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JP2005144212A - Method and system for controlling adhesion and growth of marine organism - Google Patents

Method and system for controlling adhesion and growth of marine organism Download PDF

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JP2005144212A
JP2005144212A JP2003380966A JP2003380966A JP2005144212A JP 2005144212 A JP2005144212 A JP 2005144212A JP 2003380966 A JP2003380966 A JP 2003380966A JP 2003380966 A JP2003380966 A JP 2003380966A JP 2005144212 A JP2005144212 A JP 2005144212A
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seawater
cooling water
sea
growth
valve
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Kenji Tokumasa
賢治 徳政
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Chugoku Electric Power Co Inc
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Chugoku Electric Power Co Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To control the concentration of chlorine in seawater discharged into sea at low level while effectively controlling the adhesion and growth of marine organisms, such as shellfishes, adhering to the passage composing a cooling water system with a chlorine-based chemical when cooling target equipment with seawater. <P>SOLUTION: A chemical injection part 32 is installed in the vicinity of the water intake port 24 of a water intake passage 20 supplying seawater to a steam condenser in a thermal power plant as cooling water. The chemical injection part 32 is composed of an injection pipe 40 having an inlet 41 in the water intake passage 20, a chemical supply tank 42 for supplying a sodium hypochlorite solution to the injection pipe 40, and a valve 44 installed in the injection pipe 40. The opening and closing of the valve 44 is controlled by a control device 46. By opening and closing the valve 44 with the control device 46, the sodium hypochlorite solution is injected intermittently. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、火力発電所の復水器等の冷却対象設備に冷却水として海水を供給する冷却水流路内において海洋生物の付着及び成長を抑制するための方法及びシステムに関する。   The present invention relates to a method and a system for suppressing adhesion and growth of marine organisms in a cooling water flow path for supplying seawater as cooling water to a cooling target facility such as a condenser of a thermal power plant.

冷却水として海水を利用する火力発電所においては、海から海水を取り入れて復水器に供給する取水路や、復水器を通った海水を海へ放出するための放水路の内部に貝等の海洋生物が付着し易い。かかる海洋生物の付着量が多くなると、冷却水の流路が塞がれて冷却性能が低下するなどの不具合を招くおそれがある。そこで、従来より、例えば、特許文献1や特許文献2に開示されるように、次亜塩素酸ナトリウム溶液や二酸化塩素等の塩素系薬剤を冷却水の流路に注入することにより、流路において海洋生物の付着及び成長を抑制することが行われている。
特開平7−265867号公報 特開平11−37666号公報
In thermal power plants that use seawater as cooling water, shells, etc. are placed inside the intake channel that takes seawater from the ocean and supplies it to the condenser, and the discharge channel that releases the seawater that has passed through the condenser to the ocean. The marine life is easy to adhere. When the adhesion amount of such marine organisms increases, there is a risk of causing problems such as blocking the cooling water flow path and lowering the cooling performance. Therefore, conventionally, as disclosed in, for example, Patent Document 1 and Patent Document 2, by injecting a chlorine-based chemical such as sodium hypochlorite solution or chlorine dioxide into the flow path of cooling water, Suppression of the attachment and growth of marine organisms has been carried out.
JP-A-7-265867 Japanese Patent Laid-Open No. 11-37666

上述のように、火力発電所において冷却水として利用された後の海水は海へ放出されるが、環境保全のために、海への放出水に含まれる塩素濃度(残留塩素濃度)は一定の協定値以下であることが要求される。したがって、海洋生物を除去するための塩素系薬剤の注入量も、上記の要求を満足できるように制限しなければならず、この制限の範囲内で十分な除去効果を得ることは容易でない。   As mentioned above, seawater after being used as cooling water in thermal power plants is released to the sea, but for environmental conservation, the chlorine concentration (residual chlorine concentration) contained in the discharged water to the sea is constant. It is required to be below the agreed value. Therefore, the injection amount of the chlorinated chemical for removing marine organisms must be limited so as to satisfy the above requirements, and it is not easy to obtain a sufficient removal effect within the limits.

本発明は上記の点に鑑みてなされたものであり、冷却対象設備を海水により冷却するにあたり、冷却水流路内において海洋生物の付着及び成長を塩素系薬剤で効果的に抑制しつつ、海へ放出される海水中の塩素濃度を低く抑えることができるようにすることを目的とする。   The present invention has been made in view of the above points, and when cooling a facility to be cooled with seawater, the adhesion and growth of marine organisms are effectively suppressed with a chlorine-based chemical in the cooling water flow path, while entering the sea. The purpose is to make it possible to keep the chlorine concentration in the released seawater low.

上記の目的を達成するため、請求項1に記載された発明は、冷却水として海から海水を取り入れて冷却対象設備に供給し、この冷却対象設備を通った後の海水を海へ放出するための冷却水流路内において海洋生物の付着及び成長を抑制する方法であって、前記冷却水流路へ塩素系薬剤を間欠的に注入することを特徴とする。   In order to achieve the above object, the invention described in claim 1 is for taking seawater from the sea as cooling water and supplying it to the facility to be cooled, and discharging the seawater after passing through the facility to be cooled to the sea. This is a method for suppressing the adhesion and growth of marine organisms in the cooling water flow path, characterized by intermittently injecting a chlorine-based chemical into the cooling water flow path.

本発明によれば、塩素系薬剤の注入が間欠的に行われるので、注入位置での残留塩素濃度はパルス状に変化する。この塩素濃度は、冷却水が下流側へ流れるにつれて次第に平準化していき、海への放出位置における残留塩素濃度はほぼ一定の小さな値となる。したがって、本発明によれば、冷却水流路内の残留塩素濃度のピーク値を大きく確保して、海洋生物の付着及び成長を効果的に抑制しつつ、海へ放出される海水中の残留塩素濃度を低く抑えることができる。   According to the present invention, since the chlorine-based chemical is injected intermittently, the residual chlorine concentration at the injection position changes in a pulse shape. This chlorine concentration is gradually leveled as the cooling water flows downstream, and the residual chlorine concentration at the discharge position to the sea becomes a substantially constant small value. Therefore, according to the present invention, the residual chlorine concentration in the seawater released to the sea is secured while ensuring a large peak value of the residual chlorine concentration in the cooling water flow path and effectively suppressing the adhesion and growth of marine organisms. Can be kept low.

また、請求項2に記載された発明は、請求項1記載の方法において、前記塩素系薬剤として次亜塩素酸ナトリウムを注入することを特徴とする。   The invention described in claim 2 is characterized in that, in the method according to claim 1, sodium hypochlorite is injected as the chlorinated drug.

また、請求項3に記載された発明は、冷却水として海水を冷却対象設備に供給するための冷却水流路内において海洋生物の付着及び成長を抑制するシステムであって、
前記冷却水流路内へ塩素系薬剤を注入するための注入管と、
前記注入管に設けられた開閉バルブと、
前記開閉バルブを間欠的に開閉させる制御手段と、を備えることを特徴とする。
The invention described in claim 3 is a system that suppresses the adhesion and growth of marine organisms in a cooling water flow path for supplying seawater as cooling water to a facility to be cooled,
An injection tube for injecting a chlorine-based chemical into the cooling water flow path;
An on-off valve provided in the injection pipe;
And a control means for intermittently opening and closing the opening / closing valve.

本発明によれば、冷却対象設備を海水により冷却するにあたり、冷却水流路内において貝等の海洋生物の付着及び成長を塩素系薬剤で効果的に抑制しつつ、海へ放出される海水中の塩素濃度を低く抑えることができる。   According to the present invention, when cooling a facility to be cooled with seawater, while the adhesion and growth of shellfish and other marine organisms are effectively suppressed with a chlorine-based chemical in the cooling water flow path, Chlorine concentration can be kept low.

図1は、本発明の一実施形態に係わる火力発電所10の概略平面図である。同図に示す如く、火力発電所10は海2に臨む敷地に建設されている。火力発電所10には、燃料貯蔵設備12、LNGタンク14、発電設備16等の各種設備が設けられている。本実施形態では、発電設備16に設けられた復水器18を海水で冷却するものとしており、海2から海水を取り込んで復水器18へ供給するための取水路20と、復水器18を通った海水を海2へ放出するための放水路22とが設置されている。海水は取水路20の先端の取水口24から取り込まれ、取水路20を流れて復水器18を通過し、放水路22を流れてその先端の放水口26から海2へ放出される。なお、取水路20及び放水路22が本発明の「冷却水流路」に相当する。   FIG. 1 is a schematic plan view of a thermal power plant 10 according to an embodiment of the present invention. As shown in the figure, the thermal power plant 10 is constructed on a site facing the sea 2. The thermal power plant 10 is provided with various facilities such as a fuel storage facility 12, an LNG tank 14, and a power generation facility 16. In this embodiment, the condenser 18 provided in the power generation facility 16 is cooled with seawater. The intake 20 for taking seawater from the sea 2 and supplying it to the condenser 18, and the condenser 18. A water discharge channel 22 for discharging the seawater that has passed through to the sea 2 is installed. Seawater is taken in from the intake port 24 at the tip of the intake channel 20, flows through the intake channel 20, passes through the condenser 18, flows through the discharge channel 22, and is discharged from the discharge port 26 at the tip of the intake channel 20. The intake channel 20 and the discharge channel 22 correspond to the “cooling water channel” of the present invention.

上記のように、取水路20及び放水路22には海水が流れるため、流路内には貝等の海洋生物が付着・繁殖し易い。そして、流路内に多量の海洋生物が付着すると、流路が塞がれて十分な流量が得られなくなる等のために冷却性能が低下するおそれがある。特に、取水路20については、低い水温の海水を取り込めるように、取水口24が陸地からかなり離れた沖合いに設けられるため、取水路20は非常に長くなって、海洋生物の付着の影響を受け易い。   As described above, since seawater flows through the intake channel 20 and the discharge channel 22, marine organisms such as shellfish are easily attached and propagated in the channel. If a large amount of marine organisms adhere to the flow path, the flow performance may be reduced because the flow path is blocked and a sufficient flow rate cannot be obtained. In particular, with regard to the intake channel 20, since the intake 24 is provided offshore far away from the land so that low temperature seawater can be taken in, the intake channel 20 becomes very long and is affected by the attachment of marine organisms. easy.

そこで、本実施形態では、取水路20の取水口24近傍の地点で、取水路20に、塩素系薬剤として次亜塩素酸ナトリウム溶液を注入することにより、取水路20や放水路22内壁面における貝等の海洋生物の付着や成長を抑制することとしている。ただし、次亜塩素酸ナトリウムに限らず、例えば二酸化塩素等の他の塩素系薬剤を用いてもよい。   Therefore, in this embodiment, by injecting a sodium hypochlorite solution as a chlorinated chemical into the intake channel 20 at a point near the intake port 24 of the intake channel 20, the inner wall surface of the intake channel 20 or the discharge channel 22. Suppresses the adhesion and growth of marine organisms such as shellfish. However, it is not limited to sodium hypochlorite, and other chlorinated chemicals such as chlorine dioxide may be used.

図2は、取水路20及び放水路22からなる冷却水系統28を模式図的に示す。同図に示す如く、復水器18と取水路20との接続部には、海水ポンプ30が設けられており、この海水ポンプ30により海水が取水口24から取水路20へ吸入される。取水路20の取水口24の近傍には、薬剤注入部32が設けられている。また、放水路22の放水口26の近傍には、海2へ放出される海水中の残留塩素濃度を検出する残留塩素濃度計34が設けられている。残留塩素濃度計34による検出信号は無線又は有線で陸地上に設けられた監視装置へ送られる。   FIG. 2 schematically shows a cooling water system 28 including a water intake channel 20 and a water discharge channel 22. As shown in the figure, a seawater pump 30 is provided at a connection portion between the condenser 18 and the intake channel 20, and seawater is drawn into the intake channel 20 from the intake port 24 by the seawater pump 30. A drug injection part 32 is provided in the vicinity of the water intake 24 of the water intake path 20. Further, a residual chlorine concentration meter 34 for detecting the residual chlorine concentration in the seawater discharged to the sea 2 is provided in the vicinity of the water outlet 26 of the water discharge channel 22. The detection signal from the residual chlorine concentration meter 34 is sent wirelessly or by wire to a monitoring device provided on land.

図3は、薬剤注入部32の詳細構成を示す。同図に示す如く、薬剤注入部32は、取水路20の内部に注入口41を有する注入管40、注入管40に次亜塩素酸ナトリウム溶液を供給する薬剤供給槽42、及び、注入管40に設けられたバルブ44により構成されており、バルブ44の開閉は制御装置46により制御される。図3に示す例では、注入管40の先端が海水の下流側へ向けて屈曲され、その先端に注入口41が設けられている。なお、図4に示すように、注入管40の先端部の断面が注入口41へ向けて次第に拡がるように構成してもよい。また、図5に示すように、注入管40を屈曲させずに、その下流側側面に設けた穴を注入口41としてもよい。このように、注入口41として様々な構成が考えられる。   FIG. 3 shows a detailed configuration of the drug injection unit 32. As shown in the figure, the drug injection section 32 includes an injection pipe 40 having an injection port 41 inside the intake channel 20, a drug supply tank 42 for supplying a sodium hypochlorite solution to the injection pipe 40, and an injection pipe 40. The opening and closing of the valve 44 is controlled by a control device 46. In the example shown in FIG. 3, the tip of the injection tube 40 is bent toward the downstream side of the seawater, and an injection port 41 is provided at the tip. In addition, as shown in FIG. 4, you may comprise so that the cross section of the front-end | tip part of the injection tube 40 may spread toward the injection port 41 gradually. Further, as shown in FIG. 5, a hole provided on the downstream side surface may be used as the injection port 41 without bending the injection tube 40. Thus, various structures can be considered as the injection port 41.

なお、注入管40は、好ましくは、取水路20の壁面近傍での残留塩素濃度が高くなるように壁面に沿って取り付けられる。その場合、取水路20の底部には汚泥が堆積するため、側部又は上部の壁面に沿って取り付けるものとする。また、注入管40を複数本設けてもよい。   The injection pipe 40 is preferably attached along the wall surface so that the residual chlorine concentration in the vicinity of the wall surface of the intake channel 20 is high. In that case, since sludge accumulates in the bottom part of the intake channel 20, it shall be attached along the wall surface of a side part or an upper part. A plurality of injection tubes 40 may be provided.

図6は、制御装置46により制御されるバルブ44の開閉状態(すなわち、薬剤注入のオン/オフの時間変化)(同図(a))と、それに応じた、冷却水系統26の各部(取水口24、復水器18、及び、放水口26)における残留塩素濃度の時間変化(同図(b)〜(d))を示す。なお、同図(b)〜(d)において、残留塩素濃度Mは、海水への排水中に含まれる残留塩素濃度の許容値(協定値)を表している。 FIG. 6 shows the open / close state of the valve 44 controlled by the control device 46 (that is, the time change of on / off of the drug injection) (FIG. 6A) and the respective parts (intake water) of the cooling water system 26 corresponding thereto. The time change (the figure (b)-(d)) of the residual chlorine concentration in the mouth 24, the condenser 18, and the water discharge port 26) is shown. In the figure (b) ~ (d), the residual chlorine concentration M 0 represents the allowable value of the residual chlorine concentration in the waste water to seawater (agreement value).

図6(a)に示すように、制御装置46はバルブ44を間欠的に開閉させ、これに応じて、同図(b)に示すように、取水口24における塩素濃度はパルス状に変化している。また、同図(c)に示すように、復水器18では塩素濃度波形はパルス波形から鈍った波形となり、更に、同図(d)に示すように、放水口26まで達すると、塩素濃度波形はほぼ平準化されて協定値M未満の低レベルとなっている。 As shown in FIG. 6 (a), the control device 46 opens and closes the valve 44 intermittently, and accordingly, as shown in FIG. 6 (b), the chlorine concentration at the intake port 24 changes in a pulse shape. ing. Moreover, as shown in the figure (c), in the condenser 18, the chlorine concentration waveform becomes a dull waveform from the pulse waveform, and further, when reaching the outlet 26 as shown in the figure (d), the chlorine concentration waveform has a low level of less than agreement value M 0 is substantially leveled.

このように、本実施形態では、バルブ44の開閉により次亜塩素酸ナトリウム溶液を間欠的にパルス状に注入することで、取水路20及び放水路22内での塩素濃度のピーク値を大きくしながら、放出口26から海2へ放出される海水中の残留塩素濃度を低く抑えることができる。次亜塩素酸ナトリウム溶液による貝等の海洋生物の付着及び成長を抑制する効果は、残留塩素濃度のピーク値に依存し、そのピーク値が大きいほど海洋生物の付着及び成長を効果的に抑制することができる。したがって、本実施形態では、海中へ放出される海水に含まれる残留塩素濃度を低く抑えながら、取水路20及び放水路22内に付着した貝等の海洋生物を効果的に除去することができる。特に、取水路20での残留塩素濃度のピーク値を大きくできるから、上述のように海洋生物の付着による影響を受け易い取水路20の海洋生物を効果的に除去することができる。   Thus, in this embodiment, the peak value of the chlorine concentration in the intake channel 20 and the discharge channel 22 is increased by intermittently injecting the sodium hypochlorite solution in a pulsed manner by opening and closing the valve 44. However, the residual chlorine concentration in the seawater discharged from the discharge port 26 to the sea 2 can be kept low. The effect of suppressing the attachment and growth of marine organisms such as shellfish by sodium hypochlorite solution depends on the peak value of residual chlorine concentration, and the larger the peak value, the more effectively the attachment and growth of marine organisms is suppressed. be able to. Therefore, in this embodiment, marine organisms such as shellfish attached to the intake channel 20 and the discharge channel 22 can be effectively removed while suppressing the residual chlorine concentration contained in the seawater released into the sea. In particular, since the peak value of the residual chlorine concentration in the intake channel 20 can be increased, marine organisms in the intake channel 20 that are easily affected by the attachment of marine organisms as described above can be effectively removed.

なお、バルブ44の最適な開閉時間間隔は冷却水系統28の構成によって異なるため、効果的に海洋生物が除去できるような時間間隔を実験的に決定するものとする。   Since the optimal opening / closing time interval of the valve 44 varies depending on the configuration of the cooling water system 28, the time interval at which marine organisms can be effectively removed is experimentally determined.

また、上記実施形態では、火力発電所の復水器を冷却対象設備として冷却するものとしたが、本発明は復水器に限らず、海水を用いて各種設備を冷却する場合に広く適用が可能である。   In the above embodiment, the condenser of the thermal power plant is cooled as the equipment to be cooled. However, the present invention is not limited to the condenser and is widely applied when cooling various equipment using seawater. Is possible.

本発明の一実施形態に係わる火力発電所の概略平面図である。1 is a schematic plan view of a thermal power plant according to an embodiment of the present invention. 取水路及び放水路からなる冷却水系統を模式図的に示す図である。It is a figure which shows typically the cooling water system which consists of a water intake channel and a water discharge channel. 薬剤注入部の詳細構成を示す図である。It is a figure which shows the detailed structure of a chemical | medical agent injection | pouring part. 注入管の注入口の構成例を示す図である。It is a figure which shows the structural example of the injection port of an injection tube. 注入管の注入口の別の構成例を示す図である。It is a figure which shows another structural example of the injection inlet of an injection tube. 注入管に設けられたバルブの開閉状態(薬剤注入のオン/オフの時間変化)同図(a)と、それに応じた、冷却水系統各部における塩素濃度の時間変化(同図(b)〜(d))を示す図である。Open / close state of a valve provided in the injection pipe (change in time of on / off of drug injection) (a) and the change in chlorine concentration in each part of the cooling water system corresponding thereto (figure (b) to ( It is a figure which shows d)).

符号の説明Explanation of symbols

2 海
10 火力発電所
18 復水器
20 取水路
22 放水路
24 取水口
26 放水口
28 冷却水系統
30 海水ポンプ
32 薬剤注入部
40 注入管
41 注入口
42 薬剤供給槽
44 バルブ
46 制御装置
2 Sea 10 Thermal Power Plant 18 Condenser 20 Intake Channel 22 Discharge Channel 24 Intake 26 Outlet 28 Cooling Water System 30 Seawater Pump 32 Drug Injection Portion 40 Injection Pipe 41 Inlet 42 Drug Supply Tank 44 Valve 46 Control Device

Claims (3)

冷却水として海から海水を取り入れて冷却対象設備に供給し、この冷却対象設備を通った後の海水を海へ放出するための冷却水流路内において海洋生物の付着及び成長を抑制する方法であって、前記冷却水流路内へ塩素系薬剤を間欠的に注入することを特徴とする方法。   This is a method for suppressing the adhesion and growth of marine organisms in the cooling water flow path for taking seawater from the sea as the cooling water and supplying it to the equipment to be cooled, and discharging the seawater that has passed through this equipment to the sea. And a method of intermittently injecting a chlorine-based chemical into the cooling water flow path. 前記塩素系薬剤として次亜塩素酸ナトリウムを注入することを特徴とする請求項1記載の方法。   The method according to claim 1, wherein sodium hypochlorite is injected as the chlorinated drug. 冷却水として海から海水を取り入れて冷却対象設備に供給し、この冷却対象設備を通った後の海水を海へ放出するための冷却水流路内において海洋生物の付着及び成長を抑制するシステムであって、
前記冷却水流路内へ塩素系薬剤を注入するための注入管と、
前記注入管に設けられた開閉バルブと、
前記開閉バルブを間欠的に開閉させる制御手段と、を備えることを特徴とするシステム。

It is a system that suppresses the adhesion and growth of marine organisms in the cooling water flow path for taking seawater from the sea as the cooling water and supplying it to the equipment to be cooled and discharging the seawater that has passed through this equipment to the sea. And
An injection tube for injecting a chlorine-based chemical into the cooling water flow path;
An on-off valve provided in the injection pipe;
And a control means for intermittently opening and closing the open / close valve.

JP2003380966A 2003-11-11 2003-11-11 Method and system for controlling adhesion and growth of marine organism Pending JP2005144212A (en)

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JP2009213375A (en) * 2008-03-07 2009-09-24 Chugoku Electric Power Co Inc:The Bioassay apparatus
JP2013006155A (en) * 2011-06-24 2013-01-10 Mitsubishi Heavy Ind Ltd Defoaming device and method of used discharged seawater and discharge system of used discharged seawater
WO2014027402A1 (en) 2012-08-14 2014-02-20 中国電力株式会社 Method for stopping attachment-period larvae from swimming or crawling
JP5887647B1 (en) * 2015-04-28 2016-03-16 三菱瓦斯化学株式会社 Seawater cooling water treatment method
CN108534565A (en) * 2018-03-27 2018-09-14 润电能源科学技术有限公司 Method biological in condenser is killed using the operation control of Generation Unit Condenser
JP2020032327A (en) * 2018-08-28 2020-03-05 中国電力株式会社 Chlorine enriching injection operation device and method
US11134671B2 (en) 2015-03-27 2021-10-05 The Chugoku Electric Power Co., Inc. Method for preventing settlement of sessile organisms
US11134669B2 (en) 2014-03-24 2021-10-05 The Chugoku Electric Power Co., Inc. Method for killing Pteriomorphia and barnacles using light irradiation
US11134670B2 (en) 2014-12-08 2021-10-05 The Chugoku Electric Power Co., Inc. Methods of suppressing settlement of barnacles
US11140893B2 (en) 2014-03-24 2021-10-12 The Chugoku Electric Power Co., Inc. Method for stopping swimming or crawling of adhesion-stage larvae
JP7491158B2 (en) 2020-09-17 2024-05-28 中国電力株式会社 Marine biofouling control device

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JP2009213375A (en) * 2008-03-07 2009-09-24 Chugoku Electric Power Co Inc:The Bioassay apparatus
JP2013006155A (en) * 2011-06-24 2013-01-10 Mitsubishi Heavy Ind Ltd Defoaming device and method of used discharged seawater and discharge system of used discharged seawater
WO2014027402A1 (en) 2012-08-14 2014-02-20 中国電力株式会社 Method for stopping attachment-period larvae from swimming or crawling
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JP2020032327A (en) * 2018-08-28 2020-03-05 中国電力株式会社 Chlorine enriching injection operation device and method
JP7083452B2 (en) 2018-08-28 2022-06-13 中国電力株式会社 Chlorine-enhanced injection operation equipment and method
JP7491158B2 (en) 2020-09-17 2024-05-28 中国電力株式会社 Marine biofouling control device

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