JP2007306999A - Golf ball - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a golf ball which achieves excellent performance levels in yardage, aerodynamic symmetry, spinning performance, spin stability, anti-scratching performance and the like. <P>SOLUTION: The golf ball 2 has an inner sphere, an outer layer, an inner layer and a cover. The thickness Tc of the cover is 1.0 mm or less, the hardness Hc of the cover is 20 or more to 50 or less. The north hemisphere N and the south hemisphere S of the surface of the golf ball 2 has a near-pole area 28, a near-equator area 30 and an adjustment area 32 respectively. A dimple pattern on the near-pole area 28 consists of a plurality of units made rotationally symmetrical to each other centered on the pole point P. The dimple pattern on the near-equator area 30 consists of a plurality of units made rotationally symmetrical to each other centered on the pole point P. The number of the units in the near-pole area 28 is different from the number of the units in the near-equator area 30. The dimple pattern on the adjustment area 32 can not be sectioned into a plurality of units rotationally symmetrical to each other centered on the pole point P. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a golf ball. Specifically, the present invention relates to a golf ball having an inner sphere, an outer layer, an intermediate layer, a cover, and dimples.

  A golfer's greatest concern with golf balls is flight performance. In particular, golf players place importance on the flight distance of shots with a driver. Golfers also place importance on the distance traveled by long iron and middle iron shots. Flight performance is highly dependent on resilience performance.

  Flight performance is highly dependent on dimples. The dimples disturb the air flow around the golf ball during flight and cause turbulent separation. Turbulent separation shifts the separation point of air from the golf ball backwards, reducing drag. Turbulent separation promotes the deviation between the upper separation point and the lower separation point of the golf ball due to backspin, and increases the lift acting on the golf ball. The reduction of drag and the improvement of lift are referred to as “dimple effect”. Excellent dimples better disturb the air flow.

  For golf balls, aerodynamic symmetry is important as well as flight distance. In a golf ball excellent in aerodynamic symmetry, the flight distance does not depend on the hitting point. A golfer can easily drop the golf ball to a target point. Aerodynamic symmetry is also important from the viewpoint of conforming to the rules established by the American Golf Association.

  Various proposals regarding dimple patterns have been made from the viewpoint of flight distance and aerodynamic symmetry. Japanese Laid-Open Patent Publication No. 4-109968 discloses a dimple pattern in which a hemisphere is divided into six units. Japanese Unexamined Patent Application Publication No. 2004-243124 discloses a dimple pattern in which an octahedron is used for a section in the pole vicinity region and an icosahedron is used in a section in the equator vicinity region.

  Golfers also place importance on the spin performance of golf balls. If the backspin rate is high, the run is small. For golfers, a golf ball that is subject to backspin is likely to be stationary at a target point. When the side spin rate is high, the golf ball tends to bend. For golfers, golf balls that are susceptible to side spin tend to bend intentionally. A golf ball excellent in spin performance is excellent in control performance. Advanced golfers place particular importance on control performance in shots with short irons.

  For golfers, stability of the spin rate is also important. A golf ball having a large variation in spin speed cannot easily obtain the trajectory intended by the golfer.

  In a shot with an iron, the golf ball rubs against the club face. This rubbing may damage the surface of the golf ball. Golf balls with large scratches can no longer be used. Scratch resistance is also important for golf balls.

Various proposals regarding golf balls have been made from the viewpoint of improving various performances. Japanese Laid-Open Patent Publication No. 10-328325 discloses a four-piece golf ball comprising a two-layer core and a two-layer cover. This core consists of an inner sphere and an outer layer. The surface hardness of the core is smaller than the surface hardness of the inner sphere. Japanese Laid-Open Patent Publication No. 10-328328 discloses a four-piece golf ball comprising a two-layer core and a two-layer cover. This core consists of an inner sphere and an outer layer. The surface hardness of the core is smaller than the surface hardness of the inner sphere.
JP-A-4-109968 JP-A-2004-243124 JP 10-328325 A JP-A-10-328328

  Golfers' demand for golf balls has been escalating in recent years. A high level of balance of performance is eagerly desired. An object of the present invention is to provide a golf ball having excellent flight distance, aerodynamic symmetry, spin performance, spin stability, and scratch resistance.

  The golf ball according to the present invention includes a spherical core and a cover positioned outside the core. The core includes a spherical center and an intermediate layer located outside the center. The center includes an inner sphere and an outer layer located outside the inner sphere. The cover has a thickness Tc of 1.0 mm or less. The cover has a hardness Hc of 20 to 50. Each of the northern hemisphere and the southern hemisphere on the surface of the golf ball includes a pole vicinity region, an equator vicinity region, and an adjustment region located between the pole vicinity region and the equator vicinity region. Each of the pole vicinity region, the equator vicinity region, and the adjustment region includes a large number of dimples. The dimple pattern in the pole vicinity region is composed of a plurality of units that are rotationally symmetric with respect to the pole point. The dimple pattern in the vicinity of the equator is composed of a plurality of units that are rotationally symmetric with respect to the pole. The number of units in the pole vicinity region is different from the number of units in the equator vicinity region. The dimple pattern in the adjustment region cannot be divided into a plurality of units that are rotationally symmetric with respect to each other about the pole, or is composed of a plurality of units that are rotationally symmetric with respect to each other, and the number of these units is the same. This is different from the number of units in the pole vicinity region and the equator vicinity region.

  Preferably, a peak in the hardness curve from the center point of the inner sphere to the surface of the cover is achieved in the intermediate layer.

  Preferably, the inner sphere and the outer layer are composed of a composition based on a thermosetting polymer, and the intermediate layer and the cover are composed of a composition based on a thermoplastic polymer. Preferably, the main component of the base polymer of the intermediate layer is an ionomer resin, and the main component of the base polymer of the cover is a thermoplastic polyurethane elastomer.

  Preferably, the golf ball further includes a reinforcing layer between the intermediate layer and the cover. The thickness of this reinforcing layer is 3 μm or more and 50 μm or less.

  Preferably, the ratio (D2 / D3) of the compression deformation amount D2 of the core to the compression deformation amount D3 of the golf ball is 0.98 or more and 1.10 or less.

  Preferably, the boundary line between the pole vicinity region and the adjustment region is a latitude line having a latitude of 20 ° to 40 °, and the boundary line between the adjustment region and the equator vicinity region has a latitude of 20 ° to 40 °. A parallel.

  Preferably, the total number of dimples is 360 or less, and the ratio of the total area of all the dimples to the surface area of the phantom sphere is 75% or more.

  Preferably, the number of units in the pole vicinity region is an odd number, and the number of units in the equator vicinity region is an even number.

  In a conventional golf ball having a soft cover, this cover contributes to the spin performance. This soft cover may hinder resilience performance. In the conventional golf ball, the thin cover is employed, so that the inhibition of the resilience performance by the cover is suppressed. However, a cover that is too thin cannot fully contribute to spin performance. In the golf ball according to the present invention, the cover having extremely small hardness Hc is employed, so that the cover contributes to the spin performance and the spin stability even though the cover is thin. This cover can further contribute to scratch resistance. A thin cover does not impair resilience performance. Due to the synergistic effect of the resilience performance and the dimple effect, this golf ball can provide a great flight distance. The golf ball dimple pattern also contributes to aerodynamic symmetry.

  Hereinafter, the present invention will be described in detail based on preferred embodiments with appropriate reference to the drawings.

  FIG. 1 is a partially cutaway sectional view showing a golf ball 2 according to an embodiment of the present invention. The golf ball 2 includes a spherical core 4, a reinforcing layer 6 positioned outside the core 4, and a cover 8 positioned outside the reinforcing layer 6. The core 4 includes a spherical center 10 and an intermediate layer 12 located outside the center 10. The center 10 includes an inner sphere 14 and an outer layer 16 located outside the inner sphere 14. A large number of dimples 18 are formed on the surface of the cover 8. A portion of the surface of the cover 8 other than the dimples 18 is a land 20. The golf ball 2 includes a paint layer and a mark layer on the outside of the cover 8, but these layers are not shown.

  The golf ball 2 has a diameter of 40 mm to 45 mm. The diameter is preferably 42.67 mm or more from the viewpoint that the American Golf Association (USGA) standard is satisfied. In light of suppression of air resistance, the diameter is preferably equal to or less than 44 mm, and more preferably equal to or less than 42.80 mm. The golf ball 2 has a mass of 40 g or more and 50 g or less. From the viewpoint of obtaining a large inertia, the mass is preferably 44 g or more, and more preferably 45.00 g or more. From the viewpoint that the USGA standard is satisfied, the mass is preferably equal to or less than 45.93 g.

  The inner sphere 14 is made of a composition based on a thermosetting polymer. Specifically, the inner sphere 14 is obtained by crosslinking a rubber composition. Preferred base rubbers include polybutadiene, polyisoprene, styrene-butadiene copolymer, ethylene-propylene-diene copolymer, and natural rubber. From the viewpoint of resilience performance, polybutadiene is preferred. When polybutadiene and other rubber are used in combination, it is preferable that polybutadiene is a main component. Specifically, the proportion of polybutadiene in the total base rubber is preferably 50% by mass or more, particularly 80% by mass or more. Polybutadiene having a cis-1,4 bond ratio of 40% or more, particularly 80% or more is particularly preferred.

  A co-crosslinking agent is used for crosslinking the inner sphere 14. A preferred co-crosslinking agent from the viewpoint of resilience performance is a monovalent or divalent metal salt of an α, β-unsaturated carboxylic acid having 2 to 8 carbon atoms. Specific examples of preferred co-crosslinking agents include zinc acrylate, magnesium acrylate, zinc methacrylate and magnesium methacrylate. Zinc acrylate and zinc methacrylate are particularly preferable because of high resilience performance.

  As a co-crosslinking agent, an α, β-unsaturated carboxylic acid having 2 to 8 carbon atoms and a metal oxide may be blended. Both react in the rubber composition to obtain a salt. This salt contributes to the crosslinking reaction. Preferred α, β-unsaturated carboxylic acids include acrylic acid and methacrylic acid. Preferred metal oxides include zinc oxide and magnesium oxide.

  The compounding amount of the co-crosslinking agent is preferably 10 parts by mass or more and 40 parts by mass or less with respect to 100 parts by mass of the base rubber. By setting the blending amount to 10 parts by mass or more, excellent resilience performance can be achieved. In this respect, the amount to be blended is more preferably equal to or greater than 15 parts by weight. By setting the blending amount to 40 parts by mass or less, an excellent feel at impact can be achieved. In this respect, the amount to be blended is more preferably equal to or less than 35 parts by weight.

  Preferably, the rubber composition of the inner sphere 14 includes an organic peroxide together with a co-crosslinking agent. The organic peroxide functions as a crosslinking initiator. Organic peroxides contribute to resilience performance. Suitable organic peroxides include dicumyl peroxide, 1,1-bis (t-butylperoxy) -3,3,5-trimethylcyclohexane, 2,5-dimethyl-2,5-di (t- Butyl peroxy) hexane and di-t-butyl peroxide. A particularly versatile organic peroxide is dicumyl peroxide.

  The compounding amount of the organic peroxide is preferably 0.1 parts by mass or more and 3.0 parts by mass or less with respect to 100 parts by mass of the base rubber. By setting the blending amount to 0.1 parts by mass or more, excellent resilience performance can be achieved. In this respect, the amount is more preferably equal to or greater than 0.3 parts by weight, and particularly preferably equal to or greater than 0.5 parts by weight. By setting the blending amount to 3.0 parts by mass or less, an excellent feel at impact can be achieved. In this respect, the amount to be blended is more preferably equal to or less than 2.5 parts by mass.

  Preferably, the rubber composition of the inner sphere 14 includes an organic sulfur compound. Preferred organic sulfur compounds include diphenyl disulfide, bis (4-chlorophenyl) disulfide, bis (3-chlorophenyl) disulfide, bis (4-bromophenyl) disulfide, bis (3-bromophenyl) disulfide, and bis (4-fluorophenyl). ) Monosubstituted products such as disulfide, bis (4-iodophenyl) disulfide, bis (4-cyanophenyl) disulfide; bis (2,5-dichlorophenyl) disulfide, bis (3,5-dichlorophenyl) disulfide, bis (2, 6-dichlorophenyl) disulfide, bis (2,5-dibromophenyl) disulfide, bis (3,5-dibromophenyl) disulfide, bis (2-chloro-5-bromophenyl) disulfide, bis (2-cyano-5-bromophene) Di) disubstituted compounds such as disulfide; trisubstituted compounds such as bis (2,4,6-trichlorophenyl) disulfide and bis (2-cyano-4-chloro-6-bromophenyl) disulfide; Tetra-substituted products such as 5,6-tetrachlorophenyl) disulfide; and bis (2,3,4,5,6-pentachlorophenyl) disulfide, bis (2,3,4,5,6-pentabromophenyl) disulfide, etc. The penta-substituted product is exemplified. Organic sulfur compounds contribute to resilience performance. Particularly preferred organic sulfur compounds are diphenyl disulfide and bis (pentabromophenyl) disulfide.

  In light of the resilience performance of the golf ball 2, the amount of the organic sulfur compound is preferably equal to or greater than 0.1 parts by weight and more preferably equal to or greater than 0.2 parts by weight with respect to 100 parts by weight of the base rubber. From the viewpoint of soft feel at impact, the compounding amount of the organic sulfur compound is preferably 1.5 parts by mass or less, more preferably 1.0 part by mass or less, and 0.8 parts by mass or less with respect to 100 parts by mass of the base rubber. Is particularly preferred.

  A filler may be blended in the inner sphere 14 for the purpose of adjusting specific gravity and the like. Suitable fillers include zinc oxide, barium sulfate, calcium carbonate and magnesium carbonate. As a filler, a powder made of a high specific gravity metal may be blended. Specific examples of the high specific gravity metal include tungsten and molybdenum. The blending amount of the filler is appropriately determined so that the intended specific gravity of the inner sphere 14 is achieved. A particularly preferred filler is zinc oxide. Zinc oxide functions not only as a specific gravity adjuster but also as a crosslinking aid. In the inner sphere 14, various additives such as sulfur, anti-aging agent, coloring agent, plasticizer, and dispersing agent are blended in an appropriate amount as necessary. The inner sphere 14 may be blended with a crosslinked rubber powder or a synthetic resin powder.

  The center hardness Hi of the inner sphere 14 is preferably 20 or greater and 45 or less. With the inner sphere 14 having a center hardness Hi of 20 or more, excellent resilience performance and light hit feeling can be achieved. In this respect, the central hardness Hi is more preferably equal to or greater than 24, and particularly preferably equal to or greater than 27. Due to the inner sphere 14 having a central hardness Hi of 45 or less, excessive spin in a shot with a driver is suppressed. In this respect, the center hardness Hi is more preferably 41 or less, and particularly preferably 38 or less. The center hardness Hi is measured by pressing a Shore D type hardness meter against the center point of the hemisphere obtained by cutting the inner sphere 14. For the measurement, an automatic rubber hardness measuring machine (trade name “LA1” manufactured by Kobunshi Keiki Co., Ltd.) equipped with this hardness meter is used.

  The surface hardness Hsi of the inner sphere 14 is preferably 30 or greater and 70 or less. Excellent resilience performance can be achieved by the inner sphere 14 having a surface hardness Hsi of 30 or more. In this respect, the surface hardness Hsi is more preferably equal to or greater than 40, and particularly preferably equal to or greater than 45. An excellent shot feeling can be achieved by the inner ball 14 having a surface hardness Hsi of 70 or less. In this respect, the surface hardness Hsi is more preferably equal to or less than 60, and particularly preferably equal to or less than 55. The surface hardness is measured by pressing a Shore D type hardness meter against the surface of the sphere (inner sphere 14, center 10, core 4 or golf ball 2). For the measurement, an automatic rubber hardness measuring machine (trade name “LA1” manufactured by Kobunshi Keiki Co., Ltd.) equipped with this hardness meter is used.

  From the viewpoint of achieving both shot feel and resilience performance, the difference (Hsi-Hi) between the surface hardness Hsi and the center hardness Hi is preferably 10 or more, and more preferably 15 or more. The difference (Hsi−Hi) is preferably 30 or less.

  The amount of compressive deformation Di of the inner sphere 14 is preferably 2.5 mm or greater and 6.0 mm or less. An excellent shot feeling can be achieved by the inner sphere 14 having a compression deformation amount Di of 2.5 mm or more. In this respect, the amount of compressive deformation Di is more preferably 2.8 mm or more, and particularly preferably 3.0 mm or more. As will be described later, the cover 8 of the golf ball 2 is thin. When the golf ball 2 is hit, the inner ball 14 is greatly deformed due to the thin cover 8. Excellent resilience performance can be achieved by the inner sphere 14 having a compression deformation amount Di of 6.0 mm or less. In this respect, the amount of compressive deformation Di is more preferably equal to or less than 5.5 mm, and particularly preferably equal to or less than 5.0 mm.

  In the measurement of the amount of compressive deformation, first, a sphere (inner sphere 14, center 10, core 4 or golf ball 2) is placed on a metal rigid plate. Next, the metal cylinder gradually descends toward the sphere. The sphere sandwiched between the bottom surface of the cylinder and the rigid plate is deformed. The moving distance of the cylinder from the state where the initial load of 98 N is applied to the sphere to the state where the final load of 1274 N is applied is the amount of compressive deformation.

  The diameter of the inner sphere 14 is preferably 20 mm or more, more preferably 24 mm or more, and particularly preferably 25 mm or more. The diameter of the inner sphere 14 is preferably 36 mm or less, more preferably 35 mm or less, and particularly preferably 34 mm or less. The mass of the inner sphere 14 is preferably 25 g or more and 40 g or less. The crosslinking temperature of the inner sphere 14 is usually 130 ° C. or higher and 180 ° C. or lower. The crosslinking time of the inner sphere 14 is usually 10 minutes or more and 50 minutes or less.

  The outer layer 16 is made of a composition based on a thermosetting polymer. Specifically, the outer layer 16 is obtained by crosslinking a rubber composition. A preferable base rubber is equivalent to the base rubber of the inner sphere 14.

  A co-crosslinking agent equivalent to the inner sphere 14 is used for the outer layer 16. The amount of the co-crosslinking agent is preferably 20 parts by mass or more and 50 parts by mass or less with respect to 100 parts by mass of the base rubber. By setting the blending amount to 20 parts by mass or more, excellent resilience performance can be achieved. In this respect, the amount to be blended is more preferably equal to or greater than 35 parts by weight. By setting the blending amount to 50 parts by mass or less, an excellent feel at impact can be achieved. In this respect, the amount to be blended is more preferably equal to or less than 45 parts by weight.

  Similar to the rubber composition of the inner sphere 14, an organic peroxide and an organic sulfur compound can be blended in the rubber composition of the outer layer 16. The kind and blending amount of the organic peroxide and the kind and blending amount of the organic sulfur compound are equivalent to those of the inner sphere 14. Fillers and additives equivalent to the rubber composition of the inner sphere 14 may be blended in the rubber composition.

  The thickness To of the outer layer 16 is preferably 2.3 mm or greater and 4.3 mm or less. The outer layer 16 having a thickness To of 2.3 mm or more contributes to resilience performance. In this respect, the thickness To is more preferably equal to or greater than 2.7 mm, and particularly preferably equal to or greater than 3.0 mm. The outer layer 16 having a thickness To of 4.3 mm or less does not impair the feel at impact. In this respect, the thickness To is more preferably 3.9 mm or less, and particularly preferably 3.6 mm or less.

  The surface hardness Hs1 of the center 10 composed of the inner sphere 14 and the outer layer 16 is preferably 40 or more and 80 or less. Excellent resilience performance can be achieved by the center 10 having a surface hardness Hs1 of 40 or more. In this respect, the surface hardness Hs1 is more preferably equal to or greater than 50, and particularly preferably equal to or greater than 55. An excellent feel at impact can be achieved by the center 10 having a surface hardness Hs1 of 80 or less. In this respect, the surface hardness Hs1 is more preferably equal to or less than 70, and particularly preferably equal to or less than 65.

  From the viewpoint of achieving both feel at impact and resilience performance, the difference (Hs1-Hi) between the surface hardness Hs1 and the center hardness Hi is preferably 20 or more, and more preferably 25 or more. The difference (Hs1-Hi) is preferably 40 or less.

  The difference (Hs1−Hsi) between the surface hardness Hs1 of the center 10 and the surface hardness Hsi of the inner sphere 14 is preferably 3 or more. In the center 10, the inner ball 14 mainly contributes to the hit feeling and the outer layer 16 mainly contributes to the resilience performance. In this respect, the difference (Hs1−Hsi) is more preferably 5 or greater and particularly preferably 8 or greater. The difference (Hs1-Hsi) is preferably 20 or less.

  The amount of compressive deformation D1 of the center 10 is preferably 2.7 mm or greater and 5.0 mm or less. An excellent shot feeling can be achieved by the center 10 in which the amount of compressive deformation D1 is 2.7 mm or more. In this respect, the amount of compressive deformation D1 is more preferably 2.8 mm or more, and particularly preferably 2.9 mm or more. As will be described later, the cover 8 of the golf ball 2 is thin. When the golf ball 2 is hit, the center 10 is greatly deformed due to the thin cover 8. Excellent resilience performance can be achieved by the center 10 having the amount of compressive deformation D1 of 5.0 mm or less. In this respect, the amount of compressive deformation D1 is more preferably equal to or less than 4.5 mm, and particularly preferably equal to or less than 4.0 mm.

  The diameter of the center 10 is preferably 27 mm or more, more preferably 28 mm or more, and particularly preferably 30 mm or more. The diameter of the center 10 is preferably 42 mm or less, and more preferably 39 mm or less. The mass of the center 10 is preferably 30 g or more and 45 g or less.

  In the manufacture of the center 10, a half shell is formed from the rubber composition for the outer layer. The two inner shells 14 are covered with the two half shells. The inner sphere 14 and the half shell are pressurized and heated in the mold to obtain the center 10.

  For the mid layer 12, a thermoplastic resin composition is suitably used. Examples of the base polymer of the resin composition include ionomer resins, thermoplastic polyester elastomers, thermoplastic polyamide elastomers, thermoplastic polyurethane elastomers, thermoplastic polyolefin elastomers, and thermoplastic polystyrene elastomers. In particular, an ionomer resin is preferable. The ionomer resin is highly elastic. As will be described later, the cover 8 of the golf ball 2 is thin. When the golf ball 2 is hit, the mid layer 12 is greatly deformed due to the thin cover 8. The intermediate layer 12 containing an ionomer resin contributes to resilience performance.

  An ionomer resin and another resin may be used in combination. When used in combination, the ionomer resin is the main component of the base polymer from the viewpoint of resilience performance. The proportion of the ionomer resin in the total base polymer is preferably 50% by mass or more, more preferably 70% by mass or more, and particularly preferably 85% or more.

  A preferable ionomer resin includes a binary copolymer of an α-olefin and an α, β-unsaturated carboxylic acid having 3 to 8 carbon atoms. A preferable binary copolymer contains 80% by mass or more and 90% by mass or less α-olefin and 10% by mass or more and 20% by mass or less α, β-unsaturated carboxylic acid. This binary copolymer is excellent in resilience performance. Other preferable ionomer resins include ternary α-olefin, α, β-unsaturated carboxylic acid having 3 to 8 carbon atoms and α, β-unsaturated carboxylic acid ester having 2 to 22 carbon atoms. A copolymer is mentioned. Preferred terpolymers are 70% to 85% by weight α-olefin, 5% to 30% by weight α, β-unsaturated carboxylic acid, and 1% to 25% by weight. α, β-unsaturated carboxylic acid ester. This ternary copolymer is excellent in resilience performance. In the binary copolymer and ternary copolymer, preferred α-olefins are ethylene and propylene, and preferred α, β-unsaturated carboxylic acids are acrylic acid and methacrylic acid. A particularly preferred ionomer resin is a copolymer of ethylene and acrylic acid or methacrylic acid.

  In the binary copolymer and ternary copolymer, some of the carboxyl groups are neutralized with metal ions. Examples of the metal ions for neutralization include sodium ions, potassium ions, lithium ions, zinc ions, calcium ions, magnesium ions, aluminum ions, and neodymium ions. Neutralization may be performed with two or more metal ions. Particularly suitable metal ions from the viewpoint of resilience performance and durability of the golf ball 2 are sodium ion, zinc ion, lithium ion and magnesium ion.

  Specific examples of the ionomer resin include Mitsui Dupont Polychemical's trade names “HIMILAN 1555”, “HIMILAN 1557”, “HIMILAN 1605”, “HIMILAN 1706”, “HIMILAN 1707”, “HIMILAN 1856” and “HIMILAN 1855”. "High Milan AM 7311", "High Milan AM 7315", "High Milan AM 7317", "Hi Milan AM 7318", "Hi Milan AM 7329" and "Hi Milan MK7320"; DuPont's trade names "Surlin 6120", "Surlin 6910", "Surlin 7930" , “Surlin 7940”, “Surlin 8140”, “Surlin 8150”, “Surlin 8940”, “Surlin 8945”, “Surlin 9120”, “Surlin 9150”, “Surlin 9910”, Surlyn 9945 "and" Surlyn AD8546 "; and ExxonMobil Chemical Co. under the trade name of" IOTEK7010 "," IOTEK7030 "," IOTEK7510 "," IOTEK7520 "includes" IOTEK8000 "and" IOTEK8030 ". Two or more ionomer resins may be used in combination. An ionomer resin neutralized with a monovalent metal ion and an ionomer resin neutralized with a divalent metal ion may be used in combination.

  A filler may be blended in the resin composition of the mid layer 12 for the purpose of adjusting specific gravity and the like. Suitable fillers include zinc oxide, barium sulfate, calcium carbonate and magnesium carbonate. As a filler, a powder made of a high specific gravity metal may be blended. Specific examples of the high specific gravity metal include tungsten and molybdenum. The blending amount of the filler is appropriately determined so that the intended specific gravity of the mid layer 12 is achieved. The intermediate layer 12 may be blended with a colorant, a crosslinked rubber powder, or a synthetic resin powder.

  The mid layer 12 preferably has a hardness Hm of 55 or greater and 72 or less. Excellent resilience performance can be achieved by the intermediate layer 12 having a hardness Hm of 55 or more. Moreover, the outer-hard / inner-soft core 4 is achieved by the intermediate layer 12 having a hardness Hm of 55 or more. The core 4 contributes to the suppression of spin in a shot with a driver. From these viewpoints, the hardness Hm is more preferably 58 or more, and particularly preferably 60 or more. With the mid layer 12 having a hardness Hm of 72 or less, an excellent feel at impact can be achieved. In this respect, the hardness Hm is more preferably equal to or less than 70, and particularly preferably equal to or less than 68. Preferably, the peak in the hardness curve from the center point of the inner sphere 14 to the surface of the cover 8 is achieved in the intermediate layer 12.

  In the present invention, the hardness Hm of the mid layer 12 and the hardness Hc of the cover 8 are measured in accordance with the provisions of “ASTM-D 2240-68”. For the measurement, an automatic rubber hardness meter (trade name “LA1” manufactured by Kobunshi Keiki Co., Ltd.) equipped with a Shore D hardness meter is used. For the measurement, a sheet made of the same material as that of the intermediate layer 12 (or the cover 8) and having a thickness of about 2 mm is used. Prior to measurement, the sheet is stored at a temperature of 23 ° C. for 2 weeks. At the time of measurement, three sheets are overlaid.

  The thickness Tm of the mid layer 12 is preferably 0.3 mm or greater and 2.5 mm or less. Excellent resilience performance can be achieved by the intermediate layer 12 having a thickness Tm of 0.3 mm or more. In this respect, the thickness Tm is more preferably equal to or greater than 0.5 mm, and particularly preferably equal to or greater than 0.7 mm. The mid layer 12 having a thickness Tm of 2.5 mm or less does not impair the feel at impact. In this respect, the thickness Tm is more preferably equal to or less than 2.0 mm.

  The surface hardness Hs2 of the core 4 composed of the center 10 and the intermediate layer 12 is preferably 50 or greater and 85 or less. Excellent resilience performance can be achieved by the core 4 having a surface hardness Hs2 of 50 or more. In this respect, the surface hardness Hs2 is more preferably equal to or greater than 55, and particularly preferably equal to or greater than 60. The core 4 having a surface hardness Hs2 of 85 or less does not impair the feel at impact. In this respect, the surface hardness Hs2 is more preferably equal to or less than 80, and particularly preferably equal to or less than 75.

  The amount of compressive deformation D2 of the core 4 is preferably 1.8 mm or greater and 4.0 mm or less. An excellent feel at impact can be achieved by the core 4 having the compression deformation amount D2 of 1.8 mm or more. In this respect, the amount of compressive deformation D2 is more preferably equal to or greater than 2.0 mm, and particularly preferably equal to or greater than 2.2 mm. As will be described later, the cover 8 of the golf ball 2 is thin. When the golf ball 2 is hit, the core 4 is greatly deformed due to the thin cover 8. Excellent resilience performance can be achieved by the core 4 having a compression deformation amount D2 of 4.0 mm or less. In this respect, the amount of compressive deformation D2 is more preferably equal to or less than 3.7 mm, and particularly preferably equal to or less than 3.4 mm.

  From the viewpoint of the close contact between the core 4 and the reinforcing layer 6 or the cover 8, it is preferable that the surface of the core 4 is treated to increase its roughness. Specific examples of the treatment include brushing and polishing.

  The reinforcing layer 6 is interposed between the intermediate layer 12 and the cover 8 to enhance the adhesion between them. As will be described later, the cover 8 of the golf ball 2 is extremely thin. If the thin cover 8 is hit by the edge of the club face, wrinkles are likely to occur. The reinforcing layer 6 suppresses wrinkles.

  For the base polymer of the reinforcing layer 6, a two-component curable thermosetting resin is preferably used. Specific examples of the two-component curable thermosetting resin include an epoxy resin, a urethane resin, an acrylic resin, a polyester resin, and a cellulose resin. From the viewpoint of the properties (for example, breaking strength) and durability of the reinforcing layer 6, a two-component curable epoxy resin and a two-component curable urethane resin are preferable.

  The two-component curable epoxy resin is obtained by curing the epoxy resin with a polyamide curing agent. Examples of the epoxy resin used in the two-part curable epoxy resin include bisphenol A type epoxy resin, bisphenol F type epoxy resin, and bisphenol AD type epoxy resin. The bisphenol A type epoxy resin is obtained by a reaction between bisphenol A and an epoxy group-containing compound such as epichlorohydrin. The bisphenol F type epoxy resin is obtained by a reaction between bisphenol F and an epoxy group-containing compound. The bisphenol AD type epoxy resin is obtained by a reaction between bisphenol AD and an epoxy group-containing compound. From the viewpoint of the balance of flexibility, chemical resistance, heat resistance and toughness, bisphenol A type epoxy resin is preferable.

  The polyamide-based curing agent has a plurality of amino groups and one or more amide groups. This amino group can react with an epoxy group. Specific examples of the polyamide curing agent include a polyamide amine curing agent and a modified product thereof. The polyamidoamine curing agent is obtained by a condensation reaction between a polymerized fatty acid and a polyamine. Typical polymerized fatty acids can be obtained by synthesizing natural fatty acids containing a large amount of unsaturated fatty acids such as linoleic acid and linolenic acid by heating in the presence of a catalyst. Specific examples of unsaturated fatty acids include tall oil, soybean oil, linseed oil and fish oil. A polymerized fatty acid having a dimer content of 90% by mass or more, a trimer content of 10% by mass or less, and hydrogenated is preferable. Preferred polyamines include polyethylene diamine, polyoxyalkylene diamine and derivatives thereof.

  In the mixing of the epoxy resin and the polyamide curing agent, the ratio of the epoxy equivalent of the epoxy resin and the amine active hydrogen equivalent of the polyamide curing agent is 1.0 / 1.4 or more and 1.0 / 1.0 or less. Is preferred.

  The two-component curable urethane resin is obtained by a reaction between the main agent and the curing agent. A two-component curable urethane resin obtained by a reaction between a main component containing a polyol component and a curing agent containing a polyisocyanate or a derivative thereof, a main component containing an isocyanate group-terminated urethane prepolymer, and a curing agent having active hydrogen. A two-component curable urethane resin obtained by reaction may be used. In particular, a two-component curable urethane resin obtained by a reaction between a main component containing a polyol component and a curing agent containing polyisocyanate or a derivative thereof is preferable.

  It is preferable that urethane polyol is used as the polyol component of the main agent. The urethane polyol has a urethane bond and at least two or more hydroxyl groups. Preferably, the urethane polyol has a hydroxyl group at its terminal. The urethane polyol can be obtained by reacting the polyol and the polyisocyanate at a ratio such that the hydroxyl group of the polyol component is excessive in molar ratio with respect to the isocyanate group of the polyisocyanate.

  The polyol used for the production of the urethane polyol has a plurality of hydroxyl groups. A polyol having a weight average molecular weight of 50 to 2,000, particularly 100 to 1,000 is preferred. Examples of the low molecular weight polyol include diol and triol. Specific examples of the diol include ethylene glycol, diethylene glycol, triethylene glycol, 1,3-butanediol, 1,4-butanediol, neopentyl glycol and 1,6-hexanediol. Specific examples of the triol include trimethylolpropane and hexanetriol. Polyether polyols such as polyoxyethylene glycol (PEG), polyoxypropylene glycol (PPG) and polyoxytetramethylene glycol (PTMG) as high molecular weight polyols; polyethylene adipate (PEA), polybutylene adipate (PBA) ) And polyhexamethylene adipate (PHMA); lactone polyester polyols such as poly-ε-caprolactone (PCL); polycarbonate polyols such as polyhexamethylene carbonate; and acrylic polyols. Two or more polyols may be used in combination.

The polyisocyanate used for the production of the urethane polyol has a plurality of isocyanate groups. Specific examples of the polyisocyanate include 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, a mixture of 2,4-toluene diisocyanate and 2,6-toluene diisocyanate (TDI), and 4,4′-diphenylmethane diisocyanate (MDI). ), 1,5-naphthylene diisocyanate (NDI), 3,3′-vitrylene-4,4′-diisocyanate (TODI), xylylene diisocyanate (XDI), tetramethylxylylene diisocyanate (TMXDI) and paraphenylene diisocyanate ( Aromatic polyisocyanates such as PPDI); 4,4′-dicyclohexylmethane diisocyanate (H ₁₂ MDI), hydrogenated xylylene diisocyanate (H ₆ XDI), hexamethylene diisocyanate (HDI) ) And cycloaliphatic polyisocyanates such as isophorone diisocyanate (IPDI); and aliphatic polyisocyanates. Two or more polyisocyanates may be used in combination. From the viewpoint of weather resistance, TMXDI, XDI, HDI, H ₆ XDI, IPDI and H ₁₂ MDI are preferred.

  A known catalyst can be used in the reaction of the polyol and the polyisocyanate for producing the urethane polyol. A typical catalyst is dibutyltin dilaurate.

  From the viewpoint of the strength of the reinforcing layer 6, the ratio of the urethane bond contained in the urethane polyol is preferably 0.1 mmol / g or more. From the viewpoint of the followability of the reinforcing layer 6 to the cover 8, the ratio of urethane bonds contained in the urethane polyol is preferably 5 mmol / g or less. The ratio of the urethane bond can be adjusted by adjusting the molecular weight of the polyol as a raw material and adjusting the blending ratio of the polyol and the polyisocyanate.

  From the viewpoint that the time required for the reaction between the main agent and the curing agent is short, the weight average molecular weight of the urethane polyol is preferably 4000 or more, and more preferably 4500 or more. From the viewpoint of adhesion of the reinforcing layer 6, the urethane polyol has a weight average molecular weight of preferably 10,000 or less, and more preferably 9000 or less.

  From the viewpoint of adhesion of the reinforcing layer 6, the hydroxyl value (mgKOH / g) of the urethane polyol is preferably 15 or more, and more preferably 73 or more. From the viewpoint that the time required for the reaction between the main agent and the curing agent is short, the hydroxyl value of the urethane polyol is preferably 130 or less, more preferably 120 or less.

  The main agent may contain a polyol having no urethane bond together with the urethane polyol. The aforementioned polyol, which is a raw material for urethane polyol, can be used as the main agent. Polyols that are compatible with urethane polyols are preferred. From the viewpoint that the time required for the reaction between the main agent and the curing agent is short, the ratio of the urethane polyol in the main agent is preferably 50% by mass or more and more preferably 80% by mass or more in terms of solid content. Ideally this ratio is 100% by weight.

  The curing agent contains polyisocyanate or a derivative thereof. The aforementioned polyisocyanate, which is a raw material of urethane polyol, can be used as a curing agent.

  The reinforcing layer 6 may contain additives such as a colorant (typically titanium dioxide), a phosphoric acid stabilizer, an antioxidant, a light stabilizer, a fluorescent brightener, an ultraviolet absorber, and an antiblocking agent. . The additive may be added to the main component of the two-component curable thermosetting resin, or may be added to the curing agent.

  The reinforcing layer 6 is obtained by applying a liquid in which the main agent and the curing agent are dissolved or dispersed in a solvent to the surface of the intermediate layer 12. From the viewpoint of workability, application with a spray gun is preferred. After application, the solvent volatilizes and the main agent and the curing agent react to form the reinforcing layer 6. Preferred solvents include toluene, isopropyl alcohol, xylene, methyl ethyl ketone, methyl isobutyl ketone, ethylene glycol monomethyl ether, ethylbenzene, propylene glycol monomethyl ether, isobutyl alcohol and ethyl acetate.

  From the viewpoint of suppressing wrinkles, the thickness Tr of the reinforcing layer 6 is preferably 3 μm or more, and more preferably 5 μm or more. From the viewpoint that the reinforcing layer 6 can be easily formed, the thickness Tr is preferably 300 μm or less, more preferably 100 μm or less, further 50 μm or less, and further preferably 20 μm or less. The thickness Tr is measured by observing a cross section of the golf ball 2 with a microscope. In the case where the surface of the intermediate layer 12 has irregularities by the roughening treatment, the thickness is measured immediately above the convex portions.

  From the viewpoint of suppressing wrinkles, the pencil hardness of the reinforcing layer 6 is preferably 4B or more, and more preferably B or more. From the viewpoint that the transmission loss of force from the cover 8 to the mid layer 12 is small when the golf ball 2 is hit, the pencil hardness of the reinforcing layer 6 is preferably 3H or less. The pencil hardness is measured according to the “JIS K5400” standard.

  When the intermediate layer 12 and the cover 8 are sufficiently in close contact with each other and wrinkles are not easily generated, the reinforcing layer 6 may not be provided.

  A thermoplastic resin composition is suitably used for the cover 8. Examples of the base polymer of the resin composition include thermoplastic polyurethane elastomers, thermoplastic polyester elastomers, thermoplastic polyamide elastomers, thermoplastic polyolefin elastomers, thermoplastic polystyrene elastomers, and ionomer resins. In particular, a thermoplastic polyurethane elastomer is preferable. The thermoplastic polyurethane elastomer is soft. When the golf ball 2 having the cover 8 made of thermoplastic polyurethane elastomer is hit with a short iron, the spin rate is high. The cover 8 made of a thermoplastic polyurethane elastomer contributes to control performance in a shot with a short iron. The thermoplastic polyurethane elastomer also contributes to the scratch resistance performance of the cover 8. Furthermore, with a thermoplastic polyurethane elastomer, an excellent feel at impact when hit with a putter or a short iron can be achieved.

  A thermoplastic polyurethane elastomer and other resin may be used in combination. When used in combination, a thermoplastic polyurethane elastomer is the main component of the base polymer from the viewpoint of control performance. The ratio of the thermoplastic polyurethane elastomer in the total base polymer is preferably 50% by mass or more, more preferably 70% by mass or more, and particularly preferably 85% by mass or more.

  The thermoplastic polyurethane elastomer includes a polyurethane component as a hard segment and a polyester component or a polyether component as a soft segment. Examples of the curing agent for the polyurethane component include alicyclic diisocyanate, aromatic diisocyanate and aliphatic diisocyanate. In particular, alicyclic diisocyanates are preferred. Since the alicyclic diisocyanate does not have a double bond in the main chain, yellowing of the cover 8 is suppressed. Moreover, since the alicyclic diisocyanate is excellent in strength, damage to the cover 8 is suppressed. Two or more diisocyanates may be used in combination.

Examples of alicyclic diisocyanates include 4,4′-dicyclohexylmethane diisocyanate (H ₁₂ MDI), 1,3-bis (isocyanatomethyl) cyclohexane (H ₆ XDI), isophorone diisocyanate (IPDI), and trans-1,4- Examples are cyclohexane diisocyanate (CHDI). From the viewpoint of versatility and workability, H ₁₂ MDI is preferable.

  Aromatic diisocyanates include 4,4'-diphenylmethane diisocyanate (MDI) and toluene diisocyanate (TDI). As the aliphatic diisocyanate, hexamethylene diisocyanate (HDI) is exemplified.

  A thermoplastic polyurethane elastomer having a material hardness of 50 or less, more preferably 45 or less, further 38 or less, and even 34 or less is preferable. With this elastomer, a small hardness Hc of the cover 8 can be achieved. From the viewpoint of preventing excessive spin, the material hardness is preferably 20 or more, and more preferably 26 or more. For measurement of material hardness, a sheet made of a single polymer is used. The measuring method is equivalent to the measuring method of the hardness Hm of the mid layer 12.

  Specific examples of the thermoplastic polyurethane elastomer include BASF Japan trade names “Elastolan XNY80A”, “Elastolan XNY85A”, “Elastolan XNY90A”, trade name “Elastolan XNY97A”, trade name “Elastolan XNY585” and Trade name “Elastollan XKP016N”; trade name “Rezamin P4585LS” and trade name “Rezamin PS62490” of Dainichi Seika Kogyo Co., Ltd. From the viewpoint that a small hardness Hc can be achieved, “Elastolan XNY80A”, “Elastolan XNY85A”, and “Elastolan XNY90A” are particularly preferable.

  If necessary, the cover 8 includes a colorant such as titanium dioxide, a filler such as barium sulfate, a dispersant, an antioxidant, an ultraviolet absorber, a light stabilizer, a fluorescent agent, a fluorescent whitening agent, and the like. Appropriate amount is blended. For the purpose of adjusting the specific gravity, the cover 8 may be mixed with a powder of a high specific gravity metal such as tungsten or molybdenum.

  The cover 8 has a hardness Hc of 50 or less. This cover 8 is soft. When the golf ball 2 is hit with a short iron, the cover 8 is sufficiently deformed even though the thickness Tc is small. By this deformation, a long contact time between the face of the short iron and the golf ball 2 is achieved. A long spin time provides a large spin rate. Long contact times can also suppress spin rate variation. In addition, this cover 8 can also achieve excellent scratch resistance. Further, the cover 8 can achieve an excellent shot feeling when hit with a putter or a short iron. Since the cover 8 is thin, when the golf ball 2 is hit with a driver, the cover 8 does not hinder the resilience performance even though the hardness Hc is small. The golf ball 2 is excellent in spin performance, spin stability, scratch resistance, feel at impact, and resilience performance. A large flight distance is obtained by the resilience performance and the dimple effect described later. From these viewpoints, the hardness Hc is more preferably 45 or less, and particularly preferably 40 or less. From the viewpoint of suppressing spin in a shot with a driver, the hardness is preferably 20 or more, more preferably 23 or more, and particularly preferably 26 or more.

  The cover 8 has a thickness Tc of 1.0 mm or less. As described above, the cover 8 is soft. The soft cover 8 is disadvantageous in terms of the coefficient of restitution of the golf ball 2. In the shot with the driver, the core 4 of the golf ball 2 is also greatly deformed. By setting the thickness Tc to 1.0 mm or less, even if the cover 8 is soft, the cover 8 does not have a significant adverse effect on the coefficient of restitution upon a shot with a driver. By using an ionomer resin for the mid layer 12, excellent flight performance in a shot with a driver can be achieved.

  In light of flight performance, the thickness Tc is more preferably equal to or less than 0.8 mm, and particularly preferably equal to or less than 0.5 mm. In light of suppression of an excessively low spin rate, the thickness Tc is preferably equal to or greater than 0.1 mm, and more preferably equal to or greater than 0.2 mm.

  The amount of compressive deformation D3 of the golf ball 2 is preferably 2.20 mm or more and 2.90 mm or less. The golf ball 2 having a compression deformation amount D3 of 2.20 mm or more is excellent in feel at impact. In this respect, the amount of compressive deformation D3 is more preferably equal to or greater than 2.25 mm, and particularly preferably equal to or greater than 2.30 mm. The golf ball 2 having a compression deformation amount D3 of 2.90 mm or less is excellent in resilience performance. In this respect, the amount of compressive deformation D3 is more preferably equal to or less than 2.85 mm, and particularly preferably equal to or less than 2.80 mm.

  In the golf ball 2 according to the present invention, the difference between the compression deformation amount D3 and the compression deformation amount D2 is small. In other words, the ratio (D2 / D3) is close to 1.00. The ratio (D2 / D3) is an index that depends on the thickness and hardness Hc of the cover 8. In the golf ball 2 having a ratio (D2 / D3) close to 1.00, the influence of the cover 8 on the amount of compressive deformation D3 is small. In the golf ball 2 having a ratio (D2 / D3) close to 1.00, the cover 8 is thin and the hardness Hc of the cover 8 is low. The cover 8 contributes to spin performance, spin stability, and scratch resistance.

  The ratio (D2 / D3) is preferably 0.98 or more and 1.10 or less. When the golf ball 2 having a ratio (D2 / D3) of 0.98 or more is hit with a driver, excessive spin does not occur. In this respect, the ratio (D2 / D3) is more preferably 0.99 or higher and particularly preferably 1.00 or higher. The golf ball 2 having a ratio (D2 / D3) of 1.10 or less is excellent in spin performance and spin stability in a shot with a short iron. In this respect, the ratio (D2 / D3) is more preferably equal to or less than 1.08, still more preferably equal to or less than 1.07, and particularly preferably equal to or less than 1.05.

  FIG. 2 is an enlarged front view showing the golf ball 2 of FIG. In FIG. 2, two pole points P, two first latitude lines 22, two second latitude lines 24, and an equator 26 are depicted. The latitude of the pole P is 90 °, and the latitude of the equator 26 is 0 °. The latitude of the first latitude line 22 is greater than the latitude of the second latitude line 24.

  The golf ball 2 includes a northern hemisphere N above the equator 26 and a southern hemisphere S below the equator 26. Each of the northern hemisphere N and the southern hemisphere S includes a pole vicinity region 28, an equator vicinity region 30, and an adjustment region 32. The first latitude line 22 is a boundary line between the pole vicinity region 28 and the adjustment region 32. The second latitude line 24 is a boundary line between the equator vicinity region 30 and the adjustment region 32. The pole vicinity region 28 is located between the pole point P and the first latitude line 22. The equator vicinity region 30 is located between the second latitude line 24 and the equator 26. The adjustment region 32 is located between the first latitude line 22 and the second latitude line 24. In other words, the adjustment region 32 is located between the pole vicinity region 28 and the equator vicinity region 30.

  Each of the pole vicinity region 28, the equator vicinity region 30, and the adjustment region 32 includes a large number of dimples 18. As is apparent from FIG. 2, the planar shape of all the dimples 18 is a circle. In the dimple 18 that intersects the first latitude line 22 or the second latitude line 24, the region to which the dimple 18 belongs is determined based on the center position of the dimple 18. The dimple 18 that intersects the first latitude line 22 and whose center is located in the pole vicinity region 28 belongs to the pole vicinity region 28. The dimple 18 that intersects the first latitude line 22 and whose center is located in the adjustment region 32 belongs to the adjustment region 32. The dimple 18 that intersects the second latitude line 24 and whose center is located in the equator vicinity region 30 belongs to the equator vicinity region 30. The dimple 18 that intersects the second latitude line 24 and whose center is located in the adjustment region 32 belongs to the adjustment region 32. The center of the dimple 18 is a point where a straight line connecting the deepest part of the dimple 18 and the center of the golf ball 2 intersects the phantom sphere. The phantom sphere is the surface of the golf ball 2 when it is assumed that the dimple 18 does not exist.

  3, 4 and 5 are plan views showing the golf ball 2 of FIG. In FIG. 3, five first meridians 34 are shown together with the first latitude line 22 and the second latitude line 24. In FIG. 3, the pole vicinity region 28 is surrounded by the first latitude line 22. The pole vicinity region 28 can be partitioned into five units Up. The unit Up is a spherical triangle. The outline of the unit Up consists of a part of the first latitude line 22 and two first meridians 34. In FIG. 3, the type of the dimple 18 is indicated by reference signs A, B, E, and F with respect to one unit Up. The pole vicinity region 28 includes a dimple A having a diameter of 4.55 mm, a dimple B having a diameter of 4.45 mm, a dimple E having a diameter of 3.85 m, and a dimple F having a diameter of 3.00 mm. I have.

  The dimple pattern of the five units Up is 72 ° rotationally symmetric. In other words, when the dimple pattern of a certain unit Up rotates 72 degrees in the longitude direction around the pole P, it substantially overlaps with the dimple pattern of the adjacent unit Up. Here, the “substantially overlap” state includes not only a state where one dimple 18 completely coincides with the other dimple 18, but also a state where one dimple 18 slightly deviates from the other dimple 18. Here, the “slightly shifted state” includes a state in which the center of one dimple 18 is slightly separated from the center of the other dimple 18. The distance between the center of one dimple 18 and the center of the other dimple 18 is preferably 1.0 mm or less, and more preferably 0.5 mm or less. Here, the “slightly shifted state” includes a state in which the size of one dimple 18 is slightly different from the size of the other dimple 18. The dimensional difference is preferably 0.5 mm or less, and more preferably 0.3 mm or less. The dimension means the length of the longest line segment that can be drawn on the outline of the dimple 18. In the case of the circular dimple 18, the dimension thereof matches the diameter.

  In FIG. 4, six second meridians 36 are shown together with the first latitude line 22 and the second latitude line 24. In FIG. 4, the outside of the second latitude line 24 is the equator vicinity region 30. The equator vicinity region 30 can be partitioned into six units Ue. The unit Ue is a spherical trapezoid. The outline of the unit Ue includes a part of the second latitude line 24, two second meridians 36, and a part of the equator 26 (see FIG. 2). In FIG. 4, the type of the dimple 18 is indicated by reference signs A to F with respect to one unit Ue. The pole vicinity region 28 includes a dimple A having a diameter of 4.55 mm, a dimple B having a diameter of 4.45 mm, a dimple C having a diameter of 4.25 mm, a dimple D having a diameter of 4.10 mm, A dimple E having a diameter of 3.85 m and a dimple F having a diameter of 3.00 mm are provided.

  The dimple pattern of the six units Ue is 60 ° rotationally symmetric. In other words, when the dimple pattern of a certain unit Ue rotates 60 ° in the longitude direction around the pole P, it substantially overlaps with the dimple pattern of the adjacent unit Ue. The dimple pattern in the equator vicinity region 30 can be divided into three units. In this case, the dimple pattern of each unit is 120 ° rotationally symmetric. The dimple pattern in the equator vicinity region 30 can be divided into two units. In this case, the dimple pattern of each unit is 180 ° rotationally symmetric. The dimple pattern in the equator vicinity region 30 has three rotational symmetry angles (ie, 60 °, 120 °, and 180 °). In a region having a plurality of rotational symmetry angles, the unit Ue is partitioned based on the smallest rotational symmetry angle (60 ° in this example).

  FIG. 5 shows a first latitude line 22 and a second latitude line 24. In FIG. 5, the adjustment region 32 is surrounded by the first latitude line 22 and the second latitude line 24. In FIG. 5, the types of the dimples 18 included in the adjustment region 32 are indicated by reference signs A, D, and E. The adjustment region 32 includes a dimple A having a diameter of 4.55 mm, a dimple D having a diameter of 4.10 mm, and a dimple E having a diameter of 3.85 m.

  The dimple pattern in the adjustment region 32 is line symmetric with respect to the XX line in plan view. This dimple pattern has no symmetry line other than the XX line. When the rotation is more than 0 ° and less than 360 ° around the pole P, the dimple patterns do not overlap each other. In other words, the dimple pattern in the adjustment region 32 cannot be partitioned into a plurality of units that are rotationally symmetric with respect to each other.

  The dimple pattern in the adjustment region 32 may be divided into a plurality of units that are rotationally symmetric. In this case, the number of units in the adjustment region 32 needs to be different from the number of units Up in the pole vicinity region 28, and further needs to be different from the number of units Ue in the equator vicinity region 30.

  In this golf ball 2, the number Np of units Up in the pole vicinity region 28 is 5, and the number Ne of units Ue in the equator vicinity region 30 is 6. They are different. The dimple pattern in which the number Np and the number Ne are different is rich in change. In the golf ball 2, the air flow during flight is well disturbed. This golf ball 2 is excellent in flight performance. The combination (Np, Ne) of the number Np and the number Ne is not limited to (5, 6). Other combinations include (2,3), (2,4), (2,5), (2,6), (3,2), (3,4), (3,5), (3 , 6), (4,2), (4,3), (4,5), (4,6), (5,2), (5,3), (5,4), (6,2) ), (6, 3), (6, 4) and (6, 5).

  Although the details of the reason are unknown, according to the knowledge obtained by the present inventor, when one of the number Np and the number Ne is an odd number and the other is an even number, a large dimple effect is obtained. Furthermore, when the difference between the number Np and the number Ne is 1, a particularly large dimple effect is obtained. Combinations with this difference of 1 include (2,3), (3,2), (3,4), (4,3), (4,5), (5,4), (5,6 ) And (6, 5). The reason why the combination having a difference of 1 is preferable is not clear in detail, but due to the small difference between the phase of the pole vicinity region 28 and the phase of the equator vicinity region 30, the dimple effect in the pole vicinity region 28. And the dimple effect in the equator vicinity region 30 is assumed to be synchronized and synthesized.

  From the viewpoint of the dimple effect, it is preferable that the pole vicinity region 28 has a sufficient area and the equator vicinity region 30 has a sufficient area. From the viewpoint of the area of the equator vicinity region 30, the latitude of the first latitude line 22 and the second latitude line 24 is preferably 20 ° or more, and more preferably 25 ° or more. From the viewpoint of the area of the pole vicinity region 28, the latitudes of the first latitude line 22 and the second latitude line 24 are preferably 40 ° or less, and more preferably 35 ° or less. The first latitude line 22 can be arbitrarily selected from an infinite number of latitude lines. The second latitude line 24 can also be arbitrarily selected from an infinite number of latitude lines.

  From the viewpoint of contribution of the pole vicinity region 28 to the dimple effect, the ratio of the number of the dimples 18 existing in the pole vicinity region 28 to the total number of the dimples 18 is preferably 20% or more, and more preferably 25% or more. This ratio is preferably 40% or less.

  From the viewpoint of contribution of the equator vicinity region 30 to the dimple effect, the ratio of the number of the dimples 18 existing in the equator vicinity region 30 to the total number of the dimples 18 is preferably 40% or more, and more preferably 45% or more. This ratio is preferably 65% or less.

  If the pole vicinity region 28 is adjacent to the equator vicinity region 30 across the boundary line, the dimples 18 cannot be densely arranged near the boundary line due to the difference in the number of units. In this case, there is a wide land in the vicinity of the boundary line. Wide lands inhibit the dimple effect. In the golf ball 2 according to the present invention, the adjustment region 32 exists between the pole vicinity region 28 and the equator vicinity region 30. In the adjustment region 32, since the dimples 18 can be arranged without being restricted by the number of units, the land area can be suppressed. By this adjustment area 32, a high occupation rate (detailed later) is achieved.

  From the viewpoint of the occupation ratio, it is preferable that the adjustment region 32 has a sufficient area. From this point of view, the difference between the latitude of the first latitude line 22 and the latitude of the second latitude line 24 is preferably 5 ° or more. If the adjustment region 32 is too wide, the dimple effect due to the difference between the number Np and the number Ne is impaired. From the viewpoint of the dimple effect, the difference between the latitude of the first latitude line 22 and the latitude of the second latitude line 24 is preferably 15 ° or less, and more preferably 10 ° or less.

  From the viewpoint of the occupation ratio, the ratio of the number of the dimples 18 existing in the adjustment region 32 to the total number of the dimples 18 is preferably 5% or more, and more preferably 8% or more. From the viewpoint of the dimple effect due to the difference between the number Np and the number Ne, this ratio is preferably 20% or less, more preferably 18% or less, and particularly preferably 16% or less.

  In the golf ball 2 in which the pole vicinity region 28 is partitioned into units Up and the equator vicinity region 30 is partitioned into units Ue, a cycle of the pattern is generated by rotation. The greater the number Np of units Up and the number Ne of units Ue, the shorter the period. The smaller the number Np and the number Ne, the longer the period. An appropriate period enhances the dimple effect. From the viewpoint of an appropriate period, the number Np and the number Ne are preferably 4 or more and 6 or less, and particularly preferably 5 or more and 6 or less. The most preferable combinations (NP, Ne) of the number Np and the number Ne are (5, 6) and (6, 5). In the golf ball 2 shown in FIGS. 2 to 5, (Np, Ne) is (5, 6).

  From the viewpoint of aerodynamic symmetry, it is preferable that the dimple pattern of the northern hemisphere N and the dimple pattern of the southern hemisphere S are equivalent. When the dimple pattern of the northern hemisphere N and the pattern that is mirror-symmetrical with respect to the plane including the equator 26 substantially overlaps the dimple pattern of the southern hemisphere S, the two patterns are equivalent. When a dimple pattern in the northern hemisphere N and a pattern that is mirror-symmetrical with respect to the plane including the equator 26 substantially overlaps with the dimple pattern in the southern hemisphere S when rotated about the pole P, the two patterns are equivalent. is there.

  In view of obtaining a sufficient dimple effect, the total number of the dimples 18 is preferably 200 or more, and particularly preferably 260 or more. From the viewpoint that each dimple 18 can have a sufficient diameter, the total number is preferably 500 or less, more preferably 360 or less, and particularly preferably 350 or less.

  FIG. 6 is an enlarged cross-sectional view showing a part of the golf ball 2 of FIG. FIG. 6 shows a cross section along a plane passing through the deepest part of the dimple 18 and the center of the golf ball 2. The vertical direction in FIG. 6 is the depth direction of the dimple 18. In FIG. 4, what is indicated by a two-dot chain line 38 is a virtual sphere. The dimple 18 is recessed from the phantom sphere 38. The land 20 coincides with the phantom sphere 38.

  In FIG. 6, what is indicated by a double arrow di is the diameter of the dimple 18. The diameter di is a distance between one contact point Ed and the other contact point Ed when a common tangent line T is drawn on both sides of the dimple 18. The contact point Ed is also the edge of the dimple 18. The edge Ed defines the outline of the dimple 18. The diameter di is preferably 2.00 mm or greater and 6.00 mm or less. A large dimple effect can be obtained by setting the diameter di to 2.00 mm or more. In this respect, the diameter di is more preferably equal to or greater than 2.20 mm, and particularly preferably equal to or greater than 2.40 mm. By setting the diameter di to 6.00 mm or less, the essential feature of the golf ball 2 that is substantially a sphere is maintained. In this respect, the diameter di is more preferably equal to or less than 5.80 mm, and particularly preferably equal to or less than 5.60 mm.

The area s of the dimple 18 is an area of a region surrounded by a contour line when the center of the golf ball 2 is viewed from infinity. In the case of the circular dimple 18, the area s is calculated by the following mathematical formula.
s = (di / 2) ²・ π
In the golf ball 2 shown in FIGS. 1 to 6, the area of the dimple A is 16.26 mm ² , the area of the dimple B is 15.55 mm ² , and the area of the dimple C is 14.19 mm ² , The area of the dimple D is 13.20 mm ² , the area of the dimple E is 11.64 mm ² , and the area of the dimple F is 7.07 mm ² .

In the present invention, the ratio of the total area s of all the dimples 18 to the surface area of the phantom sphere 38 is referred to as an occupation ratio. From the viewpoint of obtaining a sufficient dimple effect, the occupation ratio is preferably 75% or more, more preferably 78% or more, and particularly preferably 81% or more. The occupation ratio is preferably 90% or less. In the golf ball 2 shown in FIGS. 2 to 6, the total area of the dimples 18 is 4675.2 mm ² . Since the surface area of the phantom sphere 38 of the golf ball 2 is 5754.9 mm ² , the occupation ratio is 81.2%.

In the present invention, “dimple volume” means the volume of a portion surrounded by a plane including the outline of the dimple 18 and the surface of the dimple 18. From the viewpoint of rising of the golf ball 2 is suppressed, the total volume of the dimples 18 is preferably 250 mm ³ or more, more preferably 260 mm ³ or more, 270 mm ³ or more is particularly preferable. In view of dropping of the golf ball 2 is suppressed, the total volume is preferably 400 mm ³ or less, more preferably 390 mm ³ or less, 380 mm ³ or less is particularly preferred.

  In light of suppression of hops in the golf ball 2, the depth of the dimple 18 is preferably 0.05 mm or greater, more preferably 0.08 mm or greater, and particularly preferably 0.10 mm or greater. In light of suppression of dropping of the golf ball 2, the depth is preferably equal to or less than 0.60 mm, more preferably equal to or less than 0.45 mm, and particularly preferably equal to or less than 0.40 mm. The depth is a distance between the tangent line T and the deepest part of the dimple 18.

  In the present invention, the size of each part of the dimple 18 is measured in the golf ball 2 to which no paint is applied. The size may be measured in the golf ball 2 after the paint layer is removed.

  Hereinafter, the effects of the present invention will be clarified by examples. However, the present invention should not be construed in a limited manner based on the description of the examples.

[Example 1]
100 parts by weight of polybutadiene (trade name “BR-730” from JSR), 26 parts by weight of zinc acrylate (trade name “ZN-DA90S” from Nippon Shokubai Co., Ltd.), 5.0 parts by weight of zinc oxide (Mitsui Metals) Company name "Zinc oxide 2 types"), an appropriate amount of barium sulfate, 0.5 parts by weight of diphenyl disulfide (Sumitomo Seika) and 0.9 parts by weight of dicumyl peroxide (Nippon Yushi Co., Ltd.) A rubber composition was obtained. This rubber composition was put into a mold composed of an upper mold and a lower mold each having a hemispherical cavity and heated at a temperature of 170 ° C. for 15 minutes to obtain an inner sphere having a diameter of 32.4 mm.

  100 parts by mass of polybutadiene (trade name “BR-11” by JSR), 40 parts by mass of zinc acrylate (previously “ZN-DA90S”), 5.0 parts by mass of zinc oxide (previously described “zinc oxide 2”) Seeds)) 10 parts by weight of barium sulfate, 0.5 parts by weight of diphenyl disulfide (Sumitomo Seika Co., Ltd.) and 0.9 parts by weight of dicumyl peroxide (Nippon Yushi Co., Ltd.) were kneaded to obtain a rubber composition. It was. A half shell was produced from this rubber composition. The inner sphere was covered with two half shells. Both the inner sphere and the half shell were put into a mold composed of an upper mold and a lower mold having a hemispherical cavity, and heated at a temperature of 170 ° C. for 15 minutes to obtain a center. The diameter of this center was 39.0 mm. This center consists of an inner sphere and an outer layer. The thickness To of the outer layer was 3.3 mm.

  50 parts by mass of ionomer resin (previously referred to as “Himiran 1605”), 50 parts by mass of other ionomer resin (previously described “Surlin 9945”), 4 parts by mass of titanium dioxide and 0.1 part by mass of ultramarine blue. The resin composition was obtained by kneading with a shaft extruder. This resin composition was coated around the center by an injection molding method to obtain a core. The core diameter was 42.2 mm. This core consists of a center and an intermediate layer. The intermediate layer had a thickness Tm of 1.6 mm.

  A coating composition (trade name “Porin 750LE”, manufactured by Shinto Paint Co., Ltd.) using a two-component curable epoxy resin as a base polymer was prepared. The main component liquid of this coating composition was 30 parts by mass of a bisphenol A type solid epoxy resin. The curing agent liquid of this coating composition is composed of 40 parts by mass of modified polyamidoamine, 55 parts by mass of solvent, and 5 parts by mass of titanium oxide. The mass ratio with respect to the curing agent liquid is 1/1 This coating composition was applied to the surface of the intermediate layer with a spray gun and kept in a 40 ° C. atmosphere for 24 hours to obtain a reinforcing layer. The layer thickness Tr was 10 μm.

  100 parts by mass of a thermoplastic polyurethane elastomer (Elastolan XNY80A described above), 4 parts by mass of titanium dioxide and 0.1 parts by mass of ultramarine blue were kneaded with a twin screw extruder to obtain a resin composition. A half shell was obtained from this resin composition by compression molding. The core was covered with two half shells. The half shell and the core were both put into a final mold including an upper mold and a lower mold having a hemispherical cavity and a large number of pimples on the cavity surface, and a cover was obtained by a compression molding method. The cover thickness Tc was 0.3 mm. A large number of dimples having a reversed pimple shape were formed on the cover. A paint layer was formed around the cover to obtain a golf ball of Example 1. This golf ball had a diameter of 42.8 mm and a mass of 45.5 g. This golf ball has a dimple pattern (type I) shown in FIGS. Details of the dimple specifications are shown in Tables 1 and 2 below.

[Examples 2 to 11 and Comparative Examples 1 to 5]
Golf balls of Examples 2 to 11 and Comparative Examples 1 to 5 are obtained in the same manner as in Example 1 except that the material, the diameter of the inner sphere, and the cover thickness Tc are as shown in Tables 3 to 8 below. It was.

[Comparative Example 6]
A golf ball of Comparative Example 6 was obtained in the same manner as in Example 2 except that the final mold was changed and the dimple pattern (type II) whose specifications were shown in Tables 1 and 2 below was formed. FIG. 7 is a front view showing the golf ball, and FIG. 8 is a plan view thereof. The golf ball's northern and southern hemispheres have a unit U that is 120 ° rotationally symmetric. In each of the northern and southern hemispheres, the number of units U is three. In FIG. 8, the types of dimples are indicated by reference signs A to H for one unit.

[Comparative Example 7]
A golf ball of Comparative Example 7 was obtained in the same manner as in Example 2 except that the final mold was changed and the dimple pattern (type III) whose specifications were shown in Tables 1 and 2 below was formed. FIG. 9 is a front view showing the golf ball, and FIG. 10 is a plan view thereof. The northern hemisphere and the southern hemisphere of this golf ball have units U that are rotationally symmetrical by 72 °. In each of the northern and southern hemispheres, the number of units U is five. In FIG. 10, the types of dimples are indicated by reference signs A to G for one unit.

[Shot with driver]
A driver with a metal head was attached to a golf laboratory swing machine. A golf ball was hit under the condition that the head speed was 50 m / sec, and the ball speed and spin speed immediately after hitting and the flight distance (distance from the launching point to the resting point) were measured. Average values of 10 measurements are shown in Tables 6 to 8 below.

[Short iron shot]
An approach wedge was attached to the swing machine. Machine conditions were set so that the head speed was 21 m / sec, a golf ball was hit, and the spin speed immediately after hit was measured. The average value of 10 measurements was calculated. Furthermore, the range between the maximum value and the minimum value of 10 measurements was calculated, and rating was performed based on the following criteria.
A: The width is less than 100 rpm. B: The width is 100 rpm or more and less than 200 rpm. C: The results where the width is 200 rpm or more are shown in Tables 6 to 8 below.

[Evaluation of feel at impact]
A senior golfer hit a golf ball with a driver. This golfer was given a hit feeling based on the following criteria.
A: Good with small impact B: Normal C: Defect with large impact This result is shown in Tables 6 to 8 below.

[Evaluation of scratch resistance]
A pitching wedge was attached to the swing machine. The machine conditions were set so that the head speed was 36 m / sec, and a golf ball was hit. The surface of this golf ball was visually observed and rated based on the following criteria.
A: There is almost no scratch B: There is a scratch and there is fluff C: There is a large scratch and the result where the fluff is conspicuous is shown in Tables 6 to 8 below.

[Evaluation of aerodynamic symmetry]
A driver with a titanium head (trade name “XXIO”, Sumitomo Rubber Industries, Ltd., shaft hardness: X, loft angle: 9 °) equipped with a titanium head was attached to a swing machine manufactured by Tsurutemper. Machine conditions were set so that the head speed was 49 m / sec, and a golf ball was hit. The distance from the launch point to the fall point was measured. During the test, there was almost no wind. The average value of 20 measurements for each of the pole hitting and the seam hitting was calculated. In the pole hit, a golf ball is hit so that a straight line on a plane including the equator becomes a rotation axis of backspin. In seam hitting, a golf ball is hit such that a straight line connecting both poles becomes the rotation axis of backspin. The aerodynamic symmetry was rated based on the following criteria.
A: The difference between the flying distance of the pole hit and the flying distance of the seam hit is less than 2 m. B: The difference between the flying distance of the pole hit and the distance hit by the seam hit is not less than 2 m and less than 5 m. The results are shown in Tables 6 and 8 below when the difference in distance is 5 m or more.

  As is clear from Tables 6 to 8, the golf balls of the examples are excellent in all of flight performance, spin performance, spin stability, feel at impact, scratch resistance, and aerodynamic symmetry. From this evaluation result, the superiority of the present invention is clear.

  The golf ball according to the present invention is particularly suitable for use in golf competitions.

FIG. 1 is a partially cutaway sectional view showing a golf ball according to an embodiment of the present invention. FIG. 2 is an enlarged front view showing the golf ball of FIG. FIG. 3 is a plan view showing the golf ball of FIG. 4 is a plan view showing the golf ball of FIG. FIG. 5 is a plan view showing the golf ball of FIG. 6 is an enlarged cross-sectional view showing a part of the golf ball in FIG. FIG. 7 is a front view showing the golf ball of Comparative Example 6. FIG. 8 is a plan view showing the golf ball of FIG. FIG. 9 is a front view showing the golf ball of Comparative Example 7. FIG. 10 is a plan view showing the golf ball of FIG.

Explanation of symbols

2 ... Golf ball 4 ... Core 6 ... Reinforcement layer 8 ... Cover 10 ... Center 12 ... Intermediate layer 14 ... Inner sphere 16 ... Outer layer 18 ... Dimple 20 ... Land 22 ... First latitude line 24 ... Second latitude line 26 ... Equator 28 ... Pole vicinity area 30 ... Equatorial vicinity area 32 ... Adjustment area 34 ... First meridian 36 ... Second meridian 38 ... Virtual sphere A-F ... Dimple N ... Northern hemisphere P ... Pole S ... Southern hemisphere U, Up, Ue ... Unit

Claims (9)

It has a spherical core and a cover located outside this core,
The core includes a spherical center and an intermediate layer located outside the center,
The center includes an inner sphere and an outer layer located outside the inner sphere.
The thickness Tc of this cover is 1.0 mm or less,
The cover has a hardness Hc of 20 to 50,
Each of the northern hemisphere and the southern hemisphere on the surface includes a pole vicinity region, an equator vicinity region, and an adjustment region located between the pole vicinity region and the equator vicinity region,
Each of the pole vicinity area, the equator vicinity area, and the adjustment area includes a large number of dimples,
The dimple pattern in the pole vicinity region consists of a plurality of units that are rotationally symmetric with respect to the pole point,
The dimple pattern in the region near the equator consists of a plurality of units that are rotationally symmetric with respect to each other around the pole,
The number of units in the pole vicinity region is different from the number of units in the equator vicinity region,
The dimple pattern in the adjustment area cannot be partitioned into a plurality of units that are rotationally symmetric with respect to each other, or the number of units is the number of units that are rotationally symmetric with respect to each other. A golf ball that is different from the number of units in the pole vicinity region and the equator vicinity region.   The golf ball according to claim 1, wherein a peak in a hardness curve from the center point of the inner sphere to the surface of the cover is achieved in the intermediate layer.   3. The golf ball according to claim 1, wherein the inner sphere and the outer layer are made of a composition based on a thermosetting polymer, and the intermediate layer and the cover are made of a composition based on a thermoplastic polymer. The main component of the base polymer of the intermediate layer is an ionomer resin,
The golf ball according to claim 3, wherein a main component of the base polymer of the cover is a thermoplastic polyurethane elastomer.   The golf ball according to claim 1, further comprising a reinforcing layer having a thickness of 3 μm or more and 50 μm or less between the intermediate layer and the cover.   6. The golf ball according to claim 1, wherein a ratio (D2 / D3) of the core compressive deformation amount D2 to the compressive deformation amount D3 is 0.98 or more and 1.10 or less.   The boundary line between the pole vicinity region and the adjustment region is a latitude line whose latitude is 20 ° to 40 °, and the boundary line between the adjustment region and the equator vicinity region is a latitude line whose latitude is 20 ° to 40 °. The golf ball according to claim 1, wherein:   The golf ball according to claim 1, wherein the total number of the dimples is 360 or less, and the ratio of the total area of all the dimples to the surface area of the phantom sphere is 75% or more.   The golf ball according to claim 1, wherein the number of units in the pole vicinity region is an odd number, and the number of units in the equator vicinity region is an even number.

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