JP2005218403A - Oil and fat for microwave cooking - Google Patents
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本発明は、ジアシルグリセロール含量の高い電子レンジ調理用油脂、及び該油脂を含有する電子レンジ調理用食品に関する。 The present invention relates to a microwave cooking oil and fat having a high diacylglycerol content and a microwave cooking food containing the oil and fat.
世の中の簡便化指向を背景に、電子レンジ調理器の普及、保存加工技術の発達により、電子レンジ調理用食品が上市され、その使用量が急激な勢いで伸長している。しかし、電子レンジ調理(マイクロ波照射)を行うと、得られた食品に加熱むらが生じて、特に風味・食感の点で、満足できるものが得られていなかった。
上記課題を改善する為に、特定の糖類を含有する不凍液を使用する方法(特許文献1参照)や、起泡性を有する粉末油脂(特許文献2参照)、水酸基価とケン化価が特定範囲の油脂を用いる技術(特許文献3参照)等が開示されているが、効果が十分でない、甘味や起泡性の点で用途が限定されてしまう、電子レンジ調理時に発煙して安全性に乏しい等の問題がある。このほか、電子レンジ加熱した冷凍パンに嵩復元性を付与するために、ポリオール脂肪酸の部分エステル化物を用いる技術が開示されている(特許文献4参照)。
また、電子レンジ調理専用の特殊な容器・包装を用いた解決策が提案されている。例えば、マイクロ波吸収発熱体を用いる方法(特許文献5参照)や、内部圧力を高めた容器(特許文献6参照)が開示されている。
With the spread of microwave ovens and the development of preservation processing technology, foods for microwave oven cooking have been put on the market, and their usage is growing rapidly. However, when cooking in a microwave oven (microwave irradiation), the resulting food was unevenly heated, and a satisfactory food was not obtained particularly in terms of flavor and texture.
In order to improve the above-mentioned problems, a method using an antifreeze containing a specific saccharide (see Patent Document 1), a powdered oil and fat having foamability (see Patent Document 2), a hydroxyl value and a saponification value are in a specific range. Although the technique using the fats and oils (see Patent Document 3) is disclosed, the effect is not sufficient, the use is limited in terms of sweetness and foaming, smoke is generated during cooking in a microwave oven, and safety is poor There are problems such as. In addition, a technique using a partially esterified polyol fatty acid is disclosed in order to impart bulk restoring properties to a frozen pan heated in a microwave oven (see Patent Document 4).
In addition, a solution using a special container / packaging dedicated to microwave cooking has been proposed. For example, a method using a microwave absorption heating element (see Patent Document 5) and a container with an increased internal pressure (see Patent Document 6) are disclosed.
一方、ジアシルグリセロールには、体脂肪の蓄積を低下させ肥満を防ぐ効果や、植物ステロール類との組合せで血中コレステロールが低下することが見出されている(特許文献7〜9参照)。更に、ジアシルグリセロールを調理油用途に使用すると、調理機能、風味・食感等の点で利点のあることが知られている(特許文献10〜12参照)。
本発明の目的は、電子レンジ調理時に発煙等の心配がなく安全で、加熱むらが少なく、電子レンジ調理された食品の風味・食感が良好な、ジアシルグリセロール含量の高い電子レンジ調理用油脂及び、該油脂を含有する食品を提供することにある。 It is an object of the present invention to be safe and safe from smoke generation during cooking in a microwave oven, have little unevenness in heating, have a good flavor and texture of food cooked in a microwave oven, and have a high diacylglycerol content. Another object is to provide a food containing the oil.
電子レンジ調理時の風味・食感の劣化原因については、以下のように考えられている。すなわち、マイクロ波により、水分が局在化している部分から先に加熱されることで加熱むらが生じ、風味・食感の劣化につながっているものと考えられている。
一方、ジアシルグリセロールは、優れた健康機能があることから、食用油だけでなく、簡便な電子レンジ調理食品で使用したいという要望がある。そこで、ジアシルグリセロールを電子レンジ調理に用いたところ、著しく加熱されやすいという特異な性質を有していることを見出した。更に、ジアシルグリセロール含有電子レンジ調理食品の風味・食感が良好であることを見出し、本発明に至った。ジアシルグリセロールのこのような顕著な電子レンジ特性は、従来の油脂(トリアシルグリセロール)よりジアシルグリセロールの方が、アシル基が1分子中1つ少なく極性が高いこと、しかも、水分を吸収して保持しやすいという特徴を有していることによると考えられる。
The cause of the deterioration of flavor and texture when cooking in a microwave oven is considered as follows. That is, it is believed that heating unevenness is caused by heating from the portion where moisture is localized by microwaves, leading to deterioration of flavor and texture.
On the other hand, since diacylglycerol has an excellent health function, there is a demand to use it not only for cooking oil but also for simple microwave-cooked food. Then, when diacylglycerol was used for the microwave cooking, it discovered that it had the peculiar property that it was remarkably easy to heat. Furthermore, the present inventors have found that the flavor and texture of a microwave-cooked food containing diacylglycerol are good and have reached the present invention. This remarkable microwave characteristic of diacylglycerol is that diacylglycerol has one less acyl group per molecule and is more polar than conventional oil (triacylglycerol), and absorbs and retains moisture. This is thought to be due to the fact that it is easy to perform.
すなわち、本発明は、モノアシルグリセロールを0.1〜5重量%、トリアシルグリセロールを4.9〜84.9重量%、及び構成脂肪酸中の不飽和脂肪酸含量が80〜100重量%かつトランス酸含量が5重量%以下であるジアシルグリセロールを15〜95重量%含有する電子レンジ調理用油脂、並びに当該油脂を含有する電子レンジ調理用食品を提供するものである。 That is, the present invention provides a monoacylglycerol of 0.1 to 5% by weight, a triacylglycerol of 4.9 to 84.9% by weight, an unsaturated fatty acid content in the constituent fatty acid of 80 to 100% by weight, and a trans acid. The present invention provides a microwave cooking oil / fat containing 15 to 95% by weight of diacylglycerol having a content of 5% by weight or less, and a microwave cooking food containing the oil / fat.
本発明によれば、ジアシルグリセロール含量の高い油脂を電子レンジ調理に用いることにより、電子レンジ調理時に発煙等の心配がなく安全で、迅速に加熱されて加熱むらが少なく、電子レンジ調理食品の風味・食感を著しく向上させることができる。 According to the present invention, by using fats and oils having a high diacylglycerol content for microwave cooking, there is no concern about smoke during cooking in a microwave oven, it is safe, it is heated quickly and there is little unevenness in cooking, and the flavor of microwave cooked foods -The texture can be remarkably improved.
本発明の電子レンジ調理用油脂(A)は、ジアシルグリセロール(DG)を15〜95重量%(以下、単に%で示す)含有するが、35〜95%含有するのが好ましく、更に60〜93%、特に70〜93%、殊更80〜90%含有するのが電子レンジ調理時の加熱特性・発煙、生理効果、工業的生産性の点で好ましい。 The microwave cooking oil / fat (A) of the present invention contains diacylglycerol (DG) in an amount of 15 to 95% by weight (hereinafter simply referred to as%), preferably 35 to 95%, and more preferably 60 to 93. %, Particularly 70 to 93%, especially 80 to 90%, is preferable from the viewpoint of heating characteristics, smoke generation, physiological effects, and industrial productivity during cooking in a microwave oven.
ジアシルグリセロールは、その構成脂肪酸の80〜100%が不飽和脂肪酸であるが、好ましくは90〜100%、更に93〜100%、特に93〜98%、最も好ましくは94〜98%が不飽和脂肪酸であるのが、電子レンジ調理時の加熱特性・発煙、外観、生理効果の点でよい。ここで、この不飽和脂肪酸の炭素数は14〜24、更に16〜22であるのが好ましい。 In diacylglycerol, 80-100% of the constituent fatty acids are unsaturated fatty acids, preferably 90-100%, more preferably 93-100%, especially 93-98%, most preferably 94-98%. That is, the heating characteristics, smoke generation, appearance, and physiological effects during cooking in the microwave oven may be sufficient. Here, it is preferable that carbon number of this unsaturated fatty acid is 14-24, and also 16-22.
特に、ジアシルグリセロールを構成する脂肪酸のうち、オレイン酸の含有量は20〜65%、好ましくは25〜60%、特に30〜50%、殊更30〜45%であるのが外観、脂肪酸の摂取バランスの点で望ましい。更に生理効果の点から、ジアシルグリセロール中のジオレイルグリセロールの含有量は、45%未満、特に0〜40%が好ましい。 In particular, among fatty acids constituting diacylglycerol, the content of oleic acid is 20 to 65%, preferably 25 to 60%, particularly 30 to 50%, especially 30 to 45%. This is desirable. Furthermore, from the viewpoint of physiological effects, the content of dioleylglycerol in diacylglycerol is preferably less than 45%, particularly preferably 0 to 40%.
ジアシルグリセロールを構成する脂肪酸のうちリノール酸の含有量は15〜65%、好ましくは20〜60%、特に30〜55%、殊更35〜50%であるのが外観、脂肪酸の摂取バランスの点で望ましい。更に、酸化安定性、生理効果の点から、ジアシルグリセロール中のリノール酸/オレイン酸の含有重量比が0.01〜2.0、好ましくは0.1〜1.8、特に0.3〜1.7であることが望ましい。 Of the fatty acids constituting diacylglycerol, the linoleic acid content is 15 to 65%, preferably 20 to 60%, particularly 30 to 55%, especially 35 to 50% in terms of appearance and fatty acid intake balance. desirable. Furthermore, from the viewpoint of oxidative stability and physiological effects, the content weight ratio of linoleic acid / oleic acid in diacylglycerol is 0.01 to 2.0, preferably 0.1 to 1.8, particularly 0.3 to 1. .7 is desirable.
ジアシルグリセロールを構成する脂肪酸のうちリノレン酸の含有量は15%未満、好ましくは0〜13%、更に1〜10%、特に2〜9%であるのが外観、脂肪酸の摂取バランス、酸化安定性の点で望ましい。リノレン酸には、異性体としてα−リノレン酸とγ−リノレン酸が知られているが、α−リノレン酸が好ましい。 Of the fatty acids constituting diacylglycerol, the content of linolenic acid is less than 15%, preferably 0-13%, more preferably 1-10%, especially 2-9%. Appearance, fatty acid intake balance, oxidation stability This is desirable. As linolenic acid, α-linolenic acid and γ-linolenic acid are known as isomers, and α-linolenic acid is preferable.
ジアシルグリセロールを構成する脂肪酸のうち、飽和脂肪酸の含有量は20%以下未満であるが、0〜10%、更に0〜7%、特に2〜7%、殊更2〜6%であるのが、外観、生理効果、工業的生産性の点でよい。飽和脂肪酸としては、炭素数14〜24、特に16〜22のものが好ましく、パルミチン酸、ステアリン酸が最も好ましい。 Of the fatty acids constituting diacylglycerol, the content of saturated fatty acids is less than 20%, but it is 0-10%, more preferably 0-7%, especially 2-7%, especially 2-6%. It is sufficient in terms of appearance, physiological effect, and industrial productivity. As the saturated fatty acid, those having 14 to 24 carbon atoms, particularly 16 to 22 carbon atoms are preferable, and palmitic acid and stearic acid are most preferable.
ジアシルグリセロールを構成する脂肪酸のうち、トランス型不飽和脂肪酸の含有量は、0〜5%、好ましくは0.1〜4%であるのが風味、生理効果、外観、工業的生産性の点で好ましい。 Among the fatty acids constituting diacylglycerol, the content of trans-unsaturated fatty acids is 0 to 5%, preferably 0.1 to 4% in terms of flavor, physiological effect, appearance, and industrial productivity. preferable.
ジアシルグリセロールを構成する脂肪酸中、炭素数12以下の脂肪酸の含有量は、風味、電子レンジ調理時の発煙の点で5%以下であるのが好ましく、更に0〜2%、特に0〜1%、実質的に含まないのが最も好ましい。残余の構成脂肪酸は炭素数14〜24、特に16〜22であるのが好ましい。 In the fatty acid constituting the diacylglycerol, the content of fatty acids having 12 or less carbon atoms is preferably 5% or less, more preferably 0 to 2%, particularly 0 to 1% in terms of flavor and smoke generation during microwave cooking. Most preferably, it is substantially free. The remaining constituent fatty acids preferably have 14 to 24 carbon atoms, particularly 16 to 22 carbon atoms.
また、生理効果、保存性、工業的生産性及び風味の点から、ジアシルグリセロール中の1,3−ジアシルグリセロールの割合が50%以上、より好ましくは52〜100%、更に54〜90%、特に56〜80%であるジアシルグリセロールを用いるのが好ましい。 Further, from the viewpoint of physiological effect, storage stability, industrial productivity and flavor, the ratio of 1,3-diacylglycerol in diacylglycerol is 50% or more, more preferably 52 to 100%, further 54 to 90%, particularly It is preferred to use diacylglycerol which is 56-80%.
本発明の油脂(A)は、トリアシルグリセロール(TG)を4.9〜84.9%含有するが、4.9〜64.9%含有するのが好ましく、更に6.9〜39.9%、特に6.9〜29.9%、殊更9.8〜19.8%含有するのが生理効果、工業的生産性、外観の点で望ましい。 The fat (A) of the present invention contains 4.9-84.9% of triacylglycerol (TG), preferably 4.9-64.9%, and more preferably 6.9-39.9. %, Especially 6.9 to 29.9%, especially 9.8 to 19.8%, is desirable in terms of physiological effects, industrial productivity and appearance.
トリアシルグリセロールの構成脂肪酸はジグリセリドと同じ構成脂肪酸であることが、生理効果、工業的生産性の点で好ましい。 The constituent fatty acid of triacylglycerol is preferably the same constituent fatty acid as diglyceride from the viewpoint of physiological effect and industrial productivity.
本発明の油脂(A)は、モノアシルグリセロール(MG)を0.1〜5%含有するが、電子レンジ調理時の風味、外観、発煙、工業的生産性等の点から0.1〜2%含有するのが好ましく、更に0.1〜1.5%、特に0.1〜1.3%、殊更0.2〜1%含有するのが好ましい。電子レンジ調理により加熱されやすいという点でモノアシルグリセロールは0.1%以上必要であるが、電子レンジ調理中の発煙等安全性の点から5%以下である。モノアシルグリセロールの構成脂肪酸はジグリセリドと同じ構成脂肪酸であることが、工業的生産性の点で好ましい。 The fat or oil (A) of the present invention contains 0.1 to 5% of monoacylglycerol (MG), but it is 0.1 to 2 in terms of flavor, appearance, smoke generation, industrial productivity, etc. during microwave cooking. %, Preferably 0.1 to 1.5%, more preferably 0.1 to 1.3%, and even more preferably 0.2 to 1%. Monoacylglycerol is required to be 0.1% or more in that it is easily heated by microwave cooking, but it is 5% or less from the viewpoint of safety such as fuming during microwave cooking. The constituent fatty acid of monoacylglycerol is preferably the same constituent fatty acid as diglyceride from the viewpoint of industrial productivity.
また、本発明の油脂(A)において、遊離脂肪酸又はその塩(FFA)は、3.5%以下に低減されるのがよく、好ましくは0〜2%、更に0〜1%、特に0〜0.5%、最も好ましくは0.05〜0.2%とするのが風味、電子レンジ調理時の発煙、工業的生産性の点で好ましい。 Moreover, in the fats and oils (A) of this invention, a free fatty acid or its salt (FFA) is good to be reduced to 3.5% or less, Preferably it is 0 to 2%, Furthermore, 0 to 1%, Especially 0 to 0. 0.5%, most preferably 0.05 to 0.2% is preferable in terms of flavor, smoke generation during microwave cooking, and industrial productivity.
本発明の油脂(A)を構成する全脂肪酸中、炭素−炭素二重結合を4つ以上有する脂肪酸の含有量は、酸化安定性、作業性、生理効果、着色等の点で0〜40%、好ましくは0〜20%、更に0〜10%、特に0〜1%であるのがよく、実質的に含まないのが最も好ましい。 The content of fatty acids having 4 or more carbon-carbon double bonds in the total fatty acids constituting the fats and oils (A) of the present invention is 0 to 40% in terms of oxidation stability, workability, physiological effects, coloring, and the like. The content is preferably 0 to 20%, more preferably 0 to 10%, particularly preferably 0 to 1%, and most preferably not substantially contained.
本発明の油脂(A)の起源は、植物性油脂、動物性油脂のいずれでもよい。具体的な原料としては、菜種油、ひまわり油、とうもろこし油、大豆油、米油、紅花油、綿実油、牛脂等を挙げることができる。またこれらの油脂を分別、混合したもの、水素添加や、エステル交換反応などにより脂肪酸組成を調整したものも原料として利用できるが、水素添加していないものであることが、油脂(A)を構成する全脂肪酸中のトランス酸含量を低減させる点から好ましい。 The origin of the fats and oils (A) of the present invention may be vegetable oils or animal fats. Specific examples of the raw material include rapeseed oil, sunflower oil, corn oil, soybean oil, rice oil, safflower oil, cottonseed oil, and beef tallow. In addition, those obtained by separating and mixing these oils and fats, and those prepared by adjusting the fatty acid composition by hydrogenation or transesterification can also be used as raw materials. It is preferable from the viewpoint of reducing the trans acid content in the total fatty acid.
本発明の油脂(A)は、上述した油脂由来の脂肪酸とグリセリンとのエステル化反応、油脂とグリセリンとのエステル交換反応等により得ることができる。これらの反応はアルカリ触媒等を用いた化学反応でも行うことができるが、1,3−位選択的リパーゼ等を用いて酵素的に温和な条件で反応を行うのが風味等の点で優れており好ましい。反応により生成した過剰のモノアシルグリセロールは分子蒸留法又はクロマトグラフィー法により除去することができる。 The fats and oils (A) of the present invention can be obtained by the esterification reaction of fatty acids derived from fats and oils and glycerin, the transesterification reaction of fats and oils and glycerin, and the like. These reactions can also be carried out by chemical reactions using an alkali catalyst or the like, but it is excellent in terms of flavor and the like to carry out the reaction under mild conditions enzymatically using a 1,3-position selective lipase or the like. It is preferable. Excess monoacylglycerol produced by the reaction can be removed by molecular distillation or chromatography.
本発明の電子レンジ調理用油脂(A)には、更に成分(B)の水を含有するのが好ましい。水(B)の含有量は、油脂(A)100重量部に対して、0.02〜0.89重量部、好ましくは0.04〜0.8重量部、更に0.06〜0.6重量部、特に0.1〜0.5重量部、殊更0.2〜0.4重量部含有するのが、電子レンジ調理時の加熱特性、外観、風味の点で好ましい。
本発明において、油脂中の水の含有量は、カールフィッシャー法(「基準油脂分析試験法(日本油化学協会編)」中の「水分」2.1.3.4−1996)により測定した値のことである。
The oil / fat for microwave cooking (A) of the present invention preferably further contains water of component (B). Content of water (B) is 0.02-0.89 weight part with respect to 100 weight part of fats and oils (A), Preferably it is 0.04-0.8 weight part, Furthermore, 0.06-0.6 The content of 0.1 part by weight, particularly 0.1 to 0.5 part by weight, and especially 0.2 to 0.4 part by weight is preferable from the viewpoint of heating characteristics, appearance, and flavor during microwave cooking.
In the present invention, the content of water in fats and oils is a value measured by the Karl Fischer method ("Moisture" 2.1.3.4-1996 in "Standard fats and oils analysis test method (edited by Japan Oil Chemical Association)"). That is.
本発明の電子レンジ調理用油脂(A)には、更に成分(C)の植物ステロール類を含有するのが好ましい。植物ステロール類はコレステロール低下効果を有する成分であり、本発明において、植物ステロール類の含有量は、油脂(A)100重量部に対して、0.05〜30重量部、特に0.3〜1.2重量部が好ましい。通常の植物油以上のコレステロール低下を目的とする場合には、油脂(A)100重量部に対して植物ステロール類を1.2〜30重量部、好ましくは2〜4.7重量部の範囲で添加してもよい。
ここで植物ステロール類としては、例えばα−シトステロール、β−シトステロール、スチグマステロール、カンペステロール、α−シトスタノール、β−シトスタノール、スチグマスタノール、カンペスタノール、シクロアルテノール等のフリー体、及びこれらの脂肪酸エステル、フェルラ酸エステル、桂皮酸エステル等のエステル体が挙げられる。
It is preferable that the oil / fat for microwave oven cooking (A) of the present invention further contains plant sterols as component (C). Plant sterols are components having a cholesterol-lowering effect. In the present invention, the content of plant sterols is 0.05 to 30 parts by weight, particularly 0.3 to 1 part per 100 parts by weight of the fat (A). .2 parts by weight are preferred. For the purpose of lowering cholesterol above normal vegetable oils, plant sterols are added in an amount of 1.2 to 30 parts by weight, preferably 2 to 4.7 parts by weight per 100 parts by weight of the fat (A). May be.
Here, as plant sterols, for example, α-sitosterol, β-sitosterol, stigmasterol, campesterol, α-sitostanol, β-sitostanol, stigmasteranol, campestanol, cycloartenol and the like, and These fatty acid esters, ferulic acid esters, cinnamic acid esters and the like are exemplified.
本発明の電子レンジ調理用油脂においては、更に結晶抑制剤を添加することが好ましい。本発明で使用する結晶抑制剤としては、ポリグリセリン縮合リシノレイン酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル等のポリオール脂肪酸エステルが挙げられる。
またポリオール脂肪酸エステルは、HLB(Griffinの計算式、J. Soc. Cosmet. Chem., 1, 311(1949))が4以下、特に0.1〜3のポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステルが好ましい。
本発明において、結晶抑制剤は、油脂(A)100重量部に対して0.02〜0.5重量部、特に0.05〜0.2重量部含有するのが、外観の点で好ましい。
It is preferable to add a crystallization inhibitor further to the oil for cooking in a microwave oven according to the present invention. Examples of the crystal inhibitor used in the present invention include polyglycerin condensed ricinoleic acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and propylene glycol fatty acid ester. It is done.
Polyol fatty acid esters include polyglycerin fatty acid esters, sucrose fatty acid esters having HLB (Griffin's calculation formula, J. Soc. Cosmet. Chem., 1, 311 (1949)) of 4 or less, particularly 0.1-3. Sorbitan fatty acid esters are preferred.
In the present invention, the crystallization inhibitor is preferably contained in an amount of 0.02 to 0.5 parts by weight, particularly 0.05 to 0.2 parts by weight, based on 100 parts by weight of the fat (A).
本発明の電子レンジ調理用油脂には、抗酸化剤を含有することが好ましい。抗酸化剤の含有量は、風味、酸化安定性、着色等の点で油脂(A)100重量部に対して、0.005〜0.5重量部であるのが好ましく、更に0.04〜0.25重量部、特に0.08〜0.2重量部であるのが好ましい。抗酸化剤としては、通常、食品に使用されるものであれば何れでもよい。例えば、ビタミンE、ブチルヒドロキシトルエン(BHT)、ブチルヒドロキシアニソール(BHA)、ターシャルブチルヒドロキノン(TBHQ)、ビタミンC又はその誘導体、リン脂質、ローズマリー抽出物等の天然抗酸化剤が挙げられるが、ビタミンE、ビタミンC又はその誘導体が好ましく、これらを併用するのが更に好ましい。 It is preferable that the fats and oils for microwave oven cooking of this invention contain an antioxidant. The content of the antioxidant is preferably 0.005 to 0.5 parts by weight and more preferably 0.04 to 0.5 parts by weight with respect to 100 parts by weight of the fat (A) in terms of flavor, oxidation stability, coloring, and the like. The amount is preferably 0.25 parts by weight, particularly 0.08 to 0.2 parts by weight. Any antioxidant can be used as long as it is usually used in foods. Examples thereof include natural antioxidants such as vitamin E, butylhydroxytoluene (BHT), butylhydroxyanisole (BHA), tertiary butylhydroquinone (TBHQ), vitamin C or a derivative thereof, phospholipid, and rosemary extract. Vitamin E, vitamin C or derivatives thereof are preferable, and it is more preferable to use these in combination.
ビタミンEとしては、α、β、γ、δ−トコフェロール又はこれらの混合物を使用することができる。特に、酸化安定性の観点から、δ−トコフェロールが好ましい。ビタミンEの市販品としては、イーミックスD、イーミックス80(エーザイ(株)製)、MDE−6000((株)八代製)、Eオイル−400(理研ビタミン(株)製)等が挙げられる。本発明において、ビタミンEの含有量は、油脂(A)100重量部に対して、トコフェロールとして0.01〜0.4重量部が好ましく、0.02〜0.3重量部がより好ましく、0.05〜0.2重量部が特に好ましい。 As vitamin E, α, β, γ, δ-tocopherol or a mixture thereof can be used. In particular, from the viewpoint of oxidation stability, δ-tocopherol is preferable. Commercial products of vitamin E include Emix D, Emix 80 (manufactured by Eisai Co., Ltd.), MDE-6000 (manufactured by Yatsushiro Co., Ltd.), E oil-400 (manufactured by Riken Vitamin Co., Ltd.), and the like. . In the present invention, the content of vitamin E is preferably 0.01 to 0.4 parts by weight, more preferably 0.02 to 0.3 parts by weight as tocopherol, with respect to 100 parts by weight of the fat (A). 0.05 to 0.2 parts by weight is particularly preferable.
ビタミンC又はその誘導体としては、油脂(A)に溶解するものが好ましく、高級脂肪酸エステル、例えばアシル基の炭素数が12〜22のものがより好ましく、L−アスコルビン酸パルミテート、L−アスコルビン酸ステアレートが特に好ましく、L−アスコルビン酸パルミテートが最も好ましい。
本発明において、ビタミンC又はその誘導体の含有量は、油脂(A)100重量部に対して、アスコルビン酸として0.004〜0.1重量部が好ましく、0.006〜0.08重量部がより好ましく、0.008〜0.06重量部が特に好ましい。
また、本発明の電子レンジ調理用油脂が水と混合され、又は水を含む食品に使用された場合であって、長期保存又は明所保存される場合には、抗酸化剤としてL−アスコルビン酸脂肪酸エステルを実質的に含ませず、ビタミンE、好ましくはδ−トコフェロールを使用することが、風味劣化、異味発生を防止する点から好ましい。
Vitamin C or a derivative thereof is preferably one that dissolves in fats and oils (A), more preferably a higher fatty acid ester, for example, an acyl group having 12 to 22 carbon atoms, L-ascorbyl palmitate, L-ascorbic acid steer. The rate is particularly preferred, with L-ascorbyl palmitate being most preferred.
In the present invention, the content of vitamin C or a derivative thereof is preferably 0.004 to 0.1 parts by weight, preferably 0.006 to 0.08 parts by weight as ascorbic acid with respect to 100 parts by weight of the fat (A). More preferred is 0.008 to 0.06 parts by weight.
Moreover, when the fats and oils for microwave cooking of this invention are mixed with water, or are used for the foodstuff containing water, Comprising: When long-term preservation | save or preservation | save is carried out, L-ascorbic acid is used as an antioxidant. It is preferable to use vitamin E, preferably δ-tocopherol, substantially free from fatty acid esters, from the viewpoint of preventing flavor deterioration and occurrence of off-flavors.
本発明の電子レンジ調理用油脂においては、更に炭素数2〜8の有機カルボン酸を添加することが好ましい。炭素数2〜8の有機カルボン酸の含有量は、油脂(A)100重量部に対して、0.001〜0.01重量部であるのが好ましく、更に0.0012〜0.007、特に0.0015〜0.0045重量部、殊更0.0025〜0.0034重量部であるのが風味、外観、酸化安定性の点で好ましい。 In the microwave cooking oil / fat of the present invention, it is preferable to further add an organic carboxylic acid having 2 to 8 carbon atoms. The content of the organic carboxylic acid having 2 to 8 carbon atoms is preferably 0.001 to 0.01 parts by weight, more preferably 0.0012 to 0.007, particularly 100 parts by weight of the fat (A). The amount of 0.0015 to 0.0045 parts by weight, particularly 0.0025 to 0.0034 parts by weight, is preferable from the viewpoint of flavor, appearance, and oxidation stability.
本発明の電子レンジ調理用油脂は、前記組成の油脂に、水、植物ステロール類、更に抗酸化剤、結晶抑制剤等を添加し、撹拌することにより得ることができる。 The oil for cooking in the microwave oven of the present invention can be obtained by adding water, plant sterols, further antioxidants, crystal inhibitors and the like to the oil of the above composition and stirring.
かくして得られた電子レンジ調理用油脂は、加熱性、発煙などの電子レンジ調理性、風味、食感等の点で良好であるため、電子レンジ調理用食感改良剤、電子レンジ調理用熱伝導改良剤として利用できる他、各種電子レンジ調理食品に応用することができる。 The fats and oils for cooking in a microwave oven thus obtained are good in terms of heatability, microwave cooking properties such as fuming, flavor, texture, etc. In addition to being used as an improving agent, it can be applied to various microwave-cooked foods.
本発明の油脂を、他の食品素材と共に原料として使用することにより、電子レンジ調理用食品を製造することができる。本発明の油脂を乳化物(水中油型乳化物や油中水型乳化物)の形態で配合して、電子レンジ調理用食品を製造してもよい。特に、本発明の油脂を、電子レンジ調理用食品の表面又は、表面と内部に存在させるのが、加熱むらを抑制するうえで好ましい。 The food for microwave oven cooking can be manufactured by using the fats and oils of this invention as a raw material with another foodstuff raw material. You may manufacture the foodstuff for microwave oven cooking by mix | blending the fats and oils of this invention with the form of emulsion (oil-in-water type emulsion or water-in-oil type emulsion). In particular, it is preferable that the fats and oils of the present invention be present on the surface of the food for cooking in a microwave oven or on the surface and inside thereof in order to suppress uneven heating.
電子レンジ調理用食品としては、例えばレトルト食品、チルド食品、冷凍食品、無菌包装食品、常温流通食品等が挙げられる。具体的な製品としては、一食分のメニューを包装した食品、弁当、惣菜の他、パン、ケーキ、ビスケット、パイ、ピザ、ドーナツ等のベーカリー食品類、スープ、ソース、飲料等の乳化食品、トルティーヤチップス、ポテトチップス、ファブリケートポテト、ポップコーン等のスナック食品、チョコレート、キャラメル、キャンデー、デザート等の菓子、ハム、ソーセージ、ハンバーグ、フライドチキン等の肉加工食品等が挙げられる。 Examples of foods for cooking in a microwave oven include retort foods, chilled foods, frozen foods, aseptic packaged foods, and foods distributed at room temperature. Specific products include foods packed with a single menu, lunch boxes, side dishes, bakery foods such as bread, cakes, biscuits, pies, pizzas, donuts, emulsified foods such as soups, sauces, beverages, tortillas, etc. Examples include snack foods such as chips, potato chips, fabricate potatoes and popcorn, confectionery such as chocolate, caramel, candy and dessert, and processed meat foods such as ham, sausage, hamburger and fried chicken.
本発明の油脂の電子レンジ調理用食品への配合量は、食品の種類によっても異なるが、一般に0.5〜80%、更に1〜50%、特に5〜20%であるのが好ましい。なお、製剤調製の関係から、食品原料由来の油脂が含まれている場合は、食品原料由来の油脂と本発明の食用油脂との重量比は、95:5〜1:99が好ましく、95:5〜5:95がより好ましく、更に85:15〜5:95が、特に40:60〜5:95であるのが好ましい。 The blending amount of the fats and oils of the present invention into the food for microwave cooking differs depending on the type of food, but is generally 0.5 to 80%, more preferably 1 to 50%, and particularly preferably 5 to 20%. In addition, when the fats and oils derived from food raw materials are included from the relationship of preparation of the preparation, the weight ratio of the fats and oils derived from the food raw materials and the edible fats and oils of the present invention is preferably 95: 5 to 1:99, 95: 5 to 5:95 is more preferable, and 85:15 to 5:95 is more preferable, and 40:60 to 5:95 is particularly preferable.
電子レンジ調理用食品の応用例を挙げる。
セット食メニュー:朝食、昼食、夕食、夜食、軽食、間食等に利用できる。各メニューには本発明の油脂が含まれており、電子レンジ調理により、手軽においしく喫食できる。
The application example of the food for microwave oven cooking is given.
Set meal menu: Available for breakfast, lunch, dinner, dinner, snacks, snacks, etc. Each menu contains the fats and oils of the present invention, and can be eaten deliciously easily by microwave cooking.
朝食セット1:下記(1)〜(4)よりなる冷凍食品を、電子レンジ調理することにより喫食する。
(1)本発明の油脂を含むパンケーキ、
(2)本発明の油脂を含むスクランブルエッグ、
(3)本発明の油脂を含むソーセージ、
(4)本発明の油脂を含むベーコン
Breakfast set 1: Frozen food consisting of the following (1) to (4) is eaten by cooking in a microwave oven.
(1) A pancake containing the oil and fat of the present invention,
(2) a scrambled egg containing the oil of the present invention,
(3) sausage containing the fats and oils of the present invention,
(4) Bacon containing the oil and fat of the present invention
朝食セット2:下記(1)に、(2)と(3)をはさんだ冷凍サンドイッチを、電子レンジ調理して喫食する。
(1)本発明の油脂を含むクロワッサン
(2)本発明の油脂を含むソーセージ
(3)本発明の油脂を含むチーズ
Breakfast set 2: A frozen sandwich with (2) and (3) sandwiched between (1) and (2) below is cooked in a microwave.
(1) Croissant containing the fats and oils of the present invention (2) Sausage containing the fats and oils of the present invention (3) Cheese containing the fats and oils of the present invention
パスタセット:下記(1)と(2)を電子レンジ調理して、パスタを茹でることなく喫食する。
(1)茹でたパスタに、本発明の油脂をからめて無菌充填したもの(常温又はチルド流通)
(2)本発明の油脂入りのトマトソースをレトルトパウチ殺菌したもの(常温又はチルド流通)
Pasta set: The following (1) and (2) are cooked in a microwave and eaten without boiling the pasta.
(1) Boiled pasta filled with the oil and fat of the present invention and aseptically filled (normal temperature or chilled distribution)
(2) Retort pouch sterilized tomato sauce containing fats and oils of the present invention (normal temperature or chilled distribution)
牛丼セット:下記(1)と(2)を電子レンジ調理して喫食する。
(1)無菌充填したごはん(本発明の油脂を炊飯油として使用するのが好ましい、常温流通)
(2)本発明の油脂を含有する牛丼の具をレトルトパウチ殺菌したもの(常温流通)
Beef bowl set: The following (1) and (2) are cooked in a microwave and eaten.
(1) Aseptically filled rice (preferably using the fats and oils of the present invention as cooking oil, circulation at room temperature)
(2) Retort pouch sterilized beef bowl containing oils and fats of the present invention (circulation at normal temperature)
実施例1
次の油脂を製造した。
油脂a
大豆油脂肪酸をウインタリングにより飽和脂肪酸を低減させたもの455重量部と菜種油脂肪酸195重量部とグリセリン107重量部とを、リポザイムIM(ノボ ノルディスクバイオインダストリー社製)を使用して0.07hPaで40℃、5時間エステル化を行った。次いで酵素を濾別し、235℃で分子蒸留し、更に脱色、水洗した。次いでこの油脂150重量部に10%クエン酸水溶液7.5重量部を加え、60℃で20分間攪拌した後、110℃、0.27kPaで脱水した。これを235℃で2時間脱臭して、油脂aを調製した。
Example 1
The following fats and oils were produced.
Oil and fat a
455 parts by weight of soybean oil fatty acid with saturated fatty acid reduced by wintering, 195 parts by weight of rapeseed oil fatty acid and 107 parts by weight of glycerin at 0.07 hPa using Lipozyme IM (manufactured by Novo Nordisk Bioindustry) Esterification was performed at 40 ° C. for 5 hours. The enzyme was then filtered off, molecularly distilled at 235 ° C., further decolorized and washed with water. Next, 7.5 parts by weight of a 10% aqueous citric acid solution was added to 150 parts by weight of the oil and fat, and the mixture was stirred at 60 ° C. for 20 minutes and then dehydrated at 110 ° C. and 0.27 kPa. This was deodorized at 235 ° C. for 2 hours to prepare a fat a.
油脂b
菜種油脂肪酸650重量部とグリセリン107重量部とを、油脂Aと同様にエステル化、後処理を行い、油脂bを調製した。
Oil b
Rapeseed oil fatty acid 650 parts by weight and glycerin 107 parts by weight were esterified and post-treated in the same manner as for fats and oils A to prepare fats and oils b.
油脂c
大豆油脂肪酸650重量部とグリセリン107重量部とを、油脂Aと同様にエステル化、後処理を行い、油脂cを調製した。
Fat and oil c
Fat oil c was prepared by esterifying and post-treating 650 parts by weight of soybean oil fatty acid and 107 parts by weight of glycerin in the same manner as fat A.
油脂a、油脂b、油脂cの構成脂肪酸組成・グリセリド組成を表1に示す。 Table 1 shows the constituent fatty acid composition and glyceride composition of fats and oils a, fats and oils b, and fats and oils c.
本発明品1〜3及び、比較品1、2
油脂a、油脂b、油脂cを各100重量部に対し、クエン酸、植物ステロール類、抗酸化剤、結晶抑制剤を加えて本発明品1〜3とした。これら油脂の配合組成を表2に示す。尚、サラダ油(日清オイリオ製、TG含量98%)を比較品1に、モノグリセリド(花王製、エキセルO−95R、MG含量96%)を比較品2にした。
Invention products 1 to 3 and comparative products 1 and 2
Citric acid, plant sterols, antioxidants, and crystal inhibitors were added to 100 parts by weight of each of fats and oils a, fats and oils b, and fats and oils c to obtain products 1 to 3 of the present invention. Table 2 shows the composition of these fats and oils. Note that salad oil (Nisshin Oilio, TG content 98%) was used as comparative product 1, and monoglyceride (Kao, Excel O-95R, MG content 96%) was used as comparative product 2.
実施例2 マイクロ波照射試験(550W)
本発明品1、比較品1、比較品2を、ガラス製サンプル瓶(50mL)に20gずつ入れた(初期温度20℃)。これに蓋をしないで電子レンジ(NE−N200型、松下電器製)のターンテーブル中央に置き、550Wで3分間マイクロ波照射を行った。照射後すばやくサンプルの温度を測定し、外観を目視で評価した。結果を表3に示す。
Example 2 Microwave Irradiation Test (550W)
Inventive product 1, comparative product 1 and comparative product 2 were placed in a glass sample bottle (50 mL) 20 g at a time (initial temperature 20 ° C.). This was placed in the center of the turntable of a microwave oven (NE-N200 type, manufactured by Matsushita Electric) without a lid, and was irradiated with microwaves at 550 W for 3 minutes. The temperature of the sample was measured immediately after irradiation, and the appearance was visually evaluated. The results are shown in Table 3.
本発明品1は、マイクロ波照射時の温度上昇に優れ、発煙・着色がなく極めて良好であった。これに対し、比較品1は、外観は良好であったが、マイクロ波照射時の温度は低かった。比較品2は、マイクロ波照射時の温度は高かったが、黄色に着色し、しかも発煙が観察され、安全性の点で十分ではなかった。 The product 1 of the present invention was excellent in temperature rise at the time of microwave irradiation and was very good without smoke generation or coloring. On the other hand, the comparative product 1 had a good appearance, but the temperature during microwave irradiation was low. Comparative product 2 had a high temperature during microwave irradiation, but it was colored yellow, and smoke was observed, which was not sufficient in terms of safety.
実施例3 マイクロ波照射試験(170W)
100mLの三角フラスコに50gの油脂(本発明品1、比較品1)と蒸留水30mLとを入れ、50℃の恒温槽にて攪拌した後、室温に放冷した。これらを水分量の少ない油脂で希釈し、各サンプルを調製した。水分量は、カールフィッシャー法により測定した。尚、本発明品1の飽和水分量は8900ppm、比較品1の飽和水分量は、1028ppmであった。
これらのサンプルをガラス製サンプル瓶(50mL)に20g入れた(初期温度20℃)。次いで、これを電子レンジ(NE−N200型、松下電器製)のターンテーブル中央部に置き、マイクロ波照射(170W)した後、すばやくサンプルの温度を測定した。結果を表4に示す。
Example 3 Microwave Irradiation Test (170W)
A 100 mL Erlenmeyer flask was charged with 50 g of oil (present product 1, comparative product 1) and 30 mL of distilled water, stirred in a thermostatic bath at 50 ° C., and then allowed to cool to room temperature. These were diluted with fats and oils with a small amount of water to prepare each sample. The water content was measured by the Karl Fischer method. The saturated water content of the product 1 of the present invention was 8900 ppm, and the saturated water content of the comparative product 1 was 1028 ppm.
20 g of these samples was placed in a glass sample bottle (50 mL) (initial temperature 20 ° C.). Next, this was placed in the center of a turntable of a microwave oven (NE-N200 type, manufactured by Matsushita Electric), and after microwave irradiation (170 W), the temperature of the sample was quickly measured. The results are shown in Table 4.
本発明品1の水分量は、比較品に比べて多く、しかもマイクロ波照射時に温度上昇しやすいという特性を有していることが明らかとなった。 It has been clarified that the water content of the product 1 of the present invention is larger than that of the comparative product and has a characteristic that the temperature is likely to rise during microwave irradiation.
次に、冷凍・解凍を想定し、本発明品1の各水分量のサンプルをガラス製サンプル瓶(50mL)に20g入れて、密栓した。これを−18℃の冷凍庫にて1日静置した後、開栓し、マイクロ波照射(170W)して解凍を行った。マイクロ波照射中に目視でサンプルの外観を観察し、解凍終了(透明化)までに要した時間を測定した。結果を表5に示す。 Next, assuming freezing and thawing, 20 g of each moisture content sample of the product 1 of the present invention was put in a glass sample bottle (50 mL) and sealed. This was left standing in a freezer at −18 ° C. for 1 day, then opened and thawed by microwave irradiation (170 W). The external appearance of the sample was visually observed during the microwave irradiation, and the time required for completion of thawing (transparency) was measured. The results are shown in Table 5.
本発明品1の水分量が高くなる程、解凍に要するマイクロ波照射時間が少なくて済むことが明らかとなった。 It was found that the higher the moisture content of the product 1 of the present invention, the shorter the microwave irradiation time required for thawing.
実施例4 電子レンジ調理食品(ハンバーグ)
下記配合の原料をフードプロセッサーに入れ、よく混合した後、70gずつ小判型に成形した。これをホットプレートで加熱し(180℃、2分)、次いでオーブンで焼成した(180℃、3.5分)。放冷後、−18℃にて冷凍した。これを電子レンジ調理し(500W、3分)、風味・食感を官能で評価した。結果を表6に示す。
Example 4 Microwave cooked food (hamburger)
The raw materials having the following composition were put into a food processor and mixed well, and then formed into 70-gram oval molds. This was heated on a hot plate (180 ° C., 2 minutes) and then baked in an oven (180 ° C., 3.5 minutes). After standing to cool, it was frozen at -18 ° C. This was cooked in a microwave oven (500 W, 3 minutes), and the flavor and texture were evaluated sensuously. The results are shown in Table 6.
重量部
合挽肉(牛:豚=7:3) 67.0
パン粉 2.0
全卵 5.0
脱脂粉乳 1.0
塩 0.8
胡椒 0.1
ナツメグ 0.2
ビーフエキス 0.1
大豆蛋白質 4.0
水 8.8
コーンスターチ 1.0
油脂(本発明品3又は、比較品1)2.0
Weight part Ground meat (cow: pig = 7: 3) 67.0
Bread crumbs 2.0
Whole egg 5.0
Nonfat dry milk 1.0
Salt 0.8
Pepper 0.1
Nutmeg 0.2
Beef extract 0.1
Soy protein 4.0
Water 8.8
Cornstarch 1.0
Oil (present product 3 or comparative product 1) 2.0
本発明品3を使用したハンバーグは、比較品1よりも電子レンジ調理後の風味・食感が良好であることがわかった。 It was found that the hamburger using the product 3 of the present invention has a better flavor and texture after cooking the microwave oven than the comparative product 1.
実施例5 電子レンジ調理食品(中華まんじゅう)
市販の中華まんじゅう(山崎製パン製、あんまん、約100g/個)の端部を切り、あんをほぼ全量(約40g)取り出した。該あんに表7記載の添加物を配合し、皮に戻した。次いで、端部をセロハンテープで接着し、中華まんじゅうを再生した。これらのサンプルについて、電子レンジ調理を行った(500W、45秒)。電子レンジ調理直後及び、調理後30分静置(室温)した時の風味・食感を官能で評価した。結果を表7に示す。
Example 5 Microwave cooked food (Chinese bun)
The end of a commercially available Chinese bun (Yamazaki Bread, Anman, approx. 100 g / piece) was cut off, and almost the whole amount (about 40 g) was taken out. The additives listed in Table 7 were added to the skin and returned to the skin. Next, the ends were bonded with cellophane tape to regenerate the Chinese bun. About these samples, microwave cooking was performed (500 W, 45 seconds). The taste and texture were evaluated organoleptically immediately after cooking in a microwave oven and when left still (room temperature) for 30 minutes after cooking. The results are shown in Table 7.
本発明品Zの中華まんじゅう(あんまん)は、電子レンジ調理後、30分静置しても、比較品X、Yよりも風味・食感が良好であった。ただ単にあんに水を添加しただけでは(比較品Y)、調理後30分静置した場合の風味・食感は、改善しなかった。 The Chinese bun of the invention product Z had a better flavor and texture than the comparative products X and Y even after standing for 30 minutes after cooking in the microwave oven. Simply adding water to it (Comparative Product Y) did not improve the flavor and texture when left standing for 30 minutes after cooking.
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JP2008061577A (en) * | 2006-09-07 | 2008-03-21 | Kao Corp | Oil and fat composition |
WO2008084773A1 (en) * | 2007-01-09 | 2008-07-17 | Riken Vitamin Co., Ltd. | Pharmaceutical preparations containing fatty acid esters of l-ascorbic acid |
JP2013018970A (en) * | 2011-06-15 | 2013-01-31 | Kao Corp | Method for manufacturing refined oil-and-fat |
JP2014209885A (en) * | 2013-04-19 | 2014-11-13 | 株式会社Adeka | Plastic fat composition |
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JP2008061577A (en) * | 2006-09-07 | 2008-03-21 | Kao Corp | Oil and fat composition |
JP4589902B2 (en) * | 2006-09-07 | 2010-12-01 | 花王株式会社 | Oil composition |
WO2008084773A1 (en) * | 2007-01-09 | 2008-07-17 | Riken Vitamin Co., Ltd. | Pharmaceutical preparations containing fatty acid esters of l-ascorbic acid |
JP2008169254A (en) * | 2007-01-09 | 2008-07-24 | Riken Vitamin Co Ltd | L-ascorbic acid fatty acid ester-containing preparation |
JP2013018970A (en) * | 2011-06-15 | 2013-01-31 | Kao Corp | Method for manufacturing refined oil-and-fat |
JP2014209885A (en) * | 2013-04-19 | 2014-11-13 | 株式会社Adeka | Plastic fat composition |
JP2016093128A (en) * | 2014-11-14 | 2016-05-26 | 日清オイリオグループ株式会社 | Oil and fat composition for cooking, method for producing oil and fat composition for cooking, and method for reducing oil content remaining in cooked material after cooking |
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