JP2005255558A - Photocatalytic organism protective agent using titanium dioxide - Google Patents
Photocatalytic organism protective agent using titanium dioxide Download PDFInfo
- Publication number
- JP2005255558A JP2005255558A JP2004066317A JP2004066317A JP2005255558A JP 2005255558 A JP2005255558 A JP 2005255558A JP 2004066317 A JP2004066317 A JP 2004066317A JP 2004066317 A JP2004066317 A JP 2004066317A JP 2005255558 A JP2005255558 A JP 2005255558A
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- Prior art keywords
- animal
- photocatalytic
- agent according
- titanium dioxide
- plant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 14
- 230000001699 photocatalysis Effects 0.000 title claims description 13
- 239000003223 protective agent Substances 0.000 title claims description 7
- 241001465754 Metazoa Species 0.000 claims abstract description 29
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 8
- 241000894006 Bacteria Species 0.000 claims abstract description 7
- 241000700605 Viruses Species 0.000 claims abstract description 7
- 241000196324 Embryophyta Species 0.000 claims description 28
- 239000011814 protection agent Substances 0.000 claims description 10
- 239000011941 photocatalyst Substances 0.000 claims description 7
- 239000003344 environmental pollutant Substances 0.000 claims description 6
- 241000607479 Yersinia pestis Species 0.000 claims description 5
- 230000000844 anti-bacterial effect Effects 0.000 claims description 4
- 201000010099 disease Diseases 0.000 claims description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 4
- 239000003905 agrochemical Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 238000013032 photocatalytic reaction Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 230000009969 flowable effect Effects 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 244000144972 livestock Species 0.000 claims 5
- 244000052616 bacterial pathogen Species 0.000 claims 3
- 231100000331 toxic Toxicity 0.000 claims 2
- 230000002588 toxic effect Effects 0.000 claims 2
- 210000003608 fece Anatomy 0.000 claims 1
- 239000003673 groundwater Substances 0.000 claims 1
- 208000015181 infectious disease Diseases 0.000 claims 1
- 239000010871 livestock manure Substances 0.000 claims 1
- 238000004806 packaging method and process Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000008399 tap water Substances 0.000 claims 1
- 235000020679 tap water Nutrition 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 241000233866 Fungi Species 0.000 abstract description 3
- 239000012773 agricultural material Substances 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 5
- 241000221785 Erysiphales Species 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 230000003902 lesion Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Landscapes
- Cosmetics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Catching Or Destruction (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Protection Of Plants (AREA)
- Greenhouses (AREA)
- Fire-Extinguishing Compositions (AREA)
- Medicinal Preparation (AREA)
Abstract
Description
本発明は、有害有機化合物等から動植物を守ることのできる光触媒式動植物保護剤に関するものである。 The present invention relates to a photocatalytic animal and plant protective agent capable of protecting animals and plants from harmful organic compounds and the like.
動植物の病気・ウイルス・カビ・細菌等を防除する農薬は、有機リン系、有機塩素系、有機水銀系などのように化学合成農薬がほとんどである。使用に当たっては、病気や菌の種類によって農薬を使い分けなければならない。 Chemical pesticides such as organophosphorus, organochlorine, and organomercury are almost all of the pesticides that control animal and plant diseases, viruses, molds, and bacteria. When using it, it is necessary to use different pesticides depending on the disease and the type of fungus.
その為に複数の農薬を何度も散布することでコストもかかり、繰り返し使用すると、抵抗性ができて効果が弱まることや、化学合成農薬が動植物等に蓄積され
ることにより、自然環境に対して悪影響を与えてしまうことが多いと言う問題もあった。
Therefore, it is costly to spray multiple pesticides over and over, and repeated use reduces resistance and effectiveness, and chemically synthesized pesticides accumulate in animals and plants. There is also a problem that it often has an adverse effect.
従来の農業資材では、環境汚染物質であるといわれる、環境ホルモン・ダイオキシン・化学合成農薬等を分解できる効力を備えたものがなかった。
ランニングコストを抑え、かつ有機化合物やウイルス・カビ・細菌等の分解能力を備えた、環境や動植物にやさしく安全かつ容易に使用できる資材がないことに
ある。
There is no material that can be used safely, easily, environmentally, or in animals and plants that has low running costs and is capable of degrading organic compounds, viruses, molds, and bacteria.
本発明の光触媒式動植物保護剤は、様々な環境汚染物質等から動植物等を守る事のできる動植物保護剤であって、二酸化チタンを含有する光触媒式動植
保護剤である。本発明の光触媒式動植物保護剤は、それ自身は変化、分解することなく、紫外線の光が当たる事によって光触媒反応をすることによって、有害な物質を分解して保護するものである。二酸化チタンを使用する現場にて、農家等が容易に希釈・分散させて使用できるようにすること。
The photocatalytic animal and plant protection agent of the present invention is an animal and plant protection agent capable of protecting animals and plants from various environmental pollutants and the like, and is a photocatalytic animal and plant protection agent containing titanium dioxide. The photocatalyst type animal and plant protection agent of the present invention is a substance that decomposes and protects harmful substances by undergoing a photocatalytic reaction when exposed to ultraviolet light without being changed or decomposed. Make it easy for farmers to dilute and disperse the titanium dioxide at the site where it is used.
光触媒は、強い酸化力により、殺菌、消臭、分解浄化などを目的として、応用が世界中で開発されている。二酸化チタンの光触媒では、紫外線で特に300〜400nmの波長の光の照射によって電子と正孔が表面に生じ、酸化還元反応を生じる。そこで光触媒は、その酸化還元反応により有機化合物等を酸化分解し、空気等を正常化する空気清浄機やタイル、防護壁、ランプ等に利用されている。 Applications of photocatalysts have been developed all over the world for the purpose of sterilization, deodorization, decomposition purification, etc. due to their strong oxidizing power. In the photocatalyst of titanium dioxide, electrons and holes are generated on the surface by irradiation with light of a wavelength of 300 to 400 nm, particularly with ultraviolet rays, and an oxidation-reduction reaction occurs. Therefore, photocatalysts are used in air purifiers, tiles, protective walls, lamps, etc. that oxidize and decompose organic compounds by the oxidation-reduction reaction to normalize air.
二酸化チタンが光触媒反応をするときに、紫外線の300〜400nmの波長を利用することにより紫外線のカット作用があり施設栽培等で施設内部の温度調整にも利用できる。その紫外線カット作用は、女性の化粧品、自動車のガラス、施設栽培での被服資材等にも使用されている。 When titanium dioxide undergoes a photocatalytic reaction, ultraviolet rays can be cut by utilizing the wavelength of 300 to 400 nm of ultraviolet rays, which can also be used for temperature adjustment inside the facility for facility cultivation or the like. The UV-blocking action is also used for women's cosmetics, automobile glass, clothing materials for facility cultivation, and the like.
化学合成の乳化剤・分散剤・界面活性剤・補助成分等を含まない。環境に動植物に安全に使用できる二酸化チタンを光触媒に使用することによって、農薬等の有害有機化合物、環境汚染物質、様々な臭気成分の分解除去及び抗菌・殺菌・ウイルス分解作用等を兼ね備え、化学合成農薬使用の削減を図る事ができる、又、施設栽培等での屋根、外壁等への使用には、紫外線カット作用による施設内作物の高温障害を抑え、害虫の中には紫外線により行動をするものが居てそのような害虫の被害を最小限に抑えることもできる。 Does not contain chemically synthesized emulsifiers, dispersants, surfactants, auxiliary ingredients, etc. By using titanium dioxide that can be safely used for animals and plants in the environment as a photocatalyst, it combines chemical removal with harmful organic compounds such as agricultural chemicals, environmental pollutants, various odorous components, and antibacterial, bactericidal, and viral decomposition. The use of pesticides can be reduced, and for use on roofs, exterior walls, etc. in facility cultivation, etc., the high-temperature damage of crops in the facility due to UV protection is suppressed, and some pests act with UV light There can be things to minimize the damage of such pests.
動植物体に散布する場合、化学合成の補助成分等を含まないことから、人畜・動植物等に安全なオリゴ糖などを展着剤等として0.01%〜10%を添加し、ムラが
ないように丁寧な散布が好ましい。
Since it does not contain chemical synthesis auxiliary ingredients when sprayed on animals and plants, add 0.01% to 10% as a spreading agent, etc., which is safe for human animals, animals and plants, etc. Spraying is preferred.
施設の屋根・外壁・作業場等に散布する場合は、二酸化チタンの希釈液に木工用ボンド等を接着剤として1%〜30%を添加し、ムラがないように丁寧な散布が
好ましい。
When spraying on the roof, outer wall, workplace, etc. of the facility, it is preferable to add 1% to 30% as a bonding agent for woodworking to a diluted solution of titanium dioxide and carefully spray so that there is no unevenness.
今までの、農薬製剤の乳剤・水和剤・フロアブル剤・ゾル剤等と同様に、使用する現場において容易に分散させることにより、農家等が従来から使用してきた噴霧機械等にて容易に散布できるようになった。そのために、作物・病気等を選ばずに紫外線の当たる作物であれば使用で切るようになった。 Like conventional emulsions, wettable powders, flowables, sols, etc. of agricultural chemicals, they can be easily dispersed on the site where they are used, so that they can be easily sprayed on farming machines, etc. I can do it now. For this reason, crops that are exposed to ultraviolet rays can be used without being selected for crops and diseases.
イチゴのうどん粉病よる殺菌・抗菌効果では、7月15日に散布したのでは翌日にはうどん粉病の白い病班が赤褐色に変色し、12月20日散布分では、4日〜5日後に変色した、2回目の散布は7日〜10日ぐらいのほうが良かった14日以上あけると部分的に再発が見られた。又、きゅうりのかっぱん病・べと病では1度散布すると14日〜20日ぐらい散布間隔をあけても良かった。しかし、月に1回〜2回の散布が望ましい。通常の化学合成農薬では得られない効果が得られた。このことから減農薬・無農薬栽培が今まで以上に容易になった。 In the sterilization and antibacterial effect of strawberry powdery mildew, when sprayed on July 15, the white lesion of powdery mildew turned reddish brown on the next day, and on December 20, the color changed after 4 to 5 days. The second spraying was better on the 7th to the 10th, and after 14 days it was partially recurred. In addition, in the case of cucumber's powdery mildew and downy mildew, once sprayed, it was good to leave the spraying interval about 14-20 days. However, spraying once or twice a month is desirable. An effect that cannot be obtained with ordinary chemically synthesized pesticides was obtained. This has made it easier than ever to reduce pesticide-free and pesticide-free cultivation.
二酸化チタンでビニールハウス・ガラス温室等の屋根・外壁等にコーティングすることによって、紫外線がカットされ施設内温度を、3度〜6度下ることが可能になり植物の高温障害等が緩和され、生育が促進し5月〜7月の品質の良い作物が収穫できるようになった。又、害虫の中には紫外線をカットすることによって、行動を阻害されるものも居て害虫による被害も抑えられた。 By coating the roof and outer walls of a greenhouse, glass greenhouse, etc. with titanium dioxide, the ultraviolet rays are cut and the temperature inside the facility can be lowered by 3 to 6 degrees, and the high temperature damage of plants is alleviated and grown. Promoted good quality crops from May to July. In addition, some insect pests were blocked by UV rays, and the damage caused by the insects was suppressed.
安全な農産物の生産という観点からも農業分野での利用、環境浄化・汚染物質の除去という面では農業・林業・土木分野でも利用の可能性は限りないものだ
推測される。
From the viewpoint of safe production of agricultural products, it is speculated that there is no limit to the possibility of use in agriculture, forestry, and civil engineering in terms of use in the agricultural field, environmental purification, and removal of pollutants.
Claims (11)
病原菌等をも効果的に分解しその後、新たな病原菌等の感染から農作物等を保護することを特徴とする請求項4記載の光触媒式動植物保護剤。 A variety of molds, viruses, bacteria, etc. occur in crops, parks, gardens, forests, roadside trees, etc., but in particular, the cultivation of facilities tends to be hot and humid, and the occurrence of diseases is remarkable. 5. The photocatalytic animal and plant protection agent according to claim 4, wherein such pathogenic bacteria are also effectively decomposed, and thereafter, crops and the like are protected from infection with new pathogenic bacteria.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004066317A JP2005255558A (en) | 2004-03-09 | 2004-03-09 | Photocatalytic organism protective agent using titanium dioxide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004066317A JP2005255558A (en) | 2004-03-09 | 2004-03-09 | Photocatalytic organism protective agent using titanium dioxide |
Publications (1)
Publication Number | Publication Date |
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JP2005255558A true JP2005255558A (en) | 2005-09-22 |
Family
ID=35081649
Family Applications (1)
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JP2004066317A Pending JP2005255558A (en) | 2004-03-09 | 2004-03-09 | Photocatalytic organism protective agent using titanium dioxide |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007136373A (en) * | 2005-11-19 | 2007-06-07 | Hikari Shokubai Kenkyusho:Kk | Method and treating agent for hindering attraction of harmful insect by photocatalyst |
JP2008050348A (en) * | 2006-07-27 | 2008-03-06 | Fujitsu Ltd | Plant epidemic prevention agent, method for plant epidemic prevention and plant epidemic prevention system, plant and method for cultivating plant |
CN102604595A (en) * | 2011-12-15 | 2012-07-25 | 宁波百仕高联合工业有限公司 | Environment-friendly self-disinfection money counting finger wetting agent and manufacturing method thereof |
ITPD20110341A1 (en) * | 2011-10-31 | 2013-05-01 | Ultrabatch S R L | LAMINAR BODY FOR MAKING GREENHOUSES AND CULTIVATION IN GREENHOUSE |
JP2014519401A (en) * | 2011-05-04 | 2014-08-14 | スチュワート・ベンソン・アベレット | Titanium dioxide photocatalytic composition and use thereof |
CN106386259A (en) * | 2016-08-31 | 2017-02-15 | 孟玲 | Novel antibiotic greenhouse |
CN107812341A (en) * | 2017-10-27 | 2018-03-20 | 于建伟 | A kind of formaldehyde scavenger, its preparation method and application |
JP2019014632A (en) * | 2017-07-10 | 2019-01-31 | 東ソー株式会社 | Titanium oxide-coated mesoporous silica |
US11083200B2 (en) | 2018-09-14 | 2021-08-10 | Fujifilm Business Innovation Corp. | Plant protection agent |
-
2004
- 2004-03-09 JP JP2004066317A patent/JP2005255558A/en active Pending
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007136373A (en) * | 2005-11-19 | 2007-06-07 | Hikari Shokubai Kenkyusho:Kk | Method and treating agent for hindering attraction of harmful insect by photocatalyst |
JP2008050348A (en) * | 2006-07-27 | 2008-03-06 | Fujitsu Ltd | Plant epidemic prevention agent, method for plant epidemic prevention and plant epidemic prevention system, plant and method for cultivating plant |
JP2014519401A (en) * | 2011-05-04 | 2014-08-14 | スチュワート・ベンソン・アベレット | Titanium dioxide photocatalytic composition and use thereof |
ITPD20110341A1 (en) * | 2011-10-31 | 2013-05-01 | Ultrabatch S R L | LAMINAR BODY FOR MAKING GREENHOUSES AND CULTIVATION IN GREENHOUSE |
WO2013064970A1 (en) * | 2011-10-31 | 2013-05-10 | Ultrabatch S.R.L. | Laminar body for making greenhouse roofs and method of greenhouse cultivation |
CN103957692A (en) * | 2011-10-31 | 2014-07-30 | 超霸责任有限公司 | Laminar body for making greenhouse roofs and method of greenhouse cultivation |
JP2015502143A (en) * | 2011-10-31 | 2015-01-22 | ウルトラバツチ・ソチエタ・ア・レスポンサビリタ・リミタータ | Laminate for producing greenhouse roof and greenhouse cultivation method |
US10015933B2 (en) | 2011-10-31 | 2018-07-10 | Cytec Industries Inc. | Laminar body for making greenhouse roofs and methods of greenhouse cultivation |
CN102604595A (en) * | 2011-12-15 | 2012-07-25 | 宁波百仕高联合工业有限公司 | Environment-friendly self-disinfection money counting finger wetting agent and manufacturing method thereof |
CN106386259A (en) * | 2016-08-31 | 2017-02-15 | 孟玲 | Novel antibiotic greenhouse |
JP2019014632A (en) * | 2017-07-10 | 2019-01-31 | 東ソー株式会社 | Titanium oxide-coated mesoporous silica |
CN107812341A (en) * | 2017-10-27 | 2018-03-20 | 于建伟 | A kind of formaldehyde scavenger, its preparation method and application |
US11083200B2 (en) | 2018-09-14 | 2021-08-10 | Fujifilm Business Innovation Corp. | Plant protection agent |
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