass% of surfactant with surfactant perfume particle | grains. By making the compounding amount of the surfactant 1% by mass or more, the effect of solubility by adding the surfactant can be exhibited. On the other hand, when the content is 5% by mass or less, properties such as foaming and dispersibility of the surfactant do not appear, so the quality of the detergent composition is not affected, and the quality of the fragrance is adversely affected. Nor.
Preferable surfactants include anionic surfactants and nonionic surfactants.

As an anionic surfactant, the following can be mentioned, for example.
(1) A linear or branched alkylbenzene sulfonate (LAS or ABS) having an alkyl group having 8 to 18 carbon atoms.
(2) Alkanesulfonate having 10 to 20 carbon atoms.
(3) C10-20 α-olefin sulfonate (AOS).
(4) Alkyl sulfate or alkenyl sulfate (AS) having 10 to 20 carbon atoms.
(5) Any one of alkylene oxides having 2 to 4 carbon atoms, or ethylene oxide and propylene oxide (molar ratio EO / PO = 0.1 / 9.9 to 9.9 / 0.1) with an average of 0.5 Alkyl (or alkenyl) ether sulfate (AES) having a linear or branched alkyl (or alkenyl) group having 10 to 20 carbon atoms added by 10 mol.
(6) Any one of alkylene oxides having 2 to 4 carbon atoms, or ethylene oxide and propylene oxide (molar ratio EO / PO = 0.1 / 9.9 to 9.9 / 0.1) on average 3 to 30 An alkyl (or alkenyl) phenyl ether sulfate having a linear or branched alkyl (or alkenyl) group having 10 to 20 carbon atoms added in a mole form.
(7) Any one of alkylene oxides having 2 to 4 carbon atoms, or ethylene oxide and propylene oxide (molar ratio EO / PO = 0.1 / 9.9 to 9.9 / 0.1) with an average of 0.5 An alkyl (or alkenyl) ether carboxylate having 10 to 20 moles of a linear or branched alkyl (or alkenyl) group having 10 to 20 carbon atoms.
(8) Alkyl polyhydric alcohol ether sulfates such as alkyl glyceryl ether sulfonic acids having 10 to 20 carbon atoms.
(9) C8-20 saturated or unsaturated α-sulfo fatty acid salt or methyl, ethyl or propyl ester thereof (α-SF or MES).
(10) Long chain monoalkyl, dialkyl or sesquialkyl phosphates.
(11) Polyoxyethylene monoalkyl, dialkyl or sesquialkyl phosphate.
(12) A higher fatty acid salt (soap) having 10 to 20 carbon atoms.
These anionic surfactants can be used as alkali metal salts such as sodium and potassium, amine salts and ammonium salts. These anionic surfactants may be used as a mixture.

Examples of nonionic surfactants include the following.
(1) Polyoxyalkylene alkyl (or alkenyl) obtained by adding an average of 3 to 30 moles, preferably 5 to 20 moles of an alkylene oxide having 2 to 4 carbon atoms to an aliphatic alcohol having 6 to 22 carbon atoms, preferably 8 to 18 carbon atoms Ether Among these, polyoxyethylene alkyl (or alkenyl) ether and polyoxyethylene polyoxypropylene alkyl (or alkenyl) ether are preferable. Examples of the aliphatic alcohol used here include primary alcohols and secondary alcohols. The alkyl group may have a branched chain. As the aliphatic alcohol, a primary alcohol is preferable.
(2) Polyoxyethylene alkyl (or alkenyl) phenyl ether (3) Fatty acid alkyl ester alkoxylate represented by, for example, the following general formula (I) in which alkylene oxide is added between ester bonds of long chain fatty acid alkyl ester
R ¹ CO (OA) _n OR ² (I)
(In the formula, R ¹ CO represents a fatty acid residue having 6 to 22 carbon atoms, preferably 8 to 18 carbon atoms, and OA is an alkylene having 2 to 4 carbon atoms such as ethylene oxide and propylene oxide, preferably 2 to 3 carbon atoms. Represents an oxide addition unit, and n represents the average number of moles of alkylene oxide added, and is generally a number of 3 to 30, preferably 5 to 20. R ² may have a substituent of 1 to 3 carbon atoms. A good lower (C1-C4) alkyl group is shown.)
(4) Polyoxyethylene sorbitan fatty acid ester (5) Polyoxyethylene sorbite fatty acid ester (6) Polyoxyethylene fatty acid ester (7) Polyoxyethylene hydrogenated castor oil (8) Glycerin fatty acid ester

Among the nonionic surfactants described above, the nonionic surfactant (1) described above is preferable, and in particular, an average of 5 to 20 moles of an alkylene oxide having 2 to 4 carbon atoms in an aliphatic alcohol having 12 to 16 carbon atoms. Added polyoxyalkylene alkyl (or alkenyl) ethers are preferred. A polyoxyethylene alkyl (or alkenyl) ether having a melting point of 50 ° C. or less and an HLB of 9 to 16, a polyoxyethylene polyoxypropylene alkyl (or alkenyl) ether, a fatty acid methyl ester ethoxylate obtained by adding ethylene oxide to a fatty acid methyl ester, A fatty acid methyl ester ethoxypropoxylate obtained by adding ethylene oxide and propylene oxide to a fatty acid methyl ester is preferably used. Moreover, these nonionic surfactants can be used individually by 1 type or in combination of 2 or more types as appropriate.
In addition, the HLB of the nonionic surfactant in the present invention is a value determined by the Griffin method (Yoshida, Shindo, Ogaki, Yamanaka Co-ed., “New Edition Surfactant Handbook”, Kogyoshosho Co., Ltd., 1991). Year, page 234).
The melting point in the present invention is a value measured by a melting point measurement method described in JIS K0064-1992 “Method for measuring melting point and melting range of chemical products”.

Neutral salts of inorganic compounds such as sodium sulfate, potassium sulfate, sodium chloride, potassium chloride, barium sulfate; phosphoric acids such as orthophosphate, pyrophosphate, tripolyphosphate, metaphosphate, hexametaphosphate, phytate Crystalline aluminosilicate; amorphous aluminosilicate; amorphous anhydrous silicic acid, calcium silicate, hydrous silicic acid, talc, titanium oxide and the like can be blended.

Organic compounds nitrilotriacetate (NTA), ethylenediaminetetraacetate (EDTA), ethylenediaminedisuccinate (EDDS), β-alanine diacetate (β-ADAA), aspartate diacetate (ASDA), methylglycine diacetate Aminocarboxylates such as salt (MGDA), ethylglycine diacetate (EGDA), iminodisuccinate (IDS); serine diacetate, hydroxyiminodisuccinate (HIDS), hydroxyethylethylenediamine triacetate, dihydroxyethyl Hydroxyaminocarboxylates such as glycine salt; Hydroxycarboxylates such as hydroxyacetate, tartrate, citrate, gluconate; pyromellitic acid salt, benzopolycarboxylate, cyclopentanetetracarboxylate, etc. Cyclocarboxylate; Carbo Ether carboxylates such as xymethyl tartronate, carboxymethyloxysuccinate, oxydisuccinate, tartaric acid mono- or disuccinate; polyacrylic acid (salt), acrylic acid-allyl alcohol copolymer (salt), water-soluble acrylic Acrylic acid polymers and copolymers such as acid-maleic acid copolymer (salt), hydroxyacrylic acid polymer (salt), polysaccharide-acrylic acid copolymer, or salts thereof; maleic acid, itaconic acid, Polymers or copolymers such as fumaric acid, tetramethylene 1,2-dicarboxylic acid, succinic acid, aspartic acid, or salts thereof; polysaccharide oxides such as starch, amylose, and pectin; polysaccharides such as carboxymethyl cellulose; High non-dissociation of polyethylene glycol, polyvinyl alcohol, polyvinyl pyrrolidone, etc. Child compounds include colorants such as water-soluble dyes, pigments.

  In addition, when mix | blending the said other raw material with the fragrance | flavor particle | grains of this invention, the fragrance | flavor contained in a fragrance | flavor particle is 2-50 mass% with respect to the mass of a fragrance | flavor particle, Preferably it is 2-35 mass%. More preferably, it is contained in an amount of 10 to 35% by mass. When the amount of the fragrance contained in the particles is 2% by mass or more, the amount of the fragrance particles added to the detergent composition can be maintained appropriately, and the amount of other components in the detergent composition can be prevented from being affected. . On the other hand, by setting it to 50 mass% or less, it becomes possible to ensure the fluidity of the perfume particles themselves.

Production method of perfume particles The perfume particles of the present invention can be produced by stirring the nonionic cellulose ether, perfume and other components, or spraying the perfume and other components on the nonionic cellulose ether. it can.
In the case of producing by stirring, for example, using a mixer such as a ribbon mixer or a high speed mixer, a predetermined amount of powdered nonionic cellulose ether and a fragrance are added to the surfactant, inorganic compound and organic as necessary. It can manufacture by adding a compound etc. and stirring and mixing.
The stirring type mixer is a mixer having a structure having a jacket.
When mixing in batch mode, the stirring type mixer is not particularly limited. For example, a horizontal stirring mixer of a type in which stirring blades are installed in a horizontal mixing tank to perform mixing; stirring at the bottom of the vertical type A suitable example is a vertical stirring mixer having blades and mixing by rotation of the stirring blades. Specific examples include the following.
As horizontal stirring mixers, Ladige mixer (manufactured by Matsubo Co., Ltd.), Proshear mixer (manufactured by Taihei Koki Co., Ltd.), ribbon mixer (manufactured by Yoshida Seisakusho Co., Ltd.), Spartan mixer (Dalton Co., Ltd.) ), Pug mixer (produced by Fuji Paudal Co., Ltd.), turbulizer (produced by Hosokawa Micron Co., Ltd.), and the like.
Examples of the vertical stirring mixer include a high speed mixer (manufactured by Fukae Powtech Co., Ltd.), a Henschel mixer (manufactured by Mitsui Mining Co., Ltd.), and New Gramachine (seisei corporation).

In addition, when producing by spraying, spray a fragrance on a predetermined amount of nonionic cellulose ether and a surfactant added as necessary using a rolling mixer such as Trommel. Can be manufactured. The container rotating type mixer is not particularly limited, and for example, a mixer that performs mixing by rotating a V-shaped, cylindrical, or double-conical mixing tank is preferable. Specific examples include the following.
Examples of the mixer that performs mixing by rotating a V-shaped mixing tank include a V-type mixer (produced by Fuji Powder Co., Ltd.), a V-type mixer (produced by Seishin Enterprise Co., Ltd.), and the like.
As a mixer that performs mixing by rotating a cylindrical mixing tank, a rocking mixer (manufactured by Aichi Electric Trading Co., Ltd.), a Doria coater (manufactured by Paulek Co., Ltd.), a rotary mixer (Maywa Kogyo Co., Ltd.) )), Drum mixer (manufactured by Sugiyama Heavy Industries Ltd.), and the like.
Examples of the mixer that performs mixing by rotating a double-conical mixing tank include a W-type mixer (manufactured by Seishin Enterprise Co., Ltd.), a double cone mixer (manufactured by ASR Corporation), and the like.
Examples of the mixer that performs mixing by rotating and revolving a cylindrical mixing tank include a dynamixer (manufactured by Mori Machinery Co., Ltd.), a cross rotary mixer (manufactured by Meiwa Kogyo Co., Ltd.), and the like.
Moreover, when mixing by a continuous type, it does not specifically limit as a container rotation type mixer, For example, a continuous type cylindrical mixer is mentioned, Specifically, a rocking mixer (Aichi Electric Trading Co., Ltd. product) is mentioned. , And can be mixed using a Doria coater (manufactured by POWREC Co., Ltd.).
Furthermore, once the powder containing the fragrance is obtained by the above method, it is uniformly mixed with a melted water-soluble polymer such as polyethylene glycol (for example, PEG # 6000M, manufactured by Lion Corporation) using a kneader. Thereafter, the mixture is cooled to room temperature with stirring, and the obtained solid material is pulverized and granulated with a pulverizer, and a product having a predetermined particle size is sieved and used as perfume particles.

Detergent composition using perfume particles The detergent composition using the perfume particles of the present invention is not particularly limited as long as it is powdery. Moreover, about the manufacturing method of a detergent composition, any method used when manufacturing a powdery detergent composition can be used. For example, a detergent composition can be produced by preparing a detergent mixture by spray drying, stirring or kneading the detergent components excluding the fragrance particles in advance, and blending the fragrance particles with the prepared detergent mixture. Further, the detergent mixture may contain a fragrance, for example, for the purpose of improving the fragrance of the finally obtained detergent composition with respect to the detergent mixture fragranced by a method other than the fragrance particles of the present invention. The perfume particles of the present invention can be blended.

  Hereinafter, the present invention will be described in more detail with reference to examples.

The following examples do not limit the scope of the present invention in any way. Further, “%” and “part” described below mean “% by mass” and “part by mass”, respectively, unless otherwise specified. In addition, among the components in the table, the surfactant, zeolite, and MA agent are blended as pure components, and the others are blended as such. The raw materials used in the examples are shown below.
Anionic surfactant MES: 14-carbon: 16-carbon: α-sulfo fatty acid methyl ester sodium salt aqueous solution (manufactured by Lion Corporation, AI = 70%)
LAS-Na: linear alkyl (10 to 14 carbon atoms) benzenesulfonic acid (Lypon LH-200 (96% pure LAS-H) manufactured by Lion Co., Ltd.) 48% sodium hydroxide aqueous solution when preparing the surfactant composition Neutralize). The compounding quantity in Table 3 shows the mass% as LAS-Na.
LAS-K: Linear alkyl (10 to 14 carbon atoms) benzenesulfonic acid (Laipon LH-200 (manufactured by Lion Corporation)) LAS-H (96% pure) was 48% hydroxylated during preparation of the surfactant composition Neutralize with aqueous potassium). The compounding quantity in Table 3 shows the mass% as LAS-K.
Soap: Fatty acid sodium having 12 to 18 carbon atoms (manufactured by Lion Corporation, pure content: 67%, titer: 40 to 45 ° C., fatty acid composition: C12: 11.7%, C14: 0.4%, C16: 29 0.2%, C18F0 (stearic acid): 0.7%, C18F1 (oleic acid): 56.8%, C18F2 (linoleic acid): 1.2%, molecular weight: 289)

Nonionic surfactant A; ECOROL 26 (ECOGREN Co., Ltd., alcohol having an alkyl group having 12 to 16 carbon atoms) average 15 mol of ethylene oxide adduct (pure 90%)
Zeolite: A-type zeolite, Shilton B (manufactured by Mizusawa Chemical Co., Ltd., pure content 80%)
MA agent: acrylic acid / maleic anhydride copolymer sodium salt, Aqualic TL-400 (manufactured by Nippon Shokubai Co., Ltd.) (pure 40% aqueous solution)
Sodium sulfite: anhydrous sodium sulfite (manufactured by Shinshu Chemical Co., Ltd.)
Sodium sulfate: neutral anhydrous sodium sulfate (manufactured by Nippon Chemical Industry Co., Ltd.)
Potassium carbonate: Potassium carbonate (powder) (Asahi Glass Co., Ltd., average particle size 490 μm, bulk density 1.30 g / cm ³ )
Sodium carbonate: grain ash (Asahi Glass Co., Ltd. average particle size 320 μm, bulk density 1.07 g / cm ³ )
Fluorescent agent: Mixture of Chino Pearl CBS-X (Ciba Specialty Chemicals) / Chino Pearl AMS-GX (Ciba Specialty Chemicals) = 3/1 (mass ratio)

Covered sodium carbonate particles: Surface-treated inorganic particles such as sodium carbonate 85%, acrylic acid / maleic anhydride copolymer sodium salt 3%, lauric acid 7%, water and the rest were prepared in the following steps.
1st step Sodium carbonate is equipped with a blade-shaped shovel, and the excavator-wall clearance is 5 mm. The shear shear mixer (Daihei Kiko Co., Ltd.) is charged (filling rate: 30% by volume), and stirring is started at 150 rpm. (Chopper rotation speed: 1015 rpm, blade tip speed (peripheral speed): 6.9 m / s). After 10 seconds from the start of stirring, an acrylic acid / maleic anhydride copolymer sodium salt aqueous solution (concentration: see MA agent described in raw material column below) is sprayed for 180 seconds with a pressure nozzle (flat nozzle) having a spray angle of 115 degrees. Then, granulation and coating operations were performed. Moreover, when the moisture content with respect to the whole particle | grain amount prepared at the 1st process exceeded 10 mass%, hot air was introduce | transduced into the said apparatus and it dried and adjusted the moisture content to 10 mass% or less.
In the second step , lauric acid was sprayed and added for 180 seconds with a pressure nozzle (full cone nozzle) having a spray angle of 60 degrees while continuing to stir the plow shear mixer. Stirring was continued for 30 seconds to obtain particles.
Third Step Next, the obtained particles are filled into a fluidized bed (Glatt-POWREX, model number FD-WRT-20, manufactured by Paulex Co., Ltd.), and after filling, 15 ° C. wind (air) is put into the fluidized bed. Feeding and particle cooling operations were performed to obtain particles cooled to 20 ° C. The air velocity in the fluidized bed was adjusted in the range of 0.2 to 10.0 m / s while confirming the fluidized state. The obtained particles were classified using a sieve having an opening of 2000 μm to obtain surface-treated inorganic particles passing through a sieve having an opening of 2000 μm.

Lauric acid: (Nippon Yushi Co., Ltd., NAA-122, melting point 43 ° C.)
Fragrance:

Enzyme: Mixture of sabinase 12T (Novozymes) / LIPEX100T (Novozymes) / Stainzyme 12T (Novozymes) = 5/4 (mass ratio)
Powdered nonionic cellulose ether
HPMC A; Metroles 60SH10000 (manufactured by Shin-Etsu Chemical Co., Ltd.) having a mass average molecular weight of about 380,000, methoxyl group substitution degree of 1.9, methoxyl group mass% of 28-30%, and hydroxypropoxyl group mass% of 7-12 Hydroxypropyl methylcellulose, median average particle size 62μm)
HPMC B; Metroles 65SH4000 (manufactured by Shin-Etsu Chemical Co., Ltd.) Mass average molecular weight of about 300,000, methoxyl group substitution degree of 1.8, methoxyl group mass% of 27-30%, hydroxypropoxyl group mass% of 4-7. 5 hydroxypropyl methylcellulose, median average particle size of 66 μm)
HPMC C; Metrows 60SH3 (manufactured by Shin-Etsu Chemical Co., Ltd.) having a mass average molecular weight of about 20,000, a methoxyl group substitution degree of 1.9, a methoxyl group mass% of 28-30%, and a hydroxyproposyl group mass% of 7-12 Hydroxypropyl methylcellulose, median average particle size 54μm)
HEC 1: HEC SE600 (manufactured by Daicel Chemical Industries) (powder: 1% aqueous solution viscosity 100-1000 mPa · s)

Silicic anhydride: Trade name Tokuseal NP, Tokuyama polyethylene glycol: Trade name PEG # 6000M (manufactured by Lion Corporation)

Manufacture of perfume particles According to the composition of Table 2, it was manufactured as follows.
Filling rate of 30 with a horizontal cylindrical rolling mixer (cylinder diameter: 585 mm, cylinder length: 490 mm, inner wall surface of drum of container 131.7 L, clearance between inner wall surface: 20 mm, height: 45 mm) The components (b) and other components in the amounts shown in Table 2 were added under the conditions of volume%, rotational speed 22 rpm, and 25 ° C., and the fragrance as component (a) was sprayed for 5 minutes while spraying. Perfume particles were obtained and passed through a sieve having an opening of 355 μm and subjected to the following test.

Preparation of detergent mixture

Manufacture of detergent mixture (a) Based on the composition of Table 3, it was manufactured as follows.
<Method for preparing surfactant-containing particles>
First, water was put into a jacketed mixing tank equipped with a stirring device, and the temperature was adjusted to 60 ° C. To this, a surfactant excluding MES and nonionic surfactant was added and stirred for 10 minutes, followed by the addition of MA agent and fluorescent agent. After further stirring for 10 minutes, a part of the zeolite (2.0 parts for the addition during mixing, 3.2 parts for the grinding aid, 1.5 parts for each surface coating zeolite from the blending amount in Table 3) Sodium carbonate, potassium carbonate and sodium sulfite were added. The slurry was further stirred for 20 minutes to prepare a slurry for spray drying having a moisture content of 38%, and then spray dried particles having a moisture content of approximately 5% were obtained using a countercurrent spray drying tower.
On the other hand, a part of the nonionic surfactant (25% with respect to MES) is added to the aqueous slurry of MES (water concentration 25%) and concentrated under reduced pressure with a thin film dryer until the water content becomes 11%. A mixed concentrate of MES and nonionic surfactant was obtained.

The above-mentioned spray-dried particles, this mixed concentrate, 2.0 parts of zeolite, 0.5 parts of nonionic surfactant except for spray addition and water are charged into a continuous kneader and kneaded at a temperature of 60 ° C. A surfactant-containing kneaded product was obtained. While extruding this surfactant-containing kneaded material using a pelleter double, it was cut with a cutter to obtain a pellet-like surfactant-containing molded product having a length of about 5 to 30 mm.
Next, 3.2 parts of particulate zeolite as a grinding aid was added to the obtained pellet-form surfactant-containing molded product, and Fitzmill was arranged in three stages in series in the presence of cold air (10 ° C., 15 m / s). Was used to grind. Finally, with a horizontal cylindrical rolling mixer, 1.5 parts of finely divided zeolite was added under the conditions of a filling rate of 30% by volume, a rotational speed of 22 rpm, and 25 ° C., while spraying 0.5 part of a nonionic surfactant, Rolled for 1 minute and surface-modified to obtain surfactant-containing particles.
<Preparation of detergent mixture>
Components such as coated sodium carbonate particles, surfactant-containing particles, and enzymes were mixed in a horizontal cylindrical rolling mixer to obtain a detergent mixture.

Manufacture of detergent mixture (I) (U) (E) (O) (F) Based on the composition of Table 3, it manufactured as follows.
<Method for preparing surfactant-containing particles>
First, water was put into a jacketed mixing tank equipped with a stirring device, and the temperature was adjusted to 60 ° C. To this, a surfactant excluding MES and nonionic surfactant was added and stirred for 10 minutes, followed by the addition of MA agent and fluorescent agent. After further stirring for 10 minutes, a part of the zeolite (2.0 parts for the addition during mixing, 3.2 parts for the grinding aid, 1.5 parts for each surface coating zeolite from the blending amount in Table 3) Sodium carbonate, potassium carbonate and sodium sulfite were added. The slurry was further stirred for 20 minutes to prepare a slurry for spray drying having a moisture content of 38%, and then spray dried particles having a moisture content of approximately 5% were obtained using a countercurrent spray drying tower.
On the other hand, a part of the nonionic surfactant (25% with respect to MES) is added to the aqueous slurry of MES (water concentration 25%) and concentrated under reduced pressure with a thin film dryer until the water content becomes 11%. A mixed concentrate of MES and nonionic surfactant was obtained.

The above-mentioned spray-dried particles, this mixed concentrate, 2.0 parts of zeolite, 0.5 parts of nonionic surfactant except for spray addition and water are charged into a continuous kneader and kneaded at a temperature of 60 ° C. A surfactant-containing kneaded product was obtained. While extruding this surfactant-containing kneaded material using a pelleter double, it was cut with a cutter to obtain a pellet-like surfactant-containing molded product having a length of about 5 to 30 mm.
Next, 3.2 parts of particulate zeolite as a grinding aid was added to the obtained pellet-form surfactant-containing molded product, and Fitzmill was arranged in three stages in series in the presence of cold air (10 ° C., 15 m / s). Was used to grind. Finally, in a horizontal cylindrical rolling mixer, 1.5 parts of finely divided zeolite was added under the conditions of a filling rate of 30% by volume, a rotational speed of 22 rpm, and 25 ° C., and 0.5 parts of nonionic surfactant and While spraying the fragrance, the surface was modified by rolling for 1 minute to obtain surfactant-containing particles.
<Preparation of detergent mixture>
Components such as coated sodium carbonate particles, surfactant-containing particles, and enzymes were mixed in a horizontal cylindrical rolling mixer to obtain a granular detergent mixture.

Manufacture of detergent mixture (ki) After producing surfactant particles in the same manner as described above based on the composition in Table 3, the coated sodium carbonate particles, surfactant particles, HPMC A, and The enzyme was mixed to obtain a granular detergent mixture.

Examples, Comparative Examples, and Reference Example Detergent Composition Examples, Comparative Example 7 and Reference Example are 100 parts by weight of detergent mixture (A). It was prepared by mixing with a mixer.
In Comparative Examples 1 to 6, the detergent mixture (I) (U) (E) (O) (F) (Ki) itself was used.

Evaluation Method The detergent compositions according to Examples and Comparative Examples were evaluated using the following methods. The following evaluation results are shown in Tables 4 and 5.

1. Storage stability of perfume in detergent composition The following evaluation was performed using the manufactured detergent composition for clothes.
(1) Test sample After the test detergent composition was manufactured by the above-described method, it was placed in a paper carton (material; Wax sand 605 g / m ² , 15 × 9 × 13.5 cm) in a full amount at room temperature for 1 day. The one stored for one month in a constant temperature and humidity chamber at 40 ° C. and 85% RH was used.
(2) Evaluation of storage stability A detergent stored for 1 day at room temperature after production was used as a reference product, and detergents stored in a constant temperature and humidity room at 40 ° C. and 85% RH were compared for one month. The evaluation was made by comparing five samples with the following evaluation criteria by five professional fragrance determination panelists, and rounding the average score.
5 points: Retaining the same fragrance as the standard product.
4 points: Slightly weaker than the standard product but retains a sufficient aroma.
3 points: Fragrance is recognized although weaker than the standard product.
2 points: Fragrance is very weak but slightly recognized.
1 point: Almost no aroma is recognized.

2. The following evaluation was performed using the manufactured detergent composition.
The evaluation results are shown in the table.
(3) Test sample After the detergent composition was manufactured by the above-mentioned method, it was put in a paper carton (material: Wax sand 605 g / m ² , 15 × 9 × 13.5 cm) and left at room temperature for 1 day. A thing was used.
(4) Clothing used Cotton towel (220cm border soft F, 71g / sheet, manufactured by Toshin Co., Ltd.) is used as clothing for evaluating the scent of the wash cloth, and BVD skin shirt is used as a bathing ratio during washing. (A round neck short sleeve T-shirt product number G0134TS, 140 g / sheet) was used.
(5) Pre-treatment of clothing Using a fully automatic washing machine (NA-F70SD1) manufactured by Matsushita Electric Industrial Co., Ltd., about 4.5 kg of new cotton towel, 40 g of standard unscented detergent (note), temperature of about 20 ° C. , 60L of tap water with a hardness of about 3 ° DH, washing 10 minutes → dehydration 3 minutes → rinsing 5 minutes → dehydration 3 minutes rinsing 5 minutes → dehydration 3 minutes was repeated twice and then experimented with air-dried water Went.
The skin shirt used for bath ratio matching was also pretreated.

(6) Washing method Using a two-tank washing machine (CW-C30A1-H1 type) manufactured by Mitsubishi Electric Corporation, put 4 cotton towels for evaluation and 5 skin shirts for bath comparison, about 20 ° C, hardness Immediately after repeating twice for 10 minutes of washing, 3 minutes of dehydration, 5 minutes of rinsing, 5 minutes of dehydration, 5 minutes of rinsing, 5 minutes of dehydration, and 3 minutes of dehydration with 30 L of tap water of about 3 ° DH. The cotton towel was dried in a constant temperature and humidity room at 25 ° C. and 65% RH and dried.
(7) Evaluation of scents Eight evaluators simultaneously performed the same type and amount of cotton towels after drying in a constant temperature and humidity chamber and after drying (after 4 hours) and after drying (24 hours). A cotton towel washed with a composition obtained by spraying a fragrance directly into detergent particles was used after 4 hours as a control sample, and the fragrance was determined according to the following evaluation criteria.
+2 points: the control sample is better.
+1 point: The control sample is slightly better.
0 point: equivalent to the control sample.
-2 points: The control sample is slightly better.
-1 point: The control sample is good.

The average score of 8 persons was calculated and the result was expressed as follows.
+1.5 to +2.0: ◎◎
+0.5 to +1.4: ◎
−0.4 to +0.4: ○
-0.5 to -1.4: △
−1.5 to −2.0: ×
In both the samples after 4 hours and 24 hours, Examples 1 to 8, Comparative Examples 6 to 7 and Reference Example are samples after 4 hours of Comparative Example 1, Example 9 is Comparative Example 2, and Example 10 is Comparative Example. 3. In Example 11, Comparative Example 4 and in Example 12, the sample after 4 hours of Comparative Example 5 was used as a control sample.
Moreover, the thing of 24 hours after Comparative Examples 1-5 evaluated the thing after 4 hours of each comparative example as a control sample.

From the evaluation results in Table 4 above, it can be seen that the examples in the scope of the present invention have good storage stability, fragrance of clothing, and sustainability thereof.
On the other hand, about Comparative Examples 1-6, although the compounding quantity of the fragrance | flavor in a detergent composition does not change compared with Example 1, each performance is falling significantly compared with an Example. I understand that.
Further, Comparative Example 7 is a fragrance supported on silicic acid anhydride and zeolite as a carrier, but compared with Example 1, although the blending amount of the fragrance in the whole detergent composition is not changed, The performance of clothing aromas and their sustainability has declined.
The reference example is a reference for confirming the influence of the ratio of the fragrance and the nonionic cellulose ether on the performance.

If the fragrance | flavor particle | grains of this invention are used, an aroma can be provided by the very easy method of adding and mixing to a laundry product. By manufacturing and storing various fragrance particles in advance, the fragrance can be changed very easily even when changing the varieties during the manufacture of laundry products. is there.
Furthermore, by adding a fragrance in the form of a fragrance particle of the present invention to a powdered laundry product, the storage stability of the fragrance is improved, the aroma of the washing object is improved, and the fragrance sustainability is also improved. Increase.

Claims (5)

  A perfume particle, wherein a perfume is supported using powdered nonionic cellulose ether as a carrier.   The perfume particle according to claim 1, wherein the powdered nonionic cellulose ether is selected from hydroxyethylcellulose, methylcellulose, hydroxypropylcellulose, hydroxyethylmethylcellulose, hydroxypropylmethylcellulose and combinations thereof.   The fragrance | flavor particle | grains of Claim 1 or 2 whose powdery nonionic cellulose ether is hydroxypropyl methylcellulose.   Hydroxypropylmethylcellulose has a weight average molecular weight of 10,000 or more, 19 to 38% by mass of methoxyl group and 2 to 16% by mass of hydroxypropoxyl group, and the substitution degree of methoxyl group is 1.0 to 2.5. The fragrance | flavor particle | grains of Claim 3 which are these.   A detergent composition comprising at least one fragrance particle according to any one of claims 1 to 4.