JP2004222560A - Emulsified composition - Google Patents
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- JP2004222560A JP2004222560A JP2003012731A JP2003012731A JP2004222560A JP 2004222560 A JP2004222560 A JP 2004222560A JP 2003012731 A JP2003012731 A JP 2003012731A JP 2003012731 A JP2003012731 A JP 2003012731A JP 2004222560 A JP2004222560 A JP 2004222560A
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- egg yolk
- polysaccharide
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Abstract
Description
【0001】
【発明の属する技術分野】
本発明は、様々な飲食品に対する添加物として好適に用いられ得る乳化組成物及びその製造方法並びに該乳化組成物を含有した飲食品に関する。
【0002】
【従来の技術】
鶏卵卵黄は、水分約50重量%、脂質約30重量%、タンパク質約15重量%等からなるエマルジョンであり、その乳化力を利用し、種々の食品に利用されている。しかしながら、水分の多い系などでは食品の粘性が低下するために、卵黄の乳化力には限界があり、例えば液状ドレッシングでは経時的に親油性成分と親水性成分とが分離してしまう。そこで、レシチンやグリセリン脂肪酸エステル等の乳化剤や、キサンタンガム等の多糖類との併用によって、製品の安定性を高める方法が報告されている(特許文献1、特許文献2等)。しかしながら、乳化剤を多用すると乳化剤の味が出てしまうことがあり、またキサンタンガム等の増粘性の多糖類を多用すると多糖類独特のヌルついた食感が出たり、増粘してしまうため、製品の安定性と風味・食感の両立は困難とされている。
【0003】
【特許文献1】
特開平7−274893号公報(請求項1、〔0009〕等)
【0004】
【発明が解決しようとする課題】
本発明は、乳化力、風味の良好な、卵黄と多糖類を含有する乳化組成物及びその製造方法並びに該乳化組成物を含有した飲食品を提供することを目的とする。
【0005】
【課題を解決するための手段】
本発明は、
(1) 卵黄と多糖類を含有した混合液を、卵黄タンパク質の熱凝固温度以下の温度に加熱する工程を含む方法により得られる、卵黄と多糖類を含有する乳化組成物、
(2) 卵黄と多糖類を含有した混合液を、卵黄タンパク質の熱凝固温度以下の温度に加熱する工程を有することを特徴とする、卵黄と多糖類を含有する乳化組成物の製造方法、並びに
(3) 前記(1)記載の乳化組成物を含有してなる飲食品
に関する。
【0006】
【発明の実施の形態】
本発明の乳化組成物は、卵黄と多糖類を含有した混合液を、卵黄中のタンパク質の熱凝固温度以下の温度に加熱する工程を含む方法ことにより得られるが、優れた乳化力を有し、かつ風味、食感も良好である。卵黄と多糖類を含有した混合液の加熱処理により、このような優れた特性が得られる理由の詳細は不明なるも、加熱処理により、卵黄タンパク質と多糖類のネットワークがより強固なものとなり、多糖類を多量に配合せずとも乳化力を向上させることができるためと推定される。
【0007】
本発明における卵黄は、液状であればその由来は鶏卵、あひる卵等、特に限定されるものではないが、供給量の関係より、鶏卵卵黄が好ましい。卵黄は一般に市販されているものを使用することができ、生卵黄に限らず、殺菌液卵黄、加塩卵黄、加糖卵黄、これらの凍結品等であってもよいが、本発明では、塩分が5〜20重量%程度の加塩卵黄が好ましい。さらに、卵黄粉末を水で希釈して卵黄液としたものや、液卵黄を水等で希釈して粘度を低下させたものを使用することもできる。
【0008】
混合液は卵黄と多糖類のみから構成されていてもよいが、粘性の観点から、混合液中の卵黄の含有量は、0.5〜80重量%が好ましく、1.0〜50重量%がより好ましい。
【0009】
本発明における多糖類としては、キサンタンガム、LMペクチン、HMペクチン等のペクチン、カッパカラギナン、イオタカラギナン、ラムダカラギナン等のカラギナン、グァーガム、タラガム、ローカストビーンガム、ジェランガム、タマリンドシードガム、アラビアガム、カラヤガム、プルラン、サイリウムシードガム、トロロアオイ、ファーセレラン、及びこれらの分解物、アルギン酸、アルギン酸ナトリウム、アルギン酸プロピレングリコールエステル、カルボキシメチルセルロースナトリウム、デンプンリン酸エステルナトリウム、デンプングリコール酸ナトリウム、メチルセルロース、ダイズ多糖類、コンニャク粉、海藻・褐藻抽出物、オクラ抽出物、アロエベラ抽出物、モモ抽出物等、一般に食品に使用できるものであれば特に限定されないが、これらのなかでは、卵黄タンパク質との反応性の観点から、ペクチン、キサンタンガム、カラギナン、ジェランガム、アルギン酸、カルボキシメチルセルロースナトリウム等の酸性多糖類が好ましく、キサンタンガム、ペクチン及びカラギナンからなる群より選ばれた少なくとも1種がより好ましい。またこれらの多糖類は単独であっても、2種以上が併用されていてもよい。
【0010】
本発明における多糖類の配合量は、多糖類の種類や粘性を考慮して適宜決定されるが、卵黄100重量部に対して、0.05〜5重量部程度が好ましく、0.1〜4重量部がより好ましく、0.2〜2重量部が特に好ましい。
【0011】
さらに、本発明の乳化組成物には、デキストリン、大豆多糖類、卵白、乳化剤等が、必要に応じて適宜配合されていてもよい。
【0012】
本発明において、卵黄と多糖類を混合する方法は、特に限定されないが、例えば、多糖類を卵黄にそのまま添加することにより混合液が増粘しすぎて、多糖類の均一分散・溶解が困難となる場合には、予め多糖類を水に分散・溶解させた水溶液を、卵黄と混合する方法が好ましい。この場合、多糖類の水溶液をいったん加熱し、多糖類を完全に膨潤・溶解させ、冷却した後、卵黄と混合することにより、多糖類をより容易に卵黄中に均一分散・溶解させることができる。また、多糖類を分散・溶解させる水の量は、特に限定されず、続く加熱工程での効率を考慮して適宜決定すればよい。
【0013】
卵黄と多糖類を含有した混合液の加熱温度は、卵黄タンパク質の熱凝固温度以下の温度であれば特に限定されず、卵黄の濃度、使用する多糖類の種類、加塩・加糖等の卵黄に対する添加物質の有無等によって最適温度は異なるが、通常、卵黄タンパク質の熱凝固温度は65〜75℃であるので、50℃〜70℃が好ましく、55℃〜65℃がより好ましい。
【0014】
卵黄と多糖類を含有した混合液の加熱方法は、プレート式(連続式)や撹拌羽根で上下左右に撹拌しつつ加熱するバッチ式の加熱法により、混合液を均一に加熱できる方法が好ましい。
【0015】
卵黄と多糖類を含有した混合液の加熱時間は、加熱温度や加熱効率によって適宜決定されるが、一例をあげると、卵黄液50重量%、精製水49.5重量%及びキサンタンガム0.5重量%からなる混合液を、プレートによる連続式加熱法により、64℃で加熱する場合、加熱時間は1〜15分間程度が好ましく、2〜10分間程度がより好ましい。なお、同様の処理をバッチ式加熱法で行う場合は、連続式加熱法に相当する熱量で処理する観点から、低温で長時間(例えば、30〜90分程度)の加熱が好ましい。
【0016】
本発明の乳化組成物は、前記のように、乳化力が高いだけでなく、風味、食感も良好であるため、様々な飲食品に対する添加物として用いることができる。
【0017】
従って、本発明ではさらに、本発明の乳化組成物を含有した飲食品を提供する。本発明の飲食品は非常に広範囲にわたるが、例えば、液状ドレッシング、アイスクリーム、ケーキ類、クッキー、パン等が挙げられる。なお、飲食品における本発明の乳化組成物の含有量は、飲食品の種類等に応じて適宜決定することが好ましい。
【0018】
【実施例】
以下、実施例により本発明をさらに詳細に説明するが、本発明はかかる実施例によりなんら限定されるものではない。
【0019】
実施例1
殻付鶏卵を割卵して卵白と卵黄を分離した後、異物除去のために卵黄液をストレーナーに通して、生卵黄(卵黄タンパク質の熱凝固温度:68℃)500gを得た。次にキサンタンガム(太陽化学(株)製)5gをホモディスパーにて精製水495gに分散・溶解させた後、湯浴にて90℃まで加熱し、室温まで冷却して、多糖類水溶液を得た。次に、生卵黄と多糖類水溶液を混合し、混合液をゆっくりと撹拌しながら63℃の湯浴にて60分間バッチ加熱処理することにより、乳化組成物を得た。加熱処理に供した混合液は、加熱開始から30分で、加熱による最高温度(62.5℃)に達した。
【0020】
実施例2
キサンタンガムの代わりに、LMペクチン(太陽化学(株)製)5gを使用した以外は、実施例1と同様にして乳化組成物を得た。
【0021】
実施例3
キサンタンガムの代わりに、カッパカラギナン(太陽化学(株)製)5gを使用した以外は、実施例1と同様にして乳化組成物を得た。
【0022】
実施例4
生卵黄の代わりに、10%加塩卵黄500gを使用した以外は、実施例1と同様にして乳化組成物を得た。
【0023】
比較例1
加熱処理を行わない以外は、実施例1と同様にして乳化組成物を得た。
【0024】
比較例2
加熱処理を行わない以外は、実施例2と同様にして乳化組成物を得た。
【0025】
比較例3
加熱処理を行わない以外は、実施例3と同様にして乳化組成物を得た。
【0026】
比較例4
加熱処理を行わない以外は、実施例4と同様にして乳化組成物を得た。
【0027】
比較例5
10%加塩卵黄550gに精製水500gのみを添加して混合し、実施例1と同様にして加熱処理することにより、乳化組成物を得た。
【0028】
比較例6
加熱処理を行わない以外は、比較例5と同様にして乳化組成物を得た。
【0029】
試験例
乳化組成物0.5gを正確に量り取り、蒸留水50mlに分散、溶解させ、卵黄含量が0.5重量%の水溶液を得た。得られた水溶液をホモミキサーにて6000r/minで撹拌しながらナタネ白絞油を5ml単位で計量しながら添加し、O/W乳化系からW/O乳化系に転層したところを終点とし、この時点のナタネ白絞油の総添加量を乳化容量とした。即ち、添加量が多い程、乳化容量が大きいと言える。この試験を計3回行い、乳化容量の平均値を求め、乳化力を評価した。結果を表1に示す。
【0030】
【表1】
【0031】
以上の結果より、実施例1〜4の乳化組成物は、比較例1〜4の乳化組成物と比較して、明らかに乳化容量が増大しているのが分かる。また、多糖類の含有量も極少量であるため、いずれの実施例の乳化組成物も、異臭やヌルつきのない、良好な風味、食感を有していた。さらに、比較例5と比較例6の結果から、加熱処理による乳化力向上の効果は、卵黄の加熱処理のみで起こるものではなく、卵黄と多糖類を適当な温度にて共に加熱処理することによって得られるものであることが分かる。
また、比較例1〜3と比較例6の対比から、実施例1〜3で用いたキサンタンガム、ペクチン、カラギナンの添加量は、それらの添加のみでは、乳化力の向上が認められない程の少量であることが分かる。
【0032】
【発明の効果】
本発明の卵黄と多糖類を含有した乳化組成物は、乳化力、風味も良好であり、その製造も容易である。従って、本発明の乳化組成物は、幅広い飲食品への適用が可能であり、食品産業に大いに貢献できるものである。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an emulsified composition that can be suitably used as an additive for various foods and drinks, a method for producing the same, and a food and drink containing the emulsified composition.
[0002]
[Prior art]
Chicken egg yolk is an emulsion composed of about 50% by weight of water, about 30% by weight of fat, about 15% by weight of protein, etc., and is used in various foods by utilizing its emulsifying power. However, in a system having a large amount of water, the viscosity of the food is reduced, so that the emulsifying power of the egg yolk is limited. For example, in a liquid dressing, the lipophilic component and the hydrophilic component are separated over time. Thus, there has been reported a method of increasing the stability of a product by using it together with an emulsifier such as lecithin or glycerin fatty acid ester or a polysaccharide such as xanthan gum (Patent Documents 1 and 2). However, if the emulsifier is used frequently, the taste of the emulsifier may appear, and if the thickening polysaccharide such as xanthan gum is used too much, the unique texture of the polysaccharide comes out or the viscosity increases. It is said that it is difficult to achieve both stability and flavor / texture.
[0003]
[Patent Document 1]
JP-A-7-274893 (Claim 1, [0009], etc.)
[0004]
[Problems to be solved by the invention]
An object of the present invention is to provide an emulsified composition containing egg yolk and polysaccharide, which has good emulsifying power and flavor, a method for producing the same, and a food or drink containing the emulsified composition.
[0005]
[Means for Solving the Problems]
The present invention
(1) an emulsion composition containing egg yolk and polysaccharide, obtained by a method including a step of heating a mixed solution containing egg yolk and polysaccharide to a temperature equal to or lower than the heat coagulation temperature of egg yolk protein;
(2) A method for producing an emulsion composition containing egg yolk and polysaccharide, comprising a step of heating a mixed solution containing egg yolk and polysaccharide to a temperature equal to or lower than the heat coagulation temperature of egg yolk protein, and (3) A food or drink comprising the emulsion composition according to (1).
[0006]
BEST MODE FOR CARRYING OUT THE INVENTION
The emulsified composition of the present invention is obtained by a method including a step of heating a mixed solution containing egg yolk and polysaccharide to a temperature equal to or lower than the thermal coagulation temperature of the protein in the egg yolk, and has an excellent emulsifying power. Also, the flavor and texture are good. The details of why such excellent properties can be obtained by heat treatment of a mixture containing egg yolk and polysaccharides are unknown, but heat treatment strengthens the network of egg yolk proteins and polysaccharides, It is estimated that the emulsifying power can be improved without adding a large amount of saccharides.
[0007]
The egg yolk in the present invention is not particularly limited as long as it is liquid, such as chicken eggs, duck eggs, etc., but chicken egg yolk is preferred in view of the supply amount. Egg yolks can be used in general, and are not limited to raw yolks, but may be germicidal yolks, salted yolks, sweetened yolks, or frozen products thereof. In the present invention, the salt content is 5%. Preference is given to salted egg yolks of up to about 20% by weight. Further, a yolk powder obtained by diluting egg yolk powder with water or a liquid yolk diluted with water or the like to reduce the viscosity can be used.
[0008]
The mixture may be composed of only the yolk and the polysaccharide, but from the viewpoint of viscosity, the content of the yolk in the mixture is preferably 0.5 to 80% by weight, and more preferably 1.0 to 50% by weight. More preferred.
[0009]
The polysaccharides in the present invention include xanthan gum, LM pectin, pectin such as HM pectin, kappa carrageenan, carrageenan such as iota carrageenan, lambda carrageenan, guar gum, cod gum, locust bean gum, gellan gum, tamarind seed gum, gum arabic, karaya gum, Pullulan, psyllium seed gum, trolley mallow, phacelerin, and their decomposed products, alginic acid, sodium alginate, propylene glycol alginate, sodium carboxymethylcellulose, sodium starch phosphate, sodium starch glycolate, methylcellulose, soybean polysaccharide, konjac powder, Specially used foods such as seaweed / brown algae extract, okra extract, aloe vera extract, peach extract, etc. Although not limited thereto, from the viewpoint of reactivity with egg yolk proteins, pectin, xanthan gum, carrageenan, gellan gum, alginic acid, acidic polysaccharides such as sodium carboxymethylcellulose are preferable, and are selected from the group consisting of xanthan gum, pectin and carrageenan. At least one of them is more preferable. These polysaccharides may be used alone or in combination of two or more.
[0010]
The blending amount of the polysaccharide in the present invention is appropriately determined in consideration of the type and viscosity of the polysaccharide, but is preferably about 0.05 to 5 parts by weight, preferably 0.1 to 4 parts by weight, per 100 parts by weight of the egg yolk. Part by weight is more preferable, and 0.2 to 2 parts by weight is particularly preferable.
[0011]
Furthermore, the emulsion composition of the present invention may optionally contain dextrin, soybean polysaccharide, egg white, emulsifier, and the like, if necessary.
[0012]
In the present invention, the method of mixing the egg yolk and the polysaccharide is not particularly limited, for example, the mixture is excessively thickened by directly adding the polysaccharide to the egg yolk, and it is difficult to uniformly disperse and dissolve the polysaccharide. In this case, a method of mixing an aqueous solution in which a polysaccharide is dispersed and dissolved in water in advance with egg yolk is preferable. In this case, once the aqueous solution of the polysaccharide is heated, the polysaccharide is completely swollen / dissolved, cooled, and then mixed with the egg yolk, whereby the polysaccharide can be more easily uniformly dispersed and dissolved in the egg yolk. . The amount of water for dispersing and dissolving the polysaccharide is not particularly limited, and may be appropriately determined in consideration of the efficiency in the subsequent heating step.
[0013]
The heating temperature of the mixed solution containing the egg yolk and the polysaccharide is not particularly limited as long as the temperature is equal to or lower than the heat coagulation temperature of the yolk protein, and the concentration of the yolk, the type of the polysaccharide to be used, and addition of salt and sweetened to the yolk. Although the optimum temperature varies depending on the presence or absence of the substance, the thermocoagulation temperature of the egg yolk protein is usually 65 to 75 ° C, and thus is preferably 50 to 70 ° C, more preferably 55 to 65 ° C.
[0014]
As a heating method of the mixed liquid containing the egg yolk and the polysaccharide, a method that can uniformly heat the mixed liquid by a plate type (continuous type) or a batch type heating method in which heating is performed while stirring up, down, left, and right with a stirring blade is preferable.
[0015]
The heating time of the mixture containing the egg yolk and the polysaccharide is appropriately determined depending on the heating temperature and the heating efficiency. For example, 50% by weight of the yolk liquid, 49.5% by weight of purified water, and 0.5% by weight of xanthan gum % Is heated at 64 ° C. by a continuous heating method using a plate, the heating time is preferably about 1 to 15 minutes, more preferably about 2 to 10 minutes. In the case where the same treatment is performed by a batch heating method, heating at a low temperature for a long time (for example, about 30 to 90 minutes) is preferable from the viewpoint of treating with a heat amount corresponding to the continuous heating method.
[0016]
As described above, the emulsified composition of the present invention not only has a high emulsifying power but also has a good flavor and texture, and thus can be used as an additive for various foods and drinks.
[0017]
Therefore, the present invention further provides a food or drink containing the emulsified composition of the present invention. Although the food and drink of the present invention are very wide-ranging, examples thereof include liquid dressings, ice creams, cakes, cookies, breads and the like. It is preferable that the content of the emulsified composition of the present invention in food and drink is appropriately determined according to the type of food and drink and the like.
[0018]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to the examples.
[0019]
Example 1
After the shelled egg was split to separate the egg white and the yolk, the yolk liquid was passed through a strainer to remove foreign substances to obtain 500 g of raw egg yolk (thermocoagulation temperature of egg yolk protein: 68 ° C.). Next, after dispersing and dissolving 5 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) in 495 g of purified water with a homodisper, the mixture was heated to 90 ° C. in a hot water bath and cooled to room temperature to obtain an aqueous polysaccharide solution. . Next, the raw egg yolk and the aqueous solution of the polysaccharide were mixed, and the mixture was subjected to batch heat treatment in a 63 ° C. water bath for 60 minutes while slowly stirring to obtain an emulsified composition. The mixed solution subjected to the heat treatment reached the maximum temperature (62.5 ° C.) due to the heating within 30 minutes from the start of the heating.
[0020]
Example 2
An emulsified composition was obtained in the same manner as in Example 1, except that 5 g of LM pectin (manufactured by Taiyo Kagaku Co., Ltd.) was used instead of xanthan gum.
[0021]
Example 3
An emulsified composition was obtained in the same manner as in Example 1 except that 5 g of kappa carrageenan (manufactured by Taiyo Chemical Co., Ltd.) was used instead of xanthan gum.
[0022]
Example 4
An emulsified composition was obtained in the same manner as in Example 1, except that 500 g of 10% salted egg yolk was used instead of raw egg yolk.
[0023]
Comparative Example 1
An emulsified composition was obtained in the same manner as in Example 1 except that the heat treatment was not performed.
[0024]
Comparative Example 2
An emulsified composition was obtained in the same manner as in Example 2 except that the heat treatment was not performed.
[0025]
Comparative Example 3
An emulsion composition was obtained in the same manner as in Example 3, except that the heat treatment was not performed.
[0026]
Comparative Example 4
An emulsified composition was obtained in the same manner as in Example 4, except that the heat treatment was not performed.
[0027]
Comparative Example 5
Only 500 g of purified water was added to 550 g of 10% salted egg yolk, mixed and heat-treated in the same manner as in Example 1 to obtain an emulsified composition.
[0028]
Comparative Example 6
An emulsified composition was obtained in the same manner as in Comparative Example 5, except that the heat treatment was not performed.
[0029]
Test Example 0.5 g of the emulsified composition was accurately weighed, dispersed and dissolved in 50 ml of distilled water to obtain an aqueous solution having a yolk content of 0.5% by weight. While the obtained aqueous solution was stirred at 6000 r / min with a homomixer, rapeseed white squeezed oil was added while being measured in 5 ml units, and the end point was obtained when the layer was transferred from the O / W emulsification system to the W / O emulsification system. The total amount of rapeseed white squeezed oil at this point was defined as the emulsification capacity. That is, it can be said that the larger the amount of addition, the larger the emulsification capacity. This test was performed three times in total, the average value of the emulsifying capacity was obtained, and the emulsifying power was evaluated. Table 1 shows the results.
[0030]
[Table 1]
[0031]
From the above results, it can be seen that the emulsified compositions of Examples 1 to 4 have clearly increased emulsifying capacity as compared with the emulsified compositions of Comparative Examples 1 to 4. In addition, since the content of the polysaccharide was extremely small, the emulsion compositions of all Examples had good flavor and texture without off-flavors and nulls. Further, from the results of Comparative Example 5 and Comparative Example 6, the effect of improving the emulsifying power by the heat treatment is not caused only by the heat treatment of the yolk, but by heating the egg yolk and the polysaccharide together at an appropriate temperature. It can be seen that it is obtained.
In addition, from the comparison of Comparative Examples 1 to 3 and Comparative Example 6, the amounts of xanthan gum, pectin, and carrageenan used in Examples 1 to 3 were so small that no improvement in the emulsifying power was observed only by their addition. It turns out that it is.
[0032]
【The invention's effect】
The emulsified composition containing the egg yolk and the polysaccharide of the present invention has good emulsifying power and flavor, and is easy to produce. Therefore, the emulsified composition of the present invention can be applied to a wide variety of foods and drinks, and can greatly contribute to the food industry.
Claims (7)
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