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JP2004255176A - Surface material for absorptive article and absorptive article using the same - Google Patents

Surface material for absorptive article and absorptive article using the same Download PDF

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JP2004255176A
JP2004255176A JP2004026359A JP2004026359A JP2004255176A JP 2004255176 A JP2004255176 A JP 2004255176A JP 2004026359 A JP2004026359 A JP 2004026359A JP 2004026359 A JP2004026359 A JP 2004026359A JP 2004255176 A JP2004255176 A JP 2004255176A
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surface material
nonwoven fabric
absorbent article
absorbent
sample
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Satoshi Hiraga
平賀  敏
Yoshiaki Kodama
美明 兒玉
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Asahi Kasei Corp
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Asahi Kasei Fibers Corp
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  • Orthopedics, Nursing, And Contraception (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a surface material for absorptive articles and an absorptive article, in which a form retaining property at the time of wetting is good, a touch to the skin is good, a humor absorbing nature is good, a sticking feeling after absorbing humors is little, and a stuffy feeling is little. <P>SOLUTION: In this surface material for the absorptive articles comprising cellulose filament nonwoven fabrics, and 70% or more of fiber composing at least the surface of the nonwoven fabric has a single fineness of 0.1-0.55 dtex. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

本発明は、パンティライナー、失禁パッド、生理用ナプキン、産褥パッド(お産用ナプキン)、使い捨ておむつ等の吸収性物品用表面材及び吸収性物品に関する。更に詳しくは、湿潤時の形態保持性が良好で、肌触りが良好で、体液吸収性が良好で、体液吸収後の貼り付き感が少なく、蒸れ感の少ない吸収性物品用表面材及び吸収性物品に関する。   The present invention relates to a surface material for absorbent articles such as a panty liner, an incontinence pad, a sanitary napkin, a puerperal pad (a napkin for childbirth), and a disposable diaper, and an absorbent article. More specifically, the surface material for absorbent articles and the absorbent article have good shape retention when wet, good touch, good body fluid absorption, little stickiness after body fluid absorption, and little stuffiness. About.

吸収性物品用表面材としては、例えば合成繊維不織布に透水剤を処理したものや、開孔フィルムに透水剤を処理したものがある。これらの表面材は、主に体液をより早く通過させて表面材の下にある吸収材へ吸収させることを目的としている。しかしながら合成繊維不織布や開孔フィルムは吸湿性に乏しく、梅雨時期や夏季等の高温高湿条件下での着用においては蒸れやすく、着用において不快感を生じるという問題があった。
このような問題を解決するために特許文献1に表面材に主としてセルロース繊維を使用することが開示されている。しかしながらセルロース繊維は、水分との親和性が高く繊維に水分を取り込むため、べたつき感が生じる等の問題があった。また、柔軟性も増すが継続着用していると形態保持性が悪くなりヨレ等の問題があった。
また、特許文献2には表面材にセルロース系長繊維不織布を用いることが開示されている。この方法によれば低目付でも乾湿強度と体液拡散性に優れる表面材が得られるものの、湿潤時の強度と、体液吸収後の形態保持性に問題があった。
Examples of the surface material for absorbent articles include those obtained by treating a synthetic fiber nonwoven fabric with a water-permeable agent and those obtained by treating a perforated film with a water-permeable agent. These facings are primarily intended to allow body fluids to pass faster and be absorbed by the absorbent under the facing. However, synthetic fiber nonwoven fabrics and apertured films have poor hygroscopicity, and tend to be stuffy when worn under high-temperature and high-humidity conditions, such as during the rainy season or summer, and have a problem of causing discomfort when worn.
In order to solve such a problem, Patent Document 1 discloses that cellulose fibers are mainly used as a surface material. However, cellulose fibers have a high affinity for water and take in water into the fibers, and thus have a problem that a sticky feeling is caused. Further, the flexibility is increased, but if the wear is continued, the shape retention is deteriorated, and there is a problem such as twisting.
Patent Document 2 discloses that a cellulosic long-fiber nonwoven fabric is used as a surface material. According to this method, although a surface material excellent in dry and wet strength and body fluid diffusibility can be obtained even with a low basis weight, there are problems in the strength when wet and the shape retention after absorbing body fluid.

特許第3200673号公報Japanese Patent No. 3200673 特開平9−154870号公報JP-A-9-154870

本発明は、湿潤時の形態保持性が良好で、肌触りが良好で、体液吸収性が良好で、体液吸収後の貼り付き感が少なく、蒸れ感の少ない吸収性物品用表面材及び吸収性物品を提供することを目的とする。   The surface material and absorbent article for an absorbent article according to the present invention have a good form retention property when wet, a good feel, a good body fluid absorption property, a small sticking feeling after absorbing the body fluid, and a little stuffy feeling. The purpose is to provide.

本発明者等は上記問題に鑑み、セルロース長繊維不織布の特徴を活かしながら湿潤時の形態安定性を向上させる方法を検討し、単繊度を低下させて湿潤時でも形態安定性が向上すること、また、単繊度を低下させることにより滑らかな触感が得られることを見出し、本発明を成すに至った。
すなわち、本発明は以下のとおりである。
(1)セルロース長繊維不織布からなる吸収性物品用表面材であって、該不織布の少なくとも表面を構成する繊維の70%以上が単繊度0.1〜0.55dtexであることを特徴とする吸収性物品用表面材。
(2)該不織布の湿潤形態保持率が80%以上であることを特徴とする(1)に記載の吸収性物品用表面材。
(3)該不織布が再生セルロース連続長繊維不織布であることを特徴とする(1)または(2)に記載の吸収性物品用表面材。
(4)少なくとも表面材と吸収材を具備する吸収性物品であって、該表面材が(1)〜(3)のいずれかに記載の吸収性物品用表面材であることを特徴とする吸収性物品。
(5)少なくとも吸収材を兼ねる表面材を具備する吸収性物品であって、該表面材が(1)〜(3)のいずれかに記載の吸収性物品用表面材であることを特徴とする吸収性物品。
In view of the above problems, the present inventors have studied a method for improving the morphological stability when wet while taking advantage of the characteristics of the cellulose long-fiber nonwoven fabric, and improving the morphological stability even when wet by reducing the single fineness, Further, they have found that a smooth tactile sensation can be obtained by reducing the single fineness, and have accomplished the present invention.
That is, the present invention is as follows.
(1) An absorbent article surface material comprising a cellulose long-fiber nonwoven fabric, wherein at least 70% of fibers constituting the surface of the nonwoven fabric have a single fineness of 0.1 to 0.55 dtex. Surface material for decorative articles.
(2) The surface material for an absorbent article according to (1), wherein the nonwoven fabric has a wet form retention of 80% or more.
(3) The surface material for an absorbent article according to (1) or (2), wherein the nonwoven fabric is a regenerated cellulose continuous filament nonwoven fabric.
(4) An absorbent article comprising at least a surface material and an absorbent, wherein the surface material is the surface material for an absorbent article according to any one of (1) to (3). Products.
(5) An absorbent article provided with a surface material also serving at least as an absorbent, wherein the surface material is the surface material for an absorbent article according to any one of (1) to (3). Absorbent articles.

本発明の吸収性物品用表面材は湿潤時の形態保持性が極めて良好で、これを用いた吸収性物品は、肌触りが良好で、体液吸収性が良好で、体液吸収後の貼り付き感が少なく、湿潤時の形態保持性が良好で、蒸れ感の少なく、従って皮膚刺激性の低い極めて理想的な吸収性物品を提供することができる。   The surface material for absorbent articles of the present invention has extremely good shape retention when wet, and an absorbent article using the same has a good touch, good body fluid absorption, and a feeling of sticking after body fluid absorption. It is possible to provide an extremely ideal absorbent article having a small amount, a good shape retention property when wet, a small stuffiness, and a low skin irritation.

本発明について以下具体的に説明する。
本発明でいうセルロース長繊維不織布とは、例えば銅アンモニア法レーヨン原液を流下緊張紡糸法によりネット上に連続で紡糸し、繊維自体の自己接着と水流交絡にて接着、交絡させた再生セルロース連続長繊維不織布や、特表2002−521585号公報に開示される方法等で製造されたリヨセル等の精製セルロース長繊維不織布のことをいう。
本発明の吸収性物品用表面材は、セルロース長繊維不職布からなることを特徴とする。セルロース長繊維不織布は、構成する繊維が長繊維であるため繊維の脱落が少なく表面材として使用した場合、綿等の短繊維不織布に比べて人体への繊維付着による汚染が少ない。
また、再生セルロース連続長繊維不織布であれば、前述したとおり自己接着と水流交絡により不織布が形成されるため、不織布形成時に接着用の樹脂等のバインダーを使用しないため、これが人体接触面にほとんどないため安全性に優れたものであるので好ましい。また、自己接着により形態安定性が高いので好ましい。
The present invention will be specifically described below.
The cellulose long-fiber nonwoven fabric referred to in the present invention is, for example, a continuous length of regenerated cellulose obtained by continuously spinning a stock solution of a copper-ammonium rayon onto a net by a down-straining spinning method, and bonding and entangled by self-adhesion of the fiber itself and hydroentanglement. The term refers to a fibrous nonwoven fabric or a purified cellulose long-fiber nonwoven fabric such as lyocell manufactured by the method disclosed in JP-T-2002-521585.
The surface material for absorbent articles of the present invention is characterized by being made of nonwoven fabric of cellulose long fiber. Cellulose long-fiber nonwoven fabrics are long fibers, so that they are less likely to fall off when used as a surface material, and are less contaminated by fiber adhesion to the human body than short-fiber nonwoven fabrics such as cotton.
In addition, in the case of a regenerated cellulose continuous filament nonwoven fabric, since a nonwoven fabric is formed by self-adhesion and hydroentanglement as described above, a binder such as an adhesive resin is not used at the time of forming the nonwoven fabric. Therefore, it is preferable because it is excellent in safety. Further, self-adhesion is preferable because of high form stability.

本発明の吸収性物品用表面材に用いられるセルロース長繊維不織布は、不織布の少なくとも表面を構成する繊維の70%以上、好ましくは80%以上、最も好ましくは100%が単繊度0.1〜0.55dtex、好ましくは0.1〜0.4dtex、更に好ましくは0.1〜0.3dtexである。不織布の少なくとも表面を形成する繊維の70%以上が単繊度0.1〜0.55dtexであることにより、同一目付で単繊度がこの範囲を超えるものと比べて、不織布を構成する繊維の交絡点や自己接着点の数が増加するので湿潤時の形態安定性が飛躍的に向上する。また、再生セルロース連続長繊維不織布の場合、単繊度が小さくなることにより単糸の精練性が向上するため白色度が増加し、衛生材料としての清潔感が向上する。更に乱反射により白色度が増加し、衛生材料としての清潔感が向上する。
不織布の少なくとも表面を構成する単繊度0.1〜0.55dtexの繊維が70%未満であると湿潤時の形態安定性と白色度が減少する。また、単繊度がこの範囲にあることにより毛細管現象で輸水性能も向上する。
The cellulose long-fiber nonwoven fabric used for the surface material for absorbent articles of the present invention is such that at least 70%, preferably 80%, and most preferably 100% of the fibers constituting at least the surface of the nonwoven fabric have a single fineness of 0.1 to 0. 0.555 dtex, preferably 0.1 to 0.4 dtex, more preferably 0.1 to 0.3 dtex. Since at least 70% of the fibers forming the surface of the nonwoven fabric have a single fineness of 0.1 to 0.55 dtex, the entanglement points of the fibers constituting the nonwoven fabric are lower than those having a single fineness exceeding this range with the same basis weight. And the number of self-adhesive points are increased, so that the morphological stability when wet is greatly improved. Further, in the case of the regenerated cellulose continuous long-fiber nonwoven fabric, the fineness of the single yarn is improved by reducing the single fineness, so that the whiteness is increased and the cleanliness as a sanitary material is improved. Furthermore, whiteness increases due to irregular reflection, and cleanliness as a sanitary material is improved.
If at least 70% of the fibers having a single fineness of 0.1 to 0.55 dtex constituting at least the surface of the nonwoven fabric are less than 70%, the form stability at the time of wetting and the whiteness are reduced. In addition, when the single fineness is in this range, the water transport performance is also improved by the capillary phenomenon.

本発明の吸収性物品に用いるセルロース繊維不織布は、湿潤形態保持率が80%以上であることが好ましく、更に好ましくは90%以上であり、最も好ましくは100%である。ここでいう湿潤形態保持率とは以下の方法で測定される。測定装置の模式図を図1に示す。不織布の機械軸方向に縦長となるように5cm×12cmにサンプルを準備し、上下1cmの部分の中央部に印をつけて測定部を作成する。サンプル重量W1 の10倍量の純水をサンプルに均一に付与する。サンプルの上下1cmをサンプル保持板に挟み固定する。1m2 あたりのサンプル重量W1 の30重量%の荷重(サンプル保持板はW1 の10重量%とし、荷重はこれを加えたもとする)をかけて30秒間吊り下げた後除重し(下部のサンプル保持板も外す)、30秒後に測定部の長さLを測定する。初期サンプル長は10cm(サンプル保持板間の長さ)として湿潤形態保持率を次式で計算する。
湿潤形態保持率(%)=(10−(L−10))/10×100
湿潤形態保持率は体液等を吸収した後のヨレ性と大きく相関する。湿潤形態保持率が80%未満では体液吸収後に表面材がヨレて着用感が低下したり、表面材が破れて吸収体が体表面に接触したりすることがある。
湿潤形態保持率は、前述した不織布を形成する繊維の配列方向、繊維の交絡状態によってコントロールすることができる。湿潤形態保持率を向上させるには、機械軸と垂直方向への繊維配列数を増加させること、不織布を構成する繊維の単繊度を低下させて繊維存在本数を増加させることにより繊維の交絡点数を増加させることにより、湿潤形態保持率を好適にすることができる。
The cellulose fiber nonwoven fabric used in the absorbent article of the present invention preferably has a wet form retention of 80% or more, more preferably 90% or more, and most preferably 100%. Here, the wet form retention is measured by the following method. FIG. 1 shows a schematic diagram of the measuring device. A sample is prepared in a size of 5 cm × 12 cm so as to be vertically elongated in the machine axis direction of the nonwoven fabric, and a measuring part is created by marking the center of the upper and lower 1 cm portions. Uniformly imparting 10 volumes of pure water sample weight W 1 to the sample. The upper and lower 1 cm of the sample is sandwiched between sample holding plates and fixed. The sample was suspended for 30 seconds by applying a load of 30% by weight of the sample weight W 1 per 1 m 2 (the sample holding plate was 10% by weight of W 1 , and the load was applied thereto), and then de-weighted (the lower part). The sample holding plate is also removed), and after 30 seconds, the length L of the measuring section is measured. The initial sample length is 10 cm (the length between the sample holding plates), and the wet form retention is calculated by the following equation.
Wet form retention (%) = (10− (L−10)) / 10 × 100
The wet form retention greatly correlates with the repellency after absorbing body fluids and the like. If the wet form retention is less than 80%, the surface material may be distorted after absorbing the body fluid and the wearing feeling may be reduced, or the surface material may be broken and the absorbent may come into contact with the body surface.
The wet form retention rate can be controlled by the arrangement direction of the fibers forming the nonwoven fabric and the entangled state of the fibers. In order to improve the wet form retention, the number of fibers arranged in the direction perpendicular to the machine axis is increased, and the number of entangled points of the fibers is increased by decreasing the single fineness of the fibers constituting the nonwoven fabric and increasing the number of fibers present. By increasing it, the wet form retention can be made favorable.

本発明の吸収性物品用表面材に用いられるセルロース長繊維不織布は、水平輸水速度が好ましくは30mm/分以上150mm/分以下、更に好ましくは40mm/分以上120mm/分以下である。ここでいう水平輸水速度とは、以下の方法で測定されたものをいう。測定装置の模式図を図2に示す。幅50mm、長さ33cmのサンプルを準備する。サンプルは垂直立ち上がり部分が30mmで、直径1.5mmのガラス棒で直角に偏向され、水平に配置される(以下、この直角偏向部を水平偏向部という。)。サンプルの支持のために同一直径のガラス棒を10mm置きに設置する。サンプル垂直立ち上がり部の下方12mmのところまでバット等に入れた水を浸す。水平偏向部に水が到達した時点から1分後の水平偏向部からの水到達長さを測定する。
測定を10回実施し、その平均値を水平輸水速度とする。水平輸水速度が30mm未満の場合、体液が拡散しにくく、液透過性が悪いと表面近くに体液が残留するためべたつき感が生じる。水平輸水速度が150mm/分を超えると、吸収性物品の大きさ(サイズ、長さ)にもよるが、吸収性物品の端近くまで体液が急速に移行するため漏れ戻りにより広範囲を汚染したり、端部より体液が下着に付着しやすくなるため好ましくない。
The cellulose long-fiber nonwoven fabric used for the surface material for absorbent articles of the present invention has a horizontal water infusion rate of preferably 30 mm / min or more and 150 mm / min or less, more preferably 40 mm / min or more and 120 mm / min or less. Here, the horizontal water infusion rate refers to a rate measured by the following method. FIG. 2 shows a schematic diagram of the measuring device. A sample having a width of 50 mm and a length of 33 cm is prepared. The sample has a vertical rising portion of 30 mm, is deflected at right angles by a glass rod having a diameter of 1.5 mm, and is arranged horizontally (hereinafter, this right angle deflecting section is referred to as a horizontal deflecting section). A glass rod of the same diameter is set every 10 mm for supporting the sample. Immerse water in a bat or the like up to 12 mm below the vertical rise part of the sample. One minute after the water reaches the horizontal deflecting unit, the length of water reaching from the horizontal deflecting unit is measured.
The measurement is performed 10 times, and the average value is taken as the horizontal water inflow rate. When the horizontal water infusion rate is less than 30 mm, the bodily fluid is hardly diffused, and when the liquid permeability is poor, the bodily fluid remains near the surface, causing a sticky feeling. If the horizontal water infusion rate exceeds 150 mm / min, depending on the size (size, length) of the absorbent article, the body fluid rapidly moves to near the end of the absorbent article, and contaminates a wide area by leaking back. And the body fluid is more likely to adhere to the underwear than at the end, which is not preferable.

本発明の吸収性物品用表面材に用いられるセルロース長繊維不織布は、好ましくは目付が7〜30g/m2 、更に好ましくは10〜25g/m2 である。目付が7g/m2 未満では湿潤時の強度が低下し着用に耐えないものとなる。目付が30g/m2 を超えると柔軟性が低下し、着用時に違和感を生じることがある。 本発明の吸収性物品用表面材に用いられるセルロース長繊維不織布は、厚みは体液を吸収材へ速やかに移行させる観点から好ましくは0.1〜0.4mm、更に好ましくは0.11〜0.3mmである。0.1mm未満であると湿潤時の強度に問題を生じることがある。0.4mmを超えると液体の吸収速度が遅くなることがありべたつき感に悪影響を及ぼすことがある。
本発明の吸収性物品用表面材に用いられるセルロース長繊維不織布は、体液を吸収材へ速やかに移行させる観点や意匠の観点から開孔部のあるメッシュ調や開孔部による模様や凹凸による模様が形成されていてもよい。体液を吸収材へ速やかに移行させるための開孔部がある場合は、開孔部の形状は特に限定されないが、強度や柔軟性の観点から開孔部の平均面積は0.1〜2mm2 が好ましく、更に好ましくは0.2〜1mm2 である。開孔部の平均面積が0.1mm2 未満では通液速度が低下することがある。開孔部の平均面積が2mm2 を超えると吸収材からの濡れ戻りにより不快感が増加することがある。また、表面材全体に占める開孔部の面積率は3〜25%が好ましく、更に好ましくは10〜20%である。表面材全体に占める開孔部の面積率が3%未満の場合は通液効果が減少することがある。表面材全体に占める開孔部の面積率が25%を超えると湿潤時の強度が低下し、ヨレ等の形態保持性に問題が生じることがある。開孔部がある場合には吸収材中の粒状の高分子吸収体が表面に洩れないように、また、吸収材への体液吸収の効率を向上させるために拡散シートが表面材と吸収材の間に入っていてもよい。
The cellulose long-fiber nonwoven fabric used for the surface material for absorbent articles of the present invention preferably has a basis weight of 7 to 30 g / m 2 , more preferably 10 to 25 g / m 2 . If the basis weight is less than 7 g / m 2 , the strength at the time of moistening is reduced, and it becomes impossible to wear. If the basis weight is more than 30 g / m 2 , the flexibility may be reduced and a feeling of strangeness may be caused when worn. The thickness of the cellulose long-fiber nonwoven fabric used for the surface material for absorbent articles of the present invention is preferably 0.1 to 0.4 mm, more preferably 0.11 to 0.4 mm, from the viewpoint of promptly transferring body fluid to the absorbent. 3 mm. If the thickness is less than 0.1 mm, a problem may occur in the wet strength. If it exceeds 0.4 mm, the absorption speed of the liquid may be reduced, which may adversely affect the stickiness.
Cellulose long-fiber nonwoven fabric used for the surface material for absorbent articles of the present invention has a mesh pattern with openings or a pattern due to openings or a pattern due to irregularities from the viewpoint of promptly transferring body fluid to the absorbent or the design. May be formed. When there is an opening for promptly transferring body fluid to the absorbent, the shape of the opening is not particularly limited, but the average area of the opening is 0.1 to 2 mm 2 from the viewpoint of strength and flexibility. And more preferably 0.2 to 1 mm 2 . If the average area of the openings is less than 0.1 mm 2 , the liquid passing speed may decrease. If the average area of the opening exceeds 2 mm 2 , discomfort may increase due to re-wetting from the absorbent. Further, the area ratio of the opening portion to the entire surface material is preferably 3 to 25%, and more preferably 10 to 20%. When the area ratio of the opening portion to the entire surface material is less than 3%, the liquid passing effect may be reduced. If the area ratio of the apertures to the entire surface material exceeds 25%, the strength at the time of wetting decreases, and a problem may occur in shape retention such as twisting. If there are openings, the diffusion sheet is made of a surface material and an absorbent material to prevent the granular polymer absorbent in the absorbent material from leaking to the surface and to improve the efficiency of bodily fluid absorption by the absorbent material. It may be in between.

本発明のセルロース長繊維不織布は、前記条件を満足していれば複合されていてもよい。例えば、吸湿性と表面材自体での体液吸収性を向上させるため、単繊度の異なるセルロース長繊維不織布を水流交絡等で複合してもよい。この場合、単繊度の異なる繊維が表面に出ることがあるが、前記条件の範囲内であれば効果に影響はない。
本発明のセルロース長繊維不織布は吸収性物品の表面材として使用される。吸収性物品は、最低限表面材と吸収材を具備していればよい。もちろん、この構造以外に防漏層としていわゆるバックシートが具備されていてもよい。通常の吸収性物品の構造は、表面材−拡散層−吸収材(大容量)−防漏層を備えた多量の体液や尿等を吸収できる構造(おむつ構造)のものと、表面材−吸収材(小容量)−防漏層の簡易構造でおりもの等少量の体液等を吸収するものとに大別できる。吸収性物品のどちらの構造でも本発明のセルロース長繊維不織布を表面材に用いると、極めて良好な効果を得ることができる。
The cellulose long-fiber nonwoven fabric of the present invention may be composited as long as the above conditions are satisfied. For example, in order to improve the hygroscopicity and the bodily fluid absorptivity of the surface material itself, nonwoven cellulose long-fiber nonwoven fabrics having different single fineness may be combined by hydroentanglement or the like. In this case, fibers having different single fineness may come out on the surface, but the effect is not affected as long as the conditions are within the above range.
The cellulose long-fiber nonwoven fabric of the present invention is used as a surface material of an absorbent article. The absorbent article may include at least the surface material and the absorbent. Of course, in addition to this structure, a so-called back sheet may be provided as a leak-proof layer. The structure of a normal absorbent article includes a surface material—a diffusion layer—an absorbent material (large capacity) —a structure provided with a leak-proof layer and capable of absorbing a large amount of body fluid, urine, and the like (diaper structure), and a surface material—absorption. Material (small capacity)-simple structure of leak-proof layer, which can be broadly divided into those absorbing small amounts of body fluids and the like. In both structures of the absorbent article, when the cellulose long fiber nonwoven fabric of the present invention is used for a surface material, an extremely good effect can be obtained.

おむつ構造においては、輸水性能が良好なので尿や体液等を非常に早く拡散しながら吸収材へ移送することができ、べたつき感が少ない。また、形態保持性に優れ、かつ、セルロース繊維の吸湿性により着用時の蒸れ感も極めて少なく快適な吸収性物品となる。更にセルロース繊維であるため皮膚刺激が少なく安全性が高いものである。おむつ構造の吸収性物品の場合、べたつき感の主原因である濡れ戻り性及び表面液保持性を減少させる観点から低目付で通液性が良好なものが好ましい。このため、目付は好ましくは7〜25g/m2 、より好ましくは10〜20g/m2 である。7g/m2 未満では、着用時の強度に問題があり、25g/m2 を超えると吸収性物品の厚みとも相まって着用時に違和感を生じることがある。更に、拡散層があり、吸収材が大容量であるので拡散層への液移行を考慮し、開孔部があることが好ましい。 In the diaper structure, since the water transport performance is good, urine, body fluid, etc. can be transferred to the absorbent while diffusing very quickly, and the feeling of stickiness is small. In addition, a comfortable absorbent article having excellent form retention and extremely little stuffiness when worn due to the hygroscopicity of the cellulose fibers. Furthermore, since it is a cellulose fiber, skin irritation is low and safety is high. In the case of an absorbent article having a diaper structure, those having a low basis weight and good liquid permeability are preferable from the viewpoint of reducing the wet-back property and the surface liquid holding property, which are the main causes of the sticky feeling. For this reason, the basis weight is preferably 7 to 25 g / m 2 , and more preferably 10 to 20 g / m 2 . If it is less than 7 g / m 2, there is a problem in the strength at the time of wearing, and if it exceeds 25 g / m 2 , an uncomfortable feeling may be caused at the time of wearing in combination with the thickness of the absorbent article. Further, since there is a diffusion layer and the absorption material has a large capacity, it is preferable to have an opening in consideration of liquid transfer to the diffusion layer.

簡易構造の吸収性物品においては、セルロース繊維の保液力により保液が可能であり、かつ、輸水性能が良好で拡散するのでべたつき感が減少する。また、形態保持性、蒸れ感、皮膚刺激等の安全性もおむつ構造と同様に良好である。表面材においても保液するため、目付は好ましくは10〜30g/m2 、より好ましくは15〜30g/m2 である。10g/m2 未満では保液力が足りずべたつき感を生じることがある。30g/m2 を超えると着用時に違和感を生じることがある。尚、簡易構造の吸収性物品には、表面材が吸収材を兼ねている場合もあり、本発明の吸収性物品はこれも含むものである。
本発明の吸収性物品は、本発明の吸収性物品用表面材を使用していれば、拡散層、吸収材、防漏層は適宜選択すればよい。拡散層(セカンドシート)は、合成繊維、例えばポリプロピレンのエアスルー不織布等が用いられてもよい。吸収材は、高分子吸収体を付与したパルプをティッシュで包んだものや、ティッシュに高分子吸収体を付着させたもの等が用いられていてもよい。防漏層(バックシート)は、吸収した体液や尿を下着等へ洩らさず、かつ、蒸れを防止する観点から透湿防水性能を有する、例えばポリオレフィンやポリエステルの微多孔シート等を用いることができる。
In an absorbent article having a simple structure, the liquid can be retained by the liquid retaining power of the cellulose fiber, and the water-transporting performance is good and the adhesive is diffused, so that the sticky feeling is reduced. In addition, safety such as shape retention, stuffiness, skin irritation and the like is also good as in the diaper structure. Since also liquid retaining the surface material, the basis weight is preferably 10 to 30 g / m 2, more preferably a 15 to 30 g / m 2. If it is less than 10 g / m 2 , the liquid-retaining ability is insufficient and a sticky feeling may be generated. If it exceeds 30 g / m 2 , an uncomfortable feeling may be caused when worn. In some cases, the surface material also functions as an absorbent in the absorbent article having a simple structure, and the absorbent article of the present invention includes this.
In the absorbent article of the present invention, as long as the surface material for an absorbent article of the present invention is used, a diffusion layer, an absorbent, and a leakproof layer may be appropriately selected. As the diffusion layer (second sheet), synthetic fibers, for example, an air-through nonwoven fabric of polypropylene or the like may be used. As the absorbent, a material obtained by wrapping a pulp provided with a polymer absorber with a tissue, a material obtained by attaching a polymer absorber to a tissue, or the like may be used. The leakproof layer (backsheet) should be made of, for example, a microporous sheet of polyolefin or polyester, which does not leak absorbed body fluids or urine to underwear and has a moisture-permeable and waterproof property from the viewpoint of preventing stuffiness. Can be.

本発明を実施例に基づいて説明する。実施例中の評価は以下の方法を用いて実施した。
(1)表面を構成する繊維の単繊度及びその構成比率
表面を構成する繊維を丸断面として繊維径から単繊度を測定する。セルロース繊維の比重を1.50とする。単繊維の直径をd(m)とすると、単繊度t(dtex)とは以下の関係が成立する。
t=π(d/2)2 ×10000×1.50×106
ここでπは円周率である。0.1dtexではd=2.91×10-6(m)=2.91(μm)、0.55dtexではd=6.83×10-6(m)=6.83(μm)となる。
表面を電子顕微鏡で観察し、単繊維の直径を測定する。観察倍率は1μmの直径が5mm程度に見える倍率で実施する。焦点があった状態で200本の直径を測定する。直径が2.91〜6.83μmの範囲の繊維本数をaとし、次式により表面を構成する繊維の単繊度割合を求める。
表面を構成する繊維の単繊度割合(%)=(a/200)×100
(2)湿潤形態保持率(表1ではWet保形率と表記)
測定試料を20℃、65%RH条件下で24時間調湿した後測定する。測定は前記装置及び方法にて実施する。
The present invention will be described based on examples. The evaluation in the examples was performed using the following method.
(1) Single fineness of fibers constituting the surface and its composition ratio The single fineness is measured from the fiber diameter using the fibers constituting the surface as a circular cross section. The specific gravity of the cellulose fiber is set to 1.50. When the diameter of a single fiber is d (m), the following relationship is established with the single fineness t (dtex).
t = π (d / 2) 2 × 10000 × 1.50 × 10 6
Here, π is a circle ratio. At 0.1 dtex, d = 2.91 × 10 −6 (m) = 2.91 (μm), and at 0.55 dtex, d = 6.83 × 10 −6 (m) = 6.83 (μm).
The surface is observed with an electron microscope, and the diameter of the single fiber is measured. The observation magnification is a magnification at which a diameter of 1 μm looks like about 5 mm. Measure 200 diameters with focus. The number of fibers having a diameter in the range of 2.91 to 6.83 μm is defined as a, and the single fineness ratio of the fibers constituting the surface is determined by the following equation.
Single fineness ratio of fiber constituting surface (%) = (a / 200) × 100
(2) Wet form retention (in Table 1, expressed as Wet retention)
The measurement is performed after the measurement sample is conditioned for 24 hours at 20 ° C. and 65% RH. The measurement is performed by the above-described device and method.

(3)水平輸水速度
測定試料を20℃、65%RH条件下で24時間調湿した後測定する。測定は前記装置及び方法にて実施する。
(4)濡れ戻り性(体液吸収性)
市販のパンティライナーを用いて以下のように評価した。
(4−1)おむつ構造のパンティライナー 花王株式会社製ロリエさらさらコットンシートを用いて実験した。尚、実験は20℃、65%RH条件下で実施した。
ヘアドライヤーを用いて表面材に熱風を当ててホットメルト接着剤を溶かし、表面材のみを剥ぐ。試験する表面材を吸収体構造部より約1cm大きい面積で準備し、バックシート面へ巻き込みバックシート表面(下着に接触する面)にセロハンテープで固定し、濡れ戻り評価用サンプルを得た。
評価用サンプルより大きいサイズの濾紙の重量W1 を測定する。得られた評価用サンプルをガラス板上に置き、1mlの水を滴下した。1分後濾紙を載せ、更にガラス板を載せ、ガラス板を含めて荷重2.5kgをかけて1分間放置する。評価用サンプル上部のガラス板及び荷重を取り除き、水を吸収した濾紙の重量W2 を測定する。濡れ戻り率は次式で計算される。
濡れ戻り率(%)=(W2 −W1 )/1×100
(4−2)簡易構造のパンティライナー
小林製薬株式会社製サラサーティコットン100を用いて実験した。評価用サンプルに滴下する水の量を0.05mlにした以外は(4−1)に記載した方法と同様の方法で評価した。
(3) Horizontal water infusion rate The sample is conditioned at 20 ° C. and 65% RH for 24 hours and then measured. The measurement is performed by the above-described device and method.
(4) Rewetting (body fluid absorption)
The evaluation was performed as follows using a commercially available panty liner.
(4-1) Diaper-structured panty liner An experiment was carried out using a laurier silky cotton sheet manufactured by Kao Corporation. The experiment was performed under the conditions of 20 ° C. and 65% RH.
Hot air is applied to the surface material using a hair dryer to dissolve the hot melt adhesive, and only the surface material is peeled off. A surface material to be tested was prepared in an area approximately 1 cm larger than the absorber structure, wound around the backsheet surface and fixed to the backsheet surface (the surface in contact with the undergarment) with cellophane tape to obtain a sample for evaluating wetting back.
The weight W 1 of the large size of the filter paper from the evaluation sample is measured. The obtained evaluation sample was placed on a glass plate, and 1 ml of water was dropped. One minute later, the filter paper is placed, and then a glass plate is placed on the plate, and a load of 2.5 kg including the glass plate is left for 1 minute while applying a load of 2.5 kg. The glass plate above the evaluation sample and the load were removed, and the weight W 2 of the filter paper that absorbed water was measured. The wetting return rate is calculated by the following equation.
Wetting return rate (%) = (W 2 −W 1 ) / 1 × 100
(4-2) Panty Liner with Simple Structure An experiment was conducted using Sarasatty Cotton 100 manufactured by Kobayashi Pharmaceutical Co., Ltd. Evaluation was performed in the same manner as in (4-1) except that the amount of water dropped on the evaluation sample was 0.05 ml.

(5)ヨレ性(湿潤時の形態保持性)
目付50g/m2 、9.8kPa荷重下での厚みが0.40mmのポリエステルニードルパンチ不織布(東洋紡績株式会社製、商品名ボランス品番4051N )を下層に、試験する表面材を上層にして端部を両面テープで接着した縦15cm、横5cmのサンプルを準備する。尚、不織布及び試験する表面材は機械軸方向(MD方向)を縦とする。このサンプルをガラス板上に両面テープを用いて試験する表面材を上にして固定する。(図3参照)
サンプル中央部に1mlの水を滴下し、1分間放置後、直径12mmのガラス棒に200gの荷重をかけて5cm/秒の速度でサンプル上を滑らせる。端まで来たらガラス棒を一旦上げ、元の位置に戻し、再度同様に滑らせる。この操作を20回繰り返した後、サンプルの状態を10名のモニターで観察し、等級をつけて平均値を求めた。(図4参照)
5級:全くヨレが見られない。
4級:若干たるみ、ヨレが見られる。
3級:たるみや1本のきついヨレが見られる。
2級:たるみや2本のきついヨレが見られる。
1級:たるみがひどく、3本以上のきついヨレが見られる。
(5) Wetability (retention of form when wet)
A polyester needle-punched nonwoven fabric (manufactured by Toyobo Co., Ltd., product name: Bolans part number: 4051N) having a basis weight of 50 g / m 2 and a thickness of 0.40 mm under a load of 9.8 kPa is a lower layer, and a surface material to be tested is an upper layer. A sample having a length of 15 cm and a width of 5 cm is prepared by adhering with a double-sided tape. The nonwoven fabric and the surface material to be tested have the machine axis direction (MD direction) as the vertical direction. The sample is fixed on a glass plate with the surface material to be tested facing up using a double-sided tape. (See Fig. 3)
1 ml of water is dropped at the center of the sample, left for 1 minute, and then a glass rod having a diameter of 12 mm is slid over the sample at a speed of 5 cm / sec while applying a load of 200 g. When it reaches the end, raise the glass rod once, return it to its original position, and slide it again. After this operation was repeated 20 times, the state of the sample was observed on 10 monitors, and the samples were graded and averaged. (See Fig. 4)
Grade 5: No twist is seen at all.
Grade 4: Slightly sagging and twisting.
Grade 3: Sagging or one sharp twist is seen.
Grade 2: Sagging and two severe twists are seen.
Grade 1: The slack is severe and three or more severe twists are seen.

(6)着用感
旭化成せんい株式会社製再生セルロース長繊維不織布(商品名ベンリーゼ品番PS140)に、三洋化成工業株式会社製高吸水樹脂(アクリル酸重合体、商品名サンフレッシュ品番ST−573)3部とポリエチレン系ホットメルト接着剤1部からなる混合粉体を20g/m2 散布し、加熱溶融して厚み0.20mmの吸液性シート(吸収材)を得た。株式会社トクヤマ製ポリエチレン系微多孔フィルム(商品名ポーラム品番PH50、厚み50μm、目付45g/m2 )を市販のパンティライナー形状に切出しバックシート(防漏層)を作成した。次に得られた吸液性シートをバックシートよりやや小さい大きさに切出し、高吸水性樹脂の付着していない面の四隅に接着剤を塗ってバックシートに貼り付けた。バックシートの端に接着剤を塗布し、更にその上に試験する表面材(トップシート)を機械軸方向(MD方向)が長さ方向になるように載せ、貼り付けた。バックシートの裏面に両面テープを用いて下着に接着固定できるようにした。
得られたパンティライナーを夏季に生理終了後3日目に1日着用し、官能評価を実施した。評価内容は肌触り、蒸れ感、柔軟性、毛羽立ち、貼り付き感、おりものがあった場合は吸収性、貼り付き感について等級をつけた。モニター数は10名で平均値により評価した。
5級:快適。または問題なし。
3級:若干気になる。または若干不快。
1級:非常に気になる。または非常に不快。
(6) Feeling of wear Three parts of a regenerated cellulose long-fiber nonwoven fabric (trade name: Bemliese part number PS140) manufactured by Asahi Kasei Fibers Co., Ltd., and a superabsorbent resin (acrylic acid polymer, trade name: Sunfresh part number ST-573) manufactured by Sanyo Chemical Industry Co., Ltd. 20 g / m 2 of a mixed powder consisting of the above and 1 part of a polyethylene hot melt adhesive was sprayed and melted by heating to obtain a 0.20 mm thick liquid absorbing sheet (absorbing material). A backsheet (leakage-proof layer) was prepared by cutting a polyethylene microporous film (trade name: Porum part number PH50, thickness: 50 μm, basis weight: 45 g / m 2 ) manufactured by Tokuyama Corporation into a commercially available panty liner shape. Next, the obtained liquid-absorbent sheet was cut out to a size slightly smaller than the backsheet, and adhesives were applied to the four corners of the surface on which the superabsorbent resin was not adhered, and attached to the backsheet. An adhesive was applied to the end of the back sheet, and a surface material (top sheet) to be tested was further placed on the back sheet so that the machine axis direction (MD direction) was the length direction, and was attached. The underside of the back sheet can be adhesively fixed to the underwear using a double-sided tape.
The obtained panty liner was worn for one day on the third day after the end of menstruation in summer, and a sensory evaluation was performed. The content of the evaluation was graded for softness, stuffiness, flexibility, fluff, stickiness, and when there was a vaginal discharge, absorptivity and stickiness. The number of monitors was evaluated by the average value of 10 persons.
Level 5: Comfortable. Or no problem.
Grade 3: I'm slightly worried. Or slightly uncomfortable.
Level 1: I am very worried. Or very uncomfortable.

[実施例1]
コットンリンターを銅アンモニア溶液で溶解し、直径0.3mmの原液吐出孔が180.9個/cm2 である紡口を用い、流下緊張下で連続してネット上に5層重ねで紡糸してシートを形成させ、高圧水流により繊維を交絡させながらシートに貫通孔及び凹部を形成させた後、乾燥させて再生セルロース連続長繊維不織布を得た。得られた再生セルロース連続長繊維不織布は、目付18.7g/m2 、厚み0.13mm、平均単繊度が0.20dtex、貫通孔の平均面積0.253mm2 、シート表面に占める貫通孔の面積率が15.3%であり、0.1〜0.55dtexの単繊維が表面に占める割合は100%であった。
得られた再生セルロース連続長繊維不織布の性能評価結果を表1(但し、湿潤形態保持率はWet保形率と略記する。)に、吸収性物品としての機能評価結果を表2に示す。表からもわかるとおり、得られた再生セルロース連続長繊維不織布は吸収性物品用表面材として極めて良好なものであった。
[Example 1]
The cotton linter is dissolved in a copper ammonia solution, and spun in five layers continuously on a net under a flowing tension using a spinneret having a stock solution discharge hole having a diameter of 0.3 mm of 180.9 pieces / cm 2. A sheet was formed, and through holes and recesses were formed in the sheet while the fibers were entangled by a high-pressure water flow, followed by drying to obtain a regenerated cellulose continuous continuous fiber nonwoven fabric. The resulting regenerated cellulose continuous long fiber nonwoven fabric, the area of the basis weight 18.7 g / m 2, thickness 0.13 mm, an average single fineness of 0.20Dtex, average area 0.253Mm 2 of the through hole, the through hole occupying the seat surface The ratio was 15.3%, and the ratio of single fibers of 0.1 to 0.55 dtex occupying the surface was 100%.
The performance evaluation results of the obtained regenerated cellulose continuous continuous fiber nonwoven fabric are shown in Table 1 (however, the wet form retention is abbreviated as Wet shape retention), and the function evaluation results as an absorbent article are shown in Table 2. As can be seen from the table, the obtained regenerated cellulose continuous filament nonwoven fabric was extremely good as a surface material for absorbent articles.

[実施例2]
原液の吐出量を増加させた以外は実施例1と同様の方法で再生セルロース連続長繊維不織布を得た。得られた再生セルロース連続長繊維不織布は、目付29.3g/m2 、厚み0.22mm、平均単繊度が0.35dtex、貫通孔の平均面積0.295mm2 、シート表面に占める貫通孔の面積率が14.9%であり、0.1〜0.55dtexの単繊維が表面に占める割合は100%であった。 得られた再生セルロース連続長繊維不織布の性能評価結果を表1に、吸収性物品としての機能評価結果を表2に示す。表からもわかるとおり、得られた再生セルロース連続長繊維不織布は吸収性物品用表面材として極めて良好なものであった。
[Example 2]
A regenerated cellulose continuous continuous fiber nonwoven fabric was obtained in the same manner as in Example 1 except that the discharge amount of the stock solution was increased. The resulting regenerated cellulose continuous long fiber nonwoven fabric, the area of the basis weight 29.3 g / m 2, thickness 0.22 mm, an average single fineness of 0.35Dtex, average area 0.295Mm 2 of the through hole, the through hole occupying the seat surface The ratio was 14.9%, and the ratio of single fibers of 0.1 to 0.55 dtex occupying the surface was 100%. Table 1 shows the performance evaluation results of the obtained regenerated cellulose continuous continuous fiber nonwoven fabric, and Table 2 shows the function evaluation results as an absorbent article. As can be seen from the table, the obtained regenerated cellulose continuous filament nonwoven fabric was extremely good as a surface material for absorbent articles.

[実施例3]
実施例1において、積層するシートの1層目と5層目は直径0.3mmの原液吐出孔が180.9個/cm2 である紡口を用い、2〜4層目は直径0.6mmの原液吐出孔が45.3個/cm2 である紡口を用い、紡糸されたシートを積層するネットのスピードを遅くした以外は実施例1と同様の方法で再生セルロース連続長繊維不織布を得た。得られた再生セルロース連続長繊維不織布は、目付28.9g/m2 、厚み0.23mm、平均単繊度が0.20dtexと2.1dtexの2種類であり、貫通孔の平均面積0.283mm2 、シート表面に占める貫通孔の面積率が19.4%であり、0.1〜0.55dtexの単繊維が表面に占める割合は73%であった。
得られた再生セルロース連続長繊維不織布の性能評価結果を表1に、吸収性物品としての機能評価結果を表2に示す。表からもわかるとおり、得られた再生セルロース連続長繊維不織布は吸収性物品用表面材として極めて良好なものであった。
[Example 3]
In Example 1, the first layer and the fifth layer of the sheets to be laminated were formed by using a spout having a stock solution discharge hole having a diameter of 0.3 mm of 180.9 / cm 2 , and the second to fourth layers having a diameter of 0.6 mm. A regenerated cellulose continuous continuous fiber nonwoven fabric was obtained in the same manner as in Example 1, except that the stock solution discharging hole of 45.3 / cm 2 was used and the speed of the net for laminating the spun sheets was reduced. Was. The obtained regenerated cellulose continuous filament nonwoven fabric has a basis weight of 28.9 g / m 2 , a thickness of 0.23 mm, an average single fineness of 0.20 dtex and 2.1 dtex, and an average area of the through holes of 0.283 mm 2. The area ratio of the through-holes occupying the sheet surface was 19.4%, and the ratio of single fibers of 0.1 to 0.55 dtex occupying the surface was 73%.
Table 1 shows the performance evaluation results of the obtained regenerated cellulose continuous continuous fiber nonwoven fabric, and Table 2 shows the function evaluation results as an absorbent article. As can be seen from the table, the obtained regenerated cellulose continuous filament nonwoven fabric was extremely good as a surface material for absorbent articles.

[比較例1]
実施例1において直径0.6mmの原液吐出孔が45.3個/cm2 である紡口を用いた以外は実施例1と同様の方法で再生セルロース連続長繊維不織布を得た。得られた再生セルロース連続長繊維不織布は、目付18.5g/m2 、厚み0.13mm、平均単繊度が2.2dtex、貫通孔の平均面積0.215mm2 、シート表面に占める貫通孔の面積率が19.1%であり、0.1〜0.55dtexの単繊維が表面に占める割合は0%であった。
得られた再生セルロース連続長繊維不織布の性能評価結果を表1に、吸収性物品としての機能評価結果を表2に示す。表1〜2からもわかるとおり、得られた再生セルロース連続長繊維不織布は吸収性物品用表面材として実施例に比べて、特に湿潤時の形態保持性(Wet保形率、ヨレ性)と着用感が劣るものであった。
[Comparative Example 1]
A regenerated cellulose continuous continuous fiber nonwoven fabric was obtained in the same manner as in Example 1, except that a spinneret having a stock solution discharge hole having a diameter of 0.6 mm and having a diameter of 45.3 / cm 2 was used. The resulting regenerated cellulose continuous long fiber nonwoven fabric, the area of the basis weight 18.5 g / m 2, thickness 0.13 mm, an average single fineness of 2.2 dtex, average area 0.215 mm 2 of the through hole, the through hole occupying the seat surface The ratio was 19.1%, and the ratio of single fibers of 0.1 to 0.55 dtex occupying the surface was 0%.
Table 1 shows the performance evaluation results of the obtained regenerated cellulose continuous continuous fiber nonwoven fabric, and Table 2 shows the function evaluation results as an absorbent article. As can be seen from Tables 1 and 2, the obtained regenerated cellulose continuous long-fiber nonwoven fabric was used as a surface material for absorbent articles, especially when it was wet, in terms of shape retention (wet shape retention, repellency) when wet. The feeling was inferior.

[比較例2]
比較例1において原液吐出量を増加させた以外は比較例1と同様の方法で再生セルロース連続長繊維不織布を得た。得られた再生セルロース連続長繊維不織布は、目付30.1g/m2 、厚み0.24mm、平均単繊度が2.1dtex、貫通孔の平均面積0.247mm2 、シート表面に占める貫通孔の面積率が18.2%であり、0.1〜0.55dtexの単繊維が表面に占める割合は0%であった。
得られた再生セルロース連続長繊維不織布の性能評価結果を表1に、吸収性物品としての機能評価結果を表2に示す。表1〜2からもわかるとおり、得られた再生セルロース連続長繊維不織布は吸収性物品用表面材として実施例に比べて、特に湿潤時の形態保持性(Wet保形率、ヨレ性)と着用感が劣るものであった。
[Comparative Example 2]
A regenerated cellulose continuous filament nonwoven fabric was obtained in the same manner as in Comparative Example 1 except that the discharge amount of the undiluted solution was increased in Comparative Example 1. The obtained regenerated cellulose continuous filament nonwoven fabric had a basis weight of 30.1 g / m 2 , a thickness of 0.24 mm, an average single fineness of 2.1 dtex, an average area of the through holes of 0.247 mm 2 , and an area of the through holes occupying the sheet surface. The ratio was 18.2%, and the ratio of single fibers of 0.1 to 0.55 dtex occupying the surface was 0%.
Table 1 shows the performance evaluation results of the obtained regenerated cellulose continuous continuous fiber nonwoven fabric, and Table 2 shows the function evaluation results as an absorbent article. As can be seen from Tables 1 and 2, the obtained regenerated cellulose continuous long-fiber nonwoven fabric was used as a surface material for absorbent articles, especially when it was wet, in terms of shape retention (wet shape retention, repellency) when wet. The feeling was inferior.

Figure 2004255176
Figure 2004255176

Figure 2004255176
Figure 2004255176

本発明の吸収性物品用表面材は湿潤時の形態保持性が極めて良好であるため、パンティライナー、失禁パッド、生理用ナプキン、産褥パッド(お産用ナプキン)、使い捨ておむつ等の吸収性物品に好適に利用できる。   Since the surface material for absorbent articles of the present invention has extremely good shape retention when wet, it is suitable for absorbent articles such as panty liners, incontinence pads, sanitary napkins, puerperal pads (napkins for childbirth), and disposable diapers. Available to

本発明の湿潤形態保持率測定装置の模式図。FIG. 1 is a schematic diagram of a wet form retention rate measuring device of the present invention. 本発明の水平輸水速度測定装置の模式図。FIG. 1 is a schematic view of a horizontal water velocity measuring device of the present invention. 本発明のヨレ性評価サンプルの模式図。FIG. 4 is a schematic view of a sample for evaluating repellency according to the present invention. 本発明のヨレ性評価の模式図。FIG. 3 is a schematic diagram of evaluation of repellency according to the present invention.

符号の説明Explanation of reference numerals

1:架台
2:サンプル保持板(2枚の間にサンプルを挟んでネジで固定)
3:サンプル
4:荷重(下方のサンプル保持板との合計がサンプル重量の30重量%)
5:垂直距離 18mm
6:サンプル浸積距離 12mm
7:サンプル支えガラス棒 1.5mm
8:支えガラス棒ピッチ 10mm
9:表面材サンプル
10:架台
11:使用液 シャチハタスタンプインキ(S−1赤)水溶液
12:表面材サンプル
13:ポリエステル不織布
14:ガラス板
15:両面テープ
16:ガラス棒(直径12mm)
1: Stand 2: Sample holding plate (fix sample with screws between two plates)
3: Sample 4: Load (total with sample holding plate below is 30% by weight of sample weight)
5: Vertical distance 18mm
6: Sample immersion distance 12mm
7: Sample support glass rod 1.5mm
8: Support glass rod pitch 10mm
9: Surface material sample 10: Stand 11: Liquid used Shachihata stamp ink (S-1 red) aqueous solution 12: Surface material sample 13: Polyester nonwoven fabric 14: Glass plate 15: Double-sided tape 16: Glass rod (diameter 12mm)

Claims (5)

セルロース長繊維不織布からなる吸収性物品用表面材であって、該不織布の少なくとも表面を構成する繊維の70%以上が単繊度0.1〜0.55dtexであることを特徴とする吸収性物品用表面材。   A surface material for an absorbent article comprising a cellulose long-fiber nonwoven fabric, wherein at least 70% or more of the fibers constituting the surface of the nonwoven fabric have a single fineness of 0.1 to 0.55 dtex. Surface material. 該不織布の湿潤形態保持率が80%以上であることを特徴とする請求項1に記載の吸収性物品用表面材。   The surface material for an absorbent article according to claim 1, wherein the wet form retention of the nonwoven fabric is 80% or more. 該不織布が再生セルロース連続長繊維不織布であることを特徴とする請求項1または2に記載の吸収性物品用表面材。   The surface material for an absorbent article according to claim 1 or 2, wherein the nonwoven fabric is a regenerated cellulose continuous filament nonwoven fabric. 少なくとも表面材と吸収材を具備する吸収性物品であって、該表面材が請求項1〜3のいずれかに記載の吸収性物品用表面材であることを特徴とする吸収性物品。   An absorbent article comprising at least a surface material and an absorbent material, wherein the surface material is the surface material for an absorbent article according to any one of claims 1 to 3. 少なくとも吸収材を兼ねる表面材を具備する吸収性物品であって、該表面材が請求項1〜3のいずれかに記載の吸収性物品用表面材であることを特徴とする吸収性物品。   An absorbent article comprising at least a surface material also serving as an absorbent, wherein the surface material is the surface material for an absorbent article according to any one of claims 1 to 3.
JP2004026359A 2003-02-05 2004-02-03 Surface material for absorptive article and absorptive article using the same Pending JP2004255176A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2015159878A1 (en) * 2014-04-15 2017-04-13 ユニ・チャーム株式会社 Absorbent articles

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2015159878A1 (en) * 2014-04-15 2017-04-13 ユニ・チャーム株式会社 Absorbent articles

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