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JP2007147085A - Rolling bearing - Google Patents

Rolling bearing Download PDF

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Publication number
JP2007147085A
JP2007147085A JP2007037530A JP2007037530A JP2007147085A JP 2007147085 A JP2007147085 A JP 2007147085A JP 2007037530 A JP2007037530 A JP 2007037530A JP 2007037530 A JP2007037530 A JP 2007037530A JP 2007147085 A JP2007147085 A JP 2007147085A
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Japan
Prior art keywords
rolling
wheel
rolling bearing
electrolytic corrosion
hexavalent chromium
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Granted
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JP2007037530A
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Japanese (ja)
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JP4606427B2 (en
Inventor
Kazuo Komori
和雄 小森
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NTN Corp
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NTN Corp
NTN Toyo Bearing Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C35/00Rigid support of bearing units; Housings, e.g. caps, covers
    • F16C35/04Rigid support of bearing units; Housings, e.g. caps, covers in the case of ball or roller bearings
    • F16C35/06Mounting or dismounting of ball or roller bearings; Fixing them onto shaft or in housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/58Raceways; Race rings
    • F16C33/583Details of specific parts of races
    • F16C33/586Details of specific parts of races outside the space between the races, e.g. end faces or bore of inner ring
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C19/00Bearings with rolling contact, for exclusively rotary movement
    • F16C19/02Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows
    • F16C19/04Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for radial load mainly
    • F16C19/06Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for radial load mainly with a single row or balls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C19/00Bearings with rolling contact, for exclusively rotary movement
    • F16C19/02Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows
    • F16C19/14Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load
    • F16C19/18Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load with two or more rows of balls
    • F16C19/181Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load with two or more rows of balls with angular contact
    • F16C19/183Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load with two or more rows of balls with angular contact with two rows at opposite angles
    • F16C19/184Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load with two or more rows of balls with angular contact with two rows at opposite angles in O-arrangement
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C19/00Bearings with rolling contact, for exclusively rotary movement
    • F16C19/52Bearings with rolling contact, for exclusively rotary movement with devices affected by abnormal or undesired conditions
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2300/00Application independent of particular apparatuses
    • F16C2300/02General use or purpose, i.e. no use, purpose, special adaptation or modification indicated or a wide variety of uses mentioned
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2326/00Articles relating to transporting
    • F16C2326/01Parts of vehicles in general
    • F16C2326/02Wheel hubs or castors

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Rolling Contact Bearings (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a rolling bearing capable of preventing occurrence of electrolytic corrosion when using this rolling bearing in a housing made of aluminum alloy and containing no toxic substance being harmful to the environment in surface treatment, in particular, a rolling bearing for a wheel. <P>SOLUTION: This rolling bearing for the wheel is provided with an outer member 1 having double rows of rolling faces 4, 4 at the inner periphery, an inner member 2 forming rolling faces 5, 5 opposing to respective rolling faces 4, 4, and double rows of rolling bodies 3, 3 provided among these opposing rolling faces 4, 5. The outer member 1 has a vehicle body mounting flange 1a at the outer periphery and is fixed to a knuckle 14 made of aluminum alloy. The inner member 2 has a ring mounting flange 2a. An electrolytic corrosion prevention membrane 17 is provided in an outside diameter face part which becomes a contact face of the outer member 1 with the knuckle 14 and on a side face of the vehicle body mounting flange 1a. This electrolytic corrosion prevention membrane 17 is formed by using hexavalent chromium-free chromate. In general, this electrolytic corrosion prevention membrane 17 using hexavalent chromium-free chromate can be applied to not only the rolling bearing for the wheel but also the rolling bearing attached to the housing made of aluminum alloy, generally. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

この発明は、アルミ合金製のハウジングに設置される転がり軸受に関し、特に、自動車等の車輪を支持する車輪用転がり軸受に関する。   The present invention relates to a rolling bearing installed in an aluminum alloy housing, and more particularly to a wheel rolling bearing that supports a wheel of an automobile or the like.

自動車の懸架装置に対して車輪を回転自在に支持する車輪用転がり軸受は、燃費向上のための軽量化が進んでいる。近年、車輪用転がり軸受では、さらなる軽量化の追求により、可及的に余肉を排除しスリム化すること、および可鍛鋳鉄等からなるナックルに代え、アルミ合金製ナックルを採用することが普及している。
アルミ合金は比重が鋼の略1/3であるから、鋼に比べて不足する剛性を補うために厚肉構造に形成したとしても、少なくとも従来の鋼製ナックルの重量を半減できる。また、アルミ合金特有の課題とされていた肉厚差から生じる巣の発生も、近年の鋳造技術の進歩によって強度に支障のない程度に抑制することが可能となり、将来、アルミ合金製ナックルの普及が拡大すると期待されている。なお、上記ナックルは、車輪用転がり軸受に対する軸受ハウジングとなる。
2. Description of the Related Art Rolling bearings for wheels that rotatably support a wheel with respect to a vehicle suspension system have been reduced in weight for improving fuel efficiency. In recent years, in rolling bearings for wheels, by pursuing further weight reduction, it has become common to eliminate surplus as much as possible, and to adopt aluminum alloy knuckles instead of knuckles made of malleable cast iron, etc. is doing.
Since the specific gravity of aluminum alloy is approximately 1/3 that of steel, even if it is formed in a thick-walled structure in order to compensate for insufficient rigidity compared to steel, at least the weight of a conventional steel knuckle can be halved. In addition, the occurrence of nests caused by the difference in wall thickness, which was regarded as a unique issue for aluminum alloys, can be suppressed to the extent that there is no problem in strength due to recent advances in casting technology. Is expected to expand. The knuckle serves as a bearing housing for the wheel rolling bearing.

アルミ合金製ナックルは軽量化に寄与する反面、車輪用転がり軸受における外方部材と金属同士の電位差を生じる材質の関係となる。そのため、外方部材におけるナックルとの接触面に泥塩水等がかかると、電池が形成され、電極腐食が発生する。電極腐食が発生すると、その接触面で固着することがあり、補修点検時の作業性が阻害される。この電極腐食は、絶縁材を介在させると防止することができるが、部品点数が増加し、そのため部品管理が煩雑となるうえ、車輪用転がり軸受のナックルへの組付けに手間がかかる。
また、車輪のタイヤに蓄積された静電気は、内方部材から、転動体、外方部材およびナックルを介して車体に流れるが、内方部材および外方部材の転走面と転動体との間で潤滑油膜が不十分なときに、この部分でスパークが発生し、車両に搭載されたラジオにノイズが発生するという問題点が有る。
The aluminum alloy knuckle contributes to weight reduction, but has a material relationship that causes a potential difference between the outer member and the metal in the wheel rolling bearing. Therefore, when muddy salt water or the like is applied to the contact surface of the outer member with the knuckle, a battery is formed and electrode corrosion occurs. When electrode corrosion occurs, it may stick to the contact surface, impeding workability during repair and inspection. This electrode corrosion can be prevented by interposing an insulating material, but the number of parts increases, so that parts management becomes complicated, and it takes time to assemble the wheel rolling bearing to the knuckle.
In addition, the static electricity accumulated in the tires of the wheels flows from the inner member to the vehicle body via the rolling elements, outer members, and knuckles, but between the rolling surfaces of the inner members and outer members and the rolling elements. However, when the lubricating oil film is insufficient, there is a problem that a spark occurs in this portion and noise is generated in the radio mounted on the vehicle.

上記の電極腐食発生の課題は、車輪用転がり軸受に限らず、アルミ合金製ハウジングに設置されて軌道輪とハウジングとの接触面に泥塩水等がかかる条件下で使用される転がり軸受に共通の課題となる。   The problem of electrode corrosion occurrence is not limited to rolling bearings for wheels, but is common to rolling bearings installed in aluminum alloy housings and used under conditions where the contact surface between the bearing ring and the housing is subject to muddy water. It becomes a challenge.

このような課題に対して、車輪用転がり軸受におけるアルミ合金製のナックルとの接触面、例えば外方部材のフランジ部分に、Zn−Niめっきと、6価クロム含有のクロメート処理とを施し、電食防止の対策とされている(例えば、特願2002−266051号)。   For such a problem, the contact surface of the wheel rolling bearing with the aluminum alloy knuckle, for example, the flange portion of the outer member, is subjected to Zn-Ni plating and chromate treatment containing hexavalent chromium, It is considered as a measure for preventing food (for example, Japanese Patent Application No. 2002-266051).

従来の電食防止用のクロメート処理におけるクロメートには、環境に有害な6価クロムが含まれている。近年、環境問題の高揚に伴って、6価クロムの使用を規制しようとする傾向にある。例えば、欧州環境規制により、6価クロムは使用できなくなる。このため、現状のZn−Niめっき,クロメート処理併用のものと同等以上の耐食性能を有し、かつ6価クロムを含まない表面処理の適用が望まれる。   The chromate in the conventional chromate treatment for preventing electrolytic corrosion contains hexavalent chromium which is harmful to the environment. In recent years, there has been a tendency to regulate the use of hexavalent chromium as environmental problems have been heightened. For example, hexavalent chromium cannot be used due to European environmental regulations. For this reason, application of a surface treatment that has a corrosion resistance equal to or better than that of the current combination of Zn—Ni plating and chromate treatment and does not contain hexavalent chromium is desired.

この発明の目的は、アルミ合金製ハウジングに用いた場合の電食の発生が抑制され、かつ表面処理に環境に対する有害物質を含まない転がり軸受を提供することである。
この発明の他の目的は、車輪用転がり軸受において、そのアルミ合金製ナックルとの接
触面での電食の発生が抑制され、かつ表面処理に環境に対する有害物質を含まないものを提供することである。
An object of the present invention is to provide a rolling bearing in which the occurrence of electrolytic corrosion when used in an aluminum alloy housing is suppressed and the surface treatment does not contain environmentally harmful substances.
Another object of the present invention is to provide a rolling bearing for a wheel in which the occurrence of electrolytic corrosion at the contact surface with the aluminum alloy knuckle is suppressed and the surface treatment does not contain any harmful substances for the environment. is there.

この発明の転がり軸受は、対向する軌道輪間に転動体を介在させてなり、アルミ合金製のハウジングにいずれかの軌道輪が接して取付けられる転がり軸受において、前記ハウジングに取付けられる軌道輪におけるハウジングとの接触面に、6価クロムフリークロメイトを使用した電食防止皮膜を設けたことを特徴とする。上記6価クロムフリークロメイトは、硝酸クロムまたは硫酸クロム等を主成分とする、6価クロムを含まないクロメートのことである。この発明の転がり軸受は、転がり形式の軸受であれば良く、ラジアル型の軸受であっても、またスラスト型の軸受であっても良い。   The rolling bearing according to the present invention is a rolling bearing in which a rolling element is interposed between opposed bearing rings, and one of the bearing rings is attached to an aluminum alloy housing, and the housing in the bearing ring attached to the housing An electrical corrosion prevention film using hexavalent chromium-free chromate is provided on the contact surface. The hexavalent chromium-free chromate is a chromate that contains chromium nitrate or chromium sulfate as a main component and does not contain hexavalent chromium. The rolling bearing of the present invention may be a rolling type bearing, and may be a radial type bearing or a thrust type bearing.

軸受の軌道輪は一般に鋼材であるため、ハウジングがアルミ合金製であると、互いに電位差を生じる金属材同士の関係となる。しかし、軌道輪のハウジングとの接触面に電食防止皮膜が設けられていると、アルミ合金製のナックルと鋼製の外方部材との当接面に泥塩水等がかかっても、電池が形成されることがなく、電極腐食が防止される。また電食防止皮膜を設けるため、別部材の絶縁材を介在させる場合と異なり、部品点数の増加がなく、部品管理の煩雑化や組付け性の低下が回避される。
電食防止皮膜には、6価クロムフリークロメイトを使用したため、6価クロムによる有害性のないものにできる。試験によると、6価クロムフリークロメイトを使用しても、下地処理のめっき層等を適宜選定することで、6価クロム含有クロメート使用の電食防止皮膜よりも、電食防止性に優れたものとできることが確認された。
Since the bearing ring of the bearing is generally made of a steel material, when the housing is made of an aluminum alloy, the metal materials that cause a potential difference are formed. However, if an electrolytic corrosion prevention film is provided on the contact surface of the bearing ring with the housing, the battery will not be damaged even if the contact surface between the aluminum alloy knuckle and the steel outer member is covered with muddy salt. It is not formed and electrode corrosion is prevented. In addition, since the electrolytic corrosion prevention film is provided, the number of parts is not increased, unlike the case where an insulating material as a separate member is interposed, and the complication of parts management and the deterioration of assemblability are avoided.
Since the electrolytic corrosion prevention film uses hexavalent chromium-free chromate, it can be made harmless by hexavalent chromium. According to the test, even if hexavalent chromium-free chromate is used, it is better than the electrolytic corrosion prevention film using hexavalent chromium-containing chromate by appropriately selecting the plating layer for the base treatment. It was confirmed that it was possible.

この発明の転がり軸受は、車輪用の転がり軸受に適用できる。この発明の車輪用転がり軸受は、アルミ合金製のナックルに固定するための車体取付フランジを外周に有し、内周に複列の転走面を有する外方部材と、一端に車輪取付フランジを有し、上記転走面のそれぞれに対向する転走面を形成した内方部材と、これら対向する転走面間に介在させた複列の転動体とを備え、車体に対して車輪を回転自在に支持する車輪用転がり軸受において、上記外方部材の上記ナックルとの接触面に、6価クロムフリークロメイトを使用した電食防止皮膜を設けたことを特徴とする。この場合、上記外方部材および内方部材が請求項1の発明の転がり軸受における各軌道輪となる。前記ナックルは、ハウジングに該当する。なお、電食防止皮膜は、外方部材のナックルとの接触面における全体に設けても良く、また一部だけに設けても良い。   The rolling bearing of this invention can be applied to a rolling bearing for wheels. The wheel rolling bearing according to the present invention has a vehicle body mounting flange on the outer periphery for fixing to an aluminum alloy knuckle, an outer member having a double row rolling surface on the inner periphery, and a wheel mounting flange on one end. And an inner member that forms a rolling surface facing each of the rolling surfaces, and a double-row rolling element interposed between the facing rolling surfaces, and rotates a wheel with respect to the vehicle body. A wheel rolling bearing that is freely supported is characterized in that an electrolytic corrosion prevention film using hexavalent chromium-free chromate is provided on a contact surface of the outer member with the knuckle. In this case, the outer member and the inner member are the bearing rings in the rolling bearing according to the first aspect of the present invention. The knuckle corresponds to a housing. The electrolytic corrosion prevention film may be provided on the entire contact surface of the outer member with the knuckle, or may be provided on only a part thereof.

自動車では軽量化が望まれ、その車輪用転がり軸受を取付けるナックルは、アルミ合金製のものが増えてきている。また、車輪用転がり軸受は、塩泥水がかかる厳しい条件下で使用されるため、アルミ合金製のナックルを使用すると、電池成形による電極腐食の問題が生じ易い。そのため、電食防止処理の要望が強い。生産性向上のために、別部材となる電気絶縁材を介在させることが難しく、また環境面への配慮も厳しく要求される。これらのため、この発明における6価クロムフリークロメイト使用の電食防止皮膜を設けたことによる電食発生の抑制、有害物質排除等の効果が、より効果的に発揮される。   In automobiles, weight reduction is desired, and the number of knuckles for mounting the rolling bearings for wheels has been increasing. In addition, since the rolling bearing for a wheel is used under severe conditions where salty mud water is applied, the use of an aluminum alloy knuckle tends to cause a problem of electrode corrosion due to battery molding. Therefore, there is a strong demand for electrolytic corrosion prevention treatment. In order to improve productivity, it is difficult to interpose an electrical insulating material as a separate member, and environmental considerations are also strictly required. For these reasons, the effects of suppressing the occurrence of electrolytic corrosion and eliminating harmful substances due to the provision of the electrolytic corrosion prevention film using hexavalent chromium-free chromate in the present invention are more effectively exhibited.

この発明において、前記電食防止皮膜は、例えば、母材表面に設けられた第1のめっき層と、この第1のめっき層の外面に重ねて設けられた6価クロムフリークロメイトの皮膜層とを含むものとされる。
6価クロムフリークロメイトの皮膜層は、母材表面のめっき層に重ねて施されることにより、その電食発生の抑制効果が優れたものとなる。
In the present invention, the electrolytic corrosion prevention film includes, for example, a first plating layer provided on the surface of the base material and a film layer of hexavalent chromium-free chromate provided on the outer surface of the first plating layer. Is included.
The film layer of hexavalent chromium-free chromate is excellent in the effect of suppressing the occurrence of electrolytic corrosion by being applied over the plating layer on the surface of the base material.

前記電食防止皮膜は、母材表面に設けられた第1のめっき層と、この第1のめっき層の外面に重ねて設けられた6価クロムフリークロメイトの皮膜層と、この皮膜層の外面に重
ねて設けられた熱硬化型コーティング材のコーティング層との3層構造を有するものであることがより好ましい。前記第1のめっき層は、例えば亜鉛ニッケルめっきの層とする。
このようなトップコーティングとなるコーティング層を設けて3層構造とすることで、6価クロムフリークロメイトの皮膜層による電食発生の抑制効果がより一層優れたものとなる。
試験の結果、第1のめっき層を亜鉛ニッケルめっきとし、上記3層構造とした場合、同じく3層構造で6価クロム含有クロメート使用した食防止皮膜よりも、電食防止性に優れたものとできることが確認された。
The electrolytic corrosion prevention film includes a first plating layer provided on the surface of the base material, a hexavalent chromium-free chromate film layer provided on the outer surface of the first plating layer, It is more preferable to have a three-layer structure with a coating layer of a thermosetting coating material provided on the outer surface. The first plating layer is, for example, a zinc nickel plating layer.
By providing such a coating layer as a top coating to form a three-layer structure, the effect of suppressing the occurrence of electrolytic corrosion by the film layer of hexavalent chromium-free chromate is further improved.
As a result of the test, when the first plating layer is zinc-nickel plating and the above three-layer structure is used, the anti-corrosion resistance is superior to the anti-corrosion film using the hexavalent chromium-containing chromate in the same three-layer structure. It was confirmed that it was possible.

この発明の転がり軸受は、対向する軌道輪間に転動体を介在させてなり、アルミ合金製のハウジングにいずれかの軌道輪が接して取付けられる転がり軸受において、前記ハウジングに取付けられる軌道輪におけるハウジングとの接触面に、6価クロムフリークロメイトを使用した電食防止皮膜を設けたため、アルミ合金製ハウジングに用いても電食の発生が抑制され、また電食防止皮膜に有害物質を含まないものとなる。
この発明の車輪用転がり軸受は、外方部材のナックルとの接触面に、6価クロムフリークロメイトを使用した電食防止皮膜を設けたため、アルミ合金製ナックルに用いても電食の発生が抑制され、また電食防止皮膜に有害物質を含まないものとなる。
The rolling bearing according to the present invention is a rolling bearing in which a rolling element is interposed between opposed bearing rings, and one of the bearing rings is attached to an aluminum alloy housing, and the housing in the bearing ring attached to the housing is provided. Since the electrolytic contact protection film using hexavalent chromium-free chromate is provided on the contact surface, the generation of electrolytic corrosion is suppressed even if it is used for an aluminum alloy housing, and no harmful substances are contained in the corrosion protection film. It will be a thing.
Since the wheel rolling bearing of the present invention is provided with an electrolytic corrosion prevention film using hexavalent chromium-free chromate on the contact surface of the outer member with the knuckle, even if it is used for an aluminum alloy knuckle, the occurrence of electrolytic corrosion is generated. It is suppressed, and the electrolytic corrosion prevention film does not contain harmful substances.

この発明の第1の実施形態を図1と共に説明する。この実施形態は、車輪用転がり軸受に適用した例である。この車輪用転がり軸受は、内輪回転タイプで、かつ駆動輪支持用のものであり、また第3世代型のものである。   A first embodiment of the present invention will be described with reference to FIG. This embodiment is an example applied to a wheel rolling bearing. The wheel rolling bearing is an inner ring rotating type and a driving wheel supporting type, and is a third generation type.

図1に示すように、この発明の第1の実施形態である車輪用転がり軸受は、内周に複列の転走面4を有する外方部材1と、これら転走面4にそれぞれ対向する転走面5を有する内方部材2と、これら複列の転走面4,5間に介在させた複列の転動体3とを備える。転動体3はボールからなり、各列毎に保持器6で保持されている。各転走面4,5は、断面が円弧状であって、背面合わせとなるように接触角が形成され、この車輪用転がり軸受は複列のアンギュラ玉軸受とされている。内外の部材2,1間に形成される環状空間のアウトボード側およびインボード側の各開口端部は、それぞれ接触式のシール7,8で密封されている。なお、アウトボード側とは車体に取付けた場合に車体外側に位置する側であり、インボード側は車体内側に位置する側である。   As shown in FIG. 1, the wheel rolling bearing according to the first embodiment of the present invention is opposed to the outer member 1 having double-row rolling surfaces 4 on the inner periphery, and these rolling surfaces 4. An inner member 2 having a rolling surface 5 and a double row rolling element 3 interposed between the double row rolling surfaces 4 and 5 are provided. The rolling elements 3 are formed of balls and are held by the cage 6 for each row. Each of the rolling surfaces 4 and 5 has an arc shape in cross section, and a contact angle is formed so as to be back-to-back, and this wheel rolling bearing is a double row angular ball bearing. The open end portions on the outboard side and the inboard side of the annular space formed between the inner and outer members 2 and 1 are sealed with contact-type seals 7 and 8, respectively. The outboard side is a side located outside the vehicle body when attached to the vehicle body, and the inboard side is a side located inside the vehicle body.

外方部材1は、固定側の部材となるものであって、ナックル14に固定するための車体取付フランジ1aを、外周における軸方向のアウトボード側寄り位置に有する。車体取付フランジ1aは、円周方向の複数箇所に取付孔21を有している。取付孔21はねじ孔とされている。   The outer member 1 is a member on the fixed side, and has a vehicle body mounting flange 1a for fixing to the knuckle 14 at a position closer to the outboard side in the axial direction on the outer periphery. The vehicle body mounting flange 1a has mounting holes 21 at a plurality of locations in the circumferential direction. The attachment hole 21 is a screw hole.

内方部材2は、回転側の部材となるものであって、車輪取付フランジ2aを有するハブ輪2Aと、このハブ輪2Aの端部外径に嵌合した別体の内輪2Bとで構成されている。ハブ輪2Aおよび内輪構成部材2Bに各列の転走面5がそれぞれ形成される。車輪取付フランジ2aは内方部材2のアウトボード側端部に位置しており、この車輪取付フランジ2aよりもアウトボード側に突出して、ブレーキパイロット部22およびホイールパイロット部23が設けられている。この車輪取付フランジ2aに、ブレーキロータ15を介して車輪16のリムがボルト18で取付けらる。ブレーキパイロット部22およびホイールパイロット部23は、それぞれブレーキロータ15および車輪16のリムの内径面に嵌合して位置決めを行う部分である。
ハブ輪2Aの内径孔には、駆動軸における等速ジョイント25の外側継手部材25aにおける軸部26が挿通されている。軸部26は、先端が雄ねじ部とされ、ナット27でハ
ブ輪2Aに締め付け固定されている。
The inner member 2 is a member on the rotation side, and includes a hub wheel 2A having a wheel mounting flange 2a and a separate inner ring 2B fitted to the outer diameter of the end of the hub wheel 2A. ing. Each row of rolling surfaces 5 is formed on the hub wheel 2A and the inner ring component 2B. The wheel mounting flange 2a is located at the end portion on the outboard side of the inner member 2, and the brake pilot portion 22 and the wheel pilot portion 23 are provided so as to protrude from the wheel mounting flange 2a to the outboard side. The rim of the wheel 16 is attached to the wheel attachment flange 2 a via the brake rotor 15 with bolts 18. The brake pilot portion 22 and the wheel pilot portion 23 are portions that are fitted and positioned on the inner diameter surfaces of the brake rotor 15 and the rim of the wheel 16, respectively.
The shaft portion 26 of the outer joint member 25a of the constant velocity joint 25 on the drive shaft is inserted through the inner diameter hole of the hub wheel 2A. The shaft portion 26 has a male screw portion at the tip, and is fastened and fixed to the hub wheel 2 </ b> A with a nut 27.

ナックル14は、車体(図示せず)に取付けられた部材であって、この車輪用転がり軸受に対して軸受ハウジングとなる。ナックル14は、軸受嵌合孔14aを有し、この軸受嵌合孔14aの外周に沿う周方向複数箇所に、ボルト挿通孔14bが設けられている。外方部材1は、外径面における車体取付フランジ1aよりもインボード側の部分がナックル14の軸受取付孔14aに嵌合し、車体取付フランジ1aがナックル14の側面に当接する状態で、ボルト19(図1)によりナックル14に取付けられる。ボルト19は、ナックル14のボルト挿通孔14bに挿通され、ねじ軸部分が車体取付フランジ1aの取付孔21に螺合する。
ナックル14は、アルミ合金製である。車輪用転がり軸受の外方部材1、内方部材2、および転動体3は、炭素鋼または高炭素クロム鋼等の鋼製である。
The knuckle 14 is a member attached to a vehicle body (not shown) and serves as a bearing housing for the wheel rolling bearing. The knuckle 14 has a bearing fitting hole 14a, and bolt insertion holes 14b are provided at a plurality of locations in the circumferential direction along the outer periphery of the bearing fitting hole 14a. The outer member 1 has a portion on the outer diameter side of the vehicle body mounting flange 1a that is inboard with the bearing mounting hole 14a of the knuckle 14, and the vehicle body mounting flange 1a is in contact with the side surface of the knuckle 14. It attaches to the knuckle 14 by 19 (FIG. 1). The bolt 19 is inserted into the bolt insertion hole 14b of the knuckle 14, and the screw shaft portion is screwed into the attachment hole 21 of the vehicle body attachment flange 1a.
The knuckle 14 is made of an aluminum alloy. The outer member 1, the inner member 2, and the rolling element 3 of the wheel rolling bearing are made of steel such as carbon steel or high carbon chrome steel.

図2に示すように、外方部材1におけるナックル14との接触面には、電食防止皮膜17が設けられている。この電食防止皮膜17は、外方部材1の外径面におけるナックル14が外嵌する外径面部分、および車体取付フランジ1aのナックル当接側となる片側の側面にわたり、連続して設けられている。すなわち、電食防止皮膜17は、外方部材1の外径面覆い部分171 と、フランジ覆い部分172 とを有する。
また、内方部材2のハブ輪2Aにおける車輪取付フランジ2aの外面、および各パイロット部22,23にも、電食防止皮膜17が設けられている。この内方部材2側の電食防止皮膜17は、車輪取付フランジ2aのブレーキロータ当接面覆い部分173 と、各パイロット部覆い部分174 とを有する。
As shown in FIG. 2, an electrolytic corrosion prevention film 17 is provided on the contact surface of the outer member 1 with the knuckle 14. This electrolytic corrosion prevention film 17 is continuously provided over the outer diameter surface portion of the outer diameter surface of the outer member 1 where the knuckle 14 is fitted and the side surface on one side which is the knuckle contact side of the vehicle body mounting flange 1a. ing. That is, the electrolytic corrosion preventing film 17 has an outer diameter surface covering portion 171 and a flange covering portion 172 of the outer member 1.
Further, the electrolytic corrosion prevention film 17 is also provided on the outer surface of the wheel mounting flange 2 a in the hub wheel 2 </ b> A of the inner member 2 and the pilot portions 22 and 23. The electrolytic corrosion prevention film 17 on the inner member 2 side has a brake rotor contact surface covering portion 173 of the wheel mounting flange 2a and each pilot portion covering portion 174.

電食防止皮膜17は、6価クロムフリークロメイトを使用したものとされる。この電食防止皮膜17は、例えば図3(A)に示すように、外方部材1等の母材28の表面に設けられた第1のめっき層17aと、このめっき層17aの外面に重ねて設けられた6価クロムフリークロメイトの皮膜層17bと、この皮膜層17bの外面に重ねて設けられた熱硬化型コーティング材のコーティング層17cとを設けた3層構造のものとされる。熱硬化型コーティング材には低温熱硬化型コーティング材が用いられる。低温熱硬化型コーティング材としては一液性低温熱硬化型コーティング材等が用いられる。
電食防止皮膜17は、この他に、図3(B)に示すように、第1のめっき層17aと6価クロムフリークロメイトの皮膜層17bとでなる2層構造としても良い。
The electrolytic corrosion prevention film 17 is assumed to use hexavalent chromium-free chromate. For example, as shown in FIG. 3A, the electrolytic corrosion preventing film 17 is overlapped with a first plating layer 17a provided on the surface of the base material 28 such as the outer member 1 and the outer surface of the plating layer 17a. The three-layer structure is provided with a hexavalent chromium-free chromate coating layer 17b and a thermosetting coating material coating layer 17c provided on the outer surface of the coating layer 17b. A low temperature thermosetting coating material is used as the thermosetting coating material. As the low temperature thermosetting coating material, a one-component low temperature thermosetting coating material or the like is used.
In addition to this, as shown in FIG. 3B, the electrolytic corrosion prevention film 17 may have a two-layer structure including a first plating layer 17a and a hexavalent chromium-free chromate film layer 17b.

電食防止皮膜17の具体例として、次の各例のものが用いられる。括弧内は各層の材質を示す。
・(Zn−Niめっき)+(6価クロムフリークロメイト)+(低温熱硬化型コーティング)
・(Zn−Niめっき)+(6価クロムフリークロメイト)
・(Znめっき)+(6価クロムフリークロメイト)+(低温熱硬化型コーティング)
・(Znめっき)+(6価クロムフリークロメイト)
・(Zn−Ni−Feめっき)+(6価クロムフリークロメイト)+(低温熱硬化型コーティング)
・(Zn−Ni−Feめっき)+(6価クロムフリークロメイト)
・(カドミウムめっき)+(6価クロムフリークロメイト)+(低温熱硬化型コーティング)
・(カドミウムめっき)+(6価クロムフリークロメイト)
As specific examples of the electrolytic corrosion preventing film 17, the following examples are used. The parentheses indicate the material of each layer.
・ (Zn-Ni plating) + (hexavalent chromium-free chromate) + (low-temperature thermosetting coating)
・ (Zn-Ni plating) + (Hexavalent chromium-free chromate)
・ (Zn plating) + (Hexavalent chromium-free chromate) + (Low-temperature thermosetting coating)
・ (Zn plating) + (Hexavalent chromium-free chromate)
-(Zn-Ni-Fe plating) + (hexavalent chromium-free chromate) + (low-temperature thermosetting coating)
・ (Zn-Ni-Fe plating) + (hexavalent chromium-free chromate)
・ (Cadmium plating) + (Hexavalent chromium-free chromate) + (Low-temperature thermosetting coating)
・ (Cadmium plating) + (Hexavalent chromium-free chromate)

6価クロムフリークロメイトの主成分としては、次の2種類が挙げられる。
・硝酸クロム+無機塩
・硫酸クロム+無機塩
上記無機塩としては、硝酸塩、硫酸塩、および塩酸塩のいずれを用いても良い。
As main components of hexavalent chromium-free chromate, there are the following two types.
· Chromium nitrate + inorganic salt · Chromium sulfate + inorganic salt As the inorganic salt, any of nitrate, sulfate, and hydrochloride may be used.

なお、一般のクロメートの主成分は、無水クロム酸(または重クロム酸)+無機塩(硝酸、硫酸、塩酸)である。その無水クロム酸(または重クロム酸)に、6価クロムが入っている。
6価クロムフリークロメイトは、一般の6価クロム含有のクロメイトに対して、無水クロム酸(または重クロム酸)の代わりに、6価クロムを含まない硝酸クロムまたは硫酸クロムを用いたものである。
The main component of general chromate is chromic anhydride (or dichromic acid) + inorganic salt (nitric acid, sulfuric acid, hydrochloric acid). The chromic anhydride (or dichromic acid) contains hexavalent chromium.
Hexavalent chromium-free chromate is obtained by using chromium nitrate not containing hexavalent chromium or chromium sulfate instead of chromic anhydride (or dichromic acid) in comparison with a chromate containing general hexavalent chromium. .

この構成の車輪用転がり軸受によると、外方部材1とナックル14とは、外方部材1が鋼材であり、ナックル14がアルミ合金製であるため、互いに電位差を生じる金属材同士の関係となる。しかし、外方部材1のナックル14との接触面が電食防止皮膜17で覆われているため、上記接触面に泥塩水等がかかっても、電池が成形されることがない。したがって、上記接触面に電極腐食が生じることが防止される。また電食防止皮膜17を設けるため、別部材の絶縁材を介在させる場合と異なり、部品点数の増加がなく、部品管理の煩雑化や組付け性の低下が回避される。電食防止皮膜17には、6価クロムフリークロメイトを使用したため、6価クロムによる有害性のないものにできる。また試験によると、6価クロムフリークロメイトを使用しても、第1のめっき層17a等を適宜選定することで、6価クロム含有クロメート使用の電食防止皮膜よりも、電食防止性に優れたものとできることが確認された。   According to the wheel rolling bearing of this configuration, the outer member 1 and the knuckle 14 are in a relationship between metal materials that cause a potential difference from each other because the outer member 1 is a steel material and the knuckle 14 is made of an aluminum alloy. . However, since the contact surface of the outer member 1 with the knuckle 14 is covered with the electrolytic corrosion prevention film 17, the battery is not molded even if the contact surface is covered with muddy salt water or the like. Therefore, electrode corrosion is prevented from occurring on the contact surface. In addition, since the electrolytic corrosion prevention film 17 is provided, the number of parts is not increased, unlike the case where an insulating material as a separate member is interposed, and the complication of parts management and the deterioration of assemblability are avoided. Since the electrolytic corrosion prevention film 17 uses hexavalent chromium-free chromate, it can be made harmless by hexavalent chromium. In addition, according to the test, even when hexavalent chromium-free chromate is used, by properly selecting the first plating layer 17a and the like, it is possible to prevent electrolytic corrosion more than the electrolytic corrosion-preventing film using hexavalent chromium-containing chromate. It was confirmed that it was excellent.

また、この実施形態では、ハブ輪2Aの車輪取付フランジ2aおよびパイロット部22,23にも電食防止皮膜17を設けたため、ブレーキロータ15にアルミ合金性のものを使用しても、ブレーキロータ15とハブ輪2Aとの接触面で電極腐食が生じることが防止される。この接触面の電極腐食が生じると、自動車の使用後の補修時に、ブレーキロータ15がハブ輪2Aに付着して離れず、取り外しが困難になることがあるが、上記接触面の電極腐食を防止することで、このような補修時のブレーキロータ15の取り外し性の困難が解消される。なお、ブレーキロータ15についても、軽量化のためにアルミ合金製のものの使用が増えると考えられる。   In this embodiment, since the electrolytic corrosion prevention film 17 is provided on the wheel mounting flange 2a and the pilot portions 22 and 23 of the hub wheel 2A, even if an aluminum alloy material is used for the brake rotor 15, the brake rotor 15 Electrode corrosion is prevented from occurring at the contact surface between the hub wheel 2A and the hub wheel 2A. If this contact surface electrode corrosion occurs, the brake rotor 15 may not adhere to the hub wheel 2A during repair after use of the automobile, and it may be difficult to remove. However, the contact surface electrode corrosion is prevented. By doing so, the difficulty of detachability of the brake rotor 15 at the time of such repair is eliminated. In addition, it is thought that the use of the one made of an aluminum alloy is also increased for the weight reduction of the brake rotor 15.

図4は、この発明における他の実施形態を示す。この実施形態は、図1ないし図3に示す第1の実施形態の車輪用転がり軸受において、従動輪用としたものである。従動輪用であるため、ハブ輪2Aは中心部に内径孔を有していない。内輪2Bのハブ輪2Aへの固定は、ハブ輪2Aに設けた加締部2bで行っている。この例においても、外方部材1のナックル14(図1参照)に対する接触面、およびハブ輪2Aにおける車輪取付用フランジ2aのブレーキロータ接触面および各パイロット部22,23の表面に電食防止皮膜17を施している。電食防止皮膜17の重なり構成,材質は、第1の実施形態に示した各例のものが使用できる。この実施形態におけるその他の構成は、第1の実施形態と同じであるので、対応部分に同一符号を付してその説明を省略する。なお、この実施形態の場合、車輪取付フランジ1aは、外方部材1の外周における軸方向の中間位置に設けられている。   FIG. 4 shows another embodiment of the present invention. This embodiment is for a driven wheel in the wheel rolling bearing of the first embodiment shown in FIGS. 1 to 3. Since it is for a driven wheel, the hub wheel 2A does not have an inner diameter hole at the center. The inner ring 2B is fixed to the hub ring 2A by a caulking portion 2b provided on the hub ring 2A. Also in this example, an electrolytic corrosion prevention film is formed on the contact surface of the outer member 1 with the knuckle 14 (see FIG. 1), the brake rotor contact surface of the wheel mounting flange 2a in the hub wheel 2A, and the surfaces of the pilot portions 22 and 23. 17 is given. As the overlapping structure and material of the electrolytic corrosion prevention film 17, those of the examples shown in the first embodiment can be used. Since other configurations in this embodiment are the same as those in the first embodiment, the corresponding parts are denoted by the same reference numerals and description thereof is omitted. In the case of this embodiment, the wheel mounting flange 1 a is provided at an intermediate position in the axial direction on the outer periphery of the outer member 1.

図5は、この発明におけるさらに他の実施形態を示す。この実施形態は、図1ないし図3に示す第1の実施形態の車輪用転がり軸受において、同じく駆動輪支持用であるが、第2世代型のものとしてある。この実施形態では、内方部材2が、ハブ輪2Cと、このハブ輪2Cの外周に嵌合させた2個の内輪2D,2Eとからなり、これら2個の内輪2D,2Eに各列の軌道面5が形成されている。外方部材1は、第1の実施形態と同じく一体の部材であり、車体取付用フランジ1aを有している。
この例においても、外方部材1のナックル14に対する接触面、並びにハブ輪2Cにおける車輪取付用フランジ2aのブレーキロータ接触面および各パイロット部22,23に電食防止皮膜17を施している。電食防止皮膜17の重なり構成,材質は、第1の実施形
態に示した各例のものか使用できる。この実施形態におけるその他の構成は、第1の実施形態と同じであるので、対応部分に同一符号を付してその説明を省略する。なお、この実施形態の場合、車輪取付フランジ1aは、外方部材1の外周における軸方向の中間位置に設けられている。また、図1ないし図5の実施形態において転動体3をボールで示したが円すいころであってもよい。
FIG. 5 shows still another embodiment of the present invention. This embodiment is a wheel rolling bearing of the first embodiment shown in FIGS. 1 to 3, which is also for driving wheel support, but is of the second generation type. In this embodiment, the inner member 2 is composed of a hub wheel 2C and two inner rings 2D and 2E fitted on the outer periphery of the hub wheel 2C, and the two inner rings 2D and 2E are arranged in each row. A raceway surface 5 is formed. The outer member 1 is an integral member as in the first embodiment, and has a vehicle body mounting flange 1a.
Also in this example, the electrolytic corrosion prevention film 17 is applied to the contact surface of the outer member 1 with respect to the knuckle 14, the brake rotor contact surface of the wheel mounting flange 2a in the hub wheel 2C, and the pilot portions 22 and 23. The overlapping structure and material of the electrolytic corrosion prevention film 17 may be those of the examples shown in the first embodiment. Since other configurations in this embodiment are the same as those in the first embodiment, the same reference numerals are given to corresponding portions, and descriptions thereof are omitted. In the case of this embodiment, the wheel mounting flange 1 a is provided at an intermediate position in the axial direction on the outer periphery of the outer member 1. Moreover, although the rolling element 3 was shown with the ball | bowl in embodiment of FIG. 1 thru | or 5, a tapered roller may be sufficient.

図6は、この発明におけるさらに他の実施形態を示す。この実施形態は、深溝玉軸受に適用した例を示す。この転がり軸受は、それぞれ軌道輪となる外輪31と内輪32の対向する軌道面34,35の間にボールからなる複数の転動体33を介在させてある。複数の転動体33は、保持器36により保持される。外輪31と内輪32の間の軸受空間の両端は、外輪31に取付けられたシール37,37により密閉される。外輪31,内輪32,および転動体33の材質は鋼製である。   FIG. 6 shows still another embodiment of the present invention. This embodiment shows an example applied to a deep groove ball bearing. In this rolling bearing, a plurality of rolling elements 33 made of balls are interposed between raceway surfaces 34 and 35 of the outer ring 31 and the inner ring 32 facing each other. The plurality of rolling elements 33 are held by a holder 36. Both ends of the bearing space between the outer ring 31 and the inner ring 32 are sealed by seals 37, 37 attached to the outer ring 31. The material of the outer ring 31, the inner ring 32, and the rolling element 33 is made of steel.

この転がり軸受は、アルミ合金製のハウジング44の内径面に外輪31の外径面が嵌合して取付けられる。この外輪31におけるハウジング44との接触面に、6価クロムフリークロメイトを使用した電食防止皮膜17が設けられている。外輪31に電食防止皮膜17を設ける範囲は、外径面だけであっても良いが、外径面から両側の幅面にわたる範囲としてある。電食防止皮膜17の重なり構成,材質は、第1の実施形態と共に前述した各例のものが使用できる。   The rolling bearing is attached by fitting the outer diameter surface of the outer ring 31 to the inner diameter surface of the housing 44 made of aluminum alloy. On the contact surface of the outer ring 31 with the housing 44, an electrolytic corrosion prevention film 17 using hexavalent chromium-free chromate is provided. The range where the electrolytic corrosion preventing film 17 is provided on the outer ring 31 may be only the outer diameter surface, but is a range extending from the outer diameter surface to the width surfaces on both sides. As the overlapping structure and material of the electrolytic corrosion prevention film 17, those described in the above examples together with the first embodiment can be used.

このような深溝玉軸受であっても、アルミ合金製ハウジング44に設置されて外輪31とハウジング44との接触面に泥塩水等がかかる条件下で使用される場合に、電食の発生の問題がある。この問題を、電食防止皮膜17によって解消することができる。電食防止皮膜17は、上記各実施形態と同じく6価クロムフリークロメイトを使用したものであるため、6価クロムによる有害性のないものにでき、また、電食防止性に優れたものとできる。   Even in such a deep groove ball bearing, when it is installed in an aluminum alloy housing 44 and used under conditions in which muddy salt water or the like is applied to the contact surface between the outer ring 31 and the housing 44, the problem of the occurrence of electrolytic corrosion There is. This problem can be solved by the electrolytic corrosion prevention film 17. Since the electrolytic corrosion prevention film 17 uses hexavalent chromium-free chromate as in the above embodiments, it can be made harmless by hexavalent chromium and has excellent electrolytic corrosion resistance. it can.

なお、この発明は、転がり軸受一般に適用することができ、例えば円すいころ軸受や、円筒ころ軸受等にも適用することができる。   The present invention can be applied to general rolling bearings, and can be applied to, for example, tapered roller bearings and cylindrical roller bearings.

次ぎに、試験例を説明する。車輪用転がり軸受における外方部材1に電食防止皮膜17を施したものについて、塩水噴霧を行い、その噴霧後、960時間経過するまでの外観観察を行った。
試験条件は、JIS Z2371に準拠した塩水噴霧試験であり、塩水濃度は5w%、雰囲気温度は35℃とした。
供試体としては、図4の実施形態にかかる車輪用転がり軸受における外方部材1について、その電食防止皮膜17を、(Zn−Niめっき)+(6価クロムフリークロメイト)+(低温熱硬化型コーティング)とした実施例と、この実施例に対して電食防止皮膜17を(Zn−Niめっき)+(6価クロム含有クロメイト)+(低温熱硬化型コーティング)に変えた比較例とにつき行った。
試験結果を、評点方法と共に表1に示す。
Next, test examples will be described. About the outer member 1 in the rolling bearing for wheels, the electrolytic corrosion prevention film 17 was applied, and spraying with salt water was performed, and the appearance was observed until 960 hours passed after the spraying.
The test conditions were a salt spray test according to JIS Z2371, the salt water concentration was 5 w%, and the ambient temperature was 35 ° C.
As the specimen, for the outer member 1 in the wheel rolling bearing according to the embodiment of FIG. 4, the electrolytic corrosion prevention film 17 is (Zn—Ni plating) + (hexavalent chromium-free chromate) + (low temperature heat). And a comparative example in which the electrolytic corrosion prevention film 17 was changed to (Zn—Ni plating) + (hexavalent chromium-containing chromate) + (low temperature thermosetting coating). I went.
The test results are shown in Table 1 together with the scoring method.

Figure 2007147085
Figure 2007147085

上記の表1より、噴霧後240時間経過の時点までは、比較例となる6価クロム含有クロメイト使用のものの方が錆の発生が少ない点で優れているが、480時間経過した後では、960時間経過の時点においても、逆に実施例における6価クロムフリークロメイト使用のものの方が錆の発生が少なく、優れていることがわかる。
これより、実際の使用を考えると、6価クロムフリークロメイトを使用した実施例品の方が電食防止性に優れていると考えられる。なお、電食防止皮膜17の具体例として示した他の皮膜についても同様の結果を得られたが、ここでは省略する。
From Table 1 above, up to 240 hours after spraying, the hexavalent chromium-containing chromate used as a comparative example is superior in terms of less rust generation, but after 480 hours, 960 Even when the time has elapsed, it can be seen that the use of hexavalent chromium-free chromate in the examples is superior in that it produces less rust.
From this, when considering actual use, it is considered that the example product using hexavalent chromium-free chromate is more excellent in electrolytic corrosion prevention. In addition, although the same result was obtained also about the other film | membrane shown as a specific example of the electrolytic corrosion prevention film | membrane 17, it abbreviate | omits here.

この発明の一実施形態にかかる車輪用転がり軸受による車輪支持構造を示す断面図である。It is sectional drawing which shows the wheel support structure by the rolling bearing for wheels concerning one Embodiment of this invention. 同車輪用転がり軸受の断面図である。It is sectional drawing of the rolling bearing for the wheels. 同軸受の電食防止皮膜の各例を示す部分拡大断面図である。It is a partial expanded sectional view which shows each example of the electrolytic corrosion prevention film of the bearing. この発明の他の実施形態における車輪用転がり軸受を示す断面図である。It is sectional drawing which shows the rolling bearing for wheels in other embodiment of this invention. この発明のさらに他の実施形態にかかる車輪用転がり軸受による車輪支持構造を示す断面図である。It is sectional drawing which shows the wheel support structure by the rolling bearing for wheels concerning further another embodiment of this invention. この発明のさらに他の実施形態の転がり軸受を示す部分断面図である。It is a fragmentary sectional view which shows the rolling bearing of further another embodiment of this invention.

符号の説明Explanation of symbols

1…外方部材
1a…車体取付フランジ
2…内方部材
2a…車輪取付フランジ
2A…ハブ輪
3…転動体
4,5…転走面
14…アルミ合金製のナックル
17…電食防止皮膜
31…外輪(軌道輪)
32…内輪(軌道輪)
33…転動体
44…アルミ合金製のハウジング
DESCRIPTION OF SYMBOLS 1 ... Outer member 1a ... Car body mounting flange 2 ... Inner member 2a ... Wheel mounting flange 2A ... Hub wheel 3 ... Rolling elements 4, 5 ... Rolling surface 14 ... Knuckle 17 made of aluminum alloy ... Electric corrosion prevention coating 31 ... Outer ring (Raceway)
32 ... Inner ring (Raceway)
33 ... rolling element 44 ... housing made of aluminum alloy

Claims (5)

対向する軌道輪間に転動体を介在させてなり、アルミ合金製のハウジングにいずれかの軌道輪が接して取付けられる転がり軸受において、前記ハウジングに取付けられる軌道輪におけるハウジングとの接触面に、6価クロムフリークロメイトを使用した電食防止皮膜を設けたことを特徴とする転がり軸受。   In a rolling bearing in which a rolling element is interposed between opposed race rings, and any of the race rings is in contact with an aluminum alloy housing, 6 on the contact surface of the race ring attached to the housing with the housing. Rolling bearings characterized by an anti-corrosion coating using valent chromium-free chromate. アルミ合金製のナックルに固定するための車体取付フランジを外周に有し、内周に複列の転走面を有する外方部材と、一端に車輪取付フランジを有し、上記転走面のそれぞれに対向する転走面を形成した内方部材と、これら対向する転走面間に介在させた複列の転動体とを備え、車体に対して車輪を回転自在に支持する車輪用の転がり軸受において、
上記外方部材の上記ナックルとの接触面に、6価クロムフリークロメイトを使用した電食防止皮膜を設けたことを特徴とする車輪用の転がり軸受。
Each of the above rolling surfaces has a vehicle body mounting flange for fixing to an aluminum alloy knuckle on the outer periphery, an outer member having a double row rolling surface on the inner periphery, and a wheel mounting flange on one end. A rolling bearing for a wheel which includes an inner member formed with a rolling surface facing the wheel and a double row rolling element interposed between the facing rolling surfaces and rotatably supports the wheel with respect to the vehicle body In
A rolling bearing for a wheel, wherein an electrolytic corrosion prevention film using hexavalent chromium-free chromate is provided on a contact surface of the outer member with the knuckle.
請求項1または請求項2において、前記電食防止皮膜が、母材表面に設けられた第1のめっき層と、この第1のめっき層の外面に重ねて設けられた6価クロムフリークロメイトの皮膜層とを含む転がり軸受。   3. The electroplating prevention film according to claim 1 or 2, wherein the electrolytic corrosion prevention film is a first plating layer provided on the surface of the base material, and a hexavalent chromium-free chromate provided on the outer surface of the first plating layer. Rolling bearing including a coating layer. 請求項1または請求項2において、前記電食防止皮膜が、母材表面に設けられた第1のめっき層と、この第1のめっき層の外面に重ねて設けられた6価クロムフリークロメイトの皮膜層と、この皮膜層の外面に重ねて設けられた熱硬化型コーティング材のコーティング層とを設けたものである転がり軸受。   3. The electroplating prevention film according to claim 1 or 2, wherein the electrolytic corrosion prevention film is a first plating layer provided on the surface of the base material, and a hexavalent chromium-free chromate provided on the outer surface of the first plating layer. And a coating layer of a thermosetting coating material provided on the outer surface of the coating layer. 請求項4において、前記第1のめっき層が亜鉛ニッケルめっきである転がり軸受。
The rolling bearing according to claim 4, wherein the first plating layer is zinc-nickel plating.
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WO2009093434A1 (en) * 2008-01-23 2009-07-30 Ntn Corporation Bearing device for wheel
WO2009122855A1 (en) * 2008-04-01 2009-10-08 Ntn株式会社 Bearing device for wheel, and axle module
WO2023149151A1 (en) * 2022-02-04 2023-08-10 Ntn株式会社 Vehicle wheel bearing device

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JP2003072310A (en) * 2001-09-05 2003-03-12 Ntn Corp Bearing system for wheel
JP2003166074A (en) * 2001-11-30 2003-06-13 Dipsol Chem Co Ltd Treatment solution for forming hexavalent chromium- free rust preventive coating on plated film with zinc and zinc alloy, hexavalent chromium-free rust preventive coating and method for forming the same

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JP2001020080A (en) * 1999-07-07 2001-01-23 Kobe Steel Ltd Composite material excellent in phosphate treatability and electrolytic corrosion resistance
JP2001080307A (en) * 1999-09-09 2001-03-27 Ntn Corp Wheel bearing device
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009093434A1 (en) * 2008-01-23 2009-07-30 Ntn Corporation Bearing device for wheel
WO2009122855A1 (en) * 2008-04-01 2009-10-08 Ntn株式会社 Bearing device for wheel, and axle module
WO2023149151A1 (en) * 2022-02-04 2023-08-10 Ntn株式会社 Vehicle wheel bearing device

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