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JP2005255558A - Photocatalytic organism protective agent using titanium dioxide - Google Patents

Photocatalytic organism protective agent using titanium dioxide Download PDF

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Publication number
JP2005255558A
JP2005255558A JP2004066317A JP2004066317A JP2005255558A JP 2005255558 A JP2005255558 A JP 2005255558A JP 2004066317 A JP2004066317 A JP 2004066317A JP 2004066317 A JP2004066317 A JP 2004066317A JP 2005255558 A JP2005255558 A JP 2005255558A
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Prior art keywords
animal
photocatalytic
agent according
titanium dioxide
plant
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Inventor
Kazuhiro Shiki
和博 志岐
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SARUTA SHIKI NOSAN KK
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SARUTA SHIKI NOSAN KK
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Priority to JP2004066317A priority Critical patent/JP2005255558A/en
Publication of JP2005255558A publication Critical patent/JP2005255558A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25Greenhouse technology, e.g. cooling systems therefor

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  • Cosmetics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Catching Or Destruction (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Catalysts (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Protection Of Plants (AREA)
  • Greenhouses (AREA)
  • Fire-Extinguishing Compositions (AREA)
  • Medicinal Preparation (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To solve the problem that there is no agricultural material that can suppress the running cost, has the ability to decompose organic compounds, viruses, fungi, bacteria, or the like, and is friendly to environment, animals and plants, and can easily and safely be handled. <P>SOLUTION: Titanium dioxide is used as a main material for this agricultural material, whereby this material has the ability to decompose organic compounds, viruses, fungi, bacteria, and the like. Even on a site where the titanium dioxide is used, it can be readily diluted, dispersed and easily sprayed by means of a simple sprayer that is generally used by agricultural houses. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、有害有機化合物等から動植物を守ることのできる光触媒式動植物保護剤に関するものである。   The present invention relates to a photocatalytic animal and plant protective agent capable of protecting animals and plants from harmful organic compounds and the like.

動植物の病気・ウイルス・カビ・細菌等を防除する農薬は、有機リン系、有機塩素系、有機水銀系などのように化学合成農薬がほとんどである。使用に当たっては、病気や菌の種類によって農薬を使い分けなければならない。   Chemical pesticides such as organophosphorus, organochlorine, and organomercury are almost all of the pesticides that control animal and plant diseases, viruses, molds, and bacteria. When using it, it is necessary to use different pesticides depending on the disease and the type of fungus.

その為に複数の農薬を何度も散布することでコストもかかり、繰り返し使用すると、抵抗性ができて効果が弱まることや、化学合成農薬が動植物等に蓄積され
ることにより、自然環境に対して悪影響を与えてしまうことが多いと言う問題もあった。
Therefore, it is costly to spray multiple pesticides over and over, and repeated use reduces resistance and effectiveness, and chemically synthesized pesticides accumulate in animals and plants. There is also a problem that it often has an adverse effect.

従来の農業資材では、環境汚染物質であるといわれる、環境ホルモン・ダイオキシン・化学合成農薬等を分解できる効力を備えたものがなかった。
特開2001−286226号公報 特開平09-316435号公報 特開2001-095379号公報 藤島 昭・橋本和仁・渡部俊也共著「光クリーン革命 」シーエムシー 1997年 日本化学会編「光が関わる触媒化学」季刊化学総説 学会出版センターNo、23,1994
None of the conventional agricultural materials have the ability to decompose environmental hormones, dioxins, chemically synthesized pesticides, etc., which are said to be environmental pollutants.
JP 2001-286226 A JP 09-316435 A JP 2001-095379 A Akira Fujishima, Kazuhito Hashimoto and Toshiya Watanabe “Light Clean Revolution” CMC 1997 The Chemical Society of Japan “Catalyst Chemistry Involving Light” Quarterly Review of Chemical Chemistry, Publishing Center No. 23, 1994

ランニングコストを抑え、かつ有機化合物やウイルス・カビ・細菌等の分解能力を備えた、環境や動植物にやさしく安全かつ容易に使用できる資材がないことに
ある。
There is no material that can be used safely, easily, environmentally, or in animals and plants that has low running costs and is capable of degrading organic compounds, viruses, molds, and bacteria.

本発明の光触媒式動植物保護剤は、様々な環境汚染物質等から動植物等を守る事のできる動植物保護剤であって、二酸化チタンを含有する光触媒式動植
保護剤である。本発明の光触媒式動植物保護剤は、それ自身は変化、分解することなく、紫外線の光が当たる事によって光触媒反応をすることによって、有害な物質を分解して保護するものである。二酸化チタンを使用する現場にて、農家等が容易に希釈・分散させて使用できるようにすること。
The photocatalytic animal and plant protection agent of the present invention is an animal and plant protection agent capable of protecting animals and plants from various environmental pollutants and the like, and is a photocatalytic animal and plant protection agent containing titanium dioxide. The photocatalyst type animal and plant protection agent of the present invention is a substance that decomposes and protects harmful substances by undergoing a photocatalytic reaction when exposed to ultraviolet light without being changed or decomposed. Make it easy for farmers to dilute and disperse the titanium dioxide at the site where it is used.

光触媒は、強い酸化力により、殺菌、消臭、分解浄化などを目的として、応用が世界中で開発されている。二酸化チタンの光触媒では、紫外線で特に300〜400nmの波長の光の照射によって電子と正孔が表面に生じ、酸化還元反応を生じる。そこで光触媒は、その酸化還元反応により有機化合物等を酸化分解し、空気等を正常化する空気清浄機やタイル、防護壁、ランプ等に利用されている。   Applications of photocatalysts have been developed all over the world for the purpose of sterilization, deodorization, decomposition purification, etc. due to their strong oxidizing power. In the photocatalyst of titanium dioxide, electrons and holes are generated on the surface by irradiation with light of a wavelength of 300 to 400 nm, particularly with ultraviolet rays, and an oxidation-reduction reaction occurs. Therefore, photocatalysts are used in air purifiers, tiles, protective walls, lamps, etc. that oxidize and decompose organic compounds by the oxidation-reduction reaction to normalize air.

二酸化チタンが光触媒反応をするときに、紫外線の300〜400nmの波長を利用することにより紫外線のカット作用があり施設栽培等で施設内部の温度調整にも利用できる。その紫外線カット作用は、女性の化粧品、自動車のガラス、施設栽培での被服資材等にも使用されている。 When titanium dioxide undergoes a photocatalytic reaction, ultraviolet rays can be cut by utilizing the wavelength of 300 to 400 nm of ultraviolet rays, which can also be used for temperature adjustment inside the facility for facility cultivation or the like. The UV-blocking action is also used for women's cosmetics, automobile glass, clothing materials for facility cultivation, and the like.

化学合成の乳化剤・分散剤・界面活性剤・補助成分等を含まない。環境に動植物に安全に使用できる二酸化チタンを光触媒に使用することによって、農薬等の有害有機化合物、環境汚染物質、様々な臭気成分の分解除去及び抗菌・殺菌・ウイルス分解作用等を兼ね備え、化学合成農薬使用の削減を図る事ができる、又、施設栽培等での屋根、外壁等への使用には、紫外線カット作用による施設内作物の高温障害を抑え、害虫の中には紫外線により行動をするものが居てそのような害虫の被害を最小限に抑えることもできる。 Does not contain chemically synthesized emulsifiers, dispersants, surfactants, auxiliary ingredients, etc. By using titanium dioxide that can be safely used for animals and plants in the environment as a photocatalyst, it combines chemical removal with harmful organic compounds such as agricultural chemicals, environmental pollutants, various odorous components, and antibacterial, bactericidal, and viral decomposition. The use of pesticides can be reduced, and for use on roofs, exterior walls, etc. in facility cultivation, etc., the high-temperature damage of crops in the facility due to UV protection is suppressed, and some pests act with UV light There can be things to minimize the damage of such pests.

動植物体に散布する場合、化学合成の補助成分等を含まないことから、人畜・動植物等に安全なオリゴ糖などを展着剤等として0.01%〜10%を添加し、ムラが
ないように丁寧な散布が好ましい。
Since it does not contain chemical synthesis auxiliary ingredients when sprayed on animals and plants, add 0.01% to 10% as a spreading agent, etc., which is safe for human animals, animals and plants, etc. Spraying is preferred.

施設の屋根・外壁・作業場等に散布する場合は、二酸化チタンの希釈液に木工用ボンド等を接着剤として1%〜30%を添加し、ムラがないように丁寧な散布が
好ましい。
When spraying on the roof, outer wall, workplace, etc. of the facility, it is preferable to add 1% to 30% as a bonding agent for woodworking to a diluted solution of titanium dioxide and carefully spray so that there is no unevenness.

今までの、農薬製剤の乳剤・水和剤・フロアブル剤・ゾル剤等と同様に、使用する現場において容易に分散させることにより、農家等が従来から使用してきた噴霧機械等にて容易に散布できるようになった。そのために、作物・病気等を選ばずに紫外線の当たる作物であれば使用で切るようになった。 Like conventional emulsions, wettable powders, flowables, sols, etc. of agricultural chemicals, they can be easily dispersed on the site where they are used, so that they can be easily sprayed on farming machines, etc. I can do it now. For this reason, crops that are exposed to ultraviolet rays can be used without being selected for crops and diseases.

イチゴのうどん粉病よる殺菌・抗菌効果では、7月15日に散布したのでは翌日にはうどん粉病の白い病班が赤褐色に変色し、12月20日散布分では、4日〜5日後に変色した、2回目の散布は7日〜10日ぐらいのほうが良かった14日以上あけると部分的に再発が見られた。又、きゅうりのかっぱん病・べと病では1度散布すると14日〜20日ぐらい散布間隔をあけても良かった。しかし、月に1回〜2回の散布が望ましい。通常の化学合成農薬では得られない効果が得られた。このことから減農薬・無農薬栽培が今まで以上に容易になった。 In the sterilization and antibacterial effect of strawberry powdery mildew, when sprayed on July 15, the white lesion of powdery mildew turned reddish brown on the next day, and on December 20, the color changed after 4 to 5 days. The second spraying was better on the 7th to the 10th, and after 14 days it was partially recurred. In addition, in the case of cucumber's powdery mildew and downy mildew, once sprayed, it was good to leave the spraying interval about 14-20 days. However, spraying once or twice a month is desirable. An effect that cannot be obtained with ordinary chemically synthesized pesticides was obtained. This has made it easier than ever to reduce pesticide-free and pesticide-free cultivation.

二酸化チタンでビニールハウス・ガラス温室等の屋根・外壁等にコーティングすることによって、紫外線がカットされ施設内温度を、3度〜6度下ることが可能になり植物の高温障害等が緩和され、生育が促進し5月〜7月の品質の良い作物が収穫できるようになった。又、害虫の中には紫外線をカットすることによって、行動を阻害されるものも居て害虫による被害も抑えられた。 By coating the roof and outer walls of a greenhouse, glass greenhouse, etc. with titanium dioxide, the ultraviolet rays are cut and the temperature inside the facility can be lowered by 3 to 6 degrees, and the high temperature damage of plants is alleviated and grown. Promoted good quality crops from May to July. In addition, some insect pests were blocked by UV rays, and the damage caused by the insects was suppressed.

安全な農産物の生産という観点からも農業分野での利用、環境浄化・汚染物質の除去という面では農業・林業・土木分野でも利用の可能性は限りないものだ
推測される。
From the viewpoint of safe production of agricultural products, it is speculated that there is no limit to the possibility of use in agriculture, forestry, and civil engineering in terms of use in the agricultural field, environmental purification, and removal of pollutants.

Claims (11)

二酸化チタンを使用した場合は紫外線の光にて、効率よく光触媒反応をする、10nm〜1000nmのアナターゼ型の二酸化チタンが、1%〜50%で構成されるフロアブル状の光触媒式動植物保護剤。   When titanium dioxide is used, it is a flowable photocatalytic animal and plant protective agent composed of 1% to 50% of anatase-type titanium dioxide of 10 nm to 1000 nm, which efficiently performs photocatalytic reaction with ultraviolet light. 成分中に、化学合成製剤の分散剤,乳化剤、界面活性剤、補助成分等が含まれず、人畜・動植物等に安全に直接散布できることを特徴とする請求項1記載の光触媒式動植物保護剤。 2. The photocatalytic animal and plant protection agent according to claim 1, wherein the component does not contain a dispersant, an emulsifier, a surfactant, an auxiliary component, or the like of the chemically synthesized preparation, and can be directly sprayed safely on human animals, animals and plants. 使用する現場において、地下水・水道水・水路等の水で容易に、約2倍〜約5000倍に希釈・分散でき、超低コストで散布できる請求項2記載の光触媒式動植物保護剤。 3. The photocatalyst type animal and plant protection agent according to claim 2, which can be easily diluted and dispersed about 2 to about 5000 times with water such as ground water, tap water, and waterways, and can be sprayed at an ultra-low cost. 通常、農家等で使用されている動力噴霧機・少量噴霧機・スイングフォグ・静電噴霧機・航空防除機等の防除機械類にて容易に散布できる請求項3記載の光触媒式動植物保護剤。 4. The photocatalytic animal and plant protection agent according to claim 3, which can be easily sprayed by a control machine such as a power sprayer, a small amount sprayer, a swing fog, an electrostatic sprayer, an aerial control machine, etc., which are usually used by farmers and the like. 農作物・公園・庭園・森林・街路樹等の残留農薬・有害有機化合物・環境汚染物質等を分解し、新たな有害有機化合物・環境汚染物質等から農作物・公園・庭園・森林・街路樹等を保護することを特徴とする請求項4記載の光触媒式動植物保護剤。 Decompose residual agricultural chemicals, toxic organic compounds, environmental pollutants, etc. in crops, parks, gardens, forests, roadside trees, etc., and produce crops, parks, gardens, forests, roadside trees, etc. from new toxic organic compounds, environmental pollutants, etc. 5. The photocatalytic animal and plant protective agent according to claim 4, which is protected. 農作物・公園・庭園・森林・街路樹等には、様々なカビ・ウイルス・細菌等が発生するが、なかでも施設栽培等ではどうしても、高温多湿になりがちで病気の発生は著しい。そうした
病原菌等をも効果的に分解しその後、新たな病原菌等の感染から農作物等を保護することを特徴とする請求項4記載の光触媒式動植物保護剤。
A variety of molds, viruses, bacteria, etc. occur in crops, parks, gardens, forests, roadside trees, etc., but in particular, the cultivation of facilities tends to be hot and humid, and the occurrence of diseases is remarkable. 5. The photocatalytic animal and plant protection agent according to claim 4, wherein such pathogenic bacteria are also effectively decomposed, and thereafter, crops and the like are protected from infection with new pathogenic bacteria.
畜産農家等の、畜産動物、糞尿、飼料残さ、堆舎、畜舎等全体から出る多種多様の臭気成分を、効果的に分解することを特徴とする請求項4記載の光触媒式動植物保護剤。 5. The photocatalytic animal and plant protective agent according to claim 4, which effectively decomposes various odor components from livestock animals, manure, feed residue, barns, barns, etc., such as livestock farmers. 畜産農家等の、畜舎等で発生するカビ・ウイルス・細菌等ほとんどのものを分解し、新たなウイルス等から畜産動物等を保護することを特徴とする請求項4記載の光触媒式動植物保護剤。 5. The photocatalytic animal and plant protective agent according to claim 4, which decomposes most of molds, viruses, bacteria, etc. generated in livestock farms, etc., such as livestock farmers, and protects livestock animals from new viruses. 農産物等を選別・包装する作業場・加工場では、様々な雑菌等が発生している。そうした雑菌等を効率よく殺菌・抗菌等できることを特徴とする請求項4記載の光触媒式動植物保護剤。 Various germs and the like are generated in workshops and processing plants for sorting and packaging agricultural products. 5. The photocatalytic animal and plant protection agent according to claim 4, which can effectively sterilize and antibacterial such bacteria. 施設栽培・ビニールハウス・ガラス温室等において屋根・外壁等に二酸化チタンをコーティングする事によって紫外線をカットし室内温度を下げることを特徴とする請求項4記載の光触媒式動植物保護剤。 5. The photocatalyst type animal and plant protection agent according to claim 4, wherein ultraviolet rays are cut and indoor temperature is lowered by coating titanium dioxide on a roof, an outer wall, etc. in greenhouse cultivation, a greenhouse, a glass greenhouse, and the like. 害虫の中には、紫外線の光を頼りに行動をしているものもいる。動植物体・施設等の屋根、外壁を二酸化チタンでコーティングする事により、害虫の飛来を少なくし被害も最小限に抑えられることを特徴とする請求項4記載の光触媒式動植物保護剤。 Some pests act on the light of ultraviolet rays. 5. The photocatalytic type animal and plant protective agent according to claim 4, wherein the roof and outer wall of an animal or plant body / facility are coated with titanium dioxide to reduce pests and minimize damage.
JP2004066317A 2004-03-09 2004-03-09 Photocatalytic organism protective agent using titanium dioxide Pending JP2005255558A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007136373A (en) * 2005-11-19 2007-06-07 Hikari Shokubai Kenkyusho:Kk Method and treating agent for hindering attraction of harmful insect by photocatalyst
JP2008050348A (en) * 2006-07-27 2008-03-06 Fujitsu Ltd Plant epidemic prevention agent, method for plant epidemic prevention and plant epidemic prevention system, plant and method for cultivating plant
CN102604595A (en) * 2011-12-15 2012-07-25 宁波百仕高联合工业有限公司 Environment-friendly self-disinfection money counting finger wetting agent and manufacturing method thereof
ITPD20110341A1 (en) * 2011-10-31 2013-05-01 Ultrabatch S R L LAMINAR BODY FOR MAKING GREENHOUSES AND CULTIVATION IN GREENHOUSE
JP2014519401A (en) * 2011-05-04 2014-08-14 スチュワート・ベンソン・アベレット Titanium dioxide photocatalytic composition and use thereof
CN106386259A (en) * 2016-08-31 2017-02-15 孟玲 Novel antibiotic greenhouse
CN107812341A (en) * 2017-10-27 2018-03-20 于建伟 A kind of formaldehyde scavenger, its preparation method and application
JP2019014632A (en) * 2017-07-10 2019-01-31 東ソー株式会社 Titanium oxide-coated mesoporous silica
US11083200B2 (en) 2018-09-14 2021-08-10 Fujifilm Business Innovation Corp. Plant protection agent

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007136373A (en) * 2005-11-19 2007-06-07 Hikari Shokubai Kenkyusho:Kk Method and treating agent for hindering attraction of harmful insect by photocatalyst
JP2008050348A (en) * 2006-07-27 2008-03-06 Fujitsu Ltd Plant epidemic prevention agent, method for plant epidemic prevention and plant epidemic prevention system, plant and method for cultivating plant
JP2014519401A (en) * 2011-05-04 2014-08-14 スチュワート・ベンソン・アベレット Titanium dioxide photocatalytic composition and use thereof
ITPD20110341A1 (en) * 2011-10-31 2013-05-01 Ultrabatch S R L LAMINAR BODY FOR MAKING GREENHOUSES AND CULTIVATION IN GREENHOUSE
WO2013064970A1 (en) * 2011-10-31 2013-05-10 Ultrabatch S.R.L. Laminar body for making greenhouse roofs and method of greenhouse cultivation
CN103957692A (en) * 2011-10-31 2014-07-30 超霸责任有限公司 Laminar body for making greenhouse roofs and method of greenhouse cultivation
JP2015502143A (en) * 2011-10-31 2015-01-22 ウルトラバツチ・ソチエタ・ア・レスポンサビリタ・リミタータ Laminate for producing greenhouse roof and greenhouse cultivation method
US10015933B2 (en) 2011-10-31 2018-07-10 Cytec Industries Inc. Laminar body for making greenhouse roofs and methods of greenhouse cultivation
CN102604595A (en) * 2011-12-15 2012-07-25 宁波百仕高联合工业有限公司 Environment-friendly self-disinfection money counting finger wetting agent and manufacturing method thereof
CN106386259A (en) * 2016-08-31 2017-02-15 孟玲 Novel antibiotic greenhouse
JP2019014632A (en) * 2017-07-10 2019-01-31 東ソー株式会社 Titanium oxide-coated mesoporous silica
CN107812341A (en) * 2017-10-27 2018-03-20 于建伟 A kind of formaldehyde scavenger, its preparation method and application
US11083200B2 (en) 2018-09-14 2021-08-10 Fujifilm Business Innovation Corp. Plant protection agent

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