JP2007016167A - Water soluble metal-working oil agent - Google Patents
Water soluble metal-working oil agent Download PDFInfo
- Publication number
- JP2007016167A JP2007016167A JP2005200466A JP2005200466A JP2007016167A JP 2007016167 A JP2007016167 A JP 2007016167A JP 2005200466 A JP2005200466 A JP 2005200466A JP 2005200466 A JP2005200466 A JP 2005200466A JP 2007016167 A JP2007016167 A JP 2007016167A
- Authority
- JP
- Japan
- Prior art keywords
- water
- acid
- soluble metal
- working fluid
- metal working
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000005555 metalworking Methods 0.000 title claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 18
- 239000003795 chemical substances by application Substances 0.000 title abstract description 12
- 150000003839 salts Chemical class 0.000 claims abstract description 19
- KGVYSMPUYYLGOM-UHFFFAOYSA-N triazine-4,5,6-tricarboxylic acid Chemical compound OC(=O)C1=NN=NC(C(O)=O)=C1C(O)=O KGVYSMPUYYLGOM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 8
- 239000012530 fluid Substances 0.000 claims description 31
- -1 aliphatic monocarboxylic acid Chemical class 0.000 claims description 17
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 3
- 239000008233 hard water Substances 0.000 abstract description 20
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 31
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 16
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 16
- 239000003921 oil Substances 0.000 description 14
- RAEOEMDZDMCHJA-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-[2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]ethyl]amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CCN(CC(O)=O)CC(O)=O)CC(O)=O RAEOEMDZDMCHJA-UHFFFAOYSA-N 0.000 description 11
- 230000002265 prevention Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 230000003449 preventive effect Effects 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000002173 cutting fluid Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 6
- 239000012085 test solution Substances 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 239000011550 stock solution Substances 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- LWBHHRRTOZQPDM-UHFFFAOYSA-N undecanedioic acid Chemical compound OC(=O)CCCCCCCCCC(O)=O LWBHHRRTOZQPDM-UHFFFAOYSA-N 0.000 description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 2
- BKKWPPMEXIXECW-UHFFFAOYSA-N 6-[[4,6-bis(5-carboxypentylamino)-1,3,5-triazin-2-yl]amino]hexanoic acid Chemical compound OC(=O)CCCCCNC1=NC(NCCCCCC(O)=O)=NC(NCCCCCC(O)=O)=N1 BKKWPPMEXIXECW-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000010730 cutting oil Substances 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000010720 hydraulic oil Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical compound C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- WYIWUIWPWHIZOH-UHFFFAOYSA-N 2-(triazin-4-yl)ethanol Chemical compound OCCC1=CC=NN=N1 WYIWUIWPWHIZOH-UHFFFAOYSA-N 0.000 description 1
- TWPOUICAAWPGSW-UHFFFAOYSA-N 2-[[4,6-bis(carboxymethylamino)-1,3,5-triazin-2-yl]amino]acetic acid Chemical compound OC(=O)CNC1=NC(NCC(O)=O)=NC(NCC(O)=O)=N1 TWPOUICAAWPGSW-UHFFFAOYSA-N 0.000 description 1
- SMNNDVUKAKPGDD-UHFFFAOYSA-N 2-butylbenzoic acid Chemical group CCCCC1=CC=CC=C1C(O)=O SMNNDVUKAKPGDD-UHFFFAOYSA-N 0.000 description 1
- AITYMYSWMONJCJ-UHFFFAOYSA-N 2-n,4-n,6-n-trihexyl-1,3,5-triazine-2,4,6-triamine Chemical compound CCCCCCNC1=NC(NCCCCCC)=NC(NCCCCCC)=N1 AITYMYSWMONJCJ-UHFFFAOYSA-N 0.000 description 1
- MRUZQPWXNODAJO-UHFFFAOYSA-N 3-[[4,6-bis(2-carboxyethylamino)-1,3,5-triazin-2-yl]amino]propanoic acid Chemical compound OC(=O)CCNC1=NC(NCCC(O)=O)=NC(NCCC(O)=O)=N1 MRUZQPWXNODAJO-UHFFFAOYSA-N 0.000 description 1
- DQSSWAOFCHHSJH-UHFFFAOYSA-N 4-[[4,6-bis(3-carboxypropylamino)-1,3,5-triazin-2-yl]amino]butanoic acid Chemical compound OC(=O)CCCNC1=NC(NCCCC(O)=O)=NC(NCCCC(O)=O)=N1 DQSSWAOFCHHSJH-UHFFFAOYSA-N 0.000 description 1
- OLWFXXDOBRWQIB-UHFFFAOYSA-N 5-[[4,6-bis(4-carboxybutylamino)-1,3,5-triazin-2-yl]amino]pentanoic acid Chemical compound OC(=O)CCCCNC1=NC(NCCCCC(O)=O)=NC(NCCCCC(O)=O)=N1 OLWFXXDOBRWQIB-UHFFFAOYSA-N 0.000 description 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- CSKUCFXSPGYOBP-UHFFFAOYSA-N [4,6-bis(carboxyamino)-1,3,5-triazin-2-yl]carbamic acid Chemical compound OC(=O)NC1=NC(NC(O)=O)=NC(NC(O)=O)=N1 CSKUCFXSPGYOBP-UHFFFAOYSA-N 0.000 description 1
- MUBKMWFYVHYZAI-UHFFFAOYSA-N [Al].[Cu].[Zn] Chemical compound [Al].[Cu].[Zn] MUBKMWFYVHYZAI-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N cyclobenzothiazole Natural products C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/14—Nitrogen-containing compounds
- C23F11/141—Amines; Quaternary ammonium compounds
- C23F11/143—Salts of amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/40—Six-membered ring containing nitrogen and carbon only
- C10M133/42—Triazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
- C10M2215/0425—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
- C10M2215/2225—Triazines used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/24—Emulsion properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
Abstract
Description
本発明は、トリアジン環を有する化合物を含有する水溶性金属工作油剤に関する。 The present invention relates to a water-soluble metal working fluid containing a compound having a triazine ring.
従来、水溶性防錆油剤はもちろん、水溶性の切削油剤、塑性加工油剤、洗浄剤、熱処理油剤、作動油、水溶性防錆剤など、水が介在した状態で使用される工作油剤や潤滑剤には防錆剤を使用するなどして錆の発生を抑える対策が採られる。 Conventionally, not only water-soluble rust preventive oil, but also water-soluble cutting oil, plastic processing oil, cleaning agent, heat treatment oil, hydraulic oil, water-soluble rust preventive agent, etc. Measures to suppress the generation of rust, such as using a rust inhibitor, are taken.
このうち、水溶性切削油剤を例に挙げて説明すると、被加工物が鉄・非鉄、金属・非金属に関係なく、加工機械の防錆のために防錆対策が施される。かかる防錆対策としては、従来、水溶性切削油剤をアルカリ性にして鉄が錆びにくい環境となるように図り、さらに錆から鉄を守る手段として脂肪酸を含む有機酸が多く使用されている。その上で、防錆剤として、例えば、セバシン酸、ドデカン二酸、ウンデカン二酸、ブラシル酸、パラターシャリーブチル安息香酸などの有機カルボン酸がアルカリ金属塩やアミン塩の形で使用されている。 Of these, a water-soluble cutting fluid will be described as an example. Regardless of whether the workpiece is iron or non-ferrous, metal or non-metal, rust prevention measures are taken for rust prevention of the processing machine. As such rust prevention measures, conventionally, an organic acid containing a fatty acid is often used as a means to protect the iron from rust by making the water-soluble cutting fluid alkaline and making the environment less susceptible to rust. In addition, organic carboxylic acids such as sebacic acid, dodecanedioic acid, undecanedioic acid, brassic acid, paratertiary butylbenzoic acid are used in the form of alkali metal salts or amine salts as rust inhibitors. .
ところで、工場で使用される水質が悪化している昨今、水の硬度も従来に比べて高くなる傾向にあること、ならびに金属の特異性を高めるため合金成分が多様化しており、水溶性切削油剤の使用される環境が悪化していることを踏まえると、防錆性に加えて、硬水安定性や耐腐敗性を有する水溶性切削液が要望されている。しかしながら、上述した有機カルボン酸は確かに防錆性は有するものの、硬水安定性や耐腐敗性は十分ではないという問題があった。 By the way, the quality of water used in factories has deteriorated, and the hardness of water tends to be higher than before, and the alloy components are diversified to increase the specificity of metals, and water-soluble cutting fluid In view of the fact that the environment in which these materials are used has deteriorated, there is a demand for water-soluble cutting fluid having hard water stability and rot resistance in addition to rust prevention. However, although the above-mentioned organic carboxylic acid certainly has rust prevention properties, there is a problem that hard water stability and rot resistance are not sufficient.
そこで、潤滑性に優れ、耐腐敗性を有するものとして、特定のスルフィド結合含有カルボン酸、ベンゾチアゾール化合物、過剰量の塩基性物質および水を含有する水溶性金属加工油が開示されている（特許文献１参照）。 Therefore, a water-soluble metalworking oil containing a specific sulfide bond-containing carboxylic acid, a benzothiazole compound, an excessive amount of a basic substance and water is disclosed as having excellent lubricity and anti-corrosion properties (patent) Reference 1).
しかしながら、特許文献１の水溶性金属加工油がさらに硬水安定性に優れているかについては明示されていない。 However, it is not specified whether the water-soluble metalworking oil of Patent Document 1 is further excellent in hard water stability.
本発明は、上記事情に鑑みてなされたものであり、硬水安定性および防錆性に優れた水溶性金属工作油剤を提供することを主たる目的とする。 This invention is made | formed in view of the said situation, and makes it a main objective to provide the water-soluble metal working fluid excellent in hard-water stability and rust prevention property.
本発明者は、特定のトリアジン環含有化合物を含有させることにより、硬水安定性および防錆性に優れた水溶性金属工作油剤が提供できることを見出し、本発明を完成した。 The present inventor has found that a water-soluble metal working fluid excellent in hard water stability and rust resistance can be provided by containing a specific triazine ring-containing compound, and has completed the present invention.
すなわち、本発明の要旨は以下のとおりである。
〔１〕 下記一般式（Ｉ）
That is, the gist of the present invention is as follows.
[1] The following general formula (I)
（式中、Ｘ１、Ｘ２及びＸ３はそれぞれ同一でイミノ基を表し、Ｒ１、Ｒ２及びＲ３はそれぞれ同一で炭素数１〜８のアルキレン基を表す。）で示されるトリアジントリカルボン酸又はその塩を含有する水溶性金属工作油剤、 (Wherein X 1 , X 2 and X 3 are the same and represent an imino group, and R 1 , R 2 and R 3 are the same and each represent an alkylene group having 1 to 8 carbon atoms). A water-soluble metal working fluid containing an acid or a salt thereof,
〔２〕 さらに脂肪族ジカルボン酸又はその塩を含有する、前記〔１〕記載の水溶性金属工作油剤、
〔３〕 さらに脂肪族モノカルボン酸又はその塩を含有する、前記〔１〕又は〔２〕記載の水溶性金属工作油剤、
〔４〕 前記トリアジントリカルボン酸又はその塩を０．５〜６０重量％含有する、前記〔１〕〜〔３〕のいずれか記載の水溶性金属工作油剤。
[2] The water-soluble metal working fluid according to [1], further containing an aliphatic dicarboxylic acid or a salt thereof,
[3] The water-soluble metal working fluid according to [1] or [2], further containing an aliphatic monocarboxylic acid or a salt thereof,
[4] The water-soluble metal working fluid according to any one of [1] to [3], containing 0.5 to 60% by weight of the triazine tricarboxylic acid or a salt thereof.
本発明によれば、硬水安定性および防錆性に優れた水溶性金属工作油剤を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the water-soluble metal working fluid excellent in hard water stability and rust prevention property can be provided.
以下、本発明について詳細に説明する。本発明の水溶性金属工作油剤は、水を主体として、以下に説明するトリアジン環含有化合物（本明細書では、「トリアジントリカルボン酸」という）又はその塩を含有するものである。 Hereinafter, the present invention will be described in detail. The water-soluble metal working fluid of the present invention contains water as a main component and a triazine ring-containing compound (hereinafter referred to as “triazine tricarboxylic acid”) or a salt thereof described below.
一般式（Ｉ）で表されるトリアジントリカルボン酸又はその塩において、Ｘ１、Ｘ２及びＸ３はそれぞれ同一でイミノ基を表し、Ｒ１、Ｒ２及びＲ３はそれぞれ同一で炭素数１〜８のアルキレン基を表す。該アルキレン基としては、直鎖状または分岐鎖状のいずれでもよいが、通常直鎖状が用いられる。具体的化合物としては、６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリメタン酸、６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリエタン酸、６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリプロパン酸、６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリブタン酸、６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリペンタン酸、６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリヘキサン酸、６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリヘプタン酸、６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリオクタン酸又はこれらアミン塩、アルカリ金属塩が挙げられ、これらの中で６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリヘキサン酸（以下、「ＴＴＨＡ」という場合がある）は Additive-Chemie Luers GmbH & Co KG社からTriazine-tri-carboxylic-acid TC（商品名）として入手できるので好適である。 In the triazine tricarboxylic acid represented by the general formula (I) or a salt thereof, X 1 , X 2 and X 3 are the same and each represent an imino group, and R 1 , R 2 and R 3 are the same and each have 1 to 1 carbon atoms 8 represents an alkylene group. The alkylene group may be either linear or branched, but is usually linear. Specific compounds include 6,6 ′, 6 ″-(1,3,5-triazine-2,4,6-triyltriimino) trimethanoic acid, 6,6 ′, 6 ″-(1,3 , 5-triazine-2,4,6-triyltriimino) triethanoic acid, 6,6 ′, 6 ″-(1,3,5-triazine-2,4,6-triyltriimino) tripropanoic acid, 6,6 ′, 6 ″-(1,3,5-triazine-2,4,6-triyltriimino) tributanoic acid, 6,6 ′, 6 ″-(1,3,5-triazine-2 , 4,6-triyltriimino) tripentanoic acid, 6,6 ′, 6 ″-(1,3,5-triazine-2,4,6-triyltriimino) trihexanoic acid, 6,6 ′, 6 ''-(1,3,5-triazine-2,4,6-triyltriimino) triheptanoic acid, 6,6 ', 6''-(1,3,5-triazine-2,4,6-tri Yltriimino) trioctanoic acid or their amine salts, alkali metal salts, among which 6,6 ′, 6 ″-(1,3,5-triazine-2,4,6-triyltriimino) trihexane An acid (hereinafter sometimes referred to as “TTHA”) is preferable because it can be obtained from Additive-Chemie Luers GmbH & Co KG as Triazine-tri-carboxylic-acid TC (trade name).
トリアジントリカルボン酸又はその塩の含有量は、特に限定されないが、水溶性金属工作油剤中、通常０．５〜６０重量％、好ましくは０．５〜２０重量％、さらに好ましくは１〜１２重量％である。また、水の含有量についても特に限定されないが、水溶性金属工作油剤中、通常３０〜９０重量％、好ましくは４０〜８０重量％、さらに好ましくは５０〜７０重量％である。このように、トリアジントリカルボン酸又はその塩および水を含有する水溶性金属工作油剤によれば、特に硬水安定性に優れるという作用効果が発揮される。 The content of triazine tricarboxylic acid or a salt thereof is not particularly limited, but is usually 0.5 to 60% by weight, preferably 0.5 to 20% by weight, more preferably 1 to 12% by weight in the water-soluble metal working fluid. It is. Moreover, although it does not specifically limit about content of water, It is 30 to 90 weight% normally in a water-soluble metal working fluid, Preferably it is 40 to 80 weight%, More preferably, it is 50 to 70 weight%. Thus, according to the water-soluble metal working fluid containing triazine tricarboxylic acid or a salt thereof and water, the effect of being particularly excellent in hard water stability is exhibited.
本発明の水溶性金属工作油剤には、必要に応じて防錆剤を含有するようにしてもよい。かかる防錆剤としては、脂肪族ジカルボン酸、脂肪族モノカルボン酸などの有機カルボン酸又はこれらのアミン塩、アルカリ金属塩を使用することが好ましい。 You may make it contain the rust preventive agent in the water-soluble metal working fluid agent of this invention as needed. As such a rust preventive, it is preferable to use organic carboxylic acids such as aliphatic dicarboxylic acids and aliphatic monocarboxylic acids, or amine salts and alkali metal salts thereof.
脂肪族ジカルボン酸としては、例えば、アジピン酸、セバシン酸、ウンデカン二酸、ドデカン二酸、ダイマー酸などが挙げられ、これらは単独で又は２種以上を混合して使用することができる。前記脂肪族ジカルボン酸又はその塩の含有量は特に限定されないが、水溶性金属工作油剤中、通常０．５〜６０重量％、好ましくは０．５〜２０重量％、さらに好ましくは０．５〜１０重量％である。 Examples of the aliphatic dicarboxylic acid include adipic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, and dimer acid, and these can be used alone or in admixture of two or more. Although content of the said aliphatic dicarboxylic acid or its salt is not specifically limited, In a water-soluble metal working fluid, it is 0.5 to 60 weight% normally, Preferably it is 0.5 to 20 weight%, More preferably, it is 0.5 to 10% by weight.
脂肪族モノカルボン酸としては、炭素数８〜１２で直鎖状または分岐鎖状の脂肪族モノカルボン酸が好ましく、例えば、オクタン酸、ノナン酸、イソノナン酸、イソデカン酸、ドデカン酸などが挙げられ、これらは単独で又は２種以上を混合して使用することができる。前記脂肪族モノカルボン酸又はその塩の含有量は特に限定されないが、水溶性金属工作油剤中、通常０．５〜６０重量％、好ましくは０．５〜２０重量％、さらに好ましくは０．５〜１０重量％である。 The aliphatic monocarboxylic acid is preferably a linear or branched aliphatic monocarboxylic acid having 8 to 12 carbon atoms, and examples thereof include octanoic acid, nonanoic acid, isononanoic acid, isodecanoic acid, and dodecanoic acid. These can be used alone or in admixture of two or more. Although content of the said aliphatic monocarboxylic acid or its salt is not specifically limited, In a water-soluble metal working fluid, it is 0.5 to 60 weight% normally, Preferably it is 0.5 to 20 weight%, More preferably, it is 0.5. -10% by weight.
このように、トリアジントリカルボン酸又はその塩、有機カルボン酸又はその塩および水を含有する水溶性金属工作油剤によれば、特に防錆性に優れるという作用効果が発揮される。 Thus, according to the water-soluble metal working fluid containing triazine tricarboxylic acid or a salt thereof, organic carboxylic acid or a salt thereof and water, an effect of being particularly excellent in rust prevention is exhibited.
本発明の水溶性金属工作油剤は、さらに、必要に応じて防錆性を向上させることを目的として、水溶性アミンを含有させることができる。かかる水溶性アミンとしては、当該技術分野で公知のものであれば特に限定されず、例えば、トリエタノールアミン、トリイソプロパノールアミン、Ｎ−メチルジエタノールアミンなどが挙げられ、これらは単独で又は２種以上を混合して使用することができる。前記水溶性アミンの含有量は特に限定されないが、水溶性金属工作油剤中、通常１０〜５０重量％、好ましくは２０〜４０重量％である。 The water-soluble metal working fluid of the present invention can further contain a water-soluble amine for the purpose of improving rust prevention as required. Such a water-soluble amine is not particularly limited as long as it is known in the art, and examples thereof include triethanolamine, triisopropanolamine, N-methyldiethanolamine, and the like. These may be used alone or in combination of two or more. Can be used as a mixture. Although content of the said water-soluble amine is not specifically limited, It is 10-50 weight% normally in a water-soluble metal working fluid, Preferably it is 20-40 weight%.
以上、本発明の水溶性金属工作油剤中に配合し得る成分について説明したが、該油剤中には本発明の効果を損なわない範囲で、当該技術分野で公知の添加剤を配合してもよい。かかる添加剤としては、例えば、防腐剤（例えば、ヒドロキシエチルトリアジン、ベンズイソチアゾリンなど）、消泡剤（例えば、ジメチルシロキサン乳化物など）などを挙げることができる。 As mentioned above, although the component which can be mix | blended with the water-soluble metal work fluid of this invention was demonstrated, you may mix | blend an additive well-known in the said technical field in this oil agent in the range which does not impair the effect of this invention. . Examples of such additives include preservatives (eg, hydroxyethyltriazine, benzisothiazoline, etc.), antifoaming agents (eg, dimethylsiloxane emulsion, etc.), and the like.
本発明の水溶性金属工作油剤は幅広い金属に適用可能であり、例えば、鋼、鉄、アルミニウム、銅、亜鉛、これらの合金、ステンレス鋼に対して好適である。 The water-soluble metal working fluid of the present invention can be applied to a wide range of metals and is suitable for, for example, steel, iron, aluminum, copper, zinc, alloys thereof, and stainless steel.
本発明の水溶性金属工作油剤は、水が介在した状態で使用される工作油剤であれば用途は特に限定されず、例えば、防錆油剤、切削油剤、塑性加工油剤、洗浄剤、熱処理剤、作動油、防錆剤として有用であり、特に切削油剤として好適に使用することができる。 The use of the water-soluble metal working fluid of the present invention is not particularly limited as long as it is a working fluid used in the presence of water, for example, rust preventive oil, cutting fluid, plastic working fluid, cleaning agent, heat treatment agent, It is useful as a hydraulic oil and a rust preventive agent, and can be suitably used particularly as a cutting oil agent.
なお、本発明の水溶性金属工作油剤は、原液をそのまま使用してもよいが、トリアジントリカルボン酸又はその塩の含有濃度が高い場合、水で希釈して使用することができる。水で希釈する場合のトリアジントリカルボン酸又はその塩の濃度は、用途および目的に応じて適宜設定すればよいが、通常は０．２重量％前後である。 In addition, although the stock solution may be used as it is, the water-soluble metal working fluid of the present invention can be used by diluting with water when the concentration of triazine tricarboxylic acid or its salt is high. The concentration of triazine tricarboxylic acid or a salt thereof when diluted with water may be appropriately set according to the use and purpose, but is usually around 0.2% by weight.
以下、試験例などにより本発明をさらに詳しく説明するが、本発明はこれらの試験例などにより限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to test examples, but the present invention is not limited to these test examples.
１．水溶性金属工作油剤の調製
表１に示す各成分を表１に記載の配合割合（単位：重量部）で室温にて均一に混合して、本発明の水溶性金属工作油剤（実施例１〜５）および比較のための水溶性金属工作油剤（比較例１，２）を調製した。
1. Preparation of Water-Soluble Metalworking Fluid Each component shown in Table 1 is uniformly mixed at a blending ratio (unit: parts by weight) described in Table 1 at room temperature, and the water-soluble metalworking fluid of the present invention (Examples 1 to 1). 5) and a comparative water-soluble metal working fluid (Comparative Examples 1 and 2) were prepared.
表１における各成分の略号は次のとおりである。
ＴＴＨＡ：トリアジントリカルボン酸としての ６,６’,６’’−（１，３，５−トリアジン−２，４，６−トリイルトリイミノ）トリヘキサン酸（Triazine-tri-carboxylic-acid TC，Additive-Chemie Luers GmbH & Co KG社製）。
ＴＥＡ：トリエタノールアミン
Abbreviations for each component in Table 1 are as follows.
TTHA: 6,6 ′, 6 ″-(1,3,5-triazine-2,4,6-triyltriimino) trihexanoic acid (Triazine-tri-carboxylic-acid TC, Additive- Chemie Luers GmbH & Co KG).
TEA: Triethanolamine
２．硬水安定性試験
２−１．耐カルシウム硬水試験
所定量の塩化カルシウムを水で溶かして、ＣａＣＯ３換算で１００、２００、３００、４００および５００ｐｐｍのカルシウム硬水を調製した。次に、前記硬水９０ｍｌに実施例１〜５および比較例１，２で得た各油剤（原液）１０ｍｌを添加して５日間静置した。試験終了後の各試験液を目視観察し、沈殿の発生の程度を以下の評価基準に基づいて評価した。表２に結果を示す。
2. Hard water stability test 2-1. Calcium Hard Water Resistance A predetermined amount of calcium chloride was dissolved in water to prepare 100, 200, 300, 400 and 500 ppm calcium hard water in terms of CaCO 3 . Next, 10 ml of each oil agent (stock solution) obtained in Examples 1 to 5 and Comparative Examples 1 and 2 was added to 90 ml of the hard water and allowed to stand for 5 days. Each test solution after the test was visually observed, and the degree of precipitation was evaluated based on the following evaluation criteria. Table 2 shows the results.
（評価基準）
Ｐａｓｓ：沈殿が発生していない
Ｆｅｗ：沈殿がわずかに発生した
×：沈殿が発生した
(Evaluation criteria)
Pass: No precipitation has occurred Few: Precipitation has slightly occurred x: Precipitation has occurred
２−２．耐マグネシウム硬水試験
所定量の塩化マグネシウムを水で溶かして、ＭｇＣＯ３換算で５００ｐｐｍと１０００ｐｐｍのマグネシウム硬水を調製した。次に、前記硬水９０ｍｌに実施例１〜５および比較例１，２で得た各油剤（原液）１０ｍｌを添加して５日間静置した。試験終了後の各試験液を目視観察し、沈殿の発生の程度を上述した評価基準に基づいて評価した。表３に結果を示す。
2-2. Magnesium Hard Water Resistance Test A predetermined amount of magnesium chloride was dissolved in water to prepare 500 ppm and 1000 ppm magnesium hard water in terms of MgCO 3 . Next, 10 ml of each oil agent (stock solution) obtained in Examples 1 to 5 and Comparative Examples 1 and 2 was added to 90 ml of the hard water and allowed to stand for 5 days. Each test solution after completion of the test was visually observed, and the degree of precipitation was evaluated based on the evaluation criteria described above. Table 3 shows the results.
表２の実施例１と比較例１，２を比べると、ＴＴＨＡはドデカン二酸やイソデカン酸に比べてカルシウム濃度の高い硬水に対して安定性が高いことが確認された。また、実施例２〜４と比較例１、さらに実施例５と比較例２を比べると、ドデカン二酸やイソデカン酸にＴＴＨＡを配合すると、前記硬水に対する安定性が飛躍的に向上することが分かった。 When Example 1 in Table 2 was compared with Comparative Examples 1 and 2, it was confirmed that TTHA was more stable against hard water having a higher calcium concentration than dodecanedioic acid and isodecanoic acid. In addition, when Examples 2 to 4 and Comparative Example 1 were compared, and Example 5 and Comparative Example 2 were compared, it was found that when TTHA was added to dodecanedioic acid or isodecanoic acid, the stability against the hard water was dramatically improved. It was.
表３の実施例１と比較例１，２を比べると、ＴＴＨＡはドデカン二酸やイソデカン酸に比べてマグネシウム濃度の高い硬水に対して安定性が高く、１０００ｐｐｍ程度でも十分に安定であることが確認された。また、実施例２〜４と比較例１、さらに実施例５と比較例２を比べると、ドデカン二酸やイソデカン酸にＴＴＨＡを配合すると、前記硬水に対する安定性が向上することが分かり、上述したカルシウム硬水に対する試験結果と同じ傾向を示した。 Comparing Example 1 with Comparative Examples 1 and 2 in Table 3, TTHA is highly stable against hard water having a high magnesium concentration compared to dodecanedioic acid and isodecanoic acid, and is sufficiently stable even at about 1000 ppm. confirmed. Further, when Examples 2 to 4 and Comparative Example 1 were compared, and Example 5 and Comparative Example 2 were compared, it was found that when TTHA was added to dodecanedioic acid or isodecanoic acid, the stability against the hard water was improved. It showed the same tendency as the test result for calcium hard water.
３．防錆試験
鋳鉄（ＦＣ２５０）のドリル切削屑約２ｇを、濾紙を敷いたシャーレに広げ、実施例１〜５および比較例１，２で得た油剤（原液）を水で希釈した２重量％の試験液２ｍｌを前記切屑屑全体に振り掛け、次いでシャーレに蓋をして２日間静置した。試験終了後の切削屑を目視観察し、発錆の度合いを以下の評価基準に基づいて評価した。表４に結果を示す。
3. Rust prevention test About 2 g of drill cutting waste of cast iron (FC250) was spread on a petri dish with filter paper, and the oil agent (stock solution) obtained in Examples 1 to 5 and Comparative Examples 1 and 2 was diluted with water. 2 ml of the test solution was sprinkled over the entire chip scraps, and then the petri dish was covered and allowed to stand for 2 days. The cutting waste after the test was visually observed, and the degree of rusting was evaluated based on the following evaluation criteria. Table 4 shows the results.
（評価基準）
Ａ：錆の発生なし
Ｂ：錆面積が切削屑全体の１０％未満
Ｃ：錆面積が切削屑全体の１０％以上２０％未満
Ｄ：錆面積が切削屑全体の２０％以上５０％未満
Ｅ：錆面積が切削屑全体の５０％以上
(Evaluation criteria)
A: No generation of rust B: Rust area is less than 10% of the whole cutting waste C: Rust area is 10% or more and less than 20% of the whole cutting waste D: Rust area is 20% or more and less than 50% of the entire cutting waste E: Rust area is 50% or more of the whole cutting waste
表４の実施例１と比較例１，２を比べると、ＴＴＨＡの防錆性は、ドデカン二酸やイソデカン酸に比べて同程度かやや低い結果となったが、実施例２〜４と比較例１、さらに実施例５と比較例２を比べると、ＴＴＨＡにドデカン二酸やイソデカン酸を配合すると、防錆性が向上することが分かった。 When comparing Example 1 of Table 4 with Comparative Examples 1 and 2, the antirust property of TTHA was similar or slightly lower than that of dodecanedioic acid or isodecanoic acid, but compared with Examples 2-4. When Example 1 and Example 5 were compared with Comparative Example 2, it was found that when dodecanedioic acid or isodecanoic acid was added to TTHA, the rust prevention property was improved.
４．腐敗試験
３００ｍｌの三角フラスコに実施例１〜５および比較例１，２で得た油剤（原液）を水で希釈した５重量％試験液を２００ｍｌ入れ、次いで後述する腐敗した乳化型切削液を２０ｍｌ、鋳鉄粉を５ｇおよび後述するＮＰ−８クラスの防錆油を５ｍｌ加えて軽く攪拌して静置した。以後、１週間毎に各試験液のｐＨ、細菌数および臭気を検査し、該検査後に前記乳化型切削液を１０ｍｌ、前記鋳鉄粉を５ｇおよび前記防錆油を５ｍｌ加えて軽く攪拌して放置する操作を繰り返した。なお、試験期間中は毎朝前記三角フラスコを軽く攪拌した。結果を表５に示す。表５において細菌数は試験液１ｍｌ当たりの菌数を示している。
4). Spoilage test Into a 300 ml Erlenmeyer flask, 200 ml of a 5 wt% test solution obtained by diluting the oils (stock solutions) obtained in Examples 1 to 5 and Comparative Examples 1 and 2 with water was added, and then 20 ml of a spoiled emulsified cutting fluid described later was added. Then, 5 g of cast iron powder and 5 ml of NP-8 class rust preventive oil described later were added and the mixture was lightly stirred and allowed to stand. Thereafter, the pH, the number of bacteria, and the odor of each test solution are inspected every week, and after the inspection, 10 ml of the emulsified cutting fluid, 5 g of the cast iron powder, and 5 ml of the rust preventive oil are added, and the mixture is allowed to stir lightly. The operation was repeated. During the test period, the Erlenmeyer flask was lightly stirred every morning. The results are shown in Table 5. In Table 5, the number of bacteria indicates the number of bacteria per 1 ml of the test solution.
（腐敗した乳化型切削液）
細菌数：８×１０８個／ｍｌ
ｐＨ：７．８６
濃度：３重量％
臭気：腐敗臭あり
（ＮＰ−８クラスの防錆油）
カルシウムスルホネート：１０重量部
鉱物油：８９．９重量部
酸化防止剤：０．１重量部
(Rotated emulsified cutting fluid)
Number of bacteria: 8 × 10 8 / ml
pH: 7.86
Concentration: 3% by weight
Odor: rot odor (NP-8 class rust preventive oil)
Calcium sulfonate: 10 parts by weight Mineral oil: 89.9 parts by weight Antioxidant: 0.1 parts by weight
表５の実施例１と比較例１を比べると、６週間後において、ＴＴＨＡはドデカン二酸に比べて耐腐敗性が高いことが確認された。このことは、実施例２〜４においてＴＴＨＡの配合量を減らしてドデカン二酸を配合すると、実施例１よりも耐腐敗性が相対的に減少することからも分かる。また、実施例１，５と比較例２を比べると、ＴＴＨＡにイソデカン酸を配合した場合に、耐腐敗性が最も向上することが確認された。 When Example 1 in Table 5 was compared with Comparative Example 1, it was confirmed that TTHA had higher spoilage resistance than dodecanedioic acid after 6 weeks. This can also be seen from the fact that when the amount of TTHA is reduced in Examples 2 to 4 and dodecanedioic acid is added, the rot resistance is relatively reduced as compared with Example 1. Further, when Examples 1 and 5 were compared with Comparative Example 2, it was confirmed that the anti-septic property was most improved when isodecanoic acid was added to TTHA.
Claims (4)
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051167A (en) * | 2009-10-28 | 2011-05-11 | 中国科学院福建物质结构研究所 | Easily and conveniently synthesized high-yield and high-performance rare-earth europium fluorescent material |
| JP2012062353A (en) * | 2010-09-14 | 2012-03-29 | Idemitsu Kosan Co Ltd | Aqueous detergent |
| WO2013134062A1 (en) * | 2012-03-08 | 2013-09-12 | The Lubrizol Corporation | Waterborne coatings, compositions, and methods thereof that provide improved corrosion protection |
| KR20190030913A (en) * | 2017-09-15 | 2019-03-25 | 주식회사다우링에너지 | Water-soluble stripper and anufacturing methodd thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2194782A (en) * | 1985-11-09 | 1988-03-16 | Ciba Geigy Ag | Additives for aqueous functional fluids |
| JPH05179243A (en) * | 1991-04-24 | 1993-07-20 | Ciba Geigy Ag | Fluid aqueous dispersion of corrosion inhibitor comprising polycarboxylic acid |
| JPH05255873A (en) * | 1992-01-18 | 1993-10-05 | Ciba Geigy Ag | Corrosion inhibiting composition |
| WO2000053701A1 (en) * | 1999-03-05 | 2000-09-14 | Castrol Limited | Lubricant composition comprising a carboxy-terminated reaction product |
| EP1041174A1 (en) * | 1999-03-30 | 2000-10-04 | Stefan Graichen | Melamine containing corrosion inhibiting composition |
| WO2003080895A1 (en) * | 2002-03-18 | 2003-10-02 | The Lubrizol Corporation | Corrosion inhibiting salts, concentrates and metal working fluids containing same |
-
2005
- 2005-07-08 JP JP2005200466A patent/JP2007016167A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2194782A (en) * | 1985-11-09 | 1988-03-16 | Ciba Geigy Ag | Additives for aqueous functional fluids |
| JPH05179243A (en) * | 1991-04-24 | 1993-07-20 | Ciba Geigy Ag | Fluid aqueous dispersion of corrosion inhibitor comprising polycarboxylic acid |
| JPH05255873A (en) * | 1992-01-18 | 1993-10-05 | Ciba Geigy Ag | Corrosion inhibiting composition |
| WO2000053701A1 (en) * | 1999-03-05 | 2000-09-14 | Castrol Limited | Lubricant composition comprising a carboxy-terminated reaction product |
| EP1041174A1 (en) * | 1999-03-30 | 2000-10-04 | Stefan Graichen | Melamine containing corrosion inhibiting composition |
| WO2003080895A1 (en) * | 2002-03-18 | 2003-10-02 | The Lubrizol Corporation | Corrosion inhibiting salts, concentrates and metal working fluids containing same |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051167A (en) * | 2009-10-28 | 2011-05-11 | 中国科学院福建物质结构研究所 | Easily and conveniently synthesized high-yield and high-performance rare-earth europium fluorescent material |
| JP2012062353A (en) * | 2010-09-14 | 2012-03-29 | Idemitsu Kosan Co Ltd | Aqueous detergent |
| US8877700B2 (en) | 2010-09-14 | 2014-11-04 | Idemitsu Kosan Co., Ltd. | Aqueous cleaning agent comprising an alkanolamine salt of at least one carboxylic acid |
| WO2013134062A1 (en) * | 2012-03-08 | 2013-09-12 | The Lubrizol Corporation | Waterborne coatings, compositions, and methods thereof that provide improved corrosion protection |
| JP2015510952A (en) * | 2012-03-08 | 2015-04-13 | ザ ルブリゾル コーポレイションＴｈｅ Ｌｕｂｒｉｚｏｌ Ｃｏｒｐｏｒａｔｉｏｎ | Aqueous coating, composition and method thereof providing improved corrosion protection |
| US9187651B2 (en) | 2012-03-08 | 2015-11-17 | The Lubrizol Corporation | Waterborne coatings, compositions, and methods thereof that provide improved corrosion protection |
| KR20190030913A (en) * | 2017-09-15 | 2019-03-25 | 주식회사다우링에너지 | Water-soluble stripper and anufacturing methodd thereof |
| KR102009640B1 (en) * | 2017-09-15 | 2019-08-12 | 주식회사 다우링에너지 | Water-soluble stripper and anufacturing methodd thereof |
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