JP2005188812A - Heat pump type refrigerating apparatus - Google Patents
Heat pump type refrigerating apparatus Download PDFInfo
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- JP2005188812A JP2005188812A JP2003429483A JP2003429483A JP2005188812A JP 2005188812 A JP2005188812 A JP 2005188812A JP 2003429483 A JP2003429483 A JP 2003429483A JP 2003429483 A JP2003429483 A JP 2003429483A JP 2005188812 A JP2005188812 A JP 2005188812A
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- 239000003507 refrigerant Substances 0.000 claims abstract description 65
- 238000010438 heat treatment Methods 0.000 claims abstract description 36
- 239000002826 coolant Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 46
- 238000001816 cooling Methods 0.000 claims description 35
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 238000005057 refrigeration Methods 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 238000010257 thawing Methods 0.000 claims description 5
- 230000035939 shock Effects 0.000 abstract description 2
- 238000004378 air conditioning Methods 0.000 abstract 3
- 239000007789 gas Substances 0.000 description 11
- 239000007788 liquid Substances 0.000 description 6
- 238000005219 brazing Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Air Conditioning Control Device (AREA)
Abstract
Description
本発明はヒートポンプ式の冷凍装置に関する。 The present invention relates to a heat pump type refrigeration apparatus.
ヒートポンプ式の冷凍装置においては、負荷側からの水等の冷却媒体と冷媒との熱交換を行なう熱交換器に、冷房(冷却)運転時には凝縮冷媒を減圧して供給し、暖房(加熱)運転時には圧縮機からの高温吐出冷媒ガスを供給している。 In a heat pump type refrigeration system, the refrigerant is decompressed and supplied to a heat exchanger that performs heat exchange between a cooling medium such as water from the load side and the refrigerant during cooling (cooling) operation, and heating (heating) operation is performed. Sometimes, high-temperature discharged refrigerant gas from the compressor is supplied.
したがって、冷房運転と暖房運転の切り替えが頻繁に行なわれると、上記熱交換器には冷房運転における低温の冷媒と暖房運転における高温の冷媒が供給されて急激な温度変化を繰り返すことになり、この急激な温度変化は熱交換器の損傷の原因となる。 Therefore, when switching between the cooling operation and the heating operation is frequently performed, the heat exchanger is supplied with a low-temperature refrigerant in the cooling operation and a high-temperature refrigerant in the heating operation, and the rapid temperature change is repeated. Sudden temperature changes can cause damage to the heat exchanger.
具体的には、熱交換器の構成部材の接合部に、温度変化による各部材の寸法変化に伴う応力が集中し、接合部やその周辺部分が破損するケースがある。
このような接合部の破損は冷媒の漏洩の原因となり、装置の運転が安定して行なわれなくなるという問題を惹き起すだけでなく、例えばアンモニアのような毒性を有する冷媒を使用する場合には、負荷側へ供給する冷却媒体への有毒冷媒の混入や装置周囲への有毒ガスの漏洩という重大な問題の原因となる。
Specifically, there is a case where stress accompanying the dimensional change of each member due to temperature change concentrates on the joint part of the constituent members of the heat exchanger, and the joint part and its peripheral part are damaged.
Such damage to the joint causes leakage of the refrigerant and not only causes a problem that the operation of the apparatus is not stably performed, but also when using a toxic refrigerant such as ammonia, This causes serious problems such as mixing of toxic refrigerant into the cooling medium supplied to the load side and leakage of toxic gas around the apparatus.
特に、熱交換器の各部材がろう付けにより接合されているもの、例えばブレージングタイプのプレート熱交換器は接合部の損傷が懸念され、このブレージングタイプのプレート熱交換器は小型で熱交換効率に優れているのに、冷房運転と暖房運転が頻繁に切り替えられるような使用環境のヒートポンプ式冷凍装置における熱交換器としては決して好適なものとはいえない。 In particular, there is a concern about damage to the joints of heat exchanger components that are joined by brazing, for example, brazing type plate heat exchangers. This brazing type plate heat exchanger is small in size and heat exchange efficiency. Although it is excellent, it cannot be said to be suitable as a heat exchanger in a heat pump refrigeration system in a usage environment in which the cooling operation and the heating operation are frequently switched.
また、上述のような温度の急激な変化に耐え得るように熱交換器を耐久性の高い素材や構造のものとすると、製作コストの上昇を招いたり、熱交換器の寸法が大となって装置の小型化の障害となったりするおそれがある。 Also, if the heat exchanger is made of a highly durable material or structure so that it can withstand rapid changes in temperature as described above, it will cause an increase in manufacturing costs and the size of the heat exchanger will increase. There is a risk of downsizing the device.
さらに近年、自然冷媒の見直しから冷媒としてアンモニアが採用されるケースが増加してきており、アンモニアはフロン系の冷媒に比して吐出ガス温度が高いので、運転切替に伴う熱交換器の温度変化はより大であり、熱交換器の損傷を未然に防止する配慮がより高度に求められる。 Furthermore, in recent years, ammonia has been increasingly used as a refrigerant due to the review of natural refrigerants. Since ammonia has a higher discharge gas temperature than chlorofluorocarbon refrigerants, the temperature change of heat exchangers associated with operation switching Therefore, a higher degree of consideration is required to prevent damage to the heat exchanger.
本発明は、負荷側の熱交換器における冷房運転時と暖房運転時の温度変化を小なるものに抑えることができて、冷房運転と暖房運転の切替が頻繁に行なわれても熱交換器への温度変化に伴うショックを軽減でき、従来から使用されている構造の熱交換器を使用することができて装置コストの上昇を招くことなく熱交換器の寿命を向上させることができるヒートポンプ式冷凍装置を提供することを課題とする。 The present invention can suppress the temperature change during the cooling operation and the heating operation in the heat exchanger on the load side to be small, and to the heat exchanger even if the switching between the cooling operation and the heating operation is frequently performed. Heat pump refrigeration that can reduce the shock caused by temperature changes and can improve the life of the heat exchanger without increasing the cost of the equipment by using a heat exchanger with a conventional structure It is an object to provide an apparatus.
上記目的を達成するために、本発明に係る装置は、圧縮した冷媒を吐出する冷媒圧縮機と、冷房運転時には凝縮器として作用し、暖房運転時には蒸発器として作用する第1の熱交換器と、冷房運転時には蒸発器として作用し、暖房運転時には凝縮器として作用して負荷側へ送られる水等の冷却媒体と熱交換する第2の熱交換器を備え、冷房運転時には圧縮機からの吐出冷媒が第1の熱交換器、第2の熱交換器の順に送られて圧縮機に戻され、暖房運転時には圧縮機からの吐出冷媒が第2の熱交換器、第1の熱交換器の順に送られて圧縮機に戻されるように、冷媒配管の途中に設けた切替弁によって切り替えられるヒートポンプ式冷凍装置において、前記第2の熱交換器と前記切替弁との間に第3の熱交換器を設け、負荷側からの冷却媒体が第3の熱交換器と第2の熱交換器をこの順に流過せしめるように構成したものとしてあり、また、前記冷媒をアンモニアとした構成のものとしてある。 In order to achieve the above object, an apparatus according to the present invention includes a refrigerant compressor that discharges a compressed refrigerant, a first heat exchanger that acts as a condenser during cooling operation and acts as an evaporator during heating operation, A second heat exchanger that acts as an evaporator during cooling operation, acts as a condenser during heating operation, and exchanges heat with a cooling medium such as water sent to the load side, and discharges from the compressor during cooling operation The refrigerant is sent in the order of the first heat exchanger and the second heat exchanger and returned to the compressor. During the heating operation, the refrigerant discharged from the compressor is supplied to the second heat exchanger and the first heat exchanger. In the heat pump refrigeration apparatus that is switched by a switching valve provided in the middle of the refrigerant pipe so as to be sent back in order and returned to the compressor, a third heat exchange is performed between the second heat exchanger and the switching valve. A cooling medium from the load side. There a heat exchanger and a second heat exchanger as configured as occupied spend flow in this order, and there as a configuration in which the refrigerant and ammonia.
また本発明に係る装置は、前記第2の熱交換器の冷媒入口において冷房運転時に冷媒の減圧を行なう膨張弁の開度を、前記第3の熱交換器の冷媒出口温度に基づいて制御するように構成したものとしてある。 The apparatus according to the present invention controls the opening degree of the expansion valve that decompresses the refrigerant during cooling operation at the refrigerant inlet of the second heat exchanger based on the refrigerant outlet temperature of the third heat exchanger. The configuration is as follows.
さらに本発明に係る装置は、前記切替弁が暖房運転時において所要の時間的間隔で冷房運転時の状態に切り替えられて、前記第1の熱交換器における逆サイクルによる除霜運転が行なわれる構成としてある。 Furthermore, the apparatus according to the present invention is configured such that the switching valve is switched to the cooling operation state at a required time interval during the heating operation, and the defrosting operation by the reverse cycle in the first heat exchanger is performed. It is as.
以下、本発明に係る装置の実施例を添付図面に示す具体例に基づいて詳細に説明する。
圧縮機1の吐出口に一端が接続された吐出管2の他端が切替弁たる四方弁3の第1ポート3aに接続され、同四方弁3の第2ポート3bに一端が接続された第1冷媒管4の他端が、第1の熱交換器たる空気熱交換器5、第1逆止弁6および第1膨張弁7を介して第2の熱交換器たる水熱交換器8の第1冷媒管接続口8aに接続されている。
なお上記水熱交換器8は、小型で熱交換効率の高い熱交換器、例えばブレージングタイプのプレート熱交換器で構成してある。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the apparatus according to the present invention will be described below in detail based on specific examples shown in the accompanying drawings.
The other end of the discharge pipe 2 whose one end is connected to the discharge port of the
The water heat exchanger 8 is a small heat exchanger having a high heat exchange efficiency, for example, a brazing type plate heat exchanger.
上記水熱交換器8の第2冷媒管接続口8bに一端が接続された第2冷媒管9の他端が前記四方弁3の第3ポート3cに接続され、同四方弁3の第4ポート3dに一端が接続された吸入管10の他端がアキュムレータ11を介して圧縮機の吸入口に接続されている。
The other end of the
また、前記第1逆止弁6を跨ぐ第1バイパス管12には第2膨張弁13が設けられ、かつ、前記第1膨張弁7を跨ぐ第2バイパス管14には第2逆止弁15を設けてある。
A
しかして前記第2冷媒管9の途中には第3の熱交換器たるサブ熱交換器16を設けてあり、被空調室17の空調器17a等の負荷側からの冷熱媒体たる例えば水がサブ熱交換器16と前記水熱交換器8とをこの順に流過するようになっていて、上記サブ熱交換器16には、温度変化に対する強度が大である熱交換器が好適であり、例えば多重管タイプの熱交換器を用いる。
Accordingly, a
具体的には前記空調器17aからの冷・温水戻り管18がサブ熱交換器16の水入口16cに接続され、同出口16dに一端が接続された冷・温水管19の他端が水熱交換器8の水入口8cに接続され、同出口8dに一端が接続された冷・温水送り管20の他端が空調器17aに接続されている。
なお、図中の符号16a、16bは冷媒管接続口を示している。
Specifically, the cold / hot
In addition, the code |
上述した構成の装置において、前記第1の熱交換器たる空気熱交換器5は装置の冷房運転時には凝縮器、暖房運転時には蒸発器として作用し、また、前記第2の熱交換器たる水熱交換器8および第3の熱交換器たるサブ熱交換器16は装置の冷房運転時には蒸発器、暖房運転時には凝縮器として作用し、以下に冷房運転時と暖房運転時における装置の作用について説明する。
In the apparatus having the above-described configuration, the air heat exchanger 5 serving as the first heat exchanger functions as a condenser during the cooling operation of the apparatus, and serves as an evaporator during the heating operation, and the water heat serving as the second heat exchanger. The exchanger 8 and the
図1は冷房運転時(冷水供給運転時)における冷媒の流れを示した構成図であり、圧縮機1からの冷媒(本実施例ではアンモニア)は四方弁3の第1ポート3aから第2ポート3bを流過して空気熱交換器5に送られ、同空気熱交換器における空気との熱交換によって凝縮し、液冷媒となって第1逆止弁6を経て第1膨張弁7にて減圧され、水熱交換器8における負荷側からの水との熱交換(水の冷却)により気化する。
FIG. 1 is a configuration diagram showing the flow of refrigerant during cooling operation (during cold water supply operation). The refrigerant (ammonia in this embodiment) from the
なお、上記第1膨張弁7の開度制御は、サブ熱交換器16の冷媒出口温度に基づいて行なう。
The opening degree control of the first expansion valve 7 is performed based on the refrigerant outlet temperature of the
気化した冷媒はサブ熱交換器16においてさらに負荷側からの水と熱交換し、水熱交換器8では気化しきれなかった液冷媒の蒸発潜熱と冷媒ガスの顕熱を奪い、その後四方弁3の第3ポート3cから第4ポート3dを経て吸入管10に入り、アキュムレータにて気液分離されて圧縮機に戻される。
The vaporized refrigerant further exchanges heat with the water from the load side in the
すなわち、負荷側からの戻り冷水はまずサブ熱交換器16である程度冷却され、さらに水熱交換器8で所要の温度に冷却される。
なお、図1中の水熱交換器8およびサブ熱交換器16の冷媒出入口および水出入口には各部位における冷媒や水の温度の値の例を付した。
That is, the return cold water from the load side is first cooled to some extent by the
In addition, the example of the value of the temperature of the refrigerant | coolant and water in each site | part was attached | subjected to the refrigerant | coolant inlet / outlet of the water heat exchanger 8 and the
暖房運転時(温水供給運転時)においては、図2に示されるように圧縮機1からの冷媒が四方弁3の第1ポート3aから第3ポート3cを流過してサブ熱交換器16に送られ、このサブ熱交換器にて負荷側からの水をある程度加熱して水熱交換器8に送られ、同水熱交換器における負荷側からの水との熱交換(水を加熱)によって凝縮し、液冷媒となって第2逆止弁15を経て第2膨張弁13にて減圧され、空気熱交換器5にて空気との熱交換により気化する。
In the heating operation (during hot water supply operation), as shown in FIG. 2, the refrigerant from the
気化した冷媒は四方弁3の第2ポート3bから第4ポート3dを経て吸入管10に入り、アキュムレータにて気液分離されて圧縮機に戻される。
The vaporized refrigerant enters the
しかして、水熱交換器8の温度は冷房運転時においては従来の装置における水熱交換器の温度と変わりはないが、暖房運転時においては圧縮機1からの高温吐出ガスがサブ熱交換器16における負荷側からの水との熱交換によって温度降下し、したがって冷房運転時と暖房運転時における水熱交換器の温度差は従来のものよりも小となる。
Thus, the temperature of the water heat exchanger 8 is not different from the temperature of the water heat exchanger in the conventional apparatus during the cooling operation, but the hot discharge gas from the
なお、図2中の水熱交換器8およびサブ熱交換器16の冷媒出入口および水出入口には各部位における冷媒や水の温度の値の例を付した。
In addition, the example of the value of the temperature of the refrigerant | coolant and water in each site | part was attached | subjected to the refrigerant | coolant inlet / outlet and water inlet / outlet of the water heat exchanger 8 and the
したがって、水熱交換器8においては冷房運転時と暖房運転時の温度変化が小となるので、冷房運転と暖房運転が頻繁に切り替えられても急激な温度変化による損傷を抑制することができ、水熱交換器の長寿命化を図ることができる。 Accordingly, since the temperature change during the cooling operation and the heating operation is small in the water heat exchanger 8, damage due to a rapid temperature change can be suppressed even when the cooling operation and the heating operation are frequently switched. The life of the water heat exchanger can be extended.
ところで、上述した実施例の装置においては、暖房運転時において第1の熱交換器たる空気熱交換器5に空気中の水分の凝縮による着霜するが、空気熱交換器に付着した霜の除霜運転は、所要の時間的間隔で切替弁たる四方弁3が暖房運転の状態から冷房運転の状態に自動的に切り替えられ、圧縮機1からの高温吐出冷媒を空気熱交換器5へ供給するいわゆる逆サイクル運転により行なう。
By the way, in the apparatus of the Example mentioned above, although the frost formation by the condensation of the water | moisture content in air is carried out to the air heat exchanger 5 which is a 1st heat exchanger at the time of heating operation, removal of the frost adhering to an air heat exchanger is carried out. In the frost operation, the four-
上述した逆サイクルによる除霜運転においては、第2の熱交換器たる水熱交換器8にも逆サイクル運転に伴う温度変化が生じるが、この場合においてもサブ熱交換器を介在せしめてあるので、前述した冷房運転・暖房運転の切替に伴う温度変化の抑制と同様に急激な温度変化が防止される。この除霜運転は例えば1時間に1回というように頻繁に行なわれるので、水熱交換器8の温度変化による損傷を防止する効果は顕著である。 In the defrosting operation by the reverse cycle described above, the temperature change accompanying the reverse cycle operation also occurs in the water heat exchanger 8 as the second heat exchanger, but even in this case, the sub heat exchanger is interposed. Similarly to the suppression of the temperature change accompanying the switching between the cooling operation and the heating operation described above, the rapid temperature change is prevented. Since this defrosting operation is frequently performed, for example, once per hour, the effect of preventing damage due to temperature change of the water heat exchanger 8 is remarkable.
なお、上述した実施例においてはアンモニア冷媒の冷凍装置について説明したが、他の冷媒を使用する装置にも適用することができるし、特に吐出ガス温度が高温となる冷媒を使用する装置には好適である。 In the above-described embodiments, the ammonia refrigerant refrigeration apparatus has been described. However, the present invention can be applied to an apparatus using other refrigerants, and is particularly suitable for an apparatus using a refrigerant whose discharge gas temperature is high. It is.
本発明に係る装置は上述した構成のものとしてあるので、暖房運転時においては負荷側の熱交換器である第2の熱交換器には、第3の熱交換器にてある程度温度が降下した吐出冷媒ガスが供給される。 Since the apparatus according to the present invention has the above-described configuration, the temperature of the second heat exchanger, which is a heat exchanger on the load side, is lowered to some extent by the third heat exchanger during heating operation. Discharged refrigerant gas is supplied.
したがって、暖房運転における第2の熱交換器の温度を低く抑えることができ、冷房運転と暖房運転が頻繁に切り替えられても第2の熱交換器の温度変化を小ならしめることができて、従来から使用されている素材、構造の熱交換器を採用しても熱交換器の損傷のおそれはまずなく、冷媒の漏洩防止および熱交換器の長寿命化を期すことができ、特に吐出冷媒ガス温度が高温であるアンモニア冷媒を使用する装置に好適である。 Therefore, the temperature of the second heat exchanger in the heating operation can be kept low, and even if the cooling operation and the heating operation are frequently switched, the temperature change of the second heat exchanger can be reduced, Even if heat exchangers with conventional materials and structures are used, there is no risk of damage to the heat exchanger, and it is possible to prevent refrigerant leakage and extend the life of the heat exchanger. It is suitable for an apparatus using an ammonia refrigerant having a high gas temperature.
また、暖房運転において第2の熱交換器へ供給される吐出ガスの温度を第3の熱交換器において降下せしめる冷熱源は負荷側から戻される水等の冷熱媒体であるので、吐出ガスの熱は確実に冷熱媒体に伝達されて冷熱の利用に無駄がなく、しかも冷房運転時、暖房運転時ともに第3の熱交換器を設けてある分、冷媒と負荷側からの冷却媒体との間の熱交換面積が大となり、熱交換効率を向上せしめることができる。 In addition, since the cold source that lowers the temperature of the discharge gas supplied to the second heat exchanger in the heating operation in the third heat exchanger is a cold medium such as water returned from the load side, the heat of the discharge gas Is reliably transmitted to the cooling medium, and there is no waste in the use of the cooling heat, and the third heat exchanger is provided for both the cooling operation and the heating operation, so that there is no difference between the refrigerant and the cooling medium from the load side. The heat exchange area becomes large, and the heat exchange efficiency can be improved.
なお、冷房運転時には第3の熱交換器の冷媒出口温度に基づいて第2の熱交換器における冷媒入口の膨張弁の開度を制御するので、第2の熱交換器における蒸発域面積を広くとることができ、効率のよい熱交換を行なうことができる。 Note that, during the cooling operation, the opening degree of the expansion valve at the refrigerant inlet in the second heat exchanger is controlled based on the refrigerant outlet temperature of the third heat exchanger, so that the evaporation area in the second heat exchanger is widened. Therefore, efficient heat exchange can be performed.
また、本発明の装置は第2の熱交換器と切替弁との間に第3の熱交換器を配設するだけの簡単な構成であり、また第3の熱交換器にも一般的に使用されている熱交換器を採用できるので、容易に製作することが可能であり、しかも既存の装置にも適用が可能であるという実用上の極めて大なるメリットがある。 In addition, the apparatus of the present invention has a simple configuration in which a third heat exchanger is simply disposed between the second heat exchanger and the switching valve, and is generally used for the third heat exchanger. Since the used heat exchanger can be adopted, it can be easily manufactured, and there is an extremely great merit in practical use that it can be applied to an existing apparatus.
さらに、本発明の装置は通常の冷房運転と暖房運転の切替に伴う第2の熱交換器への急激な温度変化を防止できるだけでなく、逆サイクル運転によって暖房時における第1の熱交換器の除霜運転が行なわれる場合にも同様に急激な温度変化を防止することができる。 Furthermore, the apparatus of the present invention not only prevents a sudden temperature change to the second heat exchanger due to switching between normal cooling operation and heating operation, but also reverses the first heat exchanger during heating by reverse cycle operation. Similarly, when the defrosting operation is performed, a sudden temperature change can be prevented.
1 圧縮機
2 吐出管
3 四方弁
4 第1冷媒管
5 空気熱交換器
6 第1逆止弁
7 第1膨張弁
8 水熱交換器
9 第2冷媒管
10 吸入管
11 アキュムレータ
12 第1バイパス管
13 第2膨張弁
14 第2バイパス管
15 第2逆止弁
16 サブ熱交換器
18 冷・温水戻り管
19 冷・温水管
20 冷・温水送り管
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100775517B1 (en) * | 2006-04-13 | 2007-11-15 | (주)팀코리아 | Heat interchanging system for manufacturing equipment of semiconductor capable of removing moisture and fluorine in a coolant |
JP2013174383A (en) * | 2012-02-24 | 2013-09-05 | Mitsubishi Electric Corp | Air conditioner |
US9366452B2 (en) | 2009-05-12 | 2016-06-14 | Mitsubishi Electric Corporation | Air-conditioning apparatus with primary and secondary heat exchange cycles |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100775517B1 (en) * | 2006-04-13 | 2007-11-15 | (주)팀코리아 | Heat interchanging system for manufacturing equipment of semiconductor capable of removing moisture and fluorine in a coolant |
US9366452B2 (en) | 2009-05-12 | 2016-06-14 | Mitsubishi Electric Corporation | Air-conditioning apparatus with primary and secondary heat exchange cycles |
US9534807B2 (en) | 2009-05-12 | 2017-01-03 | Mitsubishi Electric Corporation | Air conditioning apparatus with primary and secondary heat exchange cycles |
JP2013174383A (en) * | 2012-02-24 | 2013-09-05 | Mitsubishi Electric Corp | Air conditioner |
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