JP2004277365A - Foam forming composition for pump foamer - Google Patents
Foam forming composition for pump foamer Download PDFInfo
- Publication number
- JP2004277365A JP2004277365A JP2003073131A JP2003073131A JP2004277365A JP 2004277365 A JP2004277365 A JP 2004277365A JP 2003073131 A JP2003073131 A JP 2003073131A JP 2003073131 A JP2003073131 A JP 2003073131A JP 2004277365 A JP2004277365 A JP 2004277365A
- Authority
- JP
- Japan
- Prior art keywords
- foam
- weight
- forming composition
- parts
- cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 239000006260 foam Substances 0.000 title abstract description 25
- -1 polyoxyethylene Polymers 0.000 claims abstract description 41
- 239000002537 cosmetic Substances 0.000 claims abstract description 37
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 26
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 24
- 239000000194 fatty acid Substances 0.000 claims abstract description 24
- 229930195729 fatty acid Natural products 0.000 claims abstract description 24
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 6
- 229920000223 polyglycerol Polymers 0.000 abstract description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 12
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 12
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 8
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- 238000004140 cleaning Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 229940105990 diglycerin Drugs 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
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- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
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Abstract
Description
【０００１】
【発明の属する技術分野】
本発明は、化粧料及びその組成物に関し、更に詳細には、ポンプフォーマータイプの泡沫状化粧料に好適な化粧料及びその為の化粧料組成物に関する。
【０００２】
【従来の技術】
化粧料の機能として、「肌を清浄に整える」ことは薬事法にも規定されているとおり、重要な機能の一つである。この意味で、所謂洗浄用の化粧料は重要な化粧品構成の一つと言える。通常洗浄用の化粧料は、油性汚れを落とす油性洗浄料（クレンジング化粧料）と水性洗浄料の二種が存し、これらを用いて、油性洗浄料で油性汚れを落とした後、水性洗浄料で水性汚れを落とす、「ダブル洗顔」による洗浄が広く用いられている。かかる洗浄料の内、油性洗浄料として最も一般的なものは、液体脂を多く含有する、高内相の水中油エマルションタイプのクレンジング化粧料であるが、かかる洗浄料は、油汚れを落とす作用に優れるものの、使用後油脂が皮膚上に残存し、水性洗浄料による洗浄無しには不都合のあるものである。従って、外出先で簡単にメークアップ落としをして、化粧直しをするには、この様な油性の洗浄料は使用しにくい性質のものであった。この様な観点から、ウオッシュオフタイプの油性洗浄料が開発されているが、これについては水でウオッシュオフしやすければ油性汚れが落としにくく、油性汚れが落としやすければウオッシュオフしにくい傾向があり、完全なものとは言い難かった。この様な状況を背景に、水馴染みの良い組成物を泡沫状に噴出させて、泡の表面張力の低さを利用して油性汚れを落とす、フォーム状クレンジングの技術が開発されている。この様なフォーム状クレンジングの内、環境的な配慮からポンプフォーマーを用いたものとしては、例えば、両性界面活性剤を泡沫形成剤として用いたもの（例えば、特許文献１）、非イオン界面活性剤とアニオン性界面活性剤の組合せを用いたもの（例えば、特許文献２、３）或いはアルキルアミノジカルボン酸を用いたもの（例えば、特許文献４）などが存するが、これらの何れもがイオン性界面活性剤を用いたものである。イオン性界面活性剤を用いると、一次刺激が高まり、敏感肌の人には使いにくい欠点が生じるが、非イオン界面活性剤のみではこれまでのところ好適な泡沫は得られていない。即ち、非イオン性界面活性剤のみを界面活性剤として使用し、フォーム状クレンジング料に好適な泡沫を形成させる組成物の開発が望まれていた。
【０００３】
一方、１）非イオン界面活性剤３〜１０重量％と２）多価アルコール２〜５重量％と３）水７０〜９５重量％とを含有するフォーム形成用の化粧料組成物は全く知られていないし、かかる組成物をポンプフォーマーに充填してなる化粧料も知られていない。更に、かかる化粧料が生ずる泡沫が、水性であるにも係わらず、優れた油性汚れ除去効果を有していることも全く知られていない。
【０００４】
【発明が解決しようとする課題】
本発明は、この様な状況下為されたものであり、非イオン性界面活性剤のみを界面活性剤として使用し、フォーム状クレンジング料に好適な泡沫を形成させる組成物を提供することを課題とする。
【０００５】
【特許文献１】
特開２００２−４７１７２号公報
【特許文献２】
特開２００２−８７９４２号公報
【特許文献３】
特開平１１−３５９７２号公報
【特許文献４】
特開２００２−２５６２９８号公報
【０００６】
【課題の解決手段】
この様な状況に鑑みて、本発明者らは、非イオン性界面活性剤のみを界面活性剤として使用し、フォーム状クレンジング料に好適な泡沫を形成させる組成物を求めて、鋭意研究努力を重ねた結果、１）非イオン界面活性剤３〜１０重量％と２）多価アルコール２〜５重量％と３）水７０〜９５重量％とを含有するフォーム形成用の化粧料組成物がその様な特性を有していることを見出し、発明を完成させるに至った。即ち、本発明は、以下に示す技術に関するものである。
（１）ポンプフォーマー用の組成物であって、１）非イオン界面活性剤３〜１０重量％と２）多価アルコール２〜５重量％と３）水７０〜９５重量％とを含有することを特徴とする、泡沫形成組成物。
（２）前記非イオン性界面活性剤として、脂肪酸ポリオキシエチレングリセリルを含有することを特徴とする、（１）に記載の泡沫形成組成物。
（３）前記非イオン性界面活性剤として、ポリグリセリンの脂肪酸エステルを含有することを特徴とする、（１）又は（２）に記載の泡沫形成組成物。
（４）実質的にアニオン性界面活性剤を含有しないことを特徴とする、（１）〜（３）何れか１項に記載の泡沫形成組成物。
（５）クレンジング用の化粧料組成物であることを特徴とする、（１）〜（４）何れか１項に記載の泡沫形成組成物。
（６）（１）〜（５）何れか１項に記載の泡沫形成組成物をフォーマー容器に充填してなる、化粧料。
（７）クレンジング化粧料であることを特徴とする、（６）に記載の化粧料。
【０００７】
【発明の実施の形態】
（１）本発明の泡沫形成組成物の必須成分である非イオン界面活性剤
本発明の泡沫形成組成物は、ポンプフォーマー用の組成物であって、非イオン界面活性剤３〜１０重量％、更に好ましくは４〜８重量％含有することを特徴とする。非イオン性界面活性剤としては、化粧料分野で使用されているものであれば、特段の限定無く使用することが出来、例えば、ソルビタンセスキオレート、ソルビタンモノオレート、ソルビタントリオレート、ソルビタンセスキステアレート、ソルビタンモノステアレート等のソルビタン脂肪酸エステル類、ポリオキシエチレンソルビタンモノオレート、ポリオキシエチレンソルビタンモノステアレート等のポリオキシエチレンソルビタン脂肪酸エステル類、ポリオキシエチレンステアレート、ポリオキシエチレンオレート等のポリオキシエチレン脂肪酸エステル、ポリオキシエチレンイソステアリン酸グリセリル、ポリオキシエチレンヤシ油脂肪酸グリセリル等のポリオキシエチレン脂肪酸グリセリル、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンオレイルエーテル等のポリエキシエチレンアルキル（アルケニル）エーテル、ポリオキシエチレン硬化ヒマシ油、ラウリン酸ドデカグリセリン、ラウリン酸デカグリセリン、ラウリン酸ヘキサグリセリン、ステアリン酸デカグリセリンなどのポリグリセリン脂肪酸エステルなどが好適に例示できる。これらの内で特に好ましいものは、ポリオキシエチレン脂肪酸グリセリル及び／又はポリグリセリン脂肪酸エステルであり、この二種を併用する形態が特に好ましい。中でもポリグリセリン脂肪酸エステルとしては、ポリグリセリンラウリン酸エステルが好ましく、グリセリンの重合度としては５〜１４が特に好ましい。ポリオキシエチレン脂肪酸グリセリルとしては、ポリオキシエチレンイソステアリン酸グリセリル、ポリオキシエチレン（カプリル酸・カプリン酸）グリセリル乃至はポリオキシエチレンヤシ油脂肪酸グリセリルが特に好ましい。本発明の泡沫形成組成物に於いては、かかる非イオン性界面活性剤は唯一種含有することも可能であるし、二種以上を組み合わせて含有することも可能である。
【０００８】
（２）本発明の泡沫形成組成物の必須成分である多価アルコール
本発明の泡沫形成組成物は、ポンプフォーマー用の組成物であって、多価アルコール２〜５重量％、より好ましくは２．５〜４重量％を含有することを特徴とする。かかる多価アルコールとしては、通常化粧料で使用されているものであれば特段の限定無く使用することが出来、例えば、グリセリン、ジグリセリン、１，３−ブタンジオール、ジプロピレングリコール、ポリエチレングリコール、１，２−ペンタンジオール、１，２−ヘキシレングリコール、イソプレングリコールなどの多価アルコールが好ましく例示でき、中でも、抗菌性を有する、１，３−ブタンジオール、１，２−ペンタンジオール、１，２−ヘキシレングリコール及びイソプレングリコールから選択される１種乃至は２種以上が好ましく例示できる。本発明の泡沫形成組成物に於いては、かかる多価アルコールを唯一種含有することも出来るし、二種以上組み合わせて含有することも出来る。本発明の泡沫形成組成物に於いて、かかる多価アルコールは、油性汚れを組成物に引き出す作用を有すると同時に、泡に腰を付与する作用を有する。
【０００９】
（３）本発明の泡沫形成組成物の必須成分である水
本発明の泡沫形成組成物は、ポンプフォーマー用の組成物であって、水を７０〜９５重量％、より好ましくは８０〜９３重量％を含有することを特徴とする。本発明の泡沫形成組成物に於いて、水は、かかる含有することにより、水洗性を向上させる作用を有する。又、かかる割合の水分を含有することにより、ポンプフォーマーでの発泡性を著しく向上させることが出来る。
【００１０】
（４）本発明の泡沫形成組成物
本発明の泡沫形成組成物は前記必須成分を含有することを特徴とする。本発明の泡沫形成組成物に於いてはこれらの必須成分以外に、通常化粧料で知られている任意成分を含有することが出来る。かかる任意成分としては、例えば、スクワラン、流動パラフィン、軽質流動イソパラフィン、重質流動イソパラフィン、マイクロクリスタリンワックス、固形パラフィンなどの炭化水素類、ジメチコン、フェメチコン、シクロメチコン、アモジメチコン、ポリエーテル変性シリコーンなどのシリコーン類、ホホバ油、カルナウバワックス、モクロウ、ミツロウ、ゲイロウ、オレイン酸オクチルドデシル、イソプロピルミリステート、ネオペンチルグリコールジイソステアレート、リンゴ酸ジイソステアレートなどのエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、イソパルミチン酸、ベヘン酸、オレイン酸などの脂肪酸類、ベヘニルアルコール、セタノール、オレイルアルコール、オクタデシルアルコールなどの高級アルコール類、ヒマシ油、椰子油、水添椰子油、椿油、小麦胚芽油、イソステアリン酸トリグリセライド、イソオクタン酸トリグリセライド、オリーブオイル等のトリグリセライド類、ソジウムラウリルステアレート、ポリオキシエチレンアルキル硫酸塩、スルホコハク酸エステル塩などのアニオン界面活性剤、４級アルキルアンモニウム塩等のカチオン界面活性剤類、アルキルベタイン等の両性界面活性剤類、結晶セルロースや架橋型メチルポリシロキサン、ポリエチレン粉末、アクリル樹脂粉体等の有機粉体類、タルク、マイカ、セリサイト、炭酸マグネシウム、炭酸カルシウム、二酸化チタン、酸化鉄、紺青、群青、チタンマイカ、チタンセリサイト、シリカ等の表面処理されていても良い粉体類、アクリル酸・メタクリル酸アルキルコポリマー及び／又はその塩、カルボキシビニルポリマー及び／又はその塩、キサンタンガムやヒドロキシプロピルセルロースなどの増粘剤、レチノール、レチノイン酸、トコフェロール、リボフラビン、ピリドキシン、アスコルビン酸、アスコルビン酸リン酸エステル塩などのビタミンやグリチルリチン酸塩、グリチルレチン、ウルソール酸、オレアノール酸などのテルペン類、エストラジオール、エチニルエストラジオール、エストリオールなどのステロイド類などの有効成分、フェノキシエタノール、パラベン類、ヒビテングルコネート、塩化ベンザルコニウム等の防腐剤、ジメチルアミノ安息香酸エステル類、桂皮酸エステル類、ベンゾフェノン類などの紫外線吸収剤などが好ましく例示できる。好ましい形態としては、アニオン性界面活性剤、カチオン性界面活性剤或いは両性界面活性剤などのイオン性界面活性剤を含有しない形態である。これは、使用時の刺激感の発現が抑制できることと、かかる成分が無くとも、上記の特定の配合割合においては、コシの強い泡沫が、ポンプフォーマーによっても形成されるからである。
【００１１】
（５）本発明の化粧料
本発明の化粧料は、前記化粧料組成物をポンプフォーマー容器に充填してなることを特徴とする。ここで、ポンプフォーマー容器とは、手押しポンプの圧力により、容器の副室内に空気を導入し、ここで化粧料組成物と混合し泡沫を生じせしめる容器のことを意味する。かかる容器は既に一般小売店で市販されているものが存し、かかる市販品を利用することも可能である。かくして得られた、本発明の化粧料は、フォーマーにより生じる泡沫が、腰の強さ、一次刺激の低さ、油性成分分散力の強さと言った長所を有している為、フォーム状クレンジング、髭剃り化粧料、フォーム状育毛料、フォーム状整髪料などに適用することが出来る。特に好ましいものは、泡形成により、表面著力が著しく低下することを利用した、フォーム状クレンジングである。
【００１２】
【実施例】
以下に、実施例を挙げて、本発明について更に詳細に説明を加えるが、本発明がかかる実施例に限定を受けないことは言うまでもない。
【００１３】
＜実施例１＞
以下に示す処方に従って、本発明の泡沫形成組成物１を作成した。即ち、処方成分を８０℃で加熱攪拌し、可溶化した後、攪拌冷却し、本発明の泡沫形成組成物１を得た。
１，３−ブタンジオール ３ 重量部
ＰＯＥ（７）ヤシ油脂肪酸グリセリル ２ 重量部
ＰＯＥ（２０）イソステアリン酸グリセリル ２ 重量部
ドデカグリセリンモノラウレート ２ 重量部
スクワラン ０．１重量部
フェノキシエタノール ０．５重量部
水 ９３．４重量部
【００１４】
＜実施例２＞
実施例１の泡沫形成組成物１をポンプフォーマー容器に充填し、本発明の化粧料１を作成した。同時に、泡沫形成組成物１の非イオン性界面活性剤を全てラウリル硫酸ナトリウムに置換した比較例１、ラウリルイミダゾリニウムベタインに置換した比較例２も作成した。更に、従来のダブル洗顔のクレンジング料と水性洗顔料の組合せ（標準例）も用意した。これらについて、リップカラーを用いてクレンジング効果を調べた。上腕内側部に設けた２ｃｍ×４ｃｍの部位に、下記に示す処方のリップカラーを０．２ｇ塗布し、洗浄料０．１ｇで洗い落とす試験も同時に行った。洗浄後、リップカラー塗布部位と周囲の部位の色差をミノルタ株式会社の色差計を用いて測定した。この結果も表１に示す。尚、表中の泡沫形成組成物１とは、フォーマーに充填せず、液状のまま用いたものである。又、これらの組成物の、パネラー２０名を用いた、人パッチテストの結果も陽性率として表１に示す。これより、本発明の泡沫形成組成物は一次刺激が低く、安全性も高いことがわかる。
【００１５】
（評価の為のリップカラー）
マイクロクリスタリンワックス １０ 重量部
ポリエチレン ５ 重量部
架橋型メチルポリシロキサン ５ 重量部
固形パラフィン ５ 重量部
モクロウ ５ 重量部
カルナウバワックス ５ 重量部
ヒマシ油 ２０ 重量部
水添ヤシ油 １０ 重量部
スクワラン １５ 重量部
色素 ２０ 重量部
【００１６】
（標準例のクレンジング料）
スクワラン ３０ 重量部
セチルイソオクタネート ３０ 重量部
マイクロクリスタリンワックス ２ 重量部
ステアリン酸 １ 重量部
ステアリルアルコール ２ 重量部
ＰＯＥ（４５）ステアリン酸エステル ２ 重量部
ソルビタンセスキステアレート ３ 重量部
１０％苛性カリ水溶液 ０．２重量部
１，３−ブタンジオール ５ 重量部
水 ２４．８重量部
【００１７】
（標準例の水性洗顔料）
ステアリン酸 １５ 重量部
ミリスチン酸 １２ 重量部
ラウリン酸 ５ 重量部
セチルアルコール ０．３重量部
ベヘニルアルコール ０．２重量部
ダイズレシチン ０．１重量部
ホホバアルコール ０．１重量部
水 ３８ 重量部
水酸化カリウム ７ 重量部
グリセリン １２ 重量部
ジグリセリン ５ 重量部
カルボキシメチルセルロースナトリウム ０．３重量部
ソルビトール １０ 重量部
【００１８】
【表１】
＜実施例３〜５＞
泡沫形成組成物１の非イオン性界面活性剤の組成を変えて、同様に泡沫形成組成物及び本発明の化粧料を作成し、実施例２のクレンジング効果評価を行った。結果を表２に示す。これより、ポリオキシエチレン脂肪酸グリセリル及びポリグリセリン脂肪酸エステルの二種を併用する形態が特に好ましい事がわかる。
１，３−ブタンジオール ３ 重量部
表２に記載の非イオン性界面活性剤 ６ 重量部
スクワラン ０．１重量部
フェノキシエタノール ０．５重量部
水 ９３．４重量部
【００２０】
【表２】
＜実施例６＞
泡沫形成組成物１の非イオン性界面活性剤の内のポリグリセリン脂肪酸エステルの種類を変えて、同様に泡沫形成組成物及び本発明の化粧料を作成し、実施例２のクレンジング効果評価を行った。結果を表３に示す。これより、何れのポリグリセリンの脂肪酸エステルも使用可能であるが、ラウリン酸エステルが好ましいことがわかる。
１，３−ブタンジオール ３ 重量部
ＰＯＥ（７）ヤシ油脂肪酸グリセリル ２ 重量部
ＰＯＥ（２０）イソステアリン酸グリセリル ２ 重量部
表３に記載の非イオン性界面活性剤 ２ 重量部
スクワラン ０．１重量部
フェノキシエタノール ０．５重量部
水 ９３．４重量部
【００２２】
【表３】
【発明の効果】
本発明によれば、非イオン性界面活性剤のみを界面活性剤として使用し、フォーム状クレンジング料に好適な泡沫を形成させる組成物を提供することができる。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a cosmetic and a composition thereof, and more particularly to a cosmetic suitable for a pump-former type foamy cosmetic and a cosmetic composition therefor.
[0002]
[Prior art]
As a function of cosmetics, "cleansing the skin" is one of the important functions as prescribed in the Pharmaceutical Affairs Law. In this sense, a so-called cleaning cosmetic is one of the important cosmetic compositions. Normally, there are two types of cosmetics for cleaning, an oil-based cleaning agent (cleansing cosmetic) and an aqueous cleaning agent, which remove oil-based stains. Washing by "double face washing", which removes water-based stains, is widely used. Among these detergents, the most common oil-based detergent is a high internal phase oil-in-water emulsion type cleansing cosmetic containing a large amount of liquid fat, but such detergent has an effect of removing oil stains. However, oils and fats remain on the skin after use, which is inconvenient without washing with an aqueous detergent. Therefore, in order to easily remove make-up and to redress makeup on the go, it is difficult to use such an oil-based cleaning agent. From this point of view, a wash-off type oil-based cleaning agent has been developed.However, it is difficult to remove oil-based stains if it is easy to wash off with water, and it is difficult to wash off if oil-based stains are easily removed, It was hard to say perfect. Against this background, a foam-based cleansing technique has been developed in which a water-friendly composition is ejected in the form of foam to remove oily stains by utilizing the low surface tension of foam. Among such foam cleansings, those using a pump former in consideration of the environment include, for example, those using an amphoteric surfactant as a foam-forming agent (for example, Patent Document 1), non-ionic surfactants There are those using a combination of an agent and an anionic surfactant (for example, Patent Documents 2 and 3) and those using an alkylaminodicarboxylic acid (for example, Patent Document 4), all of which are ionic. It uses a surfactant. The use of ionic surfactants increases primary irritation and has the disadvantage of making it difficult for people with sensitive skin to use them. However, nonionic surfactants alone have not been able to obtain suitable foams so far. That is, it has been desired to develop a composition that uses only a nonionic surfactant as a surfactant and forms a foam suitable for a foam cleansing agent.
[0003]
On the other hand, cosmetic compositions for foam formation containing 1) 3 to 10% by weight of a nonionic surfactant, 2) 2 to 5% by weight of a polyhydric alcohol, and 3) 70 to 95% by weight of water are completely known. There is no known cosmetic composition obtained by filling such a composition into a pump former. Furthermore, it is not known at all that the foams produced by such cosmetics have an excellent oily stain removing effect despite being aqueous.
[0004]
[Problems to be solved by the invention]
The present invention has been made under such circumstances, and it is an object of the present invention to provide a composition that uses only a nonionic surfactant as a surfactant and forms a foam suitable for a foam cleansing material. And
[0005]
[Patent Document 1]
JP 2002-47172 A [Patent Document 2]
JP 2002-87942 A [Patent Document 3]
JP-A-11-35972 [Patent Document 4]
JP 2002-256298 A
[Means for solving the problem]
In view of such a situation, the present inventors have made intensive research efforts in search of a composition that uses only a nonionic surfactant as a surfactant and forms a foam suitable for a foam cleansing material. As a result of the superposition, a cosmetic composition for forming a foam containing 1) 3 to 10% by weight of a nonionic surfactant, 2) 2 to 5% by weight of a polyhydric alcohol and 3) 70 to 95% by weight of water is obtained. The inventors have found that they have such characteristics, and have completed the invention. That is, the present invention relates to the following technology.
(1) A composition for a pump former, comprising 1) 3 to 10% by weight of a nonionic surfactant, 2) 2 to 5% by weight of a polyhydric alcohol, and 3) 70 to 95% by weight of water. A foam-forming composition, characterized in that:
(2) The foam-forming composition according to (1), wherein the composition comprises a fatty acid polyoxyethylene glyceryl as the nonionic surfactant.
(3) The foam-forming composition according to (1) or (2), wherein the nonionic surfactant contains a fatty acid ester of polyglycerin.
(4) The foam-forming composition according to any one of (1) to (3), which does not substantially contain an anionic surfactant.
(5) The foam-forming composition according to any one of (1) to (4), which is a cosmetic composition for cleansing.
(6) A cosmetic comprising the foam-forming composition according to any one of (1) to (5) in a former container.
(7) The cosmetic according to (6), which is a cleansing cosmetic.
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
(1) Nonionic surfactant which is an essential component of the foam-forming composition of the present invention The foam-forming composition of the present invention is a composition for a pump former, and 3 to 10% by weight of a nonionic surfactant. , More preferably 4 to 8% by weight. Nonionic surfactants can be used without particular limitation as long as they are used in the cosmetics field. For example, sorbitan sesquiolate, sorbitan monooleate, sorbitan triolate, sorbitan sesquistearate Sorbitan fatty acid esters such as sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan monostearate, polyoxyethylene stearate, and polyoxyethylene such as polyoxyethylene oleate Polyoxyethylene fatty acid glyceryl, such as ethylene fatty acid ester, polyoxyethylene glyceryl isostearate, polyoxyethylene coconut oil fatty acid glyceryl, and polyoxyethylene lauryl ether Polyoxyethylene alkyl (alkenyl) ethers such as polyoxyethylene oleyl ether; polyoxyethylene hydrogenated castor oil; polyglycerol fatty acid esters such as dodecaglycerin laurate, decaglycerin laurate, hexaglycerin laurate, and decaglycerin stearate; This can be suitably exemplified. Of these, particularly preferred are polyoxyethylene fatty acid glyceryl and / or polyglycerin fatty acid ester, and a form in which these two are used in combination is particularly preferred. Among them, polyglycerin fatty acid ester is preferably polyglycerin laurate, and the degree of polymerization of glycerin is particularly preferably 5 to 14. As the polyoxyethylene fatty acid glyceryl, polyoxyethylene glyceryl isostearate, polyoxyethylene (caprylic acid / capric acid) glyceryl or polyoxyethylene coconut oil fatty acid glyceryl is particularly preferable. In the foam-forming composition of the present invention, such a nonionic surfactant may contain only one kind or two or more kinds in combination.
[0008]
(2) Polyhydric alcohol which is an essential component of the foam-forming composition of the present invention The foam-forming composition of the present invention is a composition for a pump former, and is preferably 2 to 5% by weight of a polyhydric alcohol, more preferably It is characterized by containing 2.5 to 4% by weight. As such polyhydric alcohols, those which are usually used in cosmetics can be used without any particular limitation. For example, glycerin, diglycerin, 1,3-butanediol, dipropylene glycol, polyethylene glycol, Polyhydric alcohols such as 1,2-pentanediol, 1,2-hexylene glycol and isoprene glycol can be preferably exemplified, and among them, 1,3-butanediol, 1,2-pentanediol, One or more selected from 2-hexylene glycol and isoprene glycol can be preferably exemplified. In the foam-forming composition of the present invention, such a polyhydric alcohol may be contained solely or in combination of two or more. In the foam-forming composition of the present invention, such a polyhydric alcohol has an action of drawing oily soil to the composition and, at the same time, an action of giving foam to the foam.
[0009]
(3) Water as an essential component of the foam-forming composition of the present invention The foam-forming composition of the present invention is a composition for a pump former, and contains 70 to 95% by weight of water, more preferably 80 to 93% by weight. % By weight. In the foam-forming composition of the present invention, water has an effect of improving the water-washing property by containing the water. Further, by containing such a ratio of water, the foaming property of the pump former can be remarkably improved.
[0010]
(4) Foam-forming composition of the present invention The foam-forming composition of the present invention is characterized by containing the above essential components. In addition to these essential components, the foam-forming composition of the present invention may contain optional components commonly known in cosmetics. Such optional components include, for example, squalane, liquid paraffin, light liquid isoparaffin, heavy liquid isoparaffin, microcrystalline wax, hydrocarbons such as solid paraffin, dimethicone, femethicone, cyclomethicone, amodimethicone, and polyether-modified silicone. Silicones, jojoba oil, carnauba wax, mocro, beeswax, gay wax, octyldodecyl oleate, isopropyl myristate, neopentyl glycol diisostearate, esters such as malic acid diisostearate, stearic acid, lauric acid, Fatty acids such as myristic acid, palmitic acid, isostearic acid, isopalmitic acid, behenic acid, oleic acid, behenyl alcohol, cetanol, oleyl alcohol, octadecyl alcohol Higher alcohols such as coal, castor oil, coconut oil, hydrogenated coconut oil, camellia oil, wheat germ oil, triglycerides such as isostearic acid triglyceride, isooctanoic acid triglyceride, olive oil, sodium lauryl stearate, polyoxyethylene alkyl sulfate Salts, anionic surfactants such as sulfosuccinate salts, cationic surfactants such as quaternary alkylammonium salts, amphoteric surfactants such as alkyl betaine, crystalline cellulose, cross-linked methylpolysiloxane, polyethylene powder, acrylic resin Powders that may be surface-treated such as organic powders such as powder, talc, mica, sericite, magnesium carbonate, calcium carbonate, titanium dioxide, iron oxide, navy blue, ultramarine, titanium mica, titanium sericite, silica, etc. Body, acrylic acid Alkyl acrylate copolymer and / or its salt, carboxyvinyl polymer and / or its salt, thickener such as xanthan gum and hydroxypropyl cellulose, retinol, retinoic acid, tocopherol, riboflavin, pyridoxine, ascorbic acid, ascorbic acid phosphate ester salt Active ingredients such as vitamins and glycyrrhizinates, glycyrrhetin, terpenes such as ursolic acid and oleanolic acid, estradiol, ethinyl estradiol, steroids such as estriol, phenoxyethanol, parabens, hibitene gluconate, benzalkonium chloride, etc. Preservatives, UV absorbers such as dimethylaminobenzoate, cinnamate and benzophenone are preferred. A preferred form is a form not containing an ionic surfactant such as an anionic surfactant, a cationic surfactant or an amphoteric surfactant. This is because the expression of a feeling of irritation at the time of use can be suppressed, and even if there is no such component, in the above-mentioned specific mixing ratio, a foam with strong stiffness is also formed by the pump former.
[0011]
(5) Cosmetic of the present invention The cosmetic of the present invention is characterized in that the cosmetic composition is filled in a pump former container. Here, the pump former container means a container that introduces air into the sub-chamber of the container by the pressure of the hand pump and mixes with the cosmetic composition here to generate foam. Such containers already exist on the market at general retail stores, and such commercially available products can be used. The cosmetic of the present invention thus obtained has foam strength generated by the foamer, which has strengths such as strength of the waist, low primary irritation, and strength of oily component dispersing power. It can be applied to shaving cosmetics, foam-like hair restoration, foam-like hair styling, and the like. Particularly preferred is foam cleansing, which utilizes the fact that the surface strength is significantly reduced by foam formation.
[0012]
【Example】
Hereinafter, the present invention will be described in more detail with reference to Examples, but it goes without saying that the present invention is not limited to such Examples.
[0013]
<Example 1>
According to the following formulation, a foam-forming composition 1 of the present invention was prepared. That is, the formulation components were heated and stirred at 80 ° C., solubilized, and then stirred and cooled to obtain a foam-forming composition 1 of the present invention.
1,3-butanediol 3 parts by weight POE (7) coconut oil fatty acid glyceryl 2 parts by weight POE (20) glyceryl isostearate 2 parts by weight dodecaglycerin monolaurate 2 parts by weight Squalane 0.1 part by weight Phenoxyethanol 0.5 part by weight 93.4 parts by weight of water
<Example 2>
The foam-forming composition 1 of Example 1 was filled in a pump former container to prepare the cosmetic 1 of the present invention. At the same time, Comparative Example 1 in which all nonionic surfactants of the foam-forming composition 1 were replaced with sodium lauryl sulfate, and Comparative Example 2 in which lauryl imidazolinium betaine was replaced. Furthermore, a combination (standard example) of a conventional double face cleansing agent and an aqueous face wash was also prepared. For these, the cleansing effect was examined using a lip color. A test of applying 0.2 g of a lip color having the following formulation to a 2 cm × 4 cm area provided on the inner side of the upper arm and washing it off with 0.1 g of a cleaning agent was also performed. After washing, the color difference between the lip color application site and the surrounding site was measured using a color difference meter manufactured by Minolta Co., Ltd. The results are also shown in Table 1. In addition, the foam-forming composition 1 in the table is used without filling in the former and in a liquid state. Table 1 also shows the results of a human patch test of these compositions using 20 panelists as a positive rate. This shows that the foam-forming composition of the present invention has low primary irritation and high safety.
[0015]
(Lip color for evaluation)
Microcrystalline wax 10 parts by weight Polyethylene 5 parts by weight Crosslinked methylpolysiloxane 5 parts by weight Solid paraffin 5 parts by weight Mokuro 5 parts by weight carnauba wax 5 parts by weight Castor oil 20 parts by weight hydrogenated coconut oil 10 parts by weight squalane 15 parts by weight pigment 20 parts by weight
(Standard cleansing fee)
30 parts by weight squalane 30 parts by weight cetyl isooctanoate 30 parts by weight microcrystalline wax 2 parts by weight stearic acid 1 part by weight stearyl alcohol 2 parts by weight POE (45) stearic acid ester 2 parts by weight sorbitan sesquistearate 3 parts by weight 10% aqueous caustic potassium solution 0. 2 parts by weight 1,3-butanediol 5 parts by weight Water 24.8 parts by weight
(Standard water-based face wash)
Stearic acid 15 parts by weight Myristic acid 12 parts by weight Lauric acid 5 parts by weight Cetyl alcohol 0.3 parts by weight Behenyl alcohol 0.2 parts by weight Soy lecithin 0.1 parts by weight Jojoba alcohol 0.1 parts by weight Water 38 parts by weight Potassium hydroxide 7 Parts by weight glycerin 12 parts by weight diglycerin 5 parts by weight sodium carboxymethylcellulose 0.3 part by weight sorbitol 10 parts by weight
[Table 1]
<Examples 3 to 5>
The composition of the foam-forming composition 1 and the cosmetic of the present invention were similarly prepared by changing the composition of the nonionic surfactant in the foam-forming composition 1, and the cleansing effect of Example 2 was evaluated. Table 2 shows the results. From this, it is understood that a form in which two kinds of polyoxyethylene fatty acid glyceryl and polyglycerin fatty acid ester are used in combination is particularly preferable.
1,3-butanediol 3 parts by weight Nonionic surfactant described in Table 2 6 parts by weight Squalane 0.1 part by weight Phenoxyethanol 0.5 part by weight Water 93.4 parts by weight
[Table 2]
<Example 6>
The foam-forming composition and the cosmetic of the present invention were similarly prepared by changing the type of the polyglycerin fatty acid ester among the nonionic surfactants of the foam-forming composition 1, and the cleansing effect of Example 2 was evaluated. Was. Table 3 shows the results. This shows that any polyglycerol fatty acid ester can be used, but lauric acid ester is preferable.
1,3-butanediol 3 parts by weight POE (7) coconut oil fatty acid glyceryl 2 parts by weight POE (20) glyceryl isostearate 2 parts by weight Nonionic surfactant described in Table 3 2 parts by weight Squalane 0.1 part by weight 0.5 parts by weight of phenoxyethanol 93.4 parts by weight of water
[Table 3]
【The invention's effect】
According to the present invention, it is possible to provide a composition that uses only a nonionic surfactant as a surfactant and forms a foam suitable for a foam-like cleansing agent.
Claims (7)
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010222323A (en) * | 2009-03-25 | 2010-10-07 | Kumano Yushi Kk | Makeup remover cosmetic composition |
| JP2014101333A (en) * | 2012-11-22 | 2014-06-05 | Kao Corp | Skin cosmetic |
| JP2014125436A (en) * | 2012-12-25 | 2014-07-07 | Kracie Home Products Ltd | Foamy skin lotion |
| WO2017217337A1 (en) * | 2016-06-16 | 2017-12-21 | 株式会社ポーラファルマ | Foam, screen foamer composition, and evaluation method for same |
| WO2022260024A1 (en) * | 2021-06-08 | 2022-12-15 | 花王株式会社 | Aqueous cleanser composition |
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| JPH08165234A (en) * | 1994-12-10 | 1996-06-25 | Kao Corp | Skin washing article |
| JP2001181609A (en) * | 1999-12-27 | 2001-07-03 | Daizo:Kk | Aerosol composition |
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| JPH08165234A (en) * | 1994-12-10 | 1996-06-25 | Kao Corp | Skin washing article |
| JP2001181609A (en) * | 1999-12-27 | 2001-07-03 | Daizo:Kk | Aerosol composition |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010222323A (en) * | 2009-03-25 | 2010-10-07 | Kumano Yushi Kk | Makeup remover cosmetic composition |
| JP2014101333A (en) * | 2012-11-22 | 2014-06-05 | Kao Corp | Skin cosmetic |
| JP2014125436A (en) * | 2012-12-25 | 2014-07-07 | Kracie Home Products Ltd | Foamy skin lotion |
| CN109310633A (en) * | 2016-06-16 | 2019-02-05 | 宝丽制药股份有限公司 | Foam, the composition and its evaluation method for sieving infusion |
| JP2017226653A (en) * | 2016-06-16 | 2017-12-28 | 株式会社ポーラファルマ | Composition for screen foamer |
| JP2017226654A (en) * | 2016-06-16 | 2017-12-28 | 株式会社ポーラファルマ | Foam, composition for screen foamer, and evaluation method of the same |
| WO2017217337A1 (en) * | 2016-06-16 | 2017-12-21 | 株式会社ポーラファルマ | Foam, screen foamer composition, and evaluation method for same |
| KR20190020324A (en) | 2016-06-16 | 2019-02-28 | 가부시키가이샤 폴라 파마 | Foam, composition for screen former, and evaluation method thereof |
| US11090234B2 (en) | 2016-06-16 | 2021-08-17 | Pola Pharma Inc. | Foam, screen foamer composition, and evaluation method for same |
| CN109310633B (en) * | 2016-06-16 | 2021-10-22 | 宝丽制药股份有限公司 | Composition for foam and foam screening agent and evaluation method thereof |
| JP7073050B2 (en) | 2016-06-16 | 2022-05-23 | サンファーマ株式会社 | Composition for screen former |
| AU2017285599B2 (en) * | 2016-06-16 | 2023-03-23 | Pola Pharma Inc. | Foam, screen foamer composition, and evaluation method for same |
| WO2022260024A1 (en) * | 2021-06-08 | 2022-12-15 | 花王株式会社 | Aqueous cleanser composition |
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