JP2005142026A - Secondary battery - Google Patents
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- JP2005142026A JP2005142026A JP2003377145A JP2003377145A JP2005142026A JP 2005142026 A JP2005142026 A JP 2005142026A JP 2003377145 A JP2003377145 A JP 2003377145A JP 2003377145 A JP2003377145 A JP 2003377145A JP 2005142026 A JP2005142026 A JP 2005142026A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
Description
本発明は、電池缶の内部に二次電池要素となる電極体が収容され、電池缶に設けた一対の電極端子部から電極体の発生電力を取り出すことが出来る二次電池に関するものである。 The present invention relates to a secondary battery in which an electrode body serving as a secondary battery element is accommodated in a battery can and power generated by the electrode body can be taken out from a pair of electrode terminal portions provided in the battery can.
近年、携帯型電子機器、電気自動車等の動力源として、エネルギー密度(Wh/Kg)の高いリチウムイオン二次電池が開発されており、その中でも体積エネルギー密度(Wh/l)の高い角形二次電池が注目されている。 In recent years, lithium ion secondary batteries with high energy density (Wh / Kg) have been developed as power sources for portable electronic devices, electric vehicles, etc. Among them, rectangular secondary batteries with high volume energy density (Wh / l) have been developed. Batteries are attracting attention.
角形二次電池は、図1に示す如く、直方体状の缶本体(11)と該缶本体(11)の開口部を覆う封口体(12)によって形成される電池缶(1)の内部に、発電要素となる巻き取り電極体(2)を収容して構成されており、封口体(12)には、正負一対の電極端子機構(4)(40)が配備されている。巻き取り電極体(2)は、缶本体(1)に横向きに収容されており、図9の如く巻き軸に対して垂直な方向に扁平な形状を呈している。
巻き取り電極体(2)の両電極端縁(28)(29)にはそれぞれ帯状の集電板(8)(80)が接合され、該集電板(8)(80)が図1に示す電極端子機構(4)(40)に連結されて、該電極端子機構(4)(40)から巻き取り電極体(2)の発生電力を取り出すことが可能となっている。
As shown in FIG. 1, the prismatic secondary battery has a rectangular parallelepiped can body (11) and a battery can (1) formed by a sealing body (12) covering the opening of the can body (11). A winding electrode body (2) serving as a power generation element is accommodated, and a pair of positive and negative electrode terminal mechanisms (4), (40) are provided on the sealing body (12). The winding electrode body (2) is accommodated horizontally in the can body (1) and has a flat shape in a direction perpendicular to the winding axis as shown in FIG.
Band-shaped current collector plates (8) and (80) are joined to both electrode edges (28) and (29) of the wound electrode body (2), respectively, and the current collector plates (8) and (80) are shown in FIG. It is connected to the electrode terminal mechanism (4) (40) shown, and it is possible to take out the electric power generated by the winding electrode body (2) from the electrode terminal mechanism (4) (40).
図9に示す如く、集電板(8)(80)は、巻き取り電極体(2)の電極端縁(28)(29)を覆う帯部材(81)によって形成され、該帯部材(81)には、帯部材(81)の左右両側部の間を伸びる複数の断面円弧状の凸条部(82)が、電極端縁(28)(29)に向かって突設されている。
正極側の集電板(8)を正極側の電極端縁(28)に接合する工程においては、先ず、集電板(8)を電極端縁(28)に押し付け、凸条部(82)を電極端縁(28)に食い込ませる。これによって、凸条部(82)と電極端縁(28)の間には、円筒面からなる接合部が形成される。次に、該接合面にレーザ溶接を施すことにより、凸条部(82)と電極端縁(28)が大きな接触面積で接合されることとなる。
As shown in FIG. 9, the current collector plates (8) and (80) are formed by a band member (81) covering the electrode edges (28) and (29) of the winding electrode body (2). ), A plurality of arc-shaped protrusions (82) extending between the left and right side portions of the belt member (81) project toward the electrode edges (28) and (29).
In the step of joining the current collector plate (8) on the positive electrode side to the electrode edge (28) on the positive electrode side, first, the current collector plate (8) is pressed against the electrode edge (28), and the ridge (82) Bite into the electrode edge (28). As a result, a joining portion formed of a cylindrical surface is formed between the protrusion (82) and the electrode edge (28). Next, laser welding is performed on the joint surface, so that the protrusion (82) and the electrode edge (28) are joined with a large contact area.
ところで、電池の内部抵抗を低減させるには、前記溶接接合部の電気抵抗を低減させることが有効であり、そのためには溶接を施す際の出力を増大させることが考えられる。
溶接性の改善として図10に示す集電構造が提案されている。この構造は、集電板の形状をコの字状にしていることにより、電極群の両端部の広がりを抑えるものである。しかしながら、この構造では、巻き取り電極体(2)の電極端縁(28)(29)を形成する電極の芯体の厚さが薄く隣接する芯体の間隔は、従来と変わらず大きいので、大きな出力でレーザ溶接を施すと前記溶接接合部が溶断しレーザ出力を増大することができなかった。
A current collecting structure shown in FIG. 10 has been proposed as an improvement in weldability. In this structure, the shape of the current collector plate is U-shaped, thereby suppressing the expansion of both ends of the electrode group. However, in this structure, the electrode cores forming the electrode edges (28) and (29) of the take-up electrode body (2) are thin, and the distance between adjacent core bodies is as large as before. When laser welding was performed with a large output, the weld joint was melted and the laser output could not be increased.
ところで、電池の内部抵抗を低減させるには、前記溶接接合部の電気抵抗を低減させることが有効であり、そのためには、溶接を施す際の出力を増大させることが考えられる。
しかしながら、図10に示す集電構造において、巻き取り電極体(2)の電極端縁(28)(29)を形成する電極の芯体の厚さが薄く、隣接する芯体の間隔が大きい場合には、従来よりも大きな出力もってレーザ溶接を施すと、前記溶接接合部が溶断する虞があった。
そこで本発明の目的は、集電板を電極体の電極端縁に溶接する際の出力を従来よりも増大させた場合にも、集電板を電極体に確実に接合することが出来る二次電池を提供することである。
By the way, in order to reduce the internal resistance of the battery, it is effective to reduce the electric resistance of the welded joint. For this purpose, it is conceivable to increase the output when welding is performed.
However, in the current collecting structure shown in FIG. 10, when the electrode cores forming the electrode edges (28) and (29) of the take-up electrode body (2) are thin and the distance between adjacent core bodies is large However, when laser welding is performed with a larger output than before, there is a possibility that the welded joint is melted.
Therefore, an object of the present invention is to provide a secondary that can reliably join the current collector plate to the electrode body even when the output when the current collector plate is welded to the electrode edge of the electrode body is increased as compared with the conventional case. It is to provide a battery.
本発明に係る二次電池は、電池缶(1)の内部に、それぞれ帯状の正極(21)と負極(23)の間にセパレータ(22)を介在させて積層した電極体が収容され、電極体が発生する電力を電池缶(1)に設けた正負一対の電極端子機構(4)(40)から取り出すことが出来る。
前記電極体は、両極の積層方向に扁平な形状を呈しており、該電極体の両端部に突出する正負一対の電極端縁(28)(29)には、該電極端縁(28)(29)を覆う集電板(3)(30)がそれぞれ設置されている。該集電板(3)(30)は、電極体の積層方向の厚さ以下の幅を有する平板部(31)を具え、該平板部(31)の幅方向の両端部には、電極端縁(28)(29)に向けて所定の開き角度で突出する一対のリブ(32)(32)が前記両端部に沿って形成されており、両電極端縁(28)(29)はそれぞれ、両リブ(32)(32)の間に束ねられた状態で集電板(3)(30)に接合されている。又、両集電板(3)(30)はそれぞれ、リード部材(5)(50)を介して電極端子機構(4)(40)に連結されている。
In the secondary battery according to the present invention, an electrode body in which a separator (22) is interposed between a strip-like positive electrode (21) and a negative electrode (23) is accommodated in the battery can (1), The power generated by the body can be taken out from a pair of positive and negative electrode terminal mechanisms (4) and (40) provided on the battery can (1).
The electrode body has a flat shape in the lamination direction of both electrodes, and a pair of positive and negative electrode edges (28) (29) projecting at both ends of the electrode body includes the electrode edge (28) ( Current collecting plates (3) and (30) covering 29) are respectively installed. The current collector plates (3) and (30) include a flat plate portion (31) having a width equal to or less than the thickness of the electrode body in the stacking direction. A pair of ribs (32) and (32) projecting at a predetermined opening angle toward the edges (28) and (29) are formed along the both ends, and both electrode edges (28) and (29) are respectively These are joined to the current collector plates (3) and (30) in a state of being bundled between the ribs (32) and (32). The current collector plates (3) and (30) are connected to the electrode terminal mechanisms (4) and (40) through lead members (5) and (50), respectively.
具体的構成において、両リブ(32)(32)は、平板部(31)に対して90度を超え且つ180度未満の開き角度を有している。 In a specific configuration, both the ribs (32) and (32) have an opening angle of more than 90 degrees and less than 180 degrees with respect to the flat plate portion (31).
上記本発明に係る二次電池においては、集電板(3)(30)の平板部(31)の幅方向の両端部に一対のリブ(32)(32)が形成されているため、集電板(3)(30)の剛性が増大する。従って、組立工程にて、電極体に集電板(3)(30)を押し付けた場合にも、該集電板(3)(30)を電極体に押し付ける押圧力によって該集電板(3)(30)が変形する虞はない。 In the secondary battery according to the present invention, a pair of ribs (32) and (32) are formed at both ends in the width direction of the flat plate portion (31) of the current collector plates (3) and (30). The rigidity of the electric plates (3) and (30) increases. Accordingly, even when the current collector plate (3) (30) is pressed against the electrode body in the assembly process, the current collector plate (3) is pressed by the pressing force pressing the current collector plate (3) (30) against the electrode body. ) (30) is not likely to be deformed.
又、組立工程にて、電極端縁(28)(29)に正負一対の集電板(3)(30)をそれぞれ押し付けることによって、集電板(3)(30)の平板部(31)の両側に突設された一対のリブ(32)(32)が、両リブ(32)(32)の間に電極体の複数枚の芯体端部を導入する。これに伴って、両集電板(3)(30)はそれぞれ、電極端縁(28)(29)に対して位置決めされることとなり、集電板(3)(30)の位置が巻き取り電極体(2)の前記積層方向にずれることはない。
又、前記複数枚の芯体端部は、一対のリブによって平板部(31)の中央部に向かって互いに寄せ集められて、束ねられる。そして、電極端縁(28)(29)は、前記複数枚の芯体端部が密に束ねられた状態で集電板(3)(30)に接合されることになるので、該接合部にレーザビーム若しくは電子ビームを照射して溶接を施す際に、出力を増大させて、溶接接合部に従来よりも大きな溶接熱を発生させた場合にも、該溶接接合部にて溶断が生じることはなく、両集電板(3)(30)は確実に電極端縁(28)(29)に接合される。
Further, in the assembly process, a pair of positive and negative current collector plates (3) and (30) are pressed against the electrode edges (28) and (29), respectively, so that the flat plate portion (31) of the current collector plates (3) and (30). A pair of ribs (32) and (32) projecting on both sides of the two lead the plurality of core body end portions of the electrode body between the ribs (32) and (32). Accordingly, the current collector plates (3) and (30) are positioned with respect to the electrode edges (28) and (29), respectively, and the positions of the current collector plates (3) and (30) are wound up. There is no deviation in the stacking direction of the electrode body (2).
The plurality of core end portions are gathered together and bundled toward the center portion of the flat plate portion (31) by a pair of ribs. The electrode edges (28) and (29) are joined to the current collector plates (3) and (30) in a state where the ends of the plurality of core bodies are tightly bundled. When welding is performed by irradiating a laser beam or electron beam on the welding joint, fusing may occur at the welded joint even if the output is increased and welding heat is generated at the welded joint. Rather, both current collector plates (3) and (30) are securely joined to the electrode edges (28) and (29).
又、具体的構成において、集電板(3)(30)の平板部(31)には、一対のリブ(32)(32)と交差する方向に伸びる複数の凸条部(33)が、電極端縁(28)(29)に向かって突設されている。 In a specific configuration, the flat plate portion (31) of the current collector plates (3) and (30) has a plurality of ridge portions (33) extending in a direction intersecting with the pair of ribs (32) and (32). It protrudes toward the electrode edge (28) (29).
該具体的構成においては、複数の凸条部(33)が、該凸条部(33)を含む平面内での湾曲変形に対して大きな抵抗力を発揮するため、集電板(3)(30)の剛性は更に大きなものとなり、組立工程にて、大きな押圧力が作用した場合にも集電板(3)(30)が変形する虞はない。
従って、組立工程にて、両集電板(3)(30)を電極端縁(28)(29)にそれぞれ押し付けることにより、両集電板(3)(30)の各凸条部(33)はそれぞれ、均一に電極端縁(28)(29)に食い込むことになり、各凸条部(33)と電極端縁(28)(29)との接触部に溶接を施すことによって、各凸条部(33)と電極端縁(28)(29)はそれぞれ大きな接触面積で接合される。
In the specific configuration, since the plurality of ridges (33) exhibit a large resistance to bending deformation in a plane including the ridges (33), the current collector plate (3) ( The rigidity of 30) is further increased, and there is no possibility that the current collector plates (3) and (30) are deformed even when a large pressing force is applied in the assembly process.
Accordingly, in the assembling process, both the current collector plates (3) and (30) are pressed against the electrode edges (28) and (29), respectively, so that the protruding portions (33) of the current collector plates (3) and (30) are pressed. ) Each bite uniformly into the electrode edges (28) and (29), and by welding the contact portions between the convex strips (33) and the electrode edges (28) and (29), The protrusion (33) and the electrode edge (28) (29) are joined with a large contact area.
他の具体的構成において、集電板(3)(30)の平板部(31)には、1或いは複数の貫通孔(34)が形成されている。これによって、組立工程で電極体に電解液を含浸させる際の電解液の通路が確保されることになる。 In another specific configuration, one or a plurality of through holes (34) are formed in the flat plate portion (31) of the current collector plates (3) and (30). Thus, a passage for the electrolytic solution when the electrode body is impregnated with the electrolytic solution in the assembly process is secured.
更に他の具体的構成において、集電板(3)(30)の平板部(31)には、電極端縁(28)(29)に向かって突出する一対の切り起し片(32)(32)が形成されている。両切り起し片(35)(35)はそれぞれ、平板部(31)に対して90度未満の角度範囲で切り起こされ、一方のリブ(32)側の切り起し片(35)は、該一方のリブ(32)と共に電極端縁を束ね、他方のリブ(32)側の切り起し片(35)は、該他方のリブ(32)と共に電極端縁を束ねている。 In still another specific configuration, the flat plate portion (31) of the current collector plates (3) and (30) has a pair of cut and raised pieces (32) (32) protruding toward the electrode edges (28) and (29). 32) is formed. Both the cut and raised pieces (35) and (35) are cut and raised at an angle range of less than 90 degrees with respect to the flat plate portion (31), and the cut and raised pieces (35) on one rib (32) side are The electrode edge is bundled together with one rib (32), and the cut and raised piece (35) on the other rib (32) side bundles the electrode edge together with the other rib (32).
該具体的構成においては、組立工程にて、電極端縁(28)(29)に正負一対の集電板(3)(30)をそれぞれ押し付けることによって、集電板(3)(30)の一対のリブ(32)(32)と一対の切り起し片(35)(35)が、一方のリブ(32)と該リブ(32)側の切り起し片(35)の間に電極体の複数枚の芯体端部を導入すると共に、他方のリブ(32)と該リブ(32)側の切り起し片(35)の間に複数枚の芯体端部を導入する。これによって、複数枚の芯体端部は、リブ(32)と切り起し片(35)の間に位置する平板部(31)の中央部に向かって互いに寄せ集められて、2つに束ねられる。この結果、電極端縁(28)(29)は、前記複数枚の芯体端部が密に束ねられた状態で集電板(3)(30)に接合されることになる。
又、切り起し片(35)の形成に伴って平板部(31)に開口(36)が開設されるので、該開口(36)によって、組立工程で電極体に電解液を含浸させる際の電解液の通路が確保されることになる。
In the specific configuration, in the assembly process, a pair of positive and negative current collector plates (3) and (30) are pressed against the electrode edges (28) and (29), respectively, so that the current collector plates (3) and (30) are pressed. A pair of ribs (32) and (32) and a pair of cut and raised pieces (35 and 35) are arranged between one rib (32) and the cut and raised pieces (35) on the rib (32) side. The plurality of core end portions are introduced, and the plurality of core end portions are introduced between the other rib (32) and the cut-and-raised piece (35) on the rib (32) side. As a result, the end portions of the plurality of cores are gathered together toward the center of the flat plate portion (31) located between the rib (32) and the cut and raised piece (35) and bundled into two. It is done. As a result, the electrode edges (28) and (29) are joined to the current collector plates (3) and (30) in a state where the ends of the plurality of core bodies are tightly bundled.
Further, since the opening (36) is opened in the flat plate portion (31) with the formation of the cut and raised piece (35), the opening (36) allows the electrode body to be impregnated with the electrolytic solution in the assembly process. A passage for the electrolyte is secured.
本発明の二次電池によれば、帯状の集電板を電極体の電極端縁に溶接する際の出力を従来よりも増大させた場合にも、集電板を電極体に確実に接合することが出来る。 According to the secondary battery of the present invention, even when the output when welding the belt-shaped current collector plate to the electrode edge of the electrode body is increased as compared with the conventional case, the current collector plate is securely joined to the electrode body. I can do it.
以下、本発明を角形二次電池に実施した形態につき、図面に沿って具体的に説明する。
第1実施例
本実施例の角形二次電池においては、図1に示す如く、アルミニウム製の直方体状の缶本体(11)の開口部に、アルミニウム製の封口板(12)を溶接して、直方体状の電池缶(1)が構成されている。該電池缶(1)の内部には、巻き取り電極体(2)が収容されている。該巻き取り電極体(2)は、例えば17mm×50mm×90mmの外形寸法を有している。
Hereinafter, the embodiment in which the present invention is applied to a prismatic secondary battery will be specifically described with reference to the drawings.
First Embodiment In the prismatic secondary battery of the present embodiment, as shown in FIG. 1, an aluminum sealing plate (12) is welded to the opening of an aluminum rectangular parallelepiped can body (11). A rectangular parallelepiped battery can (1) is formed. A winding electrode body (2) is accommodated in the battery can (1). The wound electrode body (2) has an outer dimension of, for example, 17 mm × 50 mm × 90 mm.
該巻き取り電極体(2)の正極及び負極は、正負一対の電極端子機構(4)(40)に繋がっており、これらの電極端子機構(4)(40)から電力を取り出すことが可能である。
又、電池缶(1)の封口板(12)には、電池缶(1)の内圧が上昇したときに動作すべきガス排出弁(13)と、組立工程で電池缶(1)の内部に電解液を注入するための注液孔を塞ぐ注液栓(14)とが取り付けられている。
The positive electrode and the negative electrode of the wound electrode body (2) are connected to a pair of positive and negative electrode terminal mechanisms (4) and (40), and electric power can be taken out from these electrode terminal mechanisms (4) and (40). is there.
In addition, the sealing plate (12) of the battery can (1) includes a gas discharge valve (13) to be operated when the internal pressure of the battery can (1) rises, and the battery can (1) in the assembly process. An injection plug (14) for closing the injection hole for injecting the electrolyte is attached.
巻き取り電極体(2)は、図3に示す如く、それぞれ帯状の正極(21)と負極(23)の間に帯状のセパレータ(22)を介在させて、これらを渦巻き状に巻回して構成されている。正極(21)は、厚さ15μmのアルミニウム箔からなる帯状芯体(25)の両面にコバルト酸リチウムからなる正極活物質(24)を塗布して構成され、負極(23)は、厚さ10μmの銅箔からなる帯状芯体(27)の両面に黒鉛からなる負極活物質(26)を塗布して構成されている。セパレータ(22)は、イオン透過性のポリプロピレン製の微多孔膜であり、該セパレータ(22)には、非水電解液が含浸されている。 As shown in FIG. 3, the wound electrode body (2) is formed by interposing a strip-shaped separator (22) between a strip-shaped positive electrode (21) and a negative electrode (23) and winding them in a spiral shape. Has been. The positive electrode (21) is formed by applying a positive electrode active material (24) made of lithium cobaltate on both surfaces of a strip-shaped core (25) made of an aluminum foil having a thickness of 15 μm, and the negative electrode (23) has a thickness of 10 μm. The negative electrode active material (26) made of graphite is applied to both surfaces of a strip-like core (27) made of copper foil. The separator (22) is a microporous membrane made of ion-permeable polypropylene, and the separator (22) is impregnated with a non-aqueous electrolyte.
正極(21)には、正極活物質(24)の塗布されている塗工部と、正極活物質(24)の塗布されていない非塗工部とが形成されている。又、負極(23)にも、負極活物質(26)の塗布されている塗工部と、負極活物質の塗布されていない非塗工部とが形成されている。
正極(21)及び負極(23)は、それぞれセパレータ(22)上に幅方向へずらして重ね合わせ、正極(21)及び負極(23)の前記非塗工部をセパレータ(22)の両端縁からそれぞれ外側へ突出させる。そして、これらを渦巻き状に巻き取った後、電極体の外周面を両側から圧縮することにより、巻き軸に垂直な方向に扁平な形状を呈する巻き取り電極体(2)が形成される。又、巻き取り電極体(2)の中央部には、両端部を貫通する中央孔(210)が形成されている。
The positive electrode (21) is formed with a coated portion where the positive electrode active material (24) is applied and an uncoated portion where the positive electrode active material (24) is not applied. The negative electrode (23) is also formed with a coated portion where the negative electrode active material (26) is applied and a non-coated portion where the negative electrode active material is not applied.
The positive electrode (21) and the negative electrode (23) are respectively shifted and overlapped on the separator (22) in the width direction, and the non-coated portions of the positive electrode (21) and the negative electrode (23) are separated from both end edges of the separator (22). Each protrudes outward. And after winding these in a spiral shape, the wound electrode body (2) which exhibits a flat shape in a direction perpendicular to the winding axis is formed by compressing the outer peripheral surface of the electrode body from both sides. A central hole (210) penetrating both ends is formed in the central portion of the winding electrode body (2).
巻き取り電極体(2)の一方の端部には、複数枚の正極(21)の芯体(25)の端縁が突出して正極側の電極端縁(28)が形成されると共に、他方の端部には、複数枚の負極(23)の芯体(27)の端縁が突出して負極側の電極端縁(29)が形成されており、電極端縁(28)(29)には、図2に示す如く、正負一対の帯状の集電板(3)(30)がそれぞれ接合されている。
正負一対の集電板(3)(30)はそれぞれ、巻き取り電極体(2)の厚さよりも僅かに小さな幅を有する帯状の平板部(31)を具え、平板部(31)の幅方向の両端部には、電極端縁(28)(29)に向けて突出する一対のリブ(32)(32)が前記両端部に沿って形成されている。尚、集電板(3)(30)の厚さは0.5mmであり、平板部(31)は14mm×50mm、リブ(32)は2mm×50mmの外形寸法を有している。
両リブ(32)(32)は、巻き取り電極体(2)の電極端縁(28)(29)と対向することとなる平板部(31)の裏面に対してそれぞれ120度の開き角度を有している。又、平板部(31)には、一対のリブ(32)(32)と交差する方向に伸びる複数(本実施例では3つ)の凸条部(33)が、電極端縁(28)(29)に向かって突設されると共に、隣接する凸条部(33)の間にはそれぞれ、複数(本実施例では3つ)の貫通孔(34)が開設されている。
尚、正極側の集電板(3)はアルミニウム製であり、負極側の集電板(30)はニッケル製である。
At one end of the wound electrode body (2), the edge of the core body (25) of the plurality of positive electrodes (21) protrudes to form the electrode edge (28) on the positive electrode side, and the other The edge of the core body (27) of the plurality of negative electrodes (23) protrudes from the end of the negative electrode (29) to form an electrode edge (29) on the negative electrode side. As shown in FIG. 2, a pair of positive and negative current collector plates (3) and (30) are joined to each other.
Each of the positive and negative current collecting plates (3) and (30) includes a strip-shaped flat plate portion (31) having a width slightly smaller than the thickness of the winding electrode body (2), and the width direction of the flat plate portion (31). A pair of ribs (32) and (32) projecting toward the electrode end edges (28) and (29) are formed along the both end portions. The
Both ribs (32) and (32) have an opening angle of 120 degrees with respect to the back surface of the flat plate portion (31) that faces the electrode edges (28) and (29) of the winding electrode body (2). Have. The flat plate portion (31) has a plurality of (three in this embodiment) ridges (33) extending in a direction crossing the pair of ribs (32) and (32), and the electrode edge (28) ( 29) and a plurality of (three in this embodiment) through holes (34) are formed between the adjacent ridges (33).
The positive current collector plate (3) is made of aluminum, and the negative current collector plate (30) is made of nickel.
図4に示す如く、巻き取り電極体(2)の両端部に接合された集電板(3)(30)の平板部(31)の表面には、集電板(3)(30)と缶本体(11)の間の電気的絶縁を図るためのポリプロピレン製の絶縁テープ(6)が貼着されており、該絶縁テープ(6)は、集電板(3)(30)の複数の貫通孔(34)と対向する位置に開口(61)が形成されている。 As shown in FIG. 4, the current collector plates (3), (30) and the surface of the flat plate portion (31) of the current collector plates (3), (30) joined to both ends of the winding electrode body (2) A polypropylene insulating tape (6) for electrical insulation between the can bodies (11) is attached, and the insulating tape (6) is a plurality of current collector plates (3) (30). An opening (61) is formed at a position facing the through hole (34).
両端部に集電板(3)(30)が接合された巻き取り電極体(2)は、その外周面を缶本体(11)の底面に沿わせた姿勢で該缶本体(11)に収容される。
又、巻き取り電極体(2)の両端部には、円弧の屈曲部を有する帯状のリード部材(5)(50)が設置され、該リード部材(5)(50)の一方の端部が集電板(3)(30)の平板部(31)の裏面に溶接されると共に、該リード部材(5)(50)の他方の端部が電極端子機構(4)(40)の基端部にかしめ固定される。
尚、正極側のリード部材(5)はアルミニウム製であり、負極側のリード部材(50)はニッケル製である。
The take-up electrode body (2) with the current collector plates (3) and (30) joined to both ends is accommodated in the can body (11) in such a posture that its outer peripheral surface is along the bottom surface of the can body (11). Is done.
Further, at both ends of the winding electrode body (2), strip-shaped lead members (5) and (50) having arc-shaped bent portions are installed, and one end portion of the lead members (5) and (50) is provided. While being welded to the back surface of the flat plate portion (31) of the current collector plates (3) and (30), the other end portion of the lead members (5) and (50) is the base end of the electrode terminal mechanism (4) and (40). It is caulked and fixed to the part.
The lead member (5) on the positive electrode side is made of aluminum, and the lead member (50) on the negative electrode side is made of nickel.
正極側の電極端子機構(4)は、図6に示す如く、封口板(12)に、第1絶縁部材(44)及び第2絶縁部材(45)を介して、フランジ部(42)を有するアルミニウム製の端子部材(41)がリベット打ちされており、該端子部材(41)のフランジ部(42)とかしめ部(43)との間で第1絶縁部材(44)及び第2絶縁部材(42)が挟圧されると共に、かしめ部(43)と第1絶縁部材(44)によってリード部材(5)の前記一方の端部が挟圧されている。
負極側の電極端子機構(40)も、端子部材(41)がニッケル製である点を除いて同様の構造を有している。
As shown in FIG. 6, the electrode terminal mechanism (4) on the positive electrode side has a flange portion (42) on the sealing plate (12) via the first insulating member (44) and the second insulating member (45). An aluminum terminal member (41) is riveted, and a first insulating member (44) and a second insulating member (between the flange portion (42) and the caulking portion (43) of the terminal member (41) ( 42) is clamped, and the one end of the lead member (5) is clamped by the caulking portion (43) and the first insulating member (44).
The electrode terminal mechanism (40) on the negative electrode side has the same structure except that the terminal member (41) is made of nickel.
上記実施例の角形二次電池の組立においては、先ず、図4に示す缶本体(11)、封口板(12)、巻き取り電極体(2)を作製すると共に、プレス加工によって正負一対の集電板(3)(30)を作製する。
次に、巻き取り電極体(2)の両端部から突出している電極端縁(28)(29)に集電板(3)(30)を押し付ける。ここで、集電板(3)(30)の剛性は、プレス加工により形成された一対のリブ(32)(32)及び凸条部(33)によって大きなものとなっているので、集電板(3)(30)を電極端縁(28)(29)に押し付ける押圧力によって集電板(3)(30)の平板部(31)が変形する虞はない。
従って、両集電板(3)(30)を電極端縁(28)(29)にそれぞれ押し付けることによって、両集電板(3)(30)の凸条部(33)は電極端縁(28)(29)にそれぞれ均一に食い込み、各凸条部(33)と電極端縁(28)(29)の間には、円筒面からなる接合部が形成される。
In assembling the prismatic secondary battery of the above embodiment, first, a can body (11), a sealing plate (12), and a winding electrode body (2) shown in FIG. Electroplates (3) and (30) are prepared.
Next, the current collector plates (3) and (30) are pressed against the electrode edges (28) and (29) protruding from both ends of the wound electrode body (2). Here, the rigidity of the current collector plates (3) and (30) is large due to the pair of ribs (32) and (32) and the ridges (33) formed by pressing. (3) There is no possibility that the flat plate portion (31) of the current collector plates (3) and (30) is deformed by the pressing force pressing the electrode edges (28) and (29).
Accordingly, by pressing the current collector plates (3) and (30) against the electrode edges (28) and (29), respectively, the protruding portions (33) of the current collector plates (3) and (30) are moved to the electrode edge ( 28) (29) bite into each of them uniformly, and a joint portion formed of a cylindrical surface is formed between each ridge (33) and the electrode edge (28) (29).
又、図5に示す如く、一対のリブ(32)(32)によって、巻き取り電極体(2)の複数枚の芯体端部が集電板(3)(30)の平板部(31)の中央部に向かって寄せ集められ、束ねられる。これに伴って、集電板(3)(30)はそれぞれ、電極端縁(28)(29)に対して位置決めされることとなり、両集電板(3)(30)の位置が巻き取り電極体(2)の厚さ方向にずれることはない。 Further, as shown in FIG. 5, a plurality of core end portions of the winding electrode body (2) are formed by a pair of ribs (32) and (32) so that the flat plate portion (31) of the current collector plates (3) and (30). They are gathered and bundled toward the center. Accordingly, the current collector plates (3) and (30) are positioned with respect to the electrode edges (28) and (29), respectively, and the positions of the current collector plates (3) and (30) are wound up. There is no deviation in the thickness direction of the electrode body (2).
この様に、巻き取り電極体(2)の電極端縁(28)(29)に集電板(3)(30)を押し付けた状態で、各凸条部(33)の内周面に向けてレーザビームを照射し、レーザ溶接を施す。このとき、電極端縁(28)(29)は、複数枚の芯体端部が従来よりも密に束ねられた状態で集電板(3)(30)に接触しているので、従来よりも大きな出力をもって溶接を施し、溶接接合部に大きな溶接熱を発生させた場合にも、該溶接接合部に溶断が生じることはなく、両集電板(3)(30)はそれぞれ電極端縁(28)(29)に確実に接合されることになる。 In this way, the current collector plates (3) and (30) are pressed against the electrode edges (28) and (29) of the winding electrode body (2), and are directed toward the inner peripheral surface of each protrusion (33). The laser beam is irradiated and laser welding is performed. At this time, the electrode edges (28) and (29) are in contact with the current collector plates (3) and (30) in a state in which the end portions of the plurality of core bodies are more tightly bundled than in the prior art. Even when welding is performed with a large output and a large welding heat is generated in the welded joint, the welded joint does not melt, and both current collector plates (3) and (30) have their respective electrode edges. (28) It is securely joined to (29).
そして、図6に示す如く、封口板(12)に対して正負一対の電極端子機構(4)(40)を組み付けると共に、一対のリード部材(5)(50)の前記他方の端部を電極端子機構(4)(40)のかしめ部(43)に固定する。
その後、両リード部材(5)(50)の前記一方の端部をそれぞれ集電板(3)(30)の平板部(31)の裏面に溶接する。
Then, as shown in FIG. 6, a pair of positive and negative electrode terminal mechanisms (4) and (40) are assembled to the sealing plate (12), and the other end of the pair of lead members (5) and (50) is connected to the electrode. Secure to the crimping part (43) of the terminal mechanism (4) (40).
Thereafter, the one end of each of the lead members (5) and (50) is welded to the back surface of the flat plate portion (31) of the current collector plates (3) and (30).
次に、図4に示す如く、両集電板(3)(30)の平板部(31)の表面に絶縁テープ(6)を貼着した後、巻き取り電極体(2)を缶本体(11)の内部に収容すると共に、封口板(12)を缶本体(11)の開口部に被せ、封口板(12)を缶本体(11)に溶接する。 Next, as shown in FIG. 4, after attaching an insulating tape (6) to the surface of the flat plate portion (31) of both current collector plates (3) and (30), the winding electrode body (2) is attached to the can body ( 11), the sealing plate (12) is placed on the opening of the can body (11), and the sealing plate (12) is welded to the can body (11).
その後、ドライボックス内にて封口板(12)の注液孔から電解液を注入する。このとき、電解液は絶縁テープ(6)の開口(61)を経て、集電板(3)(30)の貫通孔(34)から巻き取り電極体(2)の内部に供給されるため、巻き取り電極体(2)に電解液を含浸させるための時間が大幅に短縮されることとなり、これによって、電池缶(1)に電解液を注液する注液時間が大幅に短縮される。本実施例においては、図9に示す従来の集電構造を有する二次電池よりも注液時間が40%短縮された。
尚、電解液は、エチレンカーボネートとジエチルカーボネートを体積比1:1で混合した溶媒に、LiPF6を1mol/lの割合で溶解したものである。
最後に前記注液孔を注液栓(14)によって封止し、電池の組立を終了する。
Thereafter, an electrolytic solution is injected from the injection hole of the sealing plate (12) in the dry box. At this time, the electrolytic solution is supplied to the inside of the winding electrode body (2) from the through hole (34) of the current collector plates (3) and (30) through the opening (61) of the insulating tape (6). The time for impregnating the winding electrode body (2) with the electrolytic solution is greatly shortened, whereby the time for injecting the electrolytic solution into the battery can (1) is greatly shortened. In this example, the injection time was shortened by 40% compared to the secondary battery having the conventional current collecting structure shown in FIG.
Incidentally, the electrolyte, a volume ratio of ethylene carbonate and diethyl carbonate 1: mixed solvent 1, in which LiPF 6 was dissolved at a rate of 1 mol / l.
Finally, the liquid injection hole is sealed with a liquid injection stopper (14), and the assembly of the battery is completed.
上記実施例の角形二次電池において、電極端縁(28)(29)を形成する複数枚の芯体端部は、電極端縁(28)(29)を覆う集電板(3)(30)の一対のリブ(32)(32)によって密に束ねられているので、従来よりも大きな出力をもってレーザ溶接を施した場合にも、溶接接合部に溶断が生じることはない。従って、両集電板(3)(30)の凸条部(33)と電極端縁(28)(29)との溶接は確実に行なわれることとなり、これによって、内部抵抗が低減して、電池性能が向上する。本実施例では、従来よりも出力を増大させてレーザ溶接を施すことにより、図9に示す従来の集電構造を有する二次電池よりも内部抵抗が20%低減された。 In the prismatic secondary battery of the above embodiment, the ends of the plurality of cores forming the electrode edges (28) and (29) are the current collector plates (3) and (30) covering the electrode edges (28) and (29). ) Are tightly bundled by a pair of ribs (32) and (32), so that even when laser welding is performed with a larger output than in the past, fusing does not occur at the weld joint. Therefore, the projections (33) of the current collector plates (3) (30) and the electrode edges (28) (29) are securely welded, thereby reducing the internal resistance, Battery performance is improved. In this example, the internal resistance was reduced by 20% compared with the secondary battery having the conventional current collecting structure shown in FIG.
第2実施例
図7及び図8に示す本実施例の角形二次電池は、集電板(3)(30)の構造において上記第1実施例と異なるが、他の構造は第1実施例と同じであるので、集電板(3)(30)の構造についてのみ説明し、他の構造については同じ符号を付して説明を省略する。
Second Embodiment The prismatic secondary battery of this embodiment shown in FIGS. 7 and 8 is different from the first embodiment in the structure of the current collector plates (3) and (30), but the other structure is the first embodiment. Therefore, only the structure of the current collector plates (3) and (30) will be described, and the other structures will be denoted by the same reference numerals and will not be described.
図7に示す如く、本実施例の角形二次電池において、集電板(3)(30)の隣接する凸条部(33)(33)の間にはそれぞれ、巻き取り電極体(2)の電極端縁(28)(29)に向かって突出する一対の切り起し片(35)(35)が形成されている。両切り起し片(35)(35)は、平板部(31)の長手方向に伸びると共に、平板部(31)の電極端縁(28)(29)との対向面に対して120度程度の開き角度を有している。該切り起し片(35)(35)の切り起こしに伴って平板部(31)に形成された開口(36)は、後述の組立工程にて巻き取り電極体(2)に電解液を含浸させる際の通路となる。 As shown in FIG. 7, in the prismatic secondary battery of the present embodiment, the winding electrode body (2) is disposed between the adjacent protruding strips (33) and (33) of the current collector plates (3) and (30), respectively. A pair of cut and raised pieces (35) and (35) projecting toward the electrode edges (28) and (29) are formed. Both the cut and raised pieces (35) and (35) extend in the longitudinal direction of the flat plate portion (31) and are about 120 degrees with respect to the surface facing the electrode edges (28) and (29) of the flat plate portion (31). Has an opening angle. The opening (36) formed in the flat plate portion (31) as the cut and raised pieces (35) and (35) are cut and raised impregnates the winding electrode body (2) with the electrolytic solution in the assembly process described later. It becomes a passage when letting go.
上記本実施例の角形二次電池の組立において、巻き取り電極体(2)の電極端縁(28)(29)に両集電板(3)(30)をそれぞれ押し付けると、図8に示す如く、リブ(32)と切り起し片(35)の間に巻き取り電極体(2)の複数枚の芯体端部が導入される。これによって、複数枚の芯体端部は、リブ(32)と切り起し片(35)の間の平板部(31)に向かって寄せ集められ、2つに束ねられることとなる。これに伴って、両集電板(3)(30)はそれぞれ、電極端縁(28)(29)に対して位置決めされることになり、両集電板(3)(30)の位置が巻き取り電極体(2)の厚さ方向にずれることはない。 In the assembly of the prismatic secondary battery of the present embodiment, when the current collector plates (3) and (30) are pressed against the electrode edges (28) and (29) of the winding electrode body (2), respectively, as shown in FIG. As described above, a plurality of core body end portions of the wound electrode body (2) are introduced between the rib (32) and the cut and raised piece (35). As a result, the plurality of core end portions are gathered together toward the flat plate portion (31) between the rib (32) and the cut and raised piece (35) and bundled into two. Accordingly, the current collector plates (3) and (30) are positioned with respect to the electrode edges (28) and (29), respectively, and the positions of the current collector plates (3) and (30) are changed. There is no deviation in the thickness direction of the winding electrode body (2).
又、図7に示す集電板(3)(30)の凸条部(33)は、巻き取り電極体(2)の電極端縁(28)(29)に食い込み、凸条部(33)と電極端縁(28)(29)の間には、円筒面からなる接合部が形成される。ここで、集電板(3)(30)の剛性は、プレス加工により形成される一対のリブ(32)(32)、一対の切り起し片(35)(35)及び凸条部(33)によって大きなものとなっているので、平板部(31)を巻き取り電極体(2)の電極端縁(28)(29)に押し付けたときにも平板部(31)が変形することはなく、各凸条部(33)と電極端縁(28)(29)の接触面積は均一となる。 Further, the protruding strips (33) of the current collector plates (3) and (30) shown in FIG. 7 bite into the electrode edges (28) and (29) of the take-up electrode body (2) to form the protruding strips (33). Between the electrode edge (28) and the electrode edge (29), a joint portion having a cylindrical surface is formed. Here, the rigidity of the current collector plates (3) and (30) is such that the pair of ribs (32) and (32), the pair of cut and raised pieces (35) and (35), and the protrusion (33) formed by pressing. ), The flat plate portion (31) is not deformed even when the flat plate portion (31) is pressed against the electrode edges (28) (29) of the take-up electrode body (2). The contact area between each protrusion (33) and the electrode edges (28) (29) is uniform.
この様に、巻き取り電極体(2)の電極端縁(28)(29)に集電板(3)(30)の平板部(31)を押し付けた状態で、各凸条部(33)の内周面に向けてレーザビームを照射し、レーザ溶接を施す。このとき、電極端縁(28)(29)は、複数枚の芯体端部が従来よりも密に束ねられた状態で集電板(3)(30)に接触しているので、従来よりも大きな出力をもって溶接を施し、溶接接合部に大きな溶接熱を発生させた場合にも、該接合部に溶断が生じることはなく、両集電板(3)(30)はそれぞれ電極端縁(28)(29)に確実に接合されることとなる。 Thus, in the state where the flat plate portion (31) of the current collector plates (3) and (30) is pressed against the electrode edges (28) and (29) of the winding electrode body (2), each protrusion (33) A laser beam is irradiated toward the inner peripheral surface of the substrate to perform laser welding. At this time, the electrode edges (28) and (29) are in contact with the current collector plates (3) and (30) in a state in which the end portions of the plurality of core bodies are more tightly bundled than in the prior art. Even when welding is performed with a large output and large welding heat is generated in the welded joint, the fusing does not occur in the joint, and the current collector plates (3) and (30) are respectively connected to the electrode edges ( 28) It will be securely joined to (29).
そして、集電板(3)(30)を接合した巻き取り電極体(2)を電池缶(1)の内部に収容した後に、ドライボックス内にて封口板(12)の注液孔から電解液を注入する。このとき、電解液は集電板(3)(30)の切り起し部(37)に形成された開口(36)から巻き取り電極体(2)の内部に供給されるため、巻き取り電極体(2)に電解液を含浸させるための時間が大幅に短縮されることとなり、これによって、電池缶(1)に電解液を注液する注液時間が大幅に短縮される。本実施例においては、図9のに示す従来の集電構造を有する二次電池よりも注液時間が40%短縮された。 And after accommodating the winding electrode body (2) which joined current collecting plates (3) and (30) in the inside of battery can (1), it electrolyzes from the injection hole of sealing plate (12) in a dry box. Inject liquid. At this time, since the electrolytic solution is supplied into the winding electrode body (2) from the opening (36) formed in the cut and raised portion (37) of the current collector plates (3) and (30), the winding electrode The time for impregnating the body (2) with the electrolytic solution is greatly shortened, and thereby the time for injecting the electrolytic solution into the battery can (1) is significantly shortened. In this example, the injection time was 40% shorter than that of the secondary battery having the conventional current collecting structure shown in FIG.
上記実施例の角形二次電池において、電極端縁(28)(29)を形成する複数枚の芯体端部は、電極端縁(28)(29)を覆う集電板(3)(30)のリブ(32)と切り起し片(35)によって密に束ねられているので、従来よりも大きな出力をもってレーザ溶接を施した場合にも、溶接接合部に溶断が発生することない。従って、両集電板(3)(30)の凸条部(33)と電極端縁(28)(29)との溶接は確実に行なわれることとなり、これによって、内部抵抗が低減して、電池性能が向上する。本実施例では、従来よりも出力を増大させてレーザ溶接を施すことにより、図9に示す集電構造を有する二次電池よりも内部抵抗が25%低減された。 In the prismatic secondary battery of the above embodiment, the ends of the plurality of cores forming the electrode edges (28) and (29) are the current collector plates (3) and (30) covering the electrode edges (28) and (29). ) Are tightly bundled by the ribs (32) and the cut and raised pieces (35), so that even when laser welding is performed with a larger output than before, no fusing occurs in the welded joint. Therefore, the projections (33) of the current collector plates (3) (30) and the electrode edges (28) (29) are securely welded, thereby reducing the internal resistance, Battery performance is improved. In this example, the internal resistance was reduced by 25% compared to the secondary battery having the current collecting structure shown in FIG.
尚、本発明の各部構成は上記実施の形態に限らず、特許請求の範囲に記載の技術的範囲内で種々の変形が可能である。例えば、シート状の正極及び負極の間にシート状のセパレータを介在させて形成される積層型の電極体の電極端縁に、本実施例の集電板(3)(30)を接合した構成においても、上記実施例と同様の効果が得られる。 In addition, each part structure of this invention is not restricted to the said embodiment, A various deformation | transformation is possible within the technical scope as described in a claim. For example, the current collector plates (3) and (30) of this embodiment are joined to the electrode edge of a laminated electrode body formed by interposing a sheet-like separator between a sheet-like positive electrode and a negative electrode In this case, the same effect as in the above embodiment can be obtained.
(1) 電池缶
(11) 缶本体
(12) 封口板
(2) 巻き取り電極体
(28) 電極端縁
(29) 電極端縁
(3) 集電板
(30) 集電板
(31) 平板部
(32) リブ
(33) 凸条部
(34) 貫通孔
(35) 切り起し片
(36) 開口
(4) 電極端子機構
(40) 電極端子機構
(5) リード部材
(50) リード部材
(6) 絶縁テープ
(210) 巻き芯
(1) Battery can
(11) Can body
(12) Sealing plate
(2) Winding electrode body
(28) Electrode edge
(29) Electrode edge
(3) Current collector
(30) Current collector
(31) Flat plate
(32) Ribs
(33) Convex section
(34) Through hole
(35) Cut and raised pieces
(36) Opening
(4) Electrode terminal mechanism
(40) Electrode terminal mechanism
(5) Lead material
(50) Lead material
(6) Insulation tape
(210) Winding core
Claims (5)
前記電極体は、両極の積層方向に扁平な形状を呈しており、該電極体の両端部に突出する正負一対の電極端縁(28)(29)には、該電極端縁(28)(29)を覆う集電板(3)(30)がそれぞれ設置されており、該集電板(3)(30)は、電極体の積層方向の厚さ以下の幅を有する平板部(31)を具え、該平板部(31)の幅方向の両端部には、電極端縁(28)(29)に向けて所定の開き角度で突出する一対のリブ(32)(32)が前記両端部に沿って形成されており、両電極端縁(28)(29)はそれぞれ、両リブ(32)(32)の間に束ねられた状態で集電板(3)(30)に接合され、両集電板(3)(30)はそれぞれ、リード部材(5)(50)を介して電極端子機構(4)(40)に連結されていることを特徴とする二次電池。 Inside the battery can (1), an electrode body laminated with a separator (22) interposed between a strip-like positive electrode (21) and a negative electrode (23) is accommodated, and the electric power generated by the electrode body is stored in the battery can ( In the secondary battery that can be taken out from the pair of positive and negative electrode terminal mechanisms (4) and (40) provided in 1),
The electrode body has a flat shape in the lamination direction of both electrodes, and a pair of positive and negative electrode edges (28) (29) projecting at both ends of the electrode body includes the electrode edge (28) ( Current collecting plates (3) and (30) covering 29) are installed, and the current collecting plates (3) and (30) are flat plate portions (31) having a width equal to or less than the thickness in the stacking direction of the electrode bodies. A pair of ribs (32) (32) projecting at a predetermined opening angle toward the electrode edge (28) (29) at both ends in the width direction of the flat plate portion (31). The electrode edges (28) and (29) are joined to the current collector plates (3) and (30) in a state of being bundled between the ribs (32) and (32), Both current collector plates (3) and (30) are connected to electrode terminal mechanisms (4) and (40) through lead members (5) and (50), respectively, and the secondary battery.
The flat plate portion (31) of the current collector plates (3) and (30) is formed with a pair of cut and raised pieces (35) and (35) protruding toward the electrode edges (28) and (29). Both the cut and raised pieces (35) and (35) are cut and raised at an angle range of less than 90 degrees with respect to the flat plate portion (31), and the cut and raised pieces (35) on one rib (32) side are The electrode edge is bundled together with one rib (32), and the cut-and-raised piece (35) on the other rib (32) side bundles the electrode edge together with the other rib (32). Item 5. The secondary battery according to any one of Items 4.
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