JP2006253659A - Doping method and method of manufacturing field effect transistor - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To control a concentration of a donor impurity or an acceptor impurity in a processing object in which a doping is carried out by using an ion doping system, and to reduce a dispersion of the concentration. <P>SOLUTION: The adopted doping method comprises the steps of obtaining a dose amount D<SB>1</SB>of total ions necessary for obtaining a peak concentration Y corresponding to a variation of a proportion X of an ion from a first relational expression concerning the peak concentration Y of an impurity, in a first processing object in which a doping is carried out in a proportion X (0<X<1) of ions of a compound including the donor impurity or the acceptor impurity in total ions requested from a mass spectrum; and doping the ion to a second processing object by using materials gas used in the case of the doping and by using the dose amount of the total ions as a value of D<SB>1</SB>calculated in the above described step, and by using an acceleration voltage as a predetermined value in the case of the doping. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The invention disclosed in this specification relates to a doping method using an ion doping apparatus that does not perform mass separation of generated ions, and a method for manufacturing a field-effect transistor to which the method is applied.

  In the step of manufacturing a semiconductor element such as a field effect transistor, an ion implantation apparatus or an ion doping is performed when a donor impurity or an acceptor impurity is introduced into a semiconductor film formed on a substrate having an insulating surface or an object to be processed such as a semiconductor substrate. A device is used. The ion implantation apparatus is a mass separation type apparatus that can separate unnecessary ion species by a mass separator and irradiate only a desired ion species to an object to be processed disposed in a processing chamber. Therefore, it is possible to control the exact dose amount of the desired ion species.

On the other hand, since the ion doping apparatus does not include a mass separator, all ions (hereinafter referred to as total ions in this specification) extracted from the plasma generated by the ion source are included in the processing chamber. This is a non-mass separation type apparatus that irradiates the object to be processed disposed in the apparatus. Therefore, the dose amount is counted by total ions including not only the desired ion species but also unnecessary ion species, and it is difficult to accurately control the dose amount of the desired ion species.

Hereinafter, in this specification, an ion implantation apparatus is an apparatus provided with a mass separator, and an ion doping apparatus is defined as an apparatus not provided with a mass separator.

When phosphorus is used as the donor, for example, PH ₃ (phosphine) diluted with hydrogen, and when boron is used as the acceptor, for example, B ₂ H ₆ (diborane) diluted with hydrogen is used as the source gas. In the ion source, the source gas is separated into positive ions and electrons, that is, ionized, and plasma is generated. An ion beam is then extracted from the plasma. Since the source gas contains hydrogen as described above, a large amount of hydrogen ions are contained in the generated plasma. This hydrogen ion is an unnecessary ion species.

  In the ion doping apparatus, the dose amount is counted by total ions including hydrogen ions, so even if the dose amount of the total ions does not change, the ratio of the desired ion species in the total ions depends on the plasma state. Change. In this case, the dose amount of only the desired ion species changes.

Incidentally, in order to control the threshold voltage _Vth of a field effect transistor, when so-called channel doping is performed in which a portion where a channel region is formed is doped with boron as an impurity at a low concentration, the semiconductor substrate or the semiconductor film Therefore, it is required to precisely control the boron concentration. However, since this precise control is difficult with an ion doping apparatus, an ion implantation apparatus may be used only for the channel doping process.

Some ion doping apparatuses include a mass spectrum measuring device, and the ratio of a desired ion species can be monitored by using the ion doping apparatus. However, under the condition of doping boron at a low concentration as in channel doping, there is a problem that ions of boron compounds, that is, desired ion species are not measured by the mass spectrometer.

In the invention described in Patent Document 1, even under such a condition that impurities are doped at a low concentration, a mass spectrum measuring device (referred to as “E × B”) provided in an ion doping apparatus converts H ₃ ⁺ ions. Note that a strong peak based is measured. That is, the correlation between the intensity of the peak based on H ₃ ⁺ ions and the concentration of boron in the object measured by SIMS (secondary ion mass spectrometry) is found to control the boron dose. It is an invention to do.

However, even if the invention described in Patent Document 1 is adopted, it has been found that the boron concentration in the object to be processed is not stable and the variation is not small under the condition of doping impurities at a low concentration. Therefore, it cannot be said that the dose amount of boron could be accurately controlled, and there was a need to improve the invention.
JP 2004-39936 A

  The invention disclosed in this specification controls the concentration of donor impurities or acceptor impurities in the object to be processed after doping by a method different from the invention described in Patent Document 1, and reduces variation in the concentration. Objective. Another object of the present invention is to control the threshold voltage of a field effect transistor, for example, a thin film transistor, so as to reduce variation and to be a value within a predetermined range.

The invention disclosed in this specification is
The ratio X (0 <X <1) of the ion of the compound of the donor impurity or acceptor impurity in the total ions obtained from the mass spectrum and the amount of the donor impurity or acceptor impurity in the first object to be doped. From the first relational expression related to the peak concentration Y, a process of obtaining a total ion dose D ₁ required to obtain the peak concentration Y in response to a change in the ion ratio X;
Using a raw material gas used in the doping, the value of D ₁ to obtain the dose of total ion in the process, the acceleration voltage as a predetermined value at the time of the doping, the second treated by an ion doping apparatus And a step of doping the body with ions of a compound of the donor impurity or the acceptor impurity.

Other inventions disclosed in this specification are:
The ratio X (0 <X <1) of the ion of the compound of the donor impurity or acceptor impurity in the total ions obtained from the mass spectrum and the amount of the donor impurity or acceptor impurity in the first object to be doped. From the first relational expression related to the peak concentration Y and the second relational expression related to the threshold voltage of the field-effect transistor manufactured using the first object to be doped and the peak concentration Y A process of obtaining a total ion dose D ₁ required to obtain the threshold voltage in response to a change in the ion ratio X;
Using a raw material gas used in the doping, the value of D ₁ to obtain the dose of total ion in the process, the acceleration voltage as a predetermined value at the time of the doping, the second treated by an ion doping apparatus And a step of doping the body with ions of a compound of the donor impurity or the acceptor impurity.

In the case of a heavy doping condition using a source gas obtained by diluting a compound of a donor impurity or an acceptor impurity with hydrogen to a first concentration of 5% or more and 40% or less, the mass spectrum measuring device provided in the ion doping apparatus to be used In addition to the ion-based peak, a peak based on the ion of the impurity compound is measured. The acceptor impurity compound is, for example, B ₂ H ₆ , and the donor impurity compound is, for example, PH _{3. In} the case of B ₂ H ₆ , ions of the impurity compound are mainly B ₂ H _y ⁺ ions (y Is a positive integer). If the ion ratio X is 0.1 or more, the first concentration may be 5% or less. The first concentration is calculated from the ratio of the flow rate of the compound of donor impurities or acceptor impurities contained in the raw material gas to the flow rate of the raw material gas. The same applies to the second density described later. Flow rate ratio is paraphrased as volume ratio.

Under this heavy doping condition, a peak based on ions of a compound of a donor impurity or an acceptor impurity and a peak based on hydrogen ions are measured by the mass spectrometer. Each peak is not limited to a single peak, and a plurality of peaks may be measured. From the ratio of the peak intensity based on the ion of the impurity compound to the sum of these peak intensities, the ratio X (0 <X <1) of the ion of the impurity compound in the total ions can be obtained. For example, peaks based on H ⁺ ions, H ₂ ⁺ ions, H ₃ ⁺ ions, and B ₂ H _y ⁺ ions (y is a positive integer) are measured, and the intensity ratio of these peaks is 10: 5: 100: In the case of 50, the ratio X of B ₂ H _y ⁺ ions is 0.30. This is 50 divided by 165, which is the sum of 10, 5, 100 and 50.

As a dilution gas contained in the source gas, a rare gas such as helium or argon may be used instead of hydrogen.

Under the heavy doping conditions, even if the dose amount of the total ions is constant, the ratio X of ions of the compound of the donor impurity or the acceptor impurity in the total ions changes. This is because the state of the plasma generated in the ion source of the ion doping apparatus changes with time, that is, the state of the plasma is not stable over a long period of time.

After the ion ratio X is determined, the compound is used at a predetermined acceleration voltage using a source gas diluted with hydrogen to the same concentration as the first concentration or a second concentration lower than the first concentration. The donor impurity or acceptor impurity is doped into the first object to be processed without changing the ion doping apparatus. At that time, it is necessary to measure the dose amount D ₀ (cm ⁻² ) of the total ions. The second concentration may be 5% or more. For example, if the first concentration is 15%, the second concentration can be 7.5%. As a dilution gas contained in the source gas, a rare gas such as helium or argon may be used instead of hydrogen.

An object to be processed is an object to be doped, such as a semiconductor film or a semiconductor substrate formed over a substrate having an insulating surface. This doping is for the purpose of channel doping, for example. In this case, the above-mentioned concentration and dose amount are channel doping conditions.

Thereafter, the peak concentration Y (cm ⁻³ ) of the donor impurity or acceptor impurity in the first object to be processed is analyzed by an analysis method such as SIMS (secondary ion mass spectrometry). The peak concentration is the maximum value of the impurity concentration in a profile in which the horizontal axis represents the depth from the surface of the object to be processed and the vertical axis represents the concentration of the donor impurity or acceptor impurity. Since the peak concentration Y of the donor impurity or acceptor impurity in the first object to be processed in the plasma state in which the ion ratio X of the compound of the donor impurity or acceptor impurity is obtained varies depending on the value of X. Y = aX + b (a and b are real numbers) is obtained and is defined as “Expression 1”.

“Equation 1” holds only when the dose amount of the total ions when the first object is doped by the ion doping apparatus is a specific value, that is, D ₀ . In the dose amount D ₁ (cm ⁻² ) of arbitrary total ions, the relational expression Y = (D ₁ / D ₀ ) (aX + b) is used, and this is defined as “Expression 1 ′”. Note that D ₁ / D ₀ indicates a fraction with D ₀ as the denominator and D ₁ as the numerator.

From “Equation 1 ′”, it is possible to obtain the total ion dose D ₁ corresponding to the desired value of the peak concentration Y of the donor impurity or the acceptor impurity. The dose D ₁ is determined by an electronic computer. Then, the dose amount of total ions, corrected to the value of D ₁ obtained, without other conditions change may be performed doped second workpiece.

On the other hand, the threshold voltage V _th (V) of the field effect transistor manufactured through the doping process on the object to be processed is the peak concentration Y obtained by the analysis method such as SIMS or the square root of the peak concentration Y. It depends on. Therefore, these relational expressions V _th = cY + d or V _th = cY ^1/2 + d (where c and d are real numbers) are obtained, and this is referred to as “Expression 2”.

By substituting “Equation 1 ′” into “Equation 2”, the relational expression V _th = c (D ₁ / D ₀ ) (aX + b) + d or V _th = c (D ₁ / D ₀ ) ^1/2 (aX + b) ^1/2 + d is obtained, and the total ion dose D ₁ corresponding to the desired threshold voltage V _th can be obtained. The dose D ₁ is also determined by the electronic computer.

In ion doping apparatus used in determining the "Equation 1", and corrected to be the dose of total ion to the value of D _1, perform doping the semiconductor films or the semiconductor substrate, the semiconductor film or a semiconductor substrate A field effect transistor is manufactured using the same. In the above doping, conditions other than the dose amount are the same as those when the first object to be analyzed analyzed by an analysis method such as SIMS is doped.

By the way, when the conditions for heavy doping and channel doping are compared, the concentration of donor impurities or acceptor impurities in the source gas, for example, B ₂ H ₆ , is lower in the channel doping conditions than in the heavy doping conditions. The dose amount of total ions under the channel doping condition is lowered. Therefore, when the same ion doping apparatus is used, the source gas is introduced into the ion source of the apparatus under the heavy doping condition to generate plasma, and when doping is subsequently performed under the channel doping condition, the impurities in the introduced source gas are introduced. It is important to change the conditions such as the concentration of the compound and the dose amount of the total ions, and to stabilize the conditions after the change.

However, there is a problem that the concentration of the compound of the donor impurity or the acceptor impurity in the raw material gas takes much time to stabilize as compared with the dose amount of the total ions. In order to solve the problem, the processing steps described below can be employed.

Before doping is performed under channel doping conditions, the supply of the source gas is stopped, and the gas introduced into the ion source of the ion doping apparatus is switched to the dilution gas contained in the source gas. For example, when a material diluted with hydrogen of B ₂ H ₆ is used as the source gas, it is switched to hydrogen (preferably H ₂ concentration of 100%), and a material diluted with argon of B ₂ H ₆ is used as the source gas. If it is, switch to argon (preferably Ar concentration 100%). Then, plasma is generated in the ion source, and a first plasma process for irradiating the extracted ion beam onto the dummy substrate is performed for a predetermined time. The substrate used for the dummy substrate is a glass substrate, a silicon substrate, or the like, and is disposed on a stage in a processing chamber (chamber) to which an evacuation system is connected.

Thereafter, the supply of the gas for dilution is stopped, and the processing chamber is exhausted by the vacuum exhaust system. Then, a source gas obtained by diluting a compound of a donor impurity or an acceptor impurity to a concentration lower than the heavy doping condition is supplied to the ion source, and the dummy substrate is irradiated with an ion beam under a channel doping condition using the raw material gas. The second plasma treatment is performed for a predetermined time.

When the first plasma treatment is not performed, the second plasma treatment needs to be performed for about 2 hours in order to stabilize the concentration of the impurity compound in the source gas. By performing the first plasma treatment, the total time required for the first plasma treatment and the time required for the second plasma treatment can be made shorter than two hours.

When the second plasma treatment is completed, the dummy substrate on the stage is replaced with a first object to be analyzed by an analysis method such as SIMS, and the conditions for performing the second plasma treatment are maintained. The object to be processed is doped.

When the first plasma treatment is performed, the concentration of the donor impurity or the acceptor impurity in the processed object after doping is more varied than when only the second plasma treatment is performed without performing the first plasma treatment. As a result, variation in sheet resistance of the object to be processed can be reduced.

The following effects are obtained by the invention disclosed in this specification.
1) When a field effect transistor is manufactured, a target threshold voltage can be obtained even if an ion doping apparatus is used.
2) Variation in threshold voltage of the manufactured field effect transistor can be reduced.
3) Variation in the peak concentration of donor impurities or acceptor impurities in an object to be processed doped using an ion doping apparatus can be reduced.
4) Even when doping is performed at a low concentration such as channel doping, an ion implantation apparatus is not required, and therefore the manufacturing cost of a field effect transistor can be reduced.
5) When changing the concentration of the compound of the donor impurity or acceptor impurity in the source gas introduced into the ion doping apparatus from the first concentration to a second concentration lower than the first concentration, the second concentration after the change It becomes easy to stabilize.

(Embodiment 1)
An example of an ion doping apparatus used in the invention disclosed in this specification will be described below with reference to FIG.

FIG. 1 shows a schematic diagram of an ion doping apparatus. A gas supply system 102 that can supply a source gas such as B ₂ H ₆ diluted with hydrogen or a rare gas (such as helium or argon), hydrogen, and a rare gas is connected to the gas inlet 101. Source gas, hydrogen, or a rare gas is introduced from the gas supply system 102 to the plasma generation unit 104 of the ion source 103, and plasma is generated in the plasma generation unit 104. The ion source 103 further includes a discharge generating means 106 and an electrode portion 107 having an extraction electrode, an acceleration electrode, a deceleration electrode, and a ground electrode. The electrode portion 107 is also referred to as an extraction electrode system, and each of the four electrodes has a plurality of holes through which the ion beam 108 can pass. In FIG. 1, V _EXT represents an extraction voltage, V _ACC represents an acceleration voltage, and V _DEC represents a deceleration voltage.

The discharge generating means 106 shown in FIG. 1 is a filament made of a high melting point material that can withstand a high temperature of 2000 ° C. or more typified by tungsten, and is provided so as to be exposed in the plasma generation unit 104. The number of filaments is not limited to one shown in FIG. A voltage is applied to the filament from a DC power source 105 to generate a DC discharge, thereby ionizing the gas introduced into the plasma generating unit 104 to generate plasma. Instead of the filament as described above, a method may be used in which plasma is generated by generating a high frequency discharge using a flat plate electrode or an antenna having a specific shape connected to a high frequency (RF) power source.

The ion beam 108 is extracted from the plasma generated in the plasma generation unit 104 and accelerated, and is irradiated onto the substrate 111 on the stage 110 provided in the processing chamber 109. The stage 110 has a structure that can be moved together with the substrate 111 in a predetermined direction, and can accommodate a large substrate.

In the processing chamber 109, a mass spectrum measuring device 113 and a dose measuring means 114 are provided behind (downward) the stage 110. Since the stage 110 is movable as described above, the ion beam 108 can be incident on the mass spectrum measuring device 113 and the dose measuring means 114 without being blocked by the stage 110. Further, a vacuum exhaust system 112 using a known vacuum pump such as a turbo molecular pump is connected to the processing chamber 109. A means for connecting the load lock chamber directly or indirectly to the processing chamber 109 and automatically transferring the substrate 111 between the load lock chamber and the processing chamber 109 may be provided.

Next, a specific example of the process of deriving the above-described “formula 1”, “formula 1 ′”, and “formula 2” using the ion doping apparatus shown in FIG. 1 is shown below.

A source gas introduced into the plasma generating unit 104 is diluted with B ₂ H ₆ to a concentration of 5% with hydrogen, and the total ion dose is adjusted to 2.0 × 10 ¹⁶ cm ⁻² and the acceleration voltage is adjusted to 80 kV. To do. These values correspond to heavy dope conditions. Under this condition, the ratio X of boron compound ions in the total ions is obtained from the measurement results obtained by the mass spectrum measuring device 113.

FIG. 2 is a graph showing a measurement result by the mass spectrum measuring device 113, that is, a mass spectrum. The horizontal axis represents ion mass, and the vertical axis represents intensity. Peaks based on H ⁺ ions, H ₂ ⁺ ions, H ₃ ⁺ ions, and B ₂ H _y ⁺ ions (y is a positive integer) are measured in order from the smallest mass. In addition to these peaks, peaks based on BH _x ⁺ ions (x is a positive integer) may be measured. However, since the amount of BH _x ⁺ ions is extremely small compared to the amount of B ₂ H _y ⁺ ions, the peak based on BH _x ⁺ ions is very small compared to the peak based on B ₂ H _y ⁺ ions, and is quantitative. Not suitable for. From the result shown in FIG. 2, the ratio X of B ₂ H _y ⁺ ions is calculated to be 0.174.

FIG. 3 is a graph showing a measurement result (mass spectrum) by the mass spectrum measuring device 113 shown as a comparative example. A source gas obtained by diluting B ₂ H ₆ with hydrogen to a concentration of 1% is used. The total ion dose is 1.3 × 10 ¹⁴ cm ⁻² and the acceleration voltage is 25 kV. These values correspond to channel doping conditions. Under these conditions, as is clear from FIG. 3, only a peak based on H ₂ ⁺ ions and a peak based on H ₃ ⁺ ions are measured, and based on the B ₂ H _y ⁺ ions that are prominent in FIG. The peak is almost indistinguishable. Therefore, the ratio X of B ₂ H _y ⁺ ions cannot be obtained accurately from the results shown in FIG.

The amount of _B 2 _H ^{y +} ions in total ions, since a large dependence on the concentration of _B 2 _{H 6} in the raw material _gas, to obtain the percentage X of B _{2 H} ^{y +} ions with high accuracy, the raw material If the concentration of B ₂ H ₆ in the gas is 1%, it is impossible, and a concentration of 5% or more is sufficient. However, since B ₂ H ₆ is a dangerous gas, a gas having a B ₂ H ₆ concentration exceeding 40% is not usually used as a raw material gas. Further, the concentration of B ₂ H ₆ in the raw material gas does not necessarily have to be 5% or more, and the ratio X of B ₂ H _y ⁺ ions obtained from the mass spectrum is 0.1 or more, for example, 0.174 or more. If so, it may be 5% or less.

4 and 5 are graphs showing the results (mass spectrum) measured under the same conditions as in FIG. 2. When the ratio X of B ₂ H _y ⁺ ions is calculated from the results shown in FIG. When the ratio X of B ₂ H _y ⁺ ions is calculated from the result shown in FIG. Furthermore, by performing multiple measurements by mass spectrometry instrument, was determined the ratio X of the various B ₂ H _y ⁺ ions, the value of X is a result of changes in the range of 0.1 to 0.4 It was.

2, 4 and 5 show the results of measurement on different days for one week or more. On the other hand, even when the mass spectrum measurement device 113 measured a plurality of times on the same day, the ratio X of B ₂ H _y ⁺ ions did not change. This result shows that the plasma state generated in the plasma generation unit 104 of the ion doping apparatus does not change on the same day, but the plasma state changes after one week or more.

Next, the source gas was changed to B ₂ H ₆ diluted to 1% concentration with hydrogen, the total ion dose was changed to 1.3 × 10 ¹⁴ cm ⁻² , and the acceleration voltage was changed to 25 kV. A glass substrate on which a semiconductor film containing silicon as a main component is formed as a substrate 111 on the stage 110, and the semiconductor film is doped. In this doping step, a plasma state in which the ratio X of B ₂ H _y ⁺ ions is given is maintained. After doping, in this embodiment, the peak concentration Y (cm ⁻³ ) of boron in the semiconductor film is analyzed by SIMS.

FIG. 6 is a depth direction distribution of boron concentration analyzed by SIMS, where the horizontal axis represents depth (nm) and the vertical axis represents boron concentration (cm ⁻³ ). In FIG. 6, the range from the surface to a depth of about 20 nm does not reflect the actual boron concentration distribution due to measurement problems. Therefore, the maximum concentration of boron in a region deeper than 20 nm is defined as the peak concentration Y.

FIG. 7 is the result of plotting the value of Y corresponding to the value of X, with the horizontal axis representing the ratio X of B ₂ H _y ⁺ ions in total ions and the vertical axis representing the peak concentration Y of boron. From this result, when the relationship between X and Y is linearly approximated, a relational expression Y = 3.1 × 10 ¹⁸ X−2.5 × 10 ¹⁷ is derived. This corresponds to “Formula 1”. Further, the relational expression Y = (D ₁ /(1.3×10 ¹⁴ )) (3.1 × 10 ¹⁸ X−2.5 × 10 ¹⁷ ) is obtained from “Formula 1”, and this is “Formula 1 ′”. It corresponds to. D ₁ is a dose amount of arbitrary total ions.

Next, a semiconductor film mainly composed of silicon doped with channel under the same conditions as those after the change of the concentration of B ₂ H ₆ in the source gas, the dose of total ions, and the acceleration voltage is changed to the active layer (channel N channel type thin film transistor having a channel length L, a channel width W, and an LDD length of a predetermined size and a gate insulating film having a predetermined thickness is used, and the threshold voltage V _th (V) is set. taking measurement. The LDD length is the length in the same direction as the channel length in the LDD region. Note that the LDD region is not necessarily provided. In this embodiment mode, the channel length is 1 μm, the channel width is 20 μm, the LDD length is 0.2 μm, and the thickness of the gate insulating film is 40 nm. Further, a SiO _x N _y film (x>y> 0) is used as the gate insulating film. A silicon oxide film may be used as the gate insulating film.

In FIG. 8, the vertical axis represents the threshold voltage _Vth of the N-channel thin film transistor, and the horizontal axis represents the peak concentration Y of boron in the semiconductor film mainly composed of silicon which is the active layer of the N-channel thin film transistor. It is the result of plotting the value of _Vth corresponding to Y. From this result, when the relationship between V _th and Y is linearly approximated, a relational expression V _th = 2.1 × 10 ⁻¹⁸ Y−0.11 is derived. This corresponds to “Formula 2”.

In FIG. 9, the vertical axis represents the threshold voltage _{Vth of} an N-channel thin film transistor, and the horizontal axis represents the square root of the peak concentration Y of boron in a semiconductor film mainly composed of silicon which is the active layer of the N-channel thin film transistor. And the value of _Vth corresponding to the square root of Y is plotted. From this result, when the relationship between V _th and the square root of Y is linearly approximated, a relational expression V _th = 3.7 × 10 ⁻⁹ Y ^1/2 −1.7 is derived. This also corresponds to “Formula 2”. The correlation coefficient of the relational expression shown in FIG. 9 is not so different from the correlation coefficient of the relational expression shown in FIG.

By the way, in a MOS structure in which a metal, an oxide, and a semiconductor are stacked, the threshold voltage at which the conductivity type of the semiconductor surface is inverted is the acceptor impurity concentration (cm) in the semiconductor when the semiconductor is P-type. It is known that it is proportional to the square root of ^-3 ). In the case of N-type, it is proportional to the square root of the concentration (cm ⁻³ ) of the donor impurity in the semiconductor. Considering this, it is desirable to select the relational expression derived from FIG. However, when the relational expression derived from FIG. 8 is compared with the relational expression derived from FIG. 9, there is no significant difference between the two in the range where the peak concentration Y of boron is high, for example, 5 × 10 ¹⁷ cm ⁻³ or more. .

As described above, relational expressions corresponding to “Expression 1”, “Expression 1 ′”, and “Expression 2” are obtained.

(Embodiment 2)
In the case where an N-channel thin film transistor is manufactured using an ion doping apparatus in the channel doping process, the threshold voltage V _th of the N-channel thin film transistor is set to a desired value (in this embodiment, +1.0 V). The process for obtaining the dose amount of total ions when performing channel doping, which is necessary for the approach, will be described below.

From “Formula 2” obtained in Embodiment 1 of the present specification, it is necessary to obtain a threshold voltage of +1.0 V in a semiconductor film containing silicon as a main component (used as an active layer). The peak concentration Y of boron is 5.3 × 10 ¹⁷ cm ⁻³ .

When the ratio X of B ₂ H _y ⁺ ions is 0.30, X = 0.30 and Y = 5.3 × 10 ¹⁷ cm ⁻³ are applied to “Formula 1 ′” obtained in the first embodiment. Then, D ₁ = 1.0 × 10 ¹⁴ cm ⁻² is derived. From this result, the total ion dose D ₁ when performing channel doping necessary for setting the threshold voltage V _th of the N-channel thin film transistor to +1.0 V is 1.0 × 10 ¹⁴ cm ^−2. It can be seen that it is. Note that the source gas used in the channel doping step is B ₂ H ₆ used in deriving “Formula 1”, “Formula 1 ′”, and “Formula 2” in Embodiment 1 at a concentration of 1% with hydrogen. It shall be diluted.

Although X = 0.30 was calculated as an example, the total ion dose D ₁ required to obtain a desired threshold voltage varies depending on the ratio X of B ₂ H _y ⁺ ions. Therefore, the threshold voltage can be brought close to the target value by correcting the dose amount of the total ions as the ratio X of B ₂ H _y ⁺ ions changes.

Also, by substituting “Equation 1 ′” into “Equation 2”, the relational expression V _th = 2.1 × 10 ⁻¹⁸ (D ₁ /(1.3×10 ¹⁴ )) (3.1 × 10 ¹⁸ X −2.5 × 10 ¹⁷ ) −0.11 or V _th = 3.7 × 10 ⁻⁹ (D ₁ /(1.3×10 ¹⁴ )) ^1/2 (3.1 × 10 ¹⁸ X-2. 5 × 10 ¹⁷ ) ^1/2 -1.7 is determined. Using this relationship, by specifying the values of X and V _th, it is possible to derive a D _1.

An ion doping apparatus may be accompanied by an electronic computer that can control the apparatus. In this electronic computer, the above relational expression obtained by substituting "Formula 1 '" and "Formula 2" or "Formula 1'" into "Formula 2" is stored, and the target threshold voltage _Vth is input. Then, the total ion dose D ₁ necessary for obtaining the threshold voltage may be calculated. Further, it may be possible to automatically correct the dose amount of the total ions so as to be the calculated value by the output signal from the electronic computer.

The electronic computer is connected to a mass spectrum measuring device, and calculates a ratio X of a desired ion species (B ₂ H _y ^{+ in the} present embodiment) in the total ions based on the measurement result by the mass spectrum measuring device. can do. Then, depending on the value of the calculated X, calculation results of the dose D ₁ of the required total ion is adapted to change.

The desired threshold voltage is not limited to + 1.0V. In the case of an N-channel thin film transistor, by setting the desired threshold voltage to a value in the range of +0.3 V to +1.5 V, preferably +0.5 V to +1.0 V, excellent electrical characteristics and high yield are achieved. be able to.

(Embodiment 3)
After channel doping is performed on a semiconductor film containing silicon as a main component using an ion doping apparatus, the peak concentration of boron in the semiconductor film obtained from the analysis result by SIMS is set to a desired value (this embodiment A process for obtaining a dose amount of total ions at the time of doping, which is necessary to approach 4.4 × 10 ¹⁷ cm ^{−3 in the} embodiment, will be described below.

When the ratio X of B ₂ H _y ⁺ ions is 0.30, calculation is performed by applying Y = 4.4 × 10 ¹⁷ cm ⁻³ to “Equation 1 ′” obtained in the first embodiment. ₁ = 8.4 × 10 ¹³ cm ⁻² is derived. From this result, the total ion dose D ₁ required for the boron peak concentration in the semiconductor film containing silicon as the main component to be 4.4 × 10 ¹⁷ cm ⁻³ is 8.4 × 10 ¹³ cm. ^-2 . The source gas used in the channel dope process was obtained by diluting B ₂ H ₆ with hydrogen to a concentration of 1% used in deriving “Formula 1” and “Formula 1 ′” in Embodiment 1. And

Although X = 0.30 was calculated as an example, the total ion dose D ₁ necessary to obtain a desired boron peak concentration varies depending on the ratio X of B ₂ H _y ⁺ ions. Therefore, as the ratio X of B ₂ H _y ⁺ ions changes, the peak concentration of boron in the semiconductor film containing silicon as a main component is brought closer to a desired value by correcting the dose amount D ₁ of total ions. be able to.

When “Expression 1 ′” is stored in an electronic computer attached to the ion doping apparatus and a desired peak concentration Y of boron is input, the dose amount D ₁ of total ions necessary to obtain the concentration can be calculated. May be. Further, it may be possible to automatically correct the dose amount of the total ions so as to be the calculated value by the output signal from the electronic computer.

Based on the process described in the present embodiment, the channel doping is performed while correcting the dose amount of the total ions necessary for the boron peak concentration to be 4.4 × 10 ¹⁷ cm ^−3. 10 were produced. And about the produced sample, the peak concentration of boron was analyzed by SIMS. In the channel doping process, the source gas used is B ₂ H ₆ diluted with hydrogen to a concentration of 1%, and the acceleration voltage is 25 kV. As a result, three samples having a boron peak concentration in the range of 3 × 10 ¹⁷ cm ⁻³ or more and less than 4 × 10 ¹⁷ cm ⁻³ are 4 × 10 ¹⁷ cm ⁻³ or more and less than 5 × 10 ¹⁷ cm ⁻³ . There were six samples in the range, and one sample was in the range of 5 × 10 ¹⁷ cm ⁻³ or more and less than 6 × 10 ¹⁷ cm ⁻³ .

On the other hand, ten samples were prepared by performing channel doping on a semiconductor film containing silicon as a main component using an ion doping apparatus by a conventional method, and the peak concentration of boron was analyzed by SIMS. In the channel doping process, the source gas used is B ₂ H ₆ diluted with hydrogen to a concentration of 1%, and the acceleration voltage is 25 kV. Further, the dose amount of total ions is fixed to 1 × 10 ¹⁴ cm ⁻² . As a result, three samples having a boron peak concentration in the range of 2 × 10 ¹⁷ cm ⁻³ or more and less than 3 × 10 ¹⁷ cm ⁻³ are 3 × 10 ¹⁷ cm ⁻³ or more and less than 4 × 10 ¹⁷ cm ⁻³ . Three samples are in the range, 5 × 10 ¹⁷ cm ⁻³ or more and less than 6 × 10 ¹⁷ cm ⁻³ Two samples are in the range, 6 × 10 ¹⁷ cm ⁻³ or more and less than 7 × 10 ¹⁷ cm ⁻³ There was one sample in the range, one sample in the range of 8 × 10 ¹⁷ cm ⁻³ or more and less than 9 × 10 ¹⁷ cm ⁻³ .

Comparing both results, it is clear that the variation in the peak concentration of boron can be made smaller and the value close to the desired peak concentration of boron can be obtained by following the present embodiment than the conventional method.

(Embodiment 4)
In the first embodiment of the present specification, a process performed when the source gas used is changed from a 5% B ₂ H ₆ concentration to a 1% concentration will be described below.

The supply of the source gas (B ₂ H ₆ diluted to 5% with hydrogen) to the plasma generation unit 104 of the ion doping apparatus shown in FIG. 1 is stopped, and the supplied gas is switched to hydrogen. Then, a dummy process is performed for one hour by generating hydrogen plasma and irradiating the dummy substrate disposed on the stage 110 in the processing chamber 109 with the ion beam 108 extracted through the electrode unit 107. The dummy substrate may be either a glass substrate or a silicon substrate. At that time, the dose is set to 3 × 10 ¹⁵ cm ⁻² and the acceleration voltage is set to 50 kV.

Thereafter, the supply of hydrogen to the plasma generation unit 104 is stopped, and the inside of the processing chamber 109 is exhausted by the vacuum exhaust system 112 for one hour. Subsequently, a source gas obtained by diluting B ₂ H ₆ with hydrogen to 1% is supplied to the plasma generation unit 104, plasma is generated, and a dummy process is performed to irradiate the dummy substrate with the ion beam 108 extracted through the electrode unit 107. Perform for 30 minutes. At this time, the dose amount of total ions is set to 1.3 × 10 ¹⁴ cm ⁻² and the acceleration voltage is set to 25 kV.

Thereafter, the dummy substrate on the stage 110 is replaced with a glass substrate on which a semiconductor film containing silicon as a main component is formed. Doping is performed on the semiconductor film without changing conditions such as source gas, total ion dose, and acceleration voltage.

In this embodiment, the time required for the dummy process before doping the semiconductor film actually is only 1 hour 30 minutes.

A process for manufacturing a thin film transistor by applying the invention disclosed in this specification will be described below.

As shown in FIG. 10A, a base layer 902 is formed over a substrate 901 having an insulating surface. The base layer 902 includes a plurality of films and can have a structure including any two or more of a silicon nitride film containing oxygen, a silicon oxide film containing nitrogen, a silicon oxide film, and a silicon nitride film. A film mainly composed of a refractory metal (eg, tungsten) having a melting point of 2000 ° C. or higher between the substrate 901 and the base layer 902 or between any two films constituting the base layer 902, and the refractory metal One or both of the films mainly composed of the above compound can be further provided.

A semiconductor film containing silicon as a main component, for example, a crystalline or amorphous silicon film is formed over the base layer 902, and a pattern 903 having a predetermined shape is formed from the semiconductor film by a photolithography process.

Channel doping is performed on the pattern 903 using an ion doping apparatus as shown in FIG. When channel doping is performed, the source gas used is B ₂ H ₆ diluted with hydrogen to a concentration of 1%, and the acceleration voltage is 25 kV. The dose amount of the total ions is set to a value obtained according to Embodiment 2 or Embodiment 3 of the present specification. By applying the invention disclosed in this specification when setting the dose amount of total ions, a desired peak concentration of boron and a desired threshold voltage can be easily obtained.

After performing the channel doping on the semiconductor film before forming the pattern 903, the pattern 903 may be formed by a photolithography process.

After that, as shown in FIG. 10B, a gate insulating film 904 is formed so as to cover the pattern 903. Further, a conductive layer is formed over the gate insulating film 904. This conductive layer is composed of a plurality of films, and can have a structure having a metal film such as titanium, niobium, tantalum, tungsten, molybdenum, chromium, aluminum, copper, etc. In addition to the metal film, conductive metal nitride It can be set as the structure which has a physical film. Further, a gate electrode 905 having a predetermined shape is formed from this conductive layer by a photolithography process.

Next, phosphorus is doped into the hatched portion of the pattern 903 using an ion doping apparatus with the gate electrode 905 as a mask. At this time, the source gas used is PH ₃ diluted with hydrogen to a concentration of 5%, the dose amount of total ions is 2.5 × 10 ¹³ cm ⁻² , and the acceleration voltage is 80 kV. In this doping, the invention disclosed in this specification can be applied so that the total ion dose can be set so that the peak concentration of phosphorus in the pattern 903 becomes a desired value.

An insulating layer for forming a sidewall is formed so as to cover at least the side surface of the gate electrode 905 and over the gate insulating film 904. This insulating layer can have a structure including one or both of a silicon oxide film and a silicon oxide film containing nitrogen. Then, anisotropic etching is performed on this insulating layer to selectively form a sidewall 906 shown in FIG.

Using the gate electrode 905 and the side wall 906 as a mask, phosphorus is doped again. At this time, the source gas used is PH ₃ diluted with hydrogen to a concentration of 5%, the total ion dose is 3.0 × 10 ¹⁵ cm ⁻² , and the acceleration voltage is 20 kV. As a result, in the pattern 903, the region overlapping with the sidewall 906 is prevented from being doped with phosphorus, so that the source region (drain region) 907 and the drain region (source region) 908, and the LDD region (low-concentration impurity region) 909 and An LDD region (low concentration impurity region) 910 is formed in the pattern 903. A region between the LDD region (low concentration impurity region) 909 and the LDD region (low concentration impurity region) 910 below the gate electrode 905 in the pattern 903 is a channel formation region.

Next, as illustrated in FIG. 10D, an interlayer insulating layer 911 is formed. The interlayer insulating layer 911 includes a plurality of films and can have a structure including any two or more of a silicon nitride film containing oxygen, a silicon oxide film containing nitrogen, a silicon oxide film, and a silicon nitride film.

The interlayer insulating layer 911 and the gate insulating film 904 are anisotropically etched to form contact holes that expose portions of the source region (drain region) 907 and the drain region (source region) 908. After that, a wiring 912 and a wiring 913 are formed over the interlayer insulating layer 911. The wiring 912 and the wiring 913 can be formed of a plurality of films each including a metal-based film or a metal compound film exhibiting conductivity. Each of the wiring 912 and the wiring 913 is electrically connected to one of a source region (drain region) 907 and a drain region (source region) 908 through a contact hole.

Through the steps described above, an N-channel thin film transistor having a predetermined length for a channel length, a channel width, and an LDD length and a predetermined thickness for a gate insulating film can be manufactured.

Schematic of an ion doping apparatus. The figure showing the measurement result by a mass spectrum measuring device. The figure showing the measurement result by the mass spectrum measuring device shown as a comparative example. The figure showing the measurement result by a mass spectrum measuring device. The figure showing the measurement result by a mass spectrum measuring device. The figure showing the depth direction distribution of the density | concentration of the boron analyzed by SIMS. Shows the relationship between B ₂ H _y ⁺ peak concentration of boron in terms of proportions and channel doping ions in the total ion under the conditions of heavy doping. The figure showing the relationship between the threshold voltage of an N-channel thin film transistor and the peak concentration of boron in an active layer. The figure showing the relationship between the threshold voltage of an N-channel thin film transistor and the square root of the peak concentration of boron in the active layer. 10A and 10B illustrate a manufacturing process of a thin film transistor.

Explanation of symbols

DESCRIPTION OF SYMBOLS 101 Gas inlet 102 Gas supply system 103 Ion source 104 Plasma generation part 105 Power supply 106 Discharge generation means 107 Electrode part 108 Ion beam 109 Processing chamber 110 Stage 111 Substrate 112 Vacuum exhaust system 113 Mass spectrum measuring instrument 114 Dose amount measurement means 901 Substrate 902 Base layer 903 Pattern 904 Gate insulating film 905 Gate electrode 906 Side wall 907 Source region (drain region)
908 Drain region (source region)
909 LDD region (low concentration impurity region)
910 LDD region (low concentration impurity region)
911 Interlayer insulating layer 912 Wiring 913 Wiring

Claims (12)

The ratio X (0 <X <1) of the ion of the compound of the donor impurity or acceptor impurity in the total ions obtained from the mass spectrum and the amount of the donor impurity or acceptor impurity in the first object to be doped. From the first relational expression related to the peak concentration Y, a process of obtaining a total ion dose D ₁ required to obtain the peak concentration Y in response to a change in the ion ratio X;
Using a first source gas, the value of D ₁ to obtain the dose of total ion in the process, the acceleration voltage as the predetermined value, the donor impurity or an acceptor impurity to the second object to be processed by an ion doping apparatus A process of doping ions of the compound of
The first relational expression is
In the ion doping apparatus, plasma is generated using a second source gas diluted to a first concentration of 5% or more and 40% or less with a dilution gas in which the compound of the donor impurity or the acceptor impurity is hydrogen or a rare gas. And obtaining the ion ratio X from the mass spectrum,
The first source gas diluted with the diluting gas to the same concentration as the first concentration or a second concentration lower than the first concentration is used, the total ion dose is D ₀ , and the acceleration voltage is As the predetermined value, the ion doping apparatus is used to dope the ions of the compound of the donor impurity or acceptor impurity into the first object to be processed, and the peak concentration Y in the first object to be analyzed is analyzed. By
A doping method characterized by being obtained as Y = (D ₁ / D ₀ ) (aX + b) where a and b are real numbers. The ratio X (0 <X <1) of the ion of the compound of the donor impurity or acceptor impurity in the total ions obtained from the mass spectrum and the amount of the donor impurity or acceptor impurity in the first object to be doped. From the first relational expression related to the peak concentration Y and the second relational expression related to the threshold voltage of the field-effect transistor manufactured using the first object to be doped and the peak concentration Y A process of obtaining a total ion dose D ₁ required to obtain the threshold voltage in response to a change in the ion ratio X;
Using a first source gas, the value of D ₁ to obtain the dose of total ion in the process, the acceleration voltage as the predetermined value, the donor impurity or an acceptor impurity to the second object to be processed by an ion doping apparatus A process of doping ions of the compound of
The first relational expression is
In the ion doping apparatus, plasma is generated using a second source gas diluted to a first concentration of 5% or more and 40% or less with a dilution gas in which the compound of the donor impurity or the acceptor impurity is hydrogen or a rare gas. And obtaining the ion ratio X from the mass spectrum,
The first source gas diluted with the diluting gas to the same concentration as the first concentration or a second concentration lower than the first concentration is used, the total ion dose is D ₀ , and the acceleration voltage is As the predetermined value, the ion doping apparatus is used to dope the ions of the compound of the donor impurity or acceptor impurity into the first object to be processed, and the peak concentration Y in the first object to be analyzed is analyzed. By
When a and b are real numbers, Y = (D ₁ / D ₀ ) (aX + b) is obtained,
The second relational expression, when said threshold voltage is _{V th,} c and d and _real, doping method characterized in that is obtained as V th ^{= cY 1/2} + d. In claim 1 or claim 2,
The doping method, wherein the peak concentration Y is analyzed by secondary ion mass spectrometry (SIMS). In any one of Claims 1 thru | or 3,
During the change from the second source gas to the first source gas, a plasma processing is performed on the dummy substrate with a plasma of the dilution gas for a predetermined time. In any one of Claims 1 thru | or 4,
The doping method, wherein the acceptor impurity compound is B ₂ H ₆ (diborane), and the acceptor impurity compound ion is B ₂ H _y ⁺ ion (y is a positive integer). In any one of Claims 1 thru | or 5,
Doping method wherein the dose D _1, characterized in that the determined by the electronic computer. The ratio X (0 <X <1) of the donor impurity or acceptor impurity compound ion in the total ions obtained from the mass spectrum and the peak concentration Y of the donor impurity or acceptor impurity in the object to be doped From the first relational expression, the process of obtaining the total ion dose D ₁ required to obtain the peak concentration Y in response to the change in the ion ratio X;
Using a first source gas, D ₁ value of the dose obtained by the process of total ion, an acceleration voltage of a predetermined value, the semiconductor film or a semiconductor is formed on a substrate having an insulating surface by an ion doping apparatus Doping the substrate with ions of a compound of the donor impurity or acceptor impurity;
The first relational expression is
In the ion doping apparatus, plasma is generated using a second source gas diluted to a first concentration of 5% or more and 40% or less with a dilution gas in which the compound of the donor impurity or the acceptor impurity is hydrogen or a rare gas. And obtaining the ion ratio X from the mass spectrum,
The first source gas diluted with the diluting gas to the same concentration as the first concentration or a second concentration lower than the first concentration is used, the total ion dose is D ₀ , and the acceleration voltage is As the predetermined value, by doping ions of the compound of the donor impurity or acceptor impurity to the object to be processed by the ion doping apparatus, and analyzing the peak concentration Y in the object to be processed,
A method of manufacturing a field-effect transistor, wherein Y = (D ₁ / D ₀ ) (aX + b), where a and b are real numbers. The ratio X (0 <X <1) of the donor impurity or acceptor impurity compound ion in the total ions obtained from the mass spectrum and the peak concentration Y of the donor impurity or acceptor impurity in the object to be doped And the second relational expression regarding the threshold voltage and the peak concentration Y of the field-effect transistor manufactured using the object to be processed subjected to the doping, the ion ratio X In response to a change in the total ion dose D ₁ required to obtain the threshold voltage;
Using a first source gas, D ₁ value of the dose obtained by the process of total ion, an acceleration voltage of a predetermined value, the semiconductor film or a semiconductor is formed on a substrate having an insulating surface by an ion doping apparatus Doping the substrate with ions of a compound of the donor impurity or acceptor impurity;
The first relational expression is
In the ion doping apparatus, plasma is generated using a second source gas diluted to a first concentration of 5% or more and 40% or less with a dilution gas in which the compound of the donor impurity or the acceptor impurity is hydrogen or a rare gas. And obtaining the ion ratio X from the mass spectrum,
The first source gas diluted with the diluting gas to the same concentration as the first concentration or a second concentration lower than the first concentration is used, the total ion dose is D ₀ , and the acceleration voltage is As the predetermined value, by doping ions of the compound of the donor impurity or acceptor impurity to the object to be processed by the ion doping apparatus, and analyzing the peak concentration Y in the object to be processed,
When a and b are real numbers, Y = (D ₁ / D ₀ ) (aX + b) is obtained,
Said second relationship, the threshold voltage _{V th,} when the c and d and _real, a method for manufacturing a field effect transistor, characterized in that it is obtained as V th ^{= cY 1/2} + d. In claim 7 or claim 8,
The method of manufacturing a field effect transistor, wherein the peak concentration Y is analyzed by secondary ion mass spectrometry (SIMS). In any one of Claims 7 to 9,
A method for manufacturing a field effect transistor, characterized in that plasma processing is performed on a dummy substrate with plasma of the dilution gas for a predetermined time while changing from the second source gas to the first source gas. . In any one of Claims 7 to 10,
The acceptor impurity compound is B ₂ H ₆ (diborane), and the acceptor impurity compound ion is B ₂ H _y ⁺ ion (y is a positive integer). Method. In any one of Claims 7 to 11,
The method for manufacturing a field effect transistor wherein a dose D _1, characterized in that the determined by the electronic computer.

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