JP2003286136A - Foamy eye makeup cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To prepare a foamy eye makeup cosmetic making the best use of the characteristic of glittering powder, good in makeup film uniformity and usability, and easy to remove the makeup film. <P>SOLUTION: This eye makeup cosmetic contains the glittering powder and becomes foamy in its use. <P>COPYRIGHT: (C)2004,JPO

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a foamy eye makeup cosmetic containing a glittering powder. More specifically, the present invention makes use of the characteristics of the glittering powder, is excellent in the uniformity and usability of the cosmetic film, and is a foamy eye make-up cosmetic composition that is easy to remove the cosmetic film, particularly an aerosol type eye makeup. Up cosmetics.

[0002]

2. Description of the Related Art Conventional dosage forms of eye make-up cosmetics include, for example, eye color solids such as powder solids and oily solids, eyeliner pencils and liquids, mascara creams and liquids. Was the main dosage form.
Recently, the desire for makeup cosmetics has diversified,
For example, improving the makeup effect such as vividness of colors,
There has been a demand for eye make-up cosmetics that are stable in the product, that is, can be used continuously for a long period of time, and that they are easy to cleanse and have less influence on the skin. In particular, in the cosmetics for eyelashes, in addition to the volume increase and curling power of the eyelashes, the tendency to enjoy colors has become stronger.

[0003]

However, in the conventional makeup cosmetics, even if the glittering powder is blended to satisfy the vividness of the color among the above-mentioned desires, the original color of the powder is not enough. However, when a large amount of a solvent was added to improve the dispersibility of the powder, the stability over time was poor due to volatilization of the solvent during storage, and the original effect could not be provided. Further, when the adhesiveness was improved to obtain the effect of the glittering powder, it was difficult to completely remove the cosmetic material. Therefore, there has been a demand for an eye-makeup cosmetic composition that makes good use of the characteristics of the glittering powder, has excellent uniformity and usability of the cosmetic film, and is easy to remove the cosmetic film.

[0004]

Under such circumstances, the present inventor has conducted earnest research to solve the above problems, and as a result,
By making it into a foam at the time of use, the characteristics of the glittering powder are fully utilized, and the uniformity of the cosmetic film and the excellent usability such as the elasticity and stability of the foam are excellent, and the removal of the cosmetic film. It was found that a simple foamy eye makeup cosmetic can be obtained, and the present invention has been completed. That is, the foamy eye makeup cosmetic of the present invention is a foamy eye makeup cosmetic containing a glittering powder.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.
The foamy eye makeup cosmetic of the present invention is a foamy cosmetic when used, and any method such as a method of blending a propellant into an aerosol type or a method of foaming with a dispenser can be used. However, it is preferably a cosmetic composition containing a propellant to form an aerosol. When the foamy eye makeup cosmetic composition of the present invention is made into an aerosol type, it may contain a propellant, but in that case, a stock solution other than the propellant is used.

The glittering powder used in the present invention includes:
It is a powder that is usually used as a cosmetic, and may have any shape such as a plate shape, a spindle shape, a needle shape, and a particle structure such as a particle diameter, a porosity, and a non-porosity. Specifically, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated synthetic phlogopite, glass powder, titanium oxide coated glass powder, iron oxide mica titanium, black iron oxide mica titanium, iron oxide / black iron oxide Coated Mica Titanium, Konjo Coated Mica Titanium, Carmine Coated Mica Titanium, Carmine-Conju Coated Mica Titanium, Iron Oxide / Carmine Coated Mica Titanium, Iron Oxide / Conju Coated Mica Titanium, Chromium Oxide Coated Mica Titanium, Black Titanium Oxide Coated Mica Titanium, Bismuth oxychloride, fish scale foil, iron oxide coated mica, organic pigment coated mica titanium, aluminum powder, polyethylene terephthalate aluminum
Glittering powders such as epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, polyethylene terephthalate / aluminum / epoxy laminated powder and the like are used. Commercially available products include, for example, titanium oxide-coated mica, Flamenco Sparkle series, Chimica series (above, manufactured by Engelhard), Chimilon super series (manufactured by Merck), iron oxide / conju-coated mica titanium, Cloisone. Series, Duochrome series (above, Engelhard), titanium oxide coated synthetic phlogopite, Prominence series (Topy Industry), polyethylene terephthalate / aluminum / epoxy laminated powder, DC glitter series, AS glitter series (Above, manufactured by Fujiyama Sangyo Co., Ltd.) and the like can be used. The glittering powder used in the present invention is a fluorine compound, a silicone compound, a metal soap, lecithin, hydrogenated lecithin, N-.
One or two known coating agents such as long-chain acylamino acids, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes and surfactants
You may coat with 1 or more types. The amount of the glittering powder used in the present invention is in the entire composition (hereinafter, “in the entire composition” means
If a propellant is added, it should be in undiluted solution. ) 0.1-50
The mass% (hereinafter, simply indicated by “%”) is preferable, and within this range, a cosmetic having particularly vivid colors can be obtained.

By containing a water-soluble polymer in the foamy eye makeup cosmetic composition of the present invention, it acts as a protective colloid for the generated foam, so that the stability of the foam is remarkably improved and the usability is improved. Will be good. Further, the drying property of the decorative film is also improved. Examples of the water-soluble polymer used in the present invention include collagen hydrolyzate, cationized hydrolyzed collagen, coconut oil fatty acid hydrolyzed collagen, keratin, keratin hydrolyzate, cationized hydrolyzed keratin, elastin, elastin hydrolyzate. , Casein, casein sodium, casein hydrolyzate, gelatin, gelatin hydrolyzate, other soy protein, wheat protein, glutelin, whey powder, fibroin, glucagon, egg white, non-heat-coagulated egg white, egg white lysozyme, albumin fibrinogen, hemoglobin, globulin And proteins such as hydrolysates thereof or protein hydrolysates, polysaccharides such as guar gum, gum arabic, sodium alginate and carrageenan, methyl cellulose, hydroxyethyl cellulose Those of semi-synthetic polymer such as carboxymethyl cellulose, carboxyvinyl polymer, polyvinyl alcohol, polyvinyl pyrrolidone, alkylated carboxyvinyl polymer, mention may be made of synthetic such as sodium polyacrylate. Of these, gelatin and gelatin hydrolyzate are preferable in terms of forming bubbles having excellent dryness. In the present invention, the water-soluble polymer is one type or two types.
It is possible to use one or more kinds, but the blending amount is preferably 0.1 to 5% in the total composition, and in this range, usability,
In particular, a foam having good elasticity can be obtained.

In the eye makeup cosmetic of the present invention, in addition to the above-mentioned essential components, components usually used in cosmetics can be appropriately blended within a range that does not impair the effects of the present invention. For example, by containing a surfactant, the emulsification, powder dispersion, and foam stability can be improved. As the surfactant, any one can be used as long as it is a surfactant commonly used in cosmetics, and nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants and the like can be used. Can be mentioned. Among these, nonionic surfactants are preferable from the viewpoint of product stability. Examples of the nonionic surfactant include sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, ethylene oxide derivative of glycerin fatty acid ester, propylene glycol fatty acid ester, and ethylene oxide of propylene glycol fatty acid ester. Derivatives, polyethylene glycol fatty acid ester, sucrose ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene castor oil derivative, polyoxyethylene hydrogenated castor oil derivative, polyoxyethylene phytostanol Ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol Ether, polyoxyethylene cholesteryl ether, polyoxyalkylene-modified organopolysiloxanes, and the like. Of these, polyoxyethylene sorbitan fatty acid ester is particularly preferable. One kind or two or more kinds of nonionic surfactants can be used, and the amount thereof is 0.1 to 1 in the total composition.
% Is preferable, and more preferably 0.3 to 0.5%.

The aqueous component can be used as a base material and can improve the moisturizing property and the dispersion of powder. The aqueous component may be any component that is soluble in water, for example, alcohols such as ethyl alcohol and isopropyl alcohol,
Propylene glycol, 1,3-butylene glycol,
Glycols such as dipropylene glycol and polyethylene glycol; glycerols such as glycerin, diglycerin and polyglycerin; sugars (derivatives) such as sorbitol, maltitol, sucrose, starch and lactose.
Examples thereof include salts such as sodium chloride, magnesium chloride and the like, plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose, and water. Of these, lower alcohols such as ethyl alcohol are more preferable in terms of product stability when they contain an aqueous component or a non-aqueous component.

By containing the film-forming agent, the adhesiveness and the persistence can be improved especially in the cosmetics for eyelashes. Examples of the film forming agent include water-soluble film forming resins and film forming emulsion polymers. The water-soluble film-forming resin is other than the above-mentioned water-soluble polymers, and examples thereof include vinylpyrrolidone / vinyl acetate copolymer, methoxyethylene maleic anhydride copolymer, and amphoteric methacrylic acid ester copolymer. The film-forming emulsion polymer is a polymer compound dispersed in an aqueous solvent, and is not particularly limited as long as it is usually used in cosmetics, and any polymer can be used. For example, (meth) acrylic acid / alkyl (meth) acrylate copolymer emulsion polymer, alkyl (meth) acrylate copolymer emulsion polymer, alkyl (meth) acrylate / styrene copolymer emulsion polymer, vinylpyrrolidone / styrene Examples include copolymer emulsion polymers and silicone-based polymer emulsions. Among these, from the viewpoint of ease of removal, water solubility is preferable, and vinylpyrrolidone / vinyl acetate copolymer is particularly preferable. Water-soluble film forming agent is 1
One kind or two or more kinds can be used, but the blending amount thereof is preferably 0.1 to 10%, and more preferably 3 to 5% in the total composition.

Furthermore, a base material, an oily component as an emollient component, a powder component for the purpose of adjusting the feel and coloring, fibers for imparting the effect of making the eyelashes look long, an ultraviolet absorber, a moisturizing agent, an anti-fading agent, Antioxidants, defoamers, cosmetic ingredients, preservatives, fragrances, propellants and the like can be appropriately added within a range that does not impair the effects of the present invention.

As the oily component, hydrocarbons, fats and oils, waxes, regardless of the origin of animal oils, vegetable oils, synthetic oils, etc., and the properties of solid oils, semisolid oils, liquid oils, volatile oils, etc. Hydrogenated oils, ester oils, fatty acids, higher alcohols,
Examples thereof include silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents, and the like. Specifically, liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene, paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene-propylene copolymer, montan wax, Fischer-Tropsch wax and other hydrocarbons, mokuro, olive oil. , Oils such as castor oil, mink oil, macadamian nut oil, beeswax, carnauba wax, candelilla wax, waxes such as geiro, jojoba oil,
Cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, diisostearyl tribehenate, pentaerythritol rosinate, dioctanoic acid Neopentyl glycol, cholesterol fatty acid ester,
N-lauroyl-L-glutamic acid di (cholesteryl.
Behenyl octyldodecyl), stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, and other fatty acids, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, etc. Higher alcohols, low-polymerization degree dimethylpolysiloxane, high-degree polymerization degree dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, crosslinkable organopolysiloxane, fluorine-modified polysiloxane, and other silicones , Perfluorodecane, Perfluorooctane, Perfluoropolyether and other fluorinated oils, Lanolin, Lanolin acetate, Lanolin fatty acid isopropyl, Lanolin Lanolin derivatives such as call, 12
Examples thereof include oily gelling agents such as hydroxystearic acid, dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, aluminum isostearate and calcium stearate.

The powder component is not particularly limited as long as it is a powder generally used in cosmetics, such as a plate-like shape, a spindle-like shape, a needle-like shape and the like, a particle size, a particle structure such as porous and non-porous. In addition, inorganic powders, organic powders, pigment powders, composite powders and the like can be mentioned. Specifically, konjac, ultramarine, red iron oxide, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, titanium / titanium oxide sintered product, cerium oxide, magnesium oxide, zirconium oxide, antimony oxide, magnesium carbonate, calcium carbonate. , Chromium oxide, chromium hydroxide,
Carbon black, aluminum silicate, magnesium silicate, calcium silicate, barium silicate, aluminum magnesium silicate, magnesium aluminum metasilicate, mica, synthetic mica, synthetic sericite, sericite, talc, muscovite, phlogopite, red Mica, biotite, kaolin, barium sulfate, bentonite, smectite,
Inorganic powder such as diatomaceous earth, hydroxyapatite, boron nitride, polyamide resin, polyethylene resin, polyacryl resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, styrene-acryl copolymer Copolymer resin such as united resin, organic polymer resin powder such as polypropylene resin, silicone resin, urethane resin, organic powder such as N-acyl lysine, natural organic powder such as starch, silk powder, cellulose powder, organic Dye powders such as tar pigments and lake pigments of organic dyes, and composite powders such as titanium oxide-containing silicon dioxide and zinc oxide-containing silicon dioxide can be used, and these can be used alone or in combination of two or more. Further, these powders may be used as a composite of two or more kinds, such as fluorine compounds, silicone compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, higher fatty acids, higher alcohols, esters, waxes, The surface treatment may be carried out by a known method using one or more of waxes, fats and oils, hydrocarbons, surfactants, amino acid compounds, water-soluble polymers and the like.

Examples of the fibers include synthetic fibers such as nylon and polyester, artificial fibers such as rayon, natural fibers such as cellulose, and semisynthetic fibers such as acetate human silk.
As these fibers, those treated with general oil agents, silicone oils, fluorine compounds, surfactants and the like can also be used. Further, one kind or two or more kinds can be used, and when nylon is used, the length is 0.3 to 3 mm.
Those having a thickness of 0.1 to 20 denier are preferable, and those having a thickness of 0.5 to 10 denier are more preferable.

Examples of the ultraviolet absorber include benzophenone type, PABA type, cinnamic acid type, salicylic acid type, 4-
Moisturizers such as tert-butyl-4′-methoxydibenzoylmethane and oxybenzone, for example, lactate, pyrrolidonecarboxylate, and antioxidants,
Examples of cosmetic ingredients such as α-tocopherol and ascorbic acid include vitamins, anti-inflammatory agents, herbal medicines and the like, and examples of preservatives include paraoxybenzoic acid ester and phenoxyethanol.

When the aerosol type is used, a propellant is required, and as the propellant, those which are usually used in aerosol cosmetics and liquefied petroleum gas (hereinafter, referred to as "LPG") (mainly propane) are used. (Including gas, butane, isobutane), ethers such as dimethyl ether, CFC gas, nitrogen gas, and carbon dioxide gas. One or more of these can be used, but LPG, dimethyl ether, or a mixture thereof is preferable. The mixing ratio of the stock solution and the propellant is preferably 70/30 to 95/5 in terms of mass ratio.

The foamy eye make-up cosmetic composition of the present invention can be embodied as an aerosol type or a product which is sprayed in the form of foam from a nozzle of a container, and can be in the form of a solubilizing type or an emulsifying type. Examples of the eye makeup cosmetics include mascara, eye color, eyebrow, eyeliner, etc. Among them, the cosmetics for eyelashes are preferable in view of the effect.

[0018]

EXAMPLES The present invention will be further described below with reference to examples. These do not limit the present invention in any way.

Examples 1 to 4 and Comparative Examples 1 to 3: Mascara A mascara having a formulation shown in Table 1 was prepared, and the usability (spreadability, foam stability (elasticity)), uniformity of the cosmetic film, A sensory evaluation was performed by the following method regarding whether the cosmetic film was easily removed and whether the characteristic features of the glittering powder were utilized (color development).
The results are also shown in Table 1. It should be noted that Examples 1 to 4 are foam-like mascara, while Comparative Examples 1 to 3 are non-foam-like mascara.

[0020]

[Table 1]

* 1: Natrosol 250HHR (manufactured by Hercules) * 2: GKA (manufactured by Nitta Gelatin) * 3: PVP / VAE-735 (manufactured by ISP Van Dyke) * 4: Chlois en Rouge Flambe (manufactured by Engelhard) )

(Manufacturing Method) Examples 1 to 4 A. Mixing components (1) to (8), components (9), (10)
Mix evenly. B. Liquefied petroleum gas is filled in a commercially available pressure tight container. C. B is filled with A to obtain a product. Comparative Example 1 A. The components (1) to (8) are mixed, and the component (9) is uniformly mixed. B. A is filled in a container to obtain a product. Comparative Example 2 A. After components (11) to (13) are uniformly mixed at 110 ° C., (1), (15) and (16) are added and mixed uniformly. B. After mixing (4) to (8), (9) and (10) are mixed. C. Add B to A and emulsify uniformly. D. Fill C into a container to obtain a product. Comparative Example 3 A. The components (14), (21) and (22) are swollen. B. (12) and (16) to (20) are added and dissolved by heating. C. Add B to A and mix uniformly, and (5) to (7),
Add (9) and mix. D. Fill C into a container to obtain a product.

(Evaluation method) Each sample was evaluated by a sensory evaluation panel of 10 persons for each of the following a to e (1) in 7 steps using the absolute evaluation standard, and the average value of the evaluation of each sample was (2). The judgment was made using a four-step criterion. With regard to the evaluation item d, the sample was applied to the eyelashes, the panel was allowed to live a normal life, and after 6 hours, the ease of removal when using a commercially available makeup remover was evaluated. (Evaluation items) (a) Good spreadability (b) Stability of foam (elasticity) (c) Uniformity of cosmetic film (d) Ease of removal of cosmetic film (e) Color development (of glittering powder) Do you make use of the characteristics)

As is clear from the results shown in Table 1, the foamy eye makeup cosmetic composition of the present invention was found to be good in all evaluation items. Compared to this,
In Comparative Example 1 which was not in the form of foam, the usability was poor because the viscosity was low, and it was not possible to obtain a decorative film that utilized the characteristics of the glittering powder. In addition, Comparative Examples 2 and 3, which are conventional techniques, were not able to fully utilize the characteristics of the glittering powder and were not sufficient in removing the cosmetic film, as compared with the present invention.

Example 5: Foamed mascara (component) (%) (1) Polyoxyethylene sorbitan monooleate (20 EO) 1 (2) Water-soluble polymer * 1 0.3 (3) Water-soluble Polymer * 2 0.5 (4) Vinylpyrrolidone-vinyl acetate copolymer liquid * 3 8 (5) Perfume proper amount (6) 1,3-butylene glycol 5 (7) Ethanol 10 (8) Purified water balance (9 ) Glittering powder * 5 30 (10) Glittering powder * 6 10 (11) Nylon fiber (3% perfluoroalkyl phosphate ester diethanolamine salt treatment) 2 * 5: FLAMENCO SPARKLE BLUE 620J (manufactured by Topy Industries, Ltd.) * 6: Prominence BF (manufactured by Engelhard) (production method) A. Components (1) to (8) are mixed and stirred (9).
~ (11) is added. B. A is filled in a dispenser container to obtain a product. The foamy mascara obtained as described above has usability,
It was excellent in the uniformity of the cosmetic film and the ease of removing the cosmetic film, and it was a feature of the glittering powder.

Example 6: Foamed eye color (component) (%) (1) Polyoxyethylene sorbit tetraoleate 0.2 (2) Water-soluble polymer * 7 0.2 (3) Polybutene 2 (4) Liquid paraffin 1 (5) Paraoxybenzoic acid ester Appropriate amount (6) Perfume Appropriate amount (7) Para-aminobenzoic acid Appropriate amount (8) Beauty ingredient (Altea extract) Appropriate amount (9) Ethanol 10 (10) Purified water Remaining amount (11) Brightness Powder * 850 (12) Mica 5 * 7: Promois WK (manufactured by Seiwa Kasei Co., Ltd.) * 8: Chimilon Super Green (manufactured by Merck Co., Ltd.) (Production method) A. Ingredients (1) to (10) are mixed to obtain ingredient (11),
(12) is mixed uniformly (stock solution). B. Liquefied petroleum gas and dimethyl ether (mass ratio: 20 /
80) (Propellant) is filled in a commercially available pressure-resistant airtight container. B is filled with A to obtain a product (stock solution / propellant: 95
/ 5). The foamy eye color obtained as described above is excellent in usability, uniformity of the cosmetic film, and easy removal of the cosmetic film,
It was a feature of the glittering powder.

Example 7: Foamed eyebrow (component) (%) (1) Polyoxyethylene cholesteryl ether 0.25 (2) Water-soluble polymer * 9 0.3 (3) Stearic acid 2 (4) Beeswax 1 (5) Phenoxyethanol Appropriate amount (6) Perfume Appropriate amount (7) Beauty ingredient (Chamomila extract) Appropriate amount (8) Ethanol 10 (9) Purified water Remaining amount (10) Glittering powder * 10 1 * 9: Metroze 90SH-15000 ( Shin-Etsu Chemical Co., Ltd.) * 10: Cimikanu Antique Gold (manufactured by Engelhard) (Production method) A. Components (1) to (9) are mixed, and component (10) is uniformly mixed (stock solution). B. Filling a commercially available pressure-resistant airtight container with liquefied petroleum gas (propellant) C.I. B is filled with A to obtain a product (stock solution / propellant: 90
/ 10). The foamy eyebrow obtained as described above has excellent usability, uniformity of the cosmetic film, and easy removal of the cosmetic film,
It was a feature of the glittering powder.

Example 8: Foamed eyeliner (component) (%) (1) Polyoxyethylene glyceryl triisostearate 0.3 (2) Water-soluble polymer * 11 0.3 (3) Vinyl acetate resin emulsion ( Solid content 35%) 10 (4) Liquid paraffin 1 (5) Paraoxybenzoic acid ester Appropriate amount (6) Perfume Appropriate amount (7) Soybean extract solution Appropriate amount (8) Ethanol 10 (9) Purified water Remaining amount (10) Bright powder * 12 0.5 * 11 Carrageenan J (manufactured by Bert Knight) * 12 Duochrome GY227C (manufactured by Engelhard) (manufacturing method) A. Components (1) to (9) are mixed, and component (10) is uniformly mixed (stock solution). B. Filling a commercially available pressure-resistant airtight container with liquefied petroleum gas (propellant) C.I. B is filled with A to obtain a product (stock solution / propellant: 90
/ 10). The foam eyeliner obtained as described above has excellent usability, uniformity of the cosmetic film, and easy removal of the cosmetic film,
It was a feature of the glittering powder.

[0029]

Industrial Applicability As described in detail above, the foamy eye makeup cosmetic composition of the present invention utilizes the characteristics of the glittering powder, is excellent in the uniformity and usability of the cosmetic film, and is easy to remove the cosmetic film. It is a thing.

Claims (4)

[Claims] 1. A foamy eye make-up cosmetic comprising a glittering powder. 2. The foamy eye makeup cosmetic composition according to claim 1, wherein the content of the glittering powder is 0.1 to 50 mass%. 3. The foamy eye makeup cosmetic according to claim 1, further comprising a water-soluble polymer. 4. The foamy eye makeup cosmetic according to claim 1, wherein the eye makeup cosmetic is for eyelashes.